DE60327380D1 - Thermoplastische Harzzusammensetzung, Polycarbonat-Harzzusammensetzung und daraus geformter Artikel - Google Patents
Thermoplastische Harzzusammensetzung, Polycarbonat-Harzzusammensetzung und daraus geformter ArtikelInfo
- Publication number
- DE60327380D1 DE60327380D1 DE60327380T DE60327380T DE60327380D1 DE 60327380 D1 DE60327380 D1 DE 60327380D1 DE 60327380 T DE60327380 T DE 60327380T DE 60327380 T DE60327380 T DE 60327380T DE 60327380 D1 DE60327380 D1 DE 60327380D1
- Authority
- DE
- Germany
- Prior art keywords
- resin composition
- weight parts
- thermoplastic resin
- resin
- polycarbonate resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
- C08K3/041—Carbon nanotubes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
- C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/10—Block- or graft-copolymers containing polysiloxane sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/445—Block-or graft-polymers containing polysiloxane sequences containing polyester sequences
- C08G77/448—Block-or graft-polymers containing polysiloxane sequences containing polyester sequences containing polycarbonate sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Materials Engineering (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Composite Materials (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002021024A JP4122160B2 (ja) | 2002-01-30 | 2002-01-30 | ポリカーボネート樹脂組成物および成形体 |
| JP2002021023A JP3892307B2 (ja) | 2002-01-30 | 2002-01-30 | 熱可塑性樹脂組成物および成形品 |
| JP2002350850A JP3892389B2 (ja) | 2002-12-03 | 2002-12-03 | 熱可塑性樹脂組成物及び成形体 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE60327380D1 true DE60327380D1 (de) | 2009-06-04 |
Family
ID=27670275
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60327380T Expired - Lifetime DE60327380D1 (de) | 2002-01-30 | 2003-01-28 | Thermoplastische Harzzusammensetzung, Polycarbonat-Harzzusammensetzung und daraus geformter Artikel |
| DE60315132T Expired - Lifetime DE60315132T2 (de) | 2002-01-30 | 2003-01-28 | Thermoplastharzzusammensetzung, polycarbonatharzzusammensetzung und formkörper daraus |
| DE60329643T Expired - Lifetime DE60329643D1 (de) | 2002-01-30 | 2003-01-28 | Thermoplastische Harzzusammensetzung, Polycarbonat-Harzzusammensetzung und daraus geformter Artikel |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60315132T Expired - Lifetime DE60315132T2 (de) | 2002-01-30 | 2003-01-28 | Thermoplastharzzusammensetzung, polycarbonatharzzusammensetzung und formkörper daraus |
| DE60329643T Expired - Lifetime DE60329643D1 (de) | 2002-01-30 | 2003-01-28 | Thermoplastische Harzzusammensetzung, Polycarbonat-Harzzusammensetzung und daraus geformter Artikel |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US7307120B2 (de) |
| EP (3) | EP1471114B1 (de) |
| AT (1) | ATE368080T1 (de) |
| DE (3) | DE60327380D1 (de) |
| WO (1) | WO2003064536A1 (de) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7132062B1 (en) * | 2003-04-15 | 2006-11-07 | Plasticolors, Inc. | Electrically conductive additive system and method of making same |
| US7232854B2 (en) | 2004-02-03 | 2007-06-19 | General Electric Company | Polycarbonate compositions with thin-wall flame retardance |
| JP5021192B2 (ja) * | 2004-12-06 | 2012-09-05 | 出光興産株式会社 | ポリカーボネート樹脂組成物及び成形体 |
| JP4783041B2 (ja) | 2005-03-16 | 2011-09-28 | 出光興産株式会社 | 樹脂組成物、該樹脂組成物の製造方法及び該樹脂組成物の成形体 |
| CN101296981B (zh) * | 2005-10-28 | 2012-04-04 | 纳诺塞尔股份有限公司 | 耐火组合物 |
| US20080171823A1 (en) * | 2006-08-08 | 2008-07-17 | The Research Foundation Of State University Of New York | Single component flame retardant additive for polymers using nanotubes |
| KR100790424B1 (ko) * | 2006-12-22 | 2008-01-03 | 제일모직주식회사 | 전자파 차폐용 열가소성 수지 조성물 및 플라스틱 성형품 |
| US20080300331A1 (en) * | 2007-01-19 | 2008-12-04 | Jurgen Schellenberg | Polymeric foam containing long carbon nano-tubes |
| JP5189323B2 (ja) * | 2007-07-11 | 2013-04-24 | 出光興産株式会社 | 難燃性ポリカーボネート樹脂組成物及びその成形品 |
| KR100856137B1 (ko) * | 2007-08-08 | 2008-09-02 | 제일모직주식회사 | 전기전도성 열가소성 수지 조성물 및 그 성형품 |
| US7994248B2 (en) | 2008-12-11 | 2011-08-09 | Sabic Innovative Plastics Ip B.V. | Flame retardant thermoplastic polycarbonate compositions |
| US8658898B2 (en) * | 2009-04-13 | 2014-02-25 | Yazaki Corporation | Resin composition for heat-resistant electrical wire, and heat-resistant electrical wire |
| EP2308906A1 (de) * | 2009-10-07 | 2011-04-13 | Styron Europe GmbH | Schlagzäh modifizierte aromatische Monovinylidenpolymere mit niedriger Kautschukvernetzung |
| KR101269422B1 (ko) * | 2009-12-30 | 2013-06-04 | 제일모직주식회사 | 내마모성 및 전기전도성이 우수한 폴리카보네이트계 수지 조성물 및 그 제조방법 |
| US9085678B2 (en) * | 2010-01-08 | 2015-07-21 | King Abdulaziz City For Science And Technology | Clean flame retardant compositions with carbon nano tube for enhancing mechanical properties for insulation of wire and cable |
| WO2012032550A1 (en) | 2010-09-10 | 2012-03-15 | Viba S.P.A. | Flame retardant masterbatch for thermoplastic polymers and process for its production |
| WO2011125078A1 (en) * | 2010-04-08 | 2011-10-13 | Viba S.P.A. | Flame retardant masterbatch for thermoplastic polymers and process for its production |
| ES2402984T3 (es) | 2010-04-08 | 2013-05-13 | Viba S.P.A. | Mezcla madre retardante de llama para polímeros termoplásticos y proceso para su producción |
| US9234081B2 (en) | 2010-06-08 | 2016-01-12 | King Abdulaziz City For Science And Technology | Method of manufacturing a nitro blue tetrazolium and polyvinyl butyral based dosimeter film |
| WO2012089998A2 (en) * | 2010-12-29 | 2012-07-05 | University Of Bradford | Methods to improve the electrical conductivity for moulded plastic parts |
| US9932959B2 (en) | 2011-03-10 | 2018-04-03 | King Abdulaziz City For Science And Technology | Shrounded wind turbine configuration with nozzle augmented diffuser |
| JP5988971B2 (ja) * | 2011-06-17 | 2016-09-07 | 出光興産株式会社 | ポリカーボネート樹脂組成物及びそれを用いた成形体 |
| US8871019B2 (en) | 2011-11-01 | 2014-10-28 | King Abdulaziz City Science And Technology | Composition for construction materials manufacturing and the method of its production |
| JP5973738B2 (ja) | 2012-01-30 | 2016-08-23 | 出光興産株式会社 | ポリカーボネート樹脂組成物、成形品 |
| EP2883907B1 (de) * | 2012-08-08 | 2019-05-08 | Daicel Corporation | Leitfähige harzzusammensetzung auf cellulosebasis |
| DE102012022482A1 (de) * | 2012-11-19 | 2014-05-22 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Polymerzusammensetzung mit verbesserter Langzeitstabilität, hieraus hergestellte Formteile sowie Verwendungszwecke |
| KR101596542B1 (ko) * | 2012-12-27 | 2016-02-22 | 제일모직주식회사 | 적하방지 효과가 우수한 열가소성 수지 조성물 |
| US20160160001A1 (en) * | 2014-11-06 | 2016-06-09 | Northrop Grumman Systems Corporation | Ultrahigh loading of carbon nanotubes in structural resins |
| CN107408543B (zh) * | 2015-02-10 | 2021-02-05 | 日本瑞翁株式会社 | 导热片及其制造方法 |
| KR102025373B1 (ko) * | 2016-02-26 | 2019-09-25 | 주식회사 엘지화학 | 탄소복합소재 및 그 제조방법 |
| WO2019165359A1 (en) * | 2018-02-23 | 2019-08-29 | Frx Polymers, Inc. | Compositions of polyphosphonates and carbon nanotubes |
| EP3540010A1 (de) * | 2018-03-15 | 2019-09-18 | SABIC Global Technologies B.V. | Zusammensetzungen mit verbesserter schlagfestigkeit |
| CN109867966A (zh) * | 2019-03-18 | 2019-06-11 | 深圳烯湾科技有限公司 | 聚碳酸酯组合物及其制备方法和应用 |
| KR102402957B1 (ko) * | 2021-07-13 | 2022-05-30 | 대진첨단소재 주식회사 | 대전방지 수지 조성물, 이의 성형품 및 이의 제조방법 |
| EP4174125A1 (de) * | 2021-10-29 | 2023-05-03 | SHPP Global Technologies B.V. | Polycarbonatzusammensetzungen mit kohlenstoffnanoröhren (cnts) als mikrowellenabsorber in radarsensoranwendungen von kraftfahrzeugen |
| CN119798952A (zh) * | 2025-01-03 | 2025-04-11 | 广东永鑫华新型材料有限公司 | 一种高强度阻燃pcabs材料及其制备方法 |
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| US4663230A (en) | 1984-12-06 | 1987-05-05 | Hyperion Catalysis International, Inc. | Carbon fibrils, method for producing same and compositions containing same |
| GB2174095A (en) * | 1985-03-20 | 1986-10-29 | Dainichi Nippon Cables Ltd | Flame-retardant resin compositions |
| US4983663A (en) * | 1987-10-30 | 1991-01-08 | Nippon Petrochemicals Co. | Thermoplastic resin composition and method for preparing the same |
| JP2862578B2 (ja) | 1989-08-14 | 1999-03-03 | ハイピリオン・カタリシス・インターナシヨナル・インコーポレイテツド | 樹脂組成物 |
| JP3114737B2 (ja) | 1991-02-22 | 2000-12-04 | 三菱瓦斯化学株式会社 | 熱可塑性樹脂組成物 |
| US5367016A (en) * | 1991-11-28 | 1994-11-22 | Kanegafuchi Chemical Industry Co., Ltd. | Reinforced resin composition |
| US5451632A (en) | 1992-10-26 | 1995-09-19 | Idemitsu Petrochemical Co., Ltd. | Polycarbonate-polyorganosiloxane copolymer and a resin composition |
| JPH06248153A (ja) * | 1993-03-01 | 1994-09-06 | Shin Etsu Chem Co Ltd | 難燃樹脂組成物 |
| AU2613795A (en) * | 1994-05-27 | 1995-12-21 | Ciba-Geigy Ag | Polyester/polycarbonate blends having enhanced properties |
| US5393572A (en) | 1994-07-11 | 1995-02-28 | Southwest Research Institute | Ion beam assisted method of producing a diamond like carbon coating |
| DE69528121T2 (de) | 1994-07-15 | 2003-10-02 | Idemitsu Petrochemical Co., Ltd. | Polycarbonatharzzusammensetzung |
| DE19653042A1 (de) * | 1996-12-19 | 1998-06-25 | Basf Ag | Flammgeschützte Formmassen |
| US6683783B1 (en) * | 1997-03-07 | 2004-01-27 | William Marsh Rice University | Carbon fibers formed from single-wall carbon nanotubes |
| US6203911B1 (en) * | 1998-06-17 | 2001-03-20 | E. I. Du Pont De Nemours And Company | Thermoset volatile monomer molding compositions |
| US6221939B1 (en) * | 1998-08-31 | 2001-04-24 | General Electric Company | Flame retardant resin compositions containing phosphoramides, and method for making |
| JP2000281905A (ja) * | 1999-03-30 | 2000-10-10 | Teijin Chem Ltd | 電気抵抗の制御された炭素繊維含有熱可塑性樹脂組成物 |
| US6518218B1 (en) * | 1999-03-31 | 2003-02-11 | General Electric Company | Catalyst system for producing carbon fibrils |
| ATE258709T1 (de) * | 1999-05-13 | 2004-02-15 | Union Carbide Chem Plastic | Halbleitfähiger kabel-schirm |
| EP1054036A1 (de) * | 1999-05-18 | 2000-11-22 | Fina Research S.A. | Verstärkte Polymere |
| US6365677B1 (en) * | 2000-03-01 | 2002-04-02 | General Electric | Reduction of carbonized particles |
| KR100718853B1 (ko) * | 2000-03-28 | 2007-05-16 | 데이진 가세이 가부시키가이샤 | 재생 수지 조성물 |
| US6919394B2 (en) * | 2000-04-26 | 2005-07-19 | Asahi Kasei Kabushiki Kaisha | Electrically conductive resin composition and production process thereof |
| US6797386B2 (en) * | 2000-05-23 | 2004-09-28 | Daicel Chemical Industries, Ltd. | Coated molding of thermoplastic resin composition and production method therefor |
| MY142518A (en) * | 2001-01-10 | 2010-12-15 | Hitachi Chemical Co Ltd | Dihydrobenzoxazine ring-containing resin, phenolic-triazine-aldehyde condensate and epoxy resin |
| ATE513880T1 (de) * | 2001-02-05 | 2011-07-15 | Toray Industries | Kohlefaserverstärkte harzzusammensetzung, formmasse und formkörper daraus |
| JP2003012939A (ja) | 2001-07-03 | 2003-01-15 | Toray Ind Inc | カーボン含有樹脂組成物、成形材料および成形体 |
| JP4723132B2 (ja) * | 2001-08-22 | 2011-07-13 | 三菱エンジニアリングプラスチックス株式会社 | ポリカーボネート樹脂組成物 |
| WO2003025069A1 (fr) | 2001-09-14 | 2003-03-27 | Bridgestone Corporation | Composition elastomere thermoplastique |
| US6528572B1 (en) * | 2001-09-14 | 2003-03-04 | General Electric Company | Conductive polymer compositions and methods of manufacture thereof |
| JP2005517788A (ja) * | 2002-02-20 | 2005-06-16 | エレクトロヴァク・ファブリケーション・エレクトロテクニシャー・スペズィアラーティケル・ゲーエムベーハー | 難燃性ポリマー複合体及び製造方法 |
| CN1656574A (zh) * | 2002-04-01 | 2005-08-17 | 环球产权公司 | 导电的聚合物泡沫和弹性体及其制造方法 |
| US6908261B2 (en) * | 2002-05-09 | 2005-06-21 | Forward Ventures, Lp | Conductor polymer backfill composition and method of use as a reinforcement material for utility poles |
| US20060099135A1 (en) * | 2002-09-10 | 2006-05-11 | Yodh Arjun G | Carbon nanotubes: high solids dispersions and nematic gels thereof |
| US7265175B2 (en) * | 2003-10-30 | 2007-09-04 | The Trustees Of The University Of Pennsylvania | Flame retardant nanocomposite |
| JP2008501210A (ja) * | 2004-05-05 | 2008-01-17 | ユニオン・カーバイド・ケミカルズ・アンド・プラスティックス・テクノロジー・コーポレイション | 難燃性プレナムケーブル |
| US20080171823A1 (en) * | 2006-08-08 | 2008-07-17 | The Research Foundation Of State University Of New York | Single component flame retardant additive for polymers using nanotubes |
-
2003
- 2003-01-28 WO PCT/JP2003/000760 patent/WO2003064536A1/ja not_active Ceased
- 2003-01-28 US US10/500,458 patent/US7307120B2/en not_active Expired - Lifetime
- 2003-01-28 EP EP03734619A patent/EP1471114B1/de not_active Expired - Lifetime
- 2003-01-28 EP EP06126479A patent/EP1801164B1/de not_active Expired - Lifetime
- 2003-01-28 DE DE60327380T patent/DE60327380D1/de not_active Expired - Lifetime
- 2003-01-28 DE DE60315132T patent/DE60315132T2/de not_active Expired - Lifetime
- 2003-01-28 AT AT03734619T patent/ATE368080T1/de not_active IP Right Cessation
- 2003-01-28 DE DE60329643T patent/DE60329643D1/de not_active Expired - Lifetime
- 2003-01-28 EP EP08152892A patent/EP1944337B1/de not_active Expired - Lifetime
-
2007
- 2007-06-28 US US11/770,237 patent/US8044127B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP1944337A2 (de) | 2008-07-16 |
| EP1944337B1 (de) | 2009-10-07 |
| EP1944337A3 (de) | 2008-07-23 |
| DE60329643D1 (de) | 2009-11-19 |
| EP1801164A1 (de) | 2007-06-27 |
| US8044127B2 (en) | 2011-10-25 |
| ATE368080T1 (de) | 2007-08-15 |
| US20080176978A1 (en) | 2008-07-24 |
| EP1801164B1 (de) | 2009-04-22 |
| US7307120B2 (en) | 2007-12-11 |
| US20060089434A1 (en) | 2006-04-27 |
| EP1471114B1 (de) | 2007-07-25 |
| DE60315132D1 (de) | 2007-09-06 |
| EP1471114A1 (de) | 2004-10-27 |
| EP1471114A4 (de) | 2005-10-12 |
| WO2003064536A1 (en) | 2003-08-07 |
| DE60315132T2 (de) | 2007-11-15 |
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