DE406147C - Process for the production of organic sulfur compounds - Google Patents
Process for the production of organic sulfur compoundsInfo
- Publication number
- DE406147C DE406147C DEE28889D DEE0028889D DE406147C DE 406147 C DE406147 C DE 406147C DE E28889 D DEE28889 D DE E28889D DE E0028889 D DEE0028889 D DE E0028889D DE 406147 C DE406147 C DE 406147C
- Authority
- DE
- Germany
- Prior art keywords
- production
- sulfur compounds
- organic sulfur
- sulfur
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 4
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- 150000002898 organic sulfur compounds Chemical class 0.000 title claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 8
- 229910052717 sulfur Inorganic materials 0.000 claims description 8
- 239000011593 sulfur Substances 0.000 claims description 8
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 3
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims description 3
- 229910052752 metalloid Inorganic materials 0.000 claims description 2
- 150000002738 metalloids Chemical class 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims 1
- 150000003568 thioethers Chemical class 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 9
- 239000007859 condensation product Substances 0.000 description 2
- NGDNCZPCIZNCQS-UHFFFAOYSA-N ctk3j8699 Chemical compound Cl=S NGDNCZPCIZNCQS-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07G—COMPOUNDS OF UNKNOWN CONSTITUTION
- C07G99/00—Subject matter not provided for in other groups of this subclass
- C07G99/002—Compounds of unknown constitution containing sulfur
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Verfahren zur Herstellung von organischen Schwefelverbindungen. Es wurde gefunden, daß den durch Einwirkung von Acetylen auf Kupfer oder dessen Verbindungen erhaltenen Polymerisations-bzw. Kondensationsprodukten des Acetylens, die unter dem Namen Cupren bekannt sind, Schwefel angelagert oder einverleibt werden kann, wenn man die Kondensationsprodukte mit Schwefel oder Sulfiden der Metalloide, z. B. Chlorschwefel, behandelt. Die Behandlung geschieht bei erhöhter Temperatur unter 300° und kann vorteilhaft unter Druck vorgenommen werden. Die erhaltenen Produkte können in der Kautschukindustr ie verwendet werden. Beispiele: i. 5 kg Cupren wurden mit Benzol zu einem dünnen Brei angerührt und zu dieser Aufschlämmung 5 kg Chlorschwefel zugesetzt. Nach zweistündigem Erwärmen am Rückflußkühler wurde filtriert und der Rückstand mit Schwefelkohlenstoff bis zur Erschöpfung extrahiert. Die Analyse des Produktes ergab einen Schwefelgehalt von i i,o Prozent.Process for the production of organic sulfur compounds. It it was found that the action of acetylene on copper or its compounds obtained polymerization or. Condensation products of acetylene, which under are known by the name cuprene, sulfur can be deposited or incorporated, if the condensation products with sulfur or sulfides of the metalloids, eg. B. chlorosulfur treated. The treatment takes place at an elevated temperature below 300 ° and can advantageously be carried out under pressure. The products received can be used in the rubber industry. Examples: i. 5 kg of cups were made mixed with benzene to a thin paste and added to this slurry 5 kg of chlorosulfur added. After two hours of refluxing, the mixture was filtered and the Residue extracted with carbon disulfide until exhaustion. The analysis of the Product gave a sulfur content of i i, o percent.
2. 5 kg Cupren, mit Benzol zu einem Brei angerührt, wurden -wieder mit 5 kg Schwefelchlorür, entsprechend 2,37 kg Schwefel, zwei Stunden lang im Autoklav auf i8o bis 2oo° (io Atm.) erwärmt, filtriert und mit Schwefelkohlenstoff erschöpfend extrahiert. Der Filterrückstand wog getrocknet 6,05 kg, hatte also um 21 Prozent zugenommen. Die Analyse ergab 13,6 Prozent Schwefel und .4 Prozent Chlor.2. 5 kg of cuprene, mixed with benzene to a pulp, were again heated with 5 kg of sulfuric chloride, corresponding to 2.37 kg of sulfur, for two hours in an autoclave to 180 to 200 ° (10 atm.), Filtered and exhausted with carbon disulfide extracted. The dry filter residue weighed 6.05 kg, which means that it had increased by 21 percent. Analysis found 13.6 percent sulfur and .4 percent chlorine.
3. 51g Cupren, mit Benzol angeschlämmt, und 5 kg Schwefel wurden zusammen im Autoklav zwei Stundenlang auf iSo bis igo° erhitzt. Die Masse wurde hierauf abgepreßt, mit Schwefelkohlenstoff extrahiert und getrocknet. Sie enthielt 6,8 Prozent Schwefel.3. 51 g of cupren, slurried with benzene, and 5 kg of sulfur were put together heated in the autoclave to iSo to igo ° for two hours. The mass was then squeezed out extracted with carbon disulfide and dried. It contained 6.8 percent sulfur.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEE28889D DE406147C (en) | 1922-12-30 | 1922-12-30 | Process for the production of organic sulfur compounds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEE28889D DE406147C (en) | 1922-12-30 | 1922-12-30 | Process for the production of organic sulfur compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE406147C true DE406147C (en) | 1924-11-13 |
Family
ID=7073605
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEE28889D Expired DE406147C (en) | 1922-12-30 | 1922-12-30 | Process for the production of organic sulfur compounds |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE406147C (en) |
-
1922
- 1922-12-30 DE DEE28889D patent/DE406147C/en not_active Expired
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