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DE69206694D1 - Katalysatorbestandteile für Olefinpolymerisation - Google Patents

Katalysatorbestandteile für Olefinpolymerisation

Info

Publication number
DE69206694D1
DE69206694D1 DE69206694T DE69206694T DE69206694D1 DE 69206694 D1 DE69206694 D1 DE 69206694D1 DE 69206694 T DE69206694 T DE 69206694T DE 69206694 T DE69206694 T DE 69206694T DE 69206694 D1 DE69206694 D1 DE 69206694D1
Authority
DE
Germany
Prior art keywords
olefin polymerization
catalyst components
catalyst
components
olefin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69206694T
Other languages
English (en)
Other versions
DE69206694T2 (de
Inventor
Yoshio Tajima
Naoki Katoaka
Yosuke Numao
Takashi Seki
Kazuo Matsuura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Japan Polyolefins Co Ltd
Original Assignee
Nippon Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Oil Corp filed Critical Nippon Oil Corp
Publication of DE69206694D1 publication Critical patent/DE69206694D1/de
Application granted granted Critical
Publication of DE69206694T2 publication Critical patent/DE69206694T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/903—Monomer polymerized in presence of transition metal containing catalyst and hydrocarbon additive affecting polymer properties of catalyst activity

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69206694T 1991-06-27 1992-06-26 Katalysatorbestandteile für Olefinpolymerisation Expired - Fee Related DE69206694T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP18327291 1991-06-27
JP27667391 1991-09-27

Publications (2)

Publication Number Publication Date
DE69206694D1 true DE69206694D1 (de) 1996-01-25
DE69206694T2 DE69206694T2 (de) 1996-07-04

Family

ID=26501786

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69206694T Expired - Fee Related DE69206694T2 (de) 1991-06-27 1992-06-26 Katalysatorbestandteile für Olefinpolymerisation

Country Status (4)

Country Link
US (3) US5451555A (de)
EP (1) EP0520816B1 (de)
CA (1) CA2072476C (de)
DE (1) DE69206694T2 (de)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0520811B1 (de) * 1991-06-27 1996-05-08 Nippon Oil Co. Ltd. Katalysatorbestandteil für die Olefinpolymerisation
CA2072476C (en) * 1991-06-27 2002-09-03 Yoshio Tajima Catalysts components for polymerization of olefins
US5331071A (en) * 1991-11-12 1994-07-19 Nippon Oil Co., Ltd. Catalyst components for polymerization of olefins
CA2089591C (en) * 1992-02-21 1997-06-03 Kenji Nakacho Polyolefin resin and method for the preparation thereof
US5910464A (en) * 1992-06-18 1999-06-08 Montell Technology Company Bv Catalysts for the polymerization of olefins
DK0575875T3 (da) * 1992-06-18 2000-09-18 Montell Technology Company Bv Katalysator til polymerisation af olefiner
JPH06220129A (ja) * 1993-01-20 1994-08-09 Nippon Oil Co Ltd 高強度・高弾性率ポリエチレン材料の製造方法
JP3344015B2 (ja) * 1993-08-23 2002-11-11 住友化学工業株式会社 エチレン−αオレフィン共重合体及び該共重合体から成形されてなる成形体
US5700895A (en) * 1993-08-23 1997-12-23 Sumitomo Chemical Company, Limited Ethylene-α-olefin copolymer and molded article thereof
JPH07173214A (ja) * 1993-10-27 1995-07-11 Nippon Oil Co Ltd オレフィン類重合用触媒成分
AU3894395A (en) * 1994-10-31 1996-05-23 W.R. Grace & Co.-Conn. Preparation of modified polyolefin catalysts and in situ preparation of supported metallocene and ziegler-natta/metallocene polyolefin catalysts
NO315857B1 (no) * 1995-03-28 2003-11-03 Japan Polyolefines Co Ltd Etylen-<alfa>-olefin-kopolymer, blanding, film, laminert material, elektrisk isolerende material og strömkabel inneholdende denne
US5750454A (en) * 1995-05-31 1998-05-12 Nippon Oil Co., Ltd. Catalyst composition and process for the production of olefinic polymers
US5644009A (en) * 1995-11-27 1997-07-01 Industrial Technology Research Institute Catalyst composition for preparing high syndiotacticity polystyrene from styrene of other arylethylene monomers and processes using the same
US6111040A (en) * 1996-05-30 2000-08-29 Nippon Mitsubishi Oil Corporation Process for the production of olefinic polymers
US6127309A (en) * 1996-09-19 2000-10-03 Nippon Oil Co., Ltd. Catalyst for use in the alkylation of isoalkanes
US5747406A (en) * 1997-01-10 1998-05-05 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for the production of olefin polymers
WO1999002569A1 (en) 1997-07-14 1999-01-21 The Board Of Trustees Of The Leland Stanford, Jr. University CATALYSTS AND PROCESSES FOR THE SYNTHESIS OF ALTERNATING ETHYLENE/α-OLEFIN COPOLYMERS, AND ISOTACTIC COPOLYMERS THEREOF
US6054405A (en) 1997-12-29 2000-04-25 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for the polymerization of olefins
EP0933383A1 (de) 1998-01-29 1999-08-04 Union Carbide Chemicals & Plastics Technology Corporation Katalysatorzusammensetzung für die Olefinpolymerisation
TW460485B (en) * 1998-06-19 2001-10-21 Japan Polyolefins Co Ltd Ethylene.Α-olefin copolymer, and combinations, films and use thereof
US6100212A (en) * 1998-06-30 2000-08-08 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for the polymerization of olefins
CA2322496A1 (en) * 1999-01-08 2000-07-13 Raisa L. Kravchenko Ethylene copolymers with narrow composition distribution and high melting temperatures, and methods of production thereof
US6420298B1 (en) 1999-08-31 2002-07-16 Exxonmobil Oil Corporation Metallocene catalyst compositions, processes for making polyolefin resins using such catalyst compositions, and products produced thereby

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL123957C (de) * 1961-06-29
US3300458A (en) * 1963-08-19 1967-01-24 Union Carbide Corp Continuous processes for the production of ethylene polymers and catalysts suitable therefor
DE1720785A1 (de) * 1968-02-17 1971-07-22 Hoechst Ag Verfahren zur Polymerisation von alpha-Olefinen
FR2013054A1 (de) * 1968-07-16 1970-03-27 Asahi Chemical Ind
IE40215B1 (en) * 1973-12-04 1979-04-11 Ici Ltd Olefine polymer, olefine polymerisation process and catalyst
US3939137A (en) * 1974-11-22 1976-02-17 Phillips Petroleum Company Silane adjuvant for chromium oxide catalyst
SU733718A1 (ru) * 1977-12-26 1980-05-15 Предприятие П/Я Р-6603 Способ приготовлени катализатора дл циклизации бутадиена -1,3
US4359561A (en) * 1979-06-18 1982-11-16 Union Carbide Corporation High tear strength polymers
DE3127133A1 (de) * 1981-07-09 1983-01-27 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von polyolefinen und deren copolymerisaten
JPS60115603A (ja) * 1983-11-29 1985-06-22 Toa Nenryo Kogyo Kk オレフインの重合方法
US4752597A (en) * 1985-12-12 1988-06-21 Exxon Chemical Patents Inc. New polymerization catalyst
US4874880A (en) * 1987-03-10 1989-10-17 Chisso Corporation Bis(di-, tri- or tetra-substituted-cyclopentadienyl)-zirconium dihalides
US4772734A (en) * 1987-03-16 1988-09-20 The Dow Chemical Company Tantalum catalysts for the dimerization of olefins
US4717783A (en) * 1987-03-16 1988-01-05 The Dow Chemical Company Tantalum catalysts for the dimerization of olefins
US4794096A (en) * 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
JP2546859B2 (ja) * 1987-10-08 1996-10-23 東燃株式会社 エチレン重合用触媒
US4910178A (en) * 1988-09-30 1990-03-20 Texas Alkyls, Inc. Olefin polymerization or copolymerization catalyst components
JP2893743B2 (ja) * 1989-08-10 1999-05-24 三菱化学株式会社 α―オレフイン重合体の製造
DE3942366A1 (de) * 1989-12-21 1991-06-27 Hoechst Ag Verfahren zur herstellung eines syndiotaktischen propylen-copolymers
US5007950A (en) * 1989-12-22 1991-04-16 Ppg Industries, Inc. Compressed, wedged float glass bottom structure
US5021382A (en) * 1990-02-28 1991-06-04 Exxon Chemical Patents Inc. Diene activated ziegler transition metal catalyst components for ethylene polymerization
CA2072476C (en) * 1991-06-27 2002-09-03 Yoshio Tajima Catalysts components for polymerization of olefins
EP0520811B1 (de) * 1991-06-27 1996-05-08 Nippon Oil Co. Ltd. Katalysatorbestandteil für die Olefinpolymerisation
US5331071A (en) * 1991-11-12 1994-07-19 Nippon Oil Co., Ltd. Catalyst components for polymerization of olefins
US5644009A (en) * 1995-11-27 1997-07-01 Industrial Technology Research Institute Catalyst composition for preparing high syndiotacticity polystyrene from styrene of other arylethylene monomers and processes using the same

Also Published As

Publication number Publication date
EP0520816A2 (de) 1992-12-30
US5451555A (en) 1995-09-19
EP0520816B1 (de) 1995-12-13
DE69206694T2 (de) 1996-07-04
CA2072476C (en) 2002-09-03
US5594082A (en) 1997-01-14
EP0520816A3 (en) 1993-02-03
CA2072476A1 (en) 1992-12-28
US5824618A (en) 1998-10-20

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8327 Change in the person/name/address of the patent owner

Owner name: JAPAN POLYOLEFINS CO. LTD., TOKIO/TOKYO, JP

8339 Ceased/non-payment of the annual fee