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EP0550077A1 - Körnige Bleichmittelzusammensetzung für Wäsche - Google Patents

Körnige Bleichmittelzusammensetzung für Wäsche Download PDF

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Publication number
EP0550077A1
EP0550077A1 EP92200005A EP92200005A EP0550077A1 EP 0550077 A1 EP0550077 A1 EP 0550077A1 EP 92200005 A EP92200005 A EP 92200005A EP 92200005 A EP92200005 A EP 92200005A EP 0550077 A1 EP0550077 A1 EP 0550077A1
Authority
EP
European Patent Office
Prior art keywords
percarbonate
compositions
sodium
bleaching composition
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP92200005A
Other languages
English (en)
French (fr)
Inventor
Marina Trani
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to EP92200005A priority Critical patent/EP0550077A1/de
Priority to RU94035995/04A priority patent/RU94035995A/ru
Priority to BR9207019A priority patent/BR9207019A/pt
Priority to KR1019940702293A priority patent/KR940703911A/ko
Priority to JP5511910A priority patent/JPH07502770A/ja
Priority to CA002126847A priority patent/CA2126847A1/en
Priority to PCT/US1992/011222 priority patent/WO1993012843A1/en
Priority to AU34224/93A priority patent/AU666918B2/en
Priority to MX9207671A priority patent/MX9207671A/es
Priority to MA23046A priority patent/MA22754A1/fr
Priority to CN93101189A priority patent/CN1075749A/zh
Publication of EP0550077A1 publication Critical patent/EP0550077A1/de
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/1273—Crystalline layered silicates of type NaMeSixO2x+1YH2O
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3942—Inorganic per-compounds

Definitions

  • the present invention relates to bleaching compositions for laundry.
  • Granular laundry bleaching compositions are described which comprise percarbonate as the bleaching specie, said compositions being stable upon storage.
  • the inorganic perhydrate bleach most widely used in the context of laundry bleaching is sodium perborate in the form of either the monohydrate or tetrahydrate.
  • concerns about the impact of boron salts on the environment have led to an increasing interest in other perhydrate salts, of which sodium percarbonate is the most readily available.
  • Percarbonate salts particularly sodium percarbonate
  • detergent compositions containing sodium percarbonate are known in the art.
  • Percarbonate salts, particularly sodium percarbonate are attractive perhydrates for use in detergent compositions because they dissolve readily in water, are weight efficient and, after giving up their available oxygen, provide a useful source of carbonate ions for detergency purposes.
  • percarbonate salts have been restricted hitherto by the relative instability of the bleach both as is and in use .
  • Sodium percarbonate loses its available oxygen at a significant rate in the presence of ions of heavy metals such as iron, copper and manganese and also in the presence of moisture, these effects being accelerated at temperatures in excess of about 30°C.
  • Moisture and heavy metal ions are unavoidable components of conventional granular laundry treatment compositions. Also percarbonate decomposition due to moisture becomes more of an issue during storage as laundry treatment products are often stored in humid environments when the product picks up moisture. This has resulted in marginally acceptable percarbonate bleach stability under Northern European summer conditions, where the average maximum temperature over the hottest months is from 21°C to 25°C, and unacceptable stability under temperatures higher than this. Such conditions are found in the Middle East and Southern Asia and also in Southern Europe where average maximum temperatures are in the 27°C to 33°C range for the hottest summer month.
  • composition comprising an alkali metal salt of percarbonate together with a crystalline layered silicate or mixtures thereof.
  • Granular bleaching compositions comprising percarbonate have been described for instance in FR 2,385,837, US 4,428,914 and GB 1,553,505.
  • Crystalline layered silicate and their methods of preparation have been described for instance in EP-A-164 514, DE-A-34 17 649 and DE-A-37 42 043 and their application to the field of laundry treatment has been described in applicant's copending British applications GB 90 21 761.3, GB 90 18157.9 and GB 91 08639.7.
  • compositions according to the present invention also allow adequate control of the pH in the bleaching liquor, giving appropriate balance between bleaching performance and fabric safety.
  • compositions according to the present invention are granular bleaching compositions comprising more than 20% and up to 80% by weight of the total composition of an alkali metal salt of percarbonate bleach and from 5% to 80% by weight of the total composition of a crystalline layered silicate of formula NaMSi x O 2x+1 .yH2O wherein M is sodium or hydrogen, x is a number of from 1.9 to 4 and y is a number of from 0 to 20, or mixtures thereof.
  • Preferred compositions herein further comprise an anhydrous acidifying agent, preferably citric acid.
  • the compositions according to the present invention comprise an alkali metal salt of percarbonate, preferably sodium percarbonate.
  • Sodium percarbonate is available commercially as a crystalline solid. Most commercially available material includes a low level of a heavy metal sequestrant such as EDTA, 1-hydroxyethylidene 1, 1-diphosphonic acid (HEDP) or an amino-phosphonate, that is incorporated during the manufacturing process.
  • EDTA 1-hydroxyethylidene 1, 1-diphosphonic acid
  • HEDP 1-diphosphonic acid
  • the percarbonate can be incorporated into detergent compositions without additional protection.
  • the percarbonate Whilst heavy metals present in the sodium carbonate used to manufacture the percarbonate can be controlled by the inclusion of sequestrants in the reaction mixture, it is preferred that the percarbonate be protected from heavy metals present as impurities in other ingredients of the product. It has been found that the total level of Iron, Copper and Manganese ions in the product should not exceed 25 ppm and preferably should be less than 20 ppm in order to avoid an unacceptably adverse effect on percarbonate stability.
  • compositions according to the present invention comprise more than 20% by weight of the total composition of percarbonate, up to 80% by weight of the total composition, preferably from 40% to 50%.
  • the second essential component of the invention is a crystalline layered silicate.
  • the crystalline layered silicates suitable for use herein are of the granular formula NaMSi x O 2x+1 .yH2O wherein M is sodium or hydrogen, x is a number from 1.9 to 4 and y is a number from 0 to 20, or mixtures thereof.
  • Crystalline layered sodium silicates of this type are disclosed in EP-A-164 514 and methods for their preparation are disclosed in DE-A-34 17 649 and DE-A-37 42 043.
  • x in the general formula above has a value of 2, 3 or 4 and is preferably 2.
  • M is sodium and y is 0 and preferred examples of this formula comprise the ⁇ , ⁇ , ⁇ and ⁇ forms of Na2Si2O5
  • These materials are available from Hoechst AG FRG as respectively NaSKS-5, NaSKS-7, NaSKS-11 and NaSKS-6.
  • the most preferred material is ⁇ - Na2Si2O5 , NaSKS-6.
  • Crystalline layered silicates are incorporated either as dry mixed solids, or as solid components of agglomerates with other components.
  • compositions according to the present invention comprise from 5% to 80% by weight of the total composition of said crystalline layered silicates or mixtures thereof, preferably from 15% to 25%.
  • compositions according to the present invention further comprise an anhydrous acidifying agent or mixtures thereof.
  • the purpose of said acidifying agent is to control the alkalinity generated by the percarbonate in the bleaching liquor. Said agent need to be incorporated in the product in an anhydrous form, and to have a good stability in oxidizing environment.
  • Suitable anhydrous acidifying agents for use herein are carboxylic acids such as citric acid, succinic acid, adipic acid, glutaric acid, 3 chetoglutaric acid, citramalic acid, tartaric acid and maleic acid.
  • Other suitable acidifying agents include sodium bicarbonate, sodium sesquicarbonate and silicic acid. Highly preferred for use herein is citric acid.
  • citric acid is commercially available in anhydrous form, it additionally acts as a builder and a chelant, and it is biodegradable.
  • the compositions according to the present invention comprise from up to 15% by weight of the total composition of anhydrous citric acid, preferably from 2% to 8%, most preferably about 5%.
  • compositions in accordance with the invention can also comprise optional ingredients such as optical brighteners, anti dusting agents such as olefines and waxes, enzymes, chelants, dispersants, surfactants, soil release agents, photoactivated bleaches such as Zn phthalocyanine sulphonate, dyes, pigments and perfumes are examples of such optional ingredients and can be added in varying amounts as desired.
  • optional ingredients such as optical brighteners, anti dusting agents such as olefines and waxes, enzymes, chelants, dispersants, surfactants, soil release agents, photoactivated bleaches such as Zn phthalocyanine sulphonate, dyes, pigments and perfumes are examples of such optional ingredients and can be added in varying amounts as desired.
  • Optional but highly preferred ingredients are peroxy carboxylic acids bleach or precursors thereof, commonly referred to as bleach activators, which are preferably added in a prilled or agglomerated form.
  • bleach activators peroxy carboxylic acids bleach or precursors thereof, commonly referred to as bleach activators, which are preferably added in a prilled or agglomerated form.
  • suitable compounds of this type are disclosed in British Patent GB 1 586 769 and GB 2 143 231 and a method for their formation into a prilled form is described in European Published Patent Application EP-A-62 523.
  • TAED tetracetyl ethylene diamine
  • NOBS n-nonanoyloxybenzenesulphonate
  • ATC acetyl triethyl citrate
  • compositions according to the present invention naturally comprise inorganic filler salts such as alkali metal carbonates bicarbonates and sulphates.
  • inorganic filler salts such as alkali metal carbonates bicarbonates and sulphates.
  • Such fillers for instance sodium bicarbonate, may also act as acidifying agent as described herein above. Accordingly, sodium percarbonate is a preferred filler material for use herein.
  • compositions according to the present invention can be made by a variety of methods well known in the art, including dry-mixing, spray drying, agglomeration and granulation and combinations thereof.
  • compositions according to the present invention can be prepared with different bulk densities, from conventional granular products to so-called “concentrated” products (i.e. with a bulk density above 600g/l).
  • compositions 1 2 3 4 5 6 Sodium percarbonate 40.0 35.0 54.0 55.0 46.0 47.0 TAED 8.7 7.6 11.7 - 9.5 - Silicate layered SKS-6 25.0 30.0 20.0 10.0 18.0 20.0 Anhydrous citric acid 10.0 12.0 12.0 5.0 5.0 5.0 Sodium sulphate 15.3 14.3 1.0 20.0 0.5 15.0 Sodium bicarbonate - - - 5.0 18.0 - NOBS - - - - - 10.3 minors up to 100%
  • compositions were made by mixing the listed ingredients in the listed proportions.
  • the self heating rates of the products were monitored as follows.
  • the product is made and put in a bottle.
  • the bottle is then put in an oven which is heated up to 70°c.
  • a probe in the product allows to monitor the temperature of the product.
  • the bottle is covered and the system is isolated in an adiabatic/thermo bell which maintains the temperature of the oven constant at 70°c as above. This places the product in adiabatic conditions and from thereon, the temperature of the product is monitored.
  • the temperature increase thus measured is due to the self-heating of the product (runaway reaction).
  • SHR1 is the average temperature increase measured during the first two hours of adiabatic conditions
  • SHR2 is the average temperature increase measured during the three following hours
  • SHR3 is the average temperature increase measured beyond 5 hours.
  • the table below lists the results obtained for various compositions, with and without crystalline layered silicate. In some cases the runaway reaction was out of control and experiments had to be interrupted for safety reasons. Such experiments are marked "ooc" (out of control).
  • compositions 7-12 show good thermal stability, and no temperature increase is reported after 5 hours storage and beyond. In the absence of crystalline layered silicate i.e. in compositions 7a-12a, self-heating rates measured were so high that experiments had to be stopped for safety purposes.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
EP92200005A 1992-01-03 1992-01-03 Körnige Bleichmittelzusammensetzung für Wäsche Ceased EP0550077A1 (de)

Priority Applications (11)

Application Number Priority Date Filing Date Title
EP92200005A EP0550077A1 (de) 1992-01-03 1992-01-03 Körnige Bleichmittelzusammensetzung für Wäsche
RU94035995/04A RU94035995A (ru) 1992-01-03 1992-12-24 Гранулированная отбеливающая композиция
BR9207019A BR9207019A (pt) 1992-01-03 1992-12-24 Alvejante para lavagem de percarbonato granular contendo estabilizador de silicato em camadas
KR1019940702293A KR940703911A (ko) 1992-01-03 1992-12-24 층상 규산염 안정화제를 함유하는 입상 과탄산염 세탁표백제(Granular percarbonate laundry bleach containing layered silicate stabilizer)
JP5511910A JPH07502770A (ja) 1992-01-03 1992-12-24 層状シリケート安定剤を含有する粒状ペルカーボネート洗濯漂白剤
CA002126847A CA2126847A1 (en) 1992-01-03 1992-12-24 Granular percarbonate laundry bleach containing layered silicate stabilizer
PCT/US1992/011222 WO1993012843A1 (en) 1992-01-03 1992-12-24 Granular percarbonate laundry bleach containing layered silicate stabilizer
AU34224/93A AU666918B2 (en) 1992-01-03 1992-12-24 Granular percarbonate laundry bleach containing layered silicate stabilizer
MX9207671A MX9207671A (es) 1992-01-03 1992-12-30 Composicion blanqueadora granulada para lavanderia.
MA23046A MA22754A1 (fr) 1992-01-03 1992-12-30 Composition granulaire de blanchiment pour blanchisserie.
CN93101189A CN1075749A (zh) 1992-01-03 1993-01-02 粒状洗衣用漂白组合物

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP92200005A EP0550077A1 (de) 1992-01-03 1992-01-03 Körnige Bleichmittelzusammensetzung für Wäsche

Publications (1)

Publication Number Publication Date
EP0550077A1 true EP0550077A1 (de) 1993-07-07

Family

ID=8210346

Family Applications (1)

Application Number Title Priority Date Filing Date
EP92200005A Ceased EP0550077A1 (de) 1992-01-03 1992-01-03 Körnige Bleichmittelzusammensetzung für Wäsche

Country Status (11)

Country Link
EP (1) EP0550077A1 (de)
JP (1) JPH07502770A (de)
KR (1) KR940703911A (de)
CN (1) CN1075749A (de)
AU (1) AU666918B2 (de)
BR (1) BR9207019A (de)
CA (1) CA2126847A1 (de)
MA (1) MA22754A1 (de)
MX (1) MX9207671A (de)
RU (1) RU94035995A (de)
WO (1) WO1993012843A1 (de)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0639639A1 (de) * 1993-08-17 1995-02-22 The Procter & Gamble Company Percarbonat-Bleichmittel enthaltende Waschmittelzusammensetzungen
WO1995025065A1 (de) * 1994-03-14 1995-09-21 Henkel Kommanditgesellschaft Auf Aktien Lagerstabil fixiertes wasserstoffperoxid enthaltende mehrstoffgemische in feststofform, verfahren zu ihrer herstellung und ihre verwendung
WO1996001887A1 (de) * 1994-07-07 1996-01-25 Henkel Kommanditgesellschaft Auf Aktien Pulverförmiges bleich- und waschmittel
WO1996014267A1 (de) * 1994-11-02 1996-05-17 Henkel Kommanditgesellschaft Auf Aktien Direktsynthese kristalliner disilicate aus wasserglaslösung
EP0737738A2 (de) 1995-04-12 1996-10-16 Cleantabs A/S Bleichmitteltabletten
DE19525197A1 (de) * 1995-07-11 1997-01-16 Hoechst Ag Granularer Waschmittelbuilder
WO1997009269A1 (de) * 1995-09-04 1997-03-13 Henkel Kommanditgesellschaft Auf Aktien Lagerstabil fixiertes wasserstoffperoxid enthaltende mehrstoffgemische in feststofform, verfahren zu ihrer herstellung und ihre verwendung
EP0695800A3 (de) * 1994-08-04 1997-10-15 Hoechst Ag Waschmittel
EP0745664B1 (de) * 1994-02-25 1998-05-13 Eka Chemicals AB Bleichmittel
EP0750661A4 (de) * 1994-03-14 1998-10-07 Procter & Gamble Körnige bleichmittelzusammensetzung
US5854198A (en) * 1996-03-15 1998-12-29 Lever Brothers Company, Division Of Conopco, Inc. Particulate aluminosilicate-built detergent compositions comprising cogranules of zeolite map and alkali metal silicate
GB2353800A (en) * 1999-09-02 2001-03-07 Procter & Gamble Antibacterial detergent compositions
WO2009017748A1 (en) * 2007-07-30 2009-02-05 Milliken & Company Solid cleaning composition and method of use
WO2009122125A1 (en) * 2008-04-01 2009-10-08 Reckitt Benckiser Inc. Laundry treatment compositions
FR3072391A1 (fr) * 2017-10-18 2019-04-19 Quadrimex Chemical Composition extemporanee comprenant un melange de deux produits pour la destruction de polluants organophosphores et/ou organosoufres

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09511533A (ja) * 1994-09-19 1997-11-18 ザ、プロクター、エンド、ギャンブル、カンパニー 顆粒状漂白組成物

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2247533A1 (de) * 1973-10-10 1975-05-09 Du Pont
EP0337219A2 (de) * 1988-04-15 1989-10-18 Hoechst Aktiengesellschaft Lagerstabilisiertes Waschmittel mit verstärkter Bleichwirkung
EP0416366A2 (de) * 1989-09-08 1991-03-13 Hoechst Aktiengesellschaft Schichtsilikate enthaltendes Geschirrspülmittel

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3413571A1 (de) * 1984-04-11 1985-10-24 Hoechst Ag, 6230 Frankfurt Verwendung von kristallinen schichtfoermigen natriumsilikaten zur wasserenthaertung und verfahren zur wasserenthaertung
DE3526405A1 (de) * 1985-07-24 1987-02-05 Henkel Kgaa Schichtsilikate mit beschraenktem quellvermoegen, verfahren zu ihrer herstellung und ihre verwendung in wasch- und reinigungsmitteln
US5087895A (en) * 1988-02-02 1992-02-11 Motorola, Inc. Miniature microstrip/cavity oscillator
DE3812556A1 (de) * 1988-04-15 1989-10-26 Hoechst Ag Waschmittel mit lagerstabilisiertem bleichsystem

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2247533A1 (de) * 1973-10-10 1975-05-09 Du Pont
EP0337219A2 (de) * 1988-04-15 1989-10-18 Hoechst Aktiengesellschaft Lagerstabilisiertes Waschmittel mit verstärkter Bleichwirkung
EP0416366A2 (de) * 1989-09-08 1991-03-13 Hoechst Aktiengesellschaft Schichtsilikate enthaltendes Geschirrspülmittel

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
SOFW: Seifen, Ole, Fette, Wachse vol. 116, no. 20, 13 December 1990, pages 805-808, Ausburg, DE; F.J. DANY et al.: "Kristallines Schichtsilikat - ein neuer Builder" *

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0639639A1 (de) * 1993-08-17 1995-02-22 The Procter & Gamble Company Percarbonat-Bleichmittel enthaltende Waschmittelzusammensetzungen
US5846922A (en) * 1994-02-25 1998-12-08 Eka Chemicals Ab Bleaching agent
EP0745664B1 (de) * 1994-02-25 1998-05-13 Eka Chemicals AB Bleichmittel
WO1995025065A1 (de) * 1994-03-14 1995-09-21 Henkel Kommanditgesellschaft Auf Aktien Lagerstabil fixiertes wasserstoffperoxid enthaltende mehrstoffgemische in feststofform, verfahren zu ihrer herstellung und ihre verwendung
EP0750661A4 (de) * 1994-03-14 1998-10-07 Procter & Gamble Körnige bleichmittelzusammensetzung
WO1996001887A1 (de) * 1994-07-07 1996-01-25 Henkel Kommanditgesellschaft Auf Aktien Pulverförmiges bleich- und waschmittel
EP0695800A3 (de) * 1994-08-04 1997-10-15 Hoechst Ag Waschmittel
WO1996014267A1 (de) * 1994-11-02 1996-05-17 Henkel Kommanditgesellschaft Auf Aktien Direktsynthese kristalliner disilicate aus wasserglaslösung
EP0737738A3 (de) * 1995-04-12 1998-04-01 Cleantabs A/S Bleichmitteltabletten
EP0737738A2 (de) 1995-04-12 1996-10-16 Cleantabs A/S Bleichmitteltabletten
DE19525197A1 (de) * 1995-07-11 1997-01-16 Hoechst Ag Granularer Waschmittelbuilder
WO1997009269A1 (de) * 1995-09-04 1997-03-13 Henkel Kommanditgesellschaft Auf Aktien Lagerstabil fixiertes wasserstoffperoxid enthaltende mehrstoffgemische in feststofform, verfahren zu ihrer herstellung und ihre verwendung
US5854198A (en) * 1996-03-15 1998-12-29 Lever Brothers Company, Division Of Conopco, Inc. Particulate aluminosilicate-built detergent compositions comprising cogranules of zeolite map and alkali metal silicate
GB2353800A (en) * 1999-09-02 2001-03-07 Procter & Gamble Antibacterial detergent compositions
WO2009017748A1 (en) * 2007-07-30 2009-02-05 Milliken & Company Solid cleaning composition and method of use
WO2009122125A1 (en) * 2008-04-01 2009-10-08 Reckitt Benckiser Inc. Laundry treatment compositions
FR3072391A1 (fr) * 2017-10-18 2019-04-19 Quadrimex Chemical Composition extemporanee comprenant un melange de deux produits pour la destruction de polluants organophosphores et/ou organosoufres
FR3072390A1 (fr) * 2017-10-18 2019-04-19 Quadrimex Chemical Sas Composition extemporanee comprenant un melange de deux produits pour la destruction de polluants organophosphores et/ou organosoufres

Also Published As

Publication number Publication date
AU666918B2 (en) 1996-02-29
BR9207019A (pt) 1995-12-05
MA22754A1 (fr) 1993-07-01
MX9207671A (es) 1994-05-31
CA2126847A1 (en) 1993-07-08
CN1075749A (zh) 1993-09-01
RU94035995A (ru) 1996-06-20
KR940703911A (ko) 1994-12-12
JPH07502770A (ja) 1995-03-23
WO1993012843A1 (en) 1993-07-08
AU3422493A (en) 1993-07-28

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