DE546097C - Process for the protection of wool, fur, hair and the like Like. Against textile pests - Google Patents
Process for the protection of wool, fur, hair and the like Like. Against textile pestsInfo
- Publication number
- DE546097C DE546097C DEI38621D DEI0038621D DE546097C DE 546097 C DE546097 C DE 546097C DE I38621 D DEI38621 D DE I38621D DE I0038621 D DEI0038621 D DE I0038621D DE 546097 C DE546097 C DE 546097C
- Authority
- DE
- Germany
- Prior art keywords
- fur
- hair
- wool
- protection
- against textile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 241000607479 Yersinia pestis Species 0.000 title claims description 5
- 210000004209 hair Anatomy 0.000 title claims description 5
- 210000002268 wool Anatomy 0.000 title claims description 5
- 238000000034 method Methods 0.000 title claims description 4
- 239000004753 textile Substances 0.000 title claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 4
- 239000002253 acid Chemical group 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 150000005840 aryl radicals Chemical class 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims description 2
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- 239000011593 sulfur Substances 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 1
- UMGDCJDMYOKAJW-UHFFFAOYSA-N aminothiocarboxamide Natural products NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims 1
- 239000000126 substance Substances 0.000 description 4
- 150000003585 thioureas Chemical class 0.000 description 3
- 238000001035 drying Methods 0.000 description 2
- 241000907223 Bruchinae Species 0.000 description 1
- 241000258916 Leptinotarsa decemlineata Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- ZRKIRUJJBNOUHQ-UHFFFAOYSA-N N-carbamothioyl-5-phenylpentanamide Chemical compound C1(=CC=CC=C1)CCCCC(=O)NC(=S)N ZRKIRUJJBNOUHQ-UHFFFAOYSA-N 0.000 description 1
- FULZLIGZKMKICU-UHFFFAOYSA-N N-phenylthiourea Chemical compound NC(=S)NC1=CC=CC=C1 FULZLIGZKMKICU-UHFFFAOYSA-N 0.000 description 1
- 150000001722 carbon compounds Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- DUCKXCGALKOSJF-UHFFFAOYSA-N pentanoyl pentanoate Chemical compound CCCCC(=O)OC(=O)CCCC DUCKXCGALKOSJF-UHFFFAOYSA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Indole Compounds (AREA)
Description
Verfahren zum Schutze von Wolle, Pelzwerk, Haaren u. dgl. gegen Textilschädlinge Durch Patent 534 6;6 ist ein Verfahren zum Schutze von Wolle, Pelzwerk, Haaren u. dgl. egen Textilschädlinge unter Schutz gestellt.' Es besteht in der Verwendung von Thioharnstoffen der Formel worin R ein Alkyl-. Cycloall:vl-, Arall;yl-oder Arylrest und k1 ein Säurerest ist.Method for the protection of wool, fur, hair and the like against textile pests Patent 534 6; 6 provides protection for a method for the protection of wool, fur, hair and the like against textile pests. ' It consists in using thioureas of the formula wherein R is an alkyl. Cycloall: vl, arall; yl or aryl radical and k1 is an acid radical.
Es wurde nun weiter gefunden, daß Abkömmlinge des Thioharnstoffes, welche an einem Stickstoffatom einen Alkyl-, Cycloalkyl-. Aralkyl- oder Arylrest und am gleichen Stickstoffatom oder am Schwefel einen Säurerest enthalten, überraschender«,@eise ebenfalls sehr wirksame Schutzmittel gegen Fraßschäden durch Motten vorstellen. Derartige Verbindungen sind z. B. beschrieben im Chemischen Zentralblatt 19o2, I. Seite 13oo, und Chemischen Zentralblatt 19.08, I, Seite 1541.It has now been found that derivatives of thiourea, which on a nitrogen atom is an alkyl, cycloalkyl. Aralkyl or aryl radical and contain an acid residue on the same nitrogen atom or on sulfur, surprisingly «, @ise also introduce very effective means of protection against feeding damage by moths. Such compounds are e.g. B. described in Chemisches Zentralblatt 19o2, I. Page 13oo, and Chemischen Zentralblatt 19.08, I, page 1541.
Thioharnstoffe sind bisher als solche oder im kolloidalen Zustande ausschließlich zur Bekämpfung von Pflanzenschädlingen verwendet worden. Wenn sich ein chemischer Stoff aber zur Bekämpfung von Samenkäfern. Kartoffelkäfern usw. eignet, so war dadurch keineswegs gegeben, daß ein derartiger Stoff auch befähigt ist, tierischem Substrat, wie Wolle, Pelzwerk, Haaren usw., Schutz gegen Mottenfraß zu gewähren.Thioureas have hitherto been as such or in the colloidal state used exclusively to control plant pests. If a chemical but used to control seed beetles. Colorado beetles etc. are suitable, so it was by no means given that such a substance is also capable of being animal Substrate, such as wool, fur, hair, etc., to provide protection against moth damage.
Beispiel i.Example i.
Die Ware wird mit einer Lösung des nach Zentralblatt igoa, I, Seite i3oo, erhältlichen unsymmetrischen Pheny icapronylpseudothioharnstoffs so behandelt, daß i bis :2 °/o der Substanz nach dem Trocknen auf der Ware zurückbleibt, worauf sie dauernd gegen Mottenfraß geschützt ist. Ebenso verhält sich das in Richters Chemie der Kohlenstoff-verbindungen, i i. Auflage, Band a, Seite i o4, obengenannte Acetylderivat vom Schmelzpunkt 145,-Beispiel Die Ware wird mit einer Lösung von asymmetrischem Phenylvalerylthioharnstoff (hergestellt aus Monophenylthioharnstoff und Valeriansäureanhvdrid gemäß Berichte der deutschen chemischen Gesellschaft, Band 32, Seite 3658) in organischen Lösungsmitteln so behandelt, daß i °/o des Produkts nach dem Trocknen auf der Ware zurückbleibt, wonach diese gegen Mottenfraß geschützt ist. Beispiel 3 Bringt man SAcetylallylthioharnstoff (Zentralblatt i 9o8, Band I, Seite 1542, Zeile i i von oben), F. P. io3 bis i04°, in ähnlicher Weise auf die Ware, so daß i bis a °/o auf dieser zurückbleibt, so werden die Mottenraupen dauernd vom Fraß des imprägnierten Gegenstandes abgehalten.The goods are treated with a solution of the asymmetrical Pheny icapronylpseudothiourea obtainable according to Zentralblatt igoa, I, page 130, in such a way that 1 to 2% of the substance remains on the goods after drying, whereupon they are permanently protected against moth damage. The same applies to Richter's chemistry of carbon compounds, i i. Edition, Volume a, page 104, the above-mentioned acetyl derivative with a melting point of 145, -Example The goods are treated with a solution of asymmetrical phenylvalerylthiourea (made from monophenylthiourea and valeric anhydride according to reports from the German Chemical Society, Volume 32, page 3658) in organic solvents that i ° / o of the product remains on the goods after drying, after which they are protected against moth damage. Example 3 Add SA-acetylallylthiourea (Zentralblatt i 908, volume I, page 1542, line ii from above), FP io3 to i04 °, in a similar way on the goods, so that i to a ° / o remains on this, so the moth caterpillars are constantly being eaten by the impregnated object held.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEI38621D DE546097C (en) | 1928-11-24 | 1929-07-06 | Process for the protection of wool, fur, hair and the like Like. Against textile pests |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEI36214D DE534676C (en) | 1928-11-24 | 1928-11-24 | Process for the protection of wool, fur, hair and the like Like. Against textile pests |
| DEI38621D DE546097C (en) | 1928-11-24 | 1929-07-06 | Process for the protection of wool, fur, hair and the like Like. Against textile pests |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE546097C true DE546097C (en) | 1932-03-10 |
Family
ID=10209618
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEI36214D Expired DE534676C (en) | 1928-11-24 | 1928-11-24 | Process for the protection of wool, fur, hair and the like Like. Against textile pests |
| DEI38621D Expired DE546097C (en) | 1928-11-24 | 1929-07-06 | Process for the protection of wool, fur, hair and the like Like. Against textile pests |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEI36214D Expired DE534676C (en) | 1928-11-24 | 1928-11-24 | Process for the protection of wool, fur, hair and the like Like. Against textile pests |
Country Status (3)
| Country | Link |
|---|---|
| DE (2) | DE534676C (en) |
| FR (2) | FR685123A (en) |
| GB (2) | GB326567A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE850535C (en) * | 1948-10-02 | 1952-09-25 | Gerlach Gmbh E | Rat and mouse poison |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL191706A (en) * | 1952-01-08 | |||
| US2801200A (en) * | 1952-01-08 | 1957-07-30 | Shell Dev | Method of protecting plants from fungi by employing nu-haloacyl urea |
-
1928
- 1928-11-24 DE DEI36214D patent/DE534676C/en not_active Expired
- 1928-12-20 GB GB3769728A patent/GB326567A/en not_active Expired
-
1929
- 1929-07-06 DE DEI38621D patent/DE546097C/en not_active Expired
- 1929-08-08 GB GB2430729A patent/GB337823A/en not_active Expired
- 1929-11-18 FR FR685123D patent/FR685123A/en not_active Expired
-
1930
- 1930-07-01 FR FR39013D patent/FR39013E/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE850535C (en) * | 1948-10-02 | 1952-09-25 | Gerlach Gmbh E | Rat and mouse poison |
Also Published As
| Publication number | Publication date |
|---|---|
| FR39013E (en) | 1931-08-26 |
| FR685123A (en) | 1930-07-04 |
| GB326567A (en) | 1930-03-20 |
| GB337823A (en) | 1930-11-10 |
| DE534676C (en) | 1931-09-30 |
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