DE59805713D1 - GRANULAR DETERGENT - Google Patents
GRANULAR DETERGENTInfo
- Publication number
- DE59805713D1 DE59805713D1 DE59805713T DE59805713T DE59805713D1 DE 59805713 D1 DE59805713 D1 DE 59805713D1 DE 59805713 T DE59805713 T DE 59805713T DE 59805713 T DE59805713 T DE 59805713T DE 59805713 D1 DE59805713 D1 DE 59805713D1
- Authority
- DE
- Germany
- Prior art keywords
- detergents
- temperatures
- later stage
- essentially free
- bleaching agents
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003599 detergent Substances 0.000 title abstract 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract 3
- 239000007844 bleaching agent Substances 0.000 abstract 2
- 150000007524 organic acids Chemical class 0.000 abstract 2
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 235000005985 organic acids Nutrition 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C11D17/065—High-density particulate detergent compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2082—Polycarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention relates to the use of organic acids, especially citric acid, added separately or at a later stage, to help remove bleachable stains on textiles if the detergent used is essentially free of bleaching agents. To this end, granular detergents are used which have an apparent density of between 650 g/l and 1100 g/l, contain anionic and/or nonionic tensides as well as builders, and between 1 and 15 weight percent of an organic acid which is added separately or at later stage, said detergents being essentially free of bleaching agents. The advantages of such detergents are especially evident when said detergents are used for machine washing at temperatures of up to 60 DEG C and in particular at temperatures as low as 30 DEG C to 40 DEG C.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19723616A DE19723616A1 (en) | 1997-06-05 | 1997-06-05 | Granular detergent |
| PCT/EP1998/003109 WO1998055574A1 (en) | 1997-06-05 | 1998-05-27 | Granular detergent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE59805713D1 true DE59805713D1 (en) | 2002-10-31 |
Family
ID=7831510
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19723616A Ceased DE19723616A1 (en) | 1997-06-05 | 1997-06-05 | Granular detergent |
| DE59805713T Expired - Lifetime DE59805713D1 (en) | 1997-06-05 | 1998-05-27 | GRANULAR DETERGENT |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19723616A Ceased DE19723616A1 (en) | 1997-06-05 | 1997-06-05 | Granular detergent |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0986629B2 (en) |
| JP (1) | JP2002502457A (en) |
| AT (1) | ATE224942T1 (en) |
| DE (2) | DE19723616A1 (en) |
| ES (1) | ES2183384T5 (en) |
| WO (1) | WO1998055574A1 (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19854083A1 (en) * | 1998-11-24 | 2000-05-25 | Henkel Kgaa | Detergent containing citric acid |
| GC0000084A (en) * | 1998-12-12 | 2004-06-30 | Lg Household & Health Care Ltd | Process for preparing laundry powder detergents. |
| GB0006037D0 (en) | 2000-03-13 | 2000-05-03 | Unilever Plc | Detergent composition |
| GB0115552D0 (en) | 2001-05-16 | 2001-08-15 | Unilever Plc | Particulate laundry detergent composition containing zeolite |
| DE10242222A1 (en) * | 2002-09-12 | 2004-03-25 | Henkel Kgaa | Mechanically compacted washing or detergent agents containing neutralizable organic polycarboxylic acids are given improved odor values by having specific non-water-soluble builder content and pH |
| US7863237B2 (en) * | 2004-03-08 | 2011-01-04 | Ecolab Inc. | Solid cleaning products |
| KR100817687B1 (en) | 2004-09-10 | 2008-03-27 | 주식회사 엘지생활건강 | Low Density Powder Detergent Composition Containing Acidic Water Soluble Polymer and Organic Acid and Method for Producing The Same |
| WO2020109227A1 (en) | 2018-11-28 | 2020-06-04 | Unilever N.V. | Large particles |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1569617A (en) † | 1976-03-08 | 1980-06-18 | Procter & Gamble | Liquid detergent composition |
| JPS6262899A (en) † | 1985-09-13 | 1987-03-19 | 花王株式会社 | High density granular detergent composition |
| DE3812455A1 (en) * | 1987-04-15 | 1988-10-27 | Sandoz Ag | Bleach substitute for detergents |
| GB8906089D0 (en) * | 1989-03-16 | 1989-04-26 | Monsanto Europe Sa | Improved detergent compositions |
| EP0456315B1 (en) * | 1990-05-08 | 1996-08-21 | The Procter & Gamble Company | Low pH granular laundry detergent compositions containing aluminosilicate citric acid and carbonate builders |
| DE4024759A1 (en) * | 1990-08-03 | 1992-02-06 | Henkel Kgaa | BLEACH ACTIVATORS IN GRANULATE FORM |
| EP0523681B1 (en) † | 1991-07-17 | 1998-11-04 | Johannes Dr. Behrensdorf | Automatic dishwashing detergent composition and method for producing the same |
| GB9120657D0 (en) * | 1991-09-27 | 1991-11-06 | Unilever Plc | Detergent powders and process for preparing them |
| US5378388A (en) † | 1993-06-25 | 1995-01-03 | The Procter & Gamble Company | Granular detergent compositions containing selected builders in optimum ratios |
| DE4325787A1 (en) † | 1993-07-31 | 1995-02-02 | Henkel Kgaa | Detergent with an acidic component |
| DE4402051A1 (en) * | 1994-01-25 | 1995-07-27 | Henkel Kgaa | Builder for detergents or cleaners |
| GB2288187A (en) * | 1994-03-31 | 1995-10-11 | Procter & Gamble | Detergent composition |
| ID16213A (en) † | 1996-03-11 | 1997-09-11 | Kao Corp | COMPOSITION OF GRAIN DETERGENTS TO WASH CLOTHING |
| DE19638599A1 (en) * | 1996-09-20 | 1998-03-26 | Henkel Kgaa | Process for producing a particulate detergent or cleaning agent |
-
1997
- 1997-06-05 DE DE19723616A patent/DE19723616A1/en not_active Ceased
-
1998
- 1998-05-27 AT AT98930735T patent/ATE224942T1/en active
- 1998-05-27 DE DE59805713T patent/DE59805713D1/en not_active Expired - Lifetime
- 1998-05-27 WO PCT/EP1998/003109 patent/WO1998055574A1/en not_active Ceased
- 1998-05-27 EP EP98930735A patent/EP0986629B2/en not_active Expired - Lifetime
- 1998-05-27 ES ES98930735T patent/ES2183384T5/en not_active Expired - Lifetime
- 1998-05-27 JP JP50142599A patent/JP2002502457A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JP2002502457A (en) | 2002-01-22 |
| ES2183384T3 (en) | 2003-03-16 |
| WO1998055574A1 (en) | 1998-12-10 |
| ES2183384T5 (en) | 2007-11-16 |
| ATE224942T1 (en) | 2002-10-15 |
| DE19723616A1 (en) | 1998-12-10 |
| EP0986629B1 (en) | 2002-09-25 |
| EP0986629B2 (en) | 2007-05-16 |
| EP0986629A1 (en) | 2000-03-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8363 | Opposition against the patent | ||
| 8366 | Restricted maintained after opposition proceedings | ||
| 8327 | Change in the person/name/address of the patent owner |
Owner name: HENKEL AG & CO. KGAA, 40589 DUESSELDORF, DE |