DE2034562A1 - Coloured detergent solutions - contg carboxylic acids as dye stabilisers - Google Patents
Coloured detergent solutions - contg carboxylic acids as dye stabilisersInfo
- Publication number
- DE2034562A1 DE2034562A1 DE19702034562 DE2034562A DE2034562A1 DE 2034562 A1 DE2034562 A1 DE 2034562A1 DE 19702034562 DE19702034562 DE 19702034562 DE 2034562 A DE2034562 A DE 2034562A DE 2034562 A1 DE2034562 A1 DE 2034562A1
- Authority
- DE
- Germany
- Prior art keywords
- acid
- content
- dye
- means according
- carboxylic acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000001735 carboxylic acids Chemical class 0.000 title claims abstract description 8
- 239000003381 stabilizer Substances 0.000 title claims abstract description 6
- 239000003599 detergent Substances 0.000 title claims description 16
- 239000004094 surface-active agent Substances 0.000 claims abstract description 18
- 239000002253 acid Substances 0.000 claims abstract description 14
- DZBUGLKDJFMEHC-UHFFFAOYSA-N acridine Chemical compound C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 150000003839 salts Chemical class 0.000 claims abstract description 7
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 4
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims abstract description 4
- 150000004056 anthraquinones Chemical class 0.000 claims abstract description 4
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 claims abstract description 4
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical class O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 claims abstract description 4
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 claims abstract description 4
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 claims abstract description 3
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000000975 dye Substances 0.000 claims description 28
- 150000007513 acids Chemical class 0.000 claims description 11
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 10
- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 claims description 10
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 10
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 8
- 238000004851 dishwashing Methods 0.000 claims description 7
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 6
- 239000012459 cleaning agent Substances 0.000 claims description 6
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 6
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 5
- 239000001530 fumaric acid Substances 0.000 claims description 5
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 5
- 239000011976 maleic acid Substances 0.000 claims description 5
- 239000005711 Benzoic acid Substances 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 235000010233 benzoic acid Nutrition 0.000 claims description 4
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 3
- 229960004889 salicylic acid Drugs 0.000 claims description 3
- 102000004190 Enzymes Human genes 0.000 claims description 2
- 108090000790 Enzymes Proteins 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 239000008139 complexing agent Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000002304 perfume Substances 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 150000004961 triphenylmethanes Chemical class 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 1
- 238000005406 washing Methods 0.000 abstract description 2
- 238000004140 cleaning Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 230000000087 stabilizing effect Effects 0.000 description 8
- 229920003023 plastic Polymers 0.000 description 6
- 239000004033 plastic Substances 0.000 description 5
- -1 amine salts Chemical class 0.000 description 4
- 239000000987 azo dye Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- RGCKGOZRHPZPFP-UHFFFAOYSA-N Alizarin Natural products C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- HFVAFDPGUJEFBQ-UHFFFAOYSA-M alizarin red S Chemical compound [Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C=C(S([O-])(=O)=O)C(O)=C2O HFVAFDPGUJEFBQ-UHFFFAOYSA-M 0.000 description 2
- 239000001000 anthraquinone dye Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 239000011975 tartaric acid Substances 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- 229910052724 xenon Inorganic materials 0.000 description 2
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 2
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- VOQAOTALYZIMDB-UHFFFAOYSA-N 2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethyl hydrogen sulfate Chemical compound OCCOCCOCCOCCOS(O)(=O)=O VOQAOTALYZIMDB-UHFFFAOYSA-N 0.000 description 1
- SLAMLWHELXOEJZ-UHFFFAOYSA-N 2-nitrobenzoic acid Chemical compound OC(=O)C1=CC=CC=C1[N+]([O-])=O SLAMLWHELXOEJZ-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 239000000999 acridine dye Substances 0.000 description 1
- DPKHZNPWBDQZCN-UHFFFAOYSA-N acridine orange free base Chemical compound C1=CC(N(C)C)=CC2=NC3=CC(N(C)C)=CC=C3C=C21 DPKHZNPWBDQZCN-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229940042400 direct acting antivirals phosphonic acid derivative Drugs 0.000 description 1
- FPAYXBWMYIMERV-UHFFFAOYSA-L disodium;5-methyl-2-[[4-(4-methyl-2-sulfonatoanilino)-9,10-dioxoanthracen-1-yl]amino]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1S([O-])(=O)=O FPAYXBWMYIMERV-UHFFFAOYSA-L 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003007 phosphonic acid derivatives Chemical class 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- FTUYQIPAPWPHNC-UHFFFAOYSA-M sodium;4-[[4-[benzyl(ethyl)amino]phenyl]-[4-[benzyl(ethyl)azaniumylidene]cyclohexa-2,5-dien-1-ylidene]methyl]benzene-1,3-disulfonate Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=CC=CC=2)C=2C(=CC(=CC=2)S([O-])(=O)=O)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC=C1 FTUYQIPAPWPHNC-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/362—Polycarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/368—Carboxylic acids; Salts or anhydrides thereof with carboxyl groups directly bound to carbon atoms of aromatic rings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Emergency Medicine (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Lichtbeständig angefärbte flüssige oder pastenförmige Wasch-, Spül- und Reinigungsmittel Die Erfindung betrifft lichtbeständig angefärbte flüssige oder pastenförmige Wasch-, Spül- und Reinigungsmittel, die zur Verbesserung der Lichtbeständigkeit ein Farbstoff-Stabilisiermittel enthalten. Die Erfindung hat Bedeutung für solche Produkte, die in lichtdurchlässigen Glas- oder Kunststoffbehältern abgepackt werden. Liquid or paste-like washing, dishwashing and rinsing detergents colored to be light-resistant and detergents The invention relates to light-resistant colored liquid or paste-like detergents, dishwashing detergents and cleaning agents that improve lightfastness contain a dye stabilizer. The invention has relevance to such Products packed in translucent glass or plastic containers.
Gefärbte flüssige Wasch-, Spül- und Reinigungsmittel werden in ständig steigendem Umfang auf den Markt gebracht. Das Anfärben solcher Produkte ist ohne weiteres mit handelsüblichen Farbstoffen möglich, doch ist die Lichtbeständigkeit der meisten gängigen Farbstoffe in wäßrigen Tensidlösungen sehr gering.Colored liquid detergents, dishwashing detergents and cleaning agents are in constant use brought to the market to an increasing extent. The coloring of such products is without further possible with commercially available dyes, but the light resistance is of most common dyes in aqueous surfactant solutions is very low.
Schwierigkeiten treten besonders dann auf, wenn die gefärbten Produkte in klar durchsichtige oder durchscheinende Behälter, z. B. aus Glas oder durchsichtigen Kunststoffen, abgepackt sind und in dieser Form in Schaufenstern oder an anderen demldirekten Sonnenlicht ausgesetzten Orten aufgestellt werden. Es kann dann zu Farbumschlägen oder einem raschen Ausbleichen der Farbstoffe kommen, wodurch die Produkte unansehnlich und unverkäuflich werden. Die Lichtechtheit eines Farbstoffes im textilen Bereich läßt keine Rückschlüsse auf seine Lichtbeständigkeit in einer Tensidlösung zu.Difficulties arise especially when the colored products in clear transparent or translucent containers, e.g. B. made of glass or transparent Plastics, are packaged and in this form in shop windows or on others be placed in places exposed to direct sunlight. It can then too Color changes or rapid fading of the dyes occur, which causes the Products become unsightly and unsaleable. The lightfastness of a dye in the textile sector does not allow any conclusions to be drawn about its light resistance in one Surfactant solution too.
Gegenstand der Erfindung sind lichtbeständig angefärbte flüssige oder pastenförmige Wasch-, SpUl- und Reinigungsmittel auf der Basis von gelöste Farbstoffe enthaltenden Tensidlösungen, die gekennzeichnet sind durch einen Gehalt an Carbonsäuren aus der Gruppe der aliphatischen Polyearbonsauren und der aromatischen Mono- und Poiycarbonsäuren und deren wasserlöslichen Salzen.The invention relates to liquid or lightfastly colored paste-like detergents, dishwashing detergents and cleaning agents based on dissolved dyes containing surfactant solutions that are marked by a Content of carboxylic acids from the group of the aliphatic polyearboxylic acids and the aromatic mono- and polycarboxylic acids and their water-soluble salts.
Uberraschenderweise hat sich gezeigt, daß die Carbonsäuren eine erhebliche Verbesserung der Lichtbeständigkeit von Farbstoffen in Tensidlösungen bewirken, so daß die geschilderten Nachteile ganz oder weitgehend vermieden werden. Derartig stabilisierte Lösungen können unbedenklich in durchsichtige oder transparento Flaschen oder sonstige Behälter aus Glas oder lichtdurchlässigen Kunststoffen, wie Polyvinylchlorid, oder in Tuben oder Kissen aus lichtdurchlässigen plastischen Kunststoffen aus Polyvinylchlorid oder anderen plastischen Massen abgepackt und in Schaufenstern oder an anderen stark belichteten Orten aufgestellt oder gelagert werden.Surprisingly, it has been found that the carboxylic acids have a considerable Improve the light resistance of dyes in surfactant solutions, so that the disadvantages outlined are completely or largely avoided. Such Stabilized solutions can be safely stored in clear or transparent bottles or other containers made of glass or translucent plastics, such as polyvinyl chloride, or in tubes or pillows made of translucent plastic plastics made of polyvinyl chloride or other plastic masses and packed in shop windows or on other strong exposed locations or stored.
Als aliphatische Polycarbonsäuren kommen in erster Linie Dkcarbonsäuren mit 4 - 18 C-Atomen in Betracht. Die aliphatischen Reste können Doppelbindungen enthalten oder durch Hydroxyl-oder Nitrogruppen substjtuiert sein. Beispiele für geeignete Säuren sind Maleinsäure, Fumarsäure Bernsteinsäure, Sebazinsäure und Weinsäure. Als Beispiel für eine Tricarbonsäure ist Zitronensäure zu nennen.The aliphatic polycarboxylic acids are primarily dkcarboxylic acids with 4-18 carbon atoms. The aliphatic radicals can have double bonds contain or be substituted by hydroxyl or nitro groups. examples for suitable acids are maleic acid, fumaric acid, succinic acid, sebacic acid and tartaric acid. Citric acid is an example of a tricarboxylic acid.
Geeignete aromatische Mono und Polycarbonsäuren leiten sich vorzugsweise vom Benzol ab durch Substitution eines oder mehrerer Wasserstoffatome des Benzolkernes durch Carbotylgruppen.Suitable aromatic mono and polycarboxylic acids are preferably derived from benzene by substituting one or more hydrogen atoms of the benzene nucleus by carbotyl groups.
Weitere Wasserstoffatome können durch Alkylreste mit 1 - 12 C-Atomen, Halogenatome, und insbesondere Rydroxyl- oder Nitrogruppen substituiert sein. Beispiele hierfür sind Benzoesäure, o-Nitrobenzoesäure, Salizylsäure, o-Phthalsäure, Terephthalsäure und Mellithsäure.Additional hydrogen atoms can be obtained through alkyl radicals with 1 - 12 carbon atoms, Halogen atoms, and in particular hydroxyl or nitro groups, may be substituted. Examples these are benzoic acid, o-nitrobenzoic acid, salicylic acid, o-phthalic acid, terephthalic acid and mellitic acid.
In allen Fällen können auch die wasserlöslichen Salze der genannten Säuren, insbesondere die Natrium-, Kalium-, Ammonium und Aminsalze verwendet-werden. Die Carbonsäuren entfalten ihre Stabilisierwirkung in einem Konzentrationsbereich von oß2 - 5 Gewichtsprozent, bezogen auf die Tensidlösung.In all cases, the water-soluble salts of the above can also be used Acids, especially the sodium, potassium, ammonium and amine salts are used. The carboxylic acids develop their stabilizing effect in a concentration range of oß2 - 5 percent by weight, based on the surfactant solution.
Überraschenderweise hat sich gezeigt, daß die Stabilisierwirkung nicht wesentlich von der Farbstoffklasse abhängt, der die zur Anfärbung der Tensidlösung gewählten Farbstoffe angehören. Es werden Stabilisierwirkungen gegenüber in Tensidlösungen löslichen Farbstoffen beobachtet, die beispielsweise zur Klasse der Triphenylmethan-, Anthrachinon-, Azo-, Phthalocyanin-, Aminoketon-, Acridin-, Naphthol- und Pyrazolon-Farbstoffe gehören. Allerdings ist die Stabilisierwirkung nicht gegenüber allen Farbstoffen gleichmäBig ausgeprägt.Surprisingly, it has been shown that the stabilizing effect is not depends essentially on the class of dye used to color the surfactant solution chosen dyes belong to. There are stabilizing effects in relation to surfactant solutions soluble dyes observed, for example to the class of triphenylmethane, Anthraquinone, azo, phthalocyanine, aminoketone, acridine, naphthol and pyrazolone dyes belong. However, the stabilizing effect is not against all dyes evenly pronounced.
Die nachfolgenden Farbstoffe eignen sich zum Anfärben von Tensidlösungen. Sie seien als Beispiele für das Auftreten von Stabilisiereffekten genannt: Farbstoff Colour- Farbstoffklasse Index Azilanbrilliantblau 42735 Triphenylmethanfarbstöff Alizarincyaningrün 61570 Anthrachinonfärbstoff Patentblau-A 42080 Triphenylmethanfarbstoff C-ext. -Rot 12 12715 Pyrazolonfarbstoff C-ext.-Rot 17 15585 Azofarbstoff C-ext.-Rot 18 15620 Azofarbstoff Blütenrot R 1449 27920 Azofarbstoff Alizarinrubinol 3 G 68205 Anthrachinonfarbstoff C-gelb 12 14270 Azofarbstoff Acridinorange 46ovo5 Acridinfarbstoff C-orange 1 1192o I\zofarbstoff Von besonderer Bedeutung für den Stabilisierefrekt ist der pH-Wert der Tensidlösungen. Eine ausreichende Stabilisierwirkung zeigt sich nur im neutralen bis alkalischen pH-Bereich. Als günstig haben sich pH-Werte von 7 bis 12, vorzugsweise von lo bis 12 erwiesen.The following dyes are suitable for coloring surfactant solutions. They may be mentioned as examples of the occurrence of stabilizing effects: dye Color Dye Class Index Azilan Brilliant Blue 42735 Triphenylmethane Dye Alizarin Cyanine Green 61570 Anthraquinone Dye Patent Blue-A 42080 Triphenylmethane Dye C-ext. -Rot 12 12715 Pyrazolone Dye C-ext.-Red 17 15585 Azo Dye C-ext.-Red 18 15620 azo dye blossom red R 1449 27920 azo dye alizarin rubinol 3 G 68205 Anthraquinone dye C-yellow 12 14270 Azo dye acridine orange 46ovo5 Acridine dye C-orange 1192o dye Of particular importance to the The pH value of the surfactant solutions is the stabilizing factor. A sufficient stabilizing effect only shows up in the neutral to alkaline pH range. PH values have proven to be favorable from 7 to 12, preferably from 10 to 12.
Die Art der Tenside in der zu stabilisierenden Lösung ist dagegen von untergeordneter Bedeutung. Sie können zur Klasse der anionischen, ampholytischen oder nichtionogenen oberflächenaktiven Verbindungen gehören. Bevorzugt werden gut wasserlösliche Tenside, die sich zur Herstellung konzentrierter Handelsprodukte eignen, wie z. Bo Alkylsulfate, Alkyläthersulfate, Alkylsulfonate, Alkylbenzolsulfonate, Sulfobernstelnsäureester, Sulfofettsäureester, Anlagerungsprodukte von Athylenoxid bzw. Athylenoxid und Propylenoxid an höhere Fettalkohole oder Alkylphenole, Athylenoxidaddukte an Polypropylenglykole höherer Molgewichte und dergleichen.The type of surfactants in the solution to be stabilized is against it of minor importance. You can go to the class of anionic, ampholytic or nonionic surface active compounds. Preference is good water-soluble surfactants, which are used in the manufacture of concentrated commercial products suitable, such as Bo alkyl sulfates, alkyl ether sulfates, alkyl sulfonates, alkyl benzene sulfonates, Sulfosernstelic acid esters, sulfo fatty acid esters, addition products of ethylene oxide or ethylene oxide and propylene oxide with higher fatty alcohols or alkylphenols, ethylene oxide adducts to polypropylene glycols of higher molecular weights and the like.
In der Praxis werden zur Herstellung von Feinwaschmitteln, Geschirrspülmitteln, kosmetischen Waschmitteln, Haushaltsreinigungsmitteln und dergleichen meist Kombinationen der genannten Tenside in wäßriger Lösung, gegebenenfalls unter Zusatz von niederen Alkoholen oder Glykolen, angewendet.In practice, for the production of mild detergents, dishwashing detergents, Cosmetic detergents, household cleaning agents and the like mostly combinations of the surfactants mentioned in aqueous solution, optionally with the addition of lower ones Alcohols or glycols.
Die Produkte können darüber hinaus weitere Zusatz- oder Hilfsstoffe, z. B. Builder wie Phosphate, Polyphosphate oder Phosphonsäurederivate, z. B. Azetophosphonat, ferner Lösungsvermittler wie Harnstoff, Komplexbildner wie das Natriumsalz der Athylendiamintetraessigsäure, sowie Salze, Parfüms, Enzyme oder sonstige Zusatzstoffe enthalten. Derartige Produkte kommen in Form von Konzentraten mit einem Gehalt von etwa lo bis 50 Gewichtsprozent der genannten Stoffe in wäßriger oder wäßrig-alkoholischer Lösung in den Handel. Sie können dünnflüssig, hochviskos oder pastenförmig sein. Der Gehalt an Farbstoffen beträgt etwa o,ool bis o,2 Gewichtsprozent, vorzugsweise o,oo3 bis o,ol Gewichtsprozent.The products can also contain other additives or auxiliaries, z. B. builders such as phosphates, polyphosphates or phosphonic acid derivatives, e.g. B. acetophosphonate, also solubilizers such as urea, complexing agents such as the sodium salt of ethylenediaminetetraacetic acid, as well as salts, perfumes, enzymes or other additives. Such products come in the form of concentrates with a content of around lo to 50 percent by weight of the substances mentioned in aqueous or aqueous-alcoholic solution on the market. she can be thin, highly viscous or pasty. The salary of dyestuffs is about 0.02 to 0.2 percent by weight, preferably 0.03 to o, ol percent by weight.
Die Prüfung gefärbter Proben auf Lichtbeständigkeit erfolgte in einem Xenongerät, dessen Licht durch Filter so bemessen war, daß 72 Stunden Xenonlicht 3o mittleren Jahrestagen Belichtung durch Fensterglas entsprachen.The testing of colored samples for light resistance was carried out in one Xenon device, the light of which was measured by filters so that xenon light was 72 hours 3o mean anniversaries corresponded to exposure through window glass.
Es wurde folgende Tensidmischung zur Prüfung der Stabilisierwirkung herangezogen: 17 Gew.- Natrium-Alkylbenzolsulfonat 8 Gew. - Fettalkohol-C12-14-diglykoläthersulfat-Natrium 5 Gew. - Fettalkohol-C1214-octaglykoläther 5 Gew.-% Äthanol 65 Gew.-% Wasser In der folgenden Tabelle betrug die Konzentration der Stabilisiermittel l,o Gewichtsprozent, die Konzentration der Farbstoffe o,oo5 Gewichtsprozent.The following surfactant mixture was used to test the stabilizing effect used: 17% by weight sodium alkylbenzenesulfonate 8% by weight fatty alcohol C12-14 diglycol ether sulfate sodium 5% by weight fatty alcohol C1214 octaglycol ether 5% by weight ethanol 65% by weight water In In the following table, the concentration of the stabilizers was 1.0 percent by weight, the concentration of the dyes is 0.05 percent by weight.
Bei- Farbstoff Stabilisierungs- pH- -Lichtbeständigspiel mittel Wert keit in Stunden 1. Alizarinrubi- ohne 10 8 nol 3 G Fumarsäure 48 C.I. 68 205 Maleinsäure 72 Citronensäure 24 Mell iths äure 48 2. BlUtenrot ohne 10 16 R 1449 Fumarsäure 72 C.I. 27920 Maleinsäure 72 Citronensäure 48 Weinsäure 48 Sebazinsäure 72 Salizylsäure 72 Mell ithsäure 140 Bei- Farbstoff Stabilisierungs- pH- Lichtbeständigspiel mittel Wert keit in Stunden 3. Azllanbrillant- ohne 1o 36 blau Fumarsäure 72 C.I. 42 735 Maleinsäure 72 Benzoesäure 72 Terephthalsäure 72 Mellithsäure 11 72 Benzoesäure 12 72At- dye stabilization- pH- -lightfast medium value speed in hours 1. Alizarin rubi- without 10 8 nol 3 G fumaric acid 48 C.I. 68 205 maleic acid 72 Citric acid 24 Mellitic acid 48 2. Flower red without 10 16 R 1449 Fumaric acid 72 C.I. 27920 maleic acid 72 citric acid 48 tartaric acid 48 sebacic acid 72 salicylic acid 72 Mellitic acid 140 With- dye stabilization- pH- lightfast play average value in hours 3. Azllanbrillant- without 1o 36 blue fumaric acid 72 C.I. 42 735 maleic acid 72 benzoic acid 72 terephthalic acid 72 mellitic acid 11 72 benzoic acid 12 72
Claims (9)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19702034562 DE2034562A1 (en) | 1970-07-11 | 1970-07-11 | Coloured detergent solutions - contg carboxylic acids as dye stabilisers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19702034562 DE2034562A1 (en) | 1970-07-11 | 1970-07-11 | Coloured detergent solutions - contg carboxylic acids as dye stabilisers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2034562A1 true DE2034562A1 (en) | 1972-01-27 |
Family
ID=5776546
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19702034562 Pending DE2034562A1 (en) | 1970-07-11 | 1970-07-11 | Coloured detergent solutions - contg carboxylic acids as dye stabilisers |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE2034562A1 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4263276A (en) | 1978-05-19 | 1981-04-21 | Colgate-Palmolive Company | Dentifrices |
| US4526701A (en) * | 1981-08-31 | 1985-07-02 | Lever Brothers Company | Dye stabilized detergent compositions |
| US4822854A (en) * | 1987-09-23 | 1989-04-18 | The Drackett Company | Cleaning compositions containing a colorant stabilized against fading |
| US10550356B2 (en) * | 2011-09-06 | 2020-02-04 | Henkel IP & Holding GmbH | Solid and liquid textile-treating compositions |
-
1970
- 1970-07-11 DE DE19702034562 patent/DE2034562A1/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4263276A (en) | 1978-05-19 | 1981-04-21 | Colgate-Palmolive Company | Dentifrices |
| US4305928A (en) | 1978-05-19 | 1981-12-15 | Colgate-Palmolive Co. | Dentrifices |
| DK156295B (en) * | 1978-05-19 | 1989-07-31 | Colgate Palmolive Co | COLOR-STABLE FLUORABLE DENTAL CARE |
| US4526701A (en) * | 1981-08-31 | 1985-07-02 | Lever Brothers Company | Dye stabilized detergent compositions |
| US4822854A (en) * | 1987-09-23 | 1989-04-18 | The Drackett Company | Cleaning compositions containing a colorant stabilized against fading |
| US10550356B2 (en) * | 2011-09-06 | 2020-02-04 | Henkel IP & Holding GmbH | Solid and liquid textile-treating compositions |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2714978A1 (en) | COLORING PROCESS | |
| DE2524785B2 (en) | Liquid cleaning agent that does not affect the resistance of dyes | |
| DE3713052A1 (en) | AQUEOUS, LIQUID, REACTIVE DYE COMPOSITION | |
| DE739910C (en) | Production of Abkoemmlingen of the 1,4-diaminoanthraquinone | |
| DE2034562A1 (en) | Coloured detergent solutions - contg carboxylic acids as dye stabilisers | |
| DE1444726A1 (en) | Process for the production of basic dyes | |
| DE3009522A1 (en) | ANTIMICROBIAL PROPERTIES WITH AZO DYES | |
| DE2034563A1 (en) | Coloured detergent compsns - contg nitro-alkanols as dye stabilisers | |
| US2097269A (en) | Pigment and process of preparing same | |
| US2613129A (en) | Mixture of phthalocyanine vat dyes and process of making the same | |
| DE2047832A1 (en) | Process for dyeing nitrogen-containing fibers | |
| DE946975C (en) | Process for the production of real colors on cellulose esters | |
| DE2716765A1 (en) | DURABLE SOLUTION OF A QUARTAR STYRYLIC DYE | |
| DE1011396B (en) | Process for coloring polymers or copolymers made from acrylonitrile or asymmetric dicyanaethylene | |
| DE651249C (en) | Process for the production of Kuepen dyes | |
| DE3228069C2 (en) | ||
| DE1769328A1 (en) | Disazo dyes | |
| DE556477C (en) | Process for the preparation of azo dyes | |
| DE927526C (en) | Process for the production of Kuepen dyes | |
| DE610315C (en) | Process for the production of water-insoluble azo dyes on wool | |
| DE574964C (en) | Process for the preparation of water-insoluble azo dyes | |
| DE853155C (en) | Process for dyeing cellulose esters or these products with a similar color behavior | |
| O'Neill | A Dictionary of Dyeing and Calico Printing: Containing a Brief Account of All the Substances and Processes in Use in the Arts of Dyeing and Printing Textile Fabrics | |
| DE737323C (en) | Process for the production of azo dyes of the stilbene series | |
| CH250633A (en) | Dye preparation. |