DE347129C - Process for the production of lightfast colors and lacquers - Google Patents
Process for the production of lightfast colors and lacquersInfo
- Publication number
- DE347129C DE347129C DE1914347129D DE347129DD DE347129C DE 347129 C DE347129 C DE 347129C DE 1914347129 D DE1914347129 D DE 1914347129D DE 347129D D DE347129D D DE 347129DD DE 347129 C DE347129 C DE 347129C
- Authority
- DE
- Germany
- Prior art keywords
- parts
- acid
- production
- lacquers
- extra
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 3
- 238000004519 manufacturing process Methods 0.000 title description 2
- 239000003086 colorant Substances 0.000 title 1
- 239000004922 lacquer Substances 0.000 title 1
- 239000002253 acid Substances 0.000 claims description 10
- 239000000975 dye Substances 0.000 claims description 7
- 150000007513 acids Chemical class 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 claims description 2
- 125000003277 amino group Chemical group 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 2
- 239000002966 varnish Substances 0.000 claims description 2
- 210000002268 wool Anatomy 0.000 description 4
- ZUYFLSARRQBQPE-UHFFFAOYSA-M [Cl-].[Ba+] Chemical compound [Cl-].[Ba+] ZUYFLSARRQBQPE-UHFFFAOYSA-M 0.000 description 3
- IHZXTIBMKNSJCJ-UHFFFAOYSA-N 3-{[(4-{[4-(dimethylamino)phenyl](4-{ethyl[(3-sulfophenyl)methyl]amino}phenyl)methylidene}cyclohexa-2,5-dien-1-ylidene)(ethyl)azaniumyl]methyl}benzene-1-sulfonate Chemical compound C=1C=C(C(=C2C=CC(C=C2)=[N+](C)C)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S(O)(=O)=O)=C1 IHZXTIBMKNSJCJ-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- IYDGMDWEHDFVQI-UHFFFAOYSA-N phosphoric acid;trioxotungsten Chemical compound O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.OP(O)(O)=O IYDGMDWEHDFVQI-UHFFFAOYSA-N 0.000 description 2
- SHBDDIJUSNNBLQ-UHFFFAOYSA-M sodium;3-[[4-[(2-chlorophenyl)-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]cyclohexa-2,5-dien-1-ylidene]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)Cl)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SHBDDIJUSNNBLQ-UHFFFAOYSA-M 0.000 description 2
- XOSXWYQMOYSSKB-LDKJGXKFSA-L water blue Chemical compound CC1=CC(/C(\C(C=C2)=CC=C2NC(C=C2)=CC=C2S([O-])(=O)=O)=C(\C=C2)/C=C/C\2=N\C(C=C2)=CC=C2S([O-])(=O)=O)=CC(S(O)(=O)=O)=C1N.[Na+].[Na+] XOSXWYQMOYSSKB-LDKJGXKFSA-L 0.000 description 2
- IKHKJYWPWWBSFZ-UHFFFAOYSA-N 4-[[4-(diethylamino)phenyl]-(4-diethylazaniumylidenecyclohexa-2,5-dien-1-ylidene)methyl]benzene-1,3-disulfonate;hydron Chemical compound C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S(O)(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 IKHKJYWPWWBSFZ-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- RGCKGOZRHPZPFP-UHFFFAOYSA-N Alizarin Natural products C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- DGOBMKYRQHEFGQ-UHFFFAOYSA-L acid green 5 Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C=CC(=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 DGOBMKYRQHEFGQ-UHFFFAOYSA-L 0.000 description 1
- HFVAFDPGUJEFBQ-UHFFFAOYSA-M alizarin red S Chemical compound [Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C=C(S([O-])(=O)=O)C(O)=C2O HFVAFDPGUJEFBQ-UHFFFAOYSA-M 0.000 description 1
- AOADSHDCARXSGL-ZMIIQOOPSA-M alkali blue 4B Chemical compound CC1=CC(/C(\C(C=C2)=CC=C2NC2=CC=CC=C2S([O-])(=O)=O)=C(\C=C2)/C=C/C\2=N\C2=CC=CC=C2)=CC=C1N.[Na+] AOADSHDCARXSGL-ZMIIQOOPSA-M 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- 229910052601 baryte Inorganic materials 0.000 description 1
- 239000010428 baryte Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- ARZVLGVDYAMAFX-UHFFFAOYSA-L disodium 6-amino-4-hydroxy-5-[(4-nitro-2-sulfonatophenyl)diazenyl]naphthalene-2-sulfonate Chemical compound [Na+].[Na+].Nc1ccc2cc(cc(O)c2c1N=Nc1ccc(cc1S([O-])(=O)=O)[N+]([O-])=O)S([O-])(=O)=O ARZVLGVDYAMAFX-UHFFFAOYSA-L 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B69/00—Dyes not provided for by a single group of this subclass
- C09B69/02—Dyestuff salts, e.g. salts of acid dyes with basic dyes
- C09B69/06—Dyestuff salts, e.g. salts of acid dyes with basic dyes of cationic dyes with organic acids or with inorganic complex acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67316—Acids
- D06P1/67325—Complex acids, e.g. phosphomolybdic, phosphotungstic, molybdotungstic
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Coloring (AREA)
- Paper (AREA)
Description
In dem Patent 286467 und dessen Zusatz 289878 ist ein Verfahren zur Herstellung von . Farblacken aus basischen Teerfarbstoffen beschrieben, dadurch gekennzeichnet, daß diese Farbstoffe mit Phosphormetawolframsäure, anderen Phosphorwolframsäuren oder 'analogen komplexen Säuren behandelt werden. Die so erzeugten Lacke zeichnen sich durch gute Lichtechtheit aus.In the patent 286467 and its addition 289878 is a method for the production of . Color lakes from basic tar dyes, characterized in that these Dyes with phosphotungstic acid, other phosphotungstic acids or 'analogues complex acids are treated. The paints produced in this way are characterized by good quality Lightfastness.
Es wurde nun gefunden^ daß man auch saure Farbstoffe, welche außer der Sulfogruppe eine oder mehrere Aminogruppen enthalten, auf der Textilfaser, Papier, Holz, Leder, Gelatine usw. und als Lacke dadurch lichtechter machen kann, daß man sie mit komplexen Metawolframsäuren oder ihren Salzen, wie Kieselwolframsäure, Phosphorwolframsäure, Antimonwolframsäure, behandelt.It has now been found that one can also use acidic dyes which, in addition to the sulfo group contain one or more amino groups on the textile fiber, paper, wood, leather, gelatin etc. and as varnishes can be made more lightfast by using complex metatungstic acids or their salts, such as Silicatungstic acid, phosphotungstic acid, antimony tungstic acid.
Beispiel 1.
r Example 1.
r
Wolle wird in üblicher Weise mit beispielsweise ι Prozent Brillantwollblau FFR extra ι Stunde kochend gefärbt, dem Bade nach dieser Zeit 1 Prozent Phosphormetawolframsäure zugesetzt und weitere 15 Minuten gekocht. Wool is extra in the usual way with, for example, ι percent brilliant wool blue FFR Colored at the boil for 1 hour, after this time 1 percent phosphometatungstic acid is added to the bath added and cooked for another 15 minutes.
Dem auf übliche Weise angesetzten Färbebad wird die gleiche Menge Phosphormetawolframsäure wie Farbstoff zugesetzt, mit dem Färbegut eingegangen und 1 Stunde kochend gefärbt.The same amount of phosphometungstic acid is added to the dyebath prepared in the usual way like dye added, taken with the dyed material and boiled for 1 hour colored.
. Beispiel 3.. Example 3.
Zu einem Substrat, das beispielsweise folgende Zusammensetzung hat:For a substrate that has the following composition, for example:
10 Teile schwefels. Tonerde 18 Prozent Al2 O3 ι: 10 gelöst,10 parts of sulfur. Alumina 18 percent Al 2 O 3 ι: 10 dissolved,
5 Teile Soda kalz. 1:10 gelöst,
50 Teile Schwerspat,5 parts soda lime. 1:10 solved,
50 parts barite,
11 Teile Chlorbarium krist. 1:10 gelöst,
gibt man die Lösung von11 parts chlorobarium crystall. 1:10 solved,
give the solution of
3 Teilen Brillantsäuregrün 6 B oder Alkaliblau-, Baumwollblau-, Wasserblaumarken, 3 Teilen Phosphormetawolframsäure 1; 10 gelöst3 parts brilliant acid green 6 B or alkali blue, cotton blue, water blue brands, 3 parts of phosphometungstic acid 1; 10 solved
und fällt mit 4 Teilen Chlorbarium krist. ι: 10 gelöst den Farbstoff aus.and falls with 4 parts of chlorobarium crystalline. ι: 10 dissolved the dye.
100 Teile einer ioprozentigen Tonerdeblancfixepaste werden mit einer Lösung von 2 Teilen Brillantwollblau FFR extra in Wasser versetzt und mit 3 Teilen Chlorbarium krist. ι: 10 gefällt. Der Fällung werden 2 Teile gelöste Phosphormetawolframsäure hinzugefügt.100 parts of an 10% alumina blanc fix paste are treated with a solution of 2 parts of brilliant wool blue FFR extra in water and 3 parts of chlorbarium crystall. ι: 10 like. 2 parts are dissolved in the precipitation Phosphometungstic acid added.
Papierbrei, enthaltend 100 Teile trockne Cellulose, wird mit 0,5 Teilen Brillantwollblau FFR extra gefärbt, darauf mit 0,5 Teilen phosphormetawolframsaurem Natrium versetzt und wie üblich aufgearbeitet. Die Leimung ist ohne Einfluß auf den Lichtechtheitseffekt.Paper pulp containing 100 parts of dry cellulose is mixed with 0.5 parts of brilliant wool blue FFR colored extra, then mixed with 0.5 part of sodium phosphometatungstate and worked up as usual. The sizing has no effect on the lightfastness effect.
Ein sümachgares Schaffell wird gut geweicht, 20 Minuten mit 3,75 Teilen Phosphormetawolframsäure behandelt und mit beigegebenen 3,75 Teilen Brillantsäuregrün 6 B gefärbt.A curdled sheepskin is soaked well for 20 minutes with 3.75 parts of phosphometatungstic acid treated and colored with the added 3.75 parts of Brilliant Acid Green 6B.
Ebenso kann man andere als die in den Beispielen angegebenen Farbstoffe, wie z. B. gäureviolett7BN, Säureviolett R extra, Säureviolett 4 B extra, Alizarinuranol 2 B, Säuregrün GG extra, Brillantsäureblau A, B, EG, V usw., verwenden.You can also use other than those given in the examples dyes, such. B. acid violet 7BN, acid violet R extra, acid violet 4 B extra, alizarin uranol 2 B, acid green Use GG extra, brilliant acid blue A, B, EG, V etc.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE347129T | 1914-11-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE347129C true DE347129C (en) | 1922-01-12 |
Family
ID=33459976
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT286467D Active DE286467C (en) | 1914-11-01 | ||
| DE1914347129D Expired DE347129C (en) | 1914-11-01 | 1914-11-01 | Process for the production of lightfast colors and lacquers |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT286467D Active DE286467C (en) | 1914-11-01 |
Country Status (2)
| Country | Link |
|---|---|
| DE (2) | DE347129C (en) |
| GB (1) | GB143242A (en) |
-
0
- DE DENDAT286467D patent/DE286467C/de active Active
-
1914
- 1914-11-01 DE DE1914347129D patent/DE347129C/en not_active Expired
-
1920
- 1920-05-12 GB GB1316120A patent/GB143242A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB143242A (en) | 1921-04-14 |
| DE286467C (en) |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69902243T2 (en) | TRIPHENDIOXAZINE DYES FOR COLORING ORGANIC SUBSTRATES | |
| DE347129C (en) | Process for the production of lightfast colors and lacquers | |
| DE1467473A1 (en) | Process for the production of a modified colored pigment | |
| DE372345C (en) | Process for the production of a binder for tempera and watercolor paints | |
| DE729230C (en) | Process for printing animal fibers or cellulose fibers or fiber mixtures thereof with chromium stain dyes | |
| DE557197C (en) | Process for the production of metal-containing azo dyes | |
| DE734415C (en) | Process for the production of water-insoluble azo dyes on cellulose fibers | |
| DE521613C (en) | Process for the production of colorings or prints on fiber material consisting entirely or partially of cellulose acetate or on films made of cellulose acetate | |
| DE403002C (en) | Process for the production of lightfast colored lacquers | |
| DE488199C (en) | Process for the production of colored lacquers | |
| DE587652C (en) | Process for the preparation of monoazo dyes | |
| AT100707B (en) | Process for dyeing or printing acetyl cellulose. | |
| DE336629C (en) | Process for making yellow dyes | |
| DE541072C (en) | Process for dyeing or printing cellulose esters or ethers | |
| DE611522C (en) | Process for coloring rubber and rubber-like compounds | |
| DE441984C (en) | Process for developing Kuepen dyes on the fiber | |
| DE563793C (en) | Process for coloring rubber | |
| DE679767C (en) | Process for dyeing and printing textile fabrics made from cellulose fibers with ester salts of leukokuepen dyes | |
| DE920267C (en) | Process for the production of water-insoluble azo dyes | |
| DE617718C (en) | Preparations made from salts of leuco-sulfuric acid esters of dyes derived from benzanthrone | |
| DE641874C (en) | Process for the production of ice colors in stuff printing | |
| DE1518628A1 (en) | Process for the production of diethylaminocellulose | |
| DE382923C (en) | Process for the production of yellow Kuepen dyes | |
| AT55539B (en) | Process for producing true colorations on the fiber. | |
| DE423611C (en) | Process for improving printing inks removable from paper |