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DE4118088A1 - Continuous selective water cleaning - uses adsorption on separated concentrate to be mixed with separated permeate for selective removal of small concentrations of matter - Google Patents

Continuous selective water cleaning - uses adsorption on separated concentrate to be mixed with separated permeate for selective removal of small concentrations of matter

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Publication number
DE4118088A1
DE4118088A1 DE4118088A DE4118088A DE4118088A1 DE 4118088 A1 DE4118088 A1 DE 4118088A1 DE 4118088 A DE4118088 A DE 4118088A DE 4118088 A DE4118088 A DE 4118088A DE 4118088 A1 DE4118088 A1 DE 4118088A1
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DE
Germany
Prior art keywords
stage
concentrate
permeate
matter
separated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE4118088A
Other languages
German (de)
Inventor
Thomas Stoever
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Preussag Wassertechnik 28359 Bremen De GmbH
Original Assignee
Preussag Anlagenbau 3000 Hannover De GmbH
Preussag Anlagenbau GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Preussag Anlagenbau 3000 Hannover De GmbH, Preussag Anlagenbau GmbH filed Critical Preussag Anlagenbau 3000 Hannover De GmbH
Priority to DE4118088A priority Critical patent/DE4118088A1/en
Publication of DE4118088A1 publication Critical patent/DE4118088A1/en
Withdrawn legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/025Reverse osmosis; Hyperfiltration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D17/00Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
    • B01D17/02Separation of non-miscible liquids
    • B01D17/0202Separation of non-miscible liquids by ab- or adsorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D17/00Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
    • B01D17/08Thickening liquid suspensions by filtration
    • B01D17/085Thickening liquid suspensions by filtration with membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14Ultrafiltration; Microfiltration
    • B01D61/145Ultrafiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • C02F1/4693Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis electrodialysis

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  • Chemical & Material Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Molecular Biology (AREA)
  • Analytical Chemistry (AREA)
  • Nanotechnology (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

To give a continuous removal of material from a fluid in small concentrations, esp. in an adsorption process, the fluid is sepd. before it enters the prepn. stage into a concentrate rich in material and a cleaned permeate using reverse osmosis, electrodialysis or ultrafiltration. The concentrate is treated in the handling stage while the permeate passes round it to be mixed together after the concentrate has been processed. The liquid initially enters a stage in front of the treatment zone, where the liquid is sepd. for treatment. The mixed liq., using the treated concentrate and the permeate is further treated after mixing. In the treatment stage, active carbon or active earths are the adsorption agent. The water is cleaned, by adsorption of matter such as CKW, pesticide and heavy metals, while minerals are retained. ADVANTAGE - The process gives a more selective sepn. system to remove certain matter in the water, for example, while retaining other matter which is required in the liq.

Description

Die Erfindung betrifft ein Verfahren zur kontinuierlichen Ent­ fernung von in geringer Konzentration vorhandenen Inhaltsstof­ fen aus einer Flüssigkeit in einer insbesondere nach dem Ad­ sorptionsprinzip arbeitenden Aufbereitungsstufe.The invention relates to a method for continuous Ent removal of ingredients present in low concentration fen from a liquid in a particular after the ad sorption principle working preparation stage.

Zur Entfernung von Inhaltsstoffen aus Flüssigkeiten sind zahl­ reiche Aufbereitungsverfahren bekannt. Als wichtigste können hier die Sentimentation, die Filtration und die Adsorption genannt werden. Nachteilig ist bei diesen Verfahren anzusehen, daß ihre Effektivität bei geringer Konzentration der zu ent­ fernenden Inhaltsstoffe gering ist. Es sind weiterhin Verfah­ ren wie Umkehrosmose, Elektrodialyse und Ultrafiltration zur Entfernung von Inhaltsstoffen aus Flüssigkeiten bekannt. Diese Verfahren sind aber für viele Anwendungsfälle nicht genügend selektiv, so daß neben den zu entfernenden Inhaltsstoffen auch andere Inhaltsstoffe abgetrennt werden, deren Abtrennung un­ erwünscht ist. So wird beispielsweise bei der Wasseraufberei­ tung in Umkehrosmose- oder Elektrodialyseanlagen zur Entfer­ nung von Störstoffen auch die Mineralstoffzusammensetzung des Wassers sehr stark geändert. Ein Nachteil der genannten Trenn­ verfahren liegt häufig auch in der schwierigen Entsorgung des anfallenden Konzentratstroms.To remove ingredients from liquids are number known processing methods. The most important can here the sentimentation, the filtration and the adsorption to be named. A disadvantage of these processes is that that their effectiveness at low concentration ent distant ingredients is low. There are still proceedings such as reverse osmosis, electrodialysis and ultrafiltration Removal of ingredients from liquids known. These However, procedures are not sufficient for many applications selective, so that in addition to the ingredients to be removed other ingredients are separated, their separation un is desired. For example, in water treatment in reverse osmosis or electrodialysis systems for removal the mineral composition of the Water changed very much. A disadvantage of the separation mentioned often lies in the difficult disposal of the resulting concentrate flow.

Der Erfindung liegt die Aufgabe zugrunde, ein Verfahren der eingangs genannten Art hinsichtlich seiner Effektivität und Wirtschaftlichkeit zu verbessern. The invention has for its object a method of type mentioned in terms of its effectiveness and Improve economy.  

Zur Lösung dieser Aufgabe ist erfindungsgemäß vorgesehen, daß die Flüssigkeit vor dem Eintritt in die Aufbereitungsstufe in einer Trennstufe durch Umkehrosmose, Elektrodialyse oder Ul­ trafiltration in ein an Inhaltsstoffen angereichertes Konzen­ trat und ein gereinigtes Permeat getrennt wird und daß das Konzentrat in der Aufbereitungsstufe aufbereitet und das Per­ meat unter Umgehung der Aufbereitungsstufe dem aufbereiteten Konzentrat zugemischt wird.To solve this problem, the invention provides that the liquid before entering the treatment stage in a separation stage by reverse osmosis, electrodialysis or ul trafiltration in a concentrate enriched with ingredients entered and a purified permeate is separated and that the Concentrate processed in the preparation stage and the per meat bypassing the preparation stage of the prepared one Concentrate is added.

Das erfindungsgemäße Verfahren hat den Vorteil, daß nur ein Teil des aufzubereitenden Flüssigkeitstroms in die Aufberei­ tungsstufe gelangt, wodurch der Aufwand zur selektiven Entfer­ nung bestimmter Inhaltsstoffe aus der Flüssigkeit reduziert wird. Weiterhin ist von Vorteil, daß die zu entfernenden In­ haltsstoffe in dem der Aufbereitungsstufe zugeführten Konzen­ trat in erheblicher höherer Konzentration vorliegen als in der aufzubereitenden Flüssigkeit. Hierdurch wird die Effektivität der Aufbereitungsstufe gesteigert. So kann beispielsweise der Einsatz von Adsorbermaterial bei einer Aufkonzentrierung des zu adsorbierenden Inhaltsstoffs stark verringert werden und der durch die Adsorptionsstufe geleitete Flüssigkeitsstrom bis auf 10% des eingangs zugeführten Flüssigkeitsstroms reduziert werden.The process according to the invention has the advantage that only one Part of the liquid flow to be treated in the preparation tion stage, which means that the effort for selective removal reduced certain ingredients from the liquid becomes. Another advantage is that the In. To be removed Ingredients in the concentrate supplied to the processing stage occurred in a significantly higher concentration than in the liquid to be treated. This will make it more effective the processing level increased. For example, the Use of adsorber material when the to be adsorbed ingredient greatly reduced and the liquid flow passed through the adsorption stage to reduced to 10% of the incoming liquid flow will.

Wird das erfindungsgemäße Verfahren zur Trinkwasseraufberei­ tung eingesetzt, wobei dem aufzubereitenden Rohwasser in der Aufbereitungsstufe bestimmte Störstoffe entzogen werden, so ergibt sich weiterhin der Vorteil, daß die Mineralstoffzusam­ mensetzung des Reinwassers weitgehend unverändert bleiben kann. Hierbei ist vor allem die Aufbereitung des Konzentrat­ stroms durch Adsorption besonders geeignet, da Adsorbermate­ rialien die natürliche Zusammensetzung der Wasserinhaltsstoffe nur spezifisch ändern. Mit dem erfindungsgemäßen Verfahren läßt sich auch die Beladung von Adsorbenzien in der Aufberei­ tungsstufe um ein Vielfaches steigern, so daß die Regenera­ tions- oder Anschaffungskosten für das Adsorptionsmaterial vermindert werden. Besonders bei der Entfernung von Spuren­ stoffen, wie Pestiziden, Chlorkohlenwasserstoffen oder Schwer­ metallen, in der Trinkwasseraufbereitung lassen sich bisher keine ausreichenden Beladungen auf Adsorbermaterialien erzie­ len. Durch die Aufkonzentrierung der Spurenstoffe nach dem erfindungsgemäßen Verfahren wird diesem Nachteil begegnet.Will the inventive method for drinking water treatment tion used, the raw water to be treated in the Processing stage certain contaminants are withdrawn, so there is also the advantage that the minerals together The purity of the pure water remains largely unchanged can. The main thing here is the preparation of the concentrate electricity through adsorption particularly suitable, because adsorber mate rialien the natural composition of the water ingredients only change specifically. With the method according to the invention  the loading of adsorbents can also be carried out in the processing plant tion level increase many times over, so that the Regenera tion or acquisition costs for the adsorbent material can be reduced. Especially when removing traces substances such as pesticides, chlorinated hydrocarbons or heavy metals, so far in drinking water treatment do not generate sufficient loads on adsorber materials len. By concentrating the trace substances after the The method according to the invention addresses this disadvantage.

Den beschriebenen Vorteilen des erfindungsgemäßen Verfahrens steht zwar der Nachteil eines weiteren Verfahrensschritts ge­ genüber. Dieser Nachteil wird aber durch die Verringerung des Aufwands für die Aufbereitungsstufe und die Verbesserung der Leistung aufgewogen. Auch lassen neuere Entwicklungen im Be­ reich der Niederdruck-Membranen den Energieverbrauch für den notwendigen Druckaufbau in der Trennstufe geringer werden.The described advantages of the method according to the invention there is the disadvantage of a further process step ge opposite. This disadvantage is caused by the reduction in Effort for the preparation stage and the improvement of the Performance weighed. Also recent developments in the Be of low pressure membranes the energy consumption for the necessary pressure build-up in the separation stage become lower.

Erfindungsgemäß kann weiterhin vorgesehen sein, daß in einer Vorbehandlungsstufe die der Trennstufe zugeführte Flüssigkeit vorbehandelt wird. Ferner kann die gemischte Flüssigkeit aus Aufbereitungsstufe und Trennstufe einer Nachbehandlung unter­ zogen werden. Bevorzugte Adsorbenzien für die Aufbereitungs­ stufe sind Aktivkohle oder Aktivtonerde.According to the invention it can further be provided that in a Pretreatment stage the liquid supplied to the separation stage is pretreated. Furthermore, the mixed liquid can Preparation stage and separation stage of an aftertreatment under be drawn. Preferred adsorbents for processing level are activated carbon or activated alumina.

Eine bevorzugte Anwendung des erfindungsgemäßen Verfahrens wird anhand eines in der Zeichnung dargestellten Blockfließ­ bilds im folgenden näher erläutert.A preferred application of the method according to the invention is based on a block flow shown in the drawing picture explained in more detail below.

Das Blockfließbild zeigt eine Anlage zur Aufbereitung von Trinkwasser. Das bei 1 zugeführte Rohwasser wird nach einer Vorbehandlung in einer Vorbehandlungsstufe 2 einer Trennstufe 3 zugeführt, die nach dem Prinzip der Umkehrosmose arbeitet, wobei ein großer Teil des Wassers (80-90%) unter Druck Membranen als Permeat 4 passiert, während ein kleinerer Teil des Rohwassers und die darin aufkonzentrierten Inhaltsstoffe als Konzentrat von den Membranen zurückgehalten wird. Das Kon­ zentrat 5 wird einer Aufbereitungsstufe 6 zugeführt, in der mit Hilfe von Adsorbermaterial aufkonzentrierte Schadstoffe, wie CKW′s, Pestizide, Schwermetalle, adsorbiert werden, wäh­ rend die Mineralstoffe die Aufbereitungsstufe 6 passieren. Das aufbereitete Konzentrat 7 und das Permeat 4 werden wieder ver­ einigt und in einer Nachbehandlungsstufe 8 nachbehandelt. Bei 9 wird das Reinwasser aus der Nachbehandlungsstufe abgeführt.The block flow diagram shows a plant for the treatment of drinking water. The raw water supplied at 1 is fed after a pretreatment in a pretreatment stage 2 to a separation stage 3 , which works on the principle of reverse osmosis, whereby a large part of the water (80-90%) passes through membranes under pressure as permeate 4 , while a smaller part of the raw water and the ingredients concentrated therein is retained as a concentrate by the membranes. The concentrate 5 is fed to a processing stage 6 , in which concentrated pollutants, such as CHCs, pesticides, heavy metals, are adsorbed with the aid of adsorber material, while the minerals pass the processing stage 6 . The processed concentrate 7 and the permeate 4 are combined again and post-treated in a post-treatment stage 8 . At 9 , the pure water is removed from the aftertreatment stage.

Bei dem beschriebenen Verfahren ist der Wasserverlust gering und die Mineralstoffzusammensetzung des Wassers bleibt weitge­ hend unverändert. Die Ausnutzung der Adsorberkapazität der Adsorbermaterialien ist hoch.With the method described, the water loss is low and the mineral composition of the water remains wide unchanged. The exploitation of the adsorber capacity Adsorber materials are high.

Claims (4)

1. Verfahren zur kontinuierlichen Entfernung von in geringer Konzentration vorhandenen Inhaltsstoffen aus einer Flüssig­ keit in einer insbesondere nach dem Adsorptionsprinzip ar­ beitenden Aufbereitungsstufe, dadurch gekennzeichnet, daß die Flüssigkeit vor dem Eintritt in die Aufbereitungsstufe in einer Trennstufe durch Umkehrosmose, Elektrodialyse oder Ultrafiltration in ein an Inhaltsstoffen angereichertes Konzentrat und ein gereinigtes Permeat getrennt wird, daß das Konzentrat in der Aufbereitungsstufe aufbereitet und das Permeat unter Umgehung der Aufbereitungsstufe dem auf­ bereiteten Konzentrat zugemischt wird.1. A process for the continuous removal of ingredients present in a low concentration from a liquid in a processing stage which in particular works according to the adsorption principle, characterized in that the liquid before entering the processing stage in a separation stage by reverse osmosis, electrodialysis or ultrafiltration in one Ingredient-enriched concentrate and a purified permeate is separated, that the concentrate is processed in the preparation stage and the permeate is mixed with the prepared concentrate bypassing the preparation stage. 2. Verfahren nach Einspruch 1, dadurch gekennzeichnet, daß in einer Vorbehandlungsstufe die der Trennstufe zugeführte Flüssigkeit vorbehandelt wird.2. The method according to opposition 1, characterized in that in a pretreatment stage that is supplied to the separation stage Liquid is pretreated. 3. Verfahren nach einem der Ansprüche 1 oder 2, dadurch ge­ kennzeichnet, daß die gemischte Flüssigkeit aus Aufberei­ tungsstufe und Trennstufe einer Nachbehandlung unterzogen wird.3. The method according to any one of claims 1 or 2, characterized ge indicates that the mixed liquid from treatment treatment stage and separation stage subjected to an aftertreatment becomes. 4. Verfahren nach einem der Ansprüche 1 bis 3, dadurch gekenn­ zeichnet, daß die Aufbereitungsstufe Aktivkohle oder Aktiv­ tonerde als Adsorbermaterial enthält.4. The method according to any one of claims 1 to 3, characterized records that the treatment stage activated carbon or active contains alumina as adsorbent material.
DE4118088A 1991-06-01 1991-06-01 Continuous selective water cleaning - uses adsorption on separated concentrate to be mixed with separated permeate for selective removal of small concentrations of matter Withdrawn DE4118088A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE4118088A DE4118088A1 (en) 1991-06-01 1991-06-01 Continuous selective water cleaning - uses adsorption on separated concentrate to be mixed with separated permeate for selective removal of small concentrations of matter

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4118088A DE4118088A1 (en) 1991-06-01 1991-06-01 Continuous selective water cleaning - uses adsorption on separated concentrate to be mixed with separated permeate for selective removal of small concentrations of matter

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4338569A1 (en) * 1992-11-06 1994-05-26 Geesthacht Gkss Forschung Sepn of esp organic matter from liq - by adsorption preceded by membrane sepn
DE4325037A1 (en) * 1993-07-26 1995-02-02 Andreas Landmann Process water recycling plant
DE19512688A1 (en) * 1995-04-07 1996-10-10 Membrain Gmbh Condensation of vapours from beer brewing processes
EP0806399A1 (en) * 1996-05-10 1997-11-12 Wehrle-Werk Ag Process and device for purifying waste water
WO2007010549A1 (en) * 2005-07-20 2007-01-25 Mahesh Gupta A household reverse osmosis based drinking water purifier
RU2322403C2 (en) * 2005-10-25 2008-04-20 Общество с ограниченной ответственностью "Энергоэкосервис" System to prepare make-up water to be added to heat supply system

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2623210B2 (en) * 1975-06-05 1979-06-21 Creusot-Loire, Paris
DE8111288U1 (en) * 1981-04-14 1982-12-16 Dornier System Gmbh, 7990 Friedrichshafen "DEVICE FOR IMPLEMENTING PROCESS PROCESSES"
SU1542920A1 (en) * 1987-06-23 1990-02-15 Go Inzh Str I Im V P Chkalova Method of producing extra-pure water
DE3901005A1 (en) * 1989-01-14 1990-07-19 Rheinische Braunkohlenw Ag DEVICE AND METHOD FOR PURIFYING WASTE WATER
DE4116278A1 (en) * 1990-05-22 1991-11-28 Interatom Removal of nitrate(s) from drinking water using ion exchange - regeneration pipe connects anion and cation exchange units and regeneration liq. is produced by reverse osmosis

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2623210B2 (en) * 1975-06-05 1979-06-21 Creusot-Loire, Paris
DE8111288U1 (en) * 1981-04-14 1982-12-16 Dornier System Gmbh, 7990 Friedrichshafen "DEVICE FOR IMPLEMENTING PROCESS PROCESSES"
SU1542920A1 (en) * 1987-06-23 1990-02-15 Go Inzh Str I Im V P Chkalova Method of producing extra-pure water
DE3901005A1 (en) * 1989-01-14 1990-07-19 Rheinische Braunkohlenw Ag DEVICE AND METHOD FOR PURIFYING WASTE WATER
DE4116278A1 (en) * 1990-05-22 1991-11-28 Interatom Removal of nitrate(s) from drinking water using ion exchange - regeneration pipe connects anion and cation exchange units and regeneration liq. is produced by reverse osmosis

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* Cited by examiner, † Cited by third party
Title
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u.a.: Aktivkohleanwendung in der Ab- wasserreinigung. In: Korrespondenz Abwasser 35, 3/88, S.187-255 *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4338569A1 (en) * 1992-11-06 1994-05-26 Geesthacht Gkss Forschung Sepn of esp organic matter from liq - by adsorption preceded by membrane sepn
DE4325037A1 (en) * 1993-07-26 1995-02-02 Andreas Landmann Process water recycling plant
DE19512688A1 (en) * 1995-04-07 1996-10-10 Membrain Gmbh Condensation of vapours from beer brewing processes
DE19512688C2 (en) * 1995-04-07 1998-05-28 Zenon Gmbh Membranen Anlagen U Process for disposing of vapors generated during malting and / or brewing beer
EP0806399A1 (en) * 1996-05-10 1997-11-12 Wehrle-Werk Ag Process and device for purifying waste water
US6080317A (en) * 1996-05-10 2000-06-27 Wehrle-Werk Ag Process and apparatus for the purification of waste water
WO2007010549A1 (en) * 2005-07-20 2007-01-25 Mahesh Gupta A household reverse osmosis based drinking water purifier
RU2322403C2 (en) * 2005-10-25 2008-04-20 Общество с ограниченной ответственностью "Энергоэкосервис" System to prepare make-up water to be added to heat supply system

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8127 New person/name/address of the applicant

Owner name: PREUSSAG NOELL WASSERTECHNIK GMBH, 28359 BREMEN, D

8127 New person/name/address of the applicant

Owner name: PREUSSAG WASSERTECHNIK GMBH, 28359 BREMEN, DE

8139 Disposal/non-payment of the annual fee