DE3029400A1 - AGENT FOR HOUSEHOLD LAUNDRY AND METHOD - Google Patents
AGENT FOR HOUSEHOLD LAUNDRY AND METHODInfo
- Publication number
- DE3029400A1 DE3029400A1 DE19803029400 DE3029400A DE3029400A1 DE 3029400 A1 DE3029400 A1 DE 3029400A1 DE 19803029400 DE19803029400 DE 19803029400 DE 3029400 A DE3029400 A DE 3029400A DE 3029400 A1 DE3029400 A1 DE 3029400A1
- Authority
- DE
- Germany
- Prior art keywords
- washing
- wash
- approx
- program
- fatty acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims description 9
- 238000005406 washing Methods 0.000 claims description 24
- 239000004753 textile Substances 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 6
- 239000003599 detergent Substances 0.000 claims description 5
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 239000012948 isocyanate Substances 0.000 claims description 4
- 150000002513 isocyanates Chemical class 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 239000012084 conversion product Substances 0.000 claims description 2
- 239000000314 lubricant Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 230000037303 wrinkles Effects 0.000 description 5
- YQEMORVAKMFKLG-UHFFFAOYSA-N 2-stearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 229920000151 polyglycol Polymers 0.000 description 2
- 239000010695 polyglycol Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 229920004934 Dacron® Polymers 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- JXCHMDATRWUOAP-UHFFFAOYSA-N diisocyanatomethylbenzene Chemical compound O=C=NC(N=C=O)C1=CC=CC=C1 JXCHMDATRWUOAP-UHFFFAOYSA-N 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000002979 fabric softener Substances 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 230000037330 wrinkle prevention Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3726—Polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
- 2 - Case 150-4466- 2 - Case 150-4466
Die vorliegende Erfindung betrifft die Faltenverhinderung beim Waschen von Textilien in Haushalt- und Industrie-Trommel-Waschmaschinen sowie Mittel zur Faltenverhinderung in Waschprozessen.The present invention relates to wrinkle prevention in washing of textiles in household and industrial drum washing machines as well Preparations for preventing wrinkles in washing processes.
Es ist bekannt, dass es beim Waschen von Textilien in Haushalt- oder Industrie-Wäschereien auf Trommelwaschmaschinen sehr oft zur Faltenbildung und sogenannten Brüchen kommt, die die nachfolgenden Bügel- und/oder Glätteoparationen erschweren, oder fast verunmöglichen. Wenn grössere Mengen an Textilien in kleinen Waschflotten behandelt werden, vor allem bei überladenen Waschmaschinen, kommt dies besonders häufig vor. Bei synthetischen Fasern, wie Polyainid-jPblyester-jPolyacrylfaser und deren Mischungen mit'natürliehen - Fasern, vor allembei höheren Waschtemperaturen, oder auch beim Schleudern der nassen War©n,vor allem unter feuchtwarinen Bedingungen, kommt es ebenfalls zu unerwünschten Faltenbildungen und Brüchen. Wenn man bei solchen empfindlichen Geweben oder Gewirken die Trommelwaschmaschinen nicht überlädt,kann dieser Vorgang oft vermieden werden, jedoch wird der Ausnutzungsgrad der Maschinen hierdurch herabgesetzt.It is known to be used when washing textiles in household or industrial laundries on drum washing machines very often wrinkles and so-called breaks occur, which are followed by ironing and / or Make smooth operations difficult or almost impossible. Especially when large quantities of textiles are treated in small wash liquors This is particularly common with overloaded washing machines. In the case of synthetic fibers such as polyainide / polyester / polyacrylic fibers and their blends mit'naturliehen - fibers, especially at higher washing temperatures, or also when spinning wet wares, especially under humid conditions, there are also undesirable wrinkles and breaks. If you use the drum washing machines for such delicate fabrics or knitted fabrics does not overload, this process can often be avoided, but the utilization rate of the machines is reduced.
Es ist oft üblich, nach dem eigentlichen Waschprozess eine Nachbehandlung der Textilien mit meist kationischen sogenannten Weichspülmitteln durchzuführen, um hierdurch der Ware den gewünschten weichen Griff zu vermitteln und die Waschsprödigkeit zu überwinden. Solche Additive sind beispielsweise bekannte quaternäre Ammoniumverbindungen, vor allem das Distearyl-di-methylammoniumchlorid, bzw. dessen Alkoxyalkylderivate. Auch Dialkylimidazoliniumverbindungen finden hierfür Verwendung.Diese Produkte begünstigen zwar den Griff, jedoch wird die Faltenbildung meist nicht beeinflusst.It is often common to have a follow-up treatment after the actual washing process of the textiles with mostly cationic so-called fabric softeners in order to give the goods the desired soft feel and to overcome the washing brittleness. Such additives are, for example, known quaternary ammonium compounds, especially that Distearyl-dimethylammonium chloride or its alkoxyalkyl derivatives. Dialkylimidazolinium compounds are also used for this purpose Although products favor the grip, the formation of wrinkles is usually not influenced.
Bei der Verwendung von Gleitmitteln , die heute in der Färberei Anwendung finden, können nun auch in Waschvorgängen die oben aufgezeichneten Nachteile vermieden werden und falten- und bruchfreie Textilien können auchWhen using lubricants, which are now used in dyeing find, the disadvantages listed above can now also be avoided in washing processes and wrinkle-free and break-free textiles can also be used
tilt Φ C'tilt Φ C '
- 3 - Case 150-4466- 3 - Case 150-4466
in Haushalt- und Industriewaschmaschinen verwirklicht werden.be realized in household and industrial washing machines.
Gegenstand der vorliegenden Erfindung ist eine Verfahren zum Waschen von Textilien, dadurch gekennzeichnet, dass die Wäsche in Gegenwart von noch wasserlöslichen bzw. emulgierbaren Isocyanatumsetzungsprodukten alkoxy-The present invention is a method for washing Textiles, characterized in that the laundry in the presence of isocyanate conversion products that are still water-soluble or emulsifiable is alkoxy
lierter Verbindungen und/oder Fettsäuremono- oder -diglyceriden durchgeführt wird.lated compounds and / or fatty acid mono- or diglycerides carried out will.
Gegenstand der Erfindung sind weiter Waschmittel zur Durchführung des vorbeschriebenen Verfahrens sowie die derart gewaschenen Textilien.The invention also relates to detergents for carrying out the above Process and the textiles washed in this way.
Ueberraschenderweise werden nicht nur die oben angeführten Mängel vor allem die Falten- und Bruchbildung beim Waschen vermieden sondern durch den Einsatz der genannten speziellen Hilfsmittel wird eine Erhöhung der Weichheit erzielt. Weiter reduzieren die Gleitmittel die Haftreibung zwischen den Fasern und Garnen.Surprisingly, not only are the shortcomings listed above especially the formation of wrinkles and breaks during washing is avoided but through the use of the special aids mentioned, an increase in the Softness achieved. The lubricants further reduce the static friction between the fibers and yarns.
Die Mengen, in welchen die erfindungsgemäss zu verwendenden Mittel zum Einsatz kommen, liegen im allgemeinen zwischen 0,5g/l und 50g/l, speziell bei 0,5g/l bis 30g/l und vorzugsweise bei l-5g/l Waschflotte.The amounts in which the agents to be used according to the invention for Are used, are generally between 0.5g / l and 50g / l, especially 0.5g / l to 30g / l and preferably l-5g / l wash liquor.
Die erfindungsgemäss zu verwendenden Gleitmittel sind bekannt und teilweise als Färbereihilfsmittel im Handel. Sie sollen eine gewisse Wasserlöslichkeit, bzw. Wasserdispergierbarkeit von mindestens 1 g/l, vorteilhafter mindestens 25 g/l bei 20°C besitzen, wobei diese mindestens über einen Zeitraum von 12 Stunden bei Raumtemperatur stabil sein soll. Die Viskosität der 0,5%-igen Lösung soll bei 200C 100 cp nicht überschreiten.The lubricants to be used according to the invention are known and some of them are commercially available as dyeing auxiliaries. They should have a certain water solubility or water dispersibility of at least 1 g / l, more advantageously at least 25 g / l at 20 ° C., and this should be stable for at least 12 hours at room temperature. The viscosity of the 0.5% solution is at 20 0 C 100 does not exceed cp.
Die bevorzugte Gruppe der erfindungsgemäss zu verwendenden Mittel sind die Isocyanatumsetzungsprodukte oxalkylierter Verbindungen, in welchen noch freie OH-Endgruppen vorhanden sind. Besonders vorteilhaft sind die in der DE-OS 2 805 230 genannten Verbindungen, besonders die dort in den Anwendungsbeispielen 1-3 verwendeten Mittel des Beispiels 14 (Urasetzungsprodukt von rriäthanolamin mit Aethylenoxyd und weiter mit Tcluylendiisocyanat zum entsprechenden Polyurethan umgesetzt).The preferred group of agents to be used according to the invention are the isocyanate reaction products of alkoxylated compounds in which free OH end groups are still present. Are particularly advantageous the compounds mentioned in DE-OS 2 805 230, especially the agents of Example 14 used there in Application Examples 1-3 (Urasetzungproduct of triethanolamine with ethylene oxide and further with Tcluylendiisocyanat converted to the corresponding polyurethane).
- 4 - Case 150-4466.- 4 - Case 150-4466.
Weiter geeignet sind auch die Fettsäuremöno- oder -digylceride (also solche mit mindesten einer freien OH-Gruppe am Glycerin-Rest), vor allem die Monoglyceride, wobei der Fettsäurerest ein C, -C , ,vor allemein C -C1 „ Rest ist.Also suitable are the fatty acid mono- or diglycerides (i.e. those with at least one free OH group on the glycerol residue), especially the monoglycerides, the fatty acid residue being a C, -C, especially a C -C 1 "residue .
14 24 16 1814 24 16 18
Die Löslichkeits- bzw. Wasserdispergierbarkeit kann weiter verbessert werden durch Tenside, vor allem solche nicht-ionogener Art, wie z.B. Fettalkohol-polyglykoläther und ähnliche.The solubility or water dispersibility can be further improved by surfactants, especially those of a non-ionic type, such as fatty alcohol polyglycol ethers and similar.
Die nachfolgenden Beispiele erläutern das Verfahren, Teile sind Gewichtsteile oder Volumenteile, Prozente Gewichtsprozente, Temperaturangaben erfolgen in 0C.The following examples explain the process, parts are parts by weight or parts by volume, percentages are percentages by weight, temperatures are given in 0 C.
Die nachfolgenden Beispiele werden wie folgt durchgeführt:The following examples are carried out as follows:
Als Waschmaschine wurde eine vollautomatische Trommelwaschmaschine (Marke Schulthess Super 4) mit einem Inhalt der Waschtrommel von 38 dm einge- setzt. Die Steuerung des Waschprogrammes erfolgt durch Programmträger. Die Füllmenge beträgt 1,2 kg Gesamtgewicht (trockenes Material) und 22 1 kaltes Wasser (ca. 11° dH). Das Flottenverhältnis beträgt beim Waschen ca. 1:16 und beim Spülen ca. 1:20. Die Anzahl und Grosse der Versuchsmuster betragen 3 pro Qualität, Länge 40 cm / Breite 30 cm. Sämtliche Muster werden mit der Zackenschere geschnitten und die Kanten geschmolzen (Synthetik + Mischungen) um ein Ausfransen zu verhindern. Als Bailas tmaterial wird Baum-A fully automatic drum washing machine (brand Schulthess Super 4) with a washing drum content of 38 dm is used. The washing program is controlled by program carriers. the Filling amount is 1.2 kg total weight (dry material) and 22 liters cold Water (approx. 11 ° dH). The liquor ratio when washing is approx. 1:16 and when rinsing approx. 1:20. The number and size of the test samples are 3 per quality, length 40 cm / width 30 cm. All patterns are cut with pinking scissors and the edges melted (synthetic + mixtures) to prevent fraying. Tree-
woll-Popeline gebl./merc, 105 g/m Mustergrösse ca. 40 χ 30 cm verwendet. Die Beladung der Waschmaschine erfolgt so, dass zuerst das Ballastmaterial, anschliessend die diversen Versuchsmuster einzeln, leicht zusammengeballt, in die Trommel geworfen werden. Die Lage der Versuchsmuster in der Wasch- · maschine wird während der Behandlung nicht beeinflusst und bleibt rein zufällig.wool poplin blended / merc, 105 g / m sample size approx. 40 χ 30 cm used. The washing machine is loaded in such a way that first the ballast material, then the various test samples individually, are lightly clumped together, be thrown into the drum. The position of the test sample in the washing machine is not influenced during the treatment and remains pure coincidentally.
In der Vor- und Hauptwäsche werden jeweils 2 g/l des erfindungsgemäss zu verwendenden Gleitmittels zugegeben. Das Waschmittel in der Vor- und Haupt-In the pre-wash and main wash, 2 g / l of the according to the invention are added using lubricant added. The detergent in the pre- and main
- 5 - Case 150-4466- 5 - Case 150-4466
wasche ist ein handelsübliches. Die Waschmittelmenge beträgt in der Heisswäsche 60° und in der Kochwäsche 93°, ca. 1 g/l. Die Waschmittel- und Gleitmittelzugabe erfolgt - bei der Vor- und Hauptwäsche - zusammen mit dem Wassereinlauf.wash is a commercially available one. The amount of detergent is in the hot wash 60 ° and in the whites 93 °, approx. 1 g / l. Detergent and lubricant are added together with the pre- and main wash the water inlet.
Das Waschprogramm erfolgt nach DIN 53 920. Bei der Heisswäsche (60°) (Programm Nr. 4) erreicht die Temperatur in der Vorwäsche 40°, bei der Haupcwäsche 60°, die Waschdauer bei Hochs temperatur beträgt 10 min. Die Trommelbewegung erfolgt beim Waschen ab ca. 40° im Schongang (etwa 9 s Lauf, etwa 6 s Stillstand), beim Spülen im Normalgang (etwa 13,5 s Lauf, etwa 1,5 s Stillstand).The washing program is carried out in accordance with DIN 53 920. For hot washing (60 °) (program No. 4), the temperature in the prewash reaches 40 °, in the main wash 60 °, the washing time at high temperature is 10 minutes. approx. 6 s standstill), when rinsing in normal mode (approx. 13.5 s run, approx. 1.5 s standstill).
Das Spülen läuit zunächst als Pendelspülen ab, daran schliessen sich 3 normale Spülgänge an. Das letzte Spülwasser wird nicht automatisch abgepumpt (Spülstop).The rinse starts off as a pendulum rinse, followed by 3 normal rinse cycles. The last rinse water is not automatically pumped out (rinse hold).
Anschliessend wird abgepumpt (Programmkarte der Maschine wird um eine Position weitergeschoben) und ca. 16 s lang mit etwa 400 U/mih. geschleudert. Die Dauer des Programms bis zum Spülstop beträgt ca. 84 min.Then it is pumped out (program card of the machine is increased by one Position pushed further) and for approx. 16 s at approx. 400 rev / mih. hurled. The duration of the program up to the rinse hold is approx. 84 minutes.
Bei der Kochwäsche (93°) (Programm Nr. 2) erreicht die Temperatur in der Vorwäsche 40°, in der Hauptwäsche 93°. Die Waschdauer bei dieser Temperatur beträgt 10 min. Die Trommelbewegung erfolgt bis etwa 80° und während der Nachwaschzeit weitgehend itn Schongang 1, sonst im Normalgang (siehe oben).With the whites (93 °) (program no. 2) the temperature reaches the Prewash 40 °, main wash 93 °. The washing time at this temperature is 10 minutes and the drum moves up to about 80 ° and during the post-wash time largely in gentle cycle 1, otherwise in normal cycle (see above).
Das Spülen und Schleudern verläuft analog Programm Nr. 4. Die Dauer des Programms bis zum Spülstop beträgt ca. 120 min.Rinsing and spinning are the same as in program no. 4. The duration of the The program until the rinse stop is approx. 120 minutes.
Nach beendeter Waschbehandlung (inkl. Schleudergang) werden die Versuchsmuster frei hängend bei Raumtemperatur getrocknet.After completion of the washing treatment (including the spin cycle), the test samples Dried freely hanging at room temperature.
ORIGINAL INSPECTEDORIGINAL INSPECTED
«· ■-"*--·■ 3023400«· ■ -" * - · ■ 3023400
- 6 - Case 150-4466 -- 6 - Case 150-4466 -
Beispiel 1example 1
Als Substrate dienen Nylon-Satin, Nylon spun, Dacron 54-spun, Orion 75-spun sowie PES/Co 50/50 und PES/Co 67/33, alle Wash and Wear ausgerüstet.The substrates used are nylon satin, nylon spun, Dacron 54-spun, orion 75-spun as well as PES / Co 50/50 and PES / Co 67/33, all wash and wear equipped.
Als Gleitmittel wurdeUsed as a lubricant
1) ein Umsetzungsprodukt von Triäthanolamin, Aethylenoxyd und Toluylen-diisocyanat (Beispiel 14, DE-OS 2 805 230) und1) a reaction product of triethanolamine, ethylene oxide and toluylene diisocyanate (Example 14, DE-OS 2 805 230) and
•2) Glycerin-monostearat ' . '. • 2) glycerine monostearate '. '.
verwendet.used.
B e i s ρ i e 1 2 B e is ρ ie 1 2
Als Substrat dient Co-Popeline, welches Wash and Wear ausgerüstet'ist.Co-poplin, which is Wash and Wear equipped, serves as the substrate.
Als Gleitmittel werden die in Beispiel 1 genannten verwendet, wobei das Gleitmittel 2) (Glycerinmonostearat) im Gemisch mit 25% Oleylpolyglykoläther (22 Mol AeO) verwendet wurde.The lubricants mentioned in Example 1 are used, the Lubricant 2) (glycerine monostearate) mixed with 25% oleyl polyglycol ether (22 moles AeO) was used.
Bewertung der Beispiele:Evaluation of the examples:
Die gewaschenen und getrockneten Versuchsmuster wurden visuell nach der Schärfe und Anzahl der Falten resp.' Bruch- und Knitterstellen sowie aufgrund des gesamten Glättebildes beurteilt, wobei die Effektbewertung auf der Grundlage des paarweisen Vergleiches sowie in Vergleich gegen den 5-stüfigen Monsanto-Standard durchgeführt wurde.The washed and dried test samples were visually after Sharpness and number of folds resp. ' Breakages and creases as well as due to of the entire smoothness image assessed, with the effect evaluation on the basis of the pairwise comparison as well as in comparison against the 5-step Monsanto standard was carried out.
In allen Fällen war das Ergebnis gut.In all cases the result was good.
3700/WM/BG
30.07.19803700 / WM / BG
07/30/1980
Claims (2)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19803029400 DE3029400A1 (en) | 1980-08-02 | 1980-08-02 | AGENT FOR HOUSEHOLD LAUNDRY AND METHOD |
| CH4712/81A CH649590A5 (en) | 1980-08-02 | 1981-07-17 | METHOD FOR WASHING TEXTILES AND MEANS TO PREVENT WRINKLES IN WASHING PROCESSES. |
| DE19813128580 DE3128580A1 (en) | 1980-08-02 | 1981-07-20 | Composition for domestic laundry and method |
| FR8114379A FR2487873A1 (en) | 1980-08-02 | 1981-07-22 | WASHING PRODUCT AND METHOD |
| BE1/10279A BE889715A (en) | 1980-08-02 | 1981-07-23 | WASHING PRODUCT AND METHOD |
| IT8148965A IT1209882B (en) | 1980-08-02 | 1981-07-24 | WASHING PROCESS FOR TEXTILE MATERIALS |
| GB8123583A GB2081760B (en) | 1980-08-02 | 1981-07-31 | Improvements in or relating to organic compounds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19803029400 DE3029400A1 (en) | 1980-08-02 | 1980-08-02 | AGENT FOR HOUSEHOLD LAUNDRY AND METHOD |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE3029400A1 true DE3029400A1 (en) | 1982-04-29 |
Family
ID=6108772
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19803029400 Withdrawn DE3029400A1 (en) | 1980-08-02 | 1980-08-02 | AGENT FOR HOUSEHOLD LAUNDRY AND METHOD |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE889715A (en) |
| CH (1) | CH649590A5 (en) |
| DE (1) | DE3029400A1 (en) |
| FR (1) | FR2487873A1 (en) |
| GB (1) | GB2081760B (en) |
| IT (1) | IT1209882B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4236109A1 (en) * | 1992-10-26 | 1994-04-28 | Henkel Kgaa | Liquid detergent |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2749705A1 (en) * | 1976-11-17 | 1978-05-18 | Sandoz Ag | TEXTILE FINISHING AIDS |
| DE2412175B2 (en) * | 1974-03-14 | 1979-06-28 | Chemische Fabrik Kreussler & Co Gmbh, 6200 Wiesbaden | Process for finishing textiles during dry cleaning |
| DE2805230A1 (en) * | 1978-02-08 | 1979-08-09 | Sandoz Ag | Hydroxyalkyl gp-contg. polyurethane used as textile lubricant - is prepd. by reacting poly:isocyanate with oxyalkylated amine, amide or poly:ol |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU3394971A (en) * | 1970-10-20 | 1973-04-05 | Colgate Palmolive Co | Conditioning of fabrics |
| US3763047A (en) * | 1971-05-03 | 1973-10-02 | Procter & Gamble | Detergent compositions |
| BE779630R (en) * | 1972-02-21 | 1972-08-21 | Unilever Nv | Detergent compsns - contg non-ionic detergents and aliphatic esters as solvents |
| AU2101577A (en) * | 1976-01-09 | 1978-07-13 | Procter & Gamble Company, The | Fabric treatment processes and compositions |
-
1980
- 1980-08-02 DE DE19803029400 patent/DE3029400A1/en not_active Withdrawn
-
1981
- 1981-07-17 CH CH4712/81A patent/CH649590A5/en not_active IP Right Cessation
- 1981-07-22 FR FR8114379A patent/FR2487873A1/en active Granted
- 1981-07-23 BE BE1/10279A patent/BE889715A/en not_active IP Right Cessation
- 1981-07-24 IT IT8148965A patent/IT1209882B/en active
- 1981-07-31 GB GB8123583A patent/GB2081760B/en not_active Expired
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2412175B2 (en) * | 1974-03-14 | 1979-06-28 | Chemische Fabrik Kreussler & Co Gmbh, 6200 Wiesbaden | Process for finishing textiles during dry cleaning |
| DE2749705A1 (en) * | 1976-11-17 | 1978-05-18 | Sandoz Ag | TEXTILE FINISHING AIDS |
| DE2805230A1 (en) * | 1978-02-08 | 1979-08-09 | Sandoz Ag | Hydroxyalkyl gp-contg. polyurethane used as textile lubricant - is prepd. by reacting poly:isocyanate with oxyalkylated amine, amide or poly:ol |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2487873A1 (en) | 1982-02-05 |
| CH649590A5 (en) | 1985-05-31 |
| IT8148965A0 (en) | 1981-07-24 |
| BE889715A (en) | 1982-01-25 |
| GB2081760A (en) | 1982-02-24 |
| IT1209882B (en) | 1989-08-30 |
| FR2487873B1 (en) | 1984-11-09 |
| GB2081760B (en) | 1984-04-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OM8 | Search report available as to paragraph 43 lit. 1 sentence 1 patent law | ||
| 8143 | Lapsed due to claiming internal priority |