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EP0011499A1 - Produits liquides servant à déposer des parfums sur des surfaces de tissu - Google Patents

Produits liquides servant à déposer des parfums sur des surfaces de tissu Download PDF

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Publication number
EP0011499A1
EP0011499A1 EP79302599A EP79302599A EP0011499A1 EP 0011499 A1 EP0011499 A1 EP 0011499A1 EP 79302599 A EP79302599 A EP 79302599A EP 79302599 A EP79302599 A EP 79302599A EP 0011499 A1 EP0011499 A1 EP 0011499A1
Authority
EP
European Patent Office
Prior art keywords
amine
liquid formulation
formulation according
weight
particles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP79302599A
Other languages
German (de)
English (en)
Other versions
EP0011499B1 (fr
Inventor
James Barrie Melville
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Unilever NV
Original Assignee
Unilever PLC
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever PLC, Unilever NV filed Critical Unilever PLC
Priority to AT79302599T priority Critical patent/ATE357T1/de
Publication of EP0011499A1 publication Critical patent/EP0011499A1/fr
Application granted granted Critical
Publication of EP0011499B1 publication Critical patent/EP0011499B1/fr
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes
    • C11D3/502Protected perfumes
    • C11D3/505Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/40Monoamines or polyamines; Salts thereof

Definitions

  • This invention relates to liquid formulations capable of depositing perfumes on fabric surfaces.
  • the formulation may be used in diluted form and examples of the fabric surfaces are cotton, wool, polyacrylic, polyamide and polyester fibres. These formulations are intended for use in the rinse cycle of a fabric cleaning operation.
  • liquid formulations of the invention will normally be used to provide a fabric softening effect.
  • Perfumes are liquid compositions consisting of a number of organic compounds, capable of appreciation by smell.
  • the compounds are usually derived from natural sources but synthetic materials are also used.
  • Formulations intended for the laundering of fabric will normally contain a perfume to provide a pleasant after smell on the laundered fabrics.
  • powder and liquid detergent formulations, and rinse cycle formulations contain perfumes.
  • the perfume in a fabric treatment formulation used efficiently because it is a relatively high cost component of any formulation.
  • the perfume will be present in the formulation at a relatively low concentration and dilution will cause the fabric to be in contact with a liquid system containing a very low concentration of the perfume.
  • a liquid formulation for depositing perfumes on fabric surfaces wherein the formulation comprises an aqueous base having:
  • the aqueous base will contain water as a major constituent. While it is possible for this to be the sole component of the base, the latter will usually include other materials, for example, electrolytes, buffering agents, short chain alcohols, emulsifiers, colouring materials, bactericides, antioxidants, surface active agents and fluorescers.
  • alkyl groups, alkenyl groups and alkyl portion of the amino-alkyl groups may be linear or branched.
  • the amine is a primary or tertiary compound or a diamine, particularly a diamine of the formula R-NH-(CH2)3-NH2, where R is as defined above.
  • Preferred compounds are methyl dihardened tallow tertiary amine, hardened tallow primary amine, methyl, dicoco-tertiary _amine, coco primary amine and N-alkyl 1:3 propylene diamines, where the alkyl group may be hardened tallow, coconut or C 18/ C 20 mixture.
  • the amines of utility in the invention can be solid, liquid or pasty and will have a solubility in water of not more than about 1% weight/ volume. The amines will be dispersible in the aqueous base liquid.
  • the fabric conditioning agent may be selected from the classes of:
  • the perfume may be selected from any perfumes and any mixtures thereof.
  • fabric substantive perfumes suitable for use in the present invention are listed in S Arctander, Perfume Flavors and Chemicals, Volumes I and II, published by the author, Montclair, New Jersey, USA and the Merck Index, 8th Edition, Merck & Co. Inc., Rahway, New Jersey, USA.
  • Deodorant perfumes such as disclosed in United States specification 4 134 838 may also be used.
  • a method of preparing the liquid formulation of the invention includes the step of forming a liquid mixture of the amine and the perfume and dispersing the mixture in water.
  • the preferred method is to melt the amine and the perfume together and then disperse the mixture in heated water.
  • An aid to dispersion e.g. high speed stirrers, ultrasonic agitators, vibrating reeds and continuous mixers may be used.
  • the perfume effect was gauged and compared to a control formulation.
  • This control was formed by dispersing 5 g of the above quaternary ammonium salt in water (100 g) and adding 0.2 g of the same perfume.
  • Example 1 was repeated using methyl dicoco amine.
  • Example 1 was repeated using methyl di(C 18/ C 20 ) alkyl amine.
  • the long chain alkyl group was formed by a 50:50 molar mixture of C 18 and C 20 alkyl chains.
  • Example 1 was repeated using hardened tallow primary amine.
  • Example 1 was repeated using coconut primary amine.
  • Example 1 was repeated using C 18 /C 20 primary amine.
  • Example 1 was repeated using di-hardened tallow secondary amine.
  • Example 1 was repeated using di-coconut secondary amine.
  • Example 1 was repeated using dimethyl mono hardened tallow tertiary amine.
  • Example 1 was repeated using dimethyl mono-coconut tertiary amine.
  • Example 1 was repeated using dimethyl mono (C 18 / C 20 ) alkyl tertiary amine.
  • Example 1 was repeated using N-hardened tallow 1:3 propylene diamine.
  • Example 1 was repeated using N-coco 1:3 propylene diamine.
  • Example 1 was repeated using N-(C 18 /C 20 ) 1:3 propylene diamine.
  • Example 'I was repeated using a number of perfume/ -amine combinations and the results were compared with two controls.
  • Control A was an aqueous dispersion of non- ionic/cationic/perfume particles according to our German Patent Specification No. 2 732 985 containing the same quantity of perfume (0.2 g), where the non-ionic was tallow alcohol 3EO (0.9 g) and the cationic was Arosurf TA 100 (dimethyl distearyl ammonium chloride)(0.05 g).
  • Control B consisted of the same quantity of perfume dispersed in water.
  • perfume formulations used were:

Landscapes

  • Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Fats And Perfumes (AREA)
  • Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
  • Detergent Compositions (AREA)
  • Medicinal Preparation (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
EP79302599A 1978-11-17 1979-11-16 Produits liquides servant à déposer des parfums sur des surfaces de tissu Expired EP0011499B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT79302599T ATE357T1 (de) 1978-11-17 1979-11-16 Fluessige mittel zum auftragen von parfuems auf textiloberflaechen.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB7845075 1978-11-17
GB4507578 1978-11-17

Publications (2)

Publication Number Publication Date
EP0011499A1 true EP0011499A1 (fr) 1980-05-28
EP0011499B1 EP0011499B1 (fr) 1981-11-04

Family

ID=10501143

Family Applications (1)

Application Number Title Priority Date Filing Date
EP79302599A Expired EP0011499B1 (fr) 1978-11-17 1979-11-16 Produits liquides servant à déposer des parfums sur des surfaces de tissu

Country Status (11)

Country Link
EP (1) EP0011499B1 (fr)
JP (1) JPS55500911A (fr)
AT (1) ATE357T1 (fr)
AU (1) AU531802B2 (fr)
CA (1) CA1130058A (fr)
DE (1) DE2961275D1 (fr)
DK (1) DK307680A (fr)
ES (1) ES8100341A1 (fr)
PT (1) PT70463A (fr)
WO (1) WO1980001075A1 (fr)
ZA (1) ZA796187B (fr)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0034048A3 (en) * 1980-02-07 1981-12-02 Unilever Plc A method of cleaning and depositing perfume on a surface and compositions therefor
EP0041328A1 (fr) * 1980-05-16 1981-12-09 Unilever Plc Procédé de déposition de parfum sur des matières textiles et le produit utilisé ainsi
EP0036720B1 (fr) * 1980-03-11 1983-08-17 Unilever Plc Composition détergente
EP0971026A1 (fr) * 1998-07-10 2000-01-12 The Procter & Gamble Company Compositions de lavage et de nettoyage
EP0971025A1 (fr) * 1998-07-10 2000-01-12 The Procter & Gamble Company Produits de réaction d'aminé comprenant un ou plusieurs principes actifs
EP0971027A1 (fr) * 1998-07-10 2000-01-12 The Procter & Gamble Company Produits de réaction d'aminé comprenant un ou plusieurs ingrédients actifs
EP0971024A1 (fr) * 1998-07-10 2000-01-12 The Procter & Gamble Company Compositions de blanchissage et de lavage
DE10063428A1 (de) * 2000-12-20 2002-07-11 Henkel Kgaa Dispersionen nanopartikulärer riechstoffhaltiger Kompositmaterialien
US6566312B2 (en) 1998-07-10 2003-05-20 Procter & Gamble Company Amine reaction compounds comprising one or more active ingredient
US6699823B2 (en) 1998-07-10 2004-03-02 Procter & Gamble Company Amine reaction compounds comprising one or more active ingredient
US6790815B1 (en) 1998-07-10 2004-09-14 Procter & Gamble Company Amine reaction compounds comprising one or more active ingredient
WO2007029188A3 (fr) * 2005-09-07 2007-06-21 Procter & Gamble Procede d'utilisation de compositions d'entretien des tissus permettant d'obtenir une amelioration synergique de l'odeur
WO2010142480A1 (fr) * 2009-06-09 2010-12-16 Henkel Ag & Co. Kgaa Produit de lavage, de nettoyage ou d'entretien parfumé

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3790484A (en) * 1972-01-18 1974-02-05 Blalock E Fragrance-imparting laundering composition
FR2311884A1 (fr) * 1975-05-21 1976-12-17 Procter & Gamble Compositions de conditionnement de tissus
FR2318265A1 (fr) * 1975-07-14 1977-02-11 Procter & Gamble Perles et compositions pour le conditionnement des tissus
DE2732985A1 (de) * 1976-07-26 1978-02-02 Unilever Nv Fluessige textilbehandlungsmittel und verfahren zu ihrer herstellung
FR2369340A1 (fr) * 1976-10-29 1978-05-26 Procter & Gamble Composition parfumee utilisable pour le conditionnement des tissus

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3790484A (en) * 1972-01-18 1974-02-05 Blalock E Fragrance-imparting laundering composition
FR2311884A1 (fr) * 1975-05-21 1976-12-17 Procter & Gamble Compositions de conditionnement de tissus
FR2318265A1 (fr) * 1975-07-14 1977-02-11 Procter & Gamble Perles et compositions pour le conditionnement des tissus
DE2732985A1 (de) * 1976-07-26 1978-02-02 Unilever Nv Fluessige textilbehandlungsmittel und verfahren zu ihrer herstellung
FR2369340A1 (fr) * 1976-10-29 1978-05-26 Procter & Gamble Composition parfumee utilisable pour le conditionnement des tissus
US4152272A (en) * 1976-10-29 1979-05-01 The Procter & Gamble Company Fabric conditioning composition

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0034048A3 (en) * 1980-02-07 1981-12-02 Unilever Plc A method of cleaning and depositing perfume on a surface and compositions therefor
EP0036720B1 (fr) * 1980-03-11 1983-08-17 Unilever Plc Composition détergente
EP0041328A1 (fr) * 1980-05-16 1981-12-09 Unilever Plc Procédé de déposition de parfum sur des matières textiles et le produit utilisé ainsi
AU755629B2 (en) * 1998-07-10 2002-12-19 Procter & Gamble Company, The Laundry and cleaning compositions
WO2000002987A3 (fr) * 1998-07-10 2001-08-23 Procter & Gamble Composes de reaction d'amine contenant un ou plusieurs ingredients actifs
EP0971027A1 (fr) * 1998-07-10 2000-01-12 The Procter & Gamble Company Produits de réaction d'aminé comprenant un ou plusieurs ingrédients actifs
EP0971024A1 (fr) * 1998-07-10 2000-01-12 The Procter & Gamble Company Compositions de blanchissage et de lavage
WO2000002991A1 (fr) * 1998-07-10 2000-01-20 The Procter & Gamble Company Composes de reaction d'amine contenant un ou plusieurs ingredients actifs
CN100384974C (zh) * 1998-07-10 2008-04-30 宝洁公司 包含一种或多种活性成分的胺反应化合物
US6790815B1 (en) 1998-07-10 2004-09-14 Procter & Gamble Company Amine reaction compounds comprising one or more active ingredient
EP0971025A1 (fr) * 1998-07-10 2000-01-12 The Procter & Gamble Company Produits de réaction d'aminé comprenant un ou plusieurs principes actifs
US6699823B2 (en) 1998-07-10 2004-03-02 Procter & Gamble Company Amine reaction compounds comprising one or more active ingredient
EP0971026A1 (fr) * 1998-07-10 2000-01-12 The Procter & Gamble Company Compositions de lavage et de nettoyage
US6566312B2 (en) 1998-07-10 2003-05-20 Procter & Gamble Company Amine reaction compounds comprising one or more active ingredient
WO2000002981A3 (fr) * 1998-10-28 2001-08-16 Procter & Gamble Compositions de lessive et de nettoyage
WO2000002982A3 (fr) * 1998-10-28 2001-06-14 Procter & Gamble Procede servant a preparer des particules de produit de reaction d'amine
DE10063428A1 (de) * 2000-12-20 2002-07-11 Henkel Kgaa Dispersionen nanopartikulärer riechstoffhaltiger Kompositmaterialien
WO2007029188A3 (fr) * 2005-09-07 2007-06-21 Procter & Gamble Procede d'utilisation de compositions d'entretien des tissus permettant d'obtenir une amelioration synergique de l'odeur
WO2010142480A1 (fr) * 2009-06-09 2010-12-16 Henkel Ag & Co. Kgaa Produit de lavage, de nettoyage ou d'entretien parfumé

Also Published As

Publication number Publication date
ES486066A0 (es) 1980-11-01
PT70463A (en) 1979-12-01
AU5292579A (en) 1980-05-22
ATE357T1 (de) 1981-11-15
DK307680A (da) 1980-07-16
WO1980001075A1 (fr) 1980-05-29
CA1130058A (fr) 1982-08-24
AU531802B2 (en) 1983-09-08
DE2961275D1 (en) 1982-01-14
JPS55500911A (fr) 1980-11-06
ZA796187B (en) 1981-06-24
EP0011499B1 (fr) 1981-11-04
ES8100341A1 (es) 1980-11-01

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