DE20309463U1 - Special-effect cosmetic preparation in stick form is based on an oil liquid at room temperature, a wax and a colorant insoluble in the preparation and giving a fluorescent effect under UV. - Google Patents

Abstract

A preparation in the form of a stick especially for cosmetic treatment of the skin, lips, hair, eyelashes or eyebrows contains (A) an oil liquid at room temperature; (B) a wax; and (C) a colorant which is insoluble in the preparation and which gives a fluorescent effect under UV.

Description

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Heroldsberg, 17 June 2003 Reference: CS/PU/20.280/4290/nb

Schwan-STABILO Cosmetics GmbH & Co. KG

Schwanweg 1
D-90562 Heroldsberg

Preparation, especially cosmetic preparation Description

The invention relates to a preparation, in particular a cosmetic preparation according to claim 1, in particular in the form of a pen with an extruded or cast lead, which is suitable for cosmetic applications, in particular in the field of decorative cosmetics, for coloring and beautifying the skin, lips, eyelids, hair, eyelashes and eyebrows. Examples include make-up, in particular so-called party effect make-up, theater make-up, lipsticks, cheek rouge, eye shadow, eyeliner, lip liner, hair coloring pencils and the like, which produce special fluorescence effects under UV light - so-called "black light". These preparations can

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be produced as anhydrous lipid masses which contain at least one oil which is liquid at room temperature, at least one wax and at least one powdery phase, the powdery phase consisting of at least one fluorescent pigment which is insoluble in the preparation mentioned. Such preparations are usually produced by bringing the wax and oil to a temperature above the melting point of the wax, adding the powdery phase and mixing the whole thing well and then sufficiently processing it using a colloid mill, corundum disk mill or a three-roll mill to destroy agglomerates and to homogenize it. The preparation is then extruded and cut to length into leads which can be processed into pencils with a sharpenable casing using the processes known from pencil production. Alternatively, the leads can also be inserted into suitable rotary mechanisms. Other suitable methods for further processing consist of heating the preparation above its melting point and pouring it in liquid form directly into sleeves made of a sharpenable material such as wood or plastic. It is also known to pour the heated and liquid preparation into molds, remove the castings after they have cooled and then process them into wooden pencils in the manner described above. The castings obtained in this way can also be inserted into suitable rotary mechanisms. Finally, it is also known to pour the heated and liquid preparation into the holding part of a rotary mechanism and then complete this part with the remaining parts to form a rotary mechanism. Pouring can also take place directly into an appropriately designed rotary mechanism.

Pigmented preparations of the type mentioned, which contain conventional colorants in the form of the pigments mentioned below or their mixtures, are therefore well known to the person skilled in the art in many variations. To color these preparations, the person skilled in the art generally uses the colorants approved by the respective regional or national legislation, which have proven to be suitable in tests. Examples include pigments such as titanium dioxide, zinc oxide, iron oxides, chromium oxide, chromium oxide hydrate, ultramarine, manganese violet, ferric blue (Prussian blue), mica, micas coated with titanium dioxide, colored micas coated with metal oxides, bismuth oxychloride, bismuth oxychloride coated with metal oxides, platelet-shaped metal powders of aluminum, brass, bronze, copper, silver or gold, carmine and its various salts with metals, as well as varnishes.

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organic colorants with aluminum, barium, calcium, strontium or zirconium. This list is only an example and not exhaustive. The amounts used depend on the desired effects and are limited by the maximum amounts regulated in the respective national legislation. The proportions of colorants are usually in a range of 0.1 to 50 wt.%, preferably in a range of 5 to 35 wt.% and particularly preferably in a range of 10 to 25 wt.%. These quantities for the colorants are given on the condition that the sum of all ingredients of the aforementioned preparation, in particular cosmetic preparation, adds up to 100 wt.%.

The average particle size of the aforementioned colorants is generally in the range of 0.1 to 10 pm; for platelet-shaped colorants such as micas, bismuth oxychlorides and metal powders, the average particle size can also be in the range of 5 to 150 pm. In addition to the colorants, so-called "non-coloring pigments" and other fillers, such as silicon dioxide, talc, kaolin, metal salts of fatty acids such as Al, Mg, Ca, Zn or Sr stearate, palmitate or myristate, boron nitride, starch, organically modified starch, nylon powder, polytetrafluoroethylene powder or mixtures thereof, may also be present. In addition, these lipid-containing preparations contain volatile and/or non-volatile oils of vegetable, mineral or synthetic origin that are liquid at room temperature and approved for the manufacture of cosmetics and are commonly used in cosmetics - these include organosilicon compounds such as dimethicone, phenyltrimethicone, diphenyldimethicone or volatile oils such as volatile short-chain dimethicones such as hexamethyldisiloxane, cyclomethicones such as hexamethyltricyclosiloxane,

Octamethyltetracyclosiloxane, decamethylpentacyclosiloxane, dodecamethylhexacyclosiloxane, optionally also in admixture with volatile paraffins such as C-11/C-12 isoparaffins or mixtures of the oils mentioned and the like. Also mentioned are mineral oil and paraffin oil, as well as vegetable oils such as sesame oil, castor oil, sunflower oil, peanut oil, rapeseed oil, mango seed oil (Magnifera Indica), meadowfoam seed oil (Limnantes Alba), macadamia nut oil (Macadamia Ternifolia nut oil), octyldodecanol, isopropyl myristate, isopropyl palmitate, butyl stearate, isopropyl isostearate, isostearyl isostearate, caprylic/capric triglyceride, propylene glycol dicaprylate/dicaprate and others.

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Furthermore, vegetable, animal or synthetic waxes are mentioned, such as beeswax, Japanese wax (Rhus Succedanea), carnauba wax, candelilla wax, sugar cane wax, jojoba oil (Buxus Chinensis) or hydrogenated jojoba oil, silicone waxes, paraffin waxes, montan waxes, microcrystalline waxes or waxes obtained from the Fischer-Tropsch synthesis or even Vaseline or mixtures of the above-mentioned waxes can be used.

The preparation may also contain triglycerides, in particular triglycerides which are solid at room temperature and which have been obtained by hydrogenating vegetable oils, such as hydrogenated vegetable oils such as hydrogenated cottonseed oil, hydrogenated vegetable oil, hydrogenated rapeseed oil, hydrogenated castor oil, hydrogenated coco glycerides or mango seed oil (Magnifera lndica), meadowfoam seed oil (Limnantes Alba), shea butter (Butyrospermum Parkii), macadamia nut oil (Macadamia Ternifolia nut oil) or mixtures thereof. In addition to the usual commercial terms, the names familiar to the relevant experts in accordance with the "International Nomenclature of Cosmetic Ingredients" (the so-called "INCI names") are used to identify the raw materials mentioned. The required amount to be used is based on the suggestions that can be found in the above-mentioned specialist literature and is derived from the desired application. In order to avoid negative effects of prolonged storage, including during use by the end consumer - rancidity or microbial spoilage - the preparations can also contain conventional antioxidants and preservatives that are permitted by the relevant cosmetics legislation.

The above-mentioned preparations are available in a multitude of colors when mixtures of the above-mentioned colorants are used - starting from white and going through the entire spectrum of the rainbow to black. However, these decorative preparations are very disappointing when the wearer, e.g. when visiting a disco or a party, goes into rooms that are mainly or exclusively illuminated with long-wave UV light - so-called "black light". White clothing glows light blue here, and the titanium dioxide used in cosmetics also shimmers through a little. The color impression of decorative cosmetics in such rooms is usually very inconspicuous. If colorants from the group of laked fluoresceins, in particular halogenated fluoresceins - for example

Di-, tri- or tetrabromofluoresceins - this often results in bright fluorescent colors in the red tones. However, the use of lacquers made from these soluble dyes carries significant risks: healthy skin has a pH in the range of 5-6; 5.5 is said to be ideal here - the same pH range is found in sweat. Tears, on the other hand, have a slightly basic pH in the range of 7.4. Due to the moisture in the skin, it is now possible for the dyes to bleed out of dyes based on lacquered fluoresceins due to the possible different pH values in the product and on the skin, because they are dissolved out of the lacquer. This is particularly fatal because fluoresceins are very substantive and absorb onto the skin for a very long time - up to several days. The traces of this are also made even more visible in UV light. Color varnishes based on fluoresceins and halogenated fluoresceins therefore produce a very interesting effect make-up for use under "black light" - however, due to the potential risk of bleeding, these preparations can have very unpleasant side effects that are also difficult to remove from skin and hair. These potential side effects become a hindrance to sales after the first bad experience with such a product. Similar observations were also made with varnishes made from soluble quinoline and anthraquinone dyes. Titanium dioxide alone or optical brighteners such as disodium distyryldiphenyl disulfonate or similar essentially only produce light blue fluorescent colors and thus only a few possibilities for variation in the range of yellow to red fluorescent colors - an overall unsatisfactory situation.

The problem thus arose of producing preparations, in particular a cosmetic preparation, in particular in the form of a pen with an extruded or cast lead, which can be produced for cosmetic applications, in particular in the field of decorative cosmetics, by selecting from the aforementioned raw materials that are generally known to the relevant expert and coloring them with suitable colorants that are insoluble in the preparation so that they show intensive and interesting fluorescence on the skin, lips, eyelids, hair, eyelashes and eyebrows under UV light, so-called "black light", without soluble dyes being able to be dissolved out of the preparations under in-vivo conditions, e.g. through the moisture of the skin or through sweat or tears - this is to be understood as the so-called "bleeding".

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- that is, negative optical impressions which are intensified under "black light" are avoided. Under normal lighting conditions, particularly in daylight, the use of these suitable colorants, if necessary in addition to the colorants mentioned above, is intended to convey more intense color impressions by the fact that these colorants, which can be excited to fluorescence by UV light, are stimulated to emit fluorescent light by the UV component contained in daylight.

The stated object is achieved by using colorants which are insoluble in the above-mentioned preparation and which were obtained by salt formation, by forming a neutral salt - or by means of a true covalent bond - from a matrix made of a polymer material with at least one functional group in the side chain and a soluble dye with at least one functional group. To achieve the object, either colorants can be used which are produced, for example, by reacting polyesters which are also insoluble in the preparation and which contain at least one primary, secondary or tertiary amino group in the side chain with anionic dyes or polyesters which contain at least one acid residue in the side chain with cationic dyes. It is also conceivable to react polyacrylates or polymethacrylates or polyurethanes which have at least one of the above-mentioned amino groups or at least one acid group in the side chain with dyes with oppositely charged functional groups. It is essential for use that the dyes to be selected are stable to hydrolysis under in vivo conditions, which can be easily determined by a simple test - namely by storing the dye in a 1% aqueous solution of an organic hydroxy acid, such as lactic acid or citric acid, buffered to pH 5.5 for 24 hours at 37 ^° C.

For example, dyes consisting of a polyester matrix obtained by the reaction of ethylene glycol, cyclohexanedimethanol, terephthalic acid, isophthalic acid and norbornanediamine and dyes derived from fluoresceins, quinoline dyes, triphenylmethane dyes and

Anthraquinone dyes. A suitable polyester matrix is also known to the person skilled in the art as "polyester-3".

Dyes such as C.I. No. 45.380 (tetrabromofluorescein), C.I. No. 45.370:1 (mixture of dibromo-, tribromo- and tetrabromofluorescein), C.I. No. 47.000 (quinophthalone, not for use on mucous membranes), C.I. No. 47.005 (quinophthalone-disulfonic acid), C.I. No. 42.090 (triphenylmethane dye), C.I. No. 60.730 (anthraquinone dye, not for use on mucous membranes), C.I. No. 61.570 (anthraquinone dye) should be mentioned here.

The preparation according to the invention will now be explained in detail using the following examples, which, however, do not describe it conclusively. All quantities are given in percent by weight (wt. %), based on the total weight of the preparation. The raw material names used are the internationally common "INCI names" or non-proprietary names generally known to the relevant expert. The preparations found, in particular cosmetic preparations, are in the form of a pencil with an extruded or cast lead, which was obtained by extruding the preparation and inserting a cut section of the strand into wooden boards and then further processing according to the methods known from the pencil industry or by inserting it into a suitable rotary mechanism or by pouring the preparation liquefied by heating into sleeves made of a sharpenable material or pouring it into corresponding molded parts of a rotary mechanism or pouring it into molds and further processing the castings obtained after cooling according to the methods known from the pencil industry.

Example 1 - Effect lipstick, matte, extruded

Tristeann 34,000 Carnauba 3,350 Beeswax 5,000 Caprylic/Capric Triglyceride 7,500 Behenyl Alcohol 8,000 Nylon Powder 4,500 Polyester-3, Red 28 20,000 Polyester-3, Yellow 10 8,500

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-8-Example 1 - Effect lipstick, matt, extruded (continue)

Iron Oxides, Yellow C.I.-No. 77,492 3,500 Isopropyl Myristate 3,000 Stearalkonium Hectorite 2,000 Methylparaben 0.150 Propylparaben 0.050 Tocopherol Acetate 0.200 Fragrance 0.250

The waxes and oils are heated to 80 ^° C in a suitable vacuum vessel, then the stearalkonium hectorite is added and the mixture is thoroughly mixed with a gear wheel. The pigments and nylon powder are then added and the mixture is intensively homogenized. The preservatives, antioxidants and fragrance mixture are then added, briefly homogenized again and the mixture is deaerated. The mixture is placed on a three-roll mill and passed through twice. The mixture is then pressed and extruded into a strand with a diameter of around 8-10 mm and cut to length. The resulting leads are glued into wooden boards in the usual way and made into pencils that can be sharpened. The result is an intense red lipstick with bright red fluorescence in long-wave UV light.

Example 2 - Effect eyeliner, extruded

Stearic Acid 18,000

Castor Oil 9,500

Hydrogenated Castor Oil 5,500

Hydrogenated Vegetable Oil 8,000

Caprylic/Capric Triglycerides 6,000

Cetyl Palmitate 4,500

Rhus succedanea 6,000

Behenyl alcohol 2,500

Microcrystalline Wax (mp 74 ⁰ C) 2,500

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-9-Example 2 - Effect eyeliner, extruded (continue)

TaIc 4,500 Polyester-3, Blue 1 25,000 Black Iron Oxide 2,350 Disodium Distyryldiphenyl Disulfonate 0.350 Ultramarin 5,000 Methylparaben 0.150 Propylparaben 0.050 Tocopherol Acetate 0.100

The processing is analogous to example 1, but the preparation is extruded into leads with a diameter of about 4 mm, which are then processed in the known manner into wood-cased pencils. A lead with a blue color is obtained, which produces a smear that fluoresces light blue under long-wave UV light.

Example 3 - Effect lip liner, cast

Isopropyl Myristate 19,000 Castor Oil 7,500 Hydrogenated Castor Oil 5,500 Hydrogenated Vegetable Oil 8,000 Carnauba 3,500 Microcrystalline Wax (mp. 74 ⁰ C) 9,000 Acetylated Lanolin 2,500 Isopropyl Lanolin 3,700 Nylon Powder 3,500 Polyester-3, Red 28 22,000 Polyester-3, Yellow 10 12,000

- 10-Example 3 - Effect lip liner, cast (continue)

Red Iron Oxide 3,500

Methylparaben 0.150

Propylparaben 0.050

Tocopherol Acetate 0.100

The lipid components are heated to 80 ^° C and melted in a suitable vacuum vessel with agitator and gear mixer, then the powder components are added and the mixture is homogenized. Finally, the preservatives and antioxidant are added. The preparation can now be poured directly into tubes made of a sharpenable material and processed into effect lip liners with a lead of around 4 mm diameter. Alternatively, the preparation can also be poured directly into the holder of a suitable rotating mechanism, as described above. This produces a pen with an intensely red lead, the smear of which shows a bright red fluorescence in long-wave UV light.

Example 4 - Effect eyeshadow stick, cast

Polybutene 3,000

Mineral Oil 2,500

Microcrystalline Wax, m.p. 74 ⁰ C 4,500

Camauba 3,000

Beeswax 3,500

Hydrogenated Cottonsed Oil 4,000

Titanated Mica 25,000

Chromium Hydroxide Green 4,500

Polyester-3, Blue 1 10,000

Polyester-3, Yellow 10 4,500

Disodium Distyryldiphenyl Disulfonate 0.200

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Example 4 - Effect eyeshadow pencil, cast (continue)

Tocopherol Acetate 0.100 Methylparaben 0.150 Propylparaben 0.050 Cyclomethicone 25,000 C-11/C-12 isoparaffins 10,000

The lipid components, with the exception of the volatile oils, are heated to 80 ^° C in a suitable stirred tank with a stirrer and gear mixer and melted. The powder components are then added and the mixture is homogenized. The preservatives and antioxidant are then added. The mixture is then deaerated by applying a vacuum. The volatile oils are then added and the mixture is thoroughly mixed again. The preparation is then poured into tubes made of a sharpenable material with an inner diameter of around 8-10 mm using a suitable system and then processed into eye shadow sticks. Alternatively, the preparation can of course also be poured into flat pans that must be placed in airtight cassettes. This gives a blue-green effect eye shadow that shows a bright, blue-green fluorescence under long-wave UV light.

Example 5 - Effect body painting, cast (pen for body painting)

Castor Oil 5,000 Hydrogenated Castor Oil 6,000 Beeswax 4,200 Carnauba 4,000 Microcrystalline wax, m.p. 85 ⁰ C 8,500 Acetylated Lanolin 4,500

- 12-Example 5 - Effect body painting, cast (continue)

Isopropyl Lanolin 3,000 Rhus succedanea 2,500 Hydrogenated Rapeseed Oil 7,500 Titanated Mica 21,500 Yellow iron oxide 4,200 Red Iron Oxide 2,800 Polyester-3, Red 22 13,500 Polyester-3, Yellow 10 12,500 Tocopherol Acetate 0.100 Methylparaben 0.150 Propylparaben 0.050

The preparation is carried out in a known manner by melting the lipid components at around 80 ^° C in a suitable vacuum stirred tank with a stirrer and gear mixer and then adding the powder components with the exception of the coated mica and homogenizing them. The preservatives, the antioxidant and the coated mica are then added, the mixture is thoroughly mixed using the stirrer alone and deaerated by applying a vacuum. However, the preparation is not poured into sleeves made of a sharpenable material, which is also possible in principle, but into rotary mechanisms with a rotating spindle, as is generally known from deodorant sticks. The result is a bright orange lead that fluoresces intensely red-orange in long-wave UV light.

Example 6 - Effect hair dye stick, cast

Thsteahn 18,000

Hydroxystearic Acid 5,800

Carnauba 3,350

Beeswax 3,500

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-13-Example 6 - Effect hair dye pen, cast (continue)

Caprylic/Capric Triglyceride 7,500 Hydrogenated Castor Oil 6,000 Castor Oil 5,500 Dipropylene Glycol 1,500 Behenyl Alcohol 6,000 Microcrystalline Wax mp. 84 ⁰ C 3,500 Ceteareth-20 2,500 Nylon Powder 4,500 Titanium dioxide 8,500 Ultramarin 3,500 Polyester-3, Blue 1 19,500 Disodium Distyryldiphenyl Disulfonate 0.200 Methylparaben 0.150 Propylparaben 0.050 Tocopherol Acetate 0.200 Menthyl Lactate 0.250

The preparation is carried out in the manner described above, essentially analogous to Example 3. However, the preparation is not poured into sleeves made of a sharpenable material, which is also possible in principle, but rather into rotary mechanisms with a rotating spindle, as is generally known from deodorant sticks. A medium blue lead is obtained which fluoresces intensively in light blue in long-wave UV light.

By varying the colorants in the recipes shown above, which are only examples, it is of course possible to achieve other lead colors simply by trying them out.

Claims (28)

1. Preparation, in particular cosmetic preparation in the form of a stick for the field of decorative cosmetics for coloring and beautifying the skin, lips, hair, eyelashes and eyebrows, characterized in that it contains at least one oil which is liquid at room temperature, at least one wax and at least one colorant which is insoluble in the preparation and produces fluorescence effects under UV light. 2. Preparation according to claim 1, characterized in that this pencil is a make-up, a party effect make-up, a theatrical make-up, a lipstick, a cheek blusher, an eye shadow, a lip liner, an eyeliner or a hair coloring pencil. 3. Preparation according to one of the preceding claims, characterized in that it contains at least one oil which is liquid at room temperature, at least one wax and at least one colorant which is insoluble in the preparation and produces fluorescence effects under UV light and optionally also contains a triglyceride. 4. Preparation according to one of claims 1 to 3, characterized in that it is in anhydrous form. 5. Preparation according to one of the preceding claims, characterized in that it is in the form of a pen with a sharpenable casing, the lead of which can be produced by extrusion. 6. Preparation according to one of the preceding claims, characterized in that it is in the form of a pencil with a sharpenable casing, the lead of which can be produced by a casting process. 7. Preparation according to one of the preceding claims, characterized in that it is in the form of a pen with a sharpenable casing, the lead of which can be produced by direct pouring into a sleeve made of a sharpenable material. 8. Preparation according to one of the preceding claims, characterized in that the sleeve consists of a sharpenable material made of wood or plastic. 9. Preparation according to one of the preceding claims, characterized in that the colorant was obtained from a matrix of a polymer material having at least one functional group in the side chain and a soluble dye having at least one functional group by way of salt formation by formation of a neutral salt. 10. Preparation according to one of the preceding claims, characterized in that the colorant is obtained from a matrix of a polymer material having at least one functional group in the side chain and a soluble dye having at least one functional group by means of a true covalent bond. 11. Preparation according to claim 9 or 10, characterized in that the matrix is made of a polymer material selected from polyesters, polyacrylates, polymethacrylates or polyurethanes with at least one primary, secondary or tertiary amino group in the side chain or mixtures thereof and has been reacted with at least one anionic dye. 12. Preparation according to claim 9 or 10, characterized in that the matrix is made of a polymer material selected from polyesters, polyacrylates, polymethacrylates or polyurethanes with at least one acid residue in the side chain or mixtures thereof and has been reacted with at least one cationic dye. 13. Preparation according to claim 9, 10 or 11, characterized in that the matrix of polymer material was obtained by the reaction of ethylene glycol, cyclohexanedimethanol, terephthalic acid, isophthalic acid and norbornanediamine and reacted with at least one anionic dye. 14. Preparation according to claim 13, characterized in that the anionic dye is C.I. No. 42.090, C.I. No. 45.370:1, C.I. No. 45.380, C.I. No. 47.000, C.I. No. 47.005, C.I. No. 60.730, C.I. No. 61.570 or mixtures thereof. 15. Preparation according to one of claims 9 to 14, characterized in that the colorant is stable to hydrolysis and does not bleed when stored for 24 hours at 37°C in a 1% aqueous solution of an organic hydroxy acid, such as lactic acid or citric acid. 16. Preparation according to one of the preceding claims, characterized in that it optionally additionally contains at least one pigment such as titanium dioxide, zinc oxide, iron oxides, chromium oxide, chromium oxide hydrate, ultramarine, manganese violet, ferric blue (Prussian blue), mica, micas coated with titanium dioxide, colored micas coated with metal oxides, bismuth oxychloride, bismuth oxychloride coated with metal oxides, platelet-shaped metal powders of aluminum, brass, bronze, copper, silver or gold, carmine and its various salts with metals, laking of organic colorants with aluminum, barium, calcium strontium or zirconium or mixtures of the said pigments. 17. Preparation according to one of the preceding claims, characterized in that the proportions of the colorants are in a range from 0.1 to 50 wt. %, preferably in a range from 5 to 35 wt. %, very particularly preferably in a range from 10 to 25 wt. %, with the proviso that the sum of all ingredients of the preparation is 100 wt. %. 18. Preparation according to one of the preceding claims, characterized in that the oil contained in the preparation which is liquid at room temperature is a volatile oil. 19. Preparation according to claim 18, characterized in that the volatile oil is selected from short-chain dimethicones, cyclomethicones or isoparaffins or mixtures thereof. 20. Preparation according to claims 18 or 19, characterized in that the volatile oil is a hexamethyldisiloxane, hexamethyltricyclosiloxane, octamethyltetracyclosiloxane, decamethylpentacyclosiloxane or dodecamethylhexacyclosiloxane or a C-11/C-12 isoparaffin or mixtures thereof. 21. Preparation according to one of the preceding claims, characterized in that the oil contained in the preparation which is liquid at room temperature is a non-volatile oil. 22. Preparation according to one of the preceding claims, characterized in that the oil which is not volatile at room temperature is a vegetable, a mineral or a synthetic oil. 23. Preparation according to one of the preceding claims, characterized in that the oil which is not volatile at room temperature is selected from sesame oil, castor oil, sunflower oil, peanut oil, rapeseed oil, mango seed oil (Magnifera Indica), meadowfoam seed oil (Limnantes Alba), macadamia nut oil (Macadamia Ternifolia nut oil), octyldodecanol, isopropyl myristate, isopropyl palmitate, butyl stearate, isopropyl isostearate, isostearyl isostearate, mineral oil, paraffin oil, caprylic/capric triglyceride, propylene glycol dicaprylate/dicaprate, dimethicone, phenyltrimethicone, diphenyldimethicone or mixtures thereof. 24. Preparation according to one of the preceding claims, characterized in that the triglyceride contained in the preparation is a triglyceride which is solid at room temperature and which was obtained by hydrogenation of vegetable oils. 25. Preparation according to one of the preceding claims, characterized in that the triglyceride which is solid at room temperature is selected from hydrogenated cottonssed oil, hydrogenated vegetable oil, hydrogenated rapeseed oil, hydrogenated castor oil, hydrogenated coco glycerides or mixtures thereof. 26. Preparation according to one of the preceding claims, characterized in that the wax contained in the preparation is a vegetable, animal, mineral or synthetic wax. 27. Preparation according to one of the preceding claims, characterized in that the wax contained in the preparation is preferably selected from beeswax, Japan wax, carnauba wax, candelilla wax, sugar cane wax, jojoba oil, hydrogenated jojoba oil, silicone wax, paraffin wax, montan wax, microcrystalline wax, waxes from the Fischer-Tropsch synthesis or mixtures thereof. 28. Preparation according to one of the preceding claims, characterized in that it optionally also contains fillers such as silicon dioxide, talc, kaolin, metal salts of fatty acids such as Al, Mg, Ca, Zn or Sr stearate, palmitate or myristate, boron nitride, starch, organically modified starch, nylon powder, polytetrafluoroethylene powder or mixtures thereof.