DE60225204D1 - Polymerelektrolyt und Hestellungsverfahren dafür - Google Patents
Polymerelektrolyt und Hestellungsverfahren dafürInfo
- Publication number
- DE60225204D1 DE60225204D1 DE60225204T DE60225204T DE60225204D1 DE 60225204 D1 DE60225204 D1 DE 60225204D1 DE 60225204 T DE60225204 T DE 60225204T DE 60225204 T DE60225204 T DE 60225204T DE 60225204 D1 DE60225204 D1 DE 60225204D1
- Authority
- DE
- Germany
- Prior art keywords
- hestellungsverfahren
- polymer electrolyte
- electrolyte
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1058—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties
- H01M8/106—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties characterised by the chemical composition of the porous support
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/20—Polysulfones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
- C07C311/48—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups having nitrogen atoms of sulfonamide groups further bound to another hetero atom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2275—Heterogeneous membranes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
- H01B1/122—Ionic conductors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1027—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/103—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having nitrogen, e.g. sulfonated polybenzimidazoles [S-PBI], polybenzimidazoles with phosphoric acid, sulfonated polyamides [S-PA] or sulfonated polyphosphazenes [S-PPh]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1032—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2365/00—Characterised by the use of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Derivatives of such polymers
- C08J2365/02—Polyphenylenes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0082—Organic polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0088—Composites
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- Sustainable Energy (AREA)
- Sustainable Development (AREA)
- Life Sciences & Earth Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Dispersion Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Fuel Cell (AREA)
- Conductive Materials (AREA)
- Primary Cells (AREA)
- Secondary Cells (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Polyethers (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001105596 | 2001-04-04 | ||
| JP2001105596 | 2001-04-04 | ||
| JP2001297814 | 2001-09-27 | ||
| JP2001297814 | 2001-09-27 | ||
| JP2001376904A JP3969077B2 (ja) | 2001-04-04 | 2001-12-11 | 高分子電解質及びその製造方法 |
| JP2001376904 | 2001-12-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60225204D1 true DE60225204D1 (de) | 2008-04-10 |
| DE60225204T2 DE60225204T2 (de) | 2008-06-12 |
Family
ID=27346459
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60225204T Expired - Lifetime DE60225204T2 (de) | 2001-04-04 | 2002-04-02 | Polymerelektrolyt und Herstellungsverfahren dafür |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6939646B2 (de) |
| EP (1) | EP1248313B1 (de) |
| JP (1) | JP3969077B2 (de) |
| KR (1) | KR100810922B1 (de) |
| CA (1) | CA2379277C (de) |
| DE (1) | DE60225204T2 (de) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4052005B2 (ja) * | 2001-12-20 | 2008-02-27 | 住友化学株式会社 | 高分子電解質膜の製造法 |
| US7094490B2 (en) | 2002-05-13 | 2006-08-22 | Polyfuel, Inc. | Ion conductive block copolymers |
| US7202001B2 (en) | 2002-05-13 | 2007-04-10 | Polyfuel, Inc. | Sulfonated copolymer |
| US7354679B2 (en) | 2002-05-13 | 2008-04-08 | Polyfuel, Inc. | Ion conductive random copolymers |
| KR100968398B1 (ko) | 2002-06-28 | 2010-07-07 | 스미또모 가가꾸 가부시끼가이샤 | 고분자 적층막, 그 제조 방법 및 그 용도 |
| JP4345269B2 (ja) * | 2002-07-30 | 2009-10-14 | 住友化学株式会社 | 高分子積層膜、その製造方法およびその用途 |
| JP4241237B2 (ja) * | 2002-10-15 | 2009-03-18 | 住友化学株式会社 | ブロック共重合体およびその用途 |
| EP1465277A1 (de) * | 2003-03-19 | 2004-10-06 | HONDA MOTOR CO., Ltd. | Feststoff Polymerelektrolyt und Protonenleitende Membran |
| US6936377B2 (en) * | 2003-05-13 | 2005-08-30 | C. Glen Wensley | Card with embedded IC and electrochemical cell |
| US20040253520A1 (en) * | 2003-05-13 | 2004-12-16 | Wensley C. Glen | Polyimide matrix electrolyte and improved batteries therefrom |
| US20040229127A1 (en) | 2003-05-13 | 2004-11-18 | Wensley C. Glen | Polyimide matrix electrolyte |
| KR20060023174A (ko) * | 2003-06-30 | 2006-03-13 | 스미또모 가가꾸 가부시키가이샤 | 고분자 전해질 복합막, 그 제조 방법 및 그 용도 |
| CA2474314A1 (en) * | 2003-07-23 | 2005-01-23 | Takashi Ishizone | Copolymer and the use of the copolymer |
| US7390336B2 (en) * | 2003-07-29 | 2008-06-24 | Solicore, Inc. | Polyimide-based lithium metal battery |
| CN100549067C (zh) * | 2003-09-30 | 2009-10-14 | 住友化学株式会社 | 嵌段共聚物及其用途 |
| JP2005137972A (ja) * | 2003-11-04 | 2005-06-02 | Chisso Corp | ポリオレフィン樹脂製フィルター |
| GB0400626D0 (en) * | 2004-01-13 | 2004-02-11 | Johnson Matthey Plc | Polymer |
| JP2005209361A (ja) * | 2004-01-20 | 2005-08-04 | Ube Ind Ltd | 高分子電解質膜、その製造方法、燃料電池用膜−電極接合体及び燃料電池 |
| JP2005209465A (ja) * | 2004-01-22 | 2005-08-04 | Ube Ind Ltd | 高分子電解質膜の製造方法、高分子電解質膜、燃料電池用膜−電極接合体及び燃料電池 |
| JP4581477B2 (ja) * | 2004-05-12 | 2010-11-17 | トヨタ自動車株式会社 | 固体高分子電解質の製造方法、固体高分子電解質膜、及び燃料電池 |
| WO2006006357A1 (ja) * | 2004-07-12 | 2006-01-19 | Asahi Glass Company, Limited | 固体高分子型燃料電池用電解質膜、その製造方法及び固体高分子型燃料電池用膜電極接合体 |
| US20060147792A1 (en) * | 2004-07-22 | 2006-07-06 | Solicore, Inc. | Machining electrical power supply device for wire electrical discharge machining apparatus |
| JP4937755B2 (ja) * | 2004-10-15 | 2012-05-23 | パナソニック株式会社 | 燃料電池システム |
| US20070004900A1 (en) * | 2005-05-02 | 2007-01-04 | Gm Global Technology Operations, Inc. | Triblock copolymers with acidic groups |
| US7459505B2 (en) * | 2005-05-03 | 2008-12-02 | General Motors Corporation | Block copolymers with acidic groups |
| US7977394B2 (en) * | 2005-05-03 | 2011-07-12 | GM Global Technology Operations LLC | Triblock copolymers with acidic groups |
| KR100868802B1 (ko) | 2006-02-08 | 2008-11-17 | 고려대학교 산학협력단 | 복합 고분자 전해질 막, 그 제조방법 및 상기 전해질막을채용한 연료전지 |
| US7993792B2 (en) * | 2006-07-26 | 2011-08-09 | GM Global Technology Operations LLC | Polymer blocks for PEM applications |
| US8492460B2 (en) * | 2006-07-28 | 2013-07-23 | GM Global Technology Operations LLC | Fluorinated polymer blocks for PEM applications |
| US20110207000A1 (en) * | 2006-09-07 | 2011-08-25 | Jow T Richard | Nitrile additive for non-aqueous electrolyte rechargeable electrochemical cells |
| TW200847513A (en) * | 2006-11-27 | 2008-12-01 | Sumitomo Chemical Co | Method for manufacturing polyelectrolyte membrane, and polyelectrolyte membrane |
| WO2008111570A1 (ja) * | 2007-03-09 | 2008-09-18 | Sumitomo Chemical Company, Limited | 膜-電極接合体およびこれを用いた燃料電池 |
| TW200911879A (en) * | 2007-05-18 | 2009-03-16 | Polyfuel Inc | Bis(aryl)sulfonimide functionalized ion conducting polymers |
| CN102066468B (zh) * | 2008-04-24 | 2015-01-28 | 3M创新有限公司 | 质子传导材料 |
| JP5518573B2 (ja) * | 2010-05-26 | 2014-06-11 | 三菱マテリアル株式会社 | フッ素化スルホンイミド化合物の製造方法 |
| JP2014067605A (ja) * | 2012-09-26 | 2014-04-17 | Nitto Denko Corp | 高分子電解質膜およびそれを用いた燃料電池 |
| KR101998724B1 (ko) * | 2015-11-27 | 2019-10-01 | 주식회사 엘지화학 | 화합물, 이를 이용한 고분자, 이를 이용한 고분자 전해질막 |
| KR102074551B1 (ko) * | 2016-10-04 | 2020-02-06 | 주식회사 엘지화학 | 중합체 및 이를 포함하는 막 |
| KR102141267B1 (ko) * | 2016-11-04 | 2020-08-04 | 주식회사 엘지화학 | 방향족 고리를 포함하는 화합물 및 이를 포함하는 중합체 |
| JP6907558B2 (ja) * | 2017-01-25 | 2021-07-21 | 日本ゼオン株式会社 | ポリイオンコンプレックス、電気二重層キャパシタ用電解質および電気二重層キャパシタ |
| CN111834584A (zh) * | 2019-04-16 | 2020-10-27 | 住友化学株式会社 | 非水电解液二次电池用多孔层 |
| KR102386260B1 (ko) | 2020-03-25 | 2022-04-12 | 성균관대학교산학협력단 | 리튬 이차전지용 전해질막, 이를 적용한 리튬 이차전지용 막-전극 구조체의 제조방법 |
| CN114400371B (zh) * | 2021-12-13 | 2023-07-28 | 深圳市贝特瑞新能源技术研究院有限公司 | 聚合物电解质及锂离子电池 |
| CN114989437B (zh) * | 2022-05-09 | 2023-11-17 | 嘉庚创新实验室 | 聚合物及其制备方法以及阴离子交换膜 |
| WO2025165255A1 (en) * | 2024-02-01 | 2025-08-07 | Aramco Innovations LLC | Method and system for production of produced water and desalination treatment resins |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2187046A1 (fr) * | 1996-10-03 | 1998-04-03 | Alain Vallee | Sulfonylimidures et sulfonylmethylures, leur utilisation comme photoinitiateur |
| CA2683826C (fr) * | 1996-12-30 | 2013-06-11 | Hydro-Quebec | Sels d'anions pentacycliques ou derives de tetrazapentalene, et leurs utilisations comme materiaux a conduction ionique |
| US6288187B1 (en) * | 1997-07-25 | 2001-09-11 | Acep Inc. | Perfluorovinyl ionic compounds and their use in conductive materials |
| US6090895A (en) | 1998-05-22 | 2000-07-18 | 3M Innovative Properties Co., | Crosslinked ion conductive membranes |
| JP3307891B2 (ja) | 1998-12-22 | 2002-07-24 | 株式会社豊田中央研究所 | 高耐熱性高分子電解質及びこれを用いた電気化学デバイス |
-
2001
- 2001-12-11 JP JP2001376904A patent/JP3969077B2/ja not_active Expired - Fee Related
-
2002
- 2002-03-27 CA CA2379277A patent/CA2379277C/en not_active Expired - Fee Related
- 2002-03-29 US US10/108,441 patent/US6939646B2/en not_active Expired - Fee Related
- 2002-04-02 KR KR1020020018062A patent/KR100810922B1/ko not_active Expired - Fee Related
- 2002-04-02 DE DE60225204T patent/DE60225204T2/de not_active Expired - Lifetime
- 2002-04-02 EP EP02007287A patent/EP1248313B1/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| KR20020079424A (ko) | 2002-10-19 |
| US6939646B2 (en) | 2005-09-06 |
| EP1248313A2 (de) | 2002-10-09 |
| JP3969077B2 (ja) | 2007-08-29 |
| EP1248313A3 (de) | 2006-04-05 |
| JP2003173799A (ja) | 2003-06-20 |
| US20020187377A1 (en) | 2002-12-12 |
| CA2379277A1 (en) | 2002-10-04 |
| CA2379277C (en) | 2010-02-09 |
| KR100810922B1 (ko) | 2008-03-10 |
| EP1248313B1 (de) | 2008-02-27 |
| DE60225204T2 (de) | 2008-06-12 |
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