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DK200200828A - Selvregulerende katalysator - Google Patents

Selvregulerende katalysator Download PDF

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Publication number
DK200200828A
DK200200828A DK200200828A DKPA200200828A DK200200828A DK 200200828 A DK200200828 A DK 200200828A DK 200200828 A DK200200828 A DK 200200828A DK PA200200828 A DKPA200200828 A DK PA200200828A DK 200200828 A DK200200828 A DK 200200828A
Authority
DK
Denmark
Prior art keywords
passage
catalyst
self
last
catalyst according
Prior art date
Application number
DK200200828A
Other languages
English (en)
Inventor
Niels Bjarne Kampp Rasmussen
Original Assignee
Reccat Aps
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Reccat Aps filed Critical Reccat Aps
Priority to DK200200828A priority Critical patent/DK200200828A/da
Priority to PCT/DK2003/000356 priority patent/WO2003102392A1/en
Priority to US10/516,442 priority patent/US20060048501A1/en
Priority to CA002487768A priority patent/CA2487768A1/en
Priority to NZ536764A priority patent/NZ536764A/en
Priority to JP2004509253A priority patent/JP2005528552A/ja
Priority to EP03727247A priority patent/EP1532354A1/en
Priority to AU2003233782A priority patent/AU2003233782A1/en
Publication of DK200200828A publication Critical patent/DK200200828A/da

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0207Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal
    • B01J8/0221Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal in a cylindrical shaped bed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0285Heating or cooling the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0292Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds with stationary packing material in the bed, e.g. bricks, wire rings, baffles
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2803Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
    • F01N3/2825Ceramics
    • F01N3/2828Ceramic multi-channel monoliths, e.g. honeycombs
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2803Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
    • F01N3/2835Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support fibrous
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00477Controlling the temperature by thermal insulation means
    • B01J2208/00495Controlling the temperature by thermal insulation means using insulating materials or refractories
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/0053Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322Basic shape of the elements
    • B01J2219/32296Honeycombs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/324Composition or microstructure of the elements
    • B01J2219/32466Composition or microstructure of the elements comprising catalytically active material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/324Composition or microstructure of the elements
    • B01J2219/32466Composition or microstructure of the elements comprising catalytically active material
    • B01J2219/32475Composition or microstructure of the elements comprising catalytically active material involving heat exchange
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2330/00Structure of catalyst support or particle filter
    • F01N2330/02Metallic plates or honeycombs, e.g. superposed or rolled-up corrugated or otherwise deformed sheet metal
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2330/00Structure of catalyst support or particle filter
    • F01N2330/06Ceramic, e.g. monoliths
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2330/00Structure of catalyst support or particle filter
    • F01N2330/10Fibrous material, e.g. mineral or metallic wool
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2570/00Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
    • F01N2570/10Carbon or carbon oxides
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2570/00Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
    • F01N2570/12Hydrocarbons
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2570/00Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
    • F01N2570/14Nitrogen oxides
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Analytical Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Biomedical Technology (AREA)
  • Toxicology (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Ceramic Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Description

PATENTKRAV 1 Katalysator (1) til rensning af en luft- eller gasmængde indeholdende brændbare stoffer over en vis minimumsmængde, kendetegnet ved at den indeholder flere passager, som (a) er indbyrdes forbundne, som (b) har en indbyrdes varmeveksling, og (c) hvori der i det mindste i én passage er katalysatormateriale af én eller flere slags 2 Katalysator ifølge krav I,kendetegnet ved, at næstsidste passage (3) indeholder én eller flere slags katalysatormateriale (4), og at denne passage varmeveksler med sidste passage (5) i modstrøm 3 Katalysator ifølge krav 1 eller 2, kendetegnet ved, at der er tre passager i katalysatoren, hvor første passage (II) varmeveksler med anden passage (3), fortrinsvis med første passage udenpå anden passage 4 Katalysator ifølge krav 1, 2 eller 3, k e n d e t e g n e t ved, at tredjesidste passage (11) indeholder én eller flere slags katalysatormateriale 5 Katalysator ifølge krav 1, 2, 3 eller 4, kendetegnet ved, at der er et lag isolering (12) mellem tredjesidste og næstsidste passage for at nedsætte varmevekslingen 6 Katalysator ifølge krav 1, 2, 3,4 eller 5, kendetegnet ved, at tværsnitsarealerne af henholdsvis næstsidste (3) og tredjesidste (II) passage er mellem 0,5 og 10, fortrinsvis omkring 2 gange tværsmtsarealet af sidste passage (5) 7 Katalysator ifølge krav 1, 2, 3, 4, 5 eller 6, kendetegnet ved, at tværsnitsarealet af sidste passage (5) er mellem 0,5 og 5, fortrinsvis omkring 1,5 gange tværsnitsarealet af tilgangsrøret (2) til katalysatoren, hvilket tilgangsrør er udstødningsrøret for en eventuel tilknyttet forbrændingsmotor 8 Katalysator ifølge krav 1, 2, 3,4, 5, 6 eller 7, k e n d e t e g n e t ved, at sidste passage (5) består af cirkulære parallelle rør 9 Katalysator ifølge krav 1, 2, 3, 4, 5, 6 eller 7, kendetegnet ved, at sidste passage (5) består af lameller eller ikke cirkulære kanaler, dvs ikke cirkulære parallelle rør 10 Katalysator ifølge krav 8, kendetegnet ved, at rørene set i tværsnit sidder i trekant- eller firkantmønster
DK200200828A 2002-05-30 2002-05-30 Selvregulerende katalysator DK200200828A (da)

Priority Applications (8)

Application Number Priority Date Filing Date Title
DK200200828A DK200200828A (da) 2002-05-30 2002-05-30 Selvregulerende katalysator
PCT/DK2003/000356 WO2003102392A1 (en) 2002-05-30 2003-05-27 Catalytic device with internal heat exchange
US10/516,442 US20060048501A1 (en) 2002-05-30 2003-05-27 Catalytic device with internal heat exchange
CA002487768A CA2487768A1 (en) 2002-05-30 2003-05-27 Catalytic device with internal heat exchange
NZ536764A NZ536764A (en) 2002-05-30 2003-05-27 Catalytic device with internal heat exchange
JP2004509253A JP2005528552A (ja) 2002-05-30 2003-05-27 内部で熱交換を行う触媒装置
EP03727247A EP1532354A1 (en) 2002-05-30 2003-05-27 Catalytic device with internal heat exchange
AU2003233782A AU2003233782A1 (en) 2002-05-30 2003-05-27 Catalytic device with internal heat exchange

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DK200200828A DK200200828A (da) 2002-05-30 2002-05-30 Selvregulerende katalysator

Publications (1)

Publication Number Publication Date
DK200200828A true DK200200828A (da) 2003-12-01

Family

ID=29594977

Family Applications (1)

Application Number Title Priority Date Filing Date
DK200200828A DK200200828A (da) 2002-05-30 2002-05-30 Selvregulerende katalysator

Country Status (8)

Country Link
US (1) US20060048501A1 (da)
EP (1) EP1532354A1 (da)
JP (1) JP2005528552A (da)
AU (1) AU2003233782A1 (da)
CA (1) CA2487768A1 (da)
DK (1) DK200200828A (da)
NZ (1) NZ536764A (da)
WO (1) WO2003102392A1 (da)

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JP4552138B2 (ja) * 2005-06-02 2010-09-29 株式会社デンソー NOx除去装置
DE102005057666A1 (de) * 2005-12-01 2007-07-12 Emitec Gesellschaft Für Emissionstechnologie Mbh Vorrichtung und Verfahren zur thermischen Behandlung eines Abgasstroms
WO2009048994A2 (en) * 2007-10-12 2009-04-16 Dow Global Technologies Inc. Improved thermal shock resistant soot filter
DE102008051830A1 (de) * 2008-10-17 2010-04-22 Deutz Ag Verfahren und Vorrichtung zur thermischen Regeneration von Partikelfiltern an Brennkraftmaschinen mittels eines katalytischen Brenners
CN103968395A (zh) * 2013-02-04 2014-08-06 中国科学院大连化学物理研究所 一种脱除尾气中氢气的催化燃烧反应器及工艺
KR102456482B1 (ko) * 2018-04-04 2022-10-19 유니프랙스 아이 엘엘씨 활성화된 다공성 섬유 및 이를 포함하는 제품
JP7340773B2 (ja) * 2018-06-12 2023-09-08 パナソニックIpマネジメント株式会社 燃料電池システム
CN111140323B (zh) * 2020-01-02 2021-04-13 佛吉亚(柳州)排气控制技术有限公司 一种三元催化器
CA3192115A1 (en) 2020-09-21 2022-03-24 Kevin E. SITERS Homogeneous catalytic fiber coatings and methods of preparing same

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US1927286A (en) * 1926-04-09 1933-09-19 Selden Co Catalytic apparatus
US1953938A (en) * 1927-11-21 1934-04-10 Selden Co Purification of by-product ammonia
JPS5556823A (en) * 1978-10-19 1980-04-26 Daikin Ind Ltd Catalytic oxidation apparatus
DE3713964A1 (de) * 1987-04-25 1988-11-03 Bayerische Motoren Werke Ag Anordnung eines katalysatorgehaeuses in der abgasleitung von fahrzeug-brennkraftmaschinen
JPS6451126A (en) * 1987-08-20 1989-02-27 Mitsubishi Heavy Ind Ltd High temperature catalyst device
DE4109227A1 (de) * 1991-03-21 1992-09-24 Schwaebische Huettenwerke Gmbh Abgasfilter und/oder katalysator
US5303547A (en) * 1992-04-15 1994-04-19 Amoco Corporation Emissions control system and method
US5846494A (en) * 1992-04-30 1998-12-08 Gaiser; Gerd Reactor for catalytically processing gaseous fluids
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US5983628A (en) * 1998-01-29 1999-11-16 Chrysler Corporation System and method for controlling exhaust gas temperatures for increasing catalyst conversion of NOx emissions
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Also Published As

Publication number Publication date
CA2487768A1 (en) 2003-12-11
NZ536764A (en) 2006-07-28
US20060048501A1 (en) 2006-03-09
AU2003233782A1 (en) 2003-12-19
WO2003102392A1 (en) 2003-12-11
EP1532354A1 (en) 2005-05-25
JP2005528552A (ja) 2005-09-22

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