[go: up one dir, main page]

EP0564309A1 - Verfahren zur Herstellung von Stahlblechen und Stahlbleche, nach diesem Verfahren hergestellt - Google Patents

Verfahren zur Herstellung von Stahlblechen und Stahlbleche, nach diesem Verfahren hergestellt Download PDF

Info

Publication number
EP0564309A1
EP0564309A1 EP93400287A EP93400287A EP0564309A1 EP 0564309 A1 EP0564309 A1 EP 0564309A1 EP 93400287 A EP93400287 A EP 93400287A EP 93400287 A EP93400287 A EP 93400287A EP 0564309 A1 EP0564309 A1 EP 0564309A1
Authority
EP
European Patent Office
Prior art keywords
steel
sheet
temperature
rolling
less
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP93400287A
Other languages
English (en)
French (fr)
Other versions
EP0564309B1 (de
Inventor
Christian Marteau
Jacques Corquillet
Xavier Bano
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sollac SA
Original Assignee
Sollac SA
Lorraine de Laminage Continu SA SOLLAC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=9427200&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0564309(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Sollac SA, Lorraine de Laminage Continu SA SOLLAC filed Critical Sollac SA
Publication of EP0564309A1 publication Critical patent/EP0564309A1/de
Application granted granted Critical
Publication of EP0564309B1 publication Critical patent/EP0564309B1/de
Anticipated expiration legal-status Critical
Revoked legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES, PROFILES OR LIKE SEMI-MANUFACTURED PRODUCTS OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C47/00Winding-up, coiling or winding-off metal wire, metal band or other flexible metal material characterised by features relevant to metal processing only
    • B21C47/02Winding-up or coiling
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese

Definitions

  • the present invention relates to a process for producing a sheet from a steel slab, having very high mechanical strength, a formability and excellent weldability.
  • the present invention also relates to a steel sheet obtained by this process.
  • the wheel sails have thinned parts which constitute zones of weakness for these wheels.
  • manufacturers are moving towards steel having an increasingly high mechanical resistance as well as excellent stamping and welding properties.
  • the steel sheets used to make this type of part are generally part of the range of hot-rolled flat products whose mechanical characteristics are obtained by controlled rolling on a rolling mill with wide strips.
  • HLE high yield strength steel
  • HLE steel is a microalloyed steel which has an elastic limit between 315 and 690 MPa, but which has a poor formability due in particular to a ratio between the elastic limit Re and the high mechanical resistance Rm , i.e. greater than 0.85.
  • DUAL PHASE steels are also known, the structure of which is of the ferrite-martensite type and which have remarkable formability.
  • HR steels are also part of steels with high mechanical characteristics and are carbon-manganese steels which undergo a sufficiently rapid cooling after rolling associated with a winding at around 400-450 ° C.
  • the steel sheets thus produced have a ferrito-bainitic structure of intermediate formability between the HLE steel sheets and the DUAL PHASE.
  • TRIP steels are also known, that is to say with induced plastic transformation, which combine a very high mechanical resistance, greater than 800 MPa with high elongations which give them excellent formability.
  • the object of the present invention is to remedy the drawbacks mentioned above by proposing a method for producing a steel sheet having at the same time a very high mechanical strength, a good formability and an excellent weldability.
  • the steel sheets which are the subject of the present invention are obtained by hot rolling of slabs from, for example, a continuous casting installation.
  • the nitrogen content of 80 ppm verifies the 3.5N ⁇ Ti relationship, the rest being made up of iron and impurities.
  • the steel slabs from the continuous casting are heated in an oven at a temperature between 1200 and 1250 ° C and, more precisely at 1250 ° C, then introduced into a rolling mill with wide strips comprising a roughing train and a finishing train, each consisting of several rolling mill stands.
  • the essential function of this rolling is to reduce the thickness of the slab.
  • the blank obtained is then engaged in the finishing train in which a work hardening is carried out with a reduction rate varying from 70 to 95% thus producing a refining of the austenite grains.
  • the rolled blank in the finishing train is permanently engaged in one of the cages of said train where the recrystallization phenomenon is delayed.
  • the sheet that is obtained has a thickness of between 2 and 10 mm and its temperature, also called the end of rolling temperature, is between 800 and 900 ° C. and for example equal to 845 °. vs.
  • the casting of thin slabs makes it possible in particular to suppress the passage of slabs in a roughing train.
  • the thin slab is directly engaged in the finishing train in which the hardening is carried out with a reduction rate varying from 70 to 95%.
  • the combined effect of boron and niobium makes it possible to inhibit the germination of the ferrite and thus the austenite begins its transformation into bainite at temperatures lower than the usual temperatures.
  • Niobium is completely effective from 0.04% but, beyond 0.06%, the shaping properties of steel deteriorate.
  • the optimum boron is between 10 and 40ppm.
  • microalloy elements of steel are not used as above, but to inhibit ferritic and pearlitic transformation.
  • the choice of the end of rolling temperature makes it possible to generate more or less defects, called dislocations, in the crystal lattice and in which the bainite germinates.
  • the austenite is cooled at a speed of between 50 and 150 ° C / s, preferably equal to 80 ° C / s.
  • the cooled sheet is then wound at a temperature between 500 and 600 ° C, preferably between 560 and 590 ° C, and for example equal to 580 ° C.
  • the Applicant has had the merit of realizing that molybdenum allows the formation of highly fragmented complex carbides at a high winding temperature above 500 ° C and which maintain a high mechanical resistance Rm between 800 and 900 MPa.
  • a silicon content of less than 0.5% makes it possible to improve the elongation and therefore the shaping properties and makes it possible to avoid the formation of surface defects which are called fayalite during the heating of the slabs in the ovens .
  • the fayalite Fe2SiO4 forms with FeO an eutectic whose melting point is at 1177 ° C, thus this eutectic penetrates along the gamma grain boundaries and the incrustations during rolling in the roughing train are revealed during the pickling.
  • the elongation of such a proportional test piece taken in the long direction from a steel sheet is greater than 15% and for example equal to 18.2%.
  • the elongation is greater than 13% and for example equal to 15%.
  • the low Re / Rm ratio of the steel thus obtained and its elongation favorably allow its use for the manufacture of hollow profiles and in particular of tubes with high mechanical resistance.
  • the sulfur content must be less than 0.01% and this element must be globularized.
  • the presence of a low carbon content gives the steel excellent weldability, but it is advisable not to exceed the value of 0.05% beyond which there is an increase in the dispersion of the mechanical characteristics.
  • the low carbon content also prevents the formation of martensite which is rather harmful to the ductility of steel.
  • titanium is present in steel to protect boron from nitrogen and allow synergy between boron and niobium.
  • the sheet After the winding operation, the sheet has all its mechanical characteristics of use.
  • pickling is carried out, for example by immersion in one or more hydrochloric acid baths in order to remove all traces of oxide on the face of said sheet.
  • the sheet can be cut into strips by shears before delivery.
  • the strips thus obtained also have a tight flatness for which the corrugation deflection is less than 1% of the length of the corrugation and in all cases less than 10mm.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
  • Heat Treatment Of Steel (AREA)
EP19930400287 1992-02-28 1993-02-04 Verfahren zur Herstellung von Stahlblechen und Stahlbleche, nach diesem Verfahren hergestellt Revoked EP0564309B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9202407A FR2688009B1 (fr) 1992-02-28 1992-02-28 Procede d'elaboration d'une tole d'acier et tole d'acier obtenue par ce procede.
FR9202407 1992-02-28

Publications (2)

Publication Number Publication Date
EP0564309A1 true EP0564309A1 (de) 1993-10-06
EP0564309B1 EP0564309B1 (de) 1996-06-05

Family

ID=9427200

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19930400287 Revoked EP0564309B1 (de) 1992-02-28 1993-02-04 Verfahren zur Herstellung von Stahlblechen und Stahlbleche, nach diesem Verfahren hergestellt

Country Status (3)

Country Link
EP (1) EP0564309B1 (de)
DE (1) DE69302950T2 (de)
FR (1) FR2688009B1 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002048410A1 (de) * 2000-12-16 2002-06-20 Thyssenkrupp Stahl Ag Verfahren zum herstellen von warmband oder -blech aus einem mikrolegierten stahl

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2000542A1 (de) * 1968-01-22 1969-09-12 Nippon Kokan Kk
GB2019439A (en) * 1978-04-05 1979-10-31 Nippon Steel Corp Process for producing high-tension bainitic steel having high toughness and excellent weldability
EP0080809A1 (de) * 1981-10-31 1983-06-08 Nippon Steel Corporation Verfahren zur Herstellung von Stahl mit hoher Festigkeit und hoher Kaltzähigkeit

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2000542A1 (de) * 1968-01-22 1969-09-12 Nippon Kokan Kk
GB2019439A (en) * 1978-04-05 1979-10-31 Nippon Steel Corp Process for producing high-tension bainitic steel having high toughness and excellent weldability
EP0080809A1 (de) * 1981-10-31 1983-06-08 Nippon Steel Corporation Verfahren zur Herstellung von Stahl mit hoher Festigkeit und hoher Kaltzähigkeit

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002048410A1 (de) * 2000-12-16 2002-06-20 Thyssenkrupp Stahl Ag Verfahren zum herstellen von warmband oder -blech aus einem mikrolegierten stahl

Also Published As

Publication number Publication date
DE69302950T2 (de) 1997-01-16
FR2688009A1 (fr) 1993-09-03
FR2688009B1 (fr) 1994-05-27
EP0564309B1 (de) 1996-06-05
DE69302950D1 (de) 1996-07-11

Similar Documents

Publication Publication Date Title
EP2155915B2 (de) Verfahren zur herstellung kaltgewalzter und geglühter stahlbleche von sehr hoher festigkeit und in diesem verfahren hergestellte bleche
EP2707514B1 (de) Stahlblech mit hoher mechanischer festigkeit, duktilität und formbarkeit, herstellungsverfahren und anwendung derartiger bleche
EP3167091B1 (de) Heissgewalztes stahlblech und zugehöriges herstellungsverfahren
CA3047690C (en) Tempered and coated steel sheet and a method of manufacturing the same
EP2855725B1 (de) Warm- oder kaltgewalzter stahl mit niedriger dichte, verfahren zur realisierung davon und verwendung davon
EP2707515B1 (de) Verfahren zur herstellung eines martensitisches sehr hoher dehngrenze stahlblech
EP2020451A1 (de) Verfahren zur Herstellung von Stahlblechen mit hoher Widerstandsfähigkeit und Duktilität und damit hergestellte Bleche
EP1427866B1 (de) Verfahren zur herstellung von geschweissten röhren und dadurch hergestelltes rohr
JP2008519160A (ja) Twip特性をもつ高強度の鋼ストリップ又はシートの製造方法、コンポーネント及び高強度鋼ストリップ又はシートの製造方法
KR101797387B1 (ko) 성형성이 우수한 초고강도 박물 열연강판 및 그 제조방법
EP3433387B1 (de) Verfahren zur herstellung von kaltgewalzten, geschweissten stahlblechen und so hergestellte bleche
FR2486101A1 (fr) Tole d'acier laminee a froid, de solidite elevee, formable par pressage de structure a deux phases et procede pour la production de cette tole
CN110088331B (zh) 焊接性优异的电阻焊钢管用热轧钢板及其制造方法
EP2883974B1 (de) Walzdraht mit guter festigkeit und duktilität sowie herstellungsverfahren dafür
BE1011149A3 (fr) Acier ductile a haute limite elastique et procede de fabrication de cet acier.
EP1099769B1 (de) Verfahren zur Herstellung von warmgewalztem, hochfestem Stahlblech zur Umformung und insbesondere zum Tiefziehen
CN111511935B (zh) 耐久性优异的热轧钢板及其制造方法
JP2009191330A (ja) 電縫鋼管
FR2833617A1 (fr) Procede de fabrication de toles laminees a froid a tres haute resistance d'aciers dual phase micro-allies
JP6287623B2 (ja) 高強度熱延鋼板とその製造方法
EP1138796B1 (de) Hochfester warmgewalzter Stahl mit hoher Streckgrenze zur Verwendung in Kraftfahrzeugen
EP0564309B1 (de) Verfahren zur Herstellung von Stahlblechen und Stahlbleche, nach diesem Verfahren hergestellt
JPS6145688B2 (de)
BE1010142A6 (fr) Procede pour la fabrication d'une bande laminee a chaud en acier a haute resistance.
BE1010093A6 (fr) Procede pour fabriquer une bande laminee a chaud en acier a haute resistance.

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): DE FR GB IT

17P Request for examination filed

Effective date: 19930818

17Q First examination report despatched

Effective date: 19951110

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): DE FR GB IT

REF Corresponds to:

Ref document number: 69302950

Country of ref document: DE

Date of ref document: 19960711

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 19960627

ITF It: translation for a ep patent filed
PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

PLBQ Unpublished change to opponent data

Free format text: ORIGINAL CODE: EPIDOS OPPO

PLBF Reply of patent proprietor to notice(s) of opposition

Free format text: ORIGINAL CODE: EPIDOS OBSO

26 Opposition filed

Opponent name: BRITISH STEEL PLC

Effective date: 19970305

Opponent name: HOOGOVENS STAAL BV

Effective date: 19970305

Opponent name: THYSSEN STAHL AG

Effective date: 19970304

PLBF Reply of patent proprietor to notice(s) of opposition

Free format text: ORIGINAL CODE: EPIDOS OBSO

PLBF Reply of patent proprietor to notice(s) of opposition

Free format text: ORIGINAL CODE: EPIDOS OBSO

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 19980127

Year of fee payment: 6

Ref country code: GB

Payment date: 19980127

Year of fee payment: 6

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 19980226

Year of fee payment: 6

RDAH Patent revoked

Free format text: ORIGINAL CODE: EPIDOS REVO

RDAG Patent revoked

Free format text: ORIGINAL CODE: 0009271

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: PATENT REVOKED

27W Patent revoked

Effective date: 19980526

GBPR Gb: patent revoked under art. 102 of the ep convention designating the uk as contracting state

Free format text: 980526