DE908917C - Plasticizers - Google Patents
PlasticizersInfo
- Publication number
- DE908917C DE908917C DEB6210D DEB0006210D DE908917C DE 908917 C DE908917 C DE 908917C DE B6210 D DEB6210 D DE B6210D DE B0006210 D DEB0006210 D DE B0006210D DE 908917 C DE908917 C DE 908917C
- Authority
- DE
- Germany
- Prior art keywords
- parts
- plasticizers
- esters
- fatty alcohols
- branched fatty
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004014 plasticizer Substances 0.000 title claims description 5
- 150000002148 esters Chemical class 0.000 claims description 7
- 150000002191 fatty alcohols Chemical class 0.000 claims description 4
- 239000002861 polymer material Substances 0.000 claims description 3
- 239000004952 Polyamide Substances 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000000020 Nitrocellulose Substances 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- YEYKMVJDLWJFOA-UHFFFAOYSA-N 2-propoxyethanol Chemical compound CCCOCCO YEYKMVJDLWJFOA-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical class CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 1
- 229940081735 acetylcellulose Drugs 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002301 cellulose acetate Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000002649 leather substitute Substances 0.000 description 1
- -1 m-cresolpropionic acid Chemical compound 0.000 description 1
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920001290 polyvinyl ester Polymers 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002554 vinyl polymer Chemical class 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
Das Patent 905 884 betrifft unter anderem die Verwendung von Estern aus verzweigten Fettalkoholen und aromatischen Oxysäuren als Weichmacher für Polyamide.Patent 905,884 relates, among other things, to the use of esters from branched fatty alcohols and aromatic oxyacids as plasticizers for polyamides.
Es wurde nun gefunden, daß diese Ester sich auch sehr gut als Weichmachungsmittel für andere hochpolymere Stoffe verwenden lassen, wobei neben einer guten weichmachenden Wirkung eine ausgezeichnete Beständigkeit gegen die Einwirkung von Wasser, gegen künstliche und natürliche Alterung sowie eine erhebliche Verbesserung der Kältebeständigkeit erzielt wird. Als hochpolymere Stoffe, denen die genannten Ester zugesetzt werden können, seien Cellulosederivate, wie Nitrocellulose und Acetylcellulose, Polyvinylverbindungen, wie Polyvinyläther und -ester, Polyisobutylen und Butadienpolymerisate, sowie Polyurethane genannt. Die Weichmacher können in der sonst üblichen Weise in die hochpolymeren Stoffe eingearbeitet werden, z. B. über die Lösung, Schmelze oder Dispersion, durch Mischen auf dem Mischwalzwerk, in Knetmaschinen u. dgl.It has now been found that these esters also work very well as plasticizers for others High polymer materials can be used, with a good softening effect and an excellent one Resistance to the action of water, to artificial and natural aging, as well as a significant improvement in Cold resistance is achieved. As high polymer substances to which the named esters are added can be cellulose derivatives such as nitrocellulose and acetyl cellulose, polyvinyl compounds such as Polyvinyl ethers and esters, polyisobutylene and butadiene polymers, and also polyurethanes mentioned. The plasticizers can be incorporated into the high-polymer materials in the otherwise customary manner be e.g. B. via the solution, melt or dispersion, by mixing on the mixing mill, in kneading machines and the like.
Zu 500 Teilen einer 5o°/oigen wäßrigen Polyvinylacetatdispersion werden 200 Teile des Esters aus200 parts of the ester are extracted from 500 parts of a 50% aqueous polyvinyl acetate dispersion
p-Oxybenzoesäure und einem Gemisch von überwiegend verzweigten Fettalkoholen mit 8 bis Ii Kohlenstoffatomen, die durch Anlagerung von Kohlenoxyd und Wasserstoff unter Einwirkung von Katalysatoren an Olefine und nachherige Hydrierung gewonnen wurden, unter schnellem Rühren zugefügt. Nach 24stündigem Stehen wird die Dispersion auf eine Glasplatte in dünner Schicht gegossen und bei 6o° getrocknet. Es wird ein weicher, klarer Film erhalten, der sich durch gute Beständigkeit gegen Alterung, Kälte und Wasser auszeichnet.p-oxybenzoic acid and a mixture of predominantly branched fatty alcohols with 8 to Ii carbon atoms, which are formed by the addition of Carbon dioxide and hydrogen with the action of catalysts on olefins and subsequent hydrogenation were obtained, added with rapid stirring. After standing for 24 hours, the dispersion becomes poured on a glass plate in a thin layer and dried at 60 °. It will be a soft one Obtain a clear film, which is characterized by good resistance to aging, cold and water.
B ei sp i e1 2For example, 1 2
Eine homogene Lösung von 20 Teilen spritlöslicher Nitrocellulose, 10 Teilen Butanol, 10 Teilen Äthylacetat, 50 Teilen Butylacetat, 10 Teilen Äthylenglykolmonopropyläther und 20 Teilen des Esters aus einem Gemisch von überwiegend verzweigten Fettalkoholen mit 6 bis 11 Kohlenstoffatomen und m-Kresolpropionsäure, die 5 Teile Eisenoxydbraun enthält, wird achtmal auf ein Gewebe gestrichen, wobei nach jedem Aufstrich bei etwa yo° getrocknet wird. Man erhält nach Prägung ein geschmeidiges Kunstleder.A homogeneous solution of 20 parts of fuel-soluble nitrocellulose, 10 parts of butanol, 10 parts of ethyl acetate, 50 parts of butyl acetate, 10 parts of ethylene glycol monopropyl ether and 20 parts of the ester from a mixture of predominantly branched fatty alcohols with 6 to 11 carbon atoms and m-cresolpropionic acid, the 5 parts of iron oxide brown is spread eight times on a fabric, drying at about yo ° after each spread. A supple synthetic leather is obtained after embossing.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB6210D DE908917C (en) | 1942-12-16 | 1943-07-21 | Plasticizers |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB5997D DE905884C (en) | 1942-12-16 | 1942-12-16 | Plasticizers for super polyamides |
| DEB6210D DE908917C (en) | 1942-12-16 | 1943-07-21 | Plasticizers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE908917C true DE908917C (en) | 1954-04-12 |
Family
ID=25964840
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEB6210D Expired DE908917C (en) | 1942-12-16 | 1943-07-21 | Plasticizers |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE908917C (en) |
-
1943
- 1943-07-21 DE DEB6210D patent/DE908917C/en not_active Expired
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