DE2350209A1 - PHOTOGRAPHIC TREATMENT MEASURES AND DEVELOPMENT PROCEDURES - Google Patents

Description

I ¹ ATENTANWaITE

DR. E. WiEGAND DIPL-ING. Y ^. NO MAN

DR.-M. KÖHLER DIPL-ING. C GERNHARDT

MPNCHEN HAMBURG L O b UZ UvJ

TELEPHONE: 5554 7. «8000 M D N CH E N 2,

TELEGRAMS: KARPATENT MATHI LDENSTRÄSSS 12

W 41 796/75 - Ko / Ja - October 5, 1973

Fuji Photo Film Co. Ltd. Minami Ashigara-shi, Eanaga \ ira (Japan)

Photographic processing composition and processing method

This invention relates to a composition for photographic processing and, more particularly, to an improved composition for Bleaching or bleaching and fixing and a developing process. - ·

According to the invention, a photographic processing composition is provided which (1) an iron (III) ion complex or a persulfate and (2) a compound of the following general formula

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(D

where fL the groupings

denotes in which Rp is an alkyl group or a moiety - £ CHp 4tr SO ^ ", η J5 or 4 and X" means an anion and this is missing if Rp represents a - £ CHp 4tr ~ SO, "group, having.

In general, the basic treatments of a silver halide color photographic light-sensitive material are the color development and desilvering. That is, in an exposed silver halide color photographic material the silver halide is reduced with a color developer to form silver in the color development stage, and the oxidation product of the color developer reacts with a color coupler to form a color image. Then the color photographic materiaD. the desilvering stage subject where the silver formed in the previous stage with an oxidizing agent known as "bleaching agent" is referred to, is oxidized and then using a complexing agent called "fixing agent" In this way the silver is removed from the photographic material and only the color image remains on it. The development that generally

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in addition to the basic ailments mentioned above Stages of color development and desuperisation carried out involves additional processing steps to maintain the photographic and physical properties of the image as well as improving the storage properties of an image. For example, these additional measures using a hardening bath. to avoid excessive Soften the photosensitive layer or layers during processing to prevent a stop bath to effectively stop the development reaction, an image stabilization bath to stabilize the image and a film removal bath to remove the base layer carried out.

In addition, the desilvering step described above either in one step using a bleach and fix bath * in which a bleach and a fixer in combination or in two stages using a bleach bath and a separate fixer bath be performed.

Potassium ferricyanide is generally used as the bleaching solution used. However, the bleaching solution using potassium ferricyanide has the disadvantage that a fatigued bleaching solution ' must be exchanged and the ferricyanide ion and the ferrocyanidion in reduced form, which is used as an overflow during treatment and discharged as an entrained material in the wash water after bleaching, the are subject to photochemical oxidation and thus form extremely toxic cyanide vex bonds. Therefore it was desired Develop a new bleach that can be used in place of potassium ferricyanide.

. On the other hand wurden.Kaliumbichromat, iron (III) -ionkomplexsalz-e, persulfates, quinones, and copper salts so far as the bleaching agent, however, other than potassium ferricyanide used _s they are in terms of Oxidationskapazitä / fc and input

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subject to professionalism of handling *

Iron (III) ion complex salts are used as bleaching agents for a bleach and. Fixing solution used for color printing papers (DT-PS 866 605 and 966 410 and British patents 746 567, 933 088 and 1 014 396), but they will not often as color photosensitive materials for photography using silver iodobromide in high concentration used because a bleaching and fixing agent containing an iron (III) ion complex salt has a low oxidizing capacity having. Thus, it is desirable to have the oxidizing capacity of a bleaching and fixing solution or bleaching solution using an iron (III) ion complex salt to increase.

Furthermore, iron (III) ion complex salts can be used as bleaching agents be used with bromides. However, the disadvantage of an iron (III) ion complex sa3.z bleach bath is that that it takes a long time for bleaching due to a low bleaching capacity. Persulfates are used as bleaches except for iron (III) ion complex salts known. Common persulfates are used with bromides in a bleach bath, however, the disadvantage of a persulfate bleach bath is that it takes a much longer time to bleach a lower bleaching capacity than that of the iron (III) ion complex salts is required.

As described above, a bleaching solution or a bleaching-and-fixing solution using a Pisene (III) ion complex salt is prepared or a persulfate not often in color films using a high silver halide value used with sufficient sensitivity for use in a camera because of its weak bleaching capacity.

Therefore, an object of the invention is a photographic one Treatment mass that has an accelerated bleaching action but does not adversely affect photographic properties.

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Another object of the invention is the increase the bleaching capacity of a bleaching solution or a bleaching and fixing solution containing an iron (IH) ion complex salt or contains a persulfate.

Another object of the invention is a method for rapid bleaching or bleaching and fixing, of a color photographic material with photographic Sensitivity. ■

It has now been found, as a result of various investigations, that the above-described objects can be achieved with a photographic Treatment mass achieved v / can contain an iron (III) ion complex salt or a persulfate and a Compound of the general formula

has, wherein R ,, the groupings h.

Χ "

R ^ is an alkyl group (for example an alkyl group with 1 to 5 carbon atoms) or the grouping —fCIU ^ rr SO "^ η 3 or 4 and X" is an anion (e.g. a sulfonate ion or a halide ion, e.g. Cl ", Br ~ or J" ), where X "is absent when Rp the grouping - £ CH ₂ 4rr SO ^" means.

The iron (III) ion complex salt used in the present invention or persulfate acts as a "bleaching agent" of the silver image as is known. An embodiment of the invention

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Photographic treatment composition comprises at least one of the materials iron (III) ion complex salt and persulfate and the compound described above, while another embodiment of the invention comprises at least one of the materials iron (III) ion complex salt and persulfate and the compound described above and in addition one Has fixing agent, tel. Compounds of the above general formula, in which R ^ has the meaning given above, FL, a methyl radical, "ethyl radical, the grouping -4CH ₂ ^ SOJ ~ or -fCHp" ^ SO, "and in which X is a bromide ion or a p- Toluenesulfonate ion are preferred.

Each component of the composition according to the invention will now be explained in detail.

Specific examples of the compounds according to the invention, represented by the general formula described above are given below, however, is the invention is not limited to these compounds.

Connection 1

Mp 260 ⁰ C.

² ' ^OH r \\ //

Connection 2

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Fp

^{> H} 2 °

Verb ihöimg_3

CH ₇ -N

Connection 4

link 5

N-CH,

Mp 282 ⁰ C

2 Br "

The general method of making the compound represented by the general formula is as follows:

Equimolar amounts of rubeanic acid and. Pyridinal Debyd are refluxed for 3 hours in dimethylformamide heated and the crystals obtained are mixed with an appropriate reagent to obtain the desired compound quaternized.

The iron (III) ion complex used in the present invention is a complex of the iron (III) ion with a chelating agent such as aminopolycarboxylic acids and aminopolyphosphonic acids and their salts. The salts of the aminopolycarboxylic acids and the aroinopolyphosphonic acids are the Al-

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Potash, ammonium and water-soluble amine salts. Suitable alkali metal salts are the sodium, potassium and lithium salts _t and suitable water-soluble amine salts are salts of aliphatic amines such as methylamine, diethylamine, triethylamine and butylamine, alicyclic amines such as cyclohexylamine, aromatic amines such as aniline and m-toluidine and heterocyclic Amines, such as pyridine, morpholine and piperidine.

Examples of suitable aminopolycarboxylic acids, aminopolyphosphonic acids and their salts which can be used as chelating agents according to the invention are ethylenediaminetetraacetic acid,
Disodium ethylenediamine tetraacetate,
Diammonium ethylenediamine tetraacetate, tetra (trimethylammonium) ethylenediamine tetraacetate, tetrapotassium ethylenediamine tetraacetate, tetrasodium ethylenediamine tetraacetate, trisodium ethylenediamine tetraacetate,
Diethylenetriamine pentaacetic acid,
Pentasodium diethylenetriaminepentaacetate, ethylenediamine-N- (ß-oxyethyl) -N, N ·, N ^! -triacetic acid _f trisodium ethylenediamine-N- (ß-oxyethyl) -N, N ·, N '-triacetate, triammoniumethylenediamine-N-Cß-oxyäthyl ^ NyN', N ^f -triacetate, propylenediamine tetraacetic acid,
Disodium propylenediamine tetraacetate,
Nitrilotriacetic acid,
Trisodium nitrilotriac etat,
Cyclohexanediaminotetraacetic acid,
Disodium cyclohexanediamine tetraacetate, iminodiacetic acid,
Dihydroxyatiryl glycine,
Ethyl ether diamine tetraacetic acid,
Glycol ether diamine tetraacetic acid,

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235:

Ethylenediaminetetrapropionic acid,

Phenylenediaminetetraacetic acid,

1,3-Diaininopropanol ~ N, H, N ·, N * -tetramethylene phosphonic acid, ethylenediamine-N., N, N ^f , N ^T -tetramethylene phosphonic acid, 1,3-propylenediamine-N, N, N ¹ , N ¹ -tetramethylene phosphonic acid.

These compounds are given as typical examples, and the present invention is not intended to be "limited" thereby v / earth.

The iron (III) ion complex salt can be used in the form of a complex salt or it can be used in solution using an iron (III) salt, for example iron (III) sulfate, iron (III) chloride, iron - (III) nitrate, iron (III) ammonium sulfate or iron (III) phosphate and a chelating agent such as aminopolycarboxylic acid and aminopolyphosphonic acid are formed. When a complex salt is used, the complex salt can be used alone or in combination of two or more complex salts. When the complex salt is formed in solution from a ferric salt and a chelating agent, one or more ferric salts can be used and one or more chelating agents can be used. In either of these cases, the chelating agent can be used in excess to form the ferric ion complex salt. The iron (III) -ionkomplexsalze are known in the art and are described for example in US-PS 3 582 ^X 322nd · ■ "

The persulfate used as a bleaching agent in the present invention can be an alkali persulfate such as potassium persulfate or sodium persulfate or ammonium persulfate.

When the composition of the invention is used as a bleaching solution, a bromide, for example an alkali bromide, such as Potassium bromide, sodium bromide or an ammonium bromide therein in addition to the iron (III) ion complex salt and the above

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described compound of the invention be included. Furthermore, one or more inorganic acids, organic Acids or their salts with a pH buffer function, for example Boric acid, borax, sodium metaborate, acetic acid, sodium acetate, sodium carbonate, potassium carbonate, phosphoric acid, phosphorous Acid, sodium phosphate, citric acid, sodium citrate and tartaric acid.

For every 1,000 ml of a bleaching solution, the amount of the iron (III) ion complex salt or the persulfate is about 0.1 to 2 mol and that of the compound represented by the above general formula is about 2 10 "to 2 χ 10, preferably 1 χ 10 to 1 χ 10 ~ ² mol. The pH of a bleaching solution during use is generally from 3.0 to 8.0, preferably from 4.0 to 7.0, in the case of an iron (III) - ion complex salt and at 1.0 to 7.0, preferably 2.0 to 6.0 in the case of a persulfate.

On the other hand, when the composition of the invention is used as a bleaching and fixing agent, one or more fixing agents can be used uses v / earth. Suitable examples of these fixing agents are thiosulphates, e.g. sodium thiosulphate, ammonium thiosulphate, Ammonium sodium thiosulfate and potassium thiosulfate, Thiocyanates, e.g., sodium thiocyanate, ammonium thiocyanate, and Potassium thlocyanate and thioether compounds such as Ethylenebisthioglycolic acid and 3 »6-dithia-1,8-octanediol.

For every 1,000 ml of a bleaching and fixing solution, the general amount of the iron ClIII ion complex salt or the persulfate is about 0.1 to 2 mol, that of the fixing agent is about 0.2 to 4 mol and that of the general formula shown above Connection is about. 2 10 ⁶ to 2 χ 10 ² mol, preferably 1 χ 10 ⁴ to 1 χ 10 ² mol.

The above-described additives which are suitable for addition to the can be added to this bleaching and fixing solution Bleach solution and sulfites, e.g. the alkali sulfites, e.g. sodium sulfite, potassium sulfite and. At the-

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moniumsulfit are added. About the bleach and fix solution one or more compounds can also be added which accelerate the bleaching and fixing effects e.g. Japanese patent publication Sho-45-8506 described thiourea derivatives in German patent 1 127 715 described iodides, the polyethylene oxides described in German Patent 966 410, which are in the German Patent 1,290,812 described nitrogen-containing heterocyclic compounds and other thioureas can be added. The pH of the bleach and fix solution during use is usually 4.0 to 8.0. preferably 5.0 to 7.0.

The above-described bleaching agent composition of Invention can be applied to the preparation of a bleaching solution for use or as a solution to be used as a supplement and the bleaching and fixing agent composition described above can be used to make a bleach and fix solution or as a solution to supplement be used. By adding the invention Compound can increase the bleaching capacity and the iron (III) ~ ion complex salt can be used in a higher concentration can be dissolved to give an excellent bleach or bleach and fixer composition. In the case of the preparation of two or more solutions, therefore the pH table of the iron (III) ion complex salt-containing agent be increased further outside the above-mentioned pH range. The above for making the bleaching or bleaching and fixing solutions can be prematurely combined into one hatch for subsequent use .be or can be added individually at the time of use.

The invention can be appropriately applied and applied to any treatments for all types of color photographic

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graphic materials using silver halide, e.g. color papers, color negative films, color reversal films and color positive films as described in U.S. Patent 3,582,322.

The photographic processing composition containing the compound represented by the above general formula J has strong bleaching ability and can bleach silver in a short time. This bleaching period is generally less than 2 minutes, although this time varies depending on the temperature used, the processing conditions and the like. In addition, an iron (III) may be included -ionkomplex therein and will not, even at a low temperature, for example less than 10 ⁰ C precipitated. In particular, the bleaching and fixing agent composition according to the invention is superior to the bleaching and fixing agent compositions of the prior art in that it is possible with the bleaching and fixing agent composition of the invention to produce color photographic materials with a sensitivity sufficient for camera sensitivity, for example Color negative films and color reversal films, easy to bleach and fix, while it is difficult to bleach and fix such materials with prior art compositions "

The following examples are provided for. further explanation the 'invention without limiting it. Unless otherwise stated, All percentages and parts are based on weight.

example 1

This example was made using a color photographic Negative material obtained by mixing and emulsifying a red-sensitive silver iodobromide emulsion (silver iodide 7 mol%) and 1-hydroxy »4-chloro» 2 ~ n ~ dodecylnaphthoamide as Cyan coupler, mixing and emulsifying a green sensitive

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Silberöodbromids (silver iodide 6 mol #) and 1- (2 ', 4', 6 "-Trichlorphenyl) -3- (3" - (2 ^! J ', 4 " ^! -Di-tert.-amylplienoxyacetamid) -benzamid)« 5-pyrazolone as the magenta coupler, and mixing and emulsifying a blue-sensitive Silberjodbroraidemulsion (silver iodide 6 mol? o) and a- (2-methylbenzoyl) acetophenone ~ ^{(2-chloro-5'-f} dodecöxycarbon3'l) anilide as a yellow coupler and then applying of the resulting emulsions had been prepared on a triacetate film base. To emulsify the respective coupler, dibutyl phthalate and tricresyl phosphate were used as coupler solvents, sorbitan monolaurate and sodium d'odecylbenzenesulfonate were used as emulsifiers, and sodium i- (p-nonylphenoxytrioxyethylene) butane-4-sulfonate and the lauric acid auxiliary ester of sucilylic acid ester were added.

This film was "exposed" and then subjected to the following treatment I:
Treatment I.

Color development 12 min

Stop bath 4 min

Hardening bath 4 min

Water wash 4 min

Bleach and fix bath in the following
the table
give ¥ water laundry 8 min Drying Composition of the color developer Benzyl alcohol 5 ml Sodium hydroxide 0.5 g Diethylene glycol 3 ml Sodium hexametapho sphat 2 g Sodium sulfite 2 g Potassium bromide '. 2g 4 ~ Amino-3-roethyl-N-ethyl-ß-hydroxyethyl-
aniline sesquisulfate monohydrate 5 g Metaboric acid 0.5 g Sodium metaborate 77 g Water to _..._ '. . 1000 ml

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30th G 8th ml 1000 ml 1 S. 20th G 10 ml

Stop solution

Nat riumac e tat

Glacial acetic acid

Water too
Hardening bath

Natriuuihexame tapho spha t

Borax pentahydrate

Formalin (37 # ig)
Bleach · and Fixing Solution A

Iron (III) sodium ethylenediaminetetraacetate (dihydrate) 80 g

Disodium ethylenediamine tetraacetate

(dihydrate) 15 g

Sodium carbonate monohydrate - 17 g

Boric acid 5 g

Sodium sulfite 5 g

Ammonium thi ο sulfate (70 ^ ige aqueous solution) 160 ml pH 5.5

1000 ml of water

Bleach and fix solution B

2 × 10 "· ^ mol / l of the compound 1 of the invention became

added to the bleaching and fixing solution A.

Bleach and fix solution C

2 × 10 "" - 'mol / l of the compound 2 of the invention became

added to the bleaching and fixing solution A.

Bleach and fix solution D

2 × 10 "^ mol / l of the compound 3 of the invention became

added to the bleaching and fixing solution A.

Bleach and fix solution E.

2 χ 10 "· ^ mol / l of a known compound * 'became the

Bleaching and fixing solution A added.

Link*

2Br

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Bleaching and fixing solution ^ F _m .

2 χ 10 moles /], a known compound, were too added to the bleaching and fixing solution A.

Link '

2Br

The time to bleach and fix would be determined by measuring the time required to complete desilvering using X-ray fluorescence analysis, measured ,, The results obtained are in the following Table listed.

Remaining and fixing solution Time to bleach and fix

A 4 min 20 sec

B 1 min 10 sec

C 1 in in 40 sec

D 1 min 20 sec

E 3 min 20 sec

F, 2 min 50 sec.

The time required for bleaching and fixing became when the bleaching and fixing solutions B, C and D of the invention used compared to the time required for bleaching and fixing solutions A, E and F v; ar, shortened.

Example 2. "

A color paper was made _? by a silver bromide emulsion containing an emulsified Gelbkuppierdispersion _s a silver chlorobromide emulsion, an emulsified dispersion of magenta coupler (silver chloride 70 mol%) containing a _s an emulsified Cyankuppler- a Barytpapierbahn

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dispersion (silver chloride 70 mol #) containing silver chlorine • bromide emulsion and a gelatin layer containing an ultraviolet light absorber were applied. Each coupler emulsion was prepared by dissolving the coupler in a mixture of dibutyl phthalate and tricresyl phosphate and dispersing it in a gelatin solution in an o / w type using sorbitan monolaurate, Turkish red oil and sodium dodecylbenzenesulfonate as emulsifying agents. 1- (2 ', 4', 6 ^t -trichlorophenyl) -3- (3 ^lt - (2 "', 4" ^f -di-tert. ~ Amylphenoxyacetamide) -benzamide) -pyrazolone, 1- (hydroxy ) ~ 4-chloro-2-n-dodecylnaphthamide and α- (2-methylbenzoyl) -aceto- (2'-chloro-5'- "dodecoxycarbonyl) -anilide as yellow, magenta and cyan couplers, respectively. Was used as an ultraviolet absorbent that mentioned in Japanese Patent Publication Sho-45-9586 was used, as the emulsion hardener, sodium salt of 2,4-dichloro-6-hydroxy-1,3,5-triazine was used, and the thus prepared color paper was exposed to light using a color reproducer then subjected to the following color removal treatments:

development temperature Time Color development 30 ° C 6 min To stop ti 2 min Water washing !! 2 min Bleaching and fixing Il in the following Ta Belle stated Water washing Il 2 min Stabilizing bath Il 2 min Drying Il 2 min

The treatment solutions used were as follows Compositions:

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Color developer

12 ml ml 1000 ml 3.5 20 g G 2.0 ε 0.4 ε 1.0 G 4.0 G 2.0 G 2.0 G 5.0

Benzyl alcohol Diethylene glycol Sodium hydroxide Sodium sulfite Potassium bromide sodium chloride borax

Hydroxylamine sulfate ethylenediaminetetraacetic acid

4-Amino-3-methyl-N-ethyl-N- (ß-sulfonamidethyl) aniline sesquisulfate monohydrate

'' Water to top solution

Sodium thiosulphate · '■. * 10 g

Ammonium thiosulfate (70% aqueous solution)

Sodium acetate '. '

Acetic acid potash alum

Water to stabilize solution. Boric acid Sodium citrate Sodium nnetaborate tetrahydrate

Potash '

Water to - - _

Bleach and fix solution G- -

Iron (III) sulfate. . 20g.

Disodium ethylenediamine tetraacetate

dihydrate. 36 g

Sodium carbonate monohydrate 17 g

Sodium sulfite. . 5g

Ammonium thiosulfate (70% aqueous solution) 100 ml Boric acid, ■ 5g

pH advertising 6.8

Water to, 1000 ml

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30th ml 5 G 30th ml 15th G 1000 ml 5 G 5 G 3 G 15th G 1000 ml

Bleach and fix solution H

To the bleaching and fixing solution G 1 10 " ^J mol / l of the compound 3 of the invention was added.

The time required for bleaching and fixing "became measured using the bleaching and fixing solutions G and H. The results obtained are in the following Table listed:

Bleaching and fixing solution Time to bleach and fix G 60 sec

H 45 sec

The time required for bleaching and fixing was when using the bleaching and fixing solution H of the invention shortened compared to the time required using the bleaching and fixing solution G.

Example 3

Two bleach and fix solutions of the following compositions were prepared:
BI calibration and fixing solution I

Sodium sulfite 5 g

Iron (III) sodium ethylenediamine-N- (ßoxyethyl) -N _f N ^l , N ^l triacetate 180 g

Sodium thiocyanate 150 g

Sodium thiosulfate (70% aqueous solution) 50 ml 1000 ml of water

Bleach and fix solution J

3 x 10 "x ^ mol / l of the compound 1 of the invention to the bleaching and fixing solution I added.

The same color film as described in Example 1 was used used and the same treatment as described in Example 1, subjected.

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The time required for bleaching and fixing vairde using the bleaching and fixing solutions I and J. The results obtained are shown in the table below:

Bleaching and fixing solution Time for bleaching and fixing I 1 min 30 sec ·

J 45 sec

The time required for bleaching and fixing became using the bleaching and fixing solution J of the invention shortened compared to the time taken using the bleach and fixing solution I. The bleach and fix solution the invention can also be used in a satisfactory manner as a bleaching and fixing solution for a commercial interior reversal color film, for example, "according to US Pat. No. 3,502,322 can be used.

Example 4

Treatment I according to Example 1 was under. Use ■ of a bleaching and fixing solution of the following composition in place of the bleaching and fixing solution: Ble i chlösimg A

Iron (III) sodium ethylenediaminetetraacetate dihydrate 100 g

Potassium bromide 50 g

pH 6.0

1000 ml of water

Lead solution. B.

3 x 10 "- ^ mol / l of compound 3 of the invention

added to the bleaching solution A.

Fixing solution

Sodium sulfite. 4g

Sodium bisulfite ■ 4g

Ammonium thiosulfate (70% aqueous solution) 140 ml 1000 ml of water

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The time required for bleaching was made using the Blelchlösungeri A and B measured. Fixing took place in each case for 6 minutes. The results obtained are shown in the table below:

Bleach solution . Time to calibrate

A 3 min. 10 sec

B 1 min

The time required for bleaching became when using the bleaching solution B of the invention in comparison with that under Use of the bleaching solution A shortens the time required.

At sple iß 5

Similar procedure to that described in Example 4 bene was repeated using bleach solutions, each of which had the following composition:

Potassium persulfate 50 g

Potassium bromide 5g

pH 3.2 g

1000 ml of water

Bleach solution D

5 x 10 "* ·" mol / l of Compound 1 of the invention became the bleach solution C added.

The time required for bleaching was measured using bleaching solutions C and D. The results obtained are shown in the following table:

Bleach solution Time to bleach

C 13 min

D 2 min 30 sec

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The time required for bleaching was when using Preparation of the bleaching solution D of the invention compared to that shortens the time required using the bleaching solution C,

The invention has been described above on the basis of a preferred embodiment s forms are described without being limited to them.

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Claims (21)

Claims 1y photographic treatment of the street is recognized net 'by a content of (1) an iron (III) ion complex or a persulfate and (2) a compound of the general formula wherein R ,. diq groupings E. ' or
X " means _} where R _{2 is} an alkyl group or the grouping —fCH ₂ ^ - ^S0 3 "~ t ⁿ 3 or 4 and X" is an anion which is absent when R _{2 is} a grouping —fCH ₂ 4r · SO -, "* . 2. Photographiπehe treatment composition according to claim 1, characterized in that R _{2 is} a methyl radical, ethyl radical, the grouping —fCH ₂ -W SO ₇ " or —fCHg ^ Tj; SO-""andX" is a bromide ion or a p-toluenesulfonate ion means. 3. Photographic treatment composition according to claim 1 to 2, characterized in that the composition represents a bleach solution. 038.15 / 107 4. Photographic treatment composition according to claim 3, characterized in that the bleach « solution also contains a bromide and a pH buffering agent. 5. Photographer :! see. Treatment mass according to claim 4, characterized in that the Είε-en- (III) ion complex salt or the persulfate is present in an amount of about 0.1 to 2 parts per liter of bleach solution, the compound of the general formula (I) in about 2 χ 10 "to -2 2 χ 10 mol per 1 of the bleaching solution is present and where the The pH of the bleaching solution is in the range from 3 to 8 when the iron (III) ion complex. is present and is about 1 to 7, when the persulfate is present. 6. Photographic processing composition according to claim 1 to 5, characterized in that the compound of the general formula (I) is selected from the following compounds consists: 409815/1070 CH ₃ -K N-CH, 2 Br " 7. Pho.tographic treatment wet according to claim 1, there, characterized in that the mass represents a bleaching and fixing solution. 8. Photographic treatment composition according to claim 7, da- indicated by additionally contains thiosulphate. that the solution 9. Photographic processing composition according to claim 8, da characterized in that the iron (III) ion complex salt or the persulfate is present in an amount of about 0.1 to 2 hols per 1 bleaching and fixing solution, 409 8 1 5/1 070 the fixing agent in an amount of about 0.2 to 4 moles per liter Bleaching and fixing solution is present, the compound of the general formula (I) in an amount of about 2 10 "to —2 2 10 mol per 1 of the bleaching and fixing solution is present and the pH value of the bleaching and fixing solution is about 4 to 8. · 10. A method for developing an exposed light-sensitive photographic silver halide element, characterized in that - that the photographic Silver halide element is developed and brought into contact with a bath which the photographic Treatment mass according to claim 1 contains. 11. A method for developing according to claim 10, characterized in that the mass
is used as a bleach solution. ' 12. The method for Entwi disgusting according to claim 11, characterized in that a bleaching solution is used, which additionally contains a broinid and a pH buffering agent. 13. The method for developing according to claim 10, characterized in that as a compound of the general formula (I) the following compounds are used: 409515/1070 H-CH ₃ 2 CH K ⁺ - (CH, 2 Br " 14. The method for Entv / i disgusting according to claim 10, characterized in that the mass is used as a bleaching and fixing solution. 409815/1070 15. The method for developing according to claim 14, since " characterized by having a solution is used, which additionally contains thiosulfate. 16. A method of accelerating the bleaching or bleaching and fixing of a silver halide photographic element in processing the silver halide photographic element, characterized in that the photographic silver halide element subjected to a bleaching or a bleaching and fixing process with a bath containing the photographic processing composition according to claim 1. 17. A method for accelerating bleaching or bleaching and fixing according to claim 16, characterized in that marked that Hasse as a bleach solution is used. . 18. A method for accelerating the bleaching or bleaching and fixing, according to claim 17, characterized in - that a _t Bleichlösimg is used, in addition d.ie a bromide and a pH buffering agent contains · * ■ -.. " 19. Method of accelerating the bleaching or the Bleaching and fixing according to claim 16, characterized marked that as a compound of general Formula (I) the following compounds are used: 409815/1070 '2 " _Ox S- (CH ₀ ), -H 2 Br- 20. A method for accelerating the bleaching or bleaching and fixing according to claim 16, characterized in that the Hasse as bleaching and
Fixing solution used. 21. Method of accelerating bleaching or bleaching and fixation according to claim 20, characterized draws that a solution is used that too additionally contains a thiosuli'ate " 409815/1070