EP0080749A1 - Compositions détergentes liquides - Google Patents
Compositions détergentes liquides Download PDFInfo
- Publication number
- EP0080749A1 EP0080749A1 EP82201396A EP82201396A EP0080749A1 EP 0080749 A1 EP0080749 A1 EP 0080749A1 EP 82201396 A EP82201396 A EP 82201396A EP 82201396 A EP82201396 A EP 82201396A EP 0080749 A1 EP0080749 A1 EP 0080749A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition according
- terpene
- compositions
- mixtures
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000203 mixture Substances 0.000 title claims abstract description 77
- 239000007788 liquid Substances 0.000 title claims abstract description 20
- 239000003599 detergent Substances 0.000 title claims abstract description 13
- 235000007586 terpenes Nutrition 0.000 claims abstract description 28
- 150000003505 terpenes Chemical class 0.000 claims abstract description 21
- 239000004094 surface-active agent Substances 0.000 claims abstract description 15
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- -1 alkyl benzene-sulfonates Chemical class 0.000 claims description 17
- 239000000344 soap Substances 0.000 claims description 8
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- 239000003752 hydrotrope Substances 0.000 claims description 6
- 125000000129 anionic group Chemical group 0.000 claims description 5
- 239000003352 sequestering agent Substances 0.000 claims description 5
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 claims description 4
- 239000003945 anionic surfactant Substances 0.000 claims description 4
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- XMGQYMWWDOXHJM-JTQLQIEISA-N D-limonene Natural products CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 claims description 3
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 3
- 239000002280 amphoteric surfactant Substances 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 150000002628 limonene derivativess Chemical class 0.000 claims description 3
- 229910021645 metal ion Inorganic materials 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 3
- 150000003871 sulfonates Chemical class 0.000 claims description 3
- 229920001285 xanthan gum Polymers 0.000 claims description 3
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 3
- WTARULDDTDQWMU-RKDXNWHRSA-N (+)-β-pinene Chemical compound C1[C@H]2C(C)(C)[C@@H]1CCC2=C WTARULDDTDQWMU-RKDXNWHRSA-N 0.000 claims description 2
- WTARULDDTDQWMU-IUCAKERBSA-N (-)-Nopinene Natural products C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 claims description 2
- WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 claims description 2
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 claims description 2
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 229930006722 beta-pinene Natural products 0.000 claims description 2
- 229930003642 bicyclic monoterpene Natural products 0.000 claims description 2
- 150000001604 bicyclic monoterpene derivatives Chemical class 0.000 claims description 2
- LCWMKIHBLJLORW-UHFFFAOYSA-N gamma-carene Natural products C1CC(=C)CC2C(C)(C)C21 LCWMKIHBLJLORW-UHFFFAOYSA-N 0.000 claims description 2
- 235000001510 limonene Nutrition 0.000 claims description 2
- 229930003647 monocyclic monoterpene Natural products 0.000 claims description 2
- 150000002767 monocyclic monoterpene derivatives Chemical class 0.000 claims description 2
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 229920001282 polysaccharide Polymers 0.000 claims description 2
- 239000005017 polysaccharide Substances 0.000 claims description 2
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 claims description 2
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 2
- 229930006978 terpinene Natural products 0.000 claims description 2
- 150000003507 terpinene derivatives Chemical class 0.000 claims description 2
- 150000003508 terpinolene derivatives Chemical class 0.000 claims description 2
- 125000000545 (4R)-limonene group Chemical group 0.000 claims 1
- 235000013162 Cocos nucifera Nutrition 0.000 claims 1
- 244000060011 Cocos nucifera Species 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 229940077388 benzenesulfonate Drugs 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 235000019832 sodium triphosphate Nutrition 0.000 claims 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical class [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 16
- 239000002689 soil Substances 0.000 abstract description 15
- 238000009472 formulation Methods 0.000 abstract description 2
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 9
- 239000004615 ingredient Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000004519 grease Substances 0.000 description 5
- 239000002562 thickening agent Substances 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 235000019445 benzyl alcohol Nutrition 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 229930003658 monoterpene Natural products 0.000 description 2
- 150000002773 monoterpene derivatives Chemical class 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229930004725 sesquiterpene Natural products 0.000 description 2
- 150000004354 sesquiterpene derivatives Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- GDXHBFHOEYVPED-UHFFFAOYSA-N 1-(2-butoxyethoxy)butane Chemical compound CCCCOCCOCCCC GDXHBFHOEYVPED-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical compound CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- XXBBJICMFUBSKW-UHFFFAOYSA-N CCC1=CC=CC=C1.CC(C)OS(=O)(=O)C1=CC=CC=C1 Chemical class CCC1=CC=CC=C1.CC(C)OS(=O)(=O)C1=CC=CC=C1 XXBBJICMFUBSKW-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000019846 buffering salt Nutrition 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229940071118 cumenesulfonate Drugs 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 1
- 230000003311 flocculating effect Effects 0.000 description 1
- 235000015203 fruit juice Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000003165 hydrotropic effect Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000003550 marker Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000010665 pine oil Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical class OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/188—Terpenes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2051—Dihydric alcohols cyclic; polycyclic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2024—Monohydric alcohols cyclic; polycyclic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2037—Terpenes
Definitions
- This invention relates to aqueous detergent compositions suitable for use as general purpose household cleaning compositions.
- Powdered compositions consist mainly of builder or buffering salts such as phosphates, carbonates, silicates, etc., and although such compositions may display good inorganic soil removal, they are generally deficient in cleaning ability on organic soils such as the greasy/fatty/oily soils typically found in the domestic environment. Moreover, they are diluted with water prior to use.
- Liquid cleaning compositions on the other hand, have the great advantage that they can be applied to hard surfaces in neat or concentrated form so that a relatively high level of surfactant material is delivered directly to the soil. Moreover, it is a rather more straightforward task to incorporate high concentrations of anionic or nonionic surfactant in a liquid rather than a granular composition. For both these reasons, therefore, liquid cleaning compositions have the potential to provide superior grease and oily soil removal over powdered cleaning compositions.
- -liquid cleaning compositions still suffer a number of drawbacks which can limit their consumer acceptability.
- they generally contain little or no detergency builder salts and consequently they tend to have poor cleaning performance on particulate soil and also lack "robustness" under varying water hardness levels.
- they can suffer problems of product form, in particular, inhomogeneity, lack of clarity, or inadequate viscosity characteristics for consumer use.
- the higher in-product and in-use surfactant concentration necessary for improved grease handling raises problems of extensive suds formation, which require frequent rinsing and wiping by the user.
- oversudsing may be controlled to some extent by incorporating a suds-regulating material such as hydrophobic silica and/or silicone or soap, this in itself can raise problems of poor product stability and homogeneity, and problems associated with deposition of insoluble particulate or soap residues on the items or surfaces being cleaned, leading to filming, streaking and spotting.
- a suds-regulating material such as hydrophobic silica and/or silicone or soap
- the terpenes provide excellent cleaning characteristics across the range of water hardness on grease/oily soils and inorganic particulate soils, as well as on shoe polish, marker ink, bath tub soil etc, and excellent shine performance with low soil redeposition and little or no propensity to cause filming, streaking or spotting on surfaces washed therewith.
- the terpenes herein specified, and in particular those of the hydrocarbon class are valuable in regulating the sudsin g behaviour of the instant compositions in both hard and soft water and under both diluted and neat or concentrated usage, while terpenes of the terpene alcohol class are also valuable for providing effective control of product viscosity characteristics.
- Terpenes are, of course, well-known components of perfume compositions and are often incorporated into detergent compositions at low levels via the perfume. Certain terpenes have also been included in detergent compositions at higher levels; for instance, German Patent Application 21 13 732 discloses the use of aliphatic and alicyclic terpenes as anti-microbial agents in washing compositions; British Patent 1.308.190 teaches the use of dipentenes in a thixotropic liquid detergent suspension base composition. German Patent Application 27 09 690 teaches the use of pine oil (a mixture mainly of terpene alcohols) in liquid hard surface cleaning compositions. European Application 81-200540.3 teaches the use of terpenes with solvents such as benzyl alcohol and ethylene glycol dibutyl ether in liquid cleanser compositions.
- the present invention provides liquid detergent compositions which are stable, homogeneous liquids having excellent suds control across a broad range of usage and water hardness conditions and which provide excellent shine performance together with improved cleaning characteristics both on greasy/oily soils and on inorganic particulate soils, with little tendency to cause filming or streaking on washed surfaces.
- Terpene - Preferred terpenes are mono- and bicyclic mono- terpenes, especially those of the hydrocarbon class, which include the terpinenes, terpinolenes, limonenes and pinenes, and mixtures thereof. Highly preferred materials of this type are d-limonene, dipentene, ⁇ -pinene, ⁇ -pinene and the mixture of terpene hydrocarbons obtained from the essence of oranges (e.g. cold-pressed orange terpenes and orange terpene oil phase ex fruitjuice). These terpenes are used at concentrations of at least 0.5%, preferably 1% to 10%, most preferably 2%-6%, in the compositions.
- Terpene alcohols aldehydes and ketones can optionally be used, but are not as preferred as the terpenes noted above.
- the terpene alcohols do provide valuable and unexpected improvements in viscosity regulation when incorporated in the compositions of this invention at concentrations from about 1% to about 3%, more preferably from about 1.5% to about 2.5%.
- BUTYL CARBITOL (Registered Trademark) - This component of the present compositions is commercially available as 2-(2-butoxyethoxy)ethanol, and is otherwise known as diethylene glycol monobutyl ether (C 8 H 18 O 3 ). BUTYL CARBITOL is used in the present compositions at a concentration of at least about 0.5%, preferably from about 0.5% to about 10%, by weight of composition.
- BUTYL CARBITOL has unexpected advantages over solvents like benzyl alcohol: it has none of the cloying odor associated with benzyl alcohol and oxidation products thereof; it performs w p )l as a grease remover; it acts, at least partially, as a hydrotrope, thereby allowing lower levels of hydrotropes like cumene sulfonate to be used in the present compositions.
- Surfactants - Water-soluble detersive surfactants useful herein include well-known synthetic anionic, nonionic, amphoteric and zwitterionic surfactants. Typical of these are the alkyl benzene sulfates and sulfonates, paraffin sulfonates, olefin sulfonates, alkoxylated (especially ethoxylated) alcohols and alkyl phenols, amine oxides, o(-sulfonates of fatty acids and of fatty acid esters, and the like, which are well-known from the detergency art.
- detersive surfactants contain an alkyl group in the C 10 -C 18 range; the anionic detersive surfactants are most commonly used in the form of their sodium, potassium or triethanolammonium salts; the nonionics generally contain from about 3 to about 17 ethylene oxide groups.
- U.S. Patents 4.111.855 and 3.995.669 contain detailed listings of such typical detersive surfactants.
- C 12 -C 16 alkyl benzene sulfonates and C 12 -C 18 paraffin-sulfonates are especially preferred in the compositions of the present type.
- the surfactant component can comprise as little as 0.1% of the compositions herein when formulated as a spray- on type product.
- the compositions herein When formulated as standard liquid cleaners, the compositions herein generally will contain about 1% to about 20%, preferably 2% to about 8%, of surfactant.
- compositions herein can contain other ingredients which aid in their cleaning performance.
- the compositions can contain a detergent builder and/or metal ion sequestrant.
- detergent builders include the nitrilotriacetates, polycarboxylates, citrates, water-soluble phosphates, mixtures of ,especially hydrated zeolite A in the 1-10 micron particle size range, and mixtures thereof.
- Metal ion sequestrants include all of the above, plus materials like ethylenediaminetetraacetate, the amino-polyphosphonates and phosphates (DEQUEST) and a wide variety of other poly-functional organic acids and salts too numerous to mention in detail here. See U.S. Patent 3.579.454 for typical-examples of the use of such materials in various cleaning compositions.
- the builder/sequestrant will comprise about 1% to 25% of the composition. Of course, water-soluble builder/seques- trants are used if clear, homogeneous compositions are desired.
- Citric acid (2%-10% as sodium citrate) is preferred herein.
- Soaps - As mentioned hereinabove, one special problem associated with the use of liquid cleansers is their tendency to over-suds, in-use. It has been discovered that soaps, especially the alkali, ammonium and alkanolammonium salts of C 13 -C 24 fatty acids, are especially useful as suds suppressors when conjointly present with terpenes and BUTYL CARBITOL in the instant compositions. Soap concentrations of at least about 0.005%, preferably 0.05% to 2%, provide this important suds control function. Soap prepared from coconut oil fatty acids is preferred.
- Thickeners - The compositions herein may optionally be thickened. Thickened compositions tend to cling to vertical surfaces such as walls and windows, which makes them more convenient to use. It has been found that many common thickeners undesirably flocculate the compositions herein. However, it has been discovered that thickeners based on Xanthan polysaccharides are effective, non-flocculating thickeners. In general, such Xanthan thickeners are used herein at levels of about 0.01%, and higher, depending on the desires of the formulator.
- compositions herein can contain, in addition to ingredients already mentioned, various optional ingredients typically used in commercial products to provide aesthetic or additional product performance benefits.
- Typical ingredients include pH regulants, perfumes, dyes, optical brighteners, soil suspending agents, detersive enzymes, gel-control agents, freeze-thaw stabilizers, bactericides, preservatives, and the like.
- hydrotropes Another additional ingredient for use herein is represented by conventional detergent hydrotropes.
- suitable hydrotropes are urea, monoethanolamine, diethanolamine, triethanolamine and the sodium, potassium, ammonium and alkanol ammonium salts of xylene-, toluene-, ethylbenzene- and isopropyl-benzene sulfonates.
- These hydrotropes can be added to the compositions of the present invention in amounts up to about 10% by weight. It is a particular feature of the present invention, however, that stable, homogenous formulations can be prepared without the need for hydrotropic materials of this kind, or with only very minor levels such as amount of from 0 to 4% (up to 4%) by weight.
- compositions herein are formulated in the alkaline pH range, generally in the range of pH 8-11, preferably about 10-10.8.
- Caustics such as sodium hydroxide and sodium carbonate can be used to adjust and buffer the pH, as desired.
- compositions herein are in liquid form, they can be prepared by simply blending the essential and optional ingredients in water.
- Example I exhibits excellent grease removal from asphalt tile when applied neat, or as a 1-15% aqueous solution. Excessive sudsing is not a problem if usage concentrations are below about 10% in water.
- Example II exhibits good freeze-thaw stability, an excellent low suds profile, excellent odor quality and has a desirable viscosity in the range of about 15 centipoise.
- the product is conveniently used neat, or in a 1-50% aqueous solution, to remove all manner of greasy oily stains from hard surfaces.
- Example III is prepared as a fully- formulated liquid cleanser suitable for use in water in the hardness range of 7-13 grains per gallon.
- the composition provides excellent removal of both greasy and solid soils from all manner of surfaces.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8134060 | 1981-11-12 | ||
| GB8134060 | 1981-11-12 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0080749A1 true EP0080749A1 (fr) | 1983-06-08 |
| EP0080749B1 EP0080749B1 (fr) | 1986-04-16 |
Family
ID=10525808
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19820201396 Expired EP0080749B1 (fr) | 1981-11-12 | 1982-11-08 | Compositions détergentes liquides |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0080749B1 (fr) |
| JP (1) | JPS58132097A (fr) |
| CA (1) | CA1202858A (fr) |
| DE (1) | DE3270670D1 (fr) |
Cited By (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0129987A1 (fr) * | 1983-05-27 | 1985-01-02 | Optikon Limited | Compositions de nettoyage |
| FR2564105A1 (fr) * | 1984-05-10 | 1985-11-15 | Saint Marc Lessives | Composition detergente liquide et procede pour sa preparation. |
| EP0171122A1 (fr) * | 1984-08-10 | 1986-02-12 | The Procter & Gamble Company | Produit de nettoyage liquide |
| US4576738A (en) * | 1984-12-21 | 1986-03-18 | Colgate-Palmolive Company | Hard surface cleaning compositions containing pianane |
| US4581161A (en) * | 1984-01-17 | 1986-04-08 | Lever Brothers Company | Aqueous liquid detergent composition with dicarboxylic acids and organic solvent |
| EP0126545B1 (fr) * | 1983-04-19 | 1987-08-19 | The Procter & Gamble Company | Système de solution contenant des substances servant à nettoyer liquides et écurantes |
| GB2190681A (en) * | 1986-05-21 | 1987-11-25 | Colgate Palmolive Co | Microemulsion all-purpose liquid cleaning composition |
| EP0249147A1 (fr) * | 1986-06-12 | 1987-12-16 | Henkel Kommanditgesellschaft auf Aktien | Agents de nettoyage liquides pour tous usages |
| EP0164467B1 (fr) * | 1984-04-07 | 1988-06-29 | The Procter & Gamble Company | Composition de nettoyage avec un solvant |
| US4943392A (en) * | 1988-06-03 | 1990-07-24 | The Procter & Gamble Company | Containing butoxy-propanol with low secondary isomer content |
| US4966724A (en) * | 1988-01-30 | 1990-10-30 | The Procter & Gamble Company | Viscous hard-surface cleaning compositions containing a binary glycol ether solvent system |
| EP0354027A3 (fr) * | 1988-08-04 | 1991-02-06 | Envirosolv Inc. | Composition de solvants biodégradable, non toxique et non dangereuse |
| US5023008A (en) * | 1989-11-17 | 1991-06-11 | Olin Corporation | Anti-microbial composition containing aliphatic polygycidol adducts |
| US5147456A (en) * | 1990-10-01 | 1992-09-15 | Olin Corporation | Polyglycidol sulfated surfactants having antimicrobial activity |
| US5202050A (en) * | 1987-04-06 | 1993-04-13 | The Procter & Gamble Company | Method for cleaning hard-surfaces using a composition containing organic solvent and polycarboxylated chelating agent |
| US5213624A (en) * | 1991-07-19 | 1993-05-25 | Ppg Industries, Inc. | Terpene-base microemulsion cleaning composition |
| EP0559472A1 (fr) * | 1992-03-06 | 1993-09-08 | Unilever Plc | Compositions de nettoyage liquides, peu moussantes |
| EP0595383A1 (fr) * | 1992-10-26 | 1994-05-04 | The Procter & Gamble Company | Composition détergente liquide pour surfaces dures contenant des détergents tension-actifs amphocarboxylate à chaîne courte |
| US5403509A (en) * | 1992-07-20 | 1995-04-04 | Kao Corporation, S.A. | Detergent composition comprising a mono-, di- and tri-ester mixture and method of manufacturing same |
| EP0638634A3 (fr) * | 1993-07-14 | 1995-05-17 | Colgate Palmolive Co | Composition détergente sous forme de microémulsion stable. |
| US5425891A (en) * | 1992-07-20 | 1995-06-20 | Kao Corporation | Detergent composition containing an antifoaming mixture of a soap and a glycerine oxide adduct |
| US5462690A (en) * | 1994-09-09 | 1995-10-31 | Colgate-Palmolive Co. | Liquid cleaning compositions |
| EP0748865A1 (fr) * | 1995-06-12 | 1996-12-18 | Colgate-Palmolive Company (a Delaware corporation) | Agents de nettoyage liquides stabiles contenant l'huile de pin |
| US5587357A (en) * | 1994-09-09 | 1996-12-24 | Colgate-Palmolive Co. | Liquid cleaning compositions |
| WO1997034988A1 (fr) * | 1996-03-19 | 1997-09-25 | The Procter & Gamble Company | Compositions de nettoyage des verres contenant une composition nettoyante parfumee |
| US5719114A (en) * | 1996-06-28 | 1998-02-17 | Colgate Palmolive Company | Cleaning composition in various liquid forms comprising acaricidal agents |
| US5723431A (en) * | 1989-09-22 | 1998-03-03 | Colgate-Palmolive Co. | Liquid crystal compositions |
| US6159925A (en) * | 2000-04-06 | 2000-12-12 | Colgate-Palmolive Co. | Acidic liquid crystal compositions |
| US6281178B1 (en) | 1996-02-14 | 2001-08-28 | Stepan Company | Reduced residue hard surface cleaner comprising hydrotrope |
| EP1167500A1 (fr) * | 2000-06-29 | 2002-01-02 | The Procter & Gamble Company | Procédé pour le nettoyage d'une surface dure |
| GB2371307A (en) * | 2001-01-19 | 2002-07-24 | Reckitt Benckiser Nv | Liquid detergent compositions |
| WO2003095598A1 (fr) * | 2002-05-11 | 2003-11-20 | Reckitt Benckiser N.V. | Composition detergente |
| WO2004046291A1 (fr) * | 2002-11-21 | 2004-06-03 | Liquid Science Laboratories Ltd | Solvant |
| EP2447349A1 (fr) | 2010-10-29 | 2012-05-02 | The Procter & Gamble Company | Composition liquide de nettoyage d'une surface dure |
| US8785366B2 (en) | 2008-05-23 | 2014-07-22 | Colgate-Palmolive Company | Liquid cleaning compositions and methods |
| CN104789387A (zh) * | 2015-04-28 | 2015-07-22 | 苏州永创达电子有限公司 | 一种有机溶剂型清洗剂 |
| JP2016124965A (ja) * | 2014-12-26 | 2016-07-11 | ライオン株式会社 | 浴室用液体洗浄剤 |
| EP3263682A1 (fr) | 2016-06-27 | 2018-01-03 | The Procter and Gamble Company | Compositions de nettoyage d'une surface dure |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6038497A (ja) * | 1983-08-12 | 1985-02-28 | ライオン株式会社 | 発泡性硬表面洗浄剤組成物 |
| JPS6112798A (ja) * | 1984-06-27 | 1986-01-21 | ライオン株式会社 | 浴室用液体洗浄剤組成物 |
| JPS6114298A (ja) * | 1984-06-29 | 1986-01-22 | ライオン株式会社 | 液体洗浄剤組成物 |
| JPH0647677B2 (ja) * | 1984-10-02 | 1994-06-22 | ライオン株式会社 | 液体洗浄剤組成物 |
| US4620937A (en) * | 1985-02-11 | 1986-11-04 | Joseph Dellutri | All purpose cleaner containing D-Limonene |
| JPS6469698A (en) * | 1987-09-10 | 1989-03-15 | Earth Chemical Co | Liquid detergent composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1308190A (en) * | 1970-06-26 | 1973-02-21 | Unilever Ltd | Suspending liquids |
| GB1603047A (en) * | 1977-07-05 | 1981-11-18 | Dotolo V | Cleaners containing d-limonene |
| EP0040882A1 (fr) * | 1980-05-27 | 1981-12-02 | THE PROCTER & GAMBLE COMPANY | Compositions détergentes liquides |
-
1982
- 1982-11-08 EP EP19820201396 patent/EP0080749B1/fr not_active Expired
- 1982-11-08 DE DE8282201396T patent/DE3270670D1/de not_active Expired
- 1982-11-09 CA CA000415164A patent/CA1202858A/fr not_active Expired
- 1982-11-12 JP JP19878282A patent/JPS58132097A/ja active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1308190A (en) * | 1970-06-26 | 1973-02-21 | Unilever Ltd | Suspending liquids |
| GB1603047A (en) * | 1977-07-05 | 1981-11-18 | Dotolo V | Cleaners containing d-limonene |
| EP0040882A1 (fr) * | 1980-05-27 | 1981-12-02 | THE PROCTER & GAMBLE COMPANY | Compositions détergentes liquides |
Cited By (54)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0126545B1 (fr) * | 1983-04-19 | 1987-08-19 | The Procter & Gamble Company | Système de solution contenant des substances servant à nettoyer liquides et écurantes |
| EP0129987A1 (fr) * | 1983-05-27 | 1985-01-02 | Optikon Limited | Compositions de nettoyage |
| US4581161A (en) * | 1984-01-17 | 1986-04-08 | Lever Brothers Company | Aqueous liquid detergent composition with dicarboxylic acids and organic solvent |
| EP0164467B1 (fr) * | 1984-04-07 | 1988-06-29 | The Procter & Gamble Company | Composition de nettoyage avec un solvant |
| FR2564105A1 (fr) * | 1984-05-10 | 1985-11-15 | Saint Marc Lessives | Composition detergente liquide et procede pour sa preparation. |
| EP0171122A1 (fr) * | 1984-08-10 | 1986-02-12 | The Procter & Gamble Company | Produit de nettoyage liquide |
| US4576738A (en) * | 1984-12-21 | 1986-03-18 | Colgate-Palmolive Company | Hard surface cleaning compositions containing pianane |
| AU597367B2 (en) * | 1986-05-21 | 1990-05-31 | Colgate-Palmolive Company, The | Microemulsion all purpose liquid cleaning compositions |
| GB2190681B (en) * | 1986-05-21 | 1991-02-13 | Colgate Palmolive Co | Microemulsion all purpose liquid cleaning composition |
| DE3716526A1 (de) * | 1986-05-21 | 1987-11-26 | Colgate Palmolive Co | Stabile mikroemulsion |
| GB2190681A (en) * | 1986-05-21 | 1987-11-25 | Colgate Palmolive Co | Microemulsion all-purpose liquid cleaning composition |
| DE3716526C2 (de) * | 1986-05-21 | 2001-03-15 | Colgate Palmolive Co | Stabile Öl-in-Wasser-Mikroemulsion |
| US5075026A (en) * | 1986-05-21 | 1991-12-24 | Colgate-Palmolive Company | Microemulsion all purpose liquid cleaning composition |
| AT385769B (de) * | 1986-06-12 | 1988-05-10 | Henkel Austria Ges Mbh | Fluessige allzweckreinigungsmittel |
| US4790951A (en) * | 1986-06-12 | 1988-12-13 | Henkel Kommanditgesellschaft Auf Aktien | Liquid all-purpose cleaning preparations containing terpene and hydrogenated naphthalene as fat dissolving agent |
| EP0249147A1 (fr) * | 1986-06-12 | 1987-12-16 | Henkel Kommanditgesellschaft auf Aktien | Agents de nettoyage liquides pour tous usages |
| US5202050A (en) * | 1987-04-06 | 1993-04-13 | The Procter & Gamble Company | Method for cleaning hard-surfaces using a composition containing organic solvent and polycarboxylated chelating agent |
| US4966724A (en) * | 1988-01-30 | 1990-10-30 | The Procter & Gamble Company | Viscous hard-surface cleaning compositions containing a binary glycol ether solvent system |
| US4943392A (en) * | 1988-06-03 | 1990-07-24 | The Procter & Gamble Company | Containing butoxy-propanol with low secondary isomer content |
| EP0354027A3 (fr) * | 1988-08-04 | 1991-02-06 | Envirosolv Inc. | Composition de solvants biodégradable, non toxique et non dangereuse |
| US5723431A (en) * | 1989-09-22 | 1998-03-03 | Colgate-Palmolive Co. | Liquid crystal compositions |
| US5023008A (en) * | 1989-11-17 | 1991-06-11 | Olin Corporation | Anti-microbial composition containing aliphatic polygycidol adducts |
| US5147456A (en) * | 1990-10-01 | 1992-09-15 | Olin Corporation | Polyglycidol sulfated surfactants having antimicrobial activity |
| US5213624A (en) * | 1991-07-19 | 1993-05-25 | Ppg Industries, Inc. | Terpene-base microemulsion cleaning composition |
| EP0559472A1 (fr) * | 1992-03-06 | 1993-09-08 | Unilever Plc | Compositions de nettoyage liquides, peu moussantes |
| WO1993018128A1 (fr) * | 1992-03-06 | 1993-09-16 | Unilever Plc | Compositions detergentes liquides peu ecumantes |
| US5391316A (en) * | 1992-03-06 | 1995-02-21 | Lever Brothers Company, Division Of Conopco, Inc. | Low-foaming, liquid cleaning compositions containing paraffin and fatty acid salt |
| US5403509A (en) * | 1992-07-20 | 1995-04-04 | Kao Corporation, S.A. | Detergent composition comprising a mono-, di- and tri-ester mixture and method of manufacturing same |
| US5425891A (en) * | 1992-07-20 | 1995-06-20 | Kao Corporation | Detergent composition containing an antifoaming mixture of a soap and a glycerine oxide adduct |
| EP0595383A1 (fr) * | 1992-10-26 | 1994-05-04 | The Procter & Gamble Company | Composition détergente liquide pour surfaces dures contenant des détergents tension-actifs amphocarboxylate à chaîne courte |
| EP0638634A3 (fr) * | 1993-07-14 | 1995-05-17 | Colgate Palmolive Co | Composition détergente sous forme de microémulsion stable. |
| US5462690A (en) * | 1994-09-09 | 1995-10-31 | Colgate-Palmolive Co. | Liquid cleaning compositions |
| US5587357A (en) * | 1994-09-09 | 1996-12-24 | Colgate-Palmolive Co. | Liquid cleaning compositions |
| EP0748865A1 (fr) * | 1995-06-12 | 1996-12-18 | Colgate-Palmolive Company (a Delaware corporation) | Agents de nettoyage liquides stabiles contenant l'huile de pin |
| US6281178B1 (en) | 1996-02-14 | 2001-08-28 | Stepan Company | Reduced residue hard surface cleaner comprising hydrotrope |
| WO1997034988A1 (fr) * | 1996-03-19 | 1997-09-25 | The Procter & Gamble Company | Compositions de nettoyage des verres contenant une composition nettoyante parfumee |
| US6194362B1 (en) | 1996-03-19 | 2001-02-27 | The Procter & Gamble Company | Glass cleaning compositions containing blooming perfume |
| US5719114A (en) * | 1996-06-28 | 1998-02-17 | Colgate Palmolive Company | Cleaning composition in various liquid forms comprising acaricidal agents |
| US6159925A (en) * | 2000-04-06 | 2000-12-12 | Colgate-Palmolive Co. | Acidic liquid crystal compositions |
| WO2002002723A1 (fr) * | 2000-06-29 | 2002-01-10 | The Procter & Gamble Company | Procede de nettoyage d'une surface dure |
| EP1167500A1 (fr) * | 2000-06-29 | 2002-01-02 | The Procter & Gamble Company | Procédé pour le nettoyage d'une surface dure |
| WO2002002724A1 (fr) * | 2000-06-29 | 2002-01-10 | The Procter & Gamble Company | Procede de nettoyage d'une surface dure |
| US6936578B2 (en) | 2001-01-19 | 2005-08-30 | Reckitt Benckiser N.V. | Nonaqueous liquid detergent compositions |
| GB2371307B (en) * | 2001-01-19 | 2003-10-15 | Reckitt Benckiser Nv | Packaged detergent compositions |
| GB2371307A (en) * | 2001-01-19 | 2002-07-24 | Reckitt Benckiser Nv | Liquid detergent compositions |
| WO2003095598A1 (fr) * | 2002-05-11 | 2003-11-20 | Reckitt Benckiser N.V. | Composition detergente |
| WO2004046291A1 (fr) * | 2002-11-21 | 2004-06-03 | Liquid Science Laboratories Ltd | Solvant |
| US8785366B2 (en) | 2008-05-23 | 2014-07-22 | Colgate-Palmolive Company | Liquid cleaning compositions and methods |
| EP2447349A1 (fr) | 2010-10-29 | 2012-05-02 | The Procter & Gamble Company | Composition liquide de nettoyage d'une surface dure |
| WO2012058250A1 (fr) | 2010-10-29 | 2012-05-03 | The Procter & Gamble Company | Composition de nettoyage de surfaces dures sous forme de liquide épaissi |
| RU2554948C2 (ru) * | 2010-10-29 | 2015-07-10 | Дзе Проктер Энд Гэмбл Компани | Загущенная жидкая композиция для очистки твердых поверхностей |
| JP2016124965A (ja) * | 2014-12-26 | 2016-07-11 | ライオン株式会社 | 浴室用液体洗浄剤 |
| CN104789387A (zh) * | 2015-04-28 | 2015-07-22 | 苏州永创达电子有限公司 | 一种有机溶剂型清洗剂 |
| EP3263682A1 (fr) | 2016-06-27 | 2018-01-03 | The Procter and Gamble Company | Compositions de nettoyage d'une surface dure |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0080749B1 (fr) | 1986-04-16 |
| CA1202858A (fr) | 1986-04-08 |
| JPS58132097A (ja) | 1983-08-06 |
| DE3270670D1 (en) | 1986-05-22 |
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