DE905967C - Process for matting textiles - Google Patents
Process for matting textilesInfo
- Publication number
- DE905967C DE905967C DEC1376D DEC0001376D DE905967C DE 905967 C DE905967 C DE 905967C DE C1376 D DEC1376 D DE C1376D DE C0001376 D DEC0001376 D DE C0001376D DE 905967 C DE905967 C DE 905967C
- Authority
- DE
- Germany
- Prior art keywords
- matting
- aluminum
- textiles
- pigments
- salts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004753 textile Substances 0.000 title claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000008346 aqueous phase Substances 0.000 claims description 3
- 239000007900 aqueous suspension Substances 0.000 claims description 3
- 150000001768 cations Chemical class 0.000 claims description 2
- 239000000084 colloidal system Substances 0.000 claims description 2
- 239000001023 inorganic pigment Substances 0.000 claims description 2
- 230000001681 protective effect Effects 0.000 claims description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 10
- 239000000049 pigment Substances 0.000 description 10
- 235000010215 titanium dioxide Nutrition 0.000 description 6
- 239000000835 fiber Substances 0.000 description 4
- 239000004408 titanium dioxide Substances 0.000 description 4
- MJWPFSQVORELDX-UHFFFAOYSA-K aluminium formate Chemical compound [Al+3].[O-]C=O.[O-]C=O.[O-]C=O MJWPFSQVORELDX-UHFFFAOYSA-K 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- -1 aluminum ions Chemical class 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 150000003754 zirconium Chemical class 0.000 description 2
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229920002955 Art silk Polymers 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000001665 trituration Methods 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/57—Sulfates or thiosulfates of elements of Groups 3 or 13 of the Periodic Table, e.g. alums
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Coloring (AREA)
Description
Es wurde gefunden, daß wäßrige Suspensionen feinverteilter anorganischer Pigmente, deren wäßrige Phase aus einer Lösung von Aluminiumsalzen, die das Aluminium als Kation enthalten, besteht, zum Mattieren der Textilien mit Erfolg verwendet werden können. Solche Suspensionen können als Bäder dienen, aus welchen die Pigmente eine unerwartete Affinität zur Faser haben. Die Mattierung kann in der Weise vorgenommen werden, daß die PigmenteIt has been found that aqueous suspensions of finely divided inorganic pigments, their aqueous Phase consists of a solution of aluminum salts, which contain the aluminum as a cation, for Matting the textiles can be used with success. Such suspensions can be used as baths serve, from which the pigments have an unexpected affinity for the fiber. The matting can be done in the way that the pigments are made
ίο zum Aufziehen auf das Textilmaterial (z. B. Kunstseiden aus regenerierter Cellulose oder Celluloseäthern und -estern, mercerisierter Baumwolle, Naturseide usw.) gebracht werden, was zweckmäßig durch einfaches Umziehen des Mattierungsgutes in verdünnten Mattierungsbädern geschieht. Man kann auch derart arbeiten, daß die Textilien mit konzentrierten Suspensionen kurze Zeit behandelt und hierauf getrocknet werden. Die so erhältlichen Mattierungseffekte stäuben überraschenderweise nicht und können der Wäsche recht gut widerstehen. Die auf diese Art auf der Faser fixierten Pigmente verbessern ganz wesentlich die Schiebefestigkeit von ansonst schiebenden Geweben.ίο to pull onto the textile material (e.g. artificial silk made from regenerated cellulose or cellulose ethers and esters, mercerized cotton, natural silk etc.), which is expedient by simply moving the matting material in diluted Matting baths happen. You can also work in such a way that the textiles are concentrated Suspensions are treated for a short time and then dried. The matting effects thus obtainable surprisingly do not dust and can withstand laundry quite well. The on This type of pigment fixed on the fiber significantly improves the slip resistance of otherwise pushing tissues.
Als Pigmente kommen in Betracht Titandioxyd, Bariumsulfat, Kaolin, Antimonoxyd, Lithopon, usw., ferner auch gefärbte Pigmente, wie z. B. Eisenoxyd, Cadmiumsulfid usw.The pigments are titanium dioxide, barium sulfate, kaolin, antimony oxide, lithopon, etc., also colored pigments, such as. B. iron oxide, cadmium sulfide, etc.
Die Verwendung von wäßrigen Suspensionen von Pigmenten, deren wäßrige Phase aus Lösungen von Zirkonsalzen besteht, ist bereits zum Mattieren von Textilien empfohlen worden. Zirkonsalze unterscheiden sich bekanntlich aber von anderen Salzen durch eigenartige Affinitätsiverhältnisse zur Cellulosefaser. Aus dem Verhalten des Zirkons war deshalb nicht vorauszusehen, daß die wohlfeilen Aluminiumsalze die Eigenschaft haben würden, in gleicher Weise dasThe use of aqueous suspensions of pigments, the aqueous phase of which consists of solutions of Zirconium salts has already been recommended for matting textiles. Differentiate between zirconium salts It is well known, however, that it differs from other salts through peculiar affinity relationships with cellulose fibers. From the behavior of the zircon, therefore, it could not be foreseen that the cheap aluminum salts would have the property in the same way that
Ziehen der Pigmente; auf der Faser zu fördern. Dies ist um SO' überraschender, als ansonst vergleichbare Salze anderer Metalle, z. B. Magnesium oder Calcium, diese Eigenschaft nicht oder nur in untergeordnetem Maße zeigen.Pulling the pigments; to promote on the fiber. This is SO 'more surprising than otherwise comparable Salts of other metals, e.g. B. Magnesium or calcium, this property not or only to a minor extent Dimensions show.
Es ist ferner bekannt, die Pigmentteilchen durch auf der Faser erzeugte wasserunlösliche Aluminiumseife aufzukleben.It is also known to remove the pigment particles from water-insoluble aluminum soap produced on the fiber stick on.
Die Erfindung beruht im Gegensatz hierzu darauf, ίο daß durch die Aluminiumionen die Pigmentteilchen derart beeinflußt werden, daß sie Substantiven Charakter und somit eine Affinität der Cellulosefaser erhalten. Diese Beeinflussung wird wahrscheinlich durch die elektrische Ladung der Aluminiumionen bewirkt. Die Erfindung beruht also auf einer eigenartigen Erzeugung und Erhöhung des Ziehvermögens der Pigmentteilchen.In contrast to this, the invention is based on the fact that the pigment particles are formed by the aluminum ions are influenced in such a way that they have noun character and thus an affinity of the cellulose fiber obtain. This influence is likely due to the electrical charge of the aluminum ions causes. The invention is therefore based on a peculiar production and increase of the drawability the pigment particles.
10 Teile Titandioxyd (Titanweiß des Handels) und ι Teil Aluminiumformiat werden mit wenig Wasser angepastet; die so erhaltene Paste gießt man unter Umrühren in 15000 Teile Wasser von 20°. In das so bereitete Mattiierungsbad geht man mit 50O' Teilen Viskosekunstseide ein und hantiert bei gewöhnlicher Temperatur während Va Stunde. Hierauf wird gespült und getrocknet. Man erhält eine starke, nicht stäubende Mattierung, die der Wäsche recht gut widersteht. Ähnliche Effekte erzielt man, wenn das Aluminiumtrifocmiat durch Aluminiumsulfat ersetzt wird.10 parts titanium dioxide (commercial titanium white) and ι part of aluminum formate are made into a paste with a little water; the paste thus obtained is poured with stirring in 15,000 parts of water at 20 °. You go into the matting bath prepared in this way 50O 'Divide viscose rayon and handle with ordinary Temperature for Va hour. This is followed by rinsing and drying. You get a strong, non-dusting matt finish that withstands laundry quite well. Similar effects can be achieved if the aluminum trifocmate is replaced by aluminum sulfate will.
Liegt ein Titandioxyd von gröberer Beschaffenheit vor, so· kann es sich empfehlen, dem Mattierungsbad geringe Mengen, z. B. iofl/o des verwendeten Aluminiumformiates, eines geeigneten Schutzkolloides, wie Leim oder Johannisbrotkernmehl, zuzugeben. If the titanium dioxide is coarser, it may be advisable to add small amounts to the matting bath, e.g. B. io fl / o of the aluminum formate used, a suitable protective colloid such as glue or locust bean gum to add.
Viskosekunstseidengewebe wird auf dem Foulard in einer Mattierungsflotte bei gewöhnlicher Temperatur foulardiert, welche pro Liter 20 g einer Suspension enthält, die hergestellt worden ist durch Verreiben von 10 Teilen Titandioxyd (in Form von Titanweiß), ι Teil Aluminiumtriformiat mit 10 Teilen Wasser. Man erhält nach dem Abquetschen und Trocknen einen starken gleichmäßigen Matteffekt.Viscose rayon fabric is placed on the padder in a matting liquor at normal temperature padded, which contains per liter 20 g of a suspension which has been prepared by trituration of 10 parts of titanium dioxide (in the form of titanium white), ι part of aluminum triformate with 10 parts Water. After squeezing and drying, a strong, even matt effect is obtained.
Claims (1)
FranzösischePatentschriftenNr. 841 316, 739214; •deutsche Patentschrift Nr. 679 465;
Chemisches Zentralblatt, 1939, II, S. 3764.Referred publications:
French Patent No. 841 316, 739214; • German patent specification No. 679 465;
Chemisches Zentralblatt, 1939, II, p. 3764.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH549138X | 1939-08-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE905967C true DE905967C (en) | 1954-03-08 |
Family
ID=4519518
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEC1376D Expired DE905967C (en) | 1939-08-19 | 1940-08-02 | Process for matting textiles |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US2309964A (en) |
| DE (1) | DE905967C (en) |
| FR (1) | FR872222A (en) |
| GB (1) | GB549138A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3443327C1 (en) * | 1984-11-28 | 1985-09-05 | Rosorius, Gerhard, 2085 Quickborn | Process for improving the properties of textiles consisting of or containing native vegetable or animal fibers |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4283452A (en) * | 1979-09-06 | 1981-08-11 | Milliken Research Corporation | Polyester textile material having improved opacity |
| US4420507A (en) * | 1980-03-10 | 1983-12-13 | Milliken Research Corporation | Process for improving opacity of polyester textile materials |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR739214A (en) * | 1931-12-17 | 1933-01-06 | Erba A G Fabrik Chemischer Pro | Process for treating textiles and the like |
| DE679465C (en) * | 1933-10-10 | 1939-08-05 | Stockhausen & Cie Chem Fab | Process for matting rayon |
-
1940
- 1940-08-02 DE DEC1376D patent/DE905967C/en not_active Expired
- 1940-08-17 US US353149A patent/US2309964A/en not_active Expired - Lifetime
- 1940-09-11 GB GB14090/40A patent/GB549138A/en not_active Expired
- 1940-09-23 FR FR872222D patent/FR872222A/en not_active Expired
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR739214A (en) * | 1931-12-17 | 1933-01-06 | Erba A G Fabrik Chemischer Pro | Process for treating textiles and the like |
| DE679465C (en) * | 1933-10-10 | 1939-08-05 | Stockhausen & Cie Chem Fab | Process for matting rayon |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3443327C1 (en) * | 1984-11-28 | 1985-09-05 | Rosorius, Gerhard, 2085 Quickborn | Process for improving the properties of textiles consisting of or containing native vegetable or animal fibers |
| US4773912A (en) * | 1984-11-28 | 1988-09-27 | Heidelinde Nordmann | Process for increasing the performance of pleated silk or wool by treatment with keratolytic liquor and impregnating with glazing powder and heating |
Also Published As
| Publication number | Publication date |
|---|---|
| US2309964A (en) | 1943-02-02 |
| GB549138A (en) | 1942-11-09 |
| FR872222A (en) | 1942-06-02 |
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