DE3660032D1 - Process for the synthesis of trifluoro-2,2,2-ethanol - Google Patents
Process for the synthesis of trifluoro-2,2,2-ethanolInfo
- Publication number
- DE3660032D1 DE3660032D1 DE8686400802T DE3660032T DE3660032D1 DE 3660032 D1 DE3660032 D1 DE 3660032D1 DE 8686400802 T DE8686400802 T DE 8686400802T DE 3660032 T DE3660032 T DE 3660032T DE 3660032 D1 DE3660032 D1 DE 3660032D1
- Authority
- DE
- Germany
- Prior art keywords
- trifluoro
- ethanol
- synthesis
- hydrogenation
- trifluoroethanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N EtOH Substances CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title 1
- 230000015572 biosynthetic process Effects 0.000 title 1
- 238000003786 synthesis reaction Methods 0.000 title 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 1
- RHQDFWAXVIIEBN-UHFFFAOYSA-N Trifluoroethanol Chemical compound OCC(F)(F)F RHQDFWAXVIIEBN-UHFFFAOYSA-N 0.000 abstract 1
- -1 aliphatic tertiary amine Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 230000002194 synthesizing effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
- C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/34—Halogenated alcohols
- C07C31/40—Halogenated alcohols perhalogenated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Abstract
The process for synthesizing 2,2,2-trifluoroethanol by liquid phase catalytic hydrogenation of a compound of formula: <IMAGE> (I) in which R is a hydrogen atom or a linear or branched alkyl radical containing from 1 to 8 carbon atoms and optionally partially fluorinated, comprising carrying out the hydrogenation in the presence of a nickel catalyst and in the presence of an aliphatic tertiary amine as a cocatalyst.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8506121A FR2580630B1 (en) | 1985-04-23 | 1985-04-23 | PROCESS FOR THE SYNTHESIS OF 2,2,2-TRIFLUORO ETHANOL |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE3660032D1 true DE3660032D1 (en) | 1988-04-14 |
Family
ID=9318543
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE8686400802T Expired DE3660032D1 (en) | 1985-04-23 | 1986-04-15 | Process for the synthesis of trifluoro-2,2,2-ethanol |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US4658070A (en) |
| EP (1) | EP0200621B1 (en) |
| JP (1) | JPS61249941A (en) |
| KR (1) | KR910000773B1 (en) |
| AT (1) | ATE32879T1 (en) |
| AU (1) | AU591114B2 (en) |
| CA (1) | CA1251468A (en) |
| DE (1) | DE3660032D1 (en) |
| DK (1) | DK184386A (en) |
| ES (1) | ES8704438A1 (en) |
| FR (1) | FR2580630B1 (en) |
| GR (1) | GR861048B (en) |
| IE (1) | IE58474B1 (en) |
| IL (1) | IL78561A0 (en) |
| NO (1) | NO162959C (en) |
| ZA (1) | ZA863035B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001068578A1 (en) * | 2000-03-14 | 2001-09-20 | Daikin Industries, Ltd. | Trifluoroacetaldehyde trifluoroethyl hemiacetal and process for producing the same |
| US7560601B2 (en) | 2006-04-28 | 2009-07-14 | Kuraray Co., Ltd. | Method for producing 3-methyl-1,5-pentanediol |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1229058B (en) * | 1963-06-22 | 1966-11-24 | Hoechst Ag | Process for the production of 1, 1, 1-trifluoroethanol |
| JPS6059219B2 (en) * | 1981-11-18 | 1985-12-24 | セントラル硝子株式会社 | Method for producing 2-trifluoromethylpropanol |
| GB8334566D0 (en) * | 1983-12-29 | 1984-02-01 | Ici Plc | Chemical process |
| FR2567876B1 (en) * | 1984-07-18 | 1986-11-28 | Atochem | PROCESS FOR THE PREPARATION OF PURE FLUORAL AND HEXAFLUOROACETONE HYDRATES FROM HEMACETALS |
| FR2567875B1 (en) * | 1984-07-18 | 1986-08-08 | Atochem | PROCESS FOR THE SYNTHESIS OF TRIFLUORO-2,2,2 ETHANOL AND ALCOHOL HEXAFLUORO-1,1,1,3,3,3 ISOPROPYLIC |
-
1985
- 1985-04-23 FR FR8506121A patent/FR2580630B1/en not_active Expired
-
1986
- 1986-04-15 EP EP86400802A patent/EP0200621B1/en not_active Expired
- 1986-04-15 DE DE8686400802T patent/DE3660032D1/en not_active Expired
- 1986-04-15 AT AT86400802T patent/ATE32879T1/en not_active IP Right Cessation
- 1986-04-21 US US06/854,103 patent/US4658070A/en not_active Expired - Fee Related
- 1986-04-21 IL IL78561A patent/IL78561A0/en not_active IP Right Cessation
- 1986-04-21 GR GR861048A patent/GR861048B/en unknown
- 1986-04-22 IE IE107286A patent/IE58474B1/en not_active IP Right Cessation
- 1986-04-22 CA CA000507304A patent/CA1251468A/en not_active Expired
- 1986-04-22 KR KR1019860003104A patent/KR910000773B1/en not_active Expired
- 1986-04-22 DK DK184386A patent/DK184386A/en not_active Application Discontinuation
- 1986-04-22 NO NO861574A patent/NO162959C/en unknown
- 1986-04-22 ES ES554243A patent/ES8704438A1/en not_active Expired
- 1986-04-22 AU AU56471/86A patent/AU591114B2/en not_active Ceased
- 1986-04-23 JP JP61094402A patent/JPS61249941A/en active Granted
- 1986-04-23 ZA ZA863035A patent/ZA863035B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ES8704438A1 (en) | 1987-04-01 |
| IE861072L (en) | 1986-10-23 |
| KR910000773B1 (en) | 1991-02-06 |
| KR860008113A (en) | 1986-11-12 |
| FR2580630B1 (en) | 1987-05-29 |
| AU591114B2 (en) | 1989-11-30 |
| EP0200621A1 (en) | 1986-11-05 |
| JPS61249941A (en) | 1986-11-07 |
| NO162959C (en) | 1990-03-14 |
| NO861574L (en) | 1986-10-24 |
| DK184386A (en) | 1986-10-24 |
| ZA863035B (en) | 1986-12-30 |
| FR2580630A1 (en) | 1986-10-24 |
| GR861048B (en) | 1986-08-12 |
| IL78561A0 (en) | 1986-08-31 |
| JPS6311334B2 (en) | 1988-03-14 |
| ATE32879T1 (en) | 1988-03-15 |
| EP0200621B1 (en) | 1988-03-09 |
| US4658070A (en) | 1987-04-14 |
| IE58474B1 (en) | 1993-09-22 |
| NO162959B (en) | 1989-12-04 |
| ES554243A0 (en) | 1987-04-01 |
| AU5647186A (en) | 1986-10-30 |
| CA1251468A (en) | 1989-03-21 |
| DK184386D0 (en) | 1986-04-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |