DE975855C - Dyeing auxiliaries - Google Patents
Dyeing auxiliariesInfo
- Publication number
- DE975855C DE975855C DEF2408A DEF0002408A DE975855C DE 975855 C DE975855 C DE 975855C DE F2408 A DEF2408 A DE F2408A DE F0002408 A DEF0002408 A DE F0002408A DE 975855 C DE975855 C DE 975855C
- Authority
- DE
- Germany
- Prior art keywords
- acid
- amino group
- hydrocarbons
- und
- der
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004043 dyeing Methods 0.000 title claims description 8
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 5
- 125000005210 alkyl ammonium group Chemical group 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- 125000003277 amino group Chemical group 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 102000004169 proteins and genes Human genes 0.000 claims description 3
- 108090000623 proteins and genes Proteins 0.000 claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 150000007522 mineralic acids Chemical class 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 210000002268 wool Anatomy 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical class Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000004580 weight loss Effects 0.000 description 3
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 235000011167 hydrochloric acid Nutrition 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 2
- KBLAMUYRMZPYLS-UHFFFAOYSA-N 2,3-bis(2-methylpropyl)naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(O)(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 KBLAMUYRMZPYLS-UHFFFAOYSA-N 0.000 description 1
- WHKKNVAGWPTSRS-UHFFFAOYSA-N 2-dodecylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(CCCCCCCCCCCC)=CC=C21 WHKKNVAGWPTSRS-UHFFFAOYSA-N 0.000 description 1
- CTIFKKWVNGEOBU-UHFFFAOYSA-N 2-hexadecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O CTIFKKWVNGEOBU-UHFFFAOYSA-N 0.000 description 1
- WUBBRNOQWQTFEX-UHFFFAOYSA-N 4-aminosalicylic acid Chemical compound NC1=CC=C(C(O)=O)C(O)=C1 WUBBRNOQWQTFEX-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 1
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- -1 aminophenol carboxylic acid Chemical class 0.000 description 1
- 229960004909 aminosalicylic acid Drugs 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- 229940106681 chloroacetic acid Drugs 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical group NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229960002449 glycine Drugs 0.000 description 1
- 235000013905 glycine and its sodium salt Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- CACRRXGTWZXOAU-UHFFFAOYSA-N octadecane-1-sulfonic acid Chemical compound CCCCCCCCCCCCCCCCCCS(O)(=O)=O CACRRXGTWZXOAU-UHFFFAOYSA-N 0.000 description 1
- 125000006308 propyl amino group Chemical group 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 description 1
- 229960004319 trichloroacetic acid Drugs 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical group CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67316—Acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
- D06P1/621—Compounds without nitrogen
- D06P1/622—Sulfonic acids or their salts
- D06P1/625—Aromatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/647—Nitrogen-containing carboxylic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
- D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
Description
Färbereihilfsmittel Gegenstand der Erfindung ist ein Färbereihilfsmittel zum Schutz für eiweißhaltige Fasern, bestehend aus oder enthaltend Ammonium- und/oder Alkylammoniumsalze erstens einer anorganischen Säure, zweitens einer organischen Sulfonsäure und drittens einer 2 bis 7 Kohlenstoffatome enthaltenden Carbonsäure, die durch Chlor oder eine Aminogruppe bzw. durch eine Ammogruppe und einer Hydroxylgruppe substituiert ist, wobei dem Mittel gegebenenfalls noch Kohlenwasserstoffe beigefügt sein können.Dyeing auxiliaries The invention relates to a dyeing aid to protect protein-containing fibers, consisting of or containing ammonium and / or Alkylammonium salts firstly of an inorganic acid, secondly of an organic one Sulfonic acid and thirdly a carboxylic acid containing 2 to 7 carbon atoms, by chlorine or an amino group or by an ammo group and a hydroxyl group is substituted, with the agent optionally also added hydrocarbons could be.
Als Alkylammoniumkomponenten der Salze eignen sich beispielsweise solche, die Mono-, Di-oder Trimethylamingruppen oder die entsprechenden Äthyl- oder Propylamingruppen bzw. die Cyclohexylamingruppe enthalten. Als Säurekomponenten seien für die drei in Betracht kommenden Salzsäuren folgende Verbindungen beispielsweise genannt: Salzsäure, Schwefelsäure, ferner Octadecylsulfonsäure, Hexadecylbenzolsulfonsäure, Dodecylnaphthalinsulfonsäure sowie Mono-, Di-oder Trichloressigsäure, Aminoessigsäure, Aminosalicylsäure, Aminophenolcarbonsäure. Als Kohlenwasserstoffe finden vorzugsweise gesättigte Paraffine mit etwa ro bis 2o Kohlenstoffatomen im Molekül Berücksichtigung.Examples of suitable alkylammonium components of the salts are those, the mono-, di- or trimethylamine groups or the corresponding ethyl or Propylamine groups or the cyclohexylamine group contain. As acid components the following compounds are examples of the three hydrochloric acids that can be considered named: hydrochloric acid, sulfuric acid, also octadecylsulphonic acid, hexadecylbenzenesulphonic acid, Dodecylnaphthalenesulfonic acid and mono-, di- or trichloroacetic acid, aminoacetic acid, Aminosalicylic acid, aminophenol carboxylic acid. The preferred hydrocarbons are Saturated paraffins with about ro to 20 carbon atoms in the molecule are taken into account.
Die erfindungsgemäß zu verwendende Mischung kann in beliebiger Weise hergestellt werden, z. B. in der Weise, daß man fertige Ammonium- und/ oder Alkylammoniumsalze der in Betracht kommenden Säuren gegebenenfalls unter Zugabe von Kohlenwasserstoffen miteinander mischt, oder aber auch in der Weise, daß man die Säure- und Basenkomponenten in wäßrigem Medium miteinander zur Umsetzung bringt und dabei gegebenenfalls Kohlenwasserstoffeze einem beliebigenZeitpunkt hinzufügt.The mixture to be used according to the invention can be used in any desired manner be produced, e.g. B. in such a way that one finished ammonium and / or alkylammonium salts of the acids in question, optionally with the addition of hydrocarbons mixes with each other, or else also in such a way that the acid and base components react with one another in an aqueous medium and thereby optionally adding hydrocarbons at any point in time.
Die Mengenverhältnisse der einzelnen Komponenten in der Mischung können in weiten Grenzen schwanken. Eine geeignete Mischung erhält man z. B., wenn man 2o Gewichtsteile sulfochlorierte aliphatische Kohlenwasserstoffe der Kohlenstoffreihe 12 bis 18, die noch etwa 15'% unveränderte Kohlenwasserstoffe enthalten, 12 Gewichtsteile Diisobutylnaphthalinsulfonsäure und 9 Gewichtsteile Chloressigsäure allmählich unter Rühren mit 24 Gewichtsteilen 25°/ongem Ammoniakwasser versetzt, anschließend noch 13 Gewichtsteile Ammoniumsulfat zusetzt und mit Wasser auf ioo Gewichtsteile auffüllt. Die gebildete Mischung stellt eine klare, viskose Flüssigkeit dar.The proportions of the individual components in the mixture can fluctuate within wide limits. A suitable mixture is obtained, for. B. if one 20 parts by weight of sulfochlorinated aliphatic hydrocarbons of the carbon series 12 to 18, which still contain about 15% unchanged hydrocarbons, 12 parts by weight Diisobutylnaphthalenesulfonic acid and 9 parts by weight of chloroacetic acid gradually under Stirring mixed with 24 parts by weight of 25% ammonia water, then added 13 parts by weight of ammonium sulfate are added and made up to 100 parts by weight with water. The resulting mixture is a clear, viscous liquid.
Das erfindungsgemäß zu verwendende Färbereihilfsmittel bewährt sich in all den Fällen, in denen eiweißhaltige Fasern oder diese enthaltende Fasermischengen beim Färben oder beim Abziehen schädlichen chemischen Einflüssen ausgesetzt sind. Außer der faserschützenden Wirkung besitzt das vorgeschlagene Mittel auch eine gute Durchfärbewirkung beim Färben von Filzen u. dgl. Zum Unterschied von bekannten Textilhilfsmitteln, die die eine oder andere Komponente enthalten, ruft die erfindungsgemäß zu verwendende Mischung keine störenden Nebenwirkungen hervor, insbesondere wird die Anfärbbarkeit von Wolle nicht beeinträchtigt, und bei behandelten Wollfilzen führt Belichtung nicht zum Vergilben.The dyeing aid to be used according to the invention has proven itself in all cases in which protein-containing fibers or fiber mixtures containing them are exposed to harmful chemical influences during dyeing or peeling. In addition to the fiber-protecting effect, the proposed agent also has a good one Through-dyeing effect when dyeing felts and the like. In contrast to known textile auxiliaries, which contain one or the other component calls for that to be used according to the invention Mixture does not cause any disturbing side effects, especially the colorability unaffected by wool, and treated wool felts will result in exposure not to yellow.
Gegenüber bekannten Faserschutzmitteln, wie z. B. gegenüber Sulfitablaugepräparaten,
zeichnet sich das neue Mittel durch eine beträchtlich bessere Wirkung aus. Dies
geht aus den nachstehend wiedergegebenen Ergebnissen von Vergleichsversuchen hervor,
bei denen Wollgarn jeweils 45 Minuten bei 95° C in einer wässerigen o,5%igen Sodalösung
mit verschiedenen Zusätzen behandelt wurde. Es bedeutet
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF2408A DE975855C (en) | 1950-08-13 | 1950-08-13 | Dyeing auxiliaries |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF2408A DE975855C (en) | 1950-08-13 | 1950-08-13 | Dyeing auxiliaries |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE975855C true DE975855C (en) | 1962-11-15 |
Family
ID=7083263
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEF2408A Expired DE975855C (en) | 1950-08-13 | 1950-08-13 | Dyeing auxiliaries |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE975855C (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE561603C (en) * | 1929-09-10 | 1932-10-15 | Oranienburger Chem Fab Akt Ges | Process for the preservation of superoxide solutions, especially for bleaching purposes |
| DE695279C (en) * | 1934-12-18 | 1940-08-21 | Anneliese Beyer | Process for the production of aromatic di- and polysulfonic acids |
-
1950
- 1950-08-13 DE DEF2408A patent/DE975855C/en not_active Expired
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE561603C (en) * | 1929-09-10 | 1932-10-15 | Oranienburger Chem Fab Akt Ges | Process for the preservation of superoxide solutions, especially for bleaching purposes |
| DE695279C (en) * | 1934-12-18 | 1940-08-21 | Anneliese Beyer | Process for the production of aromatic di- and polysulfonic acids |
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