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DE60335824D1 - METAL-ORGANIC TRANSITION METAL COMPOUND, BICCLOPENTIALIENY LIGANDING SYSTEM, CATALYST SYSTEM AND PROCESS FOR PREPARING POLYOLEFINES - Google Patents

METAL-ORGANIC TRANSITION METAL COMPOUND, BICCLOPENTIALIENY LIGANDING SYSTEM, CATALYST SYSTEM AND PROCESS FOR PREPARING POLYOLEFINES

Info

Publication number
DE60335824D1
DE60335824D1 DE60335824T DE60335824T DE60335824D1 DE 60335824 D1 DE60335824 D1 DE 60335824D1 DE 60335824 T DE60335824 T DE 60335824T DE 60335824 T DE60335824 T DE 60335824T DE 60335824 D1 DE60335824 D1 DE 60335824D1
Authority
DE
Germany
Prior art keywords
transition metal
preparing
aryl
bicclopentialieny
liganding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60335824T
Other languages
German (de)
Inventor
Joerg Schulte
Joerg Schottek
Yoshikuni Okumura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Basell Polyolefine GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine GmbH filed Critical Basell Polyolefine GmbH
Priority to DE60335824T priority Critical patent/DE60335824D1/en
Priority claimed from PCT/EP2003/013553 external-priority patent/WO2004052945A1/en
Application granted granted Critical
Publication of DE60335824D1 publication Critical patent/DE60335824D1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Biscyclopentadienyl transition metal complex is new. Biscyclopentadienyl transition metal complex of formula (I) is new. M1 = group 3,4,5 or 6 element; X = H, halo, 1-20C alkyl, 2-20C alkenyl, 6-22C aryl, 1-10C alkyl(1-6C aryl), 1-6C aryl(1-10C alkyl), -OR6 or -NR6R7; n = oxidation number of M1 - 2 ranging from 1-4; R1, R3, R4 and R8 - R11 = H or 1-40C radical; R2 = optionally substituted 6-40C (hetero)aryl radical containing at least one of O, N, S or P; R2+R3 = ring system; R5 = 1-40C radical; and Z = -C(R8)(R9)C(R10)(R11)-. Independent claims are included for the following: (1) biscyclopentadienyl ligands of formula (II) or its double bond isomers; (2) a catalyst system (S1) for polymerizing olefins comprising (I) and at least as cation forming compound co-catalyst; and (3) preparing (I) involving reacting (II) or its bisanion with a transition metal compound.
DE60335824T 2002-12-06 2003-12-02 METAL-ORGANIC TRANSITION METAL COMPOUND, BICCLOPENTIALIENY LIGANDING SYSTEM, CATALYST SYSTEM AND PROCESS FOR PREPARING POLYOLEFINES Expired - Lifetime DE60335824D1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE60335824T DE60335824D1 (en) 2002-12-06 2003-12-02 METAL-ORGANIC TRANSITION METAL COMPOUND, BICCLOPENTIALIENY LIGANDING SYSTEM, CATALYST SYSTEM AND PROCESS FOR PREPARING POLYOLEFINES

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE10257332A DE10257332A1 (en) 2002-12-06 2002-12-06 New biscyclopentadienyl transition metal complex catalyst useful for polymerizing olefins
US44459503P 2003-02-03 2003-02-03
PCT/EP2003/013553 WO2004052945A1 (en) 2002-12-06 2003-12-02 Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and process for preparing polyolefins
DE60335824T DE60335824D1 (en) 2002-12-06 2003-12-02 METAL-ORGANIC TRANSITION METAL COMPOUND, BICCLOPENTIALIENY LIGANDING SYSTEM, CATALYST SYSTEM AND PROCESS FOR PREPARING POLYOLEFINES

Publications (1)

Publication Number Publication Date
DE60335824D1 true DE60335824D1 (en) 2011-03-03

Family

ID=32336123

Family Applications (2)

Application Number Title Priority Date Filing Date
DE10257332A Withdrawn DE10257332A1 (en) 2002-12-06 2002-12-06 New biscyclopentadienyl transition metal complex catalyst useful for polymerizing olefins
DE60335824T Expired - Lifetime DE60335824D1 (en) 2002-12-06 2003-12-02 METAL-ORGANIC TRANSITION METAL COMPOUND, BICCLOPENTIALIENY LIGANDING SYSTEM, CATALYST SYSTEM AND PROCESS FOR PREPARING POLYOLEFINES

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE10257332A Withdrawn DE10257332A1 (en) 2002-12-06 2002-12-06 New biscyclopentadienyl transition metal complex catalyst useful for polymerizing olefins

Country Status (2)

Country Link
AT (1) ATE496067T1 (en)
DE (2) DE10257332A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2532687A3 (en) * 2011-06-10 2013-04-10 Borealis AG Bridged Metallocene Catalysts

Also Published As

Publication number Publication date
ATE496067T1 (en) 2011-02-15
DE10257332A1 (en) 2004-06-24

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