DE902111C - Recording medium made of electrically conductive paper for radio broadcasting purposes u. Like. And method for its preparation - Google Patents
Recording medium made of electrically conductive paper for radio broadcasting purposes u. Like. And method for its preparationInfo
- Publication number
- DE902111C DE902111C DEI3198D DEI0003198D DE902111C DE 902111 C DE902111 C DE 902111C DE I3198 D DEI3198 D DE I3198D DE I0003198 D DEI0003198 D DE I0003198D DE 902111 C DE902111 C DE 902111C
- Authority
- DE
- Germany
- Prior art keywords
- metal powder
- recording medium
- paper
- medium according
- electrically conductive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 4
- 239000000843 powder Substances 0.000 claims description 19
- 229910052751 metal Inorganic materials 0.000 claims description 17
- 239000002184 metal Substances 0.000 claims description 17
- 239000000126 substance Substances 0.000 claims description 15
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims description 7
- 229930195725 Mannitol Natural products 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- 239000000594 mannitol Substances 0.000 claims description 7
- 235000010355 mannitol Nutrition 0.000 claims description 7
- PWVUXRBUUYZMKM-UHFFFAOYSA-N 2-(2-hydroxyethoxy)ethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOCCO PWVUXRBUUYZMKM-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 229940031768 diglycol stearate Drugs 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 150000001299 aldehydes Chemical class 0.000 claims description 4
- 150000002576 ketones Chemical class 0.000 claims description 4
- 230000001681 protective effect Effects 0.000 claims description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 4
- 239000000975 dye Substances 0.000 claims description 3
- 239000002657 fibrous material Substances 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- 235000000346 sugar Nutrition 0.000 claims description 3
- 239000004386 Erythritol Substances 0.000 claims description 2
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 238000003490 calendering Methods 0.000 claims description 2
- FKPGNMBJYBPNHL-UHFFFAOYSA-L dioxido-oxo-sulfanylidene-$l^{6}-sulfane;lead(2+) Chemical compound [Pb+2].[O-]S([O-])(=O)=S FKPGNMBJYBPNHL-UHFFFAOYSA-L 0.000 claims description 2
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 claims description 2
- 235000019414 erythritol Nutrition 0.000 claims description 2
- 229940009714 erythritol Drugs 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 150000005846 sugar alcohols Polymers 0.000 claims description 2
- 150000008163 sugars Chemical class 0.000 claims description 2
- QXKXDIKCIPXUPL-UHFFFAOYSA-N sulfanylidenemercury Chemical compound [Hg]=S QXKXDIKCIPXUPL-UHFFFAOYSA-N 0.000 claims description 2
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 claims 1
- 229960001855 mannitol Drugs 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 125000001820 oxy group Chemical class [*:1]O[*:2] 0.000 claims 1
- 229960001755 resorcinol Drugs 0.000 claims 1
- -1 aromatic alcohols Chemical class 0.000 description 4
- 239000002923 metal particle Substances 0.000 description 4
- 229920001131 Pulp (paper) Polymers 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- HFVMEOPYDLEHBR-UHFFFAOYSA-N (2-fluorophenyl)-phenylmethanol Chemical compound C=1C=CC=C(F)C=1C(O)C1=CC=CC=C1 HFVMEOPYDLEHBR-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- XWHFEIYSZLQWLG-UHFFFAOYSA-N 2-(2-hydroxypropyl)-6-methyl-1,3-dioxan-4-ol Chemical compound CC(O)CC1OC(C)CC(O)O1 XWHFEIYSZLQWLG-UHFFFAOYSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N Lactic Acid Natural products CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 239000008121 dextrose Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- VRNINGUKUJWZTH-UHFFFAOYSA-L lead(2+);dithiocyanate Chemical compound [Pb+2].[S-]C#N.[S-]C#N VRNINGUKUJWZTH-UHFFFAOYSA-L 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- ZDCHZHDOCCIZIY-UHFFFAOYSA-N phthalic acid;propane-1,2,3-triol Chemical compound OCC(O)CO.OC(=O)C1=CC=CC=C1C(O)=O ZDCHZHDOCCIZIY-UHFFFAOYSA-N 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 229960004793 sucrose Drugs 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/20—Duplicating or marking methods; Sheet materials for use therein using electric current
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/14—Carboxylic acids; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/76—Processes or apparatus for adding material to the pulp or to the paper characterised by choice of auxiliary compounds which are added separately from at least one other compound, e.g. to improve the incorporation of the latter or to obtain an enhanced combined effect
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/22—Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
-
- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04L—TRANSMISSION OF DIGITAL INFORMATION, e.g. TELEGRAPHIC COMMUNICATION
- H04L13/00—Details of the apparatus or circuits covered by groups H04L15/00 or H04L17/00
- H04L13/02—Details not particular to receiver or transmitter
- H04L13/06—Tape or page guiding or feeding devices
-
- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04N—PICTORIAL COMMUNICATION, e.g. TELEVISION
- H04N1/00—Scanning, transmission or reproduction of documents or the like, e.g. facsimile transmission; Details thereof
- H04N1/23—Reproducing arrangements
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/69—Water-insoluble compounds, e.g. fillers, pigments modified, e.g. by association with other compositions prior to incorporation in the pulp or paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
Landscapes
- Signal Processing (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Computer Networks & Wireless Communication (AREA)
- Multimedia (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Paper (AREA)
- Liquid Developers In Electrophotography (AREA)
- Electrophotography Using Other Than Carlson'S Method (AREA)
- Photoreceptors In Electrophotography (AREA)
Description
(WiGBl. S. 175)(WiGBl. P. 175)
AUSGEGEBEN AM 18. JANUAE1954ISSUED JANUARY 18, 1954
I 3198 IVb 155 fI 3198 IVb 155 f
Die Erfindung bezieht sich auf Aufzeichnungsträger aus elektrisch leitendem Papier, insbesondere mit einer leichten Farbtönung, und auf Verfahren zur Herstellung eines solchen Papiers.The invention relates to recording media made of electrically conductive paper, in particular with a slight tint, and methods of making such paper.
Es ist bereits vorgeschlagen worden, elektrisch leitendes Papier dadurch herzustellen, daß ein Faserstoff oder eine Papiermasse mit Metallpulver, ζ. Β. Aluminiumpulver, versetzt wird, wobei die einzelnen Metallpartikel das Papier leitend machen. Es hat sich jedoch gezeigt, daß die Partikel leicht oxydieren, so daß schlechte Kontaktflächen entstehen, wodurch die Leitfähigkeit des Papiers beeinträchtigt wird.It has already been proposed to produce electrically conductive paper in that a fiber material or a paper pulp with metal powder, ζ. Β. Aluminum powder, is added, with the individual metal particles make the paper conductive. However, it has been found that the particles oxidize easily, so that poor contact surfaces arise, which affects the conductivity of the paper.
Bei der Wiedergabe von Bildern durch Bildtelegraphie od. dgl. ist es sehr erwünscht, ein leicht farbiges Papier zu benutzen, das elektrisch leitend ist. Bisher war es jedoch nicht möglich, diese Aufgabe zu lösen, sondern man hat dunkles Papier benutzt, in dem Kohle enthalten war, oder man hat sich auf das Prinzip der Ionenleitung gestützt. Es ist ferner erwünscht, daß das für die Aufzeichnung zur Verwendung kommende Papier nicht vor Ingebrauchnahme vorbereitet, d.h. angefeuchtet oder getrocknet werden muß.When reproducing pictures by picture telegraphy or the like, it is very desirable to have a slightly colored Use paper that is electrically conductive. So far, however, it has not been possible to perform this task solve, but you used dark paper that contained charcoal, or you relied on that Principle of ion conduction supported. It is also desirable that the for recording for use incoming paper must not be prepared, i.e. moistened or dried, before use.
Gemäß der Erfindung wird ein elektrisch leitendes Papier oder anderer Faserstoff vorgeschlagen, in dem eine Mischung aus einem Metallpulver, ζ. Β. Aluminiumpulver, und einem diesem gegenüber sich reduzierend oder neutral verhaltenden Mittel enthalten ist.According to the invention, an electrically conductive paper or other fibrous material is proposed in which a mixture of a metal powder, ζ. Β. Aluminum powder, and one of these reducing itself or neutral agent is included.
Wie bereits erwähnt, hat man festgestellt, daß Aluminiumpulver oder ein anderes Metallpulver, das dem Papierstoff zugesetzt wird, leicht oxydiert, so daß die elektrische Leitfähigkeit des Papiers in Frage gestellt wird. Es wurde nun festgestellt, daß gewisseAs already mentioned, it has been found that aluminum powder or another metal powder that is added to the paper stock, easily oxidized, so that the electrical conductivity of the paper in question is provided. It has now been established that certain
Substanzen, die sich reduzierend oder neutral zu Metallpulvern verhalten, in der Lage sind, die Leitfähigkeit der einzelnen Metallpartikel aufrechtzuerhalten, ohne daß eine Oxyd- oder ähnlich hoch isolierende Schicht entsteht. Wird ein Metallpulver somit erfindungsgemäß mit einer solchen Substanz gemischt, so entsteht eine metallähnliche Masse, in der die Metallpartikel genügend große und reine Kontaktflächen aufweisen, die dazu geeignet sind, die Leitfähigkeit aufrechtzuerhalten.Substances that are reducing or neutral to metal powders are able to increase the conductivity of the individual metal particles to be maintained without causing an oxide or similar high insulating layer is created. Thus, according to the invention, a metal powder is provided with such a substance mixed, the result is a metal-like mass in which the metal particles have sufficiently large and pure contact surfaces that are suitable for maintaining conductivity.
Als solche Substanzen kommen z. B. feste aliphatische und aromatische Alkohole, und zwar sowohl einals auch mehrwertige, ferner Aldehyde oder Ketone mit oder ohne gelöste Elektrolyte in Frage. Eine feste Substanz, die zu hervorragenden Ergebnissen führt, ist Mannit, ein sechswertiger Alkohol, der als weißes Pulver gewonnen wird. Ein zweites wichtiges Material ist Diglykolstearat, bekanntlich ein Stearinsäureester des Diäthylenglykols, mit dem gleichwertige Resultate wie mit Mannit erzielt werden. Eine weitere Substanz, die als Schutzmasse benutzt werden kann, ist z. B. der vierwertige Alkohol Erythrit. Die bisher genannten Stoffe sind einfach aufgebaute mehrwertige Alkohole. Außerdem können jedoch auch Resorcin, ferner einwertige Alkohole, in denen mehr als io Kohlenstoffatome im Molekül enthalten sind, gewisse Zucker arten, wie z. B. Dextrose, Maltose und Rohrzucker, und gewisse Oxysäuren, wie z. B. Bernstein- oder Apfelsäure, verwendet werden. Auch höhere Aldehyde, wie z. B. der unter dem Namen Paraldol bekannte Stoff, ferner Milchsäurealdehyd, sowie Ketone, wie z. B. Benzophenon, können als feste Substanzen in gleicher Weise verwendet werden. Polyoxy verbindungen, die zum Teil verestert und strukturmäßig dem Glyzerinmonophthalat ähnlich sind, kommen in derselben Weise zur Verwendung. Bevorzugte Schutzsubstanzen sind feste mehrwertige Alkohole und ihre Abkömmlinge sowie verwandte Substanzen und ihre Derivate, wie z. B. Aldehyde, Ketone, Zucker und gewisse Oxysäuren, die die gleichen Eigenschaften aufweisen. Aus Estern bestehende Stoffe, wie z. B. Carnaubawachs, sind auch geeignete Mittel.Such substances come e.g. B. solid aliphatic and aromatic alcohols, both as also polyvalent, further aldehydes or ketones with or without dissolved electrolytes in question. A firm one Substance that gives excellent results is mannitol, a hexahydric alcohol that is known as white Powder is obtained. A second important material is diglycol stearate, known to be a stearic acid ester of diethylene glycol, with which results equivalent to those obtained with mannitol are achieved. Another substance which can be used as a protective mass is, for. B. the tetravalent alcohol erythritol. The ones mentioned so far Substances are simply composed polyvalent alcohols. In addition, however, resorcinol can also be used, furthermore monohydric alcohols, which contain more than 10 carbon atoms in the molecule, certain types of sugar, such as B. dextrose, maltose and cane sugar, and certain oxyacids, such as. B. succinic or malic acid, be used. Even higher aldehydes, such as. B. the substance known under the name Paraldol, also Lactic acid aldehyde, and ketones, such as. B. Benzophenone can be used as solid substances in the same way be used. Polyoxy compounds, which are partly esterified and structurally the glycerol monophthalate are used in the same way. Preferred protective substances are solid polyhydric alcohols and their derivatives and related substances and their derivatives, such as. B. Aldehydes, ketones, sugars and certain oxyacids that have the same properties. Made from esters existing substances, such as B. carnauba wax, are also suitable agents.
Diese Substanzen, von denen vor allem Mannit und Diglykolstearat bevorzugt werden, können geschmolzen und mit einer Menge von 30 bis 150 °/0 eines Metallpulvers, beispielsweise aus Aluminium, gemischt und dann abgekühlt werden. Solche Mischungen sind elektrisch leitend und können in den Faserstoff, also z. B. in die Papierblätter eingelagert werden. An Stelle des Aluminiumpulvers können natürlich auch andere Pulver, z. B. aus Kupfer, Messing, Bronze, Eisen und Zink, benutzt werden. Die in Flockenform anfallenden Metallpulver werden auf Grund ihrer günstigen, Licht reflektierenden und aufhellenden Eigenschaften bevorzugt. These substances, of which are preferable especially mannitol and diglycol stearate, may be melted and blended with an amount of 30 to 150 ° / 0 of a metal powder, for example of aluminum, and then cooled. Such mixtures are electrically conductive and can be in the fiber, so z. B. be stored in the paper sheets. Instead of the aluminum powder, of course, other powders, e.g. B. made of copper, brass, bronze, iron and zinc can be used. The metal powders obtained in flake form are preferred because of their favorable light-reflecting and brightening properties.
Jede Mischung eines jeden genannten Materials kann dem Papier dadurch beigegeben werden, daß man das Metallpulver zunächst mit der Papiermasse in üblicher Weise in einem Gefäß vermischt und dann, nachdem die Papierbahn wenigstens zum Teil in der üblichen Weise getrocknet worden ist, die Papiermasse mit Hilfe einer wäßrigen oder alkoholischen Lösung einer der obengenannten Schutzsubstanzen, vorzugsweise also Diglykolstearat oder Mannit, imprägniert. Das Imprägnieren kann so durchgeführt werden, daß die Papierbahn durch ein Bad der geschmolzenen festen Lösung gezogen wird oder daß die Lösung mit Hilfe einer Walze dem Papier zugeführt wird. Danach kann die Papierbahn getrocknet und heiß kalandriert werden, so daß der Mannit oder das Diglykolstearat schmilzt und eine leitende Verbindung zwischen den einzelnen Metallpartikeln in dem Papier herstellt.Any mixture of any of the named materials can be added to the paper by the metal powder is first mixed with the paper pulp in the usual way in a vessel and then, after the paper web has been dried at least partially in the usual way, the paper pulp with the aid of an aqueous or alcoholic solution of one of the above protective substances, preferably i.e. diglycol stearate or mannitol, impregnated. The impregnation can be carried out so that the paper web is pulled through a bath of the molten solid solution or that the solution with With the help of a roller the paper is fed. The paper web can then be dried and hot-calendered be, so that the mannitol or diglycol stearate melts and a conductive connection between the produces individual metal particles in the paper.
Leitende Papiere gemäß der Erfindung werden im allgemeinen mit Farbstoffen vermischt, wobei der zur Markierung benutzte Stromdurchgang durch das Papier eine Farbänderung bewirkt. Solche Beimischungen können z. B. aus Bleithiosulfat, Bleirhodanid oder Quecksilbersulfid bestehen, die gleichzeitig mit dem Metallpulver in das Mischgefäß gefüllt werden, damit sie innig mit dem Metallpulver und dem Faserstoff vermengt werden. Die Farbstoffe können auch als äußere Schicht auf die Papierbahn aufgetragen werden. Wenn der elektrische Strom durch ein Papier geleitet wird, das nach dem oben beschriebenen Verfahren hergesteEt ist, entsteht ein klares Bild, das allen Anforderungen genügt.Conductive papers according to the invention are generally mixed with dyes, the for Marking used current passage through the paper causes a color change. Such admixtures can e.g. B. consist of lead thiosulfate, lead thiocyanate or mercury sulfide, which at the same time be filled with the metal powder in the mixing vessel so that they are intimately with the metal powder and are mixed with the pulp. The dyes can also be applied to the paper web as an outer layer will. When the electric current is passed through a paper made according to the above Process is established, a clear picture emerges that meets all requirements.
Claims (7)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US286804A US2374214A (en) | 1939-07-27 | 1939-07-27 | Conductive papers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE902111C true DE902111C (en) | 1954-01-18 |
Family
ID=23100223
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEI3198D Expired DE902111C (en) | 1939-07-27 | 1940-07-27 | Recording medium made of electrically conductive paper for radio broadcasting purposes u. Like. And method for its preparation |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US2374214A (en) |
| BE (1) | BE460345A (en) |
| DE (1) | DE902111C (en) |
| FR (1) | FR889820A (en) |
| GB (1) | GB537770A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2993816A (en) * | 1960-03-30 | 1961-07-25 | Du Pont | Conducting textryls |
| US3022213A (en) * | 1958-02-13 | 1962-02-20 | Michigan Res Lab Inc | Conductive web and method of making same |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2654170A (en) * | 1949-01-17 | 1953-10-06 | Minnesota Mining & Mfg | Disintegrable label and washable container labeled therewith |
| US2662803A (en) * | 1949-06-29 | 1953-12-15 | Faximile Inc | Recording method and apparatus |
| US2726179A (en) * | 1952-01-07 | 1955-12-06 | Bosch Gmbh Robert | Recording tapes having a metal layer applied by vapour deposition |
| US2870689A (en) * | 1952-12-04 | 1959-01-27 | Helen E Brennan | Method of producing strip material |
| US3062700A (en) * | 1960-02-11 | 1962-11-06 | Harold R Dalton | Static discharging paper |
| US3132989A (en) * | 1961-02-27 | 1964-05-12 | Carrier Corp | Thermally conductive paper containing dendritic metal particles |
| DE1242020B (en) * | 1962-08-09 | 1967-06-08 | Olympia Werke Ag | Device for punching recording media by means of spark discharge |
| US3493369A (en) * | 1964-04-03 | 1970-02-03 | Appleton Coated Paper Co | Low electrical resistance varnish coatings on an insulating base |
| US3874995A (en) * | 1971-03-30 | 1975-04-01 | Us Army | Method of making aluminized paper |
| JPS58397B2 (en) * | 1976-02-19 | 1983-01-06 | 京セラミタ株式会社 | energized recorder |
| CA1141528A (en) * | 1978-08-04 | 1983-02-22 | Western Electric Company, Incorporated | Conductive adhesive system including a conductivity enhancer |
| US4806410A (en) * | 1986-09-18 | 1989-02-21 | Ranpak Corp. | Processes for the production of antistatic or static dissipative paper, and the paper products thus produced, and apparatus utilized |
| US8697934B2 (en) * | 2007-07-31 | 2014-04-15 | Kimberly-Clark Worldwide, Inc. | Sensor products using conductive webs |
| US8058194B2 (en) * | 2007-07-31 | 2011-11-15 | Kimberly-Clark Worldwide, Inc. | Conductive webs |
| WO2012081991A1 (en) * | 2010-12-15 | 2012-06-21 | Condalign As | Method for forming an anisotropic conductive paper and a paper thus formed |
| US20240300231A1 (en) * | 2021-02-10 | 2024-09-12 | Illinois Tool Works Inc. | Sheet assembly for forming one or more cards |
-
0
- BE BE460345D patent/BE460345A/xx unknown
-
1939
- 1939-07-27 US US286804A patent/US2374214A/en not_active Expired - Lifetime
-
1940
- 1940-07-12 GB GB11634/40A patent/GB537770A/en not_active Expired
- 1940-07-27 DE DEI3198D patent/DE902111C/en not_active Expired
-
1941
- 1941-03-22 FR FR889820D patent/FR889820A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3022213A (en) * | 1958-02-13 | 1962-02-20 | Michigan Res Lab Inc | Conductive web and method of making same |
| US2993816A (en) * | 1960-03-30 | 1961-07-25 | Du Pont | Conducting textryls |
Also Published As
| Publication number | Publication date |
|---|---|
| GB537770A (en) | 1941-07-04 |
| FR889820A (en) | 1944-01-20 |
| US2374214A (en) | 1945-04-24 |
| BE460345A (en) |
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