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DE69700490D1 - Olefinpolymerisation - Google Patents

Olefinpolymerisation

Info

Publication number
DE69700490D1
DE69700490D1 DE69700490T DE69700490T DE69700490D1 DE 69700490 D1 DE69700490 D1 DE 69700490D1 DE 69700490 T DE69700490 T DE 69700490T DE 69700490 T DE69700490 T DE 69700490T DE 69700490 D1 DE69700490 D1 DE 69700490D1
Authority
DE
Germany
Prior art keywords
olefin polymerization
olefin
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69700490T
Other languages
English (en)
Other versions
DE69700490T2 (de
Inventor
Gil R Hawley
Darryl Richard Fahey
Ronald Lee Halterman
Timothy Michael Ramsey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phillips Petroleum Co
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Application granted granted Critical
Publication of DE69700490D1 publication Critical patent/DE69700490D1/de
Publication of DE69700490T2 publication Critical patent/DE69700490T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE69700490T 1996-07-17 1997-07-16 Olefinpolymerisation Expired - Fee Related DE69700490T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/682,223 US5705579A (en) 1996-07-17 1996-07-17 Olefin polymerization

Publications (2)

Publication Number Publication Date
DE69700490D1 true DE69700490D1 (de) 1999-10-14
DE69700490T2 DE69700490T2 (de) 2000-01-05

Family

ID=24738745

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69700490T Expired - Fee Related DE69700490T2 (de) 1996-07-17 1997-07-16 Olefinpolymerisation

Country Status (22)

Country Link
US (1) US5705579A (de)
EP (1) EP0819705B1 (de)
JP (1) JPH1067815A (de)
KR (1) KR980008316A (de)
CN (1) CN1113070C (de)
AR (1) AR007910A1 (de)
AT (1) ATE184291T1 (de)
AU (1) AU694073B2 (de)
BR (1) BR9704007A (de)
CA (1) CA2210730C (de)
DE (1) DE69700490T2 (de)
DK (1) DK0819705T3 (de)
ES (1) ES2135966T3 (de)
GR (1) GR3032033T3 (de)
HU (1) HUP9701223A3 (de)
ID (1) ID19682A (de)
MX (1) MX9705210A (de)
MY (1) MY132781A (de)
NO (1) NO311525B1 (de)
RU (1) RU2193042C2 (de)
TW (1) TW505664B (de)
ZA (1) ZA976084B (de)

Families Citing this family (57)

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CA2331413C (en) 1998-05-18 2007-04-17 Phillips Petroleum Company Catalyst composition for polymerizing monomers
EP1242179B1 (de) 1999-12-16 2013-05-15 Chevron Phillips Chemical Company LP Organo-metall-verbundkatalysator
US7041617B2 (en) 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
KR101113341B1 (ko) 2002-10-15 2012-09-27 엑손모빌 케미칼 패턴츠 인코포레이티드 올레핀 중합용 다중 촉매 시스템 및 이로부터 제조된중합체
EP1464657A1 (de) * 2003-03-06 2004-10-06 ATOFINA Research Hydrogenierter Metallocenkatalysator
US7696280B2 (en) 2004-04-30 2010-04-13 Chevron Phillips Chemical Company, Lp HDPE resins for use in pressure pipe and related applications
US7294599B2 (en) 2004-06-25 2007-11-13 Chevron Phillips Chemical Co. Acidic activator-supports and catalysts for olefin polymerization
US7163906B2 (en) * 2004-11-04 2007-01-16 Chevron Phillips Chemical Company, Llp Organochromium/metallocene combination catalysts for producing bimodal resins
US7517939B2 (en) 2006-02-02 2009-04-14 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high molecular weight polymers with low levels of long chain branching
US7619047B2 (en) * 2006-02-22 2009-11-17 Chevron Phillips Chemical Company, Lp Dual metallocene catalysts for polymerization of bimodal polymers
US7897539B2 (en) * 2007-05-16 2011-03-01 Chevron Phillips Chemical Company Lp Methods of preparing a polymerization catalyst
US7572948B2 (en) * 2007-05-16 2009-08-11 Chevron Phillips Chemical Company, Lp Fulvene purification
US8058200B2 (en) * 2007-05-17 2011-11-15 Chevron Phillips Chemical Company, L.P. Catalysts for olefin polymerization
US20090036554A1 (en) * 2007-08-01 2009-02-05 Burke Susan E Ophthalmic compositions comprising a terpene compound
US8119553B2 (en) * 2007-09-28 2012-02-21 Chevron Phillips Chemical Company Lp Polymerization catalysts for producing polymers with low melt elasticity
US7799721B2 (en) 2007-09-28 2010-09-21 Chevron Phillips Chemical Company Lp Polymerization catalysts for producing polymers with high comonomer incorporation
JP5578854B2 (ja) * 2008-01-11 2014-08-27 三井化学株式会社 変性プロピレン樹脂
US8114946B2 (en) 2008-12-18 2012-02-14 Chevron Phillips Chemical Company Lp Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches
RU2510404C2 (ru) 2009-06-16 2014-03-27 Шеврон Филлипс Кемикал Компани Лп Олигомеризация альфа-олефинов с применением каталитических систем металлоцен-тск и применение полученных полиальфаолефинов для получения смазывающих смесей
DK2588501T3 (en) * 2010-07-01 2016-07-04 Total Res & Technology Feluy Modified catalyst media
US8476394B2 (en) 2010-09-03 2013-07-02 Chevron Philips Chemical Company Lp Polymer resins having improved barrier properties and methods of making same
US8440772B2 (en) 2011-04-28 2013-05-14 Chevron Phillips Chemical Company Lp Methods for terminating olefin polymerizations
US8487053B2 (en) 2011-11-30 2013-07-16 Chevron Phillips Chemical Company Lp Methods for removing polymer skins from reactor walls
US8501882B2 (en) 2011-12-19 2013-08-06 Chevron Phillips Chemical Company Lp Use of hydrogen and an organozinc compound for polymerization and polymer property control
JP5873930B2 (ja) * 2011-12-22 2016-03-01 ペトロレオ ブラジレイロ ソシエダ アノニマ − ペトロブラス オレフィンの重合に使用するためのアルミナ担持触媒及びその調製法
US8703883B2 (en) 2012-02-20 2014-04-22 Chevron Phillips Chemical Company Lp Systems and methods for real-time catalyst particle size control in a polymerization reactor
US10273315B2 (en) 2012-06-20 2019-04-30 Chevron Phillips Chemical Company Lp Methods for terminating olefin polymerizations
US8916494B2 (en) 2012-08-27 2014-12-23 Chevron Phillips Chemical Company Lp Vapor phase preparation of fluorided solid oxides
US8940842B2 (en) 2012-09-24 2015-01-27 Chevron Phillips Chemical Company Lp Methods for controlling dual catalyst olefin polymerizations
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
US8815357B1 (en) 2013-02-27 2014-08-26 Chevron Phillips Chemical Company Lp Polymer resins with improved processability and melt fracture characteristics
US9181369B2 (en) 2013-03-11 2015-11-10 Chevron Phillips Chemical Company Lp Polymer films having improved heat sealing properties
US10654948B2 (en) 2013-03-13 2020-05-19 Chevron Phillips Chemical Company Lp Radically coupled resins and methods of making and using same
US10577440B2 (en) 2013-03-13 2020-03-03 Chevron Phillips Chemical Company Lp Radically coupled resins and methods of making and using same
US9828451B2 (en) 2014-10-24 2017-11-28 Chevron Phillips Chemical Company Lp Polymers with improved processability for pipe applications
CA2985611C (en) 2015-05-11 2021-06-01 W.R. Grace & Co.-Conn. Process to produce modified clay, supported metallocene polymerization catalyst, catalyst produced and use thereof
WO2016183008A1 (en) 2015-05-11 2016-11-17 W.R. Grace & Co.-Conn. Process to produce modified clay, modified clay produced and use thereof
US9708426B2 (en) 2015-06-01 2017-07-18 Chevron Phillips Chemical Company Lp Liquid-solid sampling system for a loop slurry reactor
WO2017078974A1 (en) 2015-11-05 2017-05-11 Chevron Phillips Chemical Company Lp Radically coupled resins and methods of making and using same
US9645066B1 (en) 2015-12-04 2017-05-09 Chevron Phillips Chemical Company Lp Polymer compositions having improved processability and methods of making and using same
US9645131B1 (en) 2015-12-04 2017-05-09 Chevron Phillips Chemical Company Lp Polymer compositions having improved processability and methods of making and using same
US10005861B2 (en) 2016-06-09 2018-06-26 Chevron Phillips Chemical Company Lp Methods for increasing polymer production rates with halogenated hydrocarbon compounds
JP6890398B2 (ja) * 2016-10-24 2021-06-18 三井化学株式会社 遷移金属化合物、オレフィン重合用触媒およびオレフィン重合体の製造方法
US10550252B2 (en) 2017-04-20 2020-02-04 Chevron Phillips Chemical Company Lp Bimodal PE resins with improved melt strength
US10774161B2 (en) 2019-01-31 2020-09-15 Chevron Phillips Chemical Company Lp Systems and methods for polyethylene recovery with low volatile content
US11339229B2 (en) 2020-01-27 2022-05-24 Formosa Plastics Corporation, U.S.A. Process for preparing catalysts and catalyst compositions
EP4097153A1 (de) 2020-01-27 2022-12-07 Formosa Plastics Corporation, U.S.A. Verfahren zum herstellen von katalysatoren und katalysatorzusammensetzungen
US12077616B2 (en) 2021-12-15 2024-09-03 Chevron Phillips Chemical Company Lp Production of polyethylene and ethylene oligomers from ethanol and the use of biomass and waste streams as feedstocks to produce the ethanol
US11845814B2 (en) 2022-02-01 2023-12-19 Chevron Phillips Chemical Company Lp Ethylene polymerization processes and reactor systems for the production of multimodal polymers using combinations of a loop reactor and a fluidized bed reactor
US12466900B2 (en) 2022-04-19 2025-11-11 Chevron Phillips Chemical Company Lp Loop slurry periodogram control to prevent reactor fouling and reactor shutdowns
WO2023239560A1 (en) 2022-06-09 2023-12-14 Formosa Plastics Corporaton, U.S.A. Clay composite support-activators and catalyst compositions
WO2025042807A1 (en) 2023-08-22 2025-02-27 Chevron Phillips Chemical Company Lp Integrated processes utilizing water electrolysis and oxidative dehydrogenation of ethane

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US4937217A (en) * 1987-12-17 1990-06-26 Exxon Chemical Patents Inc. Method for utilizing triethylaluminum to prepare an alumoxane support for an active metallocene catalyst
US4871705A (en) * 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
US5304523A (en) * 1988-07-15 1994-04-19 Fina Technology, Inc. Process and catalyst for producing crystalline polyolefins
US5239022A (en) * 1990-11-12 1993-08-24 Hoechst Aktiengesellschaft Process for the preparation of a syndiotactic polyolefin
DE4125135A1 (de) * 1991-07-30 1993-02-04 Hoechst Ag Verfahren zur herstellung eines stereoblockpolymers
US5391789A (en) * 1991-08-08 1995-02-21 Hoechst Aktiengesellschaft Bridged, chiral metallocenes, processes for their preparation and their use as catalysts
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US5491207A (en) * 1993-12-14 1996-02-13 Exxon Chemical Patents Inc. Process of producing high molecular weight ethylene-α-olefin elastomers with an indenyl metallocene catalyst system
US5594080A (en) * 1994-03-24 1997-01-14 Leland Stanford, Jr. University Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor
IT1273662B (it) * 1994-07-20 1997-07-09 Spherilene Srl Procedimento per la preparazione di polimeri amorfi del propiline'
JP3824325B2 (ja) * 1994-12-20 2006-09-20 モンテル テクノロジー カンパニー ビーブイ 反応体ブレンドのポリプロピレン、その製造法及びメタロセンリガンドの製造法

Also Published As

Publication number Publication date
ATE184291T1 (de) 1999-09-15
CA2210730C (en) 2001-09-11
DE69700490T2 (de) 2000-01-05
EP0819705B1 (de) 1999-09-08
GR3032033T3 (en) 2000-03-31
HUP9701223A3 (en) 2001-04-28
NO973314L (no) 1998-01-19
ZA976084B (en) 1998-02-02
MX9705210A (es) 1998-04-30
TW505664B (en) 2002-10-11
BR9704007A (pt) 1998-09-01
ID19682A (id) 1998-07-30
AR007910A1 (es) 1999-11-24
EP0819705A1 (de) 1998-01-21
CN1182749A (zh) 1998-05-27
DK0819705T3 (da) 1999-12-20
MY132781A (en) 2007-10-31
JPH1067815A (ja) 1998-03-10
HU9701223D0 (en) 1997-08-28
NO973314D0 (no) 1997-07-17
NO311525B1 (no) 2001-12-03
RU2193042C2 (ru) 2002-11-20
CN1113070C (zh) 2003-07-02
HUP9701223A2 (hu) 1999-06-28
ES2135966T3 (es) 1999-11-01
CA2210730A1 (en) 1998-01-17
US5705579A (en) 1998-01-06
AU2850397A (en) 1998-01-29
AU694073B2 (en) 1998-07-09
KR980008316A (ko) 1998-04-30

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Legal Events

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8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee