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DE602004006965D1 - Polymerisationskatalysatoren, organische übergangsmetallverbindungen, verfahren zur herstellung von polyolefinen - Google Patents

Polymerisationskatalysatoren, organische übergangsmetallverbindungen, verfahren zur herstellung von polyolefinen

Info

Publication number
DE602004006965D1
DE602004006965D1 DE602004006965T DE602004006965T DE602004006965D1 DE 602004006965 D1 DE602004006965 D1 DE 602004006965D1 DE 602004006965 T DE602004006965 T DE 602004006965T DE 602004006965 T DE602004006965 T DE 602004006965T DE 602004006965 D1 DE602004006965 D1 DE 602004006965D1
Authority
DE
Germany
Prior art keywords
transition metal
polyolefines
production
hydrogen
metal compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE602004006965T
Other languages
English (en)
Other versions
DE602004006965T2 (de
Inventor
Robert L Jones
Naka Seidel
Michael Elder
John A Ewen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Basell Polyolefine GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE10305227A external-priority patent/DE10305227A1/de
Application filed by Basell Polyolefine GmbH filed Critical Basell Polyolefine GmbH
Publication of DE602004006965D1 publication Critical patent/DE602004006965D1/de
Application granted granted Critical
Publication of DE602004006965T2 publication Critical patent/DE602004006965T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/003Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/03Multinuclear procatalyst, i.e. containing two or more metals, being different or not
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE602004006965T 2003-02-07 2004-02-05 Polymerisationskatalysatoren, organische übergangsmetallverbindungen, verfahren zur herstellung von polyolefinen Expired - Lifetime DE602004006965T2 (de)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DE10305227A DE10305227A1 (de) 2003-02-07 2003-02-07 Polymerisationskatalysatoren, Organoübergangsmetallverbindungen, Verfahren zur Herstellung von Polyolefinen und Polyolefine
DE10305227 2003-02-07
US45448203P 2003-03-13 2003-03-13
US454482P 2003-03-13
PCT/EP2004/001050 WO2004069881A1 (en) 2003-02-07 2004-02-05 Polymerization catalysts, organic transition metal compounds, process for preparing polyolefins and polyolefins

Publications (2)

Publication Number Publication Date
DE602004006965D1 true DE602004006965D1 (de) 2007-07-26
DE602004006965T2 DE602004006965T2 (de) 2008-02-21

Family

ID=32851843

Family Applications (1)

Application Number Title Priority Date Filing Date
DE602004006965T Expired - Lifetime DE602004006965T2 (de) 2003-02-07 2004-02-05 Polymerisationskatalysatoren, organische übergangsmetallverbindungen, verfahren zur herstellung von polyolefinen

Country Status (6)

Country Link
US (1) US7544749B2 (de)
EP (1) EP1590377B1 (de)
JP (1) JP2006516668A (de)
AT (1) ATE364637T1 (de)
DE (1) DE602004006965T2 (de)
WO (1) WO2004069881A1 (de)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7301040B2 (en) 2005-08-18 2007-11-27 Fina Technology, Inc. Bidentate catalyst for olefin polymerization, methods of forming such and products therefrom
US20130059991A1 (en) * 2010-02-12 2013-03-07 Sumitomo Chemical Company, Limited Catalyst for stereoselective olefin polymerization and method for manufacturing stereoselective polyolefin
CN103068831B (zh) * 2010-06-18 2016-08-03 雷蒙特亚特特拉维夫大学有限公司 Salalen配体及有机金属络合物
US8957171B2 (en) 2012-08-03 2015-02-17 Exxonmobil Chemical Patents Inc. Catalysts comprising salan ligands
EP2880096B1 (de) 2012-08-03 2018-01-03 ExxonMobil Chemical Patents Inc. Verfahren zur herstellung von polyalphaolefinen unter verwendung von modifizierten salankatalysatorverbindungen und damit hergestellte polyalphaolefine
CN104379680B (zh) 2012-08-03 2017-11-28 埃克森美孚化学专利公司 具有长链支化的乙烯基封端的聚烯烃
US9382349B2 (en) 2012-08-03 2016-07-05 Exxonmobil Chemical Patents Inc. Polyalphaolefins prepared using modified Salan catalyst compounds
US8952114B2 (en) 2012-08-03 2015-02-10 Exxonmobil Chemical Patents Inc. Halogenated catalysts comprising Salan ligands
EP2880006B1 (de) 2012-08-03 2017-12-20 ExxonMobil Chemical Patents Inc. Unsymmetrische katalysatoren mit salan-liganden
US9120879B2 (en) 2012-11-02 2015-09-01 Exxonmobil Chemical Patents Inc. Supported Salan catalysts
US8937137B2 (en) 2013-03-13 2015-01-20 Exxonmobil Chemical Patents Inc. Diphenylamine salan catalyst
US9200099B2 (en) 2013-06-20 2015-12-01 Exxonmobil Chemical Patents Inc. Salenol catalyst
CN105142777B (zh) 2013-06-20 2017-12-26 埃克森美孚化学专利公司 长桥Salen催化剂
US9150676B2 (en) 2013-06-20 2015-10-06 Exxonmobil Chemical Patents Inc. Thio-salalen catalyst
JP6336870B2 (ja) * 2013-09-30 2018-06-06 日本ポリプロ株式会社 ビフェノール化合物及びそれを用いるオレフィン重合用触媒並びにオレフィン重合体の製造方法
WO2015088819A1 (en) 2013-12-13 2015-06-18 Exxonmobil Chemical Patents Inc. Cyclopentadienyl-substituted salan catalysts
JP2015182992A (ja) * 2014-03-26 2015-10-22 三井化学株式会社 遷移金属化合物、オレフィン重合用触媒、および、オレフィン系重合体の製造方法
EP3126325B1 (de) 2014-03-31 2019-04-24 ExxonMobil Chemical Patents Inc. Phenylenverbrückte salalenkatalysatoren
WO2017130103A1 (en) * 2016-01-25 2017-08-03 Reliance Industries Limited Process for preparing a transition metal-schiff base imine ligand complex

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2141797T5 (es) 1990-01-02 2008-06-01 Exxonmobil Chemical Patents Inc. Catalizadores ionicos de metalocenos soportados para la polimerizacion de olefinas.
KR100378973B1 (ko) 1994-06-24 2003-08-19 엑손모빌 케미칼 패턴츠 인코포레이티드 중합촉매시스템, 이의 제조방법 및 용도
KR100405780B1 (ko) * 1996-04-22 2004-03-30 닛뽕폴리올레핀가부시키가이샤 폴리올레핀제조용촉매및폴리올레핀의제조방법
EP0931099A1 (de) 1997-03-07 1999-07-28 Basell Polyolefine GmbH Verfahren zur herstellung von olefinpolymerisaten mit erhöhtem schmelzpunkt
TWI246520B (en) * 1997-04-25 2006-01-01 Mitsui Chemicals Inc Processes for olefin polymerization
DE19733017A1 (de) * 1997-07-31 1999-02-04 Hoechst Ag Chemische Verbindung
US6521561B1 (en) 1998-05-01 2003-02-18 President And Fellows Of Harvard College Main-group metal based asymmetric catalysts and applications thereof
DE19833170A1 (de) * 1998-07-23 2000-01-27 Targor Gmbh Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz
CN100340568C (zh) 1998-11-25 2007-10-03 塔戈尔股份有限公司 茂金属一卤化物
WO2002012171A1 (en) * 2000-08-05 2002-02-14 Korea Institute Of Science And Technology Method for preparing chiral compound by asymmetric ring opening reactions of epoxides
US7235618B2 (en) * 2000-08-22 2007-06-26 Exxonmobil Chemical Patents Inc. Polypropylene polymers
JP2002179724A (ja) * 2000-12-14 2002-06-26 Tonen Chem Corp マンガン錯体含有触媒成分および触媒並びにそれを用いるポリオレフィンの製造方法
JP2002268030A (ja) * 2001-03-07 2002-09-18 Fuji Xerox Co Ltd 光書き込み型記録媒体
JP2002308843A (ja) * 2001-04-06 2002-10-23 Mitsubishi Rayon Co Ltd オレフィン類重合触媒及びオレフィン系重合体の製造方法
JP2002338616A (ja) * 2001-05-14 2002-11-27 Sumitomo Chem Co Ltd オレフィン重合用触媒の評価方法

Also Published As

Publication number Publication date
ATE364637T1 (de) 2007-07-15
US20060100092A1 (en) 2006-05-11
EP1590377A1 (de) 2005-11-02
DE602004006965T2 (de) 2008-02-21
WO2004069881A1 (en) 2004-08-19
JP2006516668A (ja) 2006-07-06
EP1590377B1 (de) 2007-06-13
US7544749B2 (en) 2009-06-09

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