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DE411449C - Process for the production of fuel briquettes from small coal using sulphite cellulose waste liquor - Google Patents

Process for the production of fuel briquettes from small coal using sulphite cellulose waste liquor

Info

Publication number
DE411449C
DE411449C DEP45631D DEP0045631D DE411449C DE 411449 C DE411449 C DE 411449C DE P45631 D DEP45631 D DE P45631D DE P0045631 D DEP0045631 D DE P0045631D DE 411449 C DE411449 C DE 411449C
Authority
DE
Germany
Prior art keywords
sulphite
waste liquor
production
coal
liquor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEP45631D
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HANNA BRIKETTIERUNGSGESELLSCHA
Original Assignee
HANNA BRIKETTIERUNGSGESELLSCHA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HANNA BRIKETTIERUNGSGESELLSCHA filed Critical HANNA BRIKETTIERUNGSGESELLSCHA
Priority to DEP45631D priority Critical patent/DE411449C/en
Priority to DEH99657D priority patent/DE416942C/en
Application granted granted Critical
Publication of DE411449C publication Critical patent/DE411449C/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L5/00—Solid fuels
    • C10L5/02—Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
    • C10L5/06—Methods of shaping, e.g. pelletizing or briquetting
    • C10L5/10—Methods of shaping, e.g. pelletizing or briquetting with the aid of binders, e.g. pretreated binders
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L5/00—Solid fuels
    • C10L5/02—Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
    • C10L5/06—Methods of shaping, e.g. pelletizing or briquetting
    • C10L5/10—Methods of shaping, e.g. pelletizing or briquetting with the aid of binders, e.g. pretreated binders
    • C10L5/14—Methods of shaping, e.g. pelletizing or briquetting with the aid of binders, e.g. pretreated binders with organic binders
    • C10L5/20—Methods of shaping, e.g. pelletizing or briquetting with the aid of binders, e.g. pretreated binders with organic binders with sulfite lye

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Description

Verfahren zur Herstellung von Brennstoffbriketten aus Kohlenklein mittels Sulfitzelluloseablauge. Die Erfindung betrifft ein Verfahren zur Herstellung von Brennstoffbriketten aus Kohlenklein aller Art mittels Sulfitzelluloseablauge, Gips, Alaun und Formaldehyd. Gegenüber bekannten Verfahren dieser Art besteht das Neue und Eigenartige des vorliegenden Verfahrens darin, daß hier das Kohlenklein vor dem Zusatz der Sulfitablauge mit Schwefelkalzium vermischt und daß der Sulfitablauge Salpeter zugesetzt wird worauf alle Bestandteile miteinander vermischt und das Gemisch in der Kälte gepreßt wird. Es gelingt auf diese Weise, transportfähige, wetterbeständige Brikette ohne Anwendung künstlich erhöhter Temperatur herzustellen, das ganze Brikettierungsverfahren also vollständig in der Kälte auszuführen, während bei den bekannten Verfahren stets mindestens eine nachträgliche Erhitzung erforderlich war, um zu wetterbeständigen Briketten zu gelangen.Process for the production of fuel briquettes from small coal by means of sulphite cellulose liquor. The invention relates to a method of manufacture of fuel briquettes made from coal of all kinds using sulphite cellulose waste liquor, Plaster of paris, alum and formaldehyde. Compared to known methods of this type, there is What is new and peculiar to the present process is that the coal is here before the addition of the sulphite liquor mixed with calcium sulphide and that the sulphite liquor Saltpeter is added whereupon all ingredients are mixed together and the mixture pressed in the cold. It succeeds in this way, transportable, weather-resistant To produce briquettes without applying artificially elevated temperatures, the whole briquetting process thus to be carried out completely in the cold, while with the known methods always at least one subsequent heating was required in order to be weatherproof Briquettes to arrive.

Bei Ausführung des Verfahrens kann man Kohlenabfälle aller Art, wie Kohlenstaub, Kohlen- und Koksgrus, Kohlenschlamm, Schlacke, Lösche u. dgl., für sich oder in Verbindung finit andern Abfällen verwenden. Diese werden mit 2 Prozent Schwefelkalzium gut durchmischt, alsdann werden bis zu q.Prozent Gips zugesetzt. Der so erhaltenen Mischung werden dann 3 Prozent einer Sulfitzellstoffablauge hinzugesetzt, die zuvor mit o,o5 Prozent salpetersaurem Kali o,o5 Prozent Alaun und o,o25 Prozent Formaldehyd versetzt worden ist. Als Sulfitablauge wird zweckmäßig solche von 35° B6 (im Verhältnis 1 : 3 mit Wasser verdünnt) benutzt. Beim Zusammenbringen dieser Bestandteile bzw. beim Zusatz des Schwefelkalziums zu der in der angegebenen Weise mit Salpeter ti. dgl. versetzten Stilfitablatige tritt plötzlich eine sehr starke Verdickung dieser Lauge unter Wärmeentwicklung ein, was auf den Eintritt einer chemischen Reaktion zurückzuführen ist, durch die die Gewinnung der wetterbeständigen Brikette erst ermöglicht wird.When carrying out the process, coal waste of all kinds, such as coal dust, coal and coke breeze, coal sludge, slag, sludge and the like, can be used by itself or in conjunction with other waste. These are mixed well with 2 percent calcium sulfate, then up to q percent gypsum is added. The mixture thus obtained is then added with 3 percent of a sulphite pulp waste liquor to which 0.05 percent potassium nitric acid, 0.05 percent alum and 0.025 percent formaldehyde has been added. The sulphite waste liquor used is expediently 35 ° B6 ( diluted in a ratio of 1 : 3 with water). When combining these constituents or when adding the calcium sulphide to the saltpeter ti in the manner indicated. Like. Staggered Stilfitablatige suddenly a very strong thickening of this lye occurs with the development of heat, which is due to the occurrence of a chemical reaction, through which the extraction of the weather-resistant briquette is made possible in the first place.

Vor Einbringen in die Presse läßt man die Masse etwa io Minuten stehen. Die dann erdfeuchte Masse wird in die Presse gebrächt und kann hier zu beliebigen Formstücken gepreßt werden. Die die Presse `-erlassenden Formlinge sind sofort transportfähig.The mass is allowed to stand for about 10 minutes before it is placed in the press. The earth-moist mass is then brought into the press and can be used here as desired Moldings are pressed. The briquettes that are released from the press can be transported immediately.

Claims (1)

PATENTANSPRÜCHE: i. Verfahren zur Herstellung von Brennstoffbriketten aus Kohlenklein mittels Sulfitzelluloseablauge, Gips, Alaun und Formaldehyd, dadurch gekennzeichriet, daß das Kohlenklein vor dem Zusatz der Sulfitablauge mit Schwefelkalzium vermischt und der Sulfitablauge Salpeter hinzugefügt wird, worauf alle Bestandteile miteinander vermischt und das Gemisch durch Pressen in der Kälte zu transportfähigen, wetterbeständigen Briketten geformt wird. z. Verfahren nach Anspruch i, gekennzeichnet durch die Verwendung von weniger als 5 Prozent Sulfitablauge (von 35' Be) und weniger als i Prozent Formaldehyd. PATENT CLAIMS: i. Process for the production of fuel briquettes from coal pebbles using sulphite cellulose liquor, gypsum, alum and formaldehyde, characterized in that the coal pebbles are mixed with calcium sulphide before the sulphite liquor is added and saltpeter is added to the sulphite waste liquor, whereupon all components are mixed together and the mixture is pressed in the cold is formed into transportable, weather-resistant briquettes. z. Process according to Claim i, characterized by the use of less than 5 percent sulphite waste liquor (of 35% Be) and less than 1 percent formaldehyde.
DEP45631D 1923-01-30 1923-01-30 Process for the production of fuel briquettes from small coal using sulphite cellulose waste liquor Expired DE411449C (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DEP45631D DE411449C (en) 1923-01-30 1923-01-30 Process for the production of fuel briquettes from small coal using sulphite cellulose waste liquor
DEH99657D DE416942C (en) 1923-01-30 1924-12-14 Process for producing fuel briquettes from coal

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP45631D DE411449C (en) 1923-01-30 1923-01-30 Process for the production of fuel briquettes from small coal using sulphite cellulose waste liquor
DEH99657D DE416942C (en) 1923-01-30 1924-12-14 Process for producing fuel briquettes from coal

Publications (1)

Publication Number Publication Date
DE411449C true DE411449C (en) 1925-03-28

Family

ID=33099005

Family Applications (2)

Application Number Title Priority Date Filing Date
DEP45631D Expired DE411449C (en) 1923-01-30 1923-01-30 Process for the production of fuel briquettes from small coal using sulphite cellulose waste liquor
DEH99657D Expired DE416942C (en) 1923-01-30 1924-12-14 Process for producing fuel briquettes from coal

Family Applications After (1)

Application Number Title Priority Date Filing Date
DEH99657D Expired DE416942C (en) 1923-01-30 1924-12-14 Process for producing fuel briquettes from coal

Country Status (1)

Country Link
DE (2) DE411449C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022073587A1 (en) 2020-10-06 2022-04-14 Wacker Chemie Ag Method for producing alkyl silicone resins

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022073587A1 (en) 2020-10-06 2022-04-14 Wacker Chemie Ag Method for producing alkyl silicone resins

Also Published As

Publication number Publication date
DE416942C (en) 1925-08-03

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