DE60314865D1 - Verfahren zur herstellung von modifiziertem polymer, danach erhaltenes modifiziertes polymer und kautschukzusammensetzung - Google Patents
Verfahren zur herstellung von modifiziertem polymer, danach erhaltenes modifiziertes polymer und kautschukzusammensetzungInfo
- Publication number
- DE60314865D1 DE60314865D1 DE60314865T DE60314865T DE60314865D1 DE 60314865 D1 DE60314865 D1 DE 60314865D1 DE 60314865 T DE60314865 T DE 60314865T DE 60314865 T DE60314865 T DE 60314865T DE 60314865 D1 DE60314865 D1 DE 60314865D1
- Authority
- DE
- Germany
- Prior art keywords
- modified polymer
- production
- rubber composition
- polymer
- modified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000642 polymer Polymers 0.000 title 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/442—Block-or graft-polymers containing polysiloxane sequences containing vinyl polymer sequences
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
- C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
- C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/42—Introducing metal atoms or metal-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/10—Block- or graft-copolymers containing polysiloxane sequences
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Tires In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002110285 | 2002-04-12 | ||
| JP2002110285 | 2002-04-12 | ||
| PCT/JP2003/004632 WO2003087171A1 (en) | 2002-04-12 | 2003-04-11 | Process for producing modified polymer, modified polymer obtained by the process, and rubber composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60314865D1 true DE60314865D1 (de) | 2007-08-23 |
| DE60314865T2 DE60314865T2 (de) | 2008-03-13 |
Family
ID=29243225
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60314865T Expired - Lifetime DE60314865T2 (de) | 2002-04-12 | 2003-04-11 | Verfahren zur herstellung von modifiziertem polymer, danach erhaltenes modifiziertes polymer und kautschukzusammensetzung |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7683151B2 (de) |
| EP (1) | EP1505087B1 (de) |
| JP (3) | JP4265971B2 (de) |
| CN (1) | CN1304433C (de) |
| DE (1) | DE60314865T2 (de) |
| ES (1) | ES2290484T3 (de) |
| WO (1) | WO2003087171A1 (de) |
Families Citing this family (77)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100702325B1 (ko) * | 2002-05-24 | 2007-03-30 | 주식회사 만도 | 전자제어 현가장치의 안티 스쿼트 제어방법 |
| JP4596126B2 (ja) * | 2003-05-22 | 2010-12-08 | Jsr株式会社 | 変性共役ジエン系重合体の製造方法およびゴム組成物 |
| DE602004013672D1 (de) | 2003-05-22 | 2008-06-26 | Jsr Corp | Verfahren zur Herstellung eines modifizierten, konjugierten Dienpolymers und dieses enthaltende Elastomerzusammensetzung |
| ES2437197T3 (es) | 2003-06-09 | 2014-01-09 | Bridgestone Corporation | Composiciones elastoméricas de histéresis mejorada que comprenden polímeros terminados con isocianato-alcoxisilanos |
| JP2005232364A (ja) * | 2004-02-20 | 2005-09-02 | Bridgestone Corp | 変性共役ジエン系重合体、並びにそれを用いたゴム組成物及びタイヤ |
| JP4829475B2 (ja) * | 2004-02-20 | 2011-12-07 | 株式会社ブリヂストン | 変性共役ジエン系重合体、並びにそれを用いたゴム組成物及びタイヤ |
| JP4539177B2 (ja) * | 2004-06-04 | 2010-09-08 | 住友化学株式会社 | 変性ジエン系重合体ゴム、その製造方法及びゴム組成物 |
| US7625981B2 (en) * | 2004-06-04 | 2009-12-01 | Sumitomo Chemical Company, Limited | Process for producing modified polymer rubber |
| JP4944376B2 (ja) | 2004-12-22 | 2012-05-30 | 株式会社ブリヂストン | ゴム組成物、その製造方法及びタイヤ |
| ES2334702T3 (es) * | 2005-01-14 | 2010-03-15 | Bridgestone Corporation | Procedimiento de preparacion de un neumatico con esfuerzo de silice mejorado. |
| US7868081B2 (en) * | 2005-03-04 | 2011-01-11 | Bridgestone Corporation | Rubber composition and tire using same |
| JP2006257262A (ja) * | 2005-03-17 | 2006-09-28 | Sumitomo Chemical Co Ltd | 変性ジエン系重合体ゴム及びその製造方法 |
| KR101262406B1 (ko) * | 2005-03-18 | 2013-05-08 | 제이에스알 가부시끼가이샤 | 변성 중합체의 제조 방법 |
| JP4735812B2 (ja) * | 2005-04-20 | 2011-07-27 | 株式会社ブリヂストン | タイヤ |
| JP5350577B2 (ja) | 2005-09-15 | 2013-11-27 | 株式会社ブリヂストン | ゴム組成物およびそれを用いたタイヤ |
| CN101268107B (zh) | 2005-09-22 | 2012-10-10 | 旭化成化学株式会社 | 共轭二烯系聚合物及其制造方法 |
| ZA200803331B (en) * | 2005-10-05 | 2009-10-28 | Jsr Corp | Process for producing modified conjugated diene polymer, modified conjugated diene polymer obtained by the process, and rubber composition containing the same |
| EP2003137B1 (de) * | 2006-04-05 | 2015-10-28 | Bridgestone Corporation | Aktivierter silanverbundstoff, kautschukzusammensetzung damit und reifen |
| US20090308513A1 (en) * | 2006-07-06 | 2009-12-17 | Bridgestone Corporation | Rubber composition and pneumatic tire using the same |
| US20090306269A1 (en) * | 2006-07-06 | 2009-12-10 | Bridgestone Corporation | Rubber composition and pneumatic tire using the same |
| CN102344513B (zh) | 2006-07-24 | 2013-10-16 | 旭化成化学株式会社 | 改性共轭二烯系聚合物及其制造方法 |
| US20080103261A1 (en) * | 2006-10-25 | 2008-05-01 | Bridgestone Corporation | Process for producing modified conjugated diene based polymer, modified conjugated diene based polymer produced by the process, rubber composition, and tire |
| JP5745733B2 (ja) * | 2006-10-25 | 2015-07-08 | Jsr株式会社 | 変性重合体の製造方法、その方法により得られた変性重合体とそのゴム組成物 |
| RU2451693C2 (ru) * | 2007-03-23 | 2012-05-27 | Джей эс а КОРПОРЕЙШН | Способ получения модифицированного полимера сопряженного диена, модифицированный полимер и каучуковая композиция |
| JP5119738B2 (ja) | 2007-05-18 | 2013-01-16 | トヨタ自動車株式会社 | アルカリ型燃料電池用の電極触媒、アルカリ型燃料電池、及び、アルカリ型燃料電池用電極触媒の形成方法 |
| US8110635B2 (en) * | 2007-06-27 | 2012-02-07 | Sumitomo Chemical Company, Limited | Method for producing conjugated diene polymer, conjugated diene polymer, and polymer composition |
| WO2009022665A1 (ja) * | 2007-08-10 | 2009-02-19 | Bridgestone Corporation | 空気入りタイヤ |
| JP5319108B2 (ja) * | 2007-12-25 | 2013-10-16 | 株式会社ブリヂストン | ゴム組成物及びそれを用いたタイヤ |
| JP5463042B2 (ja) * | 2008-01-17 | 2014-04-09 | 株式会社ブリヂストン | ゴム組成物及びそれを用いたタイヤ |
| JP5363738B2 (ja) * | 2008-01-28 | 2013-12-11 | 株式会社ブリヂストン | ゴム組成物及びそれを用いた空気入りタイヤ |
| JP5473360B2 (ja) * | 2008-03-10 | 2014-04-16 | 株式会社ブリヂストン | ゴム組成物及びそれを用いたタイヤ |
| US9623705B2 (en) | 2008-03-10 | 2017-04-18 | Bridgestone Corporation | Method for producing modified conjugated diene polymer/copolymer, modified conjugated diene polymer/copolymer, and rubber composition and tire using the same |
| JP2009256549A (ja) * | 2008-04-21 | 2009-11-05 | Bridgestone Corp | タイヤ |
| JP2009263479A (ja) * | 2008-04-24 | 2009-11-12 | Bridgestone Corp | ゴム組成物及びそれを用いたタイヤ |
| JP2009262835A (ja) * | 2008-04-25 | 2009-11-12 | Bridgestone Corp | タイヤ |
| JP2009263586A (ja) * | 2008-04-28 | 2009-11-12 | Bridgestone Corp | タイヤ |
| US9279045B2 (en) | 2008-04-30 | 2016-03-08 | Bridgestone Corporation | Tire prepared by using rubber composition containing modified polymer |
| JP5512933B2 (ja) * | 2008-04-30 | 2014-06-04 | 株式会社ブリヂストン | 変性共役ジエン系共重合体の製造方法、その方法により得られた変性共役ジエン系共重合体、ゴム組成物及びタイヤ |
| JPWO2009133888A1 (ja) * | 2008-04-30 | 2011-09-01 | 株式会社ブリヂストン | 変性共役ジエン系共重合体の製造方法、その方法により得られた変性共役ジエン系共重合体、ゴム組成物及びタイヤ |
| JP6085077B2 (ja) * | 2008-04-30 | 2017-02-22 | 株式会社ブリヂストン | ゴム組成物及びそれを用いたタイヤ |
| JP5091921B2 (ja) * | 2008-09-19 | 2012-12-05 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物 |
| JP5415743B2 (ja) * | 2008-11-11 | 2014-02-12 | 住友ゴム工業株式会社 | チェーファー又はクリンチ用ゴム組成物、及び空気入りタイヤ |
| US8022159B2 (en) * | 2008-11-24 | 2011-09-20 | The Goodyear Tire & Rubber Company | Terminating compounds, polymers, and their uses in rubber compositions and tires |
| JP5257046B2 (ja) * | 2008-12-16 | 2013-08-07 | 日本ゼオン株式会社 | 脂環式炭化水素ランダム共重合体、その製造方法、樹脂組成物、及び成形物 |
| JP5262672B2 (ja) * | 2008-12-17 | 2013-08-14 | 信越化学工業株式会社 | 液晶素子用感圧接着剤組成物 |
| JP2010241983A (ja) * | 2009-04-07 | 2010-10-28 | Bridgestone Corp | ゴム組成物の製造方法 |
| BRPI1011967B1 (pt) | 2009-04-30 | 2020-04-07 | Bridgestone Corp | pneumático |
| JP5297888B2 (ja) * | 2009-05-20 | 2013-09-25 | 株式会社ブリヂストン | 変性剤、変性共役ジエン系重合体の製造方法、変性共役ジエン系重合体、ゴム組成物および空気入りタイヤ |
| EP2476709A4 (de) | 2009-09-09 | 2013-08-14 | Bridgestone Corp | Modifizierungsmittel, verfahren zur herstellung eines modifizierten konjugierten dienpolymers mithilfe des modifizierungsmittels und modifiziertes konjugiertes dienpolymer |
| EP2674455B1 (de) * | 2011-02-09 | 2018-01-10 | JSR Corporation | Kautschukzusammensetzung, verfahren zu ihrer herstellung und reifen |
| JP5924270B2 (ja) * | 2011-02-09 | 2016-05-25 | Jsr株式会社 | ゴム組成物の製造方法およびタイヤの製造方法 |
| JP6004677B2 (ja) * | 2011-03-31 | 2016-10-12 | 住友化学株式会社 | 変性共役ジエン系重合体の製造方法、変性共役ジエン系重合体、及び重合体組成物 |
| JP5684050B2 (ja) * | 2011-06-03 | 2015-03-11 | 東洋ゴム工業株式会社 | 変性ジエン系ゴム、ゴム組成物及び空気入りタイヤ |
| SG187314A1 (en) * | 2011-07-13 | 2013-02-28 | Sumitomo Chemical Co | Method for producing modified conjugated diene-based polymer, and method for producing vulcanized polymer |
| JP2013043927A (ja) * | 2011-08-23 | 2013-03-04 | Sumitomo Rubber Ind Ltd | ゴム組成物及び空気入りタイヤ |
| TWI585115B (zh) | 2011-12-15 | 2017-06-01 | 普利司通股份有限公司 | 經穩定之多價陰離子聚合反應引發劑及其製備方法 |
| ES2596368T3 (es) * | 2012-03-20 | 2017-01-09 | Trinseo Europe Gmbh | Composiciones de polímeros modificados |
| JP6086650B2 (ja) * | 2012-03-22 | 2017-03-01 | 日本エラストマー株式会社 | カップリングされた重合体の製造方法 |
| CN103374137B (zh) * | 2012-04-23 | 2015-08-26 | 中国石油化工股份有限公司 | 一种含活性结合硫的苯乙烯-共轭二烯共聚物的制备和应用 |
| DE112013003160B4 (de) * | 2012-08-03 | 2023-05-17 | Sumitomo Rubber Industries, Ltd. | Luftreifen und dessen Verwendung |
| CN102898838A (zh) * | 2012-10-22 | 2013-01-30 | 广东普赛特电子科技股份有限公司 | 一种纳米改性电子硅酮胶及其制备方法 |
| WO2015089356A2 (en) | 2013-12-12 | 2015-06-18 | Firestone Polymers, Llc | Method for producing polymeric compositions including functionalized polymers |
| US20160052344A1 (en) * | 2014-08-20 | 2016-02-25 | The Goodyear Tire & Rubber Company | Rubber composition containing tin carboxylate salt |
| KR101672645B1 (ko) * | 2014-12-22 | 2016-11-03 | 주식회사 엘지화학 | 관능기가 도입된 아미노실란계 말단변성제, 이를 이용하는 말단변성 공역디엔계 중합체의 제조방법, 및 이에 따라 제조한 말단변성 공역디엔계 중합체 |
| CN107428940B (zh) | 2014-12-30 | 2020-12-15 | 株式会社普利司通 | 末端官能化聚合物及相关方法 |
| JP6715857B2 (ja) * | 2015-03-13 | 2020-07-01 | 株式会社ブリヂストン | タイヤを製造するための二酸化ケイ素含有ゴムコンパウンドの製造方法 |
| IT201600108121A1 (it) * | 2016-10-26 | 2018-04-26 | Pirelli | Nuovi materiali di rinforzo, composizioni elastomeriche e pneumatici per ruote di veicoli che li comprendono |
| EP3778654B1 (de) * | 2018-03-27 | 2025-02-26 | Zeon Corporation | Verfahren zur herstellung von konjugiertem dienkautschuk |
| US20210023881A1 (en) * | 2018-04-02 | 2021-01-28 | Sumitomo Rubber Industries, Ltd. | Rubber composition for tire, and pneumatic tire |
| KR102678859B1 (ko) | 2018-10-12 | 2024-06-28 | 브리지스톤 어메리카스 타이어 오퍼레이션스, 엘엘씨 | 안정화된 목표 점도를 갖는 개질된 다이엔 공중합체 |
| KR102625110B1 (ko) * | 2019-03-27 | 2024-01-12 | 가부시키가이샤 에네오스 마테리아루 | 중합체 조성물, 가교 중합체 및, 타이어 |
| JP7314034B2 (ja) * | 2019-11-29 | 2023-07-25 | 株式会社ブリヂストン | ゴム組成物及びタイヤ |
| US12018108B2 (en) | 2019-11-29 | 2024-06-25 | Lg Chem, Ltd. | Modified conjugated diene-based polymer |
| JP7364442B2 (ja) * | 2019-11-29 | 2023-10-18 | 株式会社ブリヂストン | ゴム組成物及びタイヤ |
| KR102536519B1 (ko) * | 2019-11-29 | 2023-05-26 | 주식회사 엘지화학 | 변성제 및 이를 이용하여 제조된 변성 공액디엔계 중합체 |
| EP4071208B1 (de) | 2019-12-06 | 2025-09-10 | ENEOS Materials Corporation | Herstellungsverfahren für eine polymerzusammensetzung |
| EP4349905A4 (de) * | 2021-05-28 | 2024-10-02 | Bridgestone Corporation | Reifenkautschukzusammensetzung, laufflächenkautschuk und reifen |
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|---|---|---|---|---|
| JPS56104906A (en) * | 1980-01-25 | 1981-08-21 | Asahi Chem Ind Co Ltd | Polymer having reactive end group |
| US4379891A (en) * | 1981-06-15 | 1983-04-12 | Shell Oil Company | Multifunctional coupling agent |
| JPH03504026A (ja) * | 1989-02-16 | 1991-09-05 | イーストマン コダック カンパニー | シリル末端化ポリマー |
| US5840800A (en) * | 1995-11-02 | 1998-11-24 | Dow Corning Corporation | Crosslinked emulsions of pre-formed silicon modified organic polymers |
| US6191247B1 (en) * | 1996-04-10 | 2001-02-20 | The Yokohama Rubber Co., Ltd. | Polysiloxane composition having superior storage stability and rubber composition containing same |
| US6228908B1 (en) | 1997-07-11 | 2001-05-08 | Bridgestone Corporation | Diene polymers and copolymers incorporating partial coupling and terminals formed from hydrocarboxysilane compounds |
| US6008295A (en) * | 1997-07-11 | 1999-12-28 | Bridgestone Corporation | Diene polymers and copolymers incorporating partial coupling and terminals formed from hydrocarboxysilane compounds |
| US6274688B1 (en) * | 1997-07-28 | 2001-08-14 | Kaneka Corporation | Functional groups-terminated vinyl polymers |
| JP4177935B2 (ja) | 1998-06-19 | 2008-11-05 | 株式会社カネカ | 反応性ホットメルト接着剤 |
| US6403693B2 (en) * | 1999-06-18 | 2002-06-11 | The Goodyear Tire & Rubber Company | Silica reinforced rubber composition and use in tires |
| ES2320087T3 (es) * | 1999-11-12 | 2009-05-19 | Bridgestone Corporation | Polimeros modificados preparados con catalizadores basados en lantanido. |
| DE69907230T2 (de) * | 1999-12-02 | 2004-02-05 | Bridgestone Corp. | Polymer, Verfahren zur Herstellung und Verwendung dieses Polymers in einer Kautschukmischung |
| US6573412B1 (en) * | 2000-05-12 | 2003-06-03 | Bridgestone Corporation | Chain-coupled polymeric alkoxide compounds having controlled viscosity |
| EP1449857B1 (de) * | 2001-11-27 | 2010-10-13 | Bridgestone Corporation | Polymer auf basis von konjugierten dienen, herstellungsverfahren dafür und dieses enthaltende kautschukzusammensetzungen |
| ES2400176T3 (es) * | 2001-12-03 | 2013-04-08 | Bridgestone Corporation | Proceso para producir polímero modificado, polímero modificado obtenido mediante el proceso y composición de caucho |
-
2003
- 2003-04-11 JP JP2003584126A patent/JP4265971B2/ja not_active Expired - Lifetime
- 2003-04-11 ES ES03746460T patent/ES2290484T3/es not_active Expired - Lifetime
- 2003-04-11 EP EP03746460A patent/EP1505087B1/de not_active Expired - Lifetime
- 2003-04-11 CN CNB038081970A patent/CN1304433C/zh not_active Expired - Lifetime
- 2003-04-11 US US10/510,684 patent/US7683151B2/en not_active Expired - Lifetime
- 2003-04-11 WO PCT/JP2003/004632 patent/WO2003087171A1/ja not_active Ceased
- 2003-04-11 DE DE60314865T patent/DE60314865T2/de not_active Expired - Lifetime
-
2008
- 2008-03-21 JP JP2008074507A patent/JP5069593B2/ja not_active Expired - Lifetime
- 2008-03-21 JP JP2008074506A patent/JP5313530B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP2008202054A (ja) | 2008-09-04 |
| EP1505087A4 (de) | 2006-05-03 |
| JP2008208376A (ja) | 2008-09-11 |
| CN1304433C (zh) | 2007-03-14 |
| JP4265971B2 (ja) | 2009-05-20 |
| DE60314865T2 (de) | 2008-03-13 |
| JP5069593B2 (ja) | 2012-11-07 |
| CN1646576A (zh) | 2005-07-27 |
| US20050159554A1 (en) | 2005-07-21 |
| EP1505087B1 (de) | 2007-07-11 |
| JP5313530B2 (ja) | 2013-10-09 |
| JPWO2003087171A1 (ja) | 2005-08-18 |
| EP1505087A1 (de) | 2005-02-09 |
| US7683151B2 (en) | 2010-03-23 |
| ES2290484T3 (es) | 2008-02-16 |
| WO2003087171A1 (en) | 2003-10-23 |
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