DE855700C - Process for the production of chlorine dioxide - Google Patents
Process for the production of chlorine dioxideInfo
- Publication number
- DE855700C DE855700C DEK7577A DEK0007577A DE855700C DE 855700 C DE855700 C DE 855700C DE K7577 A DEK7577 A DE K7577A DE K0007577 A DEK0007577 A DE K0007577A DE 855700 C DE855700 C DE 855700C
- Authority
- DE
- Germany
- Prior art keywords
- production
- sodium chlorite
- chlorine dioxide
- water
- chlorine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title claims description 12
- 238000000034 method Methods 0.000 title claims description 7
- 239000004155 Chlorine dioxide Substances 0.000 title claims description 6
- 235000019398 chlorine dioxide Nutrition 0.000 title claims description 6
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 claims description 9
- 229960002218 sodium chlorite Drugs 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/023—Preparation from chlorites or chlorates
- C01B11/024—Preparation from chlorites or chlorates from chlorites
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
Bei der Herstellung von; Chlordioxyd ist man bisfer davon ausgegangen, Natriumc'hlorat mit Schwefelsäure oder Oxalsäure zu 'behandeln und durch ein inertes Gas das Chlordioxyd aus diesem Gemisch auszutreiben. Bei'-diesem Verfahren entsteht jedoch explosives Chlordioxyd und die damit ' verbundenen Nachteile haben dazu geführt, daß man in folgender Weise .gearbeitet hat: Natriumchlorit (NaC10Q) wird mit einer Mischung behandelt, die aus Natriumhypochlorit und Schwefelsäure hergestellt ist. Wenn man dieses Verfahren zugrunde legt, so ist man jedoch an drei Komponenten gebunden.In the production of; Chlorine dioxide has until now been assumed Sodium chlorate to be treated with sulfuric acid or oxalic acid and replaced by an inert Gas to expel the chlorine dioxide from this mixture. In this process arises however, explosive chlorine dioxide and the disadvantages associated with it have led to that one has worked in the following way: Sodium chlorite (NaC10Q) is mixed with a Treated mixture made from sodium hypochlorite and sulfuric acid. Using this procedure as a basis, however, is tied to three components.
Der Herstellung der Chlordioxydlösung@ aus Natriumchlorit und Chlorwasser hat nach den bisherigen Ergebnissen eine komplizierte Apparatur erfordert, einen Reaktionsturm mit Füllringen und zeitlich genaue Einhaltung von Temperatur und Konzentrationsbedingungen.The production of the chlorine dioxide solution @ from sodium chlorite and chlorine water has required a complicated apparatus according to the results so far, a Reaction tower with filling rings and precise adherence to temperature and concentration conditions.
>Überraschenderweise ist festgestellt worden, daß bei der Vermischung von Natriumchlorit und Chlorwasser die Herstellung des Ohlordioxyds in einfachster Weise dadurch gelingt, daß man die beiden Stoffe in wäßriger Lösung mittels einer besonderen Mischeinrichtung direkt in Berührung bringt.- Diese Mischeinrichtung besteht in einem Mischglas mit Injektor, in welches im Gegenstrom zum Chlor die Natriumchloritlösung eingepumpt wird (siehe-hierzu Beispiel i in der Zeichnung).> Surprisingly, it has been found that when mixed From sodium chlorite and chlorinated water, the production of carbon dioxide in the simplest possible way Way succeeds in that one of the two substances in aqueous solution by means of a brings special mixing device into direct contact - this mixing device consists of a mixing glass with an injector in which the Sodium chlorite solution is pumped in (see example i in the drawing).
Der Verfahren geht davon aus, daß man Chlor aus einer Flasche a durch eine Meßvorrichtung b zum Mischglas c strömen läßt. Im Mischglas c befindet sich die Mischvorrichtung d, die durch die Wasserarmatur e mit Wasser versorgt wird. Per Mischvorrichtung strömt weiter über die Dosierpumpe g das im Vorratsbehälter aufgespeicherte Natriumchlorit als-Lösung zu.The method assumes that you get chlorine from a bottle a through allows a measuring device b to flow to the mixing glass c. In the mixing glass c is located the mixing device d, which is supplied with water by the water fitting e. The mixing device continues to flow through the metering pump g in the storage container stored sodium chlorite as a solution too.
Auch läBt sich die Vermischung beider Stoffe in einem Injektor durchführen, den man mit Chlorwasser zu betreiben hat (siehe hierzu Beispiel 2 a und 2b in der Zeichnung).The two substances can also be mixed in one injector, which one has to operate with chlorinated water (see example 2 a and 2b in the Drawing).
Diese Ausführungsform benutzt einen Vorratsbehälter f für das N atriumchlorit, das einem Behälter h mit Schwimmer zuläuft, um ein konstantes Niveau zu erreichen. Die Einstellung erfolgt mit einem Ventil und ist ablesbar an der Meßvorrichtung i. Die abgemessene Natriumchloritlösung läuft direkt dem Injektor k zu, der mit Chlorwasser von bestimmter Konzentration versorgt wird.This embodiment uses a storage container f for the sodium chlorite, which runs towards a container h with a float in order to achieve a constant level. The setting is made with a valve and can be read on the measuring device i. The measured sodium chlorite solution runs directly to the injector k, which is with Chlorinated water of a certain concentration is supplied.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEK7577A DE855700C (en) | 1950-10-05 | 1950-10-05 | Process for the production of chlorine dioxide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEK7577A DE855700C (en) | 1950-10-05 | 1950-10-05 | Process for the production of chlorine dioxide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE855700C true DE855700C (en) | 1952-11-17 |
Family
ID=7211598
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEK7577A Expired DE855700C (en) | 1950-10-05 | 1950-10-05 | Process for the production of chlorine dioxide |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE855700C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4247531A (en) * | 1979-08-13 | 1981-01-27 | Rio Linda Chemical | Chlorine dioxide generation apparatus and process |
| US4250144A (en) * | 1979-06-14 | 1981-02-10 | Fischer & Porter Company | Chlorine dioxide generating system |
-
1950
- 1950-10-05 DE DEK7577A patent/DE855700C/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4250144A (en) * | 1979-06-14 | 1981-02-10 | Fischer & Porter Company | Chlorine dioxide generating system |
| US4247531A (en) * | 1979-08-13 | 1981-01-27 | Rio Linda Chemical | Chlorine dioxide generation apparatus and process |
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