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DE69919425D1 - Silberkatalysator zur Herstellung von Ethylenoxid , Verfahren zu seiner Herstellung und Verfahren zur Herstellung von Ethylenoxid - Google Patents

Silberkatalysator zur Herstellung von Ethylenoxid , Verfahren zu seiner Herstellung und Verfahren zur Herstellung von Ethylenoxid

Info

Publication number
DE69919425D1
DE69919425D1 DE69919425T DE69919425T DE69919425D1 DE 69919425 D1 DE69919425 D1 DE 69919425D1 DE 69919425 T DE69919425 T DE 69919425T DE 69919425 T DE69919425 T DE 69919425T DE 69919425 D1 DE69919425 D1 DE 69919425D1
Authority
DE
Germany
Prior art keywords
production
ethylene oxide
silver catalyst
silver
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69919425T
Other languages
English (en)
Other versions
DE69919425T2 (de
Inventor
Hitoshi Takada
Masahide Shima
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Shokubai Co Ltd
Original Assignee
Nippon Shokubai Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Shokubai Co Ltd filed Critical Nippon Shokubai Co Ltd
Publication of DE69919425D1 publication Critical patent/DE69919425D1/de
Application granted granted Critical
Publication of DE69919425T2 publication Critical patent/DE69919425T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/657—Pore diameter larger than 1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
DE69919425T 1998-02-20 1999-02-17 Silberkatalysator zur Herstellung von Ethylenoxid , Verfahren zu seiner Herstellung und Verfahren zur Herstellung von Ethylenoxid Expired - Lifetime DE69919425T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP3832798 1998-02-20
JP3832798 1998-02-20

Publications (2)

Publication Number Publication Date
DE69919425D1 true DE69919425D1 (de) 2004-09-23
DE69919425T2 DE69919425T2 (de) 2005-09-08

Family

ID=12522199

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69919425T Expired - Lifetime DE69919425T2 (de) 1998-02-20 1999-02-17 Silberkatalysator zur Herstellung von Ethylenoxid , Verfahren zu seiner Herstellung und Verfahren zur Herstellung von Ethylenoxid

Country Status (3)

Country Link
US (1) US6103916A (de)
EP (1) EP0937498B1 (de)
DE (1) DE69919425T2 (de)

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US6455713B1 (en) * 1998-09-14 2002-09-24 Eastman Chemical Company Reactivation of Cs-promoted, Ag catalysts for the selective epoxidation of butadiene to 3,4-epoxy-1-butene
US7232786B2 (en) 1998-09-14 2007-06-19 Shell Oil Company Catalyst composition
US7504525B2 (en) 1998-09-14 2009-03-17 Shell Oil Company Catalyst composition
RU2225255C2 (ru) 1998-09-14 2004-03-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Носитель катализатора эпоксидирования, его получение и применение
US7232918B2 (en) 2001-11-06 2007-06-19 Shell Oil Company Catalyst composition
CA2343783C (en) * 1998-09-14 2008-02-12 Shell Internationale Research Maatschappij B.V. Process for removing ionizable species from catalyst surface to improve catalytic properties
CA2448322A1 (en) * 2001-03-30 2002-10-10 Shell Internationale Research Maatschappij B.V. Process for preparing a group viii-metal containing catalyst, use thereof for preparing an alkenyl carboxylate
US6831037B2 (en) * 2002-02-25 2004-12-14 Saint-Gobain Norpro Corporation Catalyst carriers
RU2342190C2 (ru) * 2002-02-25 2008-12-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Катализатор и способ его применения
US6987080B2 (en) * 2002-03-01 2006-01-17 Scientific Design Company, Inc. Ethylene oxide catalyst carrier preparation
JP4421201B2 (ja) 2002-03-27 2010-02-24 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 触媒を調製する方法、触媒、および触媒の使用
US6750173B2 (en) 2002-04-08 2004-06-15 Scientific Design Company, Inc. Ethylene oxide catalyst
US6858560B2 (en) 2003-04-23 2005-02-22 Scientific Design Co., Inc. Ethylene oxide catalyst
US6846774B2 (en) * 2003-04-23 2005-01-25 Scientific Design Co., Inc. Ethylene oxide catalyst
US20040225138A1 (en) 2003-05-07 2004-11-11 Mcallister Paul Michael Reactor system and process for the manufacture of ethylene oxide
AU2004238820B2 (en) 2003-05-07 2008-01-31 Shell Internationale Research Maatschappij B.V. Silver-containing catalysts, the manufacture of such silver containing catalysts, and the use thereof
US20040224841A1 (en) 2003-05-07 2004-11-11 Marek Matusz Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof
CN1838990A (zh) * 2003-08-22 2006-09-27 联合碳化化学及塑料技术公司 改性氧化铝载体和用于制造烯化氧的银基催化剂
CA2538992C (en) * 2003-08-22 2013-02-19 Union Carbide Chemicals & Plastics Technology Corporation Improved alumina carriers and silver-based catalysts for the production of alkylene oxides
TW200600190A (en) 2004-04-01 2006-01-01 Shell Int Research Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation
TW200602123A (en) * 2004-04-01 2006-01-16 Shell Int Research Process for preparing a catalyst, the catalyst, and a use of the catalyst
TW200613056A (en) * 2004-04-01 2006-05-01 Shell Int Research A process for preparing a silver catalyst, the catalyst, and a use of the catalyst for olefin oxidation
EP1807189A2 (de) 2004-09-24 2007-07-18 Shell Internationale Research Maatschappij B.V. Prozess zur auswahl geformter partikel, prozess zum installieren eines systems, prozess zur umsetzung eines gasförmigen ausgangsmaterials in einem solchen system, computerprogrammprodukt und computersystem
US7759284B2 (en) * 2005-05-09 2010-07-20 Scientific Design Company, Inc. Calcination in an inert gas in the presence of a small concentration of an oxidizing component
TW201109083A (en) * 2005-06-07 2011-03-16 Saint Gobain Ceramics & Plastics Inc A process for preparing a catalyst carrier
MX2007015271A (es) 2005-06-07 2008-02-22 Shell Int Research Catalizador, proceso para preparar el mismo, y proceso para producir oxido de olefina, 1,2-diol, 1,2-diol eter o una alcanolamina.
US8318627B2 (en) * 2005-08-10 2012-11-27 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Process for preparation of a catalyst carrier
US8008515B2 (en) * 2006-05-02 2011-08-30 Nippon Shokubai Co., Ltd. Catalyst for partial oxidation of olefin, preparation method thereof, and process for preparing alkylene oxide
US7977274B2 (en) * 2006-09-29 2011-07-12 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Catalyst with bimodal pore size distribution and the use thereof
EP2125202A2 (de) 2006-11-20 2009-12-02 Shell Internationale Research Maatschappij B.V. Verfahren zur behandlung eines trägers, verfahren zur herstellung eines katalysators, katalysator und verwendung des katalysators
DE102007028332A1 (de) 2007-06-15 2008-12-18 Basf Se Verfahren zum Beschicken eines Reaktors mit einem Katalysatorfestbett, das wenigstens ringförmige Katalysatorformkörper K umfasst
US8349765B2 (en) * 2008-07-18 2013-01-08 Scientific Design Company, Inc. Mullite-containing carrier for ethylene oxide catalysts
CN102463141B (zh) * 2010-11-02 2015-05-06 中国石油化工股份有限公司 一种氧化铝载体、其制备方法、由其制成的银催化剂及其应用
TWI632138B (zh) * 2013-05-16 2018-08-11 科學設計股份有限公司 具有降低鈉含量之建基於銀之環氧乙烷觸媒
TWI632954B (zh) 2013-05-16 2018-08-21 科學設計股份有限公司 改善環氧乙烷觸媒的催化效能之載體處理

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US2901441A (en) * 1953-01-28 1959-08-25 Publicker Ind Inc Preparation of an oxidation catalyst
BE731346A (de) * 1968-04-10 1969-09-15
GB1575810A (en) * 1976-10-21 1980-10-01 Shell Int Research Process for the performance of silver catalysts
JPS56105750A (en) * 1980-01-24 1981-08-22 Nippon Shokubai Kagaku Kogyo Co Ltd Silver catalyst for production of ethylene oxide
JPS57107240A (en) * 1980-12-26 1982-07-03 Nippon Shokubai Kagaku Kogyo Co Ltd Production of silver catalyst for producing ethylene oxide
JPS60216844A (ja) * 1984-04-13 1985-10-30 Nippon Shokubai Kagaku Kogyo Co Ltd エチレンオキシド製造用銀触媒
DE3669668D1 (de) * 1985-07-31 1990-04-26 Ici Plc Verfahren zur aktivierung der katalysatoren zur herstellung von alkylenoxiden.
US4994587A (en) * 1985-08-12 1991-02-19 Union Carbide Chemicals And Plastics Company, Inc. Catalytic system for epoxidation of alkenes employing low sodium catalyst supports
JPS6287246A (ja) * 1985-10-12 1987-04-21 Nippon Shokubai Kagaku Kogyo Co Ltd エチレンオキシド製造用銀触媒の製造方法
JPS62114654A (ja) * 1985-11-14 1987-05-26 Nippon Shokubai Kagaku Kogyo Co Ltd エチレンオキシド製造用銀触媒の製造方法
AU586048B2 (en) * 1985-11-12 1989-06-29 Nippon Shokubai Kagaku Kogyo Co. Ltd. Silver catalyst for production of ethylene oxide and method for manufacture thereof
JP2637537B2 (ja) * 1989-01-24 1997-08-06 株式会社日本触媒 エチレンオキシド製造用銀触媒およびその製造方法
US5187140A (en) * 1989-10-18 1993-02-16 Union Carbide Chemicals & Plastics Technology Corporation Alkylene oxide catalysts containing high silver content
CA2089510C (en) * 1992-02-27 1998-09-01 Shinichi Nagase Silver catalyst for production of ethylene oxide and method for production of the catalyst
US5705661A (en) * 1995-09-25 1998-01-06 Mitsubishi Chemical Corporation Catalyst for production of ethylene oxide

Also Published As

Publication number Publication date
EP0937498A1 (de) 1999-08-25
DE69919425T2 (de) 2005-09-08
EP0937498B1 (de) 2004-08-18
US6103916A (en) 2000-08-15

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