DE2814329A1 - Washing agents contg. N-vinyl-oxazolidone polymers - inhibiting transfer of dyes from coloured textiles onto white textiles - Google Patents
Washing agents contg. N-vinyl-oxazolidone polymers - inhibiting transfer of dyes from coloured textiles onto white textilesInfo
- Publication number
- DE2814329A1 DE2814329A1 DE19782814329 DE2814329A DE2814329A1 DE 2814329 A1 DE2814329 A1 DE 2814329A1 DE 19782814329 DE19782814329 DE 19782814329 DE 2814329 A DE2814329 A DE 2814329A DE 2814329 A1 DE2814329 A1 DE 2814329A1
- Authority
- DE
- Germany
- Prior art keywords
- vinyl
- means according
- acid
- copolymer
- textiles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- XHULUQRDNLRXPF-UHFFFAOYSA-N 3-ethenyl-1,3-oxazolidin-2-id-4-one Chemical compound C(=C)N1[CH-]OCC1=O XHULUQRDNLRXPF-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 229920000642 polymer Polymers 0.000 title claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 14
- 230000002401 inhibitory effect Effects 0.000 title claims description 4
- 239000004753 textile Substances 0.000 title abstract description 15
- 238000005406 washing Methods 0.000 title description 14
- 239000000975 dye Substances 0.000 title description 9
- 229920001577 copolymer Polymers 0.000 claims abstract description 25
- 239000000654 additive Substances 0.000 claims abstract description 6
- 125000000129 anionic group Chemical group 0.000 claims abstract description 6
- 150000001875 compounds Chemical class 0.000 claims description 25
- 239000003599 detergent Substances 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 12
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 claims description 10
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 8
- -1 methacrylic compound Chemical class 0.000 claims description 7
- 239000003945 anionic surfactant Substances 0.000 claims description 5
- 238000002845 discoloration Methods 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 3
- 239000012459 cleaning agent Substances 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- 229920001519 homopolymer Polymers 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 abstract description 3
- 239000002253 acid Substances 0.000 description 22
- 150000003839 salts Chemical class 0.000 description 13
- 239000011734 sodium Substances 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- 239000000194 fatty acid Substances 0.000 description 9
- 229910052708 sodium Inorganic materials 0.000 description 9
- 150000007513 acids Chemical class 0.000 description 8
- 239000007844 bleaching agent Substances 0.000 description 8
- 235000014113 dietary fatty acids Nutrition 0.000 description 8
- 229930195729 fatty acid Natural products 0.000 description 8
- 150000004665 fatty acids Chemical class 0.000 description 8
- 239000004744 fabric Substances 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000012190 activator Substances 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 239000003513 alkali Substances 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 239000000344 soap Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000004952 Polyamide Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000013543 active substance Substances 0.000 description 4
- 150000001447 alkali salts Chemical class 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 239000003112 inhibitor Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- 229920002647 polyamide Polymers 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000003760 tallow Substances 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical class COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical class C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical class CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 150000002825 nitriles Chemical class 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229920001451 polypropylene glycol Polymers 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical class OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 230000000536 complexating effect Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 229940088598 enzyme Drugs 0.000 description 2
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 125000004494 ethyl ester group Chemical group 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 2
- 239000000391 magnesium silicate Substances 0.000 description 2
- 229910052919 magnesium silicate Inorganic materials 0.000 description 2
- 235000019792 magnesium silicate Nutrition 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 2
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- YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 description 1
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- JDSQBDGCMUXRBM-UHFFFAOYSA-N 2-[2-(2-butoxypropoxy)propoxy]propan-1-ol Chemical group CCCCOC(C)COC(C)COC(C)CO JDSQBDGCMUXRBM-UHFFFAOYSA-N 0.000 description 1
- UGFSLKRMHPGLFU-UHFFFAOYSA-N 2-[5-(1,3-benzoxazol-2-yl)thiophen-2-yl]-1,3-benzoxazole Chemical compound C1=CC=C2OC(C3=CC=C(S3)C=3OC4=CC=CC=C4N=3)=NC2=C1 UGFSLKRMHPGLFU-UHFFFAOYSA-N 0.000 description 1
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- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 238000001792 White test Methods 0.000 description 1
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 1
- 125000000738 acetamido group Chemical group [H]C([H])([H])C(=O)N([H])[*] 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Substances CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000003926 acrylamides Chemical class 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 229940025131 amylases Drugs 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 229960001506 brilliant green Drugs 0.000 description 1
- HXCILVUBKWANLN-UHFFFAOYSA-N brilliant green cation Chemical compound C1=CC(N(CC)CC)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](CC)CC)C=C1 HXCILVUBKWANLN-UHFFFAOYSA-N 0.000 description 1
- KDPAWGWELVVRCH-UHFFFAOYSA-N bromoacetic acid Chemical class OC(=O)CBr KDPAWGWELVVRCH-UHFFFAOYSA-N 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000004202 carbamide Chemical class 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001734 carboxylic acid salts Chemical class 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- YOCIQNIEQYCORH-UHFFFAOYSA-M chembl2028361 Chemical compound [Na+].OC1=CC=C2C=C(S([O-])(=O)=O)C=CC2=C1N=NC1=CC=CC=C1 YOCIQNIEQYCORH-UHFFFAOYSA-M 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- 229940106681 chloroacetic acid Drugs 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- AFYCEAFSNDLKSX-UHFFFAOYSA-N coumarin 460 Chemical compound CC1=CC(=O)OC2=CC(N(CC)CC)=CC=C21 AFYCEAFSNDLKSX-UHFFFAOYSA-N 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 150000001470 diamides Chemical class 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical group OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical class C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical group C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 235000019239 indanthrene blue RS Nutrition 0.000 description 1
- UHOKSCJSTAHBSO-UHFFFAOYSA-N indanthrone blue Chemical compound C1=CC=C2C(=O)C3=CC=C4NC5=C6C(=O)C7=CC=CC=C7C(=O)C6=CC=C5NC4=C3C(=O)C2=C1 UHOKSCJSTAHBSO-UHFFFAOYSA-N 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 150000008040 ionic compounds Chemical class 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- VRIVJOXICYMTAG-IYEMJOQQSA-L iron(ii) gluconate Chemical compound [Fe+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O VRIVJOXICYMTAG-IYEMJOQQSA-L 0.000 description 1
- 229920005684 linear copolymer Polymers 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- LWXVCCOAQYNXNX-UHFFFAOYSA-N lithium hypochlorite Chemical compound [Li+].Cl[O-] LWXVCCOAQYNXNX-UHFFFAOYSA-N 0.000 description 1
- MBKDYNNUVRNNRF-UHFFFAOYSA-N medronic acid Chemical compound OP(O)(=O)CP(O)(O)=O MBKDYNNUVRNNRF-UHFFFAOYSA-N 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- JFZUABNDWZQLIJ-UHFFFAOYSA-N methyl 2-[(2-chloroacetyl)amino]benzoate Chemical compound COC(=O)C1=CC=CC=C1NC(=O)CCl JFZUABNDWZQLIJ-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- CXHHBNMLPJOKQD-UHFFFAOYSA-N methyl hydrogen carbonate Chemical group COC(O)=O CXHHBNMLPJOKQD-UHFFFAOYSA-N 0.000 description 1
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- UFOIOXZLTXNHQH-UHFFFAOYSA-N oxolane-2,3,4,5-tetracarboxylic acid Chemical compound OC(=O)C1OC(C(O)=O)C(C(O)=O)C1C(O)=O UFOIOXZLTXNHQH-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001444 polymaleic acid Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- BXNRKCXZILSQHE-UHFFFAOYSA-N propane-1,2,3-triol;sulfuric acid Chemical compound OS(O)(=O)=O.OCC(O)CO BXNRKCXZILSQHE-UHFFFAOYSA-N 0.000 description 1
- KCXFHTAICRTXLI-UHFFFAOYSA-M propane-1-sulfonate Chemical compound CCCS([O-])(=O)=O KCXFHTAICRTXLI-UHFFFAOYSA-M 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019351 sodium silicates Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 125000005420 sulfonamido group Chemical group S(=O)(=O)(N*)* 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 229950009390 symclosene Drugs 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 229920006027 ternary co-polymer Polymers 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical class [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 239000001226 triphosphate Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Waschmittel mit einem Gehalt an verfärbungsinhibierenden ZusätzenLaundry detergent with a content of discoloration-inhibiting additives
Gegenstand der vorliegenden Erfindung ist ein Wasch- und Reinigungsmittel, das neben üblicherweise in derartigen Mitteln vorhandenen Tensiden, Gerüstsalzen, Bleichmitteln und sonstigen Begleitstoffen eine Verbindung enthält, die einer Farbstoffübertragung von farbigen Textilien auf weiße oder hellfarbige Textilien während eines gemeinsamen Waschens entgegenwirken. Aus der DE-OS 22 32 353 sind derartige Mittel bereits bekannt, wobei der die Farbstoffübertragung inhibierende Wirkstoff aus Polyvinylpyrrolidon besteht. Diese Mittel weisen jedoch Nachteile auf, die einmal darin bestehen, daß die Wirkung gegenüber einer Reihe von Ausfärbungen bzw, Textilien sehr gering ist und zum anderen, daß die Anwendung des Inhibitors auf solche Waschmittel beschränkt ist, die keine anionischen Tenside enthalten. Aniontenside zählen jedoch wegen ihrer vielseitigen anwendungstechnischen Vorteile zu den wichtigsten bzw. gebräuchlichsten Waschmittelbestandteilen.The present invention is a detergent and cleaning agent, in addition to surfactants, framework salts, Bleach and other accompanying substances contain a compound that causes dye transfer from colored textiles to white or light-colored textiles during a joint Counteracting washing. From DE-OS 22 32 353 such means are already known, wherein the dye transfer inhibiting agent is polyvinylpyrrolidone consists. However, these means have disadvantages that are once that the effect on a number of dyeings or textiles is very low and on the other hand, that the use of the inhibitor is limited to such detergents that do not contain anionic surfactants. However, anionic surfactants count because of them versatile application-related advantages to the most important or most common Detergent ingredients.
Durch die vorliegende Erfindung werden die aufgezeigten Nachteile vermieden. Gegenstand der Erfindung ist ein Wasch- und Reinigungsmittel, enthaltend anionische und/ oder nichtionische Tenside, Gerüstsubstanzen und sonstige übliche Waschmittelzusätze, gekennzeichnet durch einen auf das Gesamtgewicht der Mittel bezogenen Gehalt an 0,1 bis 5 Gew.-% an einem in Wasser löslichen bzw. dispergierbaren Homo- bzw. Copolymeren des N-Vinyloxazolidons.The disadvantages indicated are eliminated by the present invention avoided. The invention relates to a washing and cleaning agent containing anionic and / or nonionic surfactants, builders and other common ones Detergent additives, characterized by one based on the total weight of the agent based content of 0.1 to 5 wt .-% of a water-soluble or dispersible Homo- or copolymers of N-vinyl oxazolidone.
Der Polymerisationsgrad der Polymeren kann innerhalb weiter Grenzen liegen und beträgt beispielsweise 10 bis 10000, vorzugsweise jedoch 20 bis 5000. Da die Bestimmung des ttolekulargewic}ltes und damit des Polymerisationsgrades vielfach schwierig ist, wird meist die spezifische Viskosität als Maß für den Polymerisationsgrad angegeben. Erfindungsgemäß gut geeignet sind Polymere und Copolymere mit einer in 1-gewichtsprozentigex wäßriger Lösung bei 20 °C bestimmten spezifischen Viskosität von 0,01 bis 5 und insbesonuere von 0,1 bis 1. Die Elerstellung der Polyneren, für die kein Schutz begehrt wird, kann in bekannter Weise durch radikalisch initiierte erfolgen, wobei in wäßriger Lösung oder in einem organischen Lösungsmittel gearbeitet werden kann.The degree of polymerization of the polymers can be within wide limits are and is, for example, 10 to 10,000, but preferably 20 to 5000. Since the determination of the molecular weight and thus the degree of polymerisation is multiple is difficult, the specific viscosity is usually considered Measure for indicated the degree of polymerization. According to the invention, polymers and are well suited Copolymers with a 1% by weight aqueous solution at 20 ° C determined specific viscosity from 0.01 to 5 and in particular from 0.1 to 1. The preparation the polymers, for which no protection is sought, can in a known manner by radical initiated take place in aqueous solution or in an organic solvent can be worked.
Außer dem homopolymeren Poly-N-vinyloxazolidon, das sich als sehr wirksam erwiesen hat, kommen lineare und vernetzte Copolymere in Frage. Zur Bildung linearer Copolymere geeignete, eine olefinische Doppelbindung aufweisende Verbindungen sind: Kohlenwasserstoffe wie Äthylen, Propylen und Styrol; Vinyl- bzw. Allylverbindungen, wie Vinylmethyläther, Vinyläthyläther, Allylmethyläther, Allyläthyläther, Vinylacetat und -propionat (die gyf. nach der Copolymerisation ganz oder teilweise verseift sein können), Allylacetat, Allylalkohol, N-Vinylpyrrolidon und N-Vinyloxazol idon sowie Derivate der Acryl- bzw. ethacrylsäure, z.B. deren Methyl- oder Äthylester, Amide und Nitrile; Derivate olefinischer Di cariJonsäuren, wie die Methyl- und Äthylester, Diamide und Nitrile der Maleinsäure und Fumarsäure. Besonders geeignete copolymerisierbare Verbindungen sind N-Vinylpyrrolidon, N-Vinyloxazolidon, Vinylacetat und (MetI)-Acrylamid. Es können auch mehrere der vorgenannten copolymerisierbaren Verbindungen in einem Copolymeren eingesetzt werden Besonders geeignete Terpolymere sind z.13. die des N-Vinyloxazolidons mit N-Vinylimidazol und N-VinylpyrroliLon. in den Copolymeren soll der Anteil des N-Vinyloxazolläons mindestens 25 I6l%, vozugsweise mindestens 30 ZQ] --q und insbesondere mindestens 50 Mol-% betragen. In solchen Copolymerell, bei deren Herstellung so'..?ohl von N-Vinylox@zolidon als auch von N-Vinylimidazol ausgegangen wird, oll der molare Anteil des N-Vinyloxazolidons großer sein als der des N-Vinylimidazols.Except for the homopolymeric poly-N-vinyloxazolidone, which has proven to be very has proven effective, linear and crosslinked copolymers come into question. For education compounds having an olefinic double bond which are suitable for linear copolymers are: hydrocarbons such as ethylene, propylene and styrene; Vinyl or allyl compounds, such as vinyl methyl ether, vinyl ethyl ether, allyl methyl ether, allyl ethyl ether, vinyl acetate and propionate (which may be wholly or partially saponified after copolymerization can be), allyl acetate, allyl alcohol, N-vinylpyrrolidone and N-vinyloxazolidone as well as derivatives of acrylic or ethacrylic acid, e.g. their methyl or ethyl esters, Amides and nitriles; Derivatives of olefinic dicarionic acids, such as the methyl and ethyl esters, Diamides and nitriles of maleic acid and fumaric acid. Particularly suitable copolymerizable ones Compounds are N-vinylpyrrolidone, N-vinyloxazolidone, vinyl acetate and (MetI) -acrylamide. Several of the aforementioned copolymerizable compounds can also be used in one Copolymers are used Particularly suitable terpolymers are e.g. the des N-Vinyloxazolidons with N-Vinylimidazole and N-VinylpyrroliLon. in the copolymers should the proportion of N-Vinyloxazolläons at least 25 I6l%, preferably at least 30 ZQ] --q and in particular at least 50 mol%. In such copolymers in their production so '..? ohl of N-Vinylox @ zolidon as well as of N-vinylimidazole It is assumed that the molar proportion of N-vinyloxazolidone should be greater than that of N-vinylimidazole.
Beispiele für besonders geeignete Copolymere sind demnach solche aus N-Vinyloxazolidon und N-Vinylpyrrolidon im Molverhältnis 1 : 2 bis 100 : 1, des N-Vinyloxazolidons und des N-Vinylimidazols im Molverhältnis 1 : 0,99 bis 100 : 1 sowie des ternären Copolymeren aus N-Vinyloxazolidon, N-Vinylpyrrolidon und N-Vinylimidazol im Molverhältnis 1 : 1 : 0,99 bis 100 : 1 : 1 bzw. 100 : 100 : 1 bz. 100 : 1 : 99.Examples of particularly suitable copolymers are accordingly those from N-vinyloxazolidone and N-vinylpyrrolidone in a molar ratio of 1: 2 to 100: 1, des N-vinyl oxazolidone and N-vinyl imidazole in a molar ratio of 1: 0.99 to 100: 1 and the ternary copolymer of N-vinyloxazolidone, N-vinylpyrrolidone and N-vinylimidazole in a molar ratio of 1: 1: 0.99 to 100: 1: 1 or 100: 100: 1 or 100: 1: 99.
Schließlich können die Copolymeren auch unter Mitverwendung von Verbindungen mit 2 oder mehr copolymerisierbaren Doppelbindungen hergestellt werden. Da solche copolymerisierbaren Verbindungen zu dreidimensional vernetzten Polymeren mit hoher Viskosität und abnehmender Wasserlöslichkeit führen, soll ihr Anteil weniger als 10 Mol-%, vorzugsweise weniger als 5 Mol-% bezogen auf insgesamt anwesende polymerisierbare Verbindungen betragen. Beispiele für geeignete Verbindungen sind Methylen-bis-acrylamid, Divinylbenzol, Triallylcyanurat und Tetraallyloxyethan.Finally, the copolymers can also be used with compounds with 2 or more copolymerizable double bonds. Because such copolymerizable compounds to three-dimensionally crosslinked polymers with high Viscosity and decreasing water solubility lead, their proportion should be less than 10 mol%, preferably less than 5 mol%, based on the total amount of polymerizable Connections amount. Examples of suitable compounds are methylene-bis-acrylamide, Divinylbenzene, triallyl cyanurate and tetraallyloxyethane.
Der Gehalt der erfindungsgemäßen Mittel an den Homo- bzw.The content of the agents according to the invention in the homo- or
Copolymeren des N-Vinyloxazolidons beträgt 0,1 bis 10,vorzugsweise 0,2 bis 5 und insbesondere 0,5 bis 4 Gew.-%.Copolymers of N-vinyl oxazolidone is 0.1 to 10, preferably 0.2 to 5 and in particular 0.5 to 4% by weight.
Außer den genannten Polymeren enthalten die erfindungsgemäßen Mittel noch anionische und/oder nichtionische Tenside sowie die Waschkraft verstärkende bzw. Erdaikaliionen bindende Gerüstsubstanzen. Geeignete weitere Bestandteile sind Waschalkalien, Neutral salze, Bleichmittel, vergrauungsverhütende Mittel, optische Aufheller, Enzyme und Stabilisatoren sowie weitere, in Waschmitteln üblicherweise eingesetzte Hilfs-und Zusatzstoffe' Geeignete anionische Waschaktivsubstanzen sind solche vom Sulfonat- oder Sulfattyp, beispielsweise Alkylbenzolsul fonate , insbesondere n-Vodecylbenzolsulfonat, ferner Olefinsul fonate, h'-Sulfofettsäureester, primäre und sekundäre Alkylsulfate sowie die Sulfate von ätho4ylierten oder propoxylierten höhermolekularen Alkoholen.In addition to the polymers mentioned, the agents according to the invention contain also anionic and / or nonionic surfactants and detergency enhancing agents or structural substances that bind alkaline ions. Suitable further ingredients are Washing alkalis, neutral salts, bleaching agents, anti-graying agents, optical ones Brighteners, enzymes and stabilizers as well as others, usually in detergents Auxiliaries and additives used are suitable anionic washing active substances those of the sulfonate or sulfate type, for example alkylbenzene sulfonates, in particular n-Vodecylbenzenesulfonate, also Olefinsul fonate, h'-sulfofatty acid ester, primary and secondary alkyl sulfates as well as the sulfates of ethoxylated or propoxylated higher molecular weight alcohols.
Weitere Verbinduagen dieser Klasse, die gegebenenfalls in den Waschmitteln vorliegen können, sind die höhermolekularen sulfatierten Partialäther und Part-ialester von mehrwertigen Alkoholen, wie die Alkalisalze der Monoalkyläther bzw. der MonoSettsäureester des Glycerinmonoschwefelsäurees ters bzw.Other compounds of this class that may be used in detergents are the higher molecular weight sulfated partial ethers and partial esters of polyhydric alcohols, such as the alkali salts of the monoalkyl ethers or the mono-fatty acid esters of glycerol monosulfuric acid or
der l,2-Dioxypropansulfonsäure. Ferner kommen Sulfate von äthoxylierten oder propoxylierten Fettsäureainiden und Alkylphenolen sowie Fettsäuretauride und Fettsäureisät'nionate in Frage. Weitere geeignete anionische Waschrohstoffe sind Alkaliseifen von Fettsäuren natürlichen oder synthetischen Ursprungs, z.B. die Natriunseifen von Zokos-, Palmkern- oder Talgfettsäuren.of 1,2-dioxypropanesulfonic acid. Furthermore, sulfates come from ethoxylated or propoxylated fatty acid amides and alkylphenols and fatty acid taurides and Fettäureisät'nionate in question. Other suitable anionic detergent raw materials are Alkaline soaps of fatty acids of natural or synthetic origin, e.g. sodium soaps of coconut, palm kernel or tallow fatty acids.
Die anionischen Waschrohstoffe können in Form der Natrium-, Kalium- und Ammoniumsalze sowie als Salze organischer Basen, wie Mono-, Di- oder Triäthanolamin, vorliegen. Sofern die genannten anionischen und zwitterionischen Verbindungen einen aliphatischen Kohlenwasserstoffrest besitzen, soll dieser bevorzugt geradkettig sein und 8 bis 22 Kohlenstoffatome auf weisen. In den Verbindungen mit einem araliphatischer Kohlenwasserstoffrest enthalten die vorzugsweise unverzweigten Alkylketten im Mittel 6 bis 15 Kohlenstoffatome.The anionic detergent raw materials can be in the form of sodium, potassium and ammonium salts and as salts of organic bases, such as mono-, di- or triethanolamine, are present. If the anionic and zwitterionic compounds mentioned have a have an aliphatic hydrocarbon radical, this should preferably be straight-chain and have 8 to 22 carbon atoms. In compounds with an araliphatic The preferably unbranched alkyl chains contain hydrocarbon radicals on average 6 to 15 carbon atoms.
Als nichtionische oberflächenaktive Waschaktivsubstanzen kommen in erster Linie Polyglylkolätherderivate von Alkoholen, Fettsäuren und Alkylphenolen in Frage, die 3 bis 30 Glykoläthergruppen und 8 bis 20 Kohlenstoffatome im Kohlern"asserstoffrest enthalten. Besonders geeignet sind Polyglykolther derivate, in denen die Zahl der Äthylenglykoläthergruppen 5 bis 15 beträgt und deren Kohlenwasserstoffreste sich von geradkettigen, primären Alkoholen mit 12 bis 18 Kohlenstoffatomen oder von Alkylphenolen mit einer geradkettigen, 6 bis 14 Lohlenstoffatome aufweisenden Alkylkette ableiten.As nonionic surface-active washing-active substances come in primarily polyglylcol ether derivatives of alcohols, fatty acids and alkylphenols in question, the 3 to 30 glycol ether groups and 8 to 20 carbon atoms in Kohlern "hydrogen radical contain. Polyglykolther derivatives in which the number of Ethylene glycol ether groups is 5 to 15 and their hydrocarbon radicals of straight-chain, primary alcohols with 12 to 18 carbon atoms or of alkylphenols derive with a straight-chain alkyl chain having 6 to 14 carbon atoms.
Weitere geeignete nichtionische Waschrohstoffe sind die wasser -löslichen, 20 bis 250 Äthylenglykoläthergruppen und 10 bis tC3 Propyl englykoläthergrup en enthaltenden Polyäthylenoxidaddukte e an Polypropylenglykol> Äthylendiaminopolypropylenglykol und Alkylpolypropylenglykol mit 1 bis 10 Kohlenstoffatomen in der Alkylkette. Die genannten Verbirdungen enthalten üblicherweise pro Propylenglykol-Einheit 1 bis 5 Äthylenglyileinheiten.Other suitable non-ionic washing raw materials are the water-soluble, 20 to 250 ethylene glycol ether groups and 10 to tC3 propylene glycol ether groups containing polyethylene oxide adducts with polypropylene glycol> ethylenediamine polypropylene glycol and alkyl polypropylene glycol having 1 to 10 carbon atoms in the alkyl chain. the Verbirdungen mentioned usually contain 1 to per propylene glycol unit 5 ethylene glycol units.
Aucb nichtionische Verbindungen vom Typ der Aminoxide und Sulfoxide, die gegebenenfalls auch äthoxyliert sein können, sind verwendbar.Also non-ionic compounds of the amine oxide and sulfoxide type, which can optionally also be ethoxylated can be used.
Es können auch zwitterionische Waschaktivsubstanzen mitverwendet werden, wie Alkylbetaine und Alkylsulfobetaine, z.B. Zwitterionic washing active substances can also be used such as alkyl betaines and alkyl sulfobetaines, e.g.
das 3-(N,N-Dimethyl-N-alkylammonium)-propan-1-sulfonat und 3- ( N , N-Dimethyl-N-alkylammonium)-2-hydroxypropan-1-sulfonat. 3- (N, N-dimethyl-N-alkylammonium) propane-1-sulfonate and 3- (N , N-dimethyl-N-alkylammonium) -2-hydroxypropane-1-sulfonate.
Als Gerüstsubstanzen können Phosphate verwendet werden, wie Pentanatriumtriphosphat und dessen Gemische mit dessen Hydrolyseprodukten, d.h.-tiatriumpyro- und Orthophosphaten bzw. den besonders zur Herstellung flüssiger Waschmittel geeigneten sauren und neutralen Kaliumpyrophosphaten. Phosphates, such as pentasodium triphosphate, can be used as builder substances and its mixtures with its hydrolysis products, i.e. tiatrium pyro and orthophosphates or the acidic and neutral detergents, which are particularly suitable for the production of liquid detergents Potassium pyrophosphates.
Andere geeignete Gerüstsubstanzen sind komplexierend wirkende Aminopolycarbonsäuren. Hierzu zählen insbesondere Alkalisalze der Nitrilotriessigsäure und A-Lhylendiaminotetraessigsäure. Geeignet sind ferner die Salze der Diäthylentriaminopentaessigsäure sowie der höheren Homologen der genannten Aminow polycarbonsäure. Diese Homologe können beispielsweise durch Polymerisation eines Esters, Amids oder Nitrils des N-Essigsätireaziridins und anschließende Verseifung zu carbonsauren Salzen oder durch Umsetzung von Polyäthylenimin mit chloressigsauren oder bromessigsauren Salzen in alkalischem Milieu hergestellt werden. Weitere geeignete Aminopolycarbonsäuren sind Poly-(N-bernsteinsäure)-äthylenimin, Poly-(N-tricarballylsäure)-äthylenimin und Poly-(N-butan-2,3,4-tricarbonsäure)-äthylenimin, die analog den N-Essigsäurederivaten erhältlich sind, Weiterhin können komplexierend wirkende polyphosphonsaure Salze anwesend sein, z.B. die Alkalisalze von Aminopolyphosphonsäuren, insbesondere Aminotri-(methylenchosphonsäure), 1 -Nydroxyäthan-1, 1 -diphosphonsäure, Methylendiphosphonsäure, Äthylendiphosphonsäure sowie Salze der höheren Homologen der genannten Polyphosphonsäuren. Auch Gemische der vorgenannten Koniplexierungsnittel sind verwendbar. Other suitable builder substances are complexing aminopolycarboxylic acids. These include, in particular, alkali salts of nitrilotriacetic acid and alpha-ethylenediaminetetraacetic acid. The salts of diethylenetriaminopentaacetic acid and the higher salts are also suitable Homologues of the aminov mentioned polycarboxylic acid. These homologues can for example by polymerizing an ester, amide or nitrile of N-acetic acid aziridine and subsequent saponification to carboxylic acid salts or by reaction of polyethyleneimine made with chloroacetic acid or bromoacetic acid salts in an alkaline medium will. Other suitable aminopolycarboxylic acids are poly (N-succinic acid) ethyleneimine, Poly (N-tricarballylic acid) ethyleneimine and poly (N-butane-2,3,4-tricarboxylic acid) ethyleneimine, which are obtainable analogously to the N-acetic acid derivatives, can also be complexing active polyphosphonic acid salts be present, e.g. the alkali salts of aminopolyphosphonic acids, in particular aminotri (methylene phosphonic acid), 1-hydroxyethane-1, 1 -diphosphonic acid, Methylenediphosphonic acid, ethylenediphosphonic acid and salts of the higher homologues of the polyphosphonic acids mentioned. Also mixtures of the aforementioned Koniplexierungsmittel are usable.
Von besonderer Bedeutung sind die stickstoff- und phosphorfreien, mit Calciumionen Komplexsalze bildenden Polycarbonsäuren,- wozu auch Carboxylgruppen enthaltende Polymerisate zählen. Geeignet sind Citronensäure, Weinsäure, Bensolhexacarbonsäure und Tetrahydrofurantetracarbonsäure. Auch Carboxymethyläthergruppen enthaltende Polycarbonsäuren sind brauchbar, wie 2,Z'-Oxydlbernsteinsäure sowie mit Glykolsäure teilweise oder vollständig verätherte mehrwertige Alkohole oder Hydroxycarbonsäuren, beispielsweise Triscarboxymettylglycerin, Biscarboxymethylglycerinsaure und carboxymethy.-lierte bzw. oxydierte Polysaccharide. Weiterhin eignen sich die polymeren Carbonsäuren mit einem Molekulargewicht von mindestens 350 in Form der wasserlöslichen Natrium- oder Xaliumsalze, wie Polyacrylsäure, Polmethacrylsäure, Polyd-hydroxyacrylsäureS Polymaleinsäure, Polyitaconsäure, Polymesaconsäure, Polybutentricarbonsäure sowie die Copolymerisate der entsprechenden monomeren Carbonsäuren untereinander oder mit äthylenisch ungesättigten Verbindungen wie Äthylen.Of particular importance are the nitrogen- and phosphorus-free, Polycarboxylic acids forming complex salts with calcium ions, including carboxyl groups containing polymers include. Citric acid, tartaric acid and benzene hexacarboxylic acid are suitable and tetrahydrofuran tetracarboxylic acid. Also containing carboxymethyl ether groups Polycarboxylic acids are useful, such as 2, Z'-oxydisuccinic acid, as well as with glycolic acid partially or completely etherified polyhydric alcohols or hydroxycarboxylic acids, for example Triscarboxymettylglycerin, Biscarboxymethylglycerinsaure and carboxymethyl-lated or oxidized polysaccharides. The polymeric carboxylic acids are also suitable with a molecular weight of at least 350 in the form of the water-soluble sodium or xaluminum salts, such as polyacrylic acid, polmethacrylic acid, polyhydroxyacrylic acid Polymaleic acid, polyitaconic acid, polymesaconic acid, polybutenetricarboxylic acid as well the copolymers of the corresponding monomeric carboxylic acids with one another or with ethylenically unsaturated compounds such as ethylene.
Propylen, Isobutylen, Vinylmethyläther oder Furan.Propylene, isobutylene, vinyl methyl ether or furan.
Auch in Wasser unlösliche Komplexbildner können verwendet werden. Hierzu zählen phosphorylierte Cellulose und Pfropfpolymere der Acrylsäure oder Methacrylsäure auf Cellulose, die als Gewebe oder Faservliese vorliegen können. Weiterhin sind räumlich vernetzte und dadurch wasserunlöslich gemachte Copolymere der Acryl-, Methacryl-, Croton- und Maleinsäure sowie anderer polymerisierbarer Polycarbonsäuren, gegebenenfalls mit weiteren äthylenisch ungesättigten Verbindungen in Form der Natrium- oder Kaiiumsalze als Sequestrierungsmittel geeignet. Diese unlöslichen Copolymeren können als Vlies, Schwzämme oder auch in Form feingemahlener, spezifisch leichter Schäume mit offenzelliger Struktur vorliegen.Complexing agents which are insoluble in water can also be used. These include phosphorylated cellulose and graft polymers of acrylic acid or methacrylic acid on cellulose, which can be in the form of woven or non-woven fabrics. Furthermore are spatially cross-linked and thus water-insoluble copolymers of acrylic, methacrylic, Crotonic and maleic acid and other polymerizable polycarboxylic acids, optionally with other ethylenically unsaturated compounds in the form of sodium or potassium salts suitable as a sequestering agent. These insoluble copolymers can be used as fleece, Sponges or in the form of finely ground, specifically light foams with open-celled ones Structure.
Als wasserunlösliche Gerüstsubstanzen eignen sich ferner Alkalialuminiumsilikate und AL>aliborsilikate, die gegebenenfalls gebundenes Wasser enthalten und ein Calciumbindevermögen von mindestens 50 mg CaO/g Aktivsubstanz aufweisen. Hierzu zählen insbesondere Verbindungen der Formel (Na20)Al203(Si02) y worin x eine Zahl von 0,7 bis 1,5 und y eine Zahl von 1,3 bis 4 bedeuten. Auch Gemische der vorgenannten wasserlös lichen und wasserunlöslichen Gerüstsubstanzen sind brauchbar.Alkali aluminum silicates are also suitable as water-insoluble builder substances and AL> aliborosilicates, which may contain bound water and a Have calcium binding capacity of at least 50 mg CaO / g active substance. For this include in particular compounds of the formula (Na 2 O) Al 2 O 3 (SiO 2) y in which x is a number from 0.7 to 1.5 and y is a number from 1.3 to 4. Also mixtures of the aforementioned water-soluble and water-insoluble builder substances can be used.
Als Waschalkalien eignen sich die Carbonate, Bicarbonate, Borate und Silikate des Natriums und Kaliums, insbesondere Natriumcarbonat und Natriumsilikate mit einem Verhältnis von Na2O : SiO2 wie 1 : 1 bis 1 : 3,5.The carbonates, bicarbonates, borates and are suitable as washing alkalis Silicates of sodium and potassium, in particular sodium carbonate and sodium silicates with a ratio of Na2O: SiO2 such as 1: 1 to 1: 3.5.
Als bleichend wirkende Stoffe kommen Sauerstoff abgebende Bleichmittel, wie Alkaliperborate, -percarbonate, -perpyrophosphate und -persilikate sowie Harnstoffperhydrat in Frage.Oxygen-releasing bleaches are used as bleaching agents, such as alkali perborates, percarbonates, perpyrophosphates and persilicates as well as urea perhydrate in question.
Bevorzugt wird Natriumperborat in wasserfreier Form oder als Tetrahydrat verwendet. Zwecks Stabilisierung der Perverbindungen können die Mittel Magnesiumsilikat enthalten, beispielsweise in Mengen von 3 bis 2b Gew.-%, bezogen auf die Menge an Perborat. Zur Textilwäsche bei Temperaturen unterhalb 70 0C anzuwendende Mittel, sogenannte Kaltwaschmittel, können Bleichaktivatoren aus der Klasse der N- oder O-Acylverbindungen enthalten, die mit Wasserstoffperoxid in wäßriger Lösung unter Bildung von Persäuren reagieren.Sodium perborate is preferred in anhydrous form or as tetrahydrate used. To stabilize the per compounds, the agents can use magnesium silicate contain, for example in amounts of 3 to 2b wt .-%, based on the amount of Perborate. Agents to be used for washing textiles at temperatures below 70 ° C, so-called cold detergents, bleach activators from the class of N or Contain O-acyl compounds with hydrogen peroxide in aqueous solution taking React formation of peracids.
Bevorzugte Bleichaktivatoren sind das Tetraacetylmethylendiamin, das Tetraacetyläthylendiamin und das Tetraacetylglykolunl. Die aus dem Bleichaktivator oder aus der Perverbindung bestehenden Pulverpartikel können mit Hüllsubstanzen, wie wasserlöslichen Polymeren oder Fettsäuren überzogen sein, um eine Wechselwirkung zwischen der Perverbindung.und dem Aktivator während der Lagerung zu vermeiden.Preferred bleach activators are tetraacetylmethylenediamine, the Tetraacetylethylenediamine and the Tetraacetylglykolunl. The ones from the bleach activator or powder particles consisting of the per compound can be coated with coating substances, like water-soluble polymers or fatty acids coated to interact between the per connection and the activator during storage.
Anstelle der bleichenden Perverbindungen und deren Gemische mit Bleichaktivatoren können auch aktivchlorhaltige Bleichmittel, beispielsweise Natriumhypochlorit, Lithiuinhypochlorit, Na- oder K-dichlorisocyanurat oder Trichlorisocyanursäure oder auch Gemische aus Alkalipersulfaten und Alkalichloriden, die bei der Anwendung unter Bildung von Hypochlorit reagieren, mit den erfindungsgemäßen Waschmitteln kombiniert werden.Instead of the bleaching per compounds and their mixtures with bleach activators Active chlorine-containing bleaches, for example sodium hypochlorite, lithium hypochlorite, Na or K dichloroisocyanurate or trichloroisocyanuric acid or mixtures of Alkali persulphates and alkali chlorides which, when used, form hypochlorite react, are combined with the detergents according to the invention.
Dieses Kombinieren kann bereits bei der Herstellung der Waschmittel oder auch unmittelbar vor oder während der Anwendung erfolgen. Zur Vermeidung von Verlusten können die Aktivchlorverbindungen ebenfalls mit anorganischen oder organischen Hüllsubstanzen umhüllt bzw. granuliert sein.This combination can already be done during the manufacture of the detergent or immediately before or during the application. To avoid The active chlorine compounds can also lose losses with inorganic or organic compounds Coating substances be coated or granulated.
Die Waschmittel können ferner optische Aufheller enthalten insbesondere Derivate der Diaminostilbendisulfonsäure bzw.The detergents can also contain optical brighteners, in particular Derivatives of diaminostilbene disulfonic acid or
deren Alkalimetallsalze. Geeignet sind z.B. Salze der 4,4'-Bis(-2"-anilino-4"-morpholino-1,3,5-triazinyl-6"-amino) -stilben-2,2'-disulfonsäure oder gleichartig aufgebaute Verbindungen, die anstelle der Morpholinogruppe -eine Diäthanol- -aminogruppe, eine Methylaminogruppe oder eine ß-Methoxyäthylaminogruppe tragen. Weiterhin kommen als Aufheller £ür Polyamidfasern solche vom Typ der Diarylpyrazoline in -Frage, beispielsweise 1-(-p-Sulfonamidophenyl)-3-(p-chlorphenyl) -#²-pyrazolin sowie gleichartig aufgebaute Verbindungen, die anstelle der Sulfonamidogruppe eine Carboxymethyl- oder Acetylaminogruppe tragen. Brauchbar sind ferner substituierte Aminocumarine, z.B. das 4-Methyl-7-dimethylamino- oder das 4-Methyl-7-diäthylaminocumarin. Weiterhin sind als Polyamidaufheller die Verbindungen 1 - (2-Benzirnidazolyl) -2-(1-hydroxyäthyl-2-benzimidazolyl)-äthylen und 1 -Athyl-3-phenyl-7-diäthylamino-carbostyril brauchbar. Als Aufheller fur.Polyester- und Polyamidfasern sind die Verbindungen 2,5-Di-(2-benzoxazolyl)-thiophen, 2-(2-Benzoxazolyl)-naphtho-[2,3-b]-thiophen und 1 ,2-Di- (5-methyl-2-benzoxazolyl) -äthylen geeignet. Weiterhin kennen Aufheller von Typ der substituierten Diphenylstyrile anwesend sein. Auch Gemische der vorgenannten Aufheller können verwendet werden Als Vergrauungsinhibitoren eignen sich insbesondere Carboxymethylcellulose, Methylcellulose, ferner wasserlösliche Polyester und Polyamide aus mehrwertigen Carbonsäuren und Glykolen bzw. Diaminen, die freie, zur Salzbildung befähigte Carboxylgruppen, Betaingruppen oder Sulfobetaingruppen aufweisen sowie kolloidal in Wasser lösliche Polymere bzw. Copolymere des Vinylalkohols, Vinylpyrrolidons, Acrylamids und Acrylnitrils.their alkali metal salts. For example, salts of 4,4'-bis (-2 "-anilino-4" -morpholino-1,3,5-triazinyl-6 "-amino) are suitable -stilbene-2,2'-disulfonic acid or similarly structured compounds that instead of the morpholino group -a diethanol- amino group, a methylamino group or carry a ß-methoxyethylamino group. Polyamide fibers are also used as brighteners those of the diarylpyrazoline type in question, for example 1 - (- p-sulfonamidophenyl) -3- (p-chlorophenyl) - # ²-pyrazoline and similarly structured compounds that replace the sulfonamido group carry a carboxymethyl or acetylamino group. Substituted ones can also be used Aminocoumarins, e.g. 4-methyl-7-dimethylamino- or 4-methyl-7-diethylaminocoumarin. The compounds 1- (2-benzimidazolyl) -2- (1-hydroxyethyl-2-benzimidazolyl) -ethylene are also used as polyamide brighteners and 1-ethyl-3-phenyl-7-diethylamino-carbostyril can be used. As a brightener for polyester and polyamide fibers are the compounds 2,5-di- (2-benzoxazolyl) -thiophene, 2- (2-benzoxazolyl) -naphtho- [2,3-b] -thiophene and 1,2-di- (5-methyl-2-benzoxazolyl) -ethylene are suitable. Also know about brighteners of the substituted diphenylstyrile type be present. Also mixtures of the aforementioned Brighteners can be used Suitable as graying inhibitors in particular carboxymethyl cellulose, methyl cellulose, and also water-soluble ones Polyesters and polyamides made from polybasic carboxylic acids and glycols or diamines, the free carboxyl groups, betaine groups or sulfobetaine groups capable of salt formation as well as polymers or copolymers of vinyl alcohol which are colloidally soluble in water, Vinyl pyrrolidones, acrylamides and acrylonitrile.
Die Mittel können ferner Enzyme aus der Klasse der Probeassn, Lipasen und amylasen bzw. deren Gemische enthalten. Besonders geeignet sind aus Bakterienstämmen oder Pilzen, wie Bacillus subtilis, Bacillus licheniformis und Streptomyces griseus gewonnene enzymatische Wirkstoffe.The agents can also include enzymes from the class of the sample, lipases and amylases or mixtures thereof. Bacterial strains are particularly suitable or fungi such as Bacillus subtilis, Bacillus licheniformis and Streptomyces griseus obtained enzymatic active ingredients.
Als weitere Bestandteile kommen Neutralsalze, insbesondere Natriumsulfat, sowie Biocide, wie halogenierte Diphenylmethane, Salicylanilide, Carbanilide und Phenole in Betracht. Flüssige Mittel können außerdem hydrotrope Substanzen und Lösungsmittel enthalten, wie Alkalisalze der Benzol-, Toluol- oder Xylolsulfonsäure, Harnstoff, Glycerin, Polyglycerin, Di- oder Triglylcol, Polyäthylenglykol' Äthanol, i-Propanol und Ätheralkohole.Neutral salts, especially sodium sulfate, are also used as well as biocides such as halogenated diphenylmethanes, salicylanilides, carbanilides and Phenols into consideration. Liquid agents can also contain hydrotropes and solvents contain, such as alkali salts of benzene, toluene or xylene sulfonic acid, urea, Glycerine, polyglycerine, di- or triglylcol, polyethylene glycol, ethanol, i-propanol and ethereal alcohols.
Gegebenenfalls können noch bekannte Schauminhibitoren, wie gesättigte Fettsäuren und deren Alkaliseifen mit 20 bis 24 C"Atomen, Trialkylmelamine, Kohlenwasserstoffe und Silikone, anwesend sein.If necessary, known foam inhibitors, such as saturated Fatty acids and their alkali soaps with 20 to 24 C "atoms, trialkyl melamines, hydrocarbons and silicones, be present.
Die quantitave Zusammensetzung der erfindungsgemäßen Waschmittel kann innerhalb weiter Grenzen schwanken, vorzugsweise innerhalb der folgenden (in Gewichtsprozent): 0,1 - 10 %, vorzugsweise 0,2-5 96 Polymeres gemäß Erfindung 0,5 - 30 , vorzugsweise 1 - 20 Seife und bzw.The quantitative composition of the detergents according to the invention can fluctuate within wide limits, preferably within the following (in percent by weight): 0.1-10%, preferably 0.2-596 polymer according to the invention 0.5-30, preferably 1 - 20 soap and resp.
oder Sulfat- bzw. Sulfonat-Tensid, 0,5 - 30 %, vorzugsweise 1 - 20 f nichtionisches Tensid, O - 60 , vorzugsweise 5 - 50 % phosphorfreie Gerüstsub stanzen, O - 60 %, vorzugsweise 10 - 50 % phosphorhaltige Gerüstsubstanz, O - 25 % Waschalkalien, O - 30 %, vorzugsweise 10 - 25 an Sauerstoff abgebenden Bleichmitteln, insbesondere Na-Perborat und dessen Kombination mit Bleichaktivatoren und Stabilisatoren, 0 - %, vorzugsweise 0,5 - 2 % an vergrauungsverhUt enden Substanzen, 0 - 1 % optische Aufheller, Farb- und Duftstoffe, sowie antimikrobielle Substanzen, 0 - 3 %, vorzugsweise 0,2 - 2 9d an Schauminhibitoren. or sulfate or sulfonate surfactant, 0.5-30%, preferably 1-20 f nonionic surfactant, 0 - 60, preferably 5 - 50% phosphorus-free framework sub punch, O - 60%, preferably 10 - 50% phosphorus-containing structural substance, O - 25 % Washing alkalis, 0 - 30%, preferably 10 - 25 of oxygen-releasing bleaches, in particular Na perborate and its combination with bleach activators and stabilizers, 0 -%, preferably 0.5 - 2% of anti-graying substances, 0 - 1% optical Brighteners, dyes and fragrances, as well as antimicrobial substances, 0-3%, preferably 0.2-2 9d of foam inhibitors.
Beispiele A. Herstellung der Polymeren 1. Zur Herstellung von Poly-N-vinyloxazolidon werden in einem 500 ml fassenden Kolben 150 g Xylol, 30 g N-Vinyloxazolidon und 1 g Azoisobuttersäuredinitril unter Stickstoffatmosphäre 3 Stunden unter Rühren auf 95 °C erhitzt, wobei das Polymere in Form eines weißen Pulvers ausfällt. Nach dem Abkühlen wird das Poly-N-vinyloxazolidon abfiltriert, mehrfach mit Xylol gewaschen und im Vakuumschrank bei 50 OC getrocknet. Examples A. Preparation of the polymers 1. For the preparation of poly-N-vinyloxazolidone are in a 500 ml flask 150 g of xylene, 30 g of N-Vinyloxazolidon and 1 g of azoisobutyric acid dinitrile under a nitrogen atmosphere for 3 hours with stirring heated to 95 ° C, the polymer precipitates in the form of a white powder. To After cooling, the poly-N-vinyloxazolidone is filtered off and washed several times with xylene and dried in a vacuum oven at 50 ° C.
Die bei 20 OC in 1 %iger Lösung bestimmte spezifische Vistosität betrug 0,10. The specific visosity determined at 20 OC in 1% solution was 0.10.
2. Zur Herstellung eines N-Vinyloxazolidon-N-Vinylimidazol-Copolymeren (Molverhältnis 1 : 0,9) werden 12,2 g N-Vinyloxazolidon und 9,4 g N-Vinylimidazol in 120 g Methanol, das durch einstündiges Solchen unter Stickstoffatmosphäre von Sauerstoff befreit worden ist, 15 g N-Vinyloxazolidon, 15 g N-Vinylimidazol und 0,6 g Azoisobuttersäuredinitril gelöst und die Lösung 6 Stunden unter Rühren und Stickstoffdurchleitung zum Sieden erhitzt. Nach dem Abkühlen wird das Polymere durch Eingießen des Reaktionsgemisches in ca.2. For the preparation of an N-vinyloxazolidone-N-vinylimidazole copolymer (Molar ratio 1: 0.9) are 12.2 g of N-vinyl oxazolidone and 9.4 g of N-vinyl imidazole in 120 g of methanol, which is obtained by soaking for one hour under a nitrogen atmosphere Has been deoxygenated, 15 g of N-vinyloxazolidone, 15 g of N-vinylimidazole and Dissolved 0.6 g of azoisobutyric acid dinitrile and the solution for 6 hours with stirring and Bubbling nitrogen through heated to boiling. After cooling, the polymer will through Pour the reaction mixture into approx.
4 1 Äther ausgefällt, abfiltriert und im Vakuumschrank bei 50 OC getrocknet. Spez. Viskosität: 0,26. 4 1 ether precipitated, filtered off and placed in a vacuum cabinet at 50 OC dried. Specific viscosity: 0.26.
3. Zwecks Herstellung eines N-Vinyloxazolidon-N-Vinylpyrrolidon-Copolymerisates (Molverhältnis 1 : 1) werden 10 g N-Vinyloxazolidon und 10 g N-Vinylpyrrolidon in der in Beispiel 2 angegebenen Weise in Gegenwart von 0,6 g Azoisobuttersäuredinitril in 120 g Methanol polymerisiert und das Copolymere durch Ausfällen isoliert. Spez. Viskosität: 0,28.3. For the purpose of producing an N-vinyloxazolidone-N-vinylpyrrolidone copolymer (Molar ratio 1: 1) 10 g of N-vinyl oxazolidone and 10 g of N-vinyl pyrrolidone in the manner indicated in Example 2 in the presence of 0.6 g of azoisobutyric acid dinitrile polymerized in 120 g of methanol and isolated the copolymer by precipitation. Spec. Viscosity: 0.28.
4. Ein durch Copolymerisation von 12,2 g N-Vinyloxazolidon, 11,1 g N-Vinylpyrrolidon und 9,-4 g N-Vinylimidazol (Molverhältnis 1,1 : 1 : 1) gemäß Beispiel 2 hergestelltes Copolymeres wies eine spezifische Viskosität von 0,4 auf.4. A copolymerization of 12.2 g of N-vinyloxazolidone, 11.1 g N-vinylpyrrolidone and 9.4 g of N-vinylimidazole (molar ratio 1.1: 1: 1) according to the example 2 had a specific viscosity of 0.4.
B. Waschversuche Textilproben aus Baumwolle wurden mit folgenden Farbstoffen gefärbt.B. Washing tests Textile samples made of cotton were made with the following dyes colored.
a) Cibacronbrillantorange 2GE b) Naphthol AS-OL Variaminblausalz B c) Siriuslichtscharlach BN d) Indanthrenbrillantgrün GG e) Siriuslichtblau BL Diese eingefärbten Textilproben wurden gemeinsam mit verschiedenen, nachstehend aufgeführten farblosen Testgeweben im Launderometer gewaschen. a) Cibacron brilliant orange 2GE b) Naphthol AS-OL Variamin blue salt B c) Sirius light scarlet BN d) Indanthrene brilliant green GG e) Sirius light blue BL These dyed textile samples were used along with various ones below listed colorless test fabrics washed in the launderometer.
I) Baumwolle II) veredelte Baumwolle (wash and ear Ausrüstung) III) Mischgewebe aus Polyester und veredelter Baumwolle (1 : 1) IV) Polyestergewebe V) Polyurethangewebe (Lycra % Das <ewichtsverhältnis von angefärbtem Baumwollgewebe zu weißem Testgewebe betrug 2 : 1. Es wurden 7,5 g/l eines Was climittels folgender Zusanimensetzung verwendet (in Gew.-%) 4,0 % Polymeres gemäß Erfindung 8,5 % Na-n-Dodecylbenzolsulfonat 2,5 % Talgalkohol, 14-fach äthoxyliert 1,5 % Talgalkohol, 5-fach äthoxyliert 3,5 % Na-Seife (Talgfettsäure zu Cocosfettsäure 9 : 1) 40,0 % Natriumtripolyphosphat 5,5 % Natriumsilikat (Na20 : SiO2 = 1 : 3,3) 1,5 % Magnesiumsilikat 0,5 % Na-Athylendiaminotetraacetat 1,5 % Na-Carboxymethylcellulose 20,0 % Natriumperborat 0,3 t optische Aufheller und Duftstoffe Rest Natriumsulfat Bei Einsatz des Baumwolltestgewebes (I) betrugen das Flottenverhältnis (Textilgewicht in g zu Waschflotte in ml) 1 : 12 und die Waschtemperatur 90 °C. Die übrigen Testgewebe wurden bei einem Flottenverhältnis von 1 : 30 und einer Temperatur von 60 °C gewaschen, wobei nach dem Aufheizen der Waschflotte auf die angegebenen Temperaturen eine Waschzeit von jeweils 15 Minuten eingehalten wurde. Nach dem Waschen wurde 3mal mit Leitungswasser nachgespült. Die Wasserhärte betrug l6° dH. I) Cotton II) Refined cotton (wash and ear equipment) III) Mixture of polyester and refined cotton (1: 1) IV) Polyester fabric V) Polyurethane fabric (Lycra% the weight ratio of dyed cotton fabric to white test fabric was 2: 1. 7.5 g / l of a detergent was obtained as follows Composition used (in% by weight) 4.0% polymer according to the invention 8.5% Na-n-dodecylbenzenesulfonate 2.5% tallow alcohol, 14-fold ethoxylated 1.5% tallow alcohol, 5 times ethoxylated 3.5% Na soap (tallow fatty acid to coconut fatty acid 9: 1) 40.0% Sodium tripolyphosphate 5.5% sodium silicate (Na20: SiO2 = 1: 3.3) 1.5% magnesium silicate 0.5% Na ethylenediaminotetraacetate 1.5% Na carboxymethyl cellulose 20.0% sodium perborate 0.3 t optical brighteners and fragrances, residual sodium sulfate when using the cotton test fabric (I) the liquor ratio (textile weight in g to washing liquor in ml) was 1: 12 and the washing temperature 90 ° C. The remaining test fabrics were at a liquor ratio Washed at 1:30 and a temperature of 60 ° C, after heating the Wash liquor to the specified temperatures a washing time of 15 minutes each was adhered to. After washing, it was rinsed 3 times with tap water. the Water hardness was 16 ° dH.
Zunächst wurden die Versuche in AXwesenheit der erfindungsgemäß zu verwendenden polyraeren Ver frbungsi nilibitoren durchgeführt und die aufgetretene Farbübertragung photometrisch gemessen.First of all, the experiments in the presence of AX were made according to the invention using polyraeren discoloration inilibitors carried out and the occurred Color transfer measured photometrically.
Anschließend wurde der Versuch in Gegenwart des Polymeren wiederholt und wieder die Remission der Testgewebe photometrisch bestimmt. Die Differenz ER der beiden Remissionswerte ist ein Maß für die "Verfärbungsinhibiexung", d.h. die Schutzwirkung des betreffenden Polymeren. Sämtliche in der folgenden Tabelle aufgeführten Differenzwerte sind flittelwerte aus jeweils 5 Parallelversuchen. Die Ergebnisse sind in der folgenden Tabelle zusammengestellt. Die Bezeichnungen aI) bII)-bIII) usw. stehen für die Kombinationen aus Farbstoff a) mit Textilmaterial I), Farbstoff b) mit Textilmaterial II, Farbstoff b) mit Textil material III) usw. Für die jeweiligen Farbmessunyen wurde das Gerät tElrepho" der Fa. Carl Zeiß in Kombination mit folgenden Filtern verwendet.The experiment was then repeated in the presence of the polymer and again the remission of the test tissue photometrically certainly. The difference ER of the two reflectance values is a measure of the "discoloration inhibition", i.e. the protective effect of the polymer in question. All in the following table The difference values listed are the average values from 5 parallel tests. the The results are compiled in the following table. The designations aI) bII) -bIII) etc. stand for the combinations of dye a) with textile material I), dye b) with textile material II, dye b) with textile material III) etc. The device tElrepho "from Carl Zeiss in Used in combination with the following filters.
Farbstoff a) Filter 46/5 " b) n 40/9 n c) n 46/5 " d) " 46/2 " e)
" 40/9 Die Ergebnisse zeigen, daß die erfindungsgemäß verwendeten Polymeren geeignet
sind, die Farbübertragung meßbar zu verringern.
Claims (12)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19782814329 DE2814329A1 (en) | 1978-04-03 | 1978-04-03 | Washing agents contg. N-vinyl-oxazolidone polymers - inhibiting transfer of dyes from coloured textiles onto white textiles |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19782814329 DE2814329A1 (en) | 1978-04-03 | 1978-04-03 | Washing agents contg. N-vinyl-oxazolidone polymers - inhibiting transfer of dyes from coloured textiles onto white textiles |
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| Publication Number | Publication Date |
|---|---|
| DE2814329A1 true DE2814329A1 (en) | 1979-10-11 |
Family
ID=6036049
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19782814329 Withdrawn DE2814329A1 (en) | 1978-04-03 | 1978-04-03 | Washing agents contg. N-vinyl-oxazolidone polymers - inhibiting transfer of dyes from coloured textiles onto white textiles |
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Cited By (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4769080A (en) * | 1985-06-24 | 1988-09-06 | The Dow Chemical Company | Insoluble pigments and preparation thereof |
| US4769079A (en) * | 1985-06-24 | 1988-09-06 | The Dow Chemical Company | Insoluble pigments and preparation thereof |
| US4773936A (en) * | 1985-06-24 | 1988-09-27 | The Dow Chemical Company | Insoluble pigments and preparation thereof |
| EP0291808A1 (en) * | 1987-05-16 | 1988-11-23 | BASF Aktiengesellschaft | Use of water soluble copolymerisates, wherein monomers having at least two ethylenically unsaturated monomers are taking part in wasking and cleaning agents |
| EP0292766A1 (en) * | 1987-05-16 | 1988-11-30 | BASF Aktiengesellschaft | Use of water soluble copolymerisates, wherein monomers having at least two ethylenically unsaturated monomers are taking part in wasting and cleaning agents |
| EP0265257A3 (en) * | 1986-10-24 | 1989-06-07 | Unilever Plc | Detergent composition |
| US4840676A (en) * | 1985-06-24 | 1989-06-20 | The Dow Chemical Company | Insoluble pigments and preparation thereof |
| US4929381A (en) * | 1985-06-24 | 1990-05-29 | The Dow Chemical Company | Inorganic anion exchangers and preparation thereof |
| EP0372291A1 (en) * | 1988-11-28 | 1990-06-13 | Henkel Kommanditgesellschaft auf Aktien | Laundry process for discoloration-sensitive textiles |
| WO1992004437A1 (en) * | 1990-09-01 | 1992-03-19 | Henkel Kommanditgesellschaft Auf Aktien | Liquid washing agent with colour-loss inhibition properties |
| WO1994011477A1 (en) * | 1992-11-06 | 1994-05-26 | The Procter & Gamble Company | Dye transfer inhibiting compositions containing a metallocatalyst, a bleach and polyamine n-oxide polymer |
| WO1994011473A1 (en) * | 1992-11-06 | 1994-05-26 | The Procter & Gamble Company | Stable liquid detergent compositions inhibiting dye transfer |
| US5466802A (en) * | 1993-11-10 | 1995-11-14 | The Procter & Gamble Company | Detergent compositions which provide dye transfer inhibition benefits |
| US5560858A (en) * | 1992-07-15 | 1996-10-01 | The Procter & Gamble Company | Dye transfer inhibiting compositions containing a metallocatalyst, a bleach and polyamine N-oxide polymer |
| US5597795A (en) * | 1992-10-27 | 1997-01-28 | The Procter & Gamble Company | Detergent compositions inhibiting dye transfer |
| US5633225A (en) * | 1992-07-15 | 1997-05-27 | The Procter & Gamble Company | Detergent compositions inhibiting dye transfer |
| US5783548A (en) * | 1992-11-06 | 1998-07-21 | The Procter & Gamble Company | Stable liquid detergent compositions inhibiting dye transfer |
| US7179778B2 (en) | 2002-12-06 | 2007-02-20 | Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) | Liquid acid detergent comprising a phthaloylamino peroxy caproic acid |
| WO2007019981A1 (en) | 2005-08-19 | 2007-02-22 | Henkel Kommanditgesellschaft Auf Aktien | Colour protection washing product |
| US7947087B2 (en) | 2006-03-14 | 2011-05-24 | Henkel Ag & Co. Kgaa | Color transfer inhibitors, detergent compositions containing the same and uses therefor |
| DE102012219403A1 (en) | 2012-10-24 | 2014-04-24 | Henkel Ag & Co. Kgaa | Use of metal ion chelates obtained by polymerization of monoethylenically unsaturated mono-or di-carboxylic polymers to e.g. prevent the transfer of textile dyes from dyed textiles to undyed textiles, or other color in the common laundry |
| DE102013203484A1 (en) | 2013-03-01 | 2014-09-04 | Henkel Ag & Co. Kgaa | Color protecting detergents |
| DE102014220662A1 (en) | 2014-10-13 | 2016-04-14 | Henkel Ag & Co. Kgaa | Color protecting detergents |
| DE102014220663A1 (en) | 2014-10-13 | 2016-04-14 | Henkel Ag & Co. Kgaa | Color protecting detergents |
| WO2018210591A1 (en) | 2017-05-17 | 2018-11-22 | Henkel Ag & Co. Kgaa | Color-protecting detergents |
-
1978
- 1978-04-03 DE DE19782814329 patent/DE2814329A1/en not_active Withdrawn
Cited By (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4769080A (en) * | 1985-06-24 | 1988-09-06 | The Dow Chemical Company | Insoluble pigments and preparation thereof |
| US4769079A (en) * | 1985-06-24 | 1988-09-06 | The Dow Chemical Company | Insoluble pigments and preparation thereof |
| US4773936A (en) * | 1985-06-24 | 1988-09-27 | The Dow Chemical Company | Insoluble pigments and preparation thereof |
| US4840676A (en) * | 1985-06-24 | 1989-06-20 | The Dow Chemical Company | Insoluble pigments and preparation thereof |
| US4929381A (en) * | 1985-06-24 | 1990-05-29 | The Dow Chemical Company | Inorganic anion exchangers and preparation thereof |
| EP0265257A3 (en) * | 1986-10-24 | 1989-06-07 | Unilever Plc | Detergent composition |
| EP0291808A1 (en) * | 1987-05-16 | 1988-11-23 | BASF Aktiengesellschaft | Use of water soluble copolymerisates, wherein monomers having at least two ethylenically unsaturated monomers are taking part in wasking and cleaning agents |
| EP0292766A1 (en) * | 1987-05-16 | 1988-11-30 | BASF Aktiengesellschaft | Use of water soluble copolymerisates, wherein monomers having at least two ethylenically unsaturated monomers are taking part in wasting and cleaning agents |
| EP0372291A1 (en) * | 1988-11-28 | 1990-06-13 | Henkel Kommanditgesellschaft auf Aktien | Laundry process for discoloration-sensitive textiles |
| WO1990006354A1 (en) * | 1988-11-28 | 1990-06-14 | Henkel Kommanditgesellschaft Auf Aktien | Process for washing textiles prone to fading |
| WO1992004437A1 (en) * | 1990-09-01 | 1992-03-19 | Henkel Kommanditgesellschaft Auf Aktien | Liquid washing agent with colour-loss inhibition properties |
| US5633225A (en) * | 1992-07-15 | 1997-05-27 | The Procter & Gamble Company | Detergent compositions inhibiting dye transfer |
| US5560858A (en) * | 1992-07-15 | 1996-10-01 | The Procter & Gamble Company | Dye transfer inhibiting compositions containing a metallocatalyst, a bleach and polyamine N-oxide polymer |
| US5597795A (en) * | 1992-10-27 | 1997-01-28 | The Procter & Gamble Company | Detergent compositions inhibiting dye transfer |
| WO1994011477A1 (en) * | 1992-11-06 | 1994-05-26 | The Procter & Gamble Company | Dye transfer inhibiting compositions containing a metallocatalyst, a bleach and polyamine n-oxide polymer |
| US5783548A (en) * | 1992-11-06 | 1998-07-21 | The Procter & Gamble Company | Stable liquid detergent compositions inhibiting dye transfer |
| WO1994011473A1 (en) * | 1992-11-06 | 1994-05-26 | The Procter & Gamble Company | Stable liquid detergent compositions inhibiting dye transfer |
| US5466802A (en) * | 1993-11-10 | 1995-11-14 | The Procter & Gamble Company | Detergent compositions which provide dye transfer inhibition benefits |
| US7179778B2 (en) | 2002-12-06 | 2007-02-20 | Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) | Liquid acid detergent comprising a phthaloylamino peroxy caproic acid |
| US8785362B2 (en) | 2005-08-19 | 2014-07-22 | Henkel Ag & Co. Kgaa | Triazine derivative dye transfer inhibitors, washing products containing the same and uses therefor |
| WO2007019981A1 (en) | 2005-08-19 | 2007-02-22 | Henkel Kommanditgesellschaft Auf Aktien | Colour protection washing product |
| US8263541B2 (en) | 2005-08-19 | 2012-09-11 | Henkel Ag & Co. Kgaa | Triazine derivative dye transfer inhibitors, washing products containing the same and uses therefor |
| US7947087B2 (en) | 2006-03-14 | 2011-05-24 | Henkel Ag & Co. Kgaa | Color transfer inhibitors, detergent compositions containing the same and uses therefor |
| DE102012219403A1 (en) | 2012-10-24 | 2014-04-24 | Henkel Ag & Co. Kgaa | Use of metal ion chelates obtained by polymerization of monoethylenically unsaturated mono-or di-carboxylic polymers to e.g. prevent the transfer of textile dyes from dyed textiles to undyed textiles, or other color in the common laundry |
| DE102013203484A1 (en) | 2013-03-01 | 2014-09-04 | Henkel Ag & Co. Kgaa | Color protecting detergents |
| WO2014131638A1 (en) | 2013-03-01 | 2014-09-04 | Henkel Ag & Co. Kgaa | Color-protecting detergent |
| US9546344B2 (en) | 2013-03-01 | 2017-01-17 | Henkel Ag & Co. Kgaa | Color-protecting detergent |
| DE102014220662A1 (en) | 2014-10-13 | 2016-04-14 | Henkel Ag & Co. Kgaa | Color protecting detergents |
| DE102014220663A1 (en) | 2014-10-13 | 2016-04-14 | Henkel Ag & Co. Kgaa | Color protecting detergents |
| EP3009498A2 (en) | 2014-10-13 | 2016-04-20 | Henkel AG & Co. KGaA | Color-protecting detergents |
| WO2018210591A1 (en) | 2017-05-17 | 2018-11-22 | Henkel Ag & Co. Kgaa | Color-protecting detergents |
| DE102017004698A1 (en) | 2017-05-17 | 2018-11-22 | Henkel Ag & Co. Kgaa | Color protecting detergents |
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