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DE2265663C2 - herbicide - Google Patents

herbicide

Info

Publication number
DE2265663C2
DE2265663C2 DE19722265663 DE2265663A DE2265663C2 DE 2265663 C2 DE2265663 C2 DE 2265663C2 DE 19722265663 DE19722265663 DE 19722265663 DE 2265663 A DE2265663 A DE 2265663A DE 2265663 C2 DE2265663 C2 DE 2265663C2
Authority
DE
Germany
Prior art keywords
produced
mixtures
oils
mixture
active substance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE19722265663
Other languages
German (de)
Inventor
Adolf Dr. 6704 Mutterstadt Fischer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to DE19722265663 priority Critical patent/DE2265663C2/en
Priority claimed from DE2217722A external-priority patent/DE2217722C2/en
Application granted granted Critical
Publication of DE2265663C2 publication Critical patent/DE2265663C2/en
Expired legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N35/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
    • A01N35/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical at least one of the bonds to hetero atoms is to nitrogen
    • A01N35/10Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical at least one of the bonds to hetero atoms is to nitrogen containing a carbon-to-nitrogen double bond
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/88Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N45/00Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring
    • A01N45/02Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring having three carbocyclic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C65/00Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C65/21Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing ether groups, groups, groups, or groups

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

N-RNO

/SO,/SO,

In der R einen niederen Alkylresi mit bis zu 4 C-Aiomen bedeutet, oder deren Salzen, wie Alkall-, Erdalkall·, Ammonium-, Hydroxyalkyl- oder Alkylammonlum- und Hydrazinsalze, beispielsweise Salze mit Natrium, Lithium, Kalium, Calcium, Elsen, Methylammonium, Trlmethylamrnonlum. Äthylammonium, Dlälhanolammonlum, Äthanolamrnonlum, Dlmethylamln, Dlmethylälhanolamln, Hydrazin oder Phenylhydrazin, undIn the R a lower alkyl resi with up to 4 carbon atoms means, or their salts, such as alkali, alkaline earth ·, ammonium, hydroxyalkyl or Alkylammonium and hydrazine salts, for example salts with sodium, lithium, potassium, calcium, Elsen, methylammonium, trimethylammonium. Ethylammonium, Dilhanolammonium, Ethanolammonium, Dlmethylamln, Dlmethylälhanolamln, hydrazine or phenylhydrazine, and

3) 9-Hydroxy-lluorencarbonsaure-(9)3) 9-Hydroxy-lluorencarbonsaure- (9)

|ne bessere herbizide Wirkung als die Einzelwirkstoffe| ne better herbicidal effect than the individual active ingredients

I Die Wirkstoffe a und b können In Mengen von 0,5 bis kg/ha angewandt werden.I The active ingredients a and b can in amounts of 0.5 to kg / ha can be applied.

J Das Mischungsverhältnis der Wirkstoffe a : b beträgtJ The mixing ratio of the active ingredients a: b is I: I bis I : 5, vorzugsweise 3 :1 bis I : 3 Gewichtstelle.I: I to I: 5, preferably 3: 1 to I: 3 weight positions.

]Dle Mischungen sind geeignet In Nutzpflanzenkultui, z. B. Getreide, Reis, Soja. Mals, Kartoffeln, Erbsen bd Bohnen, unerwünschte Pflanzen, beispielsweise] The mixtures are suitable in cultivation of useful plants, z. B. cereals, rice, soy. Mals, potatoes, peas bd beans, unwanted plants, for example

Tabelle 1Table 1

WlrkjtoffWlrkjtoff BB. 00 33 00 AA. II. 00 1,51.5 22 00 33 00 B + AB + A kg/ha aktive Substanzkg / ha of active substance II. 00 1515th 0.750.75 00 00 00 00 1+21 + 2 Trltlcum aestlvumTrltlcum aestlvum 3030th 8585 00 4040 00 7070 8080 00 Hordeum vulgäreHordeum vulgar 3030th 9090 00 6060 6060 9090 9090 00 Gallum aparlneGallum aparlne 3030th 9595 3535 4040 7070 6060 7070 100100 Stellarla mediaStellarla media 4040 5050 100100 Lamlum emplexlcauleLamlum emplexlcaule -- 3030th 100100 0 * ohne Schldl|un|0 * without Schldl | un | 100 ■ lolale Schldl|uni100 ■ lolale Schldl | uni

VersuchsberichtTest report

Gerste {iiordeum vulgäre). Roggen (Seeale eereale). Weizen (Trltlcum aestlvum), Klebkraut (Gallum aparlne) und stengelumfassende Taubnessel (Lamlum amplexlcaule) wurden Im Gewächshaus bei einer Wuchshöhe von 4 bis 20 cm mit den Wirkstoffen A und B entsprechend Beispiel I der vorliegenden Anmeldung und deren Mischungen, jeweils emulglert oder dlsperglerl In Liter Wasser je Hektar, behandelt. Die Schädigung der Pflanzen wurde nach einer Skala von 0 bis 100 bewertet. Dabei bedeutet 100 kein Aufgang der Pflanzen bzw. völlige Zerstörung zumindest der oberirdischen Teile. Die Testergebnlsse sind In der folgenden Tabelle enthalten.Barley {iiordeum vulgare). Rye (Seeale eereale). Wheat (Trltlcum aestlvum), sticky herb (Gallum aparlne) and dead nettle that surrounds the stem (Lamlum amplexlcaule) were in a greenhouse at a height of 4 to 20 cm with the active ingredients A and B accordingly Example I of the present application and mixtures thereof, each emulsified or dlsperglerl In Liters of water per hectare. The damage to the plants was rated on a scale from 0 to 100. 100 means no emergence of the plants or complete destruction of at least the above-ground parts. the Test results are shown in the table below.

Wirkstoffe Aufwandmenge Testpflanzen und Schädigung [%]Active ingredients Application rate test plants and damage [%]

[kg/ha] Hordeum Seeale Trltlcum Gallum Lamlum[kg / ha] Hordeum Seeale Trltlcum Gallum Lamlum

vulg. ccreale aestlvum aparlne amplex.vulg. ccreale aestlvum aparlne amplex.

0.50.5 00 00 0,750.75 00 00 1.01.0 00 00 1.51.5 00 00 0.50.5 00 00 0.750.75 00 00 1.01.0 00 00 1.51.5 00 00 0,5 +1,00.5 +1.0 00 00 1,0 +0,51.0 +0.5 00 00 0,75 + 0,750.75 + 0.75 00 00

0
0
0
0
0
Q
0
0
0
0
0
0
0
0
0
0
Q
0
0
0
0
0

30 35 40 60 10 20 30 40 98 95 9730 35 40 60 10 20 30 40 98 95 97

18 30 40 50 10 20 30 40 90 90 9018 30 40 50 10 20 30 40 90 90 90

Claims (1)

Inta: AOl N 43/88
Veröffentlichungstag: 5.1.83
Inta: AOL N 43/88
Publication day: 5.1.83
Patentanspruch:Claim: Herbizid, enthaltend eine Mischung aus
a) einer Verbindung der Formel
Herbicide containing a mixture of
a) a compound of the formula
dlkoiyle Samenunkräuter, monokotyle Samenungräser oder Cyperaceen zu bekämpfen.dlkoiyle seed weeds, monocot seed weeds or to fight cyperaceae. Die Mischungen können Im Vorauflaufverfahren und/oder Im Nachauflaufverfahren angewandt werden. Die neuen Mischungen können als Herbizide In Form von Lösungen, Emulsionen, Suspensionen, Stäubemitteln oder Granulaten angewendet werden. Die Anwendungsformen richten sich ganz nach den Verwendungszwecken; sie sollen In jedem Fall eine feine Verteilung to der wirksamen Substanzen gewährleisten.The mixtures can be pre-emerged and / or be used post-emergence. The new mixtures can be used as herbicides in the form of solutions, emulsions, suspensions, dusts or granules are used. The application forms depend entirely on the intended use; they should in any case have a fine distribution to ensure the effective substances. Zur Herstellung von direkt versprühbaren Lösungen kommen Mineralölfraktionen von mittlerem bis hohem Siedepunkt wie Kerosin oder Dieselöl, ferner Kohlenteeröle sowie Öle pflanzlichen oder tierischen Ursprungs, In der R einen niederen Alkylresi mit bis zu 4 C- 15 außerdem cyclische Kohlenwasserstoffe, wie Tetrahydro-Atomen bedeutet, oder deren Salzen und naphthalin, und alkyllerte Naphthaline In Betracht,Medium to high mineral oil fractions are used to produce solutions that can be sprayed directly Boiling point like kerosene or diesel oil, also coal tar oils as well as oils of vegetable or animal origin, in the R a lower alkylresi with up to 4 C-15 also cyclic hydrocarbons, such as tetrahydro atoms means, or their salts and naphthalene, and alkyl-tertiary naphthalenes. b) 9-Hydroxy-fluorencarbonsäure-(9). Wäßrige Anwendungsformen können aus Emulsionsb) 9-Hydroxy-fluorene carboxylic acid- (9). Aqueous application forms can be made from emulsions konzentraten, Pasten oder netzbaren Pulvern (Sprltz-concentrates, pastes or wettable powders (spray pulvern) durch Zusatz von Wasser bereitet werden. Zurpowders) can be prepared by adding water. To the Herstellung von Emulsionen können die Substanzen als solche oder In einem Lösungsmittel gelöst, mittels Netzoder Dispergiermittel In Wasser homogenisiert werden. Es können aber auch aus wirksamer Substanz, Emulgier- oder Dispergiermittel und eventuell Lösungsmittel bestehende Konzentrate hergestellt werden, die zur Verdünnung mit Wasser geeignet sind Zu fertigen Spritzbrühen können Öle verschiedenen Typs zugesetzt werden.Production of emulsions can use the substances as those or dissolved in a solvent, homogenized in water by means of a wetting agent or dispersant. But it can also consist of an active substance, emulsifying or dispersing agent and possibly a solvent Concentrates are produced which are suitable for dilution with water. To finished spray liquors various types of oils can be added. Stäubemittel können durch Mischen oder gemeinsames Vermählen der wirksamen Substanzen mit einem fei'.en Trägerstoff hergestellt werden.Dusts can be produced by mixing or grinding together the active substances with one fei'.en carrier material can be produced. Granulate können durch Bindung der Wirkstoffe an feste Trägerstoffe hergestellt werden.Granules can be produced by binding the active ingredients to solid carriers. Außerdem können mit ölen direkt versprühbare Dispersionen hergestellt werden.In addition, dispersions that can be sprayed directly with oils can be used getting produced. Die Mischungen können mit Düngemitteln, Insektiziden, Fungiziden oder anderen Herbiziden gemischt werden. The mixtures can be mixed with fertilizers, insecticides, Fungicides or other herbicides. Beispiel 1example 1 Die Pflanzen Weizen (Trltlcum aestlvum), Gerste A0 (Hordeum vulgäre). Klebkraut (Gallum aparlne). Vogelmiere (Stellaria media) und stengelumfassende Taubnessel (Lamlum amplexlcaule) wurden bei einer Wuchshöhe von 4 bis 20 cm mit den nachfolgenden Einzelprodukten und deren Mischungen, jeweils emulglert oder dlsperglert In 500 Liter Wasser je Hektar, behandelt:The plants wheat (Trltlcum aestlvum), barley A0 (Hordeum vulgar). Sticky herb (Gallum aparlne). Chickweed (Stellaria media) and stalk-encompassing dead nettle (Lamlum amplexlcaule) were treated at a height of 4 to 20 cm with the following individual products and their mixtures, each emulsified or dlsperglert in 500 liters of water per hectare: A 3-lsopropyl-2.1.3-benzo-thladlazlnon-(4)-2.2-dloxld A 3-isopropyl-2.1.3-benzo-thladlazlnon- (4) -2.2-oxide 0.75, 1.5. 2 und 3 kg/ha aktive Substanz
B 9-Hydroxy-fluorencarbonsäure-(9).
0.75, 1.5. 2 and 3 kg / ha of active substance
B 9-Hydroxy-fluorene carboxylic acid- (9).
I und 3 kg/ha aktive Substanz
B + A 1.0 + 2.0 kg/ha aktive Substanz
I and 3 kg / ha of active substance
B + A 1.0 + 2.0 kg / ha of active substance
Aus nachfolgender Tabelle Ist zu ersehen, daß die Mischung nach 8 bis 12 Tagen gegenüber den Elnzel-S5 wirkstoffen eine bessere Gesamtwirkung bei günstiger Kullurpflanzenverträgllchkelt zeigt.The table below shows that the mixture after 8 to 12 days compared to the Elnzel-S5 active ingredients shows a better overall effect with favorable Kullurpflanze compatible. Die vorliegende Erfindung betrifft ein Herbizid, das ^lne Mischung aus zwei Wirkstoffen enthält.The present invention relates to a herbicide that ^ Contains a mixture of two active ingredients. Es ist bekannt, daß substituierte Fluorencarbonsäuren lind Benzihlothladiazlnone eine herbizide Wirkung [laben. Ihre herbizide Wirkung Ist jedoch schlecht.It is known that substituted fluorene carboxylic acids lind Benzihlothladiazlnone have a herbicidal effect [refresh. However, their herbicidal effects are poor. Es wurde gefunden, daß eine Mischung aus
j a) einer Verbindung der Formel
It has been found that a mixture of
yes) a compound of the formula
DE19722265663 1972-04-13 1972-04-13 herbicide Expired DE2265663C2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE19722265663 DE2265663C2 (en) 1972-04-13 1972-04-13 herbicide

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2217722A DE2217722C2 (en) 1972-04-13 1972-04-13 herbicide
DE19722265663 DE2265663C2 (en) 1972-04-13 1972-04-13 herbicide

Publications (1)

Publication Number Publication Date
DE2265663C2 true DE2265663C2 (en) 1983-01-05

Family

ID=25763055

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19722265663 Expired DE2265663C2 (en) 1972-04-13 1972-04-13 herbicide

Country Status (1)

Country Link
DE (1) DE2265663C2 (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1937551A1 (en) * 1969-07-24 1971-02-11 Basf Ag herbicide

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1937551A1 (en) * 1969-07-24 1971-02-11 Basf Ag herbicide

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Klimmer, O.R.: Pflanzenschutz- und Schädlings- bekämpfungsmittel, 2. Auflage, 1971, Seiten 87 bis 95 *

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