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DE4440319A1 - Process for improving the efficiency of an evaporation process - Google Patents

Process for improving the efficiency of an evaporation process

Info

Publication number
DE4440319A1
DE4440319A1 DE4440319A DE4440319A DE4440319A1 DE 4440319 A1 DE4440319 A1 DE 4440319A1 DE 4440319 A DE4440319 A DE 4440319A DE 4440319 A DE4440319 A DE 4440319A DE 4440319 A1 DE4440319 A1 DE 4440319A1
Authority
DE
Germany
Prior art keywords
evaporation
liquid
surface area
air
enlargement
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE4440319A
Other languages
German (de)
Inventor
Georg Dipl Ing Litinas
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to DE4440319A priority Critical patent/DE4440319A1/en
Publication of DE4440319A1 publication Critical patent/DE4440319A1/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/14Treatment of water, waste water, or sewage by heating by distillation or evaporation using solar energy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/007Energy recuperation; Heat pumps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/34Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances
    • B01D3/343Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances the substance being a gas
    • B01D3/346Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances the substance being a gas the gas being used for removing vapours, e.g. transport gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D5/00Condensation of vapours; Recovering volatile solvents by condensation
    • B01D5/0033Other features
    • B01D5/0039Recuperation of heat, e.g. use of heat pump(s), compression
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • Y02A20/138Water desalination using renewable energy
    • Y02A20/142Solar thermal; Photovoltaics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/20Controlling water pollution; Waste water treatment
    • Y02A20/208Off-grid powered water treatment
    • Y02A20/212Solar-powered wastewater sewage treatment, e.g. spray evaporation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)

Abstract

If in evaporation processes the boiling temperature cannot or may not be achieved, a liquid evaporates only at its surface as a function of the partial pressures. Two known possible methods for accelerating this process are: Generating reduced pressure and Removing the layer of saturated steam forming at the surface which functions as an insulating layer. However, in both cases the surface of this liquid is the decisive parameter. The process which is the subject matter of the present application achieves by simple means an enlargement of the active surface area - exchange surface area - by simulating a boiling process and additionally utilises the abovementioned two possible methods. This improvement is achieved by injecting dry unsaturated air at the bottom of the liquid column, which air is then removed by suction, cooled and after partial yielding of its water content is injected dry. By parametrisation of the rate of ascent by the injection pressure and/or the height of the liquid column, an enlargement of the evaporation surface area by approximately 6-fold can be achieved by this means.

Description

Die vorliegende Erfindung wurde in Verbindung mit der Problematik der Entsalzung von brackigem oder reinem Salzwasser entwickelt, so wie sich diese ergibt, wenn man primär regenerierbare Energiequellen - Sonnenstrahlung, Windkraft - einsetzen will, deren Leistungsfähigkeit stark von den Witterungsverhältnissen abhängt.The present invention has been made in connection with the problem of desalination of develops brackish or pure salt water, as it results when you primarily wants to use renewable energy sources - solar radiation, wind power - whose Efficiency strongly depends on the weather conditions.

Zur Gewinnung von reinem Wasser gibt es grundsätzlich zwei Methoden:
Die Methode der Umkehrosmose und
Die Methode der Verdampfung.
There are basically two methods for obtaining pure water:
The method of reverse osmosis and
The method of evaporation.

Nach der ersten wird das zu behandelnde Wasser mit hohen Drücken - ca. 650 m Wassersäule - durch Spezialmembrane gepreßt, dagegen nach der zweiten wird dieses Wasser durch Zufuhr von Wärme verdampft und anschließend durch Abkühlung konden­ siert. Es handelt sich hierbei um einen echten Destillationsprozeß. Die Nachbehandlung des nach der ersten oder zweiten Methode gewonnenen Wassers ist nicht Gegenstand dieser Anmeldung.After the first, the water to be treated with high pressures - approx. 650 m Water column - pressed by special membrane, but after the second this is Water evaporates by adding heat and then it is cooled siert. It is a real distillation process. The aftercare the water obtained by the first or second method is not an object this registration.

Zweck der vorliegenden Erfindung ist es, den Verdampfungsprozeß der zweiten Methode zu beschleunigen und dadurch die Effizienz und den Wirkungsgrad dieses Prozesses zu erhöhen.The purpose of the present invention is to control the evaporation process of the second Accelerate method and thereby increase the efficiency and efficiency of this Process.

Die mit der Verdampfung zusammenhängenden Vorgänge sollen zum besseren Ver­ ständnis kurz erläutert werden.The processes related to evaporation are intended to improve ver briefly explained.

Jede Flüssigkeit verdampft an ihrer Oberfläche mit unterschiedlicher Geschwindigkeit in Abhängigkeit von ihrer Temperatur und dem an ihrer Oberfläche herrschenden Partial­ druck. Durch Wärmezufuhr wird ein für jede Flüssigkeit spezifischer Punkt - Siedepunkt - erreicht, bei dem dann die Verdampfung aus der ganzen Masse dieses Me­ diums erfolgt. Dieser Vorgang wird als Sieden oder Kochen bezeichnet.Every liquid evaporates on its surface at different speeds Dependence on their temperature and the partial prevailing on their surface print. By applying heat, a specific point for each liquid is Boiling point - reached, at which the evaporation from the whole mass of this me diums takes place. This process is called boiling or boiling.

Es kann sich jedoch als zweckmäßig erweisen, diesen Prozeß auch unterhalb des Siedepunktes dieser Flüssigkeit durchzuführen, sei es weil die Leistung der Wärme­ quelle diesen Punkt nicht erreichen kann, oder aber auch weil die Durchführung dieses Destillationsprozesses unterhalb des Siedepunktes einen u. a. besseren Reinheitsgrad erwarten läßt. Der erstere Fall kann z. B. eintreten, wenn, wie eingangs erwähnt, als Wärmequelle Sonnenkollektoren eingesetzt werden, deren Leistung nicht nur von der Tageszeit, sondern auch von den allgemeinen Witterungsbedingungen abhängt. Der zweite Fall ist z. B. nicht allein in petrochemischen Verfahren, sondern auch in der Verarbeitung von z. B. Natursäften denkbar. Man möchte dort das Wasser dem Saft entziehen, ohne jedoch durch Überhitzung die sonst vorhandenen, wertvolleren Stoffe z. B. Vitamine zu zerstören.However, it can prove to be useful to have this process below the To carry out the boiling point of this liquid, either because of the power of the heat source cannot reach this point, or also because the implementation of this Distillation process below the boiling point u. a. better purity can be expected. The former case can e.g. B. occur when, as mentioned at the beginning, as Heat source solar panels are used, the performance of which is not only dependent on the Time of day, but also depends on general weather conditions. Of the second case is z. B. not only in petrochemical processes, but also in  Processing of e.g. B. natural juices conceivable. You want the water and juice there withdraw, but without overheating, the otherwise existing, more valuable substances e.g. B. to destroy vitamins.

Der Koch- oder Siedeprozeß soll also dadurch simuliert und der Verdampfungsprozeß dadurch beschleunigt werden, daß nunmehr auch bei Temperaturen unterhalb des Siede­ punktes die Verdampfung nicht allein an der Oberfläche, sondern aus der ganzen Masse des Mediums erfolgt.The cooking or boiling process should thus be simulated and the evaporation process are accelerated by the fact that now also at temperatures below the boiling point point of evaporation not only on the surface, but from the whole mass of the medium.

Erfindungsgemäß wird mittels einer geeigneten Konstruktion, z. B. eines Düsenkranzes, Luft in Bläschenform am Boden der zu verdampfenden Flüssigkeitssäule hineingepreßt und an ihrer Oberfläche abgesaugt.According to the invention by means of a suitable construction, for. B. a nozzle ring, Air in bubble form is pressed in at the bottom of the liquid column to be evaporated and vacuumed on their surface.

Es kann in Abhängigkeit der Steiggeschwindigkeit dieser Bläschen erreicht werden, daß diese in ungesättigtem, trockenem Zustand eingeblasene Luft an der Oberfläche des Mediums gesättigt austritt.Depending on the rate of climb of these bubbles, it can be achieved that this air blown in unsaturated, dry state on the surface of the Medium emerges saturated.

Damit kann also die sonst erst beim Siedepunkt erreichbare vollvolumige Verdampfung des Mediums nicht nur beschleunigt, sondern und vor allem bei niedrigeren Temperaturen als der des Siedepunktes erreicht werden.This means that the full-volume evaporation that can otherwise only be achieved at the boiling point of the medium not only accelerates, but especially at lower temperatures than that of the boiling point.

Überschlägige Berechnungen lassen erwarten, daß dadurch die für die Verdampfung maßgebende Fläche - aktive Fläche - gegenüber einer konventionellen Anlage um ein Vielfaches, bis zum Faktor 6, erhöht werden kann.Rough calculations are expected to be the result of evaporation decisive area - active area - compared to a conventional system Multiples can be increased up to a factor of 6.

Zum besseren Verständnis sei auf die zwei Schemata verwiesen die unten auch erläutert werden. Dabei sei vermerkt, daß diese schematische Darstellung, wie auch sonst üblich, mit der in der Praxis vorkommenden Installation kaum Ähnlichkeit hat und lediglich dem prinzipiellen Verständnis dient.For better understanding, please refer to the two diagrams below are explained. It should be noted that this schematic representation, as otherwise usual, has hardly any resemblance to the installation occurring in practice and only serves the basic understanding.

Schema 1 stellt den üblichen Verdampfungsprozeß dar.Scheme 1 shows the usual evaporation process.

Im linken Gefäß wird die zu bearbeitende Flüssigkeit durch Aufheizen zum Verdampfen gebracht und anschließend in das rechte Gefäß geleitet, in dem sie durch Abkühlen zum Destillat kondensiert. Die Zufuhr des Dampfes in das rechte Gefäß kann entweder mittels einer Absaugvorrichtung, oder aber auch frei - ungezwungen - durch die vorherrschen­ den Differenzdrücke zwischen einer wärmeren und einer kälteren Umgebung erfolgen.In the left vessel, the liquid to be processed is evaporated by heating brought and then passed into the right vessel, in which they by cooling to Distillate condenses. The steam can be fed into the right vessel either by means of a suction device, or freely - freely - through the prevail the differential pressures between a warmer and a colder environment.

Schema 2 stellt die hier angemeldete Modifikation dar.Scheme 2 shows the modification registered here.

Erfindungsgemäß wird Luft vom rechten Behälter abgesaugt und etwa in der Basis des linken Behälters mit Hilfe des erwähnten Kranzes, in Form von Luftbläschen hineinge­ preßt. Diese im Vergleich trockene Luft durchläuft mit einer parametrierbaren Geschwin­ digkeit die Flüssigkeit und erreicht deren Oberfläche in gesättigtem Zustand, um an­ schließend im zweiten Behälter abgekühlt und dadurch auch getrocknet zu werden, wobei sie die aufgenommene Flüssigkeitsmenge abgibt.According to the invention, air is drawn off from the right container and approximately in the base of the left container with the help of the mentioned wreath, in the form of air bubbles presses. This air, which is dry by comparison, passes through a parameterizable speed  liquid and reaches its surface in a saturated state in order to finally cooled in the second container and thereby dried, releasing the amount of liquid absorbed.

Es ist ohne weiteres ersichtlich, daß dadurch die Verdampfung nicht allein an der Ober­ fläche, sondern aus dem ganzen Volumen der zu behandelnden Flüssigkeit erfolgt; eine Tatsache, welche wie zuvor vermerkt, einer Vergrößerung der für die Verdampfung maßgebenden Fläche um bis zum Faktor 6 impliziert. Das vollvolumige Verdampfen, Kochen, welches beim Wasser auf der Höhe des Meeresspiegels bei einer Temperatur von 100°C erfolgt, kann sich nunmehr nach diesem Verfahren auch bei niedrigeren Temperaturen vollziehen.It is readily apparent that the evaporation is not only at the top area, but from the entire volume of the liquid to be treated; a Fact, which, as noted above, an increase in that for evaporation relevant area by up to a factor of 6. The full volume evaporation, Cooking, which is at water at sea level at a temperature of 100 ° C, can now be used with this method even at lower Execute temperatures.

Claims (1)

Verfahren zur Verbesserung des Wirkungsgrades eines Verdampfungsprozesses, dadurch gekennzeichnet, daß
  • 1. durch die Einleitung eines geeignet präparierten Mediums, im vorliegenden Falle trockene Luft, durch die zu verdampfende Masse eine Beschleunigung dieses Vorganges erreicht wird durch Vergrößerung der aktiven (Austausch-)Fläche,
  • 2. davon unabhängig, ob die notwendige Vorbereitung allein aus der Trocknung dieses Mediums oder aber auch zusätzlich aus seiner Anreicherung durch zweckdienlich bestimmte Beimengungen besteht,
  • 3. abhängig von dem zu erreichenden Zweck und der Beschaffenheit des zu verdampfenden Mediums, auch andere Transportmittel, im vorliegenden Falle Luft, abhängig von der maßgebenden, gegenseitigen Löslichkeit eingesetzt werden können.
Method for improving the efficiency of an evaporation process, characterized in that
  • 1. by introducing a suitably prepared medium, in the present case dry air, by means of the mass to be evaporated, this process is accelerated by increasing the active (exchange) area,
  • 2. irrespective of whether the necessary preparation consists solely of drying this medium or also of enriching it with appropriately determined additives,
  • 3. depending on the purpose to be achieved and the nature of the medium to be evaporated, other means of transport, in the present case air, depending on the decisive mutual solubility can be used.
DE4440319A 1994-11-11 1994-11-11 Process for improving the efficiency of an evaporation process Withdrawn DE4440319A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE4440319A DE4440319A1 (en) 1994-11-11 1994-11-11 Process for improving the efficiency of an evaporation process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4440319A DE4440319A1 (en) 1994-11-11 1994-11-11 Process for improving the efficiency of an evaporation process

Publications (1)

Publication Number Publication Date
DE4440319A1 true DE4440319A1 (en) 1995-04-13

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Family Applications (1)

Application Number Title Priority Date Filing Date
DE4440319A Withdrawn DE4440319A1 (en) 1994-11-11 1994-11-11 Process for improving the efficiency of an evaporation process

Country Status (1)

Country Link
DE (1) DE4440319A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19548885B4 (en) * 1994-12-29 2004-03-04 Ulrich Kothe Process for producing fruit brandies and device therefor
WO2005075045A1 (en) * 2004-02-05 2005-08-18 Peter Vinz Evaporation method for purifying and/or concentrating contaminated liquids

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19548885B4 (en) * 1994-12-29 2004-03-04 Ulrich Kothe Process for producing fruit brandies and device therefor
WO2005075045A1 (en) * 2004-02-05 2005-08-18 Peter Vinz Evaporation method for purifying and/or concentrating contaminated liquids

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Legal Events

Date Code Title Description
OAV Applicant agreed to the publication of the unexamined application as to paragraph 31 lit. 2 z1
8122 Nonbinding interest in granting licences declared
8139 Disposal/non-payment of the annual fee