DE59900461D1 - METHOD FOR THE ELECTROLYTIC REGENERATION OF POLLUTED RHODIUM SOLUTIONS - Google Patents
METHOD FOR THE ELECTROLYTIC REGENERATION OF POLLUTED RHODIUM SOLUTIONSInfo
- Publication number
- DE59900461D1 DE59900461D1 DE59900461T DE59900461T DE59900461D1 DE 59900461 D1 DE59900461 D1 DE 59900461D1 DE 59900461 T DE59900461 T DE 59900461T DE 59900461 T DE59900461 T DE 59900461T DE 59900461 D1 DE59900461 D1 DE 59900461D1
- Authority
- DE
- Germany
- Prior art keywords
- rhodium
- solution
- solutions
- cathode area
- hexavalent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D21/00—Processes for servicing or operating cells for electrolytic coating
- C25D21/16—Regeneration of process solutions
- C25D21/18—Regeneration of process solutions of electrolytes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Removal Of Specific Substances (AREA)
Abstract
The invention relates to a method for electrically regenerating rhodium solutions, designed especially for regenerating rhodium solutions containing sulphuric acid and/or phosphoric acid or rhodium chloride solutions. The solution to be regenerated is introduced in the anode area (12) of an electrolytic cell (10), which is separated from the associated cathode area (14) by an ion exchange membrane (16), said cathode area being filled with a dilute acid having a good conductivity. The rhodium solution pH is increased so as to reach a value greater than 10, preferably in the range from 10 to 14, by adding an alkaline solution, i.e. a concentrated hydroxide potassium solution. Electrolysis is carried out at electric densities that are so high that the trivalent rhodium of the rhodium solution is oxidised to form an hexavalent rhodium, and possible impurities are depleted by the ion exchange membrane (16) in the catholytes. Hexavalent rhodium is transferred in the cathode area at a speed slightly smaller than trivalent rhodium, and therefore no noticeable rhodium depletion can be observed. This is particularly true when pH during electrolysis is maintained at a value permanently greater than 1.5 by means of proper addition of alkaline solution.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19804534A DE19804534C1 (en) | 1998-02-05 | 1998-02-05 | Impure rhodium solution is regenerated by anodic oxidation in a cell with a cation exchange membrane |
| PCT/DE1999/000316 WO1999040238A2 (en) | 1998-02-05 | 1999-02-05 | Method for electrically regenerating contaminated rhodium solutions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE59900461D1 true DE59900461D1 (en) | 2002-01-10 |
Family
ID=7856724
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19804534A Expired - Fee Related DE19804534C1 (en) | 1998-02-05 | 1998-02-05 | Impure rhodium solution is regenerated by anodic oxidation in a cell with a cation exchange membrane |
| DE59900461T Expired - Fee Related DE59900461D1 (en) | 1998-02-05 | 1999-02-05 | METHOD FOR THE ELECTROLYTIC REGENERATION OF POLLUTED RHODIUM SOLUTIONS |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19804534A Expired - Fee Related DE19804534C1 (en) | 1998-02-05 | 1998-02-05 | Impure rhodium solution is regenerated by anodic oxidation in a cell with a cation exchange membrane |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP1051541B1 (en) |
| AT (1) | ATE209709T1 (en) |
| AU (1) | AU2920599A (en) |
| DE (2) | DE19804534C1 (en) |
| WO (1) | WO1999040238A2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI818791B (en) * | 2022-11-02 | 2023-10-11 | 環球晶圓股份有限公司 | Processing system and processing method for electroless nickel plating solution |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB662299A (en) * | 1949-07-08 | 1951-12-05 | Mond Nickel Co Ltd | A process for the purification of rhodium |
| US3375179A (en) * | 1964-10-29 | 1968-03-26 | Litton Systems Inc | Method of anodizing beryllium and product thereof |
| DE1592548A1 (en) * | 1966-03-29 | 1971-01-28 | Ustav Nerostnych Surovin | Process for the production of rhodium concentrate from its acidic solutions and an operating facility for this purpose |
| GB1491521A (en) * | 1975-01-07 | 1977-11-09 | Swarsab Mining | Separation and purification of rhodium |
| ZA775358B (en) * | 1977-09-06 | 1979-04-25 | Nat Inst Metallurg | The recovery and purification of rhodium |
| FR2616810B1 (en) * | 1987-03-25 | 1989-08-18 | Rhone Poulenc Sante | ELECTROCHEMICAL PROCESS FOR RECOVERING METAL RHODIUM FROM AQUEOUS SOLUTIONS OF USED CATALYSTS |
-
1998
- 1998-02-05 DE DE19804534A patent/DE19804534C1/en not_active Expired - Fee Related
-
1999
- 1999-02-05 AT AT99910109T patent/ATE209709T1/en not_active IP Right Cessation
- 1999-02-05 EP EP99910109A patent/EP1051541B1/en not_active Expired - Lifetime
- 1999-02-05 DE DE59900461T patent/DE59900461D1/en not_active Expired - Fee Related
- 1999-02-05 WO PCT/DE1999/000316 patent/WO1999040238A2/en not_active Ceased
- 1999-02-05 AU AU29205/99A patent/AU2920599A/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| WO1999040238A3 (en) | 1999-09-30 |
| EP1051541B1 (en) | 2001-11-28 |
| EP1051541A2 (en) | 2000-11-15 |
| DE19804534C1 (en) | 1999-06-24 |
| HK1034544A1 (en) | 2001-10-26 |
| WO1999040238A2 (en) | 1999-08-12 |
| AU2920599A (en) | 1999-08-23 |
| ATE209709T1 (en) | 2001-12-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |