DE818326C - Process for the production of swellable clays - Google Patents
Process for the production of swellable claysInfo
- Publication number
- DE818326C DE818326C DEA3474A DEA0003474A DE818326C DE 818326 C DE818326 C DE 818326C DE A3474 A DEA3474 A DE A3474A DE A0003474 A DEA0003474 A DE A0003474A DE 818326 C DE818326 C DE 818326C
- Authority
- DE
- Germany
- Prior art keywords
- clays
- production
- swellable clays
- clay
- swellable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 7
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000000443 aerosol Substances 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims 1
- 239000011707 mineral Substances 0.000 claims 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims 1
- 239000004927 clay Substances 0.000 description 7
- 235000012216 bentonite Nutrition 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/131—Inorganic additives
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Description
Verfahren zur Herstellung von quellfähigen Tonen Bekanntlich kommen in der Natur Tone vor, die die Eigenschaft haben, verhältnismäßig große Mengen von Wasser aufnehmen zu können, ohne daß sie in den flüssigen Zustand übergehen, vielmehr zu einer gallertartigen '.Masse erstarren, was auf der besonderen Quellfähigkeit solcher Tone beruht. Solche unter dem Namen Bentonite bekannten quellfähigen Tone kommen aber nur an vereinzelten Stellen der Erde vor, während andererseits der Bedarf an solchen Tonen für die verschiedensten Zwecke, z. B. die Erzeugung von Porzellan und anderen keramischen Gegenständen, für Gießereizwecke, in der kosmetischen und der Nahrungsmittelindustrie sehr groß ist.Process for the production of swellable clays is known to come in nature clays that have the property of relatively large amounts of To be able to absorb water without them going into the liquid state, rather solidify into a gelatinous mass, which is due to the special swelling capacity such tone is based. Such swellable clays known under the name bentonite but only occur in isolated places on earth, while on the other hand the need on such clays for various purposes, e.g. B. the production of porcelain and other ceramic objects, for foundry purposes, in cosmetic and the food industry is huge.
Es fehlte deshalb nicht an Versuchen, solche quellfähigen Tone durch Aufbereitung weniger quellfähiger Tone, z. B. durch Feinstmahlung, Trocknung unter besonderen Bedingungen, oder durch Behandlung mit Säuren und Alkalien, die nacher wieder entfernt werden sollten, oder auch durch Zusätze von anorganischen oder organischen Reagentien der verschiedensten Art, z. B. Soda, Phosphate u. dgl., künstlich herzustellen. Mit a11 diesen Mitteln lassen sich jedoch nur wenig befriedigende Ergebnisse erzielen. Der besondere Nachteil dieser Methoden besteht aber darin, daß durch die Verwendung tonfremder Substanzen eine Verunreinigung der natürlichen Tone vorgenommen wird, die sich, wie sich gezeigt hat, nicht mehr restlos entfernen läßt, so daß der Verwendung derart hergestellter künstlicher Bentonite, z. B. in der Kosmetik und der Nahrungsmittelindustrie, Grenzen gezogen sind oder zumindest ihre Verwendung in vielen Fällen bedenklich erscheint. Das neue Verfahren nach der vorliegenden Erfindung geht deshalb von dem Gedanken aus, als Zusatzstoffe zu natürlichem gewöhnlichen Ton nur arteigene Zusatzstoffe zu verwenden, wie sie im Ton bereits enthalten sind, diese aber in einer Form, wie sie eine besonders gute Quellfähigkeit von Tonen bedingen. Ausgedehnte Versuche haben nun ergeben, daß reine Kieselsäure in feinster Aufteilung, wie sie als Ärosol hergestellt werden kann, in geeigneter Menge natürlichem Ton zugesetzt, ganz vorzügliche Ergebnisse hinsichtlich der Quellfähigkeit ergibt.There was therefore no lack of attempts to produce such swellable clays Processing of less swellable clays, e.g. B. by fine grinding, drying under special conditions, or by treatment with acids and alkalis, the later should be removed again, or by adding inorganic or organic Reagents of various kinds, e.g. B. Soda, phosphates and the like. To produce artificially. With a11 these means, however, only unsatisfactory results can be achieved. The particular disadvantage of these methods is that by using non-clay substances contaminate the natural clays, which, as has been shown, can no longer be completely removed, so that the use artificial bentonites produced in this way, e.g. B. in cosmetics and the food industry, Limits are drawn or at least their use in many cases questionable appears. The new method of the present invention works therefore from the thought of being additives to natural ordinary clay only to use native additives, as they are already contained in the clay, these but in a form that requires clays to swell particularly well. Extensive experiments have now shown that pure silica in the finest division, as it can be produced as aerosol, in a suitable amount of natural clay added, gives excellent results in terms of swellability.
Das Verfahren ist auch außerordentlich wirtschaftlich, da keine chemische Aufbereitung und Reinigung der Tone notwendig ist, sondern die getrockneten und gemahlenen Tone ohne weiteres mit der beizugebenden Kieselsäure vermischt werden können. Die Versuche haben ergeben, daß dabei die geringen Zusätze von 0,5 bis ro °/o an Kieselsäuren, bezogen auf das Tongewicht, in allen Fällen genügen, gleichgültig welcher Herkunft der dabei verwendete natürliche Ton ist.The process is also extremely economical because it is not chemical Preparation and cleaning of the clays is necessary, but the dried and ground clays are easily mixed with the silica to be added can. The tests have shown that the small additions of 0.5 to ro ° / o of silicas, based on the weight of the clay, are sufficient in all cases, indifferent the origin of the natural clay used.
Da Kieselsäure auch im natürlichen Ton enthalten ist, treten bei der Verwendung solcher künstlich hergestellter Betonite keinerlei Nachteile auf.Since silica is also contained in natural clay, the Use of such artificially produced bentonite does not have any disadvantages.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEA3474A DE818326C (en) | 1950-09-12 | 1950-09-12 | Process for the production of swellable clays |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEA3474A DE818326C (en) | 1950-09-12 | 1950-09-12 | Process for the production of swellable clays |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE818326C true DE818326C (en) | 1951-10-25 |
Family
ID=6920251
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEA3474A Expired DE818326C (en) | 1950-09-12 | 1950-09-12 | Process for the production of swellable clays |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE818326C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2325618A1 (en) * | 1975-09-25 | 1977-04-22 | Jaklin Hans | PROCESS FOR IMPROVING THE RESISTANCE OF POTTERY ARTICLES TO COMPRESSION |
-
1950
- 1950-09-12 DE DEA3474A patent/DE818326C/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2325618A1 (en) * | 1975-09-25 | 1977-04-22 | Jaklin Hans | PROCESS FOR IMPROVING THE RESISTANCE OF POTTERY ARTICLES TO COMPRESSION |
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