DE466046C - Process for the production of drying agents for varnishes, lacquers and paints - Google Patents
Process for the production of drying agents for varnishes, lacquers and paintsInfo
- Publication number
- DE466046C DE466046C DEB131603D DEB0131603D DE466046C DE 466046 C DE466046 C DE 466046C DE B131603 D DEB131603 D DE B131603D DE B0131603 D DEB0131603 D DE B0131603D DE 466046 C DE466046 C DE 466046C
- Authority
- DE
- Germany
- Prior art keywords
- cobalt
- varnishes
- production
- bismuth
- paints
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002966 varnish Substances 0.000 title claims description 7
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 238000000034 method Methods 0.000 title claims description 6
- 239000003973 paint Substances 0.000 title claims description 5
- 239000004922 lacquer Substances 0.000 title claims description 3
- 239000002274 desiccant Substances 0.000 title description 5
- 229910017052 cobalt Inorganic materials 0.000 claims description 13
- 239000010941 cobalt Substances 0.000 claims description 13
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 13
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 8
- 229910052797 bismuth Inorganic materials 0.000 claims description 7
- 239000011347 resin Substances 0.000 claims description 7
- 229920005989 resin Polymers 0.000 claims description 7
- 239000003921 oil Substances 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims 2
- 235000021388 linseed oil Nutrition 0.000 description 4
- 239000000944 linseed oil Substances 0.000 description 4
- QYIGOGBGVKONDY-UHFFFAOYSA-N 1-(2-bromo-5-chlorophenyl)-3-methylpyrazole Chemical compound N1=C(C)C=CN1C1=CC(Cl)=CC=C1Br QYIGOGBGVKONDY-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- 235000004347 Perilla Nutrition 0.000 description 2
- 244000124853 Perilla frutescens Species 0.000 description 2
- 229940011182 cobalt acetate Drugs 0.000 description 2
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- SVMCDCBHSKARBQ-UHFFFAOYSA-N acetic acid;cobalt Chemical compound [Co].CC(O)=O SVMCDCBHSKARBQ-UHFFFAOYSA-N 0.000 description 1
- 150000001621 bismuth Chemical class 0.000 description 1
- 229910000416 bismuth oxide Inorganic materials 0.000 description 1
- 150000001869 cobalt compounds Chemical class 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000029142 excretion Effects 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000010491 poppyseed oil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F9/00—Compounds to be used as driers, i.e. siccatives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Description
Verfahren zur Herstellung von Trockenstoffen für Firnisse, Lacke und Farben Zur Herstellung von Trockenstoffen (Sikkativen) werden bisher Blei, Mangan und Kobaltverbindungen, entweder für sich allein oder in 'Mischung miteinander, verwendet. Kobaltsikkative bewirken eine besonders schnelle Trocknung der öle und dementsprechend der Lacke und Farben oder Firnisse, wobei der Feuchtigkeitsgrad der Luft nicht stört. Die mit Kobaltsikkativen erhaltene Elastizität und Weichheit der getrockneten Schichten ist nicht immer erwünscht. Wenn man härtere Anstriche haben will, setzt man daher Bleisikkativ e zu, wobei aber der Übelstand von Trübungen durch Ausscheidung von fettsaurem Blei u. dgl. eintritt. Auch ohne die Trübungen zeigt sich eine Vergröberung der Dispersion.Process for the production of drying agents for varnishes, lacquers and Colors For the production of dry substances (siccatives) lead and manganese are used up to now and cobalt compounds, either on their own or in a mixture with one another, used. Cobalt desiccants cause the oils and to dry particularly quickly accordingly the varnishes and paints or varnishes, with the degree of moisture the air does not disturb. The elasticity and softness obtained with cobalt desiccants the dried layers is not always desirable. If you have tougher paints want to have, one therefore adds lead siccative e, but with the disadvantage of opacities occurs through excretion of fatty acid lead and the like. Even without the cloudiness shows a coarsening of the dispersion.
Das vorliegende Verfahren zur Herstellung von Kobalttrockenstoffen bezweckt, die Härte von Kobaltfirnissen zu steigern, ohne daß die sonstigen Vorzüge der Kobaltfirnisse verlorengehen. Das Verfahren besteht darin, daß man zu den Kobalttrockenstoifen Wismutsalze hinzugibt.The present process for the manufacture of cobalt solids aims to increase the hardness of cobalt varnishes without losing the other benefits the cobalt varnishes are lost. The process consists of going to the cobalt desiccants Add bismuth salts.
Die Menge des zugesetzten Wismuts kann schwanken und hängt im wesentlichen davon ab, welchen Grad der Härte man für den Anstrich haben will.The amount of bismuth added can vary and essentially depends depends on the degree of hardness you want the paint to have.
Ein besonders günstiges Verhältnis von Kobalt zu Wismut ist .l Kobalt zu i Wismut oder 3 Kobalt zu i Wismut. Die Mengenverhältnisse können aber, wie angeführt, verändert werden.A particularly favorable ratio of cobalt to bismuth is .l cobalt to i bismuth or 3 cobalt to i bismuth. The proportions can, however, as stated, to be changed.
Sowohl Kobalt wie Wismut können als Oxyde oder Salze anorganischer oder organischer Salze verwendet werden.Both cobalt and bismuth can be more inorganic as oxides or salts or organic salts can be used.
Man schmilzt beispielsweise die Oxyde mit Harzen oder kocht Leinöl mit den Oxyden. An Stelle von Leinöl kann man auch beispielsweise Perillaöl, Mohnöl o. dgl. verwenden. Man kann die Oxyde und ebenso an deren Stelle die Salze gemeinsam mit dem Harz oder ()1 schmelzen oder erhitzen oder mischen. Man kann aber auch erst die eine Metallverbindung und dann die andere Metallverbindung zugeben.For example, the oxides are melted with resins or linseed oil is boiled with the oxides. Instead of linseed oil, you can also use perilla oil, poppy seed oil, for example or the like. The oxides can be used together with the salts in their place melt or heat or mix with the resin or () 1. But you can also first add one metal compound and then the other metal compound.
Beispiel i 25 kg wasserhelles Harz werden bei 13o° C mit 2, , kg Wismutacetat, welches mit der gleichen Menge oder mit 5 kg Harz abgerieben ist, versetzt. Man gibt dann 5 kg Kobaltacetat hinzu.Example i 25 kg of water-white resin are mixed with 2., kg of bismuth acetate at 130 ° C. which is rubbed off with the same amount or with 5 kg of resin. Man then add 5 kg of cobalt acetate.
Beispiel e i oo kg Leinöl werden mit i 5 kg Wismutacetat, zitronensaurem Wismut oder Wismutoxyd gekocht und 3okg Kobaltacetat (-nitrat) zugegeben.Example e 100 kg of linseed oil are mixed with 15 kg of bismuth acetate, citric acid Boiled bismuth or bismuth oxide and added 3 og cobalt acetate (nitrate).
Beispiel 3 Im Beispiel 2 wird Leinöl durch Perillaöl ersetzt.Example 3 In example 2, linseed oil is replaced by perilla oil.
Beispiel.l Man stellt aus ioo kg Harz und io kg essigsaurem Kobalt, welches mit 2o kg Harz abgerieben ist, bei 13o° C Kobaltsikkativ her und gibt Wismutacetat (-citrat, -formiat oder -nitrat) hinzu.Example. 1 From 100 kg of resin and 10 kg of acetic acid cobalt, which is rubbed off with 20 kg of resin, cobalt siccative at 130 ° C and adds bismuth acetate (citrate, formate or nitrate).
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB131603D DE466046C (en) | 1927-05-26 | 1927-05-26 | Process for the production of drying agents for varnishes, lacquers and paints |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB131603D DE466046C (en) | 1927-05-26 | 1927-05-26 | Process for the production of drying agents for varnishes, lacquers and paints |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE466046C true DE466046C (en) | 1928-09-29 |
Family
ID=6997897
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEB131603D Expired DE466046C (en) | 1927-05-26 | 1927-05-26 | Process for the production of drying agents for varnishes, lacquers and paints |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE466046C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2917172A1 (en) * | 1978-04-28 | 1979-11-08 | Tenneco Chem | DRYING MATERIAL MIXTURES AND THEIR USE |
| US4331575A (en) * | 1978-04-28 | 1982-05-25 | Tenneco Chemicals, Inc. | Drier systems and surface-coating compositions containing same |
-
1927
- 1927-05-26 DE DEB131603D patent/DE466046C/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2917172A1 (en) * | 1978-04-28 | 1979-11-08 | Tenneco Chem | DRYING MATERIAL MIXTURES AND THEIR USE |
| FR2424310A1 (en) * | 1978-04-28 | 1979-11-23 | Tenneco Chem | COMPOSITION OF SURFACE COATING BASED ON FILM-GENERATING RESIN, CONTAINING A METAL SICCATIVE |
| US4331575A (en) * | 1978-04-28 | 1982-05-25 | Tenneco Chemicals, Inc. | Drier systems and surface-coating compositions containing same |
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