DE296922C - - Google Patents
Info
- Publication number
- DE296922C DE296922C DENDAT296922D DE296922DA DE296922C DE 296922 C DE296922 C DE 296922C DE NDAT296922 D DENDAT296922 D DE NDAT296922D DE 296922D A DE296922D A DE 296922DA DE 296922 C DE296922 C DE 296922C
- Authority
- DE
- Germany
- Prior art keywords
- gasoline
- soap
- acid
- oxygen
- detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000344 soap Substances 0.000 claims description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 8
- 239000003599 detergent Substances 0.000 claims description 5
- 235000019270 ammonium chloride Nutrition 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 229960001922 sodium perborate Drugs 0.000 claims description 4
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 2
- 238000004880 explosion Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical class CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000011975 tartaric acid Substances 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/24—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/06—Inorganic compounds
- C11D9/08—Water-soluble compounds
- C11D9/10—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/06—Inorganic compounds
- C11D9/08—Water-soluble compounds
- C11D9/10—Salts
- C11D9/12—Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/42—Per-compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Description
tlriltlril
Gegenstand der Erfindung ist ein Verfahren zur Herstellung eines Waschmittels, das Seife, Benzin und einen Sauerstoffträger enthält. Die Mischung von Benzin oder Benzol mit einem Sauerstoffträger, z. B. Natriumperborat, ist nun gefährlich, da hierdurch leicht eine Oxydation des Benzins- herbeigeführt werden kann, was Explosionen zur Folge hat. Um eine solche Oxydation zu verhindern, wirdThe invention relates to a process for the production of a detergent, the soap, Contains gasoline and an oxygen carrier. The mixture of gasoline or benzene with an oxygen carrier, e.g. B. sodium perborate, is now dangerous, as this easily a Oxidation of the gasoline can be brought about, which results in explosions. Around to prevent such oxidation will
ίο nun nach vorliegender Erfindung dem Waschmittel kohlensaures Alkali zugegeben und diesem eine äquivalente Menge einer Säure zugefügt. Wird das so erhaltene "Waschmittel bei der Anwendung mit Wasser erhitzt, so wird neben Benzin und Sauerstoff Kohlensäure frei, so daß die Benzindämpfe von dieser eingehüllt werden und somit eine Verbrennung verhindert wird.ίο now according to the present invention the detergent carbonate added and this added an equivalent amount of an acid. If the detergent obtained in this way is heated with water during use, so carbonic acid is released in addition to gasoline and oxygen, so that the gasoline vapors from this be enveloped and thus a burn is prevented.
Statt kohlensauren Alkalis kann gegebenenfalls auch Ammoniumchlorid (Salmiak) verwendet werden. Beim Waschen tritt eine Hydrolyse der Seife ein, das dabei entstehende freie Alkali macht aus dem Salmiak Ammoniak frei, welches auch eine Oxydation der Benzindämpfe verhindert.Instead of carbonate alkalis, ammonium chloride (salmia) can also be used if necessary will. When washing, the soap hydrolyses, which is the result Free alkali releases ammonia from ammonia, which also oxidizes gasoline vapors prevented.
Es kann also das nach vorliegender Erfindung hergestellte Waschmittel ohne jede Gefahr verwendet werden. Dabei wird aber die Bleichwirkung des Sauerstoffs auf die Wäschefaser durch die Zugabe des Schutzmittels in keiner Weise beeinflußt.The detergent produced according to the present invention can therefore be used without any risk be used. In doing so, however, the bleaching effect of the oxygen on the laundry fiber is reduced not influenced in any way by the addition of the protective agent.
Das vorliegende Verfahren wird in zwei Phasen ausgeführt.The present procedure is carried out in two phases.
i. Zur Bildung des Sauerstoffträgers wird Natriumperborat mit Natriumcarbonat enthaltender Seife oder Seifenpulver gemischt und dieser Mischung eine Säure (Zitronensäure, Weinsteinsäure o. dgl.), welche mit Zukker, Gelatine, Kieselsäure usw. eingehüllt ist, zugefügt, undi. To form the oxygen carrier, sodium perborate is mixed with sodium carbonate Soap or soap powder mixed and this mixture contains an acid (citric acid, tartaric acid or the like), which is mixed with sugar, Gelatin, silica, etc. is encased, added, and
2. zur Bildung der Benzinseife wird das Benzin so behandelt, daß es mit Wasser eine Emulsion bildet, und daß diese dann der Seife eingekrückt und dadurch von dieser umhüllt wird.2. To form the gasoline soap, the gasoline is treated in such a way that it has a Forms emulsion, and that this is then indented by the soap and thus enveloped by it will.
Man erhält also bei diesem Beispiel zunächst zwei Stoffe, den Sauerstoffträger und die Benzinseife. Diese beiden Stoffe können nun gemischt oder auch'getrennt aufbewahrt werden.In this example, you first get two substances, the oxygen carrier and the petrol soap. These two substances can now be mixed or stored separately will.
In der Praxis kann das Verfahren beispielsweise in folgender Weise ausgeführt werden:In practice, for example, the method can be carried out in the following way:
Zur Erzeugung des vorstehend unter 1. genannten Sauerstoffträgers werden 3 Teile Natriumbikarbonat enthaltendes Seifenpulver mit ι Teil einer Säure gemischt (Weinsteinsäure oder Zitronensäure, die Säure ist in Kieselsäure eingehüllt) und 10 Prozent Natriumperborat (auf Benzinseife gerechnet) zugefügt, während zur Erzeugung der unter 2. oben erwähnten Benzinseife 2 Teile Seife mit 1 Teil Benzin unter Zusatz von entsprechenden Mengen Wasser zu einer Emulsion vereinigt werden. To generate the oxygen carrier mentioned under 1. above, 3 parts of sodium bicarbonate are used containing soap powder mixed with ι part of an acid (tartaric acid or citric acid, the acid is encased in silica) and 10 percent sodium perborate (calculated on petrol soap) added, while to produce the petrol soap mentioned under 2. above, 2 parts of soap with 1 part Gasoline can be combined to form an emulsion with the addition of appropriate amounts of water.
Bei dem zweiten erwähnten Ausführungsbeispiele wird statt Natriumcarbonat und Säure Ammoniumchlörid, welches mit Gelatine, Zucker o. dgl. umhüllt ist, angewendet.In the second exemplary embodiment mentioned, instead of sodium carbonate and Acid ammonium chloride, which is coated with gelatin, sugar or the like. Is used.
's. Auflage, ausgegeben am rr. Mai 's. Edition, issued on rr. May
Die Benzinemulsion kann auch in der WeiseThe gasoline emulsion can also be used in the way
hergestellt werden, daß 2 Teile Fettsäure in 5 Teilen Benzin oder Benzol gelöst und dieser Mischung 1 Teil Natronlauge 38 ° Be und 1,1 Teil Alkohol zugefügt werden.be prepared that 2 parts of fatty acid dissolved in 5 parts of gasoline or benzene and this Mixture 1 part sodium hydroxide solution 38 ° Be and 1.1 part alcohol are added.
Beim Gebrauch werden beide Stoffe in einen mit kaltem Wasser gefüllten Waschbottich gegeben und dann dessen Inhalt erhitzt. Durch das warme Wasser wird der Überzug der Säure gelöst und diese sowie das von der Seife eingehüllte Benzin oder Benzol frei. Bei etwa 40° beginnt die Kohlensäureentwicklung, bei welcher Temperatur auch die Sauerstoflentwicklung anfängt, und ist am Ende der letzteren bei etwa 100° ebenfalls beendet. Die entstehende Kohlensäure verhütet, wie oben schon angegeben wurde, eine Entzündung des Benzins.When in use, both fabrics are placed in a wash tub filled with cold water given and then heated its contents. The warm water makes the Coating of the acid dissolved and this as well as the gasoline or benzene enveloped by the soap free. At about 40 ° the carbonic acid development begins, at which temperature also the Oxygen evolution begins, and is at the end of the latter at about 100 ° as well completed. The resulting carbonic acid prevents, as has already been stated above, a Ignition of the gasoline.
Bei der Anwendung von Ammoniumchlorid (Salmiak) statt Natriumcarbonat und Säure tritt genau dieselbe Wirkung ein.When using ammonium chloride (salmia) instead of sodium carbonate and acid exactly the same effect occurs.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE148329X | 1915-12-10 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE296922C true DE296922C (en) |
Family
ID=5672624
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT296922D Active DE296922C (en) | 1915-12-10 |
Country Status (4)
| Country | Link |
|---|---|
| DE (1) | DE296922C (en) |
| FR (1) | FR518522A (en) |
| GB (1) | GB148329A (en) |
| NL (1) | NL4957C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2980621A (en) * | 1956-08-07 | 1961-04-18 | Bittenfield Morris | Spotting composition |
-
0
- DE DENDAT296922D patent/DE296922C/de active Active
- NL NL4957D patent/NL4957C/xx active
-
1920
- 1920-07-01 FR FR518522A patent/FR518522A/en not_active Expired
- 1920-07-09 GB GB20243/20A patent/GB148329A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB148329A (en) | 1921-11-09 |
| FR518522A (en) | 1921-05-27 |
| NL4957C (en) |
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