DE484196C - Process for the electrolytic extraction of pure aluminum in dense form from raw aluminum, alloys and the like. like - Google Patents
Process for the electrolytic extraction of pure aluminum in dense form from raw aluminum, alloys and the like. likeInfo
- Publication number
- DE484196C DE484196C DEA49322D DEA0049322D DE484196C DE 484196 C DE484196 C DE 484196C DE A49322 D DEA49322 D DE A49322D DE A0049322 D DEA0049322 D DE A0049322D DE 484196 C DE484196 C DE 484196C
- Authority
- DE
- Germany
- Prior art keywords
- aluminum
- electrolyte
- dense
- alloys
- raw
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052782 aluminium Inorganic materials 0.000 title claims description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims description 15
- 238000000034 method Methods 0.000 title claims description 7
- 229910045601 alloy Inorganic materials 0.000 title claims description 3
- 239000000956 alloy Substances 0.000 title claims description 3
- 238000000605 extraction Methods 0.000 title description 2
- 239000003792 electrolyte Substances 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 4
- 238000000151 deposition Methods 0.000 claims description 3
- 230000008021 deposition Effects 0.000 claims description 3
- 150000004820 halides Chemical class 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims description 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 2
- 238000004090 dissolution Methods 0.000 claims description 2
- 238000005363 electrowinning Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 230000002349 favourable effect Effects 0.000 claims 2
- 230000000996 additive effect Effects 0.000 claims 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 229910000510 noble metal Inorganic materials 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- -1 halogen salts Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/24—Refining
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Description
Verfahren zur elektrolytischen Gewinnung von reinem Aluminium in dichter Form aus Rohaluminium, Legierungen u. dgl. In einem früherem. Patent ist ein Verfahren zur elektrolytischen Gewinnung von reinem Aluminium durch Raffmation von Rohaluminium, Aluminiumlegierungen o. dgl. beschrieben, bei dem sowohl die aus dem zu raffinierenden, Aluminium enthaltenden Gut bestehenden Anoden wie auch die Kathoden in fester Form und in senkrechter Anordnung angewendet werden unter Benutzung eines Elektrolytbades, dessen Schmelzpunkt niedriger als derjenige der Elektroden ist, und der aus Halogensalzen von Aluminium und von Alkali- undloder Erdalkalimetallen besteht. Beim Arbeiten nach diesem Verfahren ist es wichtig, den Aluminiumniederschlag auf der Kathode in möglichst dichter Form bei genügender Dicke zu erhalten. Dies wird begünstigt durch die vorliegende Erfindung. Es wurde nämlich gefunden, daß durch einen gewissen Gehalt an Elektrolyten an Fremdstoffen verschiedener Art ein Herauswachsen des Kathodenniederschlages verhindert und ein dichter Niederschlag erzielt wird. Als Zusätze, welche diese Wirkung ergeben, kommen solche Metalle oder Metallverbindungen oder Salze in Frage, die edler sind als Aluminium, und deren Abscheidungs- bzw. Auflösungspotential . in dem betreffenden Elektrolyten sich von demjenigen des Aluminiums um nicht mehr als o,6 Volt unterscheidet. Solche Metalle sind beispielsweise Mangan, Zink, Cadmium, Blei, Chrom, Zinn, Kupfer, Eisen.Process for the electrowinning of pure aluminum in dense Mold made from raw aluminum, alloys and the like. Patent is a process for the electrolytic extraction of pure aluminum by refining raw aluminum, Aluminum alloys or the like described, in which both the from the to be refined, Aluminum-containing good anodes as well as the cathodes in solid form and can be used in a vertical arrangement using an electrolyte bath, the melting point of which is lower than that of the electrodes and that of halogen salts of aluminum and of alkali and / or alkaline earth metals. At work After this process it is important to keep the aluminum deposited on the cathode in the most dense form possible with sufficient thickness. This is favored by the present invention. It was found that by a certain Content of electrolytes of foreign substances of various kinds an outgrowth of the cathode precipitate prevented and a dense precipitation is achieved. As additions which these Result, such metals or metal compounds or salts come into question, which are more noble than aluminum, and their deposition or dissolution potential. in the electrolyte in question no longer differs from that of aluminum than 0.6 volts. Such metals are, for example, manganese, zinc, cadmium, Lead, chrome, tin, copper, iron.
Diese Zusätze zum Elektrolyten können auf verschiedene Weise in ihn hineingebracht werden. Entweder werden sie ihm unmittelbar zugesetzt, oder das Metall, aus welchem das betreffende Halogenid gebildet wird, wird als besondere Hilfsanode eingeführt. Dabei hat man es in der Hand, den Gehalt an dem Halogenid des Hilfsmetalles durch das Potential bzw. die Stromstärke des Hilfsstromkreises zu regeln. Zur Erzielung vollständig dichter Niederschläge genügt .bereits ein Gehalt von o,i bis o,5 ofodes Zusatzmetalles.These additives to the electrolyte can be in it in several ways be brought in. Either they are added to it immediately, or the metal, from which the halide in question is formed is called a special auxiliary anode introduced. You have it in hand, the content of the halide of the auxiliary metal to be regulated by the potential or the current strength of the auxiliary circuit. To achieve Completely dense precipitation is sufficient. A content of 0.1 to 0.5 ofodes is sufficient Additional metal.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEA49322D DE484196C (en) | 1926-11-22 | 1926-11-23 | Process for the electrolytic extraction of pure aluminum in dense form from raw aluminum, alloys and the like. like |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE280881X | 1926-11-22 | ||
| DEA49322D DE484196C (en) | 1926-11-22 | 1926-11-23 | Process for the electrolytic extraction of pure aluminum in dense form from raw aluminum, alloys and the like. like |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE484196C true DE484196C (en) | 1929-10-10 |
Family
ID=25773948
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEA49322D Expired DE484196C (en) | 1926-11-22 | 1926-11-23 | Process for the electrolytic extraction of pure aluminum in dense form from raw aluminum, alloys and the like. like |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE484196C (en) |
-
1926
- 1926-11-23 DE DEA49322D patent/DE484196C/en not_active Expired
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