DE202008016408U1 - New dye precursor combinations - Google Patents

Abstract

oder eines seiner physiologisch verträglichen Salze in Kombination mit mindestens einer weiteren Entwicklerkomponente und/oder mindestens einer Kupplerkomponente und/oder mindestens einem direktziehenden Farbstoff enthält.Agent for coloring keratinic fibers, in particular human hair, characterized in that it contains in a cosmetically acceptable carrier as developer component N- (4-amino-3-methylphenyl) -N- [3- (1H-imidzol-1-yl) propyl] amine

or one of its physiologically acceptable salts in combination with at least one further developer component and / or at least one coupler component and / or at least one substantive dye.

Description

The The present invention relates to agents for coloring keratinous Fibers containing as the developer component N- (4-amino-3-methylphenyl) -N- [3- (1H-imidzol-1-yl) propyl] amine or one of its physiologically acceptable salts in Combination with at least one further developer component and / or at least one coupler component and / or at least one substantive Dye containing, the use of these combinations to achieve of colorations with good gray coverage and a corresponding Dyeing process.

For the dyeing of keratin fibers, in particular human Hair, play the so-called oxidation dyes because their intense colors and good fastness properties a preferred Role. Such colorants contain oxidation dye precursors, so-called developer components and coupler components. The developer components form under the influence of oxidizing agents or atmospheric oxygen with each other or under coupling with one or more coupler components the actual dyes.

When Developer components usually become primary aromatic amines with another, in para or ortho position free or substituted hydroxy or amino group, Diaminopyridine derivatives, heterocyclic hydrazones, 4-aminopyrazolone derivatives and 2,4,5,6-tetraaminopyrimidine and its derivatives used.

Alone with a developer component or a special coupler / developer combination Usually it does not succeed, one on the hair of course to get an effective color nuance. In practice, therefore, are usually Combinations of different developer and / or coupler components used. There is therefore a constant need for new, improved Combinations of dye components, also in toxicological dermatologically unproblematic.

at the use of oxidation dye precursors in the course of the oxidative Hair dyeing process must have the resulting nuances have sufficiently good fastness properties to them satisfying the requirements in a satisfactory way. This also includes good washing and light fastness as well a good rubbing fastness. As rubbing fastness becomes the resistance the coloring produced on the hair compared to one Abrasion on textiles (such as clothing, towels or bed linen). For nuances with bad Rubbing fastness is often colored residue on the worn clothes or bed linen used, which is not desired by the consumer in any case. One Another essential aspect in the development of new dye (precursor) combinations is Achieving a good gray coverage. Under a good gray cover the expert understands the most homogeneous possible staining result on graying and not graying hair parts.

BB

= Farbergebnis auf unpigmentiertem Haar, beispielsweise Büffelbauchhaar

NH

= Farbergebnis auf pigmentiertem Haar

NS

= Unbehandeltes weißes Haar, beispielsweise Büffelbauchhaar

Good gray coverage is usually used when the gray coverage index (GA I) has a value greater than or equal to 80, preferably greater than or equal to 90. The gray coverage index is defined as follows:

BB

= Color result on unpigmented hair, for example buffalo belly hair

NH

= Color result on pigmented hair

NS

= Untreated white hair, for example buffalo belly hair

Surprisingly It has now been found that colorants are the N- (4-amino-3-methylphenyl) -N- [3- (1H-imidzol-1-yl) propyl] amine as a developer component, these requirements in one especially high mass.

oder eines seiner physiologisch verträglichen Salze in Kombination mit mindestens einer weiteren Entwicklerkomponente und/oder mindestens einer Kupplerkomponente und/oder mindestens einem direktziehenden Farbstoff enthält.A first subject of the present invention are therefore agents for coloring keratinic fibers, in particular human hair, which are present in a cosmetically acceptable carrier as the developer component N- (4-amino-3-methylphenyl) -N- [3- (1H-imidzol-1] yl) propyl] amine

or one of its physiologically acceptable salts in combination with at least one further developer component and / or at least one coupler component and / or at least one substantive dye.

Under "keratinic Fibers are according to the invention furs, wool, To understand feathers and especially human hair. Although the oxidation colorants according to the invention primarily suitable for dyeing keratin fibers, is in principle a use in other fields, in particular in color photography, nothing contrary.

Under "Dye (precursor) e" are inventively arbitrary combinations from one or more dye precursors with optionally one or more substantive dyes understood.

There it is partly the dyes of the invention and dye precursors are amino compounds from these in the usual way, the known acid addition salts produce. All statements of this document and accordingly the The claimed scope of protection therefore applies both to the in free form compounds as well as their physiological compatible salts of organic or inorganic acids. Examples of such salts are the hydrochlorides, which Hydrobromides, sulfates, phosphates, acetates, propionates, the citrates and the lactates. The hydrochlorides and the sulfates are particularly preferred. Completely according to the invention particularly preferred are the monohydrochlorides, the dihydrochlorides, the trihydrochlorides and the sulfates.

One most preferred salt of N- (4-amino-3-methylphenyl) -N- [3- (1H-imidzol-1-yl) propyl] amine is N- (4-amino-3-methylphenyl) -N- [3- (1H-imidzol-1-yl) propyl] amine trihydrochloride.

there It has proved to be particularly advantageous if the at least another developer component is selected from 4-amino-3-methylphenol, 2,4,5,6-tetraaminopyrimidine, 2- (2-hydroxyethyl) -p-phenylenediamine, Bis (5-amino-2-hydroxyphenyl) methane and 1- (2-hydroxyethyl) -4,5-diaminopyrazole, as well as their physiologically acceptable salts.

A Another particularly preferred developer component is 2-methoxymethyl-p-phenylenediamine or one of its physiological compatible salts.

Further It has proved to be particularly advantageous if the at least another coupler component is selected from resorcinol, 4-chlororesorcinol, m-aminophenol, 1-methoxy-2-amino-4- (2-hydroxyethylamino) benzene, 3-amino-2-chloro-6-methylphenol, 2,6-dihydroxy-3,4-dimethylpyridine, 2-methyl-4-chloro-5-aminophenol, 6-methoxy-2-methylamino-3-aminopyridine, 2-amino-3-hydroxypyridine and 2,6-di (2-hydroxyethylamino) toluene and their physiologically acceptable salts.

Farther It has proved to be particularly advantageous if the at least Another direct dye is selected Basic Brown 17, N, N'-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine, 1-methyl-3-nitro-4- (2-hydroxyethylamino) benzene, 4- (3-Hydroxypropylamino) -3-nitrophenol, Acid Red 33 and Acid Red 52 and their physiologically acceptable salts.

in the Within a very particularly preferred embodiment of the present invention contain the colorants as well also the application preparations in addition to the particularly advantageous developer components, coupler components and substantive Dyes no further dye precursors and / or dyes.

The Contain hair dye according to the invention both the developer components and the coupler components preferably in an amount of 0.005 to 20 wt .-%, preferably 0.1 to 5 wt .-%, each based on the total oxidation colorant. This developer components and coupler components in general used in about molar amounts to each other. If also the molar use has proved to be useful, so is a certain excess of individual oxidation dye precursors not disadvantageous, so that developer components and coupler components in a molar ratio of 1: 0.5 to 1: 3, in particular 1: 1 to 1: 2, may be included.

The substantive dyes are each preferably in an amount from 0.001 to 20% by weight, based on the total application preparation, used. The total amount of substantive dyes is preferably at most 20% by weight.

In a particularly preferred embodiment has it proved to be advantageous when the inventive Medium in its ready to use form, a pH of at least Have 9.5.

Accordingly contain the inventive compositions at least an alkalizing agent.

The Alkalizing agent is subject in principle no restrictions. The alkalizing agents which can be used according to the invention are preferably selected from the group formed is made of ammonia, basic amino acids, alkali hydroxides, Alkanolamines, alkali metal metasilicates, urea, morpholine, N-methylglucamine, imidazole, alkali phosphates and alkali hydrogen phosphates. The alkali metal ions used are preferably lithium, sodium, potassium, especially sodium or potassium.

The usable as alkalizing agent according to the invention basic amino acids are preferably selected from the group formed from L-arginine, D-arginine, D, L-arginine, L-histidine, D-histidine, D, L-histidine, L-lysine, D-lysine, D, L-lysine, particularly preferably L-arginine, D-arginine, D, L-arginine as an alkalizing agent used in the context of the invention.

The usable as alkalizing agent according to the invention Alkali hydroxides are preferably selected from the group which is formed from sodium hydroxide and potassium hydroxide.

The alkanolamines which can be used as alkalizing agents according to the invention are preferably selected from primary amines having a C ₂ -C ₆ -alkyl basic body which carries at least one hydroxyl group. Particularly preferred alkanolamines are selected from the group formed from 2-aminoethan-1-ol (monoethanolamine), 3-aminopropan-1-ol, 4-aminobutan-1-ol, 5-aminopentan-1-ol, 1 -Aminopropan-2-ol, 1-aminobutan-2-ol, 1-aminopentan-2-ol, 1-aminopentan-3-ol, 1-aminopentan-4-ol, 3-amino-2-methylpropan-1-ol , 1-amino-2-methylpropan-2-ol, 3-aminopropane-1,2-diol, 2-amino-2-methylpropane-1,3-diol. Very particularly preferred alkanolamines according to the invention are selected from the group consisting of 2-aminoethane-1-ol, 2-amino-2-methylpropan-1-ol and 2-amino-2-methylpropane-1,3-diol.

Especially Preferably, the alkalizing agent is selected from at least one compound from the group that is formed from Ammonia, 2-aminoethanol, 2-amino-2-methylpropan-1-ol, 2-amino-2-methyl-propane-1,3-diol, Potassium hydroxide, L-arginine, D-arginine, DL-arginine, N-methylglucamine, Morpholine, imidazole and urea.

All particularly preferred alkalizing agent in the sense of the present invention Invention are selected from the ammonia, alkali hydroxides, Monoethanolamine, arginine and 2-amino-2-methylpropan-1-ol. Ammonia, Sodium hydroxide, potassium hydroxide and monoethanolamine are particularly prefers.

The Application preparation is by means of the alkalizing agent combination preferably adjusted to a pH of at least 9.5; it is particularly preferred according to the invention if the pH of the application preparation has a pH of 9.5 to 10.5 preferably from 9.7 to 10.2.

In a particularly preferred embodiment of the present invention Invention contain the agents according to the invention as alkalizing agent ammonia in combination with another Alkalizing. With regard to the preferred further alkalizing agents reference is made to the above statements.

Further it has proved to be advantageous if the inventive Means at least one nonionic emulsifier selected of ethoxylated, linear fatty alcohols, preferably a chain length with 8 to 22 carbon atoms and a degree of ethoxylation of At least 40% of an ethoxylated fatty alcohol is used in the sense the invention an addition product of ethylene oxide to a fatty alcohol understood, wherein the degree of ethoxylation, the molar amount of ethylene oxide (EO), the average deposited per mole of fatty alcohol has been.

In a preferred embodiment was further surprising found that the combination of at least one ethoxylated Fatty alcohol with a mean, average degree of ethoxylation and at least one ethoxylated fatty alcohol having a high, average degree of ethoxylation to a high concentration Oxidation dye precursors in the inventive Allowed funds and excellent storage stability the means guaranteed.

Preferred ethoxylated fatty alcohols are ethylene oxide addition products of capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, oleyl alcohol, Elai dyl alcohol, petroselinyl alcohol, linolyl alcohol, linolenyl alcohol, elaeostearyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol, as well as their technical mixtures. B. incurred in the high-pressure hydrogenation of technical methyl esters based on fats and oils or aldehydes from the Roelen oxo synthesis and as a monomer fraction in the dimerization of unsaturated fatty alcohols.

Especially preference is given to addition products of technical fatty alcohols or their mixtures having 12 to 18 carbon atoms such as Coconut, palm, palm kernel or tallow fatty alcohol, in particular coconut and / or tallow fatty alcohol.

Under Ethoxylated fatty alcohol with a mean, average Degree of ethoxylation is an addition product in the context of the invention from 15 to 35 moles of ethylene oxide per mole of fatty alcohol understood.

One ethoxylated fatty alcohol with a high average degree of ethoxylation is within the meaning of the invention an adduct of 40 to 100 Mole ethylene oxide per mole of fatty alcohol understood. Preferred fatty alcohols having a high, average degree of ethoxylation a degree of ethoxylation of 40 to 60, and most preferably from 45 to 55.

ever according to production method fall the inventive ethoxylated fatty alcohols as a mixture with a different Ethoxylierungsgradverteilung on. For the purposes of the invention, these emulsifiers therefore characterized by the average degree of ethoxylation. This is usually the digit after the fatty alcohol suffix "eth-" recognizable in the INCI name.

Preferred ethoxylated fatty alcohols having a mean, average degree of ethoxylation are, for example, the commercial products:
Ceteth-15 (Nikkol ^® BC 15 TX, Nikko Chemicals Co., Ltd.), Laneth-15 (Polychol ^® 15, Croda), ceteareth-15 (Eumulgin ^® CS 15, Cognis);
Laneth-16 (and) Ceteth-16 (and) Oleth-16 (and) Steareth-16 (sold as a mixture under the trade name Solulan ^® 16, Noveon);
Oleth-20 (Ritoleth ^® 20, company Rita Corp.), ceteth-20 (Brij ^® 58 SP company Uniqema; Lipocol ^® C 20, company Lipo Chemicals Inc.), ceteareth-20 (Surfac JH ^® 200, from Surfachem; Eumulgin ^® B2, Cognis), Laneth-20 (Polychol ^® 20, Croda);
Steareth-21 (Brij ^® 721 P, company Uniqema; Eumulgin ^® S 21, from Cognis);
Ceteareth-23 (Mergital ^® C 23, Cognis), laureth-23 ^(® Canasol BJ 35, Canamax Company);
Ceteareth-25 (Cremophor ^® A 25, BASF);
Ceteareth-27 (Plurafac ^® A-38, BASF);
Ceteareth-30 ^(® Lipocol SC 30, Lipo Chemicals Company; Eumulgin ^® B3, Cognis).

Preferred ethoxylated fatty alcohols with a high, average degree of ethoxylation are, for example, the commercial products:
Ceteth-40 (Nikkol ^® BC 40 TX, Nikko Chemicals Co., Ltd.), Laneth-40 (Polychol ^® 40, Croda);
OETH-50 (Nikkol ^® BO 50 V, Nikko Chemicals Co., Ltd.), ceteareth-50 (Genapol ^® T 500, company Clariant; Mergital ^® CS 50, Cognis);
Ceteareth-60 ^(® 1618 Finds A 72, company KAO Corp.);
Ceteareth-80 (Lutensol ^® AT 80 from BASF).

Especially preferred is ceteareth-50.

Of the or the ethoxylated fatty alcohols are ready for use in total between 0.05 and 15% by weight, preferably 0.1 and 10% by weight contain.

Particularly according to the invention preferred agents are characterized in that the weight ratio the amount of ethoxylated fatty alcohols with a mean, average Degree of ethoxylation to the amount of ethoxylated fatty alcohols with a high, average degree of ethoxylation in the colorant (a) has a value of from 3: 1 to 1: 5, preferably from 2: 1 to 1: 3.

The colorants of the invention may further contain all known for such preparations active ingredients, additives and excipients. In many cases, the colorants contain at least one surfactant, wherein in principle both anionic and zwitterionic, ampholytic, nonionic and cationic surfactants are suitable. In many cases, it has proved to be advantageous, the surfactants from anionic, zwitterioni or nonionic surfactants.

• – lineare Fettsäuren mit 10 bis 22 C-Atomen (Seifen),
• – Ethercarbonsäuren der Formel R-O-(CH₂-CH₂O)_x-CH₂-COOH, in der R eine lineare Alkylgruppe mit 10 bis 22 C-Atomen und x = 0 oder 1 bis 16 ist,
• – Acylsarcoside mit 10 bis 18 C-Atomen in der Acylgruppe,
• – Acyltauride mit 10 bis 18 C-Atomen in der Acylgruppe,
• – Acylisethionate mit 10 bis 18 C-Atomen in der Acylgruppe,
• – Sulfobernsteinsäuremono- und -dialkylester mit 8 bis 18 C-Atomen in der Alkylgruppe und Sulfobernsteinsäuremono-alkylpolyoxyethylester mit 8 bis 18 C-Atomen in der Alkylgruppe und 1 bis 6 Oxyethylgruppen,
• – lineare Alkansulfonate mit 12 bis 18 C-Atomen,
• – lineare Alpha-Olefinsulfonate mit 12 bis 18 C-Atomen,
• – Alpha-Sulfofettsäuremethylester von Fettsäuren mit 12 bis 18 C-Atomen,
• – Alkylsulfate und Alkylpolyglykolethersulfate der Formel R-O(CH₂-CH₂O)_xSO₃H, in der R eine bevorzugt lineare Alkylgruppe mit 10 bis 18 C-Atomen und x = 0 oder 1 bis 12 ist,
• – Gemische oberflächenaktiver Hydroxysulfonate gemäß DE-A-37 25 030 ,
• – sulfatierte Hydroxyalkylpolyethylen- und/oder Hydroxyalkylenpropylenglykolether gemäß DE-A-37 23 354 ,
• – Sulfonate ungesättigter Fettsäuren mit 12 bis 24 C-Atomen und 1 bis 6 Doppelbindungen gemäß DE-A-39 26 344 ,
• – Ester der Weinsäure und Zitronensäure mit Alkoholen, die Anlagerungsprodukte von etwa 2-15 Molekülen Ethylenoxid und/oder Propylenoxid an Fettalkohole mit 8 bis 22 C-Atomen darstellen.

Suitable anionic surfactants in preparations according to the invention are all anionic surfactants suitable for use on the human body. These are characterized by a water-solubilizing, anionic group such. Example, a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group having about 10 to 22 carbon atoms. In addition, glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups may be present in the molecule. Examples of suitable anionic surfactants are, in each case in the form of the sodium, potassium and ammonium as well as the mono-, di- and trialkanolammonium salts having 2 or 3 C atoms in the alkanol group,

• - linear fatty acids with 10 to 22 carbon atoms (soaps),
• Ether carboxylic acids of the formula RO- (CH ₂ -CH ₂ O) _x -CH ₂ -COOH, in which R is a linear alkyl group having 10 to 22 C atoms and x = 0 or 1 to 16,
• Acylsarcosides having 10 to 18 C atoms in the acyl group,
• Acyltaurides having 10 to 18 C atoms in the acyl group,
• Acyl isethionates having 10 to 18 C atoms in the acyl group,
• Sulfosuccinic acid mono- and dialkyl esters having 8 to 18 C atoms in the alkyl group and sulfosuccinic acid monoalkyl polyoxyethyl esters having 8 to 18 C atoms in the alkyl group and 1 to 6 oxyethyl groups,
• Linear alkanesulfonates having 12 to 18 C atoms,
• - linear alpha-olefin sulfonates having 12 to 18 C atoms,
• Alpha-sulfofatty acid methyl esters of fatty acids containing 12 to 18 carbon atoms,
• Alkyl sulfates and alkyl polyglycol ether sulfates of the formula RO (CH ₂ -CH ₂ O) _x SO ₃ H, in which R is a preferably linear alkyl group having 10 to 18 C atoms and x = 0 or 1 to 12,
• Mixtures of surface active hydroxysulfonates according to DE-A-37 25 030 .
• - Sulfated Hydroxyalkylpolyethylen- and / or Hydroxyalkylenpropylenglykolether according to DE-A-37 23 354 .
• - Sulfonates of unsaturated fatty acids having 12 to 24 carbon atoms and 1 to 6 double bonds according to DE-A-39 26 344 .
• - esters of tartaric acid and citric acid with alcohols which are adducts of about 2-15 molecules of ethylene oxide and / or propylene oxide with fatty alcohols having 8 to 22 carbon atoms.

Preferred anionic surfactants are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acids having 10 to 18 carbon atoms in the alkyl group and up to 12 glycol ether groups in the molecule and in particular salts of saturated and in particular unsaturated C ₈ -C ₂₂ carboxylic acids, such as oleic acid, stearic acid, isostearic acid and palmitic acid ,

• – Anlagerungsprodukte von 2 bis 30 Mol Ethylenoxid und/oder 0 bis 5 Mol Propylenoxid an lineare Fettalkohole mit 8 bis 22 C-Atomen, an Fettsäuren mit 12 bis 22 C-Atomen und an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe,
• – C₁₂-C₂₂-Fettsäuremono- und -diester von Anlagerungsprodukten von 1 bis 30 Mol Ethylenoxid an Glycerin,
• – C_8-C22-Alkylmono- und -oligoglycoside und deren ethoxylierte Analoga sowie
• – Anlagerungsprodukte von 5 bis 60 Mol Ethylenoxid an Rizinusöl und gehärtetes Rizinusöl.

Nonionic surfactants contain as hydrophilic group z. A polyol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether groups. Such compounds are, for example

• Addition products of 2 to 30 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide onto linear fatty alcohols having 8 to 22 carbon atoms, to fatty acids containing 12 to 22 carbon atoms and to alkylphenols having 8 to 15 carbon atoms in the alkyl group,
• C ₁₂ -C ₂₂ -fatty acid mono- and diesters of addition products of 1 to 30 mol of ethylene oxide with glycerol,
• C ₈ -C 22 alkyl mono- and oligoglycosides and their ethoxylated analogs, and
• - Addition products of 5 to 60 moles of ethylene oxide with castor oil and hydrogenated castor oil.

Preferred nonionic surfactants are alkyl polyglycosides of the general formula R ¹ O- (Z) _x . These connections are identified by the following parameters.

The alkyl radical R ¹ contains 6 to 22 carbon atoms and may be both linear and branched. Preference is given to primary linear and methyl-branched in the 2-position aliphatic radicals. Such alkyl radicals are, for example, 1-octyl, 1-decyl, 1-lauryl, 1-myristyl, 1-cetyl and 1-stearyl. Particularly preferred are 1-octyl, 1-decyl, 1-lauryl, 1-myristyl. When using so-called "oxo-alcohols" as starting materials, compounds with an odd number of carbon atoms in the alkyl chain predominate.

The alkyl polyglycosides which can be used according to the invention can contain, for example, only one particular alkyl radical R ¹ . Usually, however, these compounds are prepared starting from natural fats and oils or mineral oils. In this case, the alkyl radicals R are mixtures corresponding to the starting compounds or corresponding to the particular work-up of these compounds.

• – im Wesentlichen aus C₈- und C₁₀-Alkylgruppen,
• – im Wesentlichen aus C₁₂- und C₁₄-Alkylgruppen,
• – im Wesentlichen aus C₈- bis C₁₆-Alkylgruppen oder
• – im Wesentlichen aus C₁₂- bis C₁₆-Alkylgruppen besteht.

Particular preference is given to those alkylpolyglycosides in which R ¹

• Essentially C ₈ and C ₁₀ alkyl groups,
• Essentially of C ₁₂ and C ₁₄ alkyl groups,
• Essentially of C ₈ to C ₁₆ alkyl groups or
• - Consists essentially of C ₁₂ - to C ₁₆ -alkyl groups.

When Sugar building block Z can be any mono- or oligosaccharides be used. Usually, sugars with 5 or 6 carbon atoms and the corresponding oligosaccharides used. Such sugars are, for example, glucose, fructose, galactose, Arabinose, ribose, xylose, lyxose, allose, altrose, mannose, gulose, Idose, talose and sucrose. Preferred sugar building blocks are glucose, Fructose, galactose, arabinose and sucrose; Glucose is special prefers.

The Alkylpolyglycosides which can be used according to the invention contain on average 1.1 to 5 sugar units. Alkylpolyglykoside with x values of 1.1 to 1.6 are preferred. Very particularly preferred are alkyl glycosides in which x is 1.1 to 1.4.

The Alkyl glycosides can be used in addition to their surfactant effect serve to improve the fixation of fragrance components on the hair. The expert will be so in the event that one over the duration of the hair treatment beyond effect of the perfume oil is desired on the hair, preferably to this class of substance as a further ingredient of the invention Resort to preparations.

Also the alkoxylated homologs of said alkyl polyglycosides can used according to the invention. These homologs can average up to 10 ethylene oxide and / or Propylene oxide units per Alkylglykosideinheit included.

Furthermore, zwitterionic surfactants can be used, in particular as cosurfactants. Zwitterionic surfactants are surface-active compounds which carry at least one quaternary ammonium group and at least one -COO ^(-) or -SO ₃ ^(-) group in the molecule. Particularly suitable zwitterionic surfactants are the so-called betaines such as N-alkyl-N, N-dimethylammonium glycinates, for example cocoalkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammoniumglycinate, for example cocoacylaminopropyl-dimethylammonium glycinate, and Alkyl-3-carboxylmethyl-3-hydroxyethyl-imidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group and Kokosacylaminoethylhydroxyethylcarboxymethylglycinat. A preferred zwitterionic surfactant is the fatty acid amide derivative known by the INCI name Cocamidopropyl Betaine.

Also particularly suitable as co-surfactants are ampholytic surfactants. Ampholytic surfactants are understood as meaning those surface-active compounds which, apart from a C ₈ -C ₁₈ -alkyl or acyl group in the molecule, contain at least one free amino group and at least one -COOH or -SO ₃ H group and are capable of forming internal salts. Examples of suitable ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each having about 8 to 18 C Atoms in the alkyl group. Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and C _12-18 acylsarcosine.

According to the invention as cationic surfactants, especially those of the quaternary type Ammonium compounds, the esterquats and the amidoamines used.

preferred quaternary ammonium compounds are ammonium halides, especially chlorides and bromides, such as alkyltrimethylammonium chlorides, Dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, z. Cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, Distearyldimethylammonium chloride, lauryldimethylammonium chloride, Lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride, as well as those under the INCI names Quaternium-27 and Quaternium-83 known imidazolium compounds. The long alkyl chains of the above surfactants mentioned preferably have 10 to 18 carbon atoms.

Esterquats are known substances which contain both at least one ester function and at least one quaternary ammonium group as a structural element. Preferred ester quats are quaternized ester salts of fatty acids with triethanolamine, quaternized ester salts of fatty acids with diethanolalkylamines and quaternized ester salts of fatty acids with 1,2-dihydroxypropyldialkylamines. Such products are marketed under the trade names Stepantex® ^{®, ®} and Dehyquart® Armocare® ^®. The products Armocare ^® VGH-70, a N, N-bis (2-palmitoyloxyethyl) dimethylammonium chloride, as well as Dehyquart ^® F-75 and Dehyquart ^® AU-35 are examples of such esterquats.

The alkylamidoamines are usually prepared by amidation of natural or synthetic fatty acids and fatty acid cuts with dialkylaminoamines. An inventively particularly suitable compound from this group of substances under the name Tegoamid ^® S 18 commercial stearamidopropyl dimethylamine is.

Further Cationic surfactants which can be used according to the invention represent the quaternized protein hydrolysates.

Also suitable in the present invention are cationic silicone oils such as the commercially available products Q2-7224 (manufactured by Dow Corning, a stabilized trimethylsilylamodimethicone), Dow Corning 929 emulsion (containing a hydroxylamino-modified silicone, also referred to as amodimethicones), SM-2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker) and Abil ^® quat 3270 and 3272 (manufacturer: Th Goldschmidt; diquaternary polydimethylsiloxanes, quaternium-80.).

An example of a suitable cationic surfactant quaternary sugar derivative is the commercially available product Glucquat ^® 100 is, according to INCI nomenclature a "lauryl methyl Gluceth-10 Hydroxypropyl Dimonium Chloride".

at it may be the compounds with alkyl groups used as surfactant each are uniform substances. It is, however, in usually preferred in the preparation of these substances by native to go out with vegetable or animal raw materials, so that one Substance mixtures with different, from the respective raw material receives dependent alkyl chain lengths.

at the surfactants, the adducts of ethylene and / or propylene oxide represent fatty alcohols or derivatives of these addition products, can both products with a "normal" homolog distribution as well as those with a narrow homolog distribution become. Under "normal" homolog distribution are mixtures understood by homologues who are involved in the reaction of fatty alcohol and alkylene oxide using alkali metals, alkali metal hydroxides or alkali metal alcoholates as catalysts. Narrowed homolog distributions are obtained when, for example Hydrotalcites, alkaline earth metal salts of ether carboxylic acids, Alkaline earth metal oxides, hydroxides or alcoholates as catalysts be used. The use of products with narrow homolog distribution may be preferred.

• – nichtionische Polymere wie beispielsweise Vinylpyrrolidon/Vinylacrylat-Copolymere, Polyvinylpyrrolidon und Vinylpyrrolidon/Vinylacetat-Copolymere und Polysiloxane,
• – kationische Polymere wie quaternisierte Celluloseether, Polysiloxane mit quaternären Gruppen, Dimethyldiallylammoniumchlorid-Polymere, Acrylamid-Dimethyldiallyl-ammoniumchlorid-Copolymere, mit Diethylsulfat quaternierte Dimethylamino-ethylmethacrylat-Vinylpyrrolidon-Copolymere, Vinylpyrrolidon-Imidazolinium-methochlorid-Copolymere und quaternierter Polyvinylalkohol,
• – zwitterionische und amphotere Polymere wie beispielsweise Acrylamidopropyl-trimethylammoniumchlorid/Acrylat-Copolymere und Octylacrylamid/Methyl-methacrylat/tert-Butylaminoethylmethacrylat/2-Hydroxypropylmethacrylat-Copolymere,
• – anionische Polymere wie beispielsweise Polyacrylsäuren, vernetzte Polyacrylsäuren, Vinylacetat/Crotonsäure-Copolymere, Vinylpyrrolidon/Vinylacrylat-Copolymere, Vinylacetat/Butylmaleat/Isobornylacrylat-Copolymere, Methylvinylether/Malein-säureanhydrid-Copolymere und Acrylsäure/Ethylacrylat/N-tert.Butyl-acrylamid-Terpolymere,
• – Verdickungsmittel wie Agar-Agar, Guar-Gum, Alginate, Xanthan-Gum, Gummi arabicum, Karaya-Gummi, Johannisbrotkernmehl, Leinsamengummen, Dextrane, Cellulose-Derivate, z. B. Methylcellulose, Hydroxyalkylcellulose und Carboxymethylcellulose, Stärke-Fraktionen und Derivate wie Amylose, Amylopektin und Dextrine, Tone wie z. B. Bentonit oder vollsynthetische Hydrokolloide wie z. B. Polyvinylalkohol,
• – Strukturanten wie Maleinsäure und Milchsäure,
• – haarkonditionierende Verbindungen wie Phospholipide, beispielsweise Sojalecithin, Ei-Lecitin und Kephaline,
• – Proteinhydrolysate, insbesondere Elastin-, Kollagen-, Kerstin-, Milcheiweiß-, Sojaprotein- und Weizenproteinhydrolysate, deren Kondensationsprodukte mit Fettsäuren sowie quaternisierte Proteinhydrolysate,
• – Parfümöle, Dimethylisosorbid und Cyclodextrine,
• – Lösungsmittel und -vermittler wie Ethanol, Isopropanol, Ethylenglykol, Propylenglykol, Glycerin und Diethylenglykol,
• – faserstrukturverbessernde Wirkstoffe, insbesondere Mono-, Di- und Oligosaccharide wie beispielsweise Glucose, Galactose, Fructose, Fruchtzucker und Lactose,
• – quaternierte Amine wie Methyl-1-alkylamidoethyl-2-alkylimidazolinium-methosulfat
• – Entschäumer wie Silikone,
• – Farbstoffe zum Anfärben des Mittels,
• – Antischuppenwirkstoffe wie Piroctone Olamine, Zink Omadine und Climbazol,
• – Lichtschutzmittel, insbesondere derivatisierte Benzophenone, Zimtsäure-Derivate und Triazine,
• – Substanzen zur Einstellung des pH-Wertes, wie beispielsweise übliche Säuren, insbesondere Genußsäuren und Basen,
• – Wirkstoffe wie Allantoin, Pyrrolidoncarbonsäuren und deren Salze sowie Bisabolol,
• – Vitamine, Provitamine und Vitaminvorstufen, insbesondere solche der Gruppen A, B₃, B₅, B₆, C, E, F und H,
• – Pflanzenextrakte wie die Extrakte aus Grünem Tee, Eichenrinde, Brennessel, Hamamelis, Hopfen, Kamille, Klettenwurzel, Schachtelhalm, Weißdorn, Lindenblüten, Mandel, Aloe Vera, Fichtennadel, Roßkastanie, Sandelholz, Wacholder, Kokosnuß, Mango, Aprikose, Limone, Weizen, Kiwi, Melone, Orange, Grapefruit, Salbei, Rosmarin, Birke, Malve, Wiesenschaumkraut, Quendel, Schafgarbe, Thymian, Melisse, Hauhechel, Huflattich, Eibisch, Meristem, Ginseng und Ingwerwurzel,
• – Cholesterin,
• – Konsistenzgeber wie Zuckerester, Polyolester oder Polyolalkylether,
• – Fette und Wachse wie Walrat, Bienenwachs, Montanwachs und Paraffine,
• – Fettsäurealkanolamide,
• – Komplexbildner wie EDTA, NTA, β-Alanindiessigsäure und Phosphonsäuren,
• – Quell- und Penetrationsstoffe wie Glycerin, Propylenglykolmonoethylether, Carbonate, Hydrogencarbonate, Guanidine, Harnstoffe sowie primäre, sekundäre und tertiäre Phosphate,
• – Trübungsmittel wie Latex, Styrol/PVP- und Styrol/Acrylamid-Copolymere
• – Perlglanzmittel wie Ethylenglykolmono- und -distearat sowie PEG-3-distearat,
• – Pigmente,
• – Stabilisierungsmittel für Wassserstoffperoxid und andere Oxidationsmittel,
• – Treibmittel wie Propan-Butan-Gemische, N₂O, Dimethylether, CO₂ und Luft,
• – Antioxidantien,

enthaltenFurthermore, the colorants according to the invention further active ingredients, auxiliaries and additives, such as

• Nonionic polymers such as vinyl pyrrolidone / vinyl acrylate copolymers, polyvinyl pyrrolidone and vinyl pyrrolidone / vinyl acetate copolymers and polysiloxanes,
• Cationic polymers such as quaternized cellulose ethers, quaternary group polysiloxanes, dimethyldiallylammonium chloride polymers, acrylamide-dimethyldiallyl-ammonium chloride copolymers, diethyl sulfate quaternized dimethylaminoethylmethacrylate-vinylpyrrolidone copolymers, vinylpyrrolidone-imidazolinium methochloride copolymers and quaternized polyvinyl alcohol,
• Zwitterionic and amphoteric polymers such as, for example, acrylamidopropyltrimethylammonium chloride / acrylate copolymers and octylacrylamide / methyl methacrylate / tert-butylaminoethyl methacrylate / 2-hydroxypropyl methacrylate copolymers,
• Anionic polymers such as, for example, polyacrylic acids, crosslinked polyacrylic acids, vinyl acetate / crotonic acid copolymers, vinylpyrrolidone / vinyl acrylate copolymers, vinyl acetate / butyl maleate / isobornyl acrylate copolymers, methyl vinyl ether / maleic anhydride copolymers and acrylic acid / ethyl acrylate / N-tert-butyl acrylamide terpolymers
• Thickeners such as agar-agar, guar gum, alginates, xanthan gum, gum arabic, karaya gum, locust bean gum, linseed gums, dextrans, cellulose derivatives, e.g. For example, methylcellulose, hydroxyalkylcellulose and carboxymethylcellulose, starch fractions and derivatives such as amylose, amylopectin and dextrins, clays such. As bentonite or fully synthetic hydrocolloids such. For example, polyvinyl alcohol,
• - structurants such as maleic acid and lactic acid,
• Hair-conditioning compounds such as phospholipids, for example soya lecithin, egg lecithin and cephalins,
• Protein hydrolysates, in particular elastin, collagen, keratin, milk protein, soy protein and wheat protein hydrolysates, their condensation products with fatty acids and quaternized protein hydrolysates,
• Perfume oils, dimethylisosorbide and cyclodextrins,
• Solvents and mediators such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerol and diethylene glycol,
• Fiber-structure-improving active substances, in particular mono-, di- and oligosaccharides such as, for example, glucose, galactose, fructose, fructose and lactose,
• Quaternized amines such as methyl-1-alkylamidoethyl-2-alkylimidazolinium methosulfate
• Defoamers like silicones,
• Dyes for staining the agent,
• Anti-dandruff agents such as Piroctone Olamine, Zinc Omadine and Climbazole,
• - light stabilizers, in particular derivatized benzophenones, cinnamic acid derivatives and triazines,
• Substances for adjusting the pH, such as, for example, customary acids, in particular edible acids and bases,
• - active substances such as allantoin, pyrrolidonecarboxylic acids and their salts, and bisabolol,
• Vitamins, provitamins and vitamin precursors, in particular those of groups A, B ₃ , B ₅ , B ₆ , C, E, F and H,
• - Plant extracts such as extracts of green tea, oak bark, stinging nettle, witch hazel, hops, chamomile, burdock root, horsetail, hawthorn, linden, almond, aloe vera, spruce needle, horse chestnut, sandalwood, juniper, coconut, mango, apricot, lime, wheat, Kiwi, melon, orange, grapefruit, sage, rosemary, birch, mallow, meadowfoam, quenelle, yarrow, thyme, balm, toadstool, coltsfoot, marshmallow, meristem, ginseng and ginger root,
• - cholesterol,
• Bodying agents such as sugar esters, polyol esters or polyol alkyl ethers,
• - fats and waxes such as spermaceti, beeswax, montan wax and paraffins,
• Fatty acid alkanolamides,
• Complexing agents such as EDTA, NTA, β-alaninediacetic acid and phosphonic acids,
• - swelling and penetrating substances such as glycerol, propylene glycol monoethyl ether, carbonates, bicarbonates, guanidines, ureas and primary, secondary and tertiary phosphates,
• Opacifiers such as latex, styrene / PVP and styrene / acrylamide copolymers
• Pearlescing agents such as ethylene glycol mono- and distearate and PEG-3-distearate,
• - pigments,
• Stabilizer for hydrogen peroxide and other oxidizing agents,
• Propellants such as propane-butane mixtures, N ₂ O, dimethyl ether, CO ₂ and air,
• - antioxidants,

contain

In terms of additional optional components and the quantities used These components are expressly referred to the person skilled in the art Referred to known relevant manuals.

The agents of the invention contain the dye (precursor) e preferably in a suitable aqueous, alcoholic or aqueous-alcoholic carrier. For the purpose the hair coloring are such carriers, for example Creams, emulsions, gels or surfactant-containing foaming Solutions, such as shampoos, foam aerosols or other preparations for use on the hair are suitable. But it is also conceivable, the dye precursors in a powdered or tablet-shaped To integrate formulation.

For the purposes of the present invention, "aqueous-alcoholic solutions" are to be understood as meaning aqueous solutions containing from 3 to 70% by weight of a C ₁ -C ₄ -alcohol, in particular ethanol or isopropanol for example, methoxybutanol, benzyl alcohol, ethyl diglycol or 1,2-propylene glycol, all water-soluble organic solvents being preferred.

The actual oxidative staining of the fibers can basically done with atmospheric oxygen. However, preference is given to a chemical Oxidizing agent used, especially if in addition to the staining a whitening effect on human hair is desired. When Oxidizing agents include persulfates, chlorites and especially hydrogen peroxide or its addition products of urea, melamine and sodium borate in Question. However, according to the invention, the oxidation colorant also be applied to the hair together with a catalyst, the oxidation of the dye precursors, eg. B. by atmospheric oxygen, activated. Such catalysts are z. As metal ions, iodides, Quinones or certain enzymes.

Suitable metal ions are, for example, Zn ^{2 +,} Cu ^{2 +,} Fe ^{2 +,} Fe ^{3 +,} Mn ^{2 +,} Mn ^{4 +,} Li ^+, Mg ^2+, Ca and Al ^3+, are particularly suitable here Zn ^{2 +,} Cu ^{2 +} and Mn ^{2 +} . The metal ions can in principle be used in the form of any physiologically acceptable salt or in the form of a complex compound. Preferred salts are the acetates, sulfates, halides, lactates and tartrates. By using these metal salts, both the formation of the dyeing can be accelerated and the color shade can be specifically influenced.

• – Pyranose-Oxidase und z. B. D-Glucose oder Galactose,
• – Glucose-Oxidase und D-Glucose,
• – Glycerin-Oxidase und Glycerin,
• – Pyruvat-Oxidase und Benztraubensäure oder deren Salze,
• – Alkohol-Oxidase und Alkohol (MeOH, EtOH),
• – Lactat-Oxidase und Milchsäure und deren Salze,
• – Tyrosinase-Oxidase und Tyrosin,
• – Uricase und Harnsäure oder deren Salze,
• – Cholinoxidase und Cholin,
• – Aminosäure-Oxidase und Aminosäuren.

Suitable enzymes are z. As peroxidases, which can significantly increase the effect of small amounts of hydrogen peroxide. Furthermore, such enzymes are suitable according to the invention which directly oxidize the oxidation dye precursors with the aid of atmospheric oxygen, such as, for example, the laccases, or generate small amounts of hydrogen peroxide in situ and thus biocatalytically activate the oxidation of the dye precursors. Particularly suitable catalysts for the oxidation of the dye precursors are the so-called 2-electron oxidoreductases in combination with the specific substrates, for. B.

• - pyranose oxidase and z. D-glucose or galactose,
• Glucose oxidase and D-glucose,
• - glycerol oxidase and glycerin,
• Pyruvate oxidase and pyruvic acid or its salts,
• Alcohol oxidase and alcohol (MeOH, EtOH),
• Lactate oxidase and lactic acid and their salts,
• Tyrosinase oxidase and tyrosine,
• Uricase and uric acid or their salts,
• - choline oxidase and choline,
• - amino acid oxidase and amino acids.

The actual hair dye is conveniently immediately before use by mixing the preparation of the Oxidizing agent with the preparation containing the dye precursors, produced. The resulting ready-to-use hair dye preparation should preferably have a pH in the range of 6 to 12. Particularly preferred is the application of the hair dye in a slightly alkaline environment. The application temperatures can range between 15 and 40 ° C. To an exposure time of 5 to 45 minutes becomes the hair dye by rinsing away from the hair to be dyed. The washing with a shampoo is eliminated if a strong surfactant-containing carrier, for. B. a dyeing shampoo, has been used.

Especially For hair that is difficult to dye, the preparation may be mixed with the Dye precursors but also without prior mixing with the Oxidation component to be applied to the hair. After a Einwirkdauer of 20 to 30 minutes will then - if necessary after an intermediate rinse - the oxidation component applied. After another exposure time of 10 to 20 minutes is then rinsed and nachshampooniert if desired. In this embodiment, according to a first variant, in which the previous application of the dye precursors to effect a better penetration into the hair, the corresponding Medium adjusted to a pH of about 4 to 7. According to one second variant, first an air oxidation is sought, wherein the applied agent preferably has a pH of 7 to 10 has. In the subsequent accelerated post-oxidation can the use of acidified peroxydisulfate solutions be preferred as the oxidizing agent.

in the The work underlying this application has been shown be that the combinations of the invention lead to dyeings with good gray coverage.

One Another object of the present invention is a method for coloring keratinous fibers, in which an inventive Agent is applied to the fibers and after a contact time is rinsed off again.

In terms of further preferred embodiments of the invention Method applies mutatis mutandis to the invention Means said.

The The following examples are intended to form the subject of the present invention explain without limiting it in any way.

embodiments

Patent examples

The following dyeing formulations were prepared; Unless otherwise indicated, the quantities are by weight. 1 Colorant base A 1.1 Formulations raw material Concentration [% by weight] Hydrenol ^® D 6.9 Lorol® ^® techn 2.3 Comperlan® ^® 100 2.0 Eumulgin ^® B2 2.0 Dehyqua ^® A-CA 3.0 ammonium sulfate 0.5 sodium 0.5 ascorbic acid 0.5 AMP 95 1.0 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Gluadin® ^® W 40 0.2 Cosmedia® ^® CTH (E) 0.5 1,2-propylene glycol individually Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.88 p-aminophenol hydrochloride 0.52 resorcinol 0.43 m-aminophenol 0.8 5-amino-2-methylphenol 0.18 Disperse Violet 1 0.2

For the streak dyed with this staining cream, the following colorimetric values were determined: L value: 16.7 a-value: 1.6 b-value: -2.1

The application preparation prepared analogously to point 1.2 was additionally for determining the gray coverage on 2 different strands dyed (buffalo belly hair and alkinco, light brown). The duration of use was 30 minutes at 32 ° C. Subsequently Each strand was rinsed for one minute with lukewarm water and dried with a hair dryer. To determine the gray coverage index each strand was measured colorimetrically after drying. As a reference, the buffalo belly hair tress also became measured colorimetrically before the coloration process.

The following gray coverage index was determined: streak L value a-value b-value Δ value Gray coverage index Buffalo belly hair, uncolored 72.5 0.2 9.6 55.6 93.0 Alkinco light brown, colored 17.8 1.9 0.0 3.9 Buffalo belly hair, colored 19.3 3.9 -3.0 raw material Concentration [% by weight] Hydrenol ^® D 6.9 Lorol® ^® techn 2.3 Comperlan® ^® 100 2.0 Eumulgin ^® B2 2.0 Dehyqua ^® A-CA 3.0 ammonium sulfate 0.5 sodium 0.5 ascorbic acid 0.5 AMP 95 1.0 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Gluadin® ^® W 40 0.2 Cosmedia® ^® CTH (E) 0.5 1,2-propylene glycol individually Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.38 resorcinol 0.13 m-aminophenol 0.07 5-amino-2-methylphenol 0.22 3-Amino-2-chloro-6-methylphenol 0.07 2,7-dihydroxynaphthalene 0.08 1,5-dihydroxynaphthalene 0.05 1-phenyl-3-methyl-5-pyrazolone 0.1 HC Red 7 0.2

For the streak dyed with this staining cream, the following colorimetric values were determined: L value: 20.3 a-value: 3.7 b-value: 3.5 raw material Concentration [% by weight] Hydrenol ^® D 6.9 Lorol® ^® techn 2.3 Comperlan® ^® 100 2.0 Eumulgin ^® B2 2.0 Dehyqua ^® A-CA 3.0 ammonium sulfate 0.5 sodium 0.5 ascorbic acid 0.5 AMP 95 1.0 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Gluadin® ^® W 40 0.2 Cosmedia® ^® CTH (E) 0.5 1,2-propylene glycol individually Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.21 resorcinol 0.55 m-aminophenol 0.15 3-amino-2-methylamino-6-methoxypyridine 0.04 Basic Brown 16 0.20 raw material Concentration [% by weight] Hydrenol ^® D 6.9 Lorol® ^® techn 2.3 Comperlan® ^® 100 2.0 Eumulgin ^® B2 2.0 Dehyqua ^® A-CA 3.0 ammonium sulfate 0.5 sodium 0.5 ascorbic acid 0.5 AMP 95 1.0 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Gluadin® ^® W 40 0.2 Cosmedia® ^® CTH (E) 0.5 1,2-propylene glycol individually Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.39 resorcinol 0.30 2,4-Diaminophenoxyethanol 1.74 HC Blue 2 0.20 raw material Concentration [% by weight] Hydrenol ^® D 6.9 Lorol® ^® techn 2.3 Comperlan® ^® 100 2.0 Eumulgin ^® B2 2.0 Dehyqua ^® A-CA 3.0 ammonium sulfate 0.5 sodium 0.5 ascorbic acid 0.5 AMP 95 1.0 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Gluadin® ^® W 40 0.2 Cosmedia® ^® CTH (E) 0.5 1,2-propylene glycol individually Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.73 2,4-diaminophenoxyethanol 2 HC 1.91 resorcinol 0.33 4-nitro-o-phenylenediamine 0.30 raw material Concentration [% by weight] Hydrenol ^® D 6.9 Lorol® ^® techn 2.3 Comperlan® ^® 100 2.0 Eumulgin ^® B2 2.0 Dehyqua ^® A-CA 3.0 ammonium sulfate 0.5 sodium 0.5 ascorbic acid 0.5 AMP 95 1.0 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Gluadin® ^® W 40 0.2 Cosmedia® ^® CTH (E) 0.5 1,2-propylene glycol individually Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.82 resorcinol 0.17 2,7-dihydroxynaphthalene 0.29 1,3-bis (2,4-diaminophenoxy) propan-tetrahydrochloird 0.44 Basic Violet 2 0.30 raw material Concentration [% by weight] Hydrenol ^® D 6.9 Lorol® ^® techn 2.3 Comperlan® ^® 100 2.0 Eumulgin ^® B2 2.0 Dehyqua ^® A-CA 3.0 ammonium sulfate 0.5 sodium 0.5 ascorbic acid 0.5 AMP 95 1.0 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Gluadin® ^® W 40 0.2 Cosmedia® ^® CTH (E) 0.5 1,2-propylene glycol individually Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.36 resorcinol 0.24 m-aminophenol 0.12 o-aminophenol 0.16 2,6-diaminopyridine 0.55 HC Red 3 0.20 raw material Concentration [% by weight] Hydrenol ^® D 6.9 Lorol® ^® techn 2.3 Comperlan® ^® 100 2.0 Eumulgin ^® B2 2.0 Dehyqua ^® A-CA 3.0 ammonium sulfate 0.5 sodium 0.5 ascorbic acid 0.5 AMP 95 1.0 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Gluadin® ^® W 40 0.2 Cosmedia® ^® CTH (E) 0.5 1,2-propylene glycol individually Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.31 4,4'-diaminodiphenylamine sulfate 0.04 resorcinol 0.08 m-aminophenol 0.06 N, N'-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine 0.20 raw material Concentration [% by weight] Hydrenol ^® D 6.9 Lorol® ^® techn 2.3 Comperlan® ^® 100 2.0 Eumulgin ^® B2 2.0 Dehyqua ^® A-CA 3.0 ammonium sulfate 0.5 sodium 0.5 ascorbic acid 0.5 AMP 95 1.0 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Gluadin® ^® W 40 0.2 Cosmedia® ^® CTH (E) 0.5 1,2-propylene glycol individually Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.16 resorcinol 0.51 m-aminophenol 0.12 2-amino-4-Hydroxyethylaminoanisolsulfat 0.18 HC Red 13 0.30 raw material Concentration [% by weight] Hydrenol ^® D 6.9 Lorol® ^® techn 2.3 Comperlan® ^® 100 2.0 Eumulgin ^® B2 2.0 Dehyqua ^® A-CA 3.0 ammonium sulfate 0.5 sodium 0.5 ascorbic acid 0.5 AMP 95 1.0 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Gluadin® ^® W 40 0.2 Cosmedia® ^® CTH (E) 0.5 1,2-propylene glycol individually Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.55 m-aminophenol 0.22 2-amino-4-Hydroxyethylaminoanisolsulfat 0.04 4-chlororesorcinol 0.78 HC Yellow 2 0.15 HC Orange 1 0.25 raw material Concentration [% by weight] Hydrenol ^® D 6.9 Lorol® ^® techn 2.3 Comperlan® ^® 100 2.0 Eumulgin ^® B2 2.0 Dehyqua ^® A-CA 3.0 ammonium sulfate 0.5 sodium 0.5 ascorbic acid 0.5 AMP 95 1.0 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Gluadin® ^® W 40 0.2 Cosmedia® ^® CTH (E) 0.5 1,2-propylene glycol individually Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.93 4,5-diamino-1- (2-hydroxyethyl) -1H-pyrazol-sulfate 0.93 2,4-diaminophenoxyethanol dihydrochloride 0.58 resorcinol 0.56 m-aminophenol 0.09 5-amino-2-methylphenol 0.39 Hydroxyethyl-2-nitro-p-toluidine 0.3 raw material Concentration [% by weight] Hydrenol ^® D 6.9 Lorol® ^® techn 2.3 Comperlan® ^® 100 2.0 Eumulgin ^® B2 2.0 Dehyqua ^® A-CA 3.0 ammonium sulfate 0.5 sodium 0.5 ascorbic acid 0.5 AMP 95 1.0 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Gluadin® ^® W 40 0.2 Cosmedia® ^® CTH (E) 0.5 1,2-propylene glycol individually Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.39 2,4-diaminophenoxyethanol dihydrochloride 1.74 resorcinol 0.3 Basic Blue 99 0.3 raw material Concentration [% by weight] Hydrenol ^® D 6.9 Lorol® ^® techn 2.3 Comperlan® ^® 100 2.0 Eumulgin ^® B2 2.0 Dehyqua ^® A-CA 3.0 ammonium sulfate 0.5 sodium 0.5 ascorbic acid 0.5 AMP 95 1.0 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Gluadin® ^® W 40 0.2 Cosmedia® ^® CTH (E) 0.5 1,2-propylene glycol individually Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.73 resorcinol 0.3 m-aminophenol 0.19 3-amino-2-methylamino-6-methoxypyridine 0.01 2,6-dihydroxy-3,4-dimethylpyridine 0.12 HC Yellow 13 0.2 Basic Brown 17 0 raw material Concentration [% by weight] Hydrenol ^® D 6.9 Lorol® ^® techn 2.3 Comperlan® ^® 100 2.0 Eumulgin ^® B2 2.0 Dehyqua ^® A-CA 3.0 ammonium sulfate 0.5 sodium 0.5 ascorbic acid 0.5 AMP 95 1.0 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Gluadin® ^® W 40 0.2 Cosmedia® ^® CTH (E) 0.5 1,2-propylene glycol individually Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.67 resorcinol 0.27 3-amino-2-methylamino-6-methoxypyridine 0.06 4-chlororesorcinol 0.37 1,3-bis (2,4-diaminophenoxy) propane 4HCl 0.2 Basic Red 76 0.2 Basic Brown 17 0.05 raw material Concentration [% by weight] Hydrenol ^® D 6.9 Lorol® ^® techn 2.3 Comperlan® ^® 100 2.0 Eumulgin ^® B2 2.0 Dehyqua ^® A-CA 3.0 ammonium sulfate 0.5 sodium 0.5 ascorbic acid 0.5 AMP 95 1.0 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Gluadin® ^® W 40 0.2 Cosmedia® ^® CTH (E) 0.5 1,2-propylene glycol individually Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.31 4-chlororesorcinol 0.04 resorcinol 0.05 3-Amino-2-chloro-6-methylphenol 0.01 3-amino-2-methylamino-6-methoxypyridine 0.03 Basic Yellow 57 0.08 raw material Concentration [% by weight] Hydrenol ^® D 6.9 Lorol® ^® techn 2.3 Comperlan® ^® 100 2.0 Eumulgin ^® B2 2.0 Dehyqua ^® A-CA 3.0 ammonium sulfate 0.5 sodium 0.5 ascorbic acid 0.5 AMP 95 1.0 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Gluadin® ^® W 40 0.2 Cosmedia® ^® CTH (E) 0.5 1,2-propylene glycol individually Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.71 2,4,5,6-tetra-sulfate 0.23 resorcinol 0.11 2-methyl 0.11 2,7-dihydroxynaphthalene 0.2 HC Red 1 0.2 raw material Concentration [% by weight] Hydrenol ^® D 6.9 Lorol® ^® techn 2.3 Comperlan® ^® 100 2.0 Eumulgin ^® B2 2.0 Dehyqua ^® A-CA 3.0 ammonium sulfate 0.5 sodium 0.5 ascorbic acid 0.5 AMP 95 1.0 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Gluadin® ^® W 40 0.2 Cosmedia® ^® CTH (E) 0.5 1,2-propylene glycol individually Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.67 m-aminophenol 0.12 resorcinol 0.39 2-methyl 0.05 2-amino-3-hydroxypyridine 0.06 HC Blue 12 0.08 raw material Concentration [% by weight] Hydrenol ^® D 6.9 Lorol® ^® techn 2.3 Comperlan® ^® 100 2.0 Eumulgin ^® B2 2.0 Dehyqua ^® A-CA 3.0 ammonium sulfate 0.5 sodium 0.5 ascorbic acid 0.5 AMP 95 1.0 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Gluadin® ^® W 40 0.2 Cosmedia® ^® CTH (E) 0.5 1,2-propylene glycol individually Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.12 2-methyl 0.28 4-chlororesorcinol 0.13 3-amino-2-methylamino-6-methoxypyridine 0.01 Acid Violet 43 0.2 raw material Concentration [% by weight] Hydrenol ^® D 6.9 Lorol® ^® techn 2.3 Comperlan® ^® 100 2.0 Eumulgin ^® B2 2.0 Dehyqua ^® A-CA 3.0 ammonium sulfate 0.5 sodium 0.5 ascorbic acid 0.5 AMP 95 1.0 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Gluadin® ^® W 40 0.2 Cosmedia® ^® CTH (E) 0.5 1,2-propylene glycol individually Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.4437 2,4,5,6-tetra-sulfate .7741 m-aminophenol .4200 2-amino-3-hydroxypyridine .1650 4-chlororesorcinol .2400

1.2 colorations

The colorants mentioned under point 1.1 were each immediately before the coloration in the ratio 2 parts by weight cream: 1 part by weight Developer mixed with the following composition: raw material Concentration [% by weight] Lorol C 16 ^® 3.5 Eumulgin ^® B2 1.0 Disponil ^® FES 77 2.5 Ammonia 25% 0.7 dipicolinic 0.1 disodiumpyrophosphate 0.03 Turpinal® ^® SL 1.5 Hydrogen peroxide 50% 12.0 Aculyn ^® 33 10.0 water ad 100

The resulting application mixtures were each dyed to 6 cm long strands (Kerling, 80% mottled). The duration of use was 30 minutes at 32 ° C. Then each tress was rinsed for one minute with lukewarm water and dried with a hair dryer. 2 Colorant base B 2.1 Formulations raw material Concentration [%] Hydrenol ^® D 6.0 Lorol® ^® techn 6.0 Eumulgin ^® B1 3.0 Eumulgin ^® B2 3.0 PHB Methylester 0.3 PHB propyl 0.2 phenoxyethanol 1.0 PEG MG 1500 1.0 Polyglycol 400 5.0 Eumulgin ^® RO 40 1.0 Natrosol ^® 250 HR 1.0 NaOH 0.1 ammonium sulfate 0.4 sodium 0.5 benzyl alcohol 1.0 3-methoxybutanol 1.0 Dow ^Corning® 193 Fluid 0.5 Luviquat.RTM ^® Excellence 1.0 D-panthenol 0.3 NaOH ad pH 10 Citric acid (20%) water ad 100.0 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.88 p-aminophenol hydrochloride 0.52 resorcinol 0.43 m-aminophenol 0.8 5-amino-2-methylphenol 0.18 Disperse Violet 1 0.2 raw material Concentration [%] Hydrenol ^® D 6.0 Lorol® ^® techn 6.0 Eumulgin ^® B1 3.0 Eumulgin ^® B2 3.0 PHB Methylester 0.3 PHB propyl 0.2 phenoxyethanol 1.0 PEG MG 1500 1.0 Polyglycol 400 5.0 Eumulgin ^® RO 40 1.0 Natrosol ^® 250 HR 1.0 NaOH 0.1 ammonium sulfate 0.4 sodium 0.5 benzyl alcohol 1.0 3-methoxybutanol 1.0 Dow ^Corning® 193 Fluid 0.5 Luviquat.RTM ^® Excellence 1.0 D-panthenol 0.3 NaOH ad pH 10 Citric acid (20%) water ad 100.0 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.38 resorcinol 0.13 m-aminophenol 0.07 5-amino-2-methylphenol 0.22 3-Amino-2-chloro-6-methylphenol 0.07 2,7-dihydroxynaphthalene 0.08 1,5-dihydroxynaphthalene 0.05 1-phenyl-3-methyl-5-pyrazolone 0.1 HC Red 7 0.2 raw material Concentration [%] Hydrenol ^® D 6.0 Lorol® ^® techn 6.0 Eumulgin ^® B1 3.0 Eumulgin ^® B2 3.0 PHB Methylester 0.3 PHB propyl 0.2 phenoxyethanol 1.0 PEG MG 1500 1.0 Polyglycol 400 5.0 Eumulgin ^® RO 40 1.0 Natrosol ^® 250 HR 1.0 NaOH 0.1 ammonium sulfate 0.4 sodium 0.5 benzyl alcohol 1.0 3-methoxybutanol 1.0 Dow ^Corning® 193 Fluid 0.5 Luviquat.RTM ^® Excellence 1.0 D-panthenol 0.3 NaOH ad pH 10 Citric acid (20%) water ad 100.0 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.21 resorcinol 0.55 m-aminophenol 0.15 3-amino-2-methylamino-6-methoxypyridine 0.04 Basic Brown 16 0.20

For the streak dyed with this staining cream, the following colorimetric values were determined: L value: 14.7 a-value: 0.1 b-value: -2.1 raw material Concentration [%] Hydrenol ^® D 6.0 Lorol® ^® techn 6.0 Eumulgin ^® B1 3.0 Eumulgin ^® B2 3.0 PHB Methylester 0.3 PHB propyl 0.2 phenoxyethanol 1.0 PEG MG 1500 1.0 Polyglycol 400 5.0 Eumulgin ^® RO 40 1.0 Natrosol ^® 250 HR 1.0 NaOH 0.1 ammonium sulfate 0.4 sodium 0.5 benzyl alcohol 1.0 3-methoxybutanol 1.0 Dow ^Corning® 193 Fluid 0.5 Luviquat.RTM ^® Excellence 1.0 D-panthenol 0.3 NaOH ad pH 10 Citric acid (20%) water ad 100.0 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.39 resorcinol 0.30 2,4-Diaminophenoxyethanol 1.74 HC Blue 2 0.20

For the streak dyed with this staining cream, the following colorimetric values were determined: L value: 20.1 a-value: 1.3 b-value: 3.9 raw material Concentration [%] Hydrenol ^® D 6.0 Lorol® ^® techn 6.0 Eumulgin ^® B1 3.0 Eumulgin ^® B2 3.0 PHB Methylester 0.3 PHB propyl 0.2 phenoxyethanol 1.0 PEG MG 1500 1.0 Polyglycol 400 5.0 Eumulgin ^® RO 40 1.0 Natrosol ^® 250 HR 1.0 NaOH 0.1 ammonium sulfate 0.4 sodium 0.5 benzyl alcohol 1.0 3-methoxybutanol 1.0 Dow ^Corning® 193 Fluid 0.5 Luviquat.RTM ^® Excellence 1.0 D-panthenol 0.3 NaOH ad pH 10 Citric acid (20%) water ad 100.0 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.73 2,4-diaminophenoxyethanol 2 HC 1.91 resorcinol 0.33 4-nitro-o-phenylenediamine 0.30 raw material Concentration [%] Hydrenol ^® D 6.0 Lorol® ^® techn 6.0 Eumulgin ^® B1 3.0 Eumulgin ^® B2 3.0 PHB Methylester 0.3 PHB propyl 0.2 phenoxyethanol 1.0 PEG MG 1500 1.0 Polyglycol 400 5.0 Eumulgin ^® RO 40 1.0 Natrosol ^® 250 HR 1.0 NaOH 0.1 ammonium sulfate 0.4 sodium 0.5 benzyl alcohol 1.0 3-methoxybutanol 1.0 Dow ^Corning® 193 Fluid 0.5 Luviquat.RTM ^® Excellence 1.0 D-panthenol 0.3 NaOH ad pH 10 Citric acid (20%) water ad 100.0 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.82 resorcinol 0.17 2,7-dihydroxynaphthalene 0.29 1,3-bis (2,4-diaminophenoxy) propan-tetrahydrochloird 0.44 Basic Violet 2 0.30 raw material Concentration [%] Hydrenol ^® D 6.0 Lorol® ^® techn 6.0 Eumulgin ^® B1 3.0 Eumulgin ^® B2 3.0 PHB Methylester 0.3 PHB propyl 0.2 phenoxyethanol 1.0 PEG MG 1500 1.0 Polyglycol 400 5.0 Eumulgin ^® RO 40 1.0 Natrosol ^® 250 HR 1.0 NaOH 0.1 ammonium sulfate 0.4 sodium 0.5 benzyl alcohol 1.0 3-methoxybutanol 1.0 Dow ^Corning® 193 Fluid 0.5 Luviquat.RTM ^® Excellence 1.0 D-panthenol 0.3 NaOH ad pH 10 Citric acid (20%) water ad 100.0 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.36 resorcinol 0.24 m-aminophenol 0.12 o-aminophenol 0.16 2,6-diaminopyridine 0.55 HC Red 3 0.20 raw material Concentration [%] Hydrenol ^® D 6.0 Lorol® ^® techn 6.0 Eumulgin ^® B1 3.0 Eumulgin ^® B2 3.0 PHB Methylester 0.3 PHB propyl 0.2 phenoxyethanol 1.0 PEG MG 1500 1.0 Polyglycol 400 5.0 Eumulgin ^® RO 40 1.0 Natrosol ^® 250 HR 1.0 NaOH 0.1 ammonium sulfate 0.4 sodium 0.5 benzyl alcohol 1.0 3-methoxybutanol 1.0 Dow ^Corning® 193 Fluid 0.5 Luviquat.RTM ^® Excellence 1.0 D-panthenol 0.3 NaOH ad pH 10 Citric acid (20%) water ad 100.0 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.31 4,4'-diaminodiphenylamine sulfate 0.04 resorcinol 0.08 m-aminophenol 0.06 N, N'-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine 0.20 raw material Concentration [%] Hydrenol ^® D 6.0 Lorol® ^® techn 6.0 Eumulgin ^® B1 3.0 Eumulgin ^® B2 3.0 PHB Methylester 0.3 PHB propyl 0.2 phenoxyethanol 1.0 PEG MG 1500 1.0 Polyglycol 400 5.0 Eumulgin ^® RO 40 1.0 Natrosol ^® 250 HR 1.0 NaOH 0.1 ammonium sulfate 0.4 sodium 0.5 benzyl alcohol 1.0 3-methoxybutanol 1.0 Dow ^Corning® 193 Fluid 0.5 Luviquat.RTM ^® Excellence 1.0 D-panthenol 0.3 NaOH ad pH 10 Citric acid (20%) water ad 100.0 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.16 resorcinol 0.51 m-aminophenol 0.12 2-amino-4-Hydroxyethylaminoanisolsulfat 0.18 HC Red 13 0.30 raw material Concentration [%] Hydrenol ^® D 6.0 Lorol® ^® techn 6.0 Eumulgin ^® B1 3.0 Eumulgin ^® B2 3.0 PHB Methylester 0.3 PHB propyl 0.2 phenoxyethanol 1.0 PEG MG 1500 1.0 Polyglycol 400 5.0 Eumulgin ^® RO 40 1.0 Natrosol ^® 250 HR 1.0 NaOH 0.1 ammonium sulfate 0.4 sodium 0.5 benzyl alcohol 1.0 3-methoxybutanol 1.0 Dow ^Corning® 193 Fluid 0.5 Luviquat.RTM ^® Excellence 1.0 D-panthenol 0.3 NaOH ad pH 10 Citric acid (20%) water ad 100.0 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.55 m-aminophenol 0.22 2-amino-4-Hydroxyethylaminoanisolsulfat 0.04 4-chlororesorcinol 0.78 HC Yellow 2 0.15 HC Orange 1 0.25 raw material Concentration [%] Hydrenol ^® D 6.0 Lorol® ^® techn 6.0 Eumulgin ^® B1 3.0 Eumulgin ^® B2 3.0 PHB Methylester 0.3 PHB propyl 0.2 phenoxyethanol 1.0 PEG MG 1500 1.0 Polyglycol 400 5.0 Eumulgin ^® RO 40 1.0 Natrosol ^® 250 HR 1.0 NaOH 0.1 ammonium sulfate 0.4 sodium 0.5 benzyl alcohol 1.0 3-methoxybutanol 1.0 Dow ^Corning® 193 Fluid 0.5 Luviquat.RTM ^® Excellence 1.0 D-panthenol 0.3 NaOH ad pH 10 Citric acid (20%) water ad 100.0 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.93 4,5-diamino-1- (2-hydroxyethyl) -1H-pyrazol-sulfate 0.93 2,4-diaminophenoxyethanol dihydrochloride 0.58 resorcinol 0.56 m-aminophenol 0.09 5-amino-2-methylphenol 0.39 Hydroxyethyl-2-nitro-p-toluidine 0.3 raw material Concentration [%] Hydrenol ^® D 6.0 Lorol® ^® techn 6.0 Eumulgin ^® B1 3.0 Eumulgin ^® B2 3.0 PHB Methylester 0.3 PHB propyl 0.2 phenoxyethanol 1.0 PEG MG 1500 1.0 Polyglycol 400 5.0 Eumulgin ^® RO 40 1.0 Natrosol ^® 250 HR 1.0 NaOH 0.1 ammonium sulfate 0.4 sodium 0.5 benzyl alcohol 1.0 3-methoxybutanol 1.0 Dow ^Corning® 193 Fluid 0.5 Luviquat.RTM ^® Excellence 1.0 D-panthenol 0.3 NaOH ad pH 10 Citric acid (20%) water ad 100.0 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.39 2,4-diaminophenoxyethanol dihydrochloride 1.74 resorcinol 0.3 Basic Blue 99 0.3 raw material Concentration [%] Hydrenol ^® D 6.0 Lorol® ^® techn 6.0 Eumulgin ^® B1 3.0 Eumulgin ^® B2 3.0 PHB Methylester 0.3 PHB propyl 0.2 phenoxyethanol 1.0 PEG MG 1500 1.0 Polyglycol 400 5.0 Eumulgin ^® RO 40 1.0 Natrosol ^® 250 HR 1.0 NaOH 0.1 ammonium sulfate 0.4 sodium 0.5 benzyl alcohol 1.0 3-methoxybutanol 1.0 Dow ^Corning® 193 Fluid 0.5 Luviquat.RTM ^® Excellence 1.0 D-panthenol 0.3 NaOH ad pH 10 Citric acid (20%) water ad 100.0 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.73 resorcinol 0.3 m-aminophenol 0.19 3-amino-2-methylamino-6-methoxypyridine 0.01 2,6-dihydroxy-3,4-dimethylpyridine 0.12 HC Yellow 13 0.2 Basic Brown 17 0 raw material Concentration [%] Hydrenol ^® D 6.0 Lorol® ^® techn 6.0 Eumulgin ^® B1 3.0 Eumulgin ^® B2 3.0 PHB Methylester 0.3 PHB propyl 0.2 phenoxyethanol 1.0 PEG MG 1500 1.0 Polyglycol 400 5.0 Eumulgin ^® RO 40 1.0 Natrosol ^® 250 HR 1.0 NaOH 0.1 ammonium sulfate 0.4 sodium 0.5 benzyl alcohol 1.0 3-methoxybutanol 1.0 Dow ^Corning® 193 Fluid 0.5 Luviquat.RTM ^® Excellence 1.0 D-panthenol 0.3 NaOH ad pH 10 Citric acid (20%) water ad 100.0 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.67 resorcinol 0.27 3-amino-2-methylamino-6-methoxypyridine 0.06 4-chlororesorcinol 0.37 1,3-bis (2,4-diaminophenoxy) propane 4HCl 0.2 Basic Red 76 0.2 Basic Brown 17 0.05 raw material Concentration [%] Hydrenol ^® D 6.0 Lorol® ^® techn 6.0 Eumulgin ^® B1 3.0 Eumulgin ^® B2 3.0 PHB Methylester 0.3 PHB propyl 0.2 phenoxyethanol 1.0 PEG MG 1500 1.0 Polyglycol 400 5.0 Eumulgin ^® RO 40 1.0 Natrosol ^® 250 HR 1.0 NaOH 0.1 ammonium sulfate 0.4 sodium 0.5 benzyl alcohol 1.0 3-methoxybutanol 1.0 Dow ^Corning® 193 Fluid 0.5 Luviquat.RTM ^® Excellence 1.0 D-panthenol 0.3 NaOH ad pH 10 Citric acid (20%) water ad 100.0 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.31 4-chlororesorcinol 0.04 resorcinol 0.05 3-Amino-2-chloro-6-methylphenol 0.01 3-amino-2-methylamino-6-methoxypyridine 0.03 Basic Yellow 57 0.08 raw material Concentration [%] Hydrenol ^® D 6.0 Lorol® ^® techn 6.0 Eumulgin ^® B1 3.0 Eumulgin ^® B2 3.0 PHB Methylester 0.3 PHB propyl 0.2 phenoxyethanol 1.0 PEG MG 1500 1.0 Polyglycol 400 5.0 Eumulgin ^® RO 40 1.0 Natrosol ^® 250 HR 1.0 NaOH 0.1 ammonium sulfate 0.4 sodium 0.5 benzyl alcohol 1.0 3-methoxybutanol 1.0 Dow ^Corning® 193 Fluid 0.5 Luviquat.RTM ^® Excellence 1.0 D-panthenol 0.3 NaOH ad pH 10 Citric acid (20%) water ad 100.0 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.71 2,4,5,6-tetra-sulfate 0.23 resorcinol 0.11 2-methyl 0.11 2,7-dihydroxynaphthalene 0.2 HC Red 1 0.2 raw material Concentration [%] Hydrenol ^® D 6.0 Lorol® ^® techn 6.0 Eumulgin ^® B1 3.0 Eumulgin ^® B2 3.0 PHB Methylester 0.3 PHB propyl 0.2 phenoxyethanol 1.0 PEG MG 1500 1.0 Polyglycol 400 5.0 Eumulgin ^® RO 40 1.0 Natrosol ^® 250 HR 1.0 NaOH 0.1 ammonium sulfate 0.4 sodium 0.5 benzyl alcohol 1.0 3-methoxybutanol 1.0 Dow ^Corning® 193 Fluid 0.5 Luviquat.RTM ^® Excellence 1.0 D-panthenol 0.3 NaOH ad pH 10 Citric acid (20%) water ad 100.0 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.67 m-aminophenol 0.12 resorcinol 0.39 2-methyl 0.05 2-amino-3-hydroxypyridine 0.06 HC Blue 12 0.08 raw material Concentration [%] Hydrenol ^® D 6.0 Lorol® ^® techn 6.0 Eumulgin ^® B1 3.0 Eumulgin ^® B2 3.0 PHB Methylester 0.3 PHB propyl 0.2 phenoxyethanol 1.0 PEG MG 1500 1.0 Polyglycol 400 5.0 Eumulgin ^® RO 40 1.0 Natrosol ^® 250 HR 1.0 NaOH 0.1 ammonium sulfate 0.4 sodium 0.5 benzyl alcohol 1.0 3-methoxybutanol 1.0 Dow ^Corning® 193 Fluid 0.5 Luviquat.RTM ^® Excellence 1.0 D-panthenol 0.3 NaOH ad pH 10 Citric acid (20%) water ad 100.0 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.12 2-methyl 0.28 4-chlororesorcinol 0.13 3-amino-2-methylamino-6-methoxypyridine 0.01 Acid Violet 43 0.2 raw material Concentration [%] Hydrenol ^® D 6.0 Lorol® ^® techn 6.0 Eumulgin ^® B1 3.0 Eumulgin ^® B2 3.0 PHB Methylester 0.3 PHB propyl 0.2 phenoxyethanol 1.0 PEG MG 1500 1.0 Polyglycol 400 5.0 Eumulgin ^® RO 40 1.0 Natrosol ^® 250 HR 1.0 NaOH 0.1 ammonium sulfate 0.4 sodium 0.5 benzyl alcohol 1.0 3-methoxybutanol 1.0 Dow ^Corning® 193 Fluid 0.5 Luviquat.RTM ^® Excellence 1.0 D-panthenol 0.3 NaOH ad pH 10 Citric acid (20%) water ad 100.0 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.4437 2,4,5,6-tetra-sulfate .7741 m-aminophenol .4200 2-amino-3-hydroxypyridine .1650 4-chlororesorcinol .2400

2.2 colorations

The colorants mentioned under point 2.1 were in each case immediately before the coloration in the ratio 1 part by weight of cream: 1 part by weight Developer mixed with the following composition: raw material Concentration [% by weight] disodiumpyrophosphate 0.3 Disodium EDTA 0.2 Na benzoate 0.04 Emulgade® ^® F 2.1 Phosphoric acid 85% 0.04 Hydrogen peroxide 50% 12.2 Perfume 0.1 water ad 100

The resulting application mixtures were each dyed to 6 cm long strands (Kerling, 80% mottled). The duration of use was 30 minutes at 32 ° C. Then each tress was rinsed for one minute with lukewarm water and dried with a hair dryer. 3 Colorant Base C 3.1 Formulations raw material Concentration [%] Texapon.RTM ^® NSO UP 15.3 Hydrenol ^® D 2.5 Lorol® ^® techn. 4.5 Polychol ^® 5 0.4 Dow ^Corning® 345 Fluid 0.1 Eumulgin ^® O5 2.0 methylparaben 0.2 Propylparaben 0.2 phenoxyethanol 0.5 Polawax ^® GP 200 1.6 Procetyl ^® AWS 1.6 Polyethylene glycol MG 400 5.0 sodium 0.5 sodium bicarbonate 0.4 sodium 0.4 Synthalen ^® K 0.2 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.88 p-aminophenol hydrochloride 0.52 resorcinol 0.43 m-aminophenol 0.8 5-amino-2-methylphenol 0.18 Disperse Violet 1 0.2 raw material Concentration [%] Texapon.RTM ^® NSO UP 15.3 Hydrenol ^® D 2.5 Lorol® ^® techn. 4.5 Polychol ^® 5 0.4 Dow ^Corning® 345 Fluid 0.1 Eumulgin ^® O 5 2.0 methylparaben 0.2 Propylparaben 0.2 phenoxyethanol 0.5 Polawax ^® GP 200 1.6 Procetyl ^® AWS 1.6 Polyethylene glycol MG 400 5.0 sodium 0.5 sodium bicarbonate 0.4 sodium 0.4 Synthalen ^® K 0.2 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.38 resorcinol 0.13 m-aminophenol 0.07 5-amino-2-methylphenol 0.22 3-Amino-2-chloro-6-methylphenol 0.07 2,7-dihydroxynaphthalene 0.08 1,5-dihydroxynaphthalene 0.05 1-phenyl-3-methyl-5-pyrazolone 0.1 HC Red 7 0.2 raw material Concentration [%] Texapon.RTM ^® NSO UP 15.3 Hydrenol ^® D 2.5 Lorol® ^® techn. 4.5 Polychol ^® 5 0.4 Dow ^Corning® 345 Fluid 0.1 Eumulgin ^® O 5 2.0 methylparaben 0.2 Propylparaben 0.2 phenoxyethanol 0.5 Polawax ^® GP 200 1.6 Procetyl ^® AWS 1.6 Polyethylene glycol MG 400 5.0 sodium 0.5 sodium bicarbonate 0.4 sodium 0.4 Synthalen ^® K 0.2 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.21 resorcinol 0.55 m-aminophenol 0.15 3-amino-2-methylamino-6-methoxypyridine 0.04 Basic Brown 16 0.20 raw material Concentration [%] Texapon.RTM ^® NSO UP 15.3 Hydrenol ^® D 2.5 Lorol® ^® techn. 4.5 Polychol ^® 5 0.4 Dow ^Corning® 345 Fluid 0.1 Eumulgin ^® O 5 2.0 methylparaben 0.2 Propylparaben 0.2 phenoxyethanol 0.5 Polawax ^® GP 200 1.6 Procetyl ^® AWS 1.6 Polyethylene glycol MG 400 5.0 sodium 0.5 sodium bicarbonate 0.4 sodium 0.4 Synthalen ^® K 0.2 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.39 resorcinol 0.30 2,4-Diaminophenoxyethanol 1.74 HC Blue 2 0.20 raw material Concentration [%] Texapon.RTM ^® NSO UP 15.3 Hydrenol ^® D 2.5 Lorol® ^® techn. 4.5 Polychol ^® 5 0.4 Dow ^Corning® 345 Fluid 0.1 Eumulgin ^® O 5 2.0 methylparaben 0.2 Propylparaben 0.2 phenoxyethanol 0.5 Polawax ^® GP 200 1.6 Procetyl ^® AWS 1.6 Polyethylene glycol MG 400 5.0 sodium 0.5 sodium bicarbonate 0.4 sodium 0.4 Synthalen ^® K 0.2 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.73 2,4-diaminophenoxyethanol 2 HC 1.91 resorcinol 0.33 4-nitro-o-phenylenediamine 0.30

For the streak dyed with this staining cream, the following colorimetric values were determined: L value: 15.3 a-value: -1.2 b-value: -2.1

The application preparation prepared analogously to point 2.2 was additionally for determining the gray coverage on 2 different strands dyed (buffalo belly hair and alkinco, light brown).

The Application time was 30 minutes at 32 ° C. Subsequently Each strand was rinsed for one minute with lukewarm water and dried with a hair dryer.

to Determination of the gray coverage index was followed by each strand measured colorimetrically by drying. As a reference, the buffalo belly hair strand also measured colorimetrically before the coloration process.

The following gray coverage index was determined: streak L value a-value b-value Δ value Gray coverage index Buffalo belly hair, uncolored 73.4 0.1 8.2 57.1 94.9 Alkinco light brown, colored 17.0 -0.8 -0.8 2.9 Buffalo belly hair, colored 18.0 -3.2 -2.1 raw material Concentration [%] Texapon.RTM ^® NSO UP 15.3 Hydrenol ^® D 2.5 Lorol® ^® techn. 4.5 Polychol ^® 5 0.4 Dow ^Corning® 345 Fluid 0.1 Eumulgin ^® O 5 2.0 methylparaben 0.2 Propylparaben 0.2 phenoxyethanol 0.5 Polawax ^® GP 200 1.6 Procetyl ^® AWS 1.6 Polyethylene glycol MG 400 5.0 sodium 0.5 sodium bicarbonate 0.4 sodium 0.4 Synthalen ^® K 0.2 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.82 resorcinol 0.17 2,7-dihydroxynaphthalene 0.29 1,3-bis (2,4-diaminophenoxy) propan-tetrahydrochloird 0.44 Basic Violet 2 0.30

For the streak dyed with this staining cream, the following colorimetric values were determined: L value: 23.2 a-value: -5.6 b-value: 3.6 raw material Concentration [%] Texapon.RTM ^® NSO UP 15.3 Hydrenol ^® D 2.5 Lorol® ^® techn. 4.5 Polychol ^® 5 0.4 Dow ^Corning® 345 Fluid 0.1 Eumulgin ^® O 5 2.0 methylparaben 0.2 Propylparaben 0.2 phenoxyethanol 0.5 Polawax ^® GP 200 1.6 Procetyl ^® AWS 1.6 Polyethylene glycol MG 400 5.0 sodium 0.5 sodium bicarbonate 0.4 sodium 0.4 Synthalen ^® K 0.2 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.36 resorcinol 0.24 m-aminophenol 0.12 o-aminophenol 0.16 2,6-diaminopyridine 0.55 HC Red 3 0.20 raw material Concentration [%] Texapon.RTM ^® NSO UP 15.3 Hydrenol ^® D 2.5 Lorol® ^® techn. 4.5 Polychol ^® 5 0.4 Dow ^Corning® 345 Fluid 0.1 Eumulgin ^® O 5 2.0 methylparaben 0.2 Propylparaben 0.2 phenoxyethanol 0.5 Polawax ^® GP 200 1.6 Procetyl ^® AWS 1.6 Polyethylene glycol MG 400 5.0 sodium 0.5 sodium bicarbonate 0.4 sodium 0.4 Synthalen ^® K 0.2 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.31 4,4'-diaminodiphenylamine sulfate 0.04 resorcinol 0.08 m-aminophenol 0.06 N, N'-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine 0.20 raw material Concentration [%] Texapon.RTM ^® NSO UP 15.3 Hydrenol ^® D 2.5 Lorol® ^® techn. 4.5 Polychol ^® 5 0.4 Dow ^Corning® 345 Fluid 0.1 Eumulgin ^® O 5 2.0 methylparaben 0.2 Propylparaben 0.2 phenoxyethanol 0.5 Polawax ^® GP 200 1.6 Procetyl ^® AWS 1.6 Polyethylene glycol MG 400 5.0 sodium 0.5 sodium bicarbonate 0.4 sodium 0.4 Synthalen ^® K 0.2 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.16 resorcinol 0.51 m-aminophenol 0.12 2-amino-4-Hydroxyethylaminoanisolsulfat 0.18 HC Red 13 0.30 raw material Concentration [%] Texapon.RTM ^® NSO UP 15.3 Hydrenol ^® D 2.5 Lorol® ^® techn. 4.5 Polychol ^® 5 0.4 Dow ^Corning® 345 Fluid 0.1 Eumulgin ^® O 5 2.0 methylparaben 0.2 Propylparaben 0.2 phenoxyethanol 0.5 Polawax ^® GP 200 1.6 Procetyl ^® AWS 1.6 Polyethylene glycol MG 400 5.0 sodium 0.5 sodium bicarbonate 0.4 sodium 0.4 Synthalen ^® K 0.2 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.55 m-aminophenol 0.22 2-amino-4-Hydroxyethylaminoanisolsulfat 0.04 4-chlororesorcinol 0.78 HC Yellow 2 0.15 HC Orange 1 0.25 raw material Concentration [%] Texapon.RTM ^® NSO UP 15.3 Hydrenol ^® D 2.5 Lorol® ^® techn. 4.5 Polychol ^® 5 0.4 Dow ^Corning® 345 Fluid 0.1 Eumulgin ^® O 5 2.0 methylparaben 0.2 Propylparaben 0.2 phenoxyethanol 0.5 Polawax ^® GP 200 1.6 Procetyl ^® AWS 1.6 Polyethylene glycol MG 400 5.0 sodium 0.5 sodium bicarbonate 0.4 sodium 0.4 Synthalen ^® K 0.2 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.93 4,5-diamino-1- (2-hydroxyethyl) -1H-pyrazol-sulfate 0.93 2,4-diaminophenoxyethanol dihydrochloride 0.58 resorcinol 0.56 m-aminophenol 0.09 5-amino-2-methylphenol 0.39 Hydroxyethyl-2-nitro-p-toluidine 0.3 raw material Concentration [%] Texapon.RTM ^® NSO UP 15.3 Hydrenol ^® D 2.5 Lorol® ^® techn. 4.5 Polychol ^® 5 0.4 Dow ^Corning® 345 Fluid 0.1 Eumulgin ^® O 5 2.0 methylparaben 0.2 Propylparaben 0.2 phenoxyethanol 0.5 Polawax ^® GP 200 1.6 Procetyl ^® AWS 1.6 Polyethylene glycol MG 400 5.0 sodium 0.5 sodium bicarbonate 0.4 sodium 0.4 Synthalen ^® K 0.2 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.39 2,4-diaminophenoxyethanol dihydrochloride 1.74 resorcinol 0.3 Basic Blue 99 0.3 raw material Concentration [%] Texapon.RTM ^® NSO UP 15.3 Hydrenol ^® D 2.5 Lorol® ^® techn. 4.5 Polychol ^® 5 0.4 Dow ^Corning® 345 Fluid 0.1 Eumulgin ^® O 5 2.0 methylparaben 0.2 Propylparaben 0.2 phenoxyethanol 0.5 Polawax ^® GP 200 1.6 Procetyl ^® AWS 1.6 Polyethylene glycol MG 400 5.0 sodium 0.5 sodium bicarbonate 0.4 sodium 0.4 Synthalen ^® K 0.2 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.73 resorcinol 0.3 m-aminophenol 0.19 3-amino-2-methylamino-6-methoxypyridine 0.01 2,6-dihydroxy-3,4-dimethylpyridine 0.12 HC Yellow 13 0.2 Basic Brown 17 0 raw material Concentration [%] Texapon.RTM ^® NSO UP 15.3 Hydrenol ^® D 2.5 Lorol® ^® techn. 4.5 Polychol ^® 5 0.4 Dow ^Corning® 345 Fluid 0.1 Eumulgin ^® O 5 2.0 methylparaben 0.2 Propylparaben 0.2 phenoxyethanol 0.5 Polawax ^® GP 200 1.6 Procetyl ^® AWS 1.6 Polyethylene glycol MG 400 5.0 sodium 0.5 sodium bicarbonate 0.4 sodium 0.4 Synthalen ^® K 0.2 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.67 resorcinol 0.27 3-amino-2-methylamino-6-methoxypyridine 0.06 4-chlororesorcinol 0.37 1,3-bis (2,4-diaminophenoxy) propane 4HCl 0.2 Basic Red 76 0.2 Basic Brown 17 0.05 raw material Concentration [%] Texapon.RTM ^® NSO UP 15.3 Hydrenol ^® D 2.5 Lorol® ^® techn. 4.5 Polychol ^® 5 0.4 Dow ^Corning® 345 Fluid 0.1 Eumulgin ^® O 5 2.0 methylparaben 0.2 Propylparaben 0.2 phenoxyethanol 0.5 Polawax ^® GP 200 1.6 Procetyl ^® AWS 1.6 Polyethylene glycol MG 400 5.0 sodium 0.5 sodium bicarbonate 0.4 sodium 0.4 Synthalen ^® K 0.2 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.31 4-chlororesorcinol 0.04 resorcinol 0.05 3-Amino-2-chloro-6-methylphenol 0.01 3-amino-2-methylamino-6-methoxypyridine 0.03 Basic Yellow 57 0.08 raw material Concentration [%] Texapon.RTM ^® NSO UP 15.3 Hydrenol ^® D 2.5 Lorol® ^® techn. 4.5 Polychol ^® 5 0.4 Dow ^Corning® 345 Fluid 0.1 Eumulgin ^® O 5 2.0 methylparaben 0.2 Propylparaben 0.2 phenoxyethanol 0.5 Polawax ^® GP 200 1.6 Procetyl ^® AWS 1.6 Polyethylene glycol MG 400 5.0 sodium 0.5 sodium bicarbonate 0.4 sodium 0.4 Synthalen ^® K 0.2 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.71 2,4,5,6-tetra-sulfate 0.23 resorcinol 0.11 2-methyl 0.11 2,7-dihydroxynaphthalene 0.2 HC Red 1 0.2 raw material Concentration [%] Texapon.RTM ^® NSO UP 15.3 Hydrenol ^® D 2.5 Lorol® ^® techn. 4.5 Polychol ^® 5 0.4 Dow ^Corning® 345 Fluid 0.1 Eumulgin ^® O 5 2.0 methylparaben 0.2 Propylparaben 0.2 phenoxyethanol 0.5 Polawax ^® GP 200 1.6 Procetyl ^® AWS 1.6 Polyethylene glycol MG 400 5.0 sodium 0.5 sodium bicarbonate 0.4 sodium 0.4 Synthalen ^® K 0.2 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.67 m-aminophenol 0.12 resorcinol 0.39 2-methyl 0.05 2-amino-3-hydroxypyridine 0.06 HC Blue 12 0.08 raw material Concentration [%] Texapon.RTM ^® NSO UP 15.3 Hydrenol ^® D 2.5 Lorol® ^® techn. 4.5 Polychol ^® 5 0.4 Dow ^Corning® 345 Fluid 0.1 Eumulgin ^® O 5 2.0 methylparaben 0.2 Propylparaben 0.2 phenoxyethanol 0.5 Polawax ^® GP 200 1.6 Procetyl ^® AWS 1.6 Polyethylene glycol MG 400 5.0 sodium 0.5 sodium bicarbonate 0.4 sodium 0.4 Synthalen ^® K 0.2 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.12 2-methyl 0.28 4-chlororesorcinol 0.13 3-amino-2-methylamino-6-methoxypyridine 0.01 Acid Violet 43 0.2 raw material Concentration [%] Texapon.RTM ^® NSO UP 15.3 Hydrenol ^® D 2.5 Lorol® ^® techn. 4.5 Polychol ^® 5 0.4 Dow ^Corning® 345 Fluid 0.1 Eumulgin ^® O 5 2.0 methylparaben 0.2 Propylparaben 0.2 phenoxyethanol 0.5 Polawax ^® GP 200 1.6 Procetyl ^® AWS 1.6 Polyethylene glycol MG 400 5.0 sodium 0.5 sodium bicarbonate 0.4 sodium 0.4 Synthalen ^® K 0.2 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.4437 2,4,5,6-tetra-sulfate .7741 m-aminophenol .4200 2-amino-3-hydroxypyridine .1650 4-chlororesorcinol .2400

3.2 colorations

The colorants mentioned under point 3.1 were each immediately before the coloration in the ratio 1 part by weight cream: 1 part by weight Developer mixed with the following composition: raw material Concentration [% by weight] disodiumpyrophosphate 0.3 Disodium EDTA 0.2 Na benzoate 0.04 Emulgade® ^® F 2.1 Phosphoric acid 85% 0.04 Hydrogen peroxide 50% 12.2 Perfume 0.1 water ad 100

The resulting application mixtures were each dyed to 6 cm long strands (Kerling, 80% mottled). The duration of use was 30 minutes at 32 ° C. Then each tress was rinsed for one minute with lukewarm water and dried with a hair dryer. 4 Colorant base D 4.1 Formulations raw material Concentration [%] Hydrenol ^® D 6.6 Lorol® ^® techn 2.4 Cutina ^® GMS 1.5 Eumulgin ^® B1 0.6 Eumulgin ^® B2 0.6 Lamesoft ^® PO 65 2.0 Akypo Soft 45 NV ^® 10.0 Eumulgin ^® KE 2602 0.5 Texapon.RTM ^® K14 S70 2.8 ammonium sulfate 0.2 sodium 0.4 ascorbic acid 0.2 EDTA 0.4 Plantacare® ^® 2000 0.5 Luviquat ^® Care 0.7 Antil ^® 141 0.2 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Ammonia, 25% ad pH 10 water ad 100.00 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.88 p-aminophenol hydrochloride 0.52 resorcinol 0.43 m-aminophenol 0.8 5-amino-2-methylphenol 0.18 Disperse Violet 1 0.2 raw material Concentration [%] Hydrenol ^® D 6.6 Lorol® ^® techn 2.4 Cutina ^® GMS 1.5 Eumulgin ^® B1 0.6 Eumulgin ^® B2 0.6 Lamesoft ^® PO 65 2.0 Akypo Soft 45 NV ^® 10.0 Eumulgin ^® KE 2602 0.5 Texapon.RTM ^® K14 S70 2.8 ammonium sulfate 0.2 sodium 0.4 ascorbic acid 0.2 EDTA 0.4 Plantacare® ^® 2000 0.5 Luviquat ^® Care 0.7 Antil ^® 141 0.2 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Ammonia, 25% ad pH 10 water ad 100.00 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.38 resorcinol 0.13 m-aminophenol 0.07 5-amino-2-methylphenol 0.22 3-Amino-2-chloro-6-methylphenol 0.07 2,7-dihydroxynaphthalene 0.08 1,5-dihydroxynaphthalene 0.05 1-phenyl-3-methyl-5-pyrazolone 0.1 HC Red 7 0.2 raw material Concentration [%] Hydrenol ^® D 6.6 Lorol® ^® techn 2.4 Cutina ^® GMS 1.5 Eumulgin ^® B1 0.6 Eumulgin ^® B2 0.6 Lamesoft ^® PO 65 2.0 Akypo Soft 45 NV ^® 10.0 Eumulgin ^® KE 2602 0.5 Texapon.RTM ^® K14 S70 2.8 ammonium sulfate 0.2 sodium 0.4 ascorbic acid 0.2 EDTA 0.4 Plantacare® ^® 2000 0.5 Luviquat ^® Care 0.7 Antil ^® 141 0.2 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Ammonia, 25% ad pH 10 water ad 100.00 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.21 resorcinol 0.55 m-aminophenol 0.15 3-amino-2-methylamino-6-methoxypyridine 0.04 Basic Brown 16 0.20 raw material Concentration [%] Hydrenol ^® D 6.6 Lorol® ^® techn 2.4 Cutina ^® GMS 1.5 Eumulgin ^® B1 0.6 Eumulgin ^® B2 0.6 Lamesoft ^® PO 65 2.0 Akypo Soft 45 NV ^® 10.0 Eumulgin ^® KE 2602 0.5 Texapon.RTM ^® K14 S70 2.8 ammonium sulfate 0.2 sodium 0.4 ascorbic acid 0.2 EDTA 0.4 Plantacare® ^® 2000 0.5 Luviquat ^® Care 0.7 Antil ^® 141 0.2 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Ammonia, 25% ad pH 10 water ad 100.00 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.39 resorcinol 0.30 2,4-Diaminophenoxyethanol 1.74 HC Blue 2 0.20 raw material Concentration [%] Hydrenol ^® D 6.6 Lorol® ^® techn 2.4 Cutina ^® GMS 1.5 Eumulgin ^® B1 0.6 Eumulgin ^® B2 0.6 Lamesoft ^® PO 65 2.0 Akypo Soft 45 NV ^® 10.0 Eumulgin ^® KE 2602 0.5 Texapon.RTM ^® K14 S70 2.8 ammonium sulfate 0.2 sodium 0.4 ascorbic acid 0.2 EDTA 0.4 Plantacare® ^® 2000 0.5 Luviquat ^® Care 0.7 Antil ^® 141 0.2 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Ammonia, 25% ad pH 10 water ad 100.00 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.73 2,4-diaminophenoxyethanol 2 HC 1.91 resorcinol 0.33 4-nitro-o-phenylenediamine 0.30 raw material Concentration [%] Hydrenol ^® D 6.6 Lorol® ^® techn 2.4 Cutina ^® GMS 1.5 Eumulgin ^® B1 0.6 Eumulgin ^® B2 0.6 Lamesoft ^® PO 65 2.0 Akypo Soft 45 NV ^® 10.0 Eumulgin ^® KE 2602 0.5 Texapon.RTM ^® K14 S70 2.8 ammonium sulfate 0.2 sodium 0.4 ascorbic acid 0.2 EDTA 0.4 Plantacare® ^® 2000 0.5 Luviquat ^® Care 0.7 Antil ^® 141 0.2 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Ammonia, 25% ad pH 10 water ad 100.00 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.82 resorcinol 0.17 2,7-dihydroxynaphthalene 0.29 1,3-bis (2,4-diaminophenoxy) propan-tetrahydrochloird 0.44 Basic Violet 2 0.30 raw material Concentration [%] Hydrenol ^® D 6.6 Lorol® ^® techn 2.4 Cutina ^® GMS 1.5 Eumulgin ^® B1 0.6 Eumulgin ^® B2 0.6 Lamesoft ^® PO 65 2.0 Akypo Soft 45 NV ^® 10.0 Eumulgin ^® KE 2602 0.5 Texapon.RTM ^® K14 S70 2.8 ammonium sulfate 0.2 sodium 0.4 ascorbic acid 0.2 EDTA 0.4 Plantacare® ^® 2000 0.5 Luviquat ^® Care 0.7 Antil ^® 141 0.2 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Ammonia, 25% ad pH 10 water ad 100.00 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.36 resorcinol 0.24 m-aminophenol 0.12 o-aminophenol 0.16 2,6-diaminopyridine 0.55 HC Red 3 0.20

For the streak dyed with this staining cream, the following colorimetric values were determined: L value: 34.9 a-value: 6.4 b-value: 3.7 raw material Concentration [%] Hydrenol ^® D 6.6 Lorol® ^® techn 2.4 Cutina ^® GMS 1.5 Eumulgin ^® B1 0.6 Eumulgin ^® B2 0.6 Lamesoft ^® PO 65 2.0 Akypo Soft 45 NV ^® 10.0 Eumulgin ^® KE 2602 0.5 Texapon.RTM ^® K14 S70 2.8 ammonium sulfate 0.2 sodium 0.4 ascorbic acid 0.2 EDTA 0.4 Plantacare® ^® 2000 0.5 Luviquat ^® Care 0.7 Antil ^® 141 0.2 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Ammonia, 25% ad pH 10 water ad 100.00 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.31 4,4'-diaminodiphenylamine sulfate 0.04 resorcinol 0.08 m-aminophenol 0.06 N, N'-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine 0.20

For the streak dyed with this staining cream, the following colorimetric values were determined: L value: 37.0 a-value: 6.3 b-value: 4.1 raw material Concentration [%] Hydrenol ^® D 6.6 Lorol® ^® techn 2.4 Cutina ^® GMS 1.5 Eumulgin ^® B1 0.6 Eumulgin ^® B2 0.6 Lamesoft ^® PO 65 2.0 Akypo Soft 45 NV ^® 10.0 Eumulgin ^® KE 2602 0.5 Texapon.RTM ^® K14 S70 2.8 ammonium sulfate 0.2 sodium 0.4 ascorbic acid 0.2 EDTA 0.4 Plantacare® ^® 2000 0.5 Luviquat ^® Care 0.7 Antil ^® 141 0.2 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Ammonia, 25% ad pH 10 water ad 100.00 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.16 resorcinol 0.51 m-aminophenol 0.12 2-amino-4-Hydroxyethylaminoanisolsulfat 0.18 HC Red 13 0.30 raw material Concentration [%] Hydrenol ^® D 6.6 Lorol® ^® techn 2.4 Cutina ^® GMS 1.5 Eumulgin ^® B1 0.6 Eumulgin ^® B2 0.6 Lamesoft ^® PO 65 2.0 Akypo Soft 45 NV ^® 10.0 Eumulgin ^® KE 2602 0.5 Texapon.RTM ^® K14 S70 2.8 ammonium sulfate 0.2 sodium 0.4 ascorbic acid 0.2 EDTA 0.4 Plantacare® ^® 2000 0.5 Luviquat ^® Care 0.7 Antil ^® 141 0.2 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Ammonia, 25% ad pH 10 water ad 100.00 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.55 m-aminophenol 0.22 2-amino-4-Hydroxyethylaminoanisolsulfat 0.04 4-chlororesorcinol 0.78 HC Yellow 2 0.15 HC Orange 1 0.25 raw material Concentration [%] Hydrenol ^® D 6.6 Lorol® ^® techn 2.4 Cutina ^® GMS 1.5 Eumulgin ^® B1 0.6 Eumulgin ^® B2 0.6 Lamesoft ^® PO 65 2.0 Akypo Soft 45 NV ^® 10.0 Eumulgin ^® KE 2602 0.5 Texapon.RTM ^® K14 S70 2.8 ammonium sulfate 0.2 sodium 0.4 ascorbic acid 0.2 EDTA 0.4 Plantacare® ^® 2000 0.5 Luviquat ^® Care 0.7 Antil ^® 141 0.2 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Ammonia, 25% ad pH 10 water ad 100.00 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.93 4,5-diamino-1- (2-hydroxyethyl) -1H-pyrazol-sulfate 0.93 2,4-diaminophenoxyethanol dihydrochloride 0.58 resorcinol 0.56 m-aminophenol 0.09 5-amino-2-methylphenol 0.39 Hydroxyethyl-2-nitro-p-toluidine 0.3 raw material Concentration [%] Hydrenol ^® D 6.6 Lorol® ^® techn 2.4 Cutina ^® GMS 1.5 Eumulgin ^® B1 0.6 Eumulgin ^® B2 0.6 Lamesoft ^® PO 65 2.0 Akypo Soft 45 NV ^® 10.0 Eumulgin ^® KE 2602 0.5 Texapon.RTM ^® K14 S70 2.8 ammonium sulfate 0.2 sodium 0.4 ascorbic acid 0.2 EDTA 0.4 Plantacare® ^® 2000 0.5 Luviquat ^® Care 0.7 Antil ^® 141 0.2 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Ammonia, 25% ad pH 10 water ad 100.00 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.39 2,4-diaminophenoxyethanol dihydrochloride 1.74 resorcinol 0.3 Basic Blue 99 0.3 raw material Concentration [%] Hydrenol ^® D 6.6 Lorol® ^® techn 2.4 Cutina ^® GMS 1.5 Eumulgin ^® B1 0.6 Eumulgin ^® B2 0.6 Lamesoft ^® PO 65 2.0 Akypo Soft 45 NV ^® 10.0 Eumulgin ^® KE 2602 0.5 Texapon.RTM ^® K14 S70 2.8 ammonium sulfate 0.2 sodium 0.4 ascorbic acid 0.2 EDTA 0.4 Plantacare® ^® 2000 0.5 Luviquat ^® Care 0.7 Antil ^® 141 0.2 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Ammonia, 25% ad pH 10 water ad 100.00 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.73 resorcinol 0.3 m-aminophenol 0.19 3-amino-2-methylamino-6-methoxypyridine 0.01 2,6-dihydroxy-3,4-dimethylpyridine 0.12 HC Yellow 13 0.2 Basic Brown 17 0 raw material Concentration [%] Hydrenol ^® D 6.6 Lorol® ^® techn 2.4 Cutina ^® GMS 1.5 Eumulgin ^® B1 0.6 Eumulgin ^® B2 0.6 Lamesoft ^® PO 65 2.0 Akypo Soft 45 NV ^® 10.0 Eumulgin ^® KE 2602 0.5 Texapon.RTM ^® K14 S70 2.8 ammonium sulfate 0.2 sodium 0.4 ascorbic acid 0.2 EDTA 0.4 Plantacare® ^® 2000 0.5 Luviquat ^® Care 0.7 Antil ^® 141 0.2 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Ammonia, 25% ad pH 10 water ad 100.00 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.67 resorcinol 0.27 3-amino-2-methylamino-6-methoxypyridine 0.06 4-chlororesorcinol 0.37 1,3-bis (2,4-diaminophenoxy) propane 4HCl 0.2 Basic Red 76 0.2 Basic Brown 17 0.05 raw material Concentration [%] Hydrenol ^® D 6.6 Lorol® ^® techn 2.4 Cutina ^® GMS 1.5 Eumulgin ^® B1 0.6 Eumulgin ^® B2 0.6 Lamesoft ^® PO 65 2.0 Akypo Soft 45 NV ^® 10.0 Eumulgin ^® KE 2602 0.5 Texapon.RTM ^® K14 S70 2.8 ammonium sulfate 0.2 sodium 0.4 ascorbic acid 0.2 EDTA 0.4 Plantacare® ^® 2000 0.5 Luviquat ^® Care 0.7 Antil ^® 141 0.2 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Ammonia, 25% ad pH 10 water ad 100.00 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.31 4-chlororesorcinol 0.04 resorcinol 0.05 3-Amino-2-chloro-6-methylphenol 0.01 3-amino-2-methylamino-6-methoxypyridine 0.03 Basic Yellow 57 0.08 raw material Concentration [%] Hydrenol ^® D 6.6 Lorol® ^® techn 2.4 Cutina ^® GMS 1.5 Eumulgin ^® B1 0.6 Eumulgin ^® B2 0.6 Lamesoft ^® PO 65 2.0 Akypo Soft 45 NV ^® 10.0 Eumulgin ^® KE 2602 0.5 Texapon.RTM ^® K14 S70 2.8 ammonium sulfate 0.2 sodium 0.4 ascorbic acid 0.2 EDTA 0.4 Plantacare® ^® 2000 0.5 Luviquat ^® Care 0.7 Antil ^® 141 0.2 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Ammonia, 25% ad pH 10 water ad 100.00 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.71 2,4,5,6-tetra-sulfate 0.23 resorcinol 0.11 2-methyl 0.11 2,7-dihydroxynaphthalene 0.2 HC Red 1 0.2 raw material Concentration [%] Hydrenol ^® D 6.6 Lorol® ^® techn 2.4 Cutina ^® GMS 1.5 Eumulgin ^® B1 0.6 Eumulgin ^® B2 0.6 Lamesoft ^® PO 65 2.0 Akypo Soft 45 NV ^® 10.0 Eumulgin ^® KE 2602 0.5 Texapon.RTM ^® K14 S70 2.8 ammonium sulfate 0.2 sodium 0.4 ascorbic acid 0.2 EDTA 0.4 Plantacare® ^® 2000 0.5 Luviquat ^® Care 0.7 Antil ^® 141 0.2 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Ammonia, 25% ad pH 10 water ad 100.00 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.67 m-aminophenol 0.12 resorcinol 0.39 2-methyl 0.05 2-amino-3-hydroxypyridine 0.06 HC Blue 12 0.08 raw material Concentration [%] Hydrenol ^® D 6.6 Lorol® ^® techn 2.4 Cutina ^® GMS 1.5 Eumulgin ^® B1 0.6 Eumulgin ^® B2 0.6 Lamesoft ^® PO 65 2.0 Akypo Soft 45 NV ^® 10.0 Eumulgin ^® KE 2602 0.5 Texapon.RTM ^® K14 S70 2.8 ammonium sulfate 0.2 sodium 0.4 ascorbic acid 0.2 EDTA 0.4 Plantacare® ^® 2000 0.5 Luviquat ^® Care 0.7 Antil ^® 141 0.2 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Ammonia, 25% ad pH 10 water ad 100.00 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.12 2-methyl 0.28 4-chlororesorcinol 0.13 3-amino-2-methylamino-6-methoxypyridine 0.01 Acid Violet 43 0.2 raw material Concentration [%] Hydrenol ^® D 6.6 Lorol® ^® techn 2.4 Cutina ^® GMS 1.5 Eumulgin ^® B1 0.6 Eumulgin ^® B2 0.6 Lamesoft ^® PO 65 2.0 Akypo Soft 45 NV ^® 10.0 Eumulgin ^® KE 2602 0.5 Texapon.RTM ^® K14 S70 2.8 ammonium sulfate 0.2 sodium 0.4 ascorbic acid 0.2 EDTA 0.4 Plantacare® ^® 2000 0.5 Luviquat ^® Care 0.7 Antil ^® 141 0.2 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Ammonia, 25% ad pH 10 water ad 100.00 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.4437 2,4,5,6-tetra-sulfate .7741 m-aminophenol .4200 2-amino-3-hydroxypyridine .1650 4-chlororesorcinol .2400

4.2 colorations

The colorants mentioned under point 4.1 were each immediately before the coloration in the ratio 1 part by weight cream: 1 part by weight Developer mixed with the following composition: raw material Concentration [% by weight] Ammonia 25% 0.7 dipicolinic 0.1 disodiumpyrophosphate 0.03 Turpinal® ^® SL 1.5 FAEOS-Na C12-14 2EO 27% 2.0 Dow ^Corning® DB 110 0.1 Aculyn ^® 33 15.0 Hydrogen peroxide 50% 12.0 water ad 100

The resulting application mixtures were each dyed to 6 cm long strands (Kerling, 80% mottled). The duration of use was 30 minutes at 32 ° C. Then each tress was rinsed for one minute with lukewarm water and dried with a hair dryer. 5 Colorant base E 5.1 Formulations raw material Concentration [%] Texapon.RTM ^® NSO UP 10.0 Lorol® ^® techn. 5.0 Emulgade® ^® 1000 NI 3.0 Cetiol ^® HE 2.0 Dow ^Corning® 580 Wax 1.0 Elfacos ^® ST 37 2.0 methylparaben 0.4 Propylparaben 0.3 1,2-propanediol 7.5 Carbopol Ultrez ^® 10 0.1 AMP- ^Ultra® PC 2000 0.1 Water, demineralized 20.0 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 sodium benzoate 0.2 diglycol 0.5 Luviquat Mono CP ^® 0.8 Ammonia, 25% ad pH 9.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.88 p-aminophenol hydrochloride 0.52 resorcinol 0.43 m-aminophenol 0.8 5-amino-2-methylphenol 0.18 Disperse Violet 1 0.2 raw material Concentration [%] Texapon.RTM ^® NSO UP 10.0 Lorol® ^® techn. 5.0 Emulgade® ^® 1000 NI 3.0 Cetiol ^® HE 2.0 Dow ^Corning® 580 Wax 1.0 Elfacos ^® ST 37 2.0 methylparaben 0.4 Propylparaben 0.3 1,2-propanediol 7.5 Carbopol Ultrez ^® 10 0.1 AMP- ^Ultra® PC 2000 0.1 Water, demineralized 20.0 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 sodium benzoate 0.2 diglycol 0.5 Luviquat Mono CP ^® 0.8 Ammonia, 25% ad pH 9.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.38 resorcinol 0.13 m-aminophenol 0.07 5-amino-2-methylphenol 0.22 3-Amino-2-chloro-6-methylphenol 0.07 2,7-dihydroxynaphthalene 0.08 1,5-dihydroxynaphthalene 0.05 1-phenyl-3-methyl-5-pyrazolone 0.1 HC Red 7 0.2 raw material Concentration [%] Texapon.RTM ^® NSO UP 10.0 Lorol® ^® techn. 5.0 Emulgade® ^® 1000 NI 3.0 Cetiol ^® HE 2.0 Dow ^Corning® 580 Wax 1.0 Elfacos ^® ST 37 2.0 methylparaben 0.4 Propylparaben 0.3 1,2-propanediol 7.5 Carbopol Ultrez ^® 10 0.1 AMP- ^Ultra® PC 2000 0.1 Water, demineralized 20.0 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 sodium benzoate 0.2 diglycol 0.5 Luviquat Mono CP ^® 0.8 Ammonia, 25% ad pH 9.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.21 resorcinol 0.55 m-aminophenol 0.15 3-amino-2-methylamino-6-methoxypyridine 0.04 Basic Brown 16 0.20 raw material Concentration [%] Texapon.RTM ^® NSO UP 10.0 Lorol® ^® techn. 5.0 Emulgade® ^® 1000 NI 3.0 Cetiol ^® HE 2.0 Dow ^Corning® 580 Wax 1.0 Elfacos ^® ST 37 2.0 methylparaben 0.4 Propylparaben 0.3 1,2-propanediol 7.5 Carbopol Ultrez ^® 10 0.1 AMP- ^Ultra® PC 2000 0.1 Water, demineralized 20.0 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 sodium benzoate 0.2 diglycol 0.5 Luviquat Mono CP ^® 0.8 Ammonia, 25% ad pH 9.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.39 resorcinol 0.30 2,4-Diaminophenoxyethanol 1.74 HC Blue 2 0.20 raw material Concentration [%] Texapon.RTM ^® NSO UP 10.0 Lorol® ^® techn. 5.0 Emulgade® ^® 1000 NI 3.0 Cetiol ^® HE 2.0 Dow ^Corning® 580 Wax 1.0 Elfacos ^® ST 37 2.0 methylparaben 0.4 Propylparaben 0.3 1,2-propanediol 7.5 Carbopol Ultrez ^® 10 0.1 AMP- ^Ultra® PC 2000 0.1 Water, demineralized 20.0 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 sodium benzoate 0.2 diglycol 0.5 Luviquat Mono CP ^® 0.8 Ammonia, 25% ad pH 9.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.73 2,4-diaminophenoxyethanol 2 HC 1.91 resorcinol 0.33 4-nitro-o-phenylenediamine 0.30 raw material Concentration [%] Texapon.RTM ^® NSO UP 10.0 Lorol® ^® techn. 5.0 Emulgade® ^® 1000 NI 3.0 Cetiol ^® HE 2.0 Dow ^Corning® 580 Wax 1.0 Elfacos ^® ST 37 2.0 methylparaben 0.4 Propylparaben 0.3 1,2-propanediol 7.5 Carbopol Ultrez ^® 10 0.1 AMP- ^Ultra® PC 2000 0.1 Water, demineralized 20.0 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 sodium benzoate 0.2 diglycol 0.5 Luviquat Mono CP ^® 0.8 Ammonia, 25% ad pH 9.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.82 resorcinol 0.17 2,7-dihydroxynaphthalene 0.29 1,3-bis (2,4-diaminophenoxy) propan-tetrahydrochloird 0.44 Basic Violet 2 0.30 raw material Concentration [%] Texapon.RTM ^® NSO UP 10.0 Lorol® ^® techn. 5.0 Emulgade® ^® 1000 NI 3.0 Cetiol ^® HE 2.0 Dow ^Corning® 580 Wax 1.0 Elfacos ^® ST 37 2.0 methylparaben 0.4 Propylparaben 0.3 1,2-propanediol 7.5 Carbopol Ultrez ^® 10 0.1 AMP- ^Ultra® PC 2000 0.1 Water, demineralized 20.0 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 sodium benzoate 0.2 diglycol 0.5 Luviquat Mono CP ^® 0.8 Ammonia, 25% ad pH 9.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.36 resorcinol 0.24 m-aminophenol 0.12 o-aminophenol 0.16 2,6-diaminopyridine 0.55 HC Red 3 0.20 raw material Concentration [%] Texapon.RTM ^® NSO UP 10.0 Lorol® ^® techn. 5.0 Emulgade® ^® 1000 NI 3.0 Cetiol ^® HE 2.0 Dow ^Corning® 580 Wax 1.0 Elfacos ^® ST 37 2.0 methylparaben 0.4 Propylparaben 0.3 1,2-propanediol 7.5 Carbopol Ultrez ^® 10 0.1 AMP- ^Ultra® PC 2000 0.1 Water, demineralized 20.0 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 sodium benzoate 0.2 diglycol 0.5 Luviquat Mono CP ^® 0.8 Ammonia, 25% ad pH 9.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.31 4,4'-diaminodiphenylamine sulfate 0.04 resorcinol 0.08 m-aminophenol 0.06 N, N'-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine 0.20 raw material Concentration [%] Texapon.RTM ^® NSO UP 10.0 Lorol® ^® techn. 5.0 Emulgade® ^® 1000 NI 3.0 Cetiol ^® HE 2.0 Dow ^Corning® 580 Wax 1.0 Elfacos ^® ST 37 2.0 methylparaben 0.4 Propylparaben 0.3 1,2-propanediol 7.5 Carbopol Ultrez ^® 10 0.1 AMP- ^Ultra® PC 2000 0.1 Water, demineralized 20.0 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 sodium benzoate 0.2 diglycol 0.5 Luviquat Mono CP ^® 0.8 Ammonia, 25% ad pH 9.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.16 resorcinol 0.51 m-aminophenol 0.12 2-amino-4-Hydroxyethylaminoanisolsulfat 0.18 HC Red 13 0.30

For the streak dyed with this staining cream, the following colorimetric values were determined: L value: 21.1 a-value: -1.5 b-value: 2.3 raw material Concentration [%] Texapon.RTM ^® NSO UP 10.0 Lorol® ^® techn. 5.0 Emulgade® ^® 1000 NI 3.0 Cetiol ^® HE 2.0 Dow ^Corning® 580 Wax 1.0 Elfacos ^® ST 37 2.0 methylparaben 0.4 Propylparaben 0.3 1,2-propanediol 7.5 Carbopol Ultrez ^® 10 0.1 AMP- ^Ultra® PC 2000 0.1 Water, demineralized 20.0 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 sodium benzoate 0.2 diglycol 0.5 Luviquat Mono CP ^® 0.8 Ammonia, 25% ad pH 9.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.55 m-aminophenol 0.22 2-amino-4-Hydroxyethylaminoanisolsulfat 0.04 4-chlororesorcinol 0.78 HC Yellow 2 0.15 HC Orange 1 0.25

For the streak dyed with this staining cream, the following colorimetric values were determined: L value: 20.6 a-value: 1.9 b-value: 5.5 raw material Concentration [%] Texapon.RTM ^® NSO UP 10.0 Lorol® ^® techn. 5.0 Emulgade® ^® 1000 NI 3.0 Cetiol ^® HE 2.0 Dow ^Corning® 580 Wax 1.0 Elfacos ^® ST 37 2.0 methylparaben 0.4 Propylparaben 0.3 1,2-propanediol 7.5 Carbopol Ultrez ^® 10 0.1 AMP- ^Ultra® PC 2000 0.1 Water, demineralized 20.0 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 sodium benzoate 0.2 diglycol 0.5 Luviquat Mono CP ^® 0.8 Ammonia, 25% ad pH 9.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.93 4,5-diamino-1- (2-hydroxyethyl) -1H-pyrazol-sulfate 0.93 2,4-diaminophenoxyethanol dihydrochloride 0.58 resorcinol 0.56 m-aminophenol 0.09 5-amino-2-methylphenol 0.39 Hydroxyethyl-2-nitro-p-toluidine 0.3 raw material Concentration [%] Texapon.RTM ^® NSO UP 10.0 Lorol® ^® techn. 5.0 Emulgade® ^® 1000 NI 3.0 Cetiol ^® HE 2.0 Dow ^Corning® 580 Wax 1.0 Elfacos ^® ST 37 2.0 methylparaben 0.4 Propylparaben 0.3 1,2-propanediol 7.5 Carbopol Ultrez ^® 10 0.1 AMP- ^Ultra® PC 2000 0.1 Water, demineralized 20.0 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 sodium benzoate 0.2 diglycol 0.5 Luviquat Mono CP ^® 0.8 Ammonia, 25% ad pH 9.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.39 2,4-diaminophenoxyethanol dihydrochloride 1.74 resorcinol 0.3 Basic Blue 99 0.3 raw material Concentration [%] Texapon.RTM ^® NSO UP 10.0 Lorol® ^® techn. 5.0 Emulgade® ^® 1000 NI 3.0 Cetiol ^® HE 2.0 Dow ^Corning® 580 Wax 1.0 Elfacos ^® ST 37 2.0 methylparaben 0.4 Propylparaben 0.3 1,2-propanediol 7.5 Carbopol Ultrez ^® 10 0.1 AMP- ^Ultra® PC 2000 0.1 Water, demineralized 20.0 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 sodium benzoate 0.2 diglycol 0.5 Luviquat Mono CP ^® 0.8 Ammonia, 25% ad pH 9.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.73 resorcinol 0.3 m-aminophenol 0.19 3-amino-2-methylamino-6-methoxypyridine 0.01 2,6-dihydroxy-3,4-dimethylpyridine 0.12 HC Yellow 13 0.2 Basic Brown 17 0 raw material Concentration [%] Texapon.RTM ^® NSO UP 10.0 Lorol® ^® techn. 5.0 Emulgade® ^® 1000 NI 3.0 Cetiol ^® HE 2.0 Dow ^Corning® 580 Wax 1.0 Elfacos ^® ST 37 2.0 methylparaben 0.4 Propylparaben 0.3 1,2-propanediol 7.5 Carbopol Ultrez ^® 10 0.1 AMP- ^Ultra® PC 2000 0.1 Water, demineralized 20.0 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 sodium benzoate 0.2 diglycol 0.5 Luviquat Mono CP ^® 0.8 Ammonia, 25% ad pH 9.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.67 resorcinol 0.27 3-amino-2-methylamino-6-methoxypyridine 0.06 4-chlororesorcinol 0.37 1,3-bis (2,4-diaminophenoxy) propane 4HCl 0.2 Basic Red 76 0.2 Basic Brown 17 0.05 raw material Concentration [%] Texapon.RTM ^® NSO UP 10.0 Lorol® ^® techn. 5.0 Emulgade® ^® 1000 NI 3.0 Cetiol ^® HE 2.0 Dow ^Corning® 580 Wax 1.0 Elfacos ^® ST 37 2.0 methylparaben 0.4 Propylparaben 0.3 1,2-propanediol 7.5 Carbopol Ultrez ^® 10 0.1 AMP- ^Ultra® PC 2000 0.1 Water, demineralized 20.0 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 sodium benzoate 0.2 diglycol 0.5 Luviquat Mono CP ^® 0.8 Ammonia, 25% ad pH 9.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.31 4-chlororesorcinol 0.04 resorcinol 0.05 3-Amino-2-chloro-6-methylphenol 0.01 3-amino-2-methylamino-6-methoxypyridine 0.03 Basic Yellow 57 0.08 raw material Concentration [%] Texapon.RTM ^® NSO UP 10.0 Lorol® ^® techn. 5.0 Emulgade® ^® 1000 NI 3.0 Cetiol ^® HE 2.0 Dow ^Corning® 580 Wax 1.0 Elfacos ^® ST 37 2.0 methylparaben 0.4 Propylparaben 0.3 1,2-propanediol 7.5 Carbopol Ultrez ^® 10 0.1 AMP- ^Ultra® PC 2000 0.1 Water, demineralized 20.0 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 sodium benzoate 0.2 diglycol 0.5 Luviquat Mono CP ^® 0.8 Ammonia, 25% ad pH 9.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.71 2,4,5,6-tetra-sulfate 0.23 resorcinol 0.11 2-methyl 0.11 2,7-dihydroxynaphthalene 0.2 HC Red 1 0.2 raw material Concentration [%] Texapon.RTM ^® NSO UP 10.0 Lorol® ^® techn. 5.0 Emulgade® ^® 1000 NI 3.0 Cetiol ^® HE 2.0 Dow ^Corning® 580 Wax 1.0 Elfacos ^® ST 37 2.0 methylparaben 0.4 Propylparaben 0.3 1,2-propanediol 7.5 Carbopol Ultrez ^® 10 0.1 AMP- ^Ultra® PC 2000 0.1 Water, demineralized 20.0 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 sodium benzoate 0.2 diglycol 0.5 Luviquat Mono CP ^® 0.8 Ammonia, 25% ad pH 9.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.67 m-aminophenol 0.12 resorcinol 0.39 2-methyl 0.05 2-amino-3-hydroxypyridine 0.06 HC Blue 12 0.08 raw material Concentration [%] Texapon.RTM ^® NSO UP 10.0 Lorol® ^® techn. 5.0 Emulgade® ^® 1000 NI 3.0 Cetiol ^® HE 2.0 Dow ^Corning® 580 Wax 1.0 Elfacos ^® ST 37 2.0 methylparaben 0.4 Propylparaben 0.3 1,2-propanediol 7.5 Carbopol Ultrez ^® 10 0.1 AMP- ^Ultra® PC 2000 0.1 Water, demineralized 20.0 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 sodium benzoate 0.2 diglycol 0.5 Luviquat Mono CP ^® 0.8 Ammonia, 25% ad pH 9.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.12 2-methyl 0.28 4-chlororesorcinol 0.13 3-amino-2-methylamino-6-methoxypyridine 0.01 Acid Violet 43 0.2 raw material Concentration [%] Texapon.RTM ^® NSO UP 10.0 Lorol® ^® techn. 5.0 Emulgade® ^® 1000 NI 3.0 Cetiol ^® HE 2.0 Dow ^Corning® 580 Wax 1.0 Elfacos ^® ST 37 2.0 methylparaben 0.4 Propylparaben 0.3 1,2-propanediol 7.5 Carbopol Ultrez ^® 10 0.1 AMP- ^Ultra® PC 2000 0.1 Water, demineralized 20.0 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 sodium benzoate 0.2 diglycol 0.5 Luviquat Mono CP ^® 0.8 Ammonia, 25% ad pH 9.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.4437 2,4,5,6-tetra-sulfate .7741 m-aminophenol .4200 2-amino-3-hydroxypyridine .1650 4-chlororesorcinol .2400

5.2 colorations

The colorants mentioned under point 5.1 were each immediately before the coloration in the ratio 1 part by weight cream: 1 part by weight Developer mixed with the following composition: raw material Concentration [% by weight] disodiumpyrophosphate 0.3 Disodium EDTA 0.2 Na benzoate 0.04 Emulgade® ^® F 2.1 Phosphoric acid 85% 0.04 Hydrogen peroxide 50% 12.2 Perfume 0.1 water ad 100

The resulting application mixtures were each dyed to 6 cm long strands (Kerling, 80% mottled). The duration of use was 30 minutes at 32 ° C. Then each tress was rinsed for one minute with lukewarm water and dried with a hair dryer. 6 Colorant base F 6.1 Formulations raw material Concentration [%] Hydrenol ^® D 8.1 Lanette ^® 14 2.0 Lowenol ^® C 279 3.0 Cutina ^® AGS 2.0 Lorol® ^® techn. 2.8 Texapon.RTM ^® NSO 10.0 Plantapon ^® LGC 5.0 Eumulgin ^® B1 0.25 Eumulgin ^® B2 0.25 isostearic 2.0 Edenor ^® C14 0.5 Polymer W 37194 1.0 potassium hydroxide 1.2 Protelan ^® MST 35 3.0 ammonium sulfate 0.4 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Luviquat Mono CP ^® 1.5 Puricare ^® LS 9658 0.8 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.88 p-aminophenol hydrochloride 0.52 resorcinol 0.43 m-aminophenol 0.8 5-amino-2-methylphenol 0.18 Disperse Violet 1 0.2 raw material Concentration [%] Hydrenol ^® D 8.1 Lanette ^® 14 2.0 Lowenol ^® C 279 3.0 Cutina ^® AGS 2.0 Lorol® ^® techn. 2.8 Texapon.RTM ^® NSO 10.0 Plantapon ^® LGC 5.0 Eumulgin ^® B1 0.25 Eumulgin ^® B2 0.25 isostearic 2.0 Edenor ^® C14 0.5 Polymer W 37194 1.0 potassium hydroxide 1.2 Protelan ^® MST 35 3.0 ammonium sulfate 0.4 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Luviquat Mono CP ^® 1.5 Puricare ^® LS 9658 0.8 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.38 resorcinol 0.13 m-aminophenol 0.07 5-amino-2-methylphenol 0.22 3-Amino-2-chloro-6-methylphenol 0.07 2,7-dihydroxynaphthalene 0.08 1,5-dihydroxynaphthalene 0.05 1-phenyl-3-methyl-5-pyrazolone 0.1 HC Red 7 0.2 raw material Concentration [%] Hydrenol ^® D 8.1 Lanette ^® 14 2.0 Lowenol ^® C 279 3.0 Cutina ^® AGS 2.0 Lorol® ^® techn. 2.8 Texapon.RTM ^® NSO 10.0 Plantapon ^® LGC 5.0 Eumulgin ^® B1 0.25 Eumulgin ^® B2 0.25 isostearic 2.0 Edenor ^® C14 0.5 Polymer W 37194 1.0 potassium hydroxide 1.2 Protelan ^® MST 35 3.0 ammonium sulfate 0.4 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Luviquat Mono CP ^® 1.5 Puricare ^® LS 9658 0.8 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.21 resorcinol 0.55 m-aminophenol 0.15 3-amino-2-methylamino-6-methoxypyridine 0.04 Basic Brown 16 0.20 raw material Concentration [%] Hydrenol ^® D 8.1 Lanette ^® 14 2.0 Lowenol ^® C 279 3.0 Cutina ^® AGS 2.0 Lorol® ^® techn. 2.8 Texapon.RTM ^® NSO 10.0 Plantapon ^® LGC 5.0 Eumulgin ^® B1 0.25 Eumulgin ^® B2 0.25 isostearic 2.0 Edenor ^® C14 0.5 Polymer W 37194 1.0 potassium hydroxide 1.2 Protelan ^® MST 35 3.0 ammonium sulfate 0.4 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Luviquat Mono CP ^® 1.5 Puricare ^® LS 9658 0.8 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.39 resorcinol 0.30 2,4-Diaminophenoxyethanol 1.74 HC Blue 2 0.20 raw material Concentration [%] Hydrenol ^® D 8.1 Lanette ^® 14 2.0 Lowenol ^® C 279 3.0 Cutina ^® AGS 2.0 Lorol® ^® techn. 2.8 Texapon.RTM ^® NSO 10.0 Plantapon ^® LGC 5.0 Eumulgin ^® B1 0.25 Eumulgin ^® B2 0.25 isostearic 2.0 Edenor ^® C14 0.5 Polymer W 37194 1.0 potassium hydroxide 1.2 Protelan ^® MST 35 3.0 ammonium sulfate 0.4 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Luviquat Mono CP ^® 1.5 Puricare ^® LS 9658 0.8 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.73 2,4-diaminophenoxyethanol 2 HC 1.91 resorcinol 0.33 4-nitro-o-phenylenediamine 0.30 raw material Concentration [%] Hydrenol ^® D 8.1 Lanette ^® 14 2.0 Lowenol ^® C 279 3.0 Cutina ^® AGS 2.0 Lorol® ^® techn. 2.8 Texapon.RTM ^® NSO 10.0 Plantapon ^® LGC 5.0 Eumulgin ^® B1 0.25 Eumulgin ^® B2 0.25 isostearic 2.0 Edenor ^® C14 0.5 Polymer W 37194 1.0 potassium hydroxide 1.2 Protelan ^® MST 35 3.0 ammonium sulfate 0.4 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Luviquat Mono CP ^® 1.5 Puricare ^® LS 9658 0.8 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.82 resorcinol 0.17 2,7-dihydroxynaphthalene 0.29 1,3-bis (2,4-diaminophenoxy) propan-tetrahydrochloird 0.44 Basic Violet 2 0.30 raw material Concentration [%] Hydrenol ^® D 8.1 Lanette ^® 14 2.0 Lowenol ^® C 279 3.0 Cutina ^® AGS 2.0 Lorol® ^® techn. 2.8 Texapon.RTM ^® NSO 10.0 Plantapon ^® LGC 5.0 Eumulgin ^® B1 0.25 Eumulgin ^® B2 0.25 isostearic 2.0 Edenor ^® C14 0.5 Polymer W 37194 1.0 potassium hydroxide 1.2 Protelan ^® MST 35 3.0 ammonium sulfate 0.4 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Luviquat Mono CP ^® 1.5 Puricare ^® LS 9658 0.8 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.36 resorcinol 0.24 m-aminophenol 0.12 o-aminophenol 0.16 2,6-diaminopyridine 0.55 HC Red 3 0.20 raw material Concentration [%] Hydrenol ^® D 8.1 Lanette ^® 14 2.0 Lowenol ^® C 279 3.0 Cutina ^® AGS 2.0 Lorol® ^® techn. 2.8 Texapon.RTM ^® NSO 10.0 Plantapon ^® LGC 5.0 Eumulgin ^® B1 0.25 Eumulgin ^® B2 0.25 isostearic 2.0 Edenor ^® C14 0.5 Polymer W 37194 1.0 potassium hydroxide 1.2 Protelan ^® MST 35 3.0 ammonium sulfate 0.4 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Luviquat Mono CP ^® 1.5 Puricare ^® LS 9658 0.8 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.31 4,4'-diaminodiphenylamine sulfate 0.04 resorcinol 0.08 m-aminophenol 0.06 N, N'-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine 0.20 raw material Concentration [%] Hydrenol ^® D 8.1 Lanette ^® 14 2.0 Lowenol ^® C 279 3.0 Cutina ^® AGS 2.0 Lorol® ^® techn. 2.8 Texapon.RTM ^® NSO 10.0 Plantapon ^® LGC 5.0 Eumulgin ^® B1 0.25 Eumulgin ^® B2 0.25 isostearic 2.0 Edenor ^® C14 0.5 Polymer W 37194 1.0 potassium hydroxide 1.2 Protelan ^® MST 35 3.0 ammonium sulfate 0.4 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Luviquat Mono CP ^® 1.5 Puricare ^® LS 9658 0.8 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.16 resorcinol 0.51 m-aminophenol 0.12 2-amino-4-Hydroxyethylaminoanisolsulfat 0.18 HC Red 13 0.30 raw material Concentration [%] Hydrenol ^® D 8.1 Lanette ^® 14 2.0 Lowenol ^® C 279 3.0 Cutina ^® AGS 2.0 Lorol® ^® techn. 2.8 Texapon.RTM ^® NSO 10.0 Plantapon ^® LGC 5.0 Eumulgin ^® B1 0.25 Eumulgin ^® B2 0.25 isostearic 2.0 Edenor ^® C14 0.5 Polymer W 37194 1.0 potassium hydroxide 1.2 Protelan ^® MST 35 3.0 ammonium sulfate 0.4 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Luviquat Mono CP ^® 1.5 Puricare ^® LS 9658 0.8 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.55 m-aminophenol 0.22 2-amino-4-Hydroxyethylaminoanisolsulfat 0.04 4-chlororesorcinol 0.78 HC Yellow 2 0.15 HC Orange 1 0.25 raw material Concentration [%] Hydrenole ^® D 8.1 Lanette ^® 14 2.0 Lowenol ^® C 279 3.0 Cutina ^® AGS 2.0 Lorol® ^® techn. 2.8 Texapon.RTM ^® NSO 10.0 Plantapon ^® LGC 5.0 Eumulgin ^® B1 0.25 Eumulgin ^® B2 0.25 isostearic 2.0 Edenor ^® C14 0.5 Polymer W 37194 1.0 potassium hydroxide 1.2 Protelan ^® MST 35 3.0 ammonium sulfate 0.4 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Luviquat Mono CP ^® 1.5 Puricare ^® LS 9658 0.8 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.93 4,5-diamino-1- (2-hydroxyethyl) -1H-pyrazol-sulfate 0.93 2,4-diaminophenoxyethanol dihydrochloride 0.58 resorcinol 0.56 m-aminophenol 0.09 5-amino-2-methylphenol 0.39 Hydroxyethyl-2-nitro-p-toluidine 0.3

For the streak dyed with this staining cream, the following colorimetric values were determined: L value: 15.0 a-value: 1.9 b-value: 0.1

The application preparation prepared analogously to point 6.2 was additionally for determining the gray coverage on 2 different strands dyed (buffalo belly hair and alkinco, light brown). The duration of use was 30 minutes at 32 ° C. Subsequently Each strand was rinsed for one minute with lukewarm water and dried with a hair dryer.

to Determination of the gray coverage index was followed by each strand measured colorimetrically by drying. As a reference, the buffalo belly hair strand also measured colorimetrically before the coloration process.

The following gray coverage index was determined: streak L value a-value b-value Δ value Gray coverage index Buffalo belly hair, uncolored 73.5 -0.3 6.6 57.3 91.4 Alkinco light brown, colored 16.6 1.1 0.3 4.9 Buffalo belly hair, colored 18.8 5.5 0.7 raw material Concentration [%] Hydrenol ^® D 8.1 Lanette ^® 14 2.0 Lowenol ^® C 279 3.0 Cutina ^® AGS 2.0 Lorol® ^® techn. 2.8 Texapon.RTM ^® NSO 10.0 Plantapon ^® LGC 5.0 Eumulgin ^® B1 0.25 Eumulgin ^® B2 0.25 isostearic 2.0 Edenor ^® C14 0.5 Polymer W 37194 1.0 potassium hydroxide 1.2 Protelan ^® MST 35 3.0 ammonium sulfate 0.4 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Luviquat Mono CP ^® 1.5 Puricare ^® LS 9658 0.8 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.39 2,4-diaminophenoxyethanol dihydrochloride 1.74 resorcinol 0.3 Basic Blue 99 0.3

For the streak dyed with this staining cream, the following colorimetric values were determined: L value: 15.3 a-value: -0.5 b-value: -3.7

The application preparation prepared analogously to point 6.2 was additionally for determining the gray coverage on 2 different strands dyed (buffalo belly hair and alkinco, light brown).

The Application time was 30 minutes at 32 ° C. Subsequently Each strand was rinsed for one minute with lukewarm water and dried with a hair dryer.

For the determination of the gray coverage index, each strand was colorimetric after drying measure up. As a reference, the buffalo belly hair tress was also measured colorimetrically before the coloration process.

The following gray coverage index was determined: streak L value a-value b-value Δ value Gray coverage index Buffalo belly hair, uncolored 74.2 -0.4 7.7 57.7 88.6 Alkinco light brown, colored 17.1 -0.4 -0.9 6.6 Buffalo belly hair, colored 19.8 -3.5 -6.0 raw material Concentration [%] Hydrenol ^® D 8.1 Lanette ^® 14 2.0 Lowenol ^® C 279 3.0 Cutina ^® AGS 2.0 Lorol® ^® techn. 2.8 Texapon.RTM ^® NSO 10.0 Plantapon ^® LGC 5.0 Eumulgin ^® B1 0.25 Eumulgin ^® B2 0.25 isostearic 2.0 Edenor ^® C14 0.5 Polymer W 37194 1.0 potassium hydroxide 1.2 Protelan ^® MST 35 3.0 ammonium sulfate 0.4 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Luviquat Mono CP ^® 1.5 Puricare ^® LS 9658 0.8 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.73 resorcinol 0.3 m-aminophenol 0.19 3-amino-2-methylamino-6-methoxypyridine 0.01 2,6-dihydroxy-3,4-dimethylpyridine 0.12 HC Yellow 13 0.2 Basic Brown 17 0 raw material Concentration [%] Hydrenol ^® D 8.1 Lanette ^® 14 2.0 Lowenol ^® C 279 3.0 Cutina ^® AGS 2.0 Lorol® ^® techn. 2.8 Texapon.RTM ^® NSO 10.0 Plantapon ^® LGC 5.0 Eumulgin ^® B1 0.25 Eumulgin ^® B2 0.25 isostearic 2.0 Edenor ^® C14 0.5 Polymer W 37194 1.0 potassium hydroxide 1.2 Protelan ^® MST 35 3.0 ammonium sulfate 0.4 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Luviquat Mono CP ^® 1.5 Puricare ^® LS 9658 0.8 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.67 resorcinol 0.27 3-amino-2-methylamino-6-methoxypyridine 0.06 4-chlororesorcinol 0.37 1,3-bis (2,4-diaminophenoxy) propane 4HCl 0.2 Basic Red 76 0.2 Basic Brown 17 0.05 raw material Concentration [%] Hydrenol ^® D 8.1 Lanette ^® 14 2.0 Lowenol ^® C 279 3.0 Cutina ^® AGS 2.0 Lorol® ^® techn. 2.8 Texapon.RTM ^® NSO 10.0 Plantapon ^® LGC 5.0 Eumulgin ^® B1 0.25 Eumulgin ^® B2 0.25 isostearic 2.0 Edenor ^® C14 0.5 Polymer W 37194 1.0 potassium hydroxide 1.2 Protelan ^® MST 35 3.0 ammonium sulfate 0.4 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Luviquat Mono CP ^® 1.5 Puricare ^® LS 9658 0.8 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.31 4-chlororesorcinol 0.04 resorcinol 0.05 3-Amino-2-chloro-6-methylphenol 0.01 3-amino-2-methylamino-6-methoxypyridine 0.03 Basic Yellow 57 0.08 raw material Concentration [%] Hydrenol ^® D 8.1 Lanette ^® 14 2.0 Lowenol ^® C 279 3.0 Cutina ^® AGS 2.0 Lorol® ^® techn. 2.8 Texapon.RTM ^® NSO 10.0 Plantapon ^® LGC 5.0 Eumulgin ^® B1 0.25 Eumulgin ^® B2 0.25 isostearic 2.0 Edenor ^® C14 0.5 Polymer W 37194 1.0 potassium hydroxide 1.2 Protelan ^® MST 35 3.0 ammonium sulfate 0.4 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Luviquat Mono CP ^® 1.5 Puricare ^® LS 9658 0.8 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.71 2,4,5,6-tetra-sulfate 0.23 resorcinol 0.11 2-methyl 0.11 2,7-dihydroxynaphthalene 0.2 HC Red 1 0.2 raw material Concentration [%] Hydrenol ^® D 8.1 Lanette ^® 14 2.0 Lowenol ^® C 279 3.0 Cutina ^® AGS 2.0 Lorol® ^® techn. 2.8 Texapon.RTM ^® NSO 10.0 Plantapon ^® LGC 5.0 Eumulgin ^® B1 0.25 Eumulgin ^® B2 0.25 isostearic 2.0 Edenor ^® C14 0.5 Polymer W 37194 1.0 potassium hydroxide 1.2 Protelan ^® MST 35 3.0 ammonium sulfate 0.4 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Luviquat Mono CP ^® 1.5 Puricare ^® LS 9658 0.8 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.67 m-aminophenol 0.12 resorcinol 0.39 2-methyl 0.05 2-amino-3-hydroxypyridine 0.06 HC Blue 12 0.08 raw material Concentration [%] Hydrenol ^® D 8.1 Lanette ^® 14 2.0 Lowenol ^® C 279 3.0 Cutina ^® AGS 2.0 Lorol® ^® techn. 2.8 Texapon.RTM ^® NSO 10.0 Plantapon ^® LGC 5.0 Eumulgin ^® B1 0.25 Eumulgin ^® B2 0.25 isostearic 2.0 Edenor ^® C14 0.5 Polymer W 37194 1.0 potassium hydroxide 1.2 Protelan ^® MST 35 3.0 ammonium sulfate 0.4 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Luviquat Mono CP ^® 1.5 Puricare ^® LS 9658 0.8 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.12 2-methyl 0.28 4-chlororesorcinol 0.13 3-amino-2-methylamino-6-methoxypyridine 0.01 Acid Violet 43 0.2 raw material Concentration [%] Hydrenol ^® D 8.1 Lanette ^® 14 2.0 Lowenol ^® C 279 3.0 Cutina ^® AGS 2.0 Lorol® ^® techn. 2.8 Texapon.RTM ^® NSO 10.0 Plantapon ^® LGC 5.0 Eumulgin ^® B1 0.25 Eumulgin ^® B2 0.25 isostearic 2.0 Edenor ^® C14 0.5 Polymer W 37194 1.0 potassium hydroxide 1.2 Protelan ^® MST 35 3.0 ammonium sulfate 0.4 sodium 0.5 Sodium silicate 40/42 0.5 Turpinal® ^® SL 0.2 Luviquat Mono CP ^® 1.5 Puricare ^® LS 9658 0.8 Ammonia, 25% ad pH 10 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.4437 2,4,5,6-tetra-sulfate .7741 m-aminophenol .4200 2-amino-3-hydroxypyridine .1650 4-chlororesorcinol .2400

6.2 colorations

The colorants mentioned under point 6.1 were each immediately before the coloration in the ratio 1 part by weight cream: 1 part by weight Developer mixed with the following composition: raw material Concentration [% by weight] Ammonia 25% 0.6 dipicolinic 0.1 disodiumpyrophosphate 0.03 Turpinal® ^® SL 1.5 FAEOS-Na C12-14 2EO 27% 2.0 Dow ^Corning® DB 110 0.1 Aculyn ^® 33 12.0 Hydrogen peroxide, 50% 12.0 water ad 100

The resulting application mixtures were each dyed to 6 cm long strands (Kerling, 80% mottled). The duration of use was 30 minutes at 32 ° C. Then each tress was rinsed for one minute with lukewarm water and dried with a hair dryer. 7 Colorant base G 7.1 Formulations raw material Concentration [%] Ammoniumcarbomer soln. 1.0% 8.9 Ammoniumrohagit soln. 6% 1.9 Eumulgin ^® KE 2602 2.2 Potassium salt soap (12.5% in water) 22.5 Titanium dioxide ^Kronos® 1171 0.8 Cetiol ^® V 2.3 Lorol C 16 ^® 13.3 Emulgade® ^® F 1.1 Eumulgin ^® B3 0.8 Lowenol ^® C 279 0.5 Cutina ^® GMS-V 2.2 Lanette ^® N 1.5 Phospholipid ^® EFA 2.1 Dehydol ^® LS 3 deo N 0.8 EDTA-Na4 powder 87% 0.4 sodium 0.5 ascorbic acid 0.5 Puricare ^® LS 9658 1.0 Hostaphat ^® KW 340 D 1.0 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.88 p-aminophenol hydrochloride 0.52 resorcinol 0.43 m-aminophenol 0.8 5-amino-2-methylphenol 0.18 Disperse Violet 1 0.2 raw material Concentration [%] Ammoniumcarbomer soln. 1.0% 8.9 Ammoniumrohagit soln. 6% 1.9 Eumulgin ^® KE 2602 2.2 Potassium salt soap (12.5% in water) 22.5 Titanium dioxide ^Kronos® 1171 0.8 Cetiol ^® V 2.3 Lorol C 16 ^® 13.3 Emulgade® ^® F 1.1 Eumulgin ^® B3 0.8 Lowenol ^® C 279 0.5 Cutina ^® GMS-V 2.2 Lanette ^® N 1.5 Phospholipid ^® EFA 2.1 Dehydol ^® LS 3 deo N 0.8 EDTA-Na4 powder 87% 0.4 sodium 0.5 ascorbic acid 0.5 Puricare ^® LS 9658 1.0 Hostaphat ^® KW 340 D 1.0 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.38 resorcinol 0.13 m-aminophenol 0.07 5-amino-2-methylphenol 0.22 3-Amino-2-chloro-6-methylphenol 0.07 2,7-dihydroxynaphthalene 0.08 1,5-dihydroxynaphthalene 0.05 1-phenyl-3-methyl-5-pyrazolone 0.1 HC Red 7 0.2 raw material Concentration [%] Ammoniumcarbomer soln. 1.0% 8.9 Ammoniumrohagit soln. 6% 1.9 Eumulgin ^® KE 2602 2.2 Potassium salt soap (12.5% in water) 22.5 Titanium dioxide ^Kronos® 1171 0.8 Cetiol ^® V 2.3 Lorol C 16 ^® 13.3 Emulgade® ^® F 1.1 Eumulgin ^® B3 0.8 Lowenol ^® C 279 0.5 Cutina ^® GMS-V 2.2 Lanette ^® N 1.5 Phospholipid ^® EFA 2.1 Dehydol ^® LS 3 deo N 0.8 EDTA-Na4 powder 87% 0.4 sodium 0.5 ascorbic acid 0.5 Puricare ^® LS 9658 1.0 Hostaphat ^® KW 340 D 1.0 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.21 resorcinol 0.55 m-aminophenol 0.15 3-amino-2-methylamino-6-methoxypyridine 0.04 Basic Brown 16 0.20 raw material Concentration [%] Ammoniumcarbomer soln. 1.0% 8.9 Ammoniumrohagit soln. 6% 1.9 Eumulgin ^® KE 2602 2.2 Potassium salt soap (12.5% in water) 22.5 Titanium dioxide ^Kronos® 1171 0.8 Cetiol ^® V 2.3 Lorol C 16 ^® 13.3 Emulgade® ^® F 1.1 Eumulgin ^® B3 0.8 Lowenol ^® C 279 0.5 Cutina ^® GMS-V 2.2 Lanette ^® N 1.5 Phospholipid ^® EFA 2.1 Dehydol ^® LS 3 deo N 0.8 EDTA-Na4 powder 87% 0.4 sodium 0.5 ascorbic acid 0.5 Puricare ^® LS 9658 1.0 Hostaphat ^® KW 340 D 1.0 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.39 resorcinol 0.30 2,4-Diaminophenoxyethanol 1.74 HC Blue 2 0.20 raw material Concentration [%] Ammoniumcarbomer soln. 1.0% 8.9 Ammoniumrohagit soln. 6% 1.9 Eumulgin ^® KE 2602 2.2 Potassium salt soap (12.5% in water) 22.5 Titanium dioxide ^Kronos® 1171 0.8 Cetiol ^® V 2.3 Lorol C 16 ^® 13.3 Emulgade® ^® F 1.1 Eumulgin ^® B3 0.8 Lowenol ^® C 279 0.5 Cutina ^® GMS-V 2.2 Lanette ^® N 1.5 Phospholipid ^® EFA 2.1 Dehydol ^® LS 3 deo N 0.8 EDTA-Na4 powder 87% 0.4 sodium 0.5 ascorbic acid 0.5 Puricare ^® LS 9658 1.0 Hostaphat ^® KW 340 D 1.0 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazo-1-yl) propyl] amine trihydrochloride 3.73 2,4-diaminophenoxyethanol 2 HC 1.91 resorcinol 0.33 4-nitro-o-phenylenediamine 0.30 raw material Concentration [%] Ammoniumcarbomer soln. 1.0% 8.9 Ammoniumrohagit soln. 6% 1.9 Eumulgin ^® KE 2602 2.2 Potassium salt soap (12.5% in water) 22.5 Titanium dioxide ^Kronos® 1171 0.8 Cetiol ^® V 2.3 Lorol C 16 ^® 13.3 Emulgade® ^® F 1.1 Eumulgin ^® B3 0.8 Lowenol ^® C 279 0.5 Cutina ^® GMS-V 2.2 Lanette ^® N 1.5 Phospholipid ^® EFA 2.1 Dehydol ^® LS 3 deo N 0.8 EDTA-Na4 powder 87% 0.4 sodium 0.5 ascorbic acid 0.5 Puricare ^® LS 9658 1.0 Hostaphat ^® KW 340 D 1.0 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.82 resorcinol 0.17 2,7-dihydroxynaphthalene 0.29 1,3-bis (2,4-diaminophenoxy) propan-tetrahydrochloird 0.44 Basic Violet 2 0.30 raw material Concentration [%] Ammoniumcarbomer soln. 1.0% 8.9 Ammoniumrohagit soln. 6% 1.9 Eumulgin ^® KE 2602 2.2 Potassium salt soap (12.5% in water) 22.5 Titanium dioxide ^Kronos® 1171 0.8 Cetiol ^® V 2.3 Lorol C 16 ^® 13.3 Emulgade® ^® F 1.1 Eumulgin ^® B3 0.8 Lowenol ^® C 279 0.5 Cutina ^® GMS-V 2.2 Lanette ^® N 1.5 Phospholipid ^® EFA 2.1 Dehydol ^® LS 3 deo N 0.8 EDTA-Na4 powder 87% 0.4 sodium 0.5 ascorbic acid 0.5 Puricare ^® LS 9658 1.0 Hostaphat ^® KW 340 D 1.0 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.36 resorcinol 0.24 m-aminophenol 0.12 o-aminophenol 0.16 2,6-diaminopyridine 0.55 HC Red 3 0.20 raw material Concentration [%] Ammoniumcarbomer soln. 1.0% 8.9 Ammoniumrohagit soln. 6% 1.9 Eumulgin ^® KE 2602 2.2 Potassium salt soap (12.5% in water) 22.5 Titanium dioxide ^Kronos® 1171 0.8 Cetiol ^® V 2.3 Lorol C 16 ^® 13.3 Emulgade® ^® F 1.1 Eumulgin ^® B3 0.8 Lowenol ^® C 279 0.5 Cutina ^® GMS-V 2.2 Lanette ^® N 1.5 Phospholipid ^® EFA 2.1 Dehydol ^® LS 3 deo N 0.8 EDTA-Na4 powder 87% 0.4 sodium 0.5 ascorbic acid 0.5 Puricare ^® LS 9658 1.0 Hostaphat ^® KW 340 D 1.0 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.31 4,4'-diaminodiphenylamine sulfate 0.04 resorcinol 0.08 m-aminophenol 0.06 N, N'-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine 0.20 raw material Concentration [%] Ammoniumcarbomer soln. 1.0% 8.9 Ammoniumrohagit soln. 6% 1.9 Eumulgin ^® KE 2602 2.2 Potassium salt soap (12.5% in water) 22.5 Titanium dioxide ^Kronos® 1171 0.8 Cetiol ^® V 2.3 Lorol C 16 ^® 13.3 Emulgade® ^® F 1.1 Eumulgin ^® B3 0.8 Lowenol ^® C 279 0.5 Cutina ^® GMS-V 2.2 Lanette ^® N 1.5 Phospholipid ^® EFA 2.1 Dehydol ^® LS 3 deo N 0.8 EDTA-Na4 powder 87% 0.4 sodium 0.5 ascorbic acid 0.5 Puricare ^® LS 9658 1.0 Hostaphat ^® KW 340 D 1.0 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.16 resorcinol 0.51 m-aminophenol 0.12 2-amino-4-Hydroxyethylaminoanisolsulfat 0.18 HC Red 13 0.30 raw material Concentration [%] Ammoniumcarbomer soln. 1.0% 8.9 Ammoniumrohagit soln. 6% 1.9 Eumulgin ^® KE 2602 2.2 Potassium salt soap (12.5% in water) 22.5 Titanium dioxide ^Kronos® 1171 0.8 Cetiol ^® V 2.3 Lorol C 16 ^® 13.3 Emulgade® ^® F 1.1 Eumulgin ^® B3 0.8 Lowenol ^® C 279 0.5 Cutina ^® GMS-V 2.2 Lanette ^® N 1.5 Phospholipid ^® EFA 2.1 Dehydol ^® LS 3 deo N 0.8 EDTA-Na4 powder 87% 0.4 sodium 0.5 ascorbic acid 0.5 Puricare ^® LS 9658 1.0 Hostaphat ^® KW 340 D 1.0 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.55 m-aminophenol 0.22 2-amino-4-Hydroxyethylaminoanisolsulfat 0.04 4-chlororesorcinol 0.78 HC Yellow 2 0.15 HC Orange 1 0.25 raw material Concentration [%] Ammoniumcarbomer soln. 1.0% 8.9 Ammoniumrohagit soln. 6% 1.9 Eumulgin ^® KE 2602 2.2 Potassium salt soap (12.5% in water) 22.5 Titanium dioxide ^Kronos® 1171 0.8 Cetiol ^® V 2.3 Lorol C 16 ^® 13.3 Emulgade® ^® F 1.1 Eumulgin ^® B3 0.8 Lowenol ^® C 279 0.5 Cutina ^® GMS-V 2.2 Lanette ^® N 1.5 Phospholipid ^® EFA 2.1 Dehydol ^® LS 3 deo N 0.8 EDTA-Na4 powder 87% 0.4 sodium 0.5 ascorbic acid 0.5 Puricare ^® LS 9658 1.0 Hostaphat ^® KW 340 D 1.0 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.93 4,5-diamino-1- (2-hydroxyethyl) -1H-pyrazol-sulfate 0.93 2,4-diaminophenoxyethanol dihydrochloride 0.58 resorcinol 0.56 m-aminophenol 0.09 5-amino-2-methylphenol 0.39 Hydroxyethyl-2-nitro-p-toluidine 0.3 raw material Concentration [%] Ammoniumcarbomer soln. 1.0% 8.9 Ammoniumrohagit soln. 6% 1.9 Eumulgin ^® KE 2602 2.2 Potassium salt soap (12.5% in water) 22.5 Titanium dioxide ^Kronos® 1171 0.8 Cetiol ^® V 2.3 Lorol C 16 ^® 13.3 Emulgade® ^® F 1.1 Eumulgin ^® B3 0.8 Lowenol ^® C 279 0.5 Cutina ^® GMS-V 2.2 Lanette ^® N 1.5 Phospholipid ^® EFA 2.1 Dehydol ^® LS 3 deo N 0.8 EDTA-Na4 powder 87% 0.4 sodium 0.5 ascorbic acid 0.5 Puricare ^® LS 9658 1.0 Hostaphat ^® KW 340 D 1.0 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.39 2,4-diaminophenoxyethanol dihydrochloride 1.74 resorcinol 0.3 Basic Blue 99 0.3 raw material Concentration [%] Ammoniumcarbomer soln. 1.0% 8.9 Ammoniumrohagit soln. 6% 1.9 Eumulgin ^® KE 2602 2.2 Potassium salt soap (12.5% in water) 22.5 Titanium dioxide ^Kronos® 1171 0.8 Cetiol ^® V 2.3 Lorol C 16 ^® 13.3 Emulgade® ^® F 1.1 Eumulgin ^® B3 0.8 Lowenol ^® C 279 0.5 Cutina ^® GMS-V 2.2 Lanette ^® N 1.5 Phospholipid ^® EFA 2.1 Dehydol ^® LS 3 deo N 0.8 EDTA-Na4 powder 87% 0.4 sodium 0.5 ascorbic acid 0.5 Puricare ^® LS 9658 1.0 Hostaphat ^® KW 340 D 1.0 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.73 resorcinol 0.3 m-aminophenol 0.19 3-amino-2-methylamino-6-methoxypyridine 0.01 2,6-dihydroxy-3,4-dimethylpyridine 0.12 HC Yellow 13 0.2

For the streak dyed with this staining cream, the following colorimetric values were determined: L value: 22.5 a-value: -1.9 b-value: 4.8 raw material Concentration [%] Ammoniumcarbomer soln. 1.0% 8.9 Ammoniumrohagit soln. 6% 1.9 Eumulgin ^® KE 2602 2.2 Potassium salt soap (12.5% in water) 22.5 Titanium dioxide ^Kronos® 1171 0.8 Cetiol ^® V 2.3 Lorol C 16 ^® 13.3 Emulgade® ^® F 1.1 Eumulgin ^® B3 0.8 Lowenol ^® C 279 0.5 Cutina ^® GMS-V 2.2 Lanette ^® N 1.5 Phospholipid ^® EFA 2.1 Dehydol ^® LS 3 deo N 0.8 EDTA-Na4 powder 87% 0.4 sodium 0.5 ascorbic acid 0.5 Puricare ^® LS 9658 1.0 Hostaphat ^® KW 340 D 1.0 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.67 resorcinol 0.27 3-amino-2-methylamino-6-methoxypyridine 0.06 4-chlororesorcinol 0.37 1,3-bis (2,4-diaminophenoxy) propane 4HCl 0.2 Basic Red 76 0.2 Basic Brown 17 0.05

For the streak dyed with this staining cream, the following colorimetric values were determined: L value: 19.8 a-value: -2.6 b-value: 1.9 raw material Concentration [%] Ammoniumcarbomer soln. 1.0% 8.9 Ammoniumrohagit soln. 6% 1.9 Eumulgin ^® KE 2602 2.2 Potassium salt soap (12.5% in water) 22.5 Titanium dioxide ^Kronos® 1171 0.8 Cetiol ^® V 2.3 Lorol C 16 ^® 13.3 Emulgade® ^® F 1.1 Eumulgin ^® B3 0.8 Lowenol ^® C 279 0.5 Cutina ^® GMS-V 2.2 Lanette ^® N 1.5 Phospholipid ^® EFA 2.1 Dehydol ^® LS 3 deo N 0.8 EDTA-Na4 powder 87% 0.4 sodium 0.5 ascorbic acid 0.5 Puricare ^® LS 9658 1.0 Hostaphat ^® KW 340 D 1.0 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.31 4-chlororesorcinol 0.04 resorcinol 0.05 3-Amino-2-chloro-6-methylphenol 0.01 3-amino-2-methylamino-6-methoxypyridine 0.03 Basic Yellow 57 0.08 raw material Concentration [%] Ammoniumcarbomer soln. 1.0% 8.9 Ammoniumrohagit soln. 6% 1.9 Eumulgin ^® KE 2602 2.2 Potassium salt soap (12.5% in water) 22.5 Titanium dioxide ^Kronos® 1171 0.8 Cetiol ^® V 2.3 Lorol C 16 ^® 13.3 Emulgade® ^® F 1.1 Eumulgin ^® B3 0.8 Lowenol ^® C 279 0.5 Cutina ^® GMS-V 2.2 Lanette ^® N 1.5 Phospholipid ^® EFA 2.1 Dehydol ^® LS 3 deo N 0.8 EDTA-Na4 powder 87% 0.4 sodium 0.5 ascorbic acid 0.5 Puricare ^® LS 9658 1.0 Hostaphat ^® KW 340 D 1.0 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.71 2,4,5,6-tetra-sulfate 0.23 resorcinol 0.11 2-methyl 0.11 2,7-dihydroxynaphthalene 0.2 HC Red 1 0.2 raw material Concentration [%] Ammoniumcarbomer soln. 1.0% 8.9 Ammoniumrohagit soln. 6% 1.9 Eumulgin ^® KE 2602 2.2 Potassium salt soap (12.5% in water) 22.5 Titanium dioxide ^Kronos® 1171 0.8 Cetiol ^® V 2.3 Lorol C 16 ^® 13.3 Emulgade® ^® F 1.1 Eumulgin ^® B3 0.8 Lowenol ^® C 279 0.5 Cutina ^® GMS-V 2.2 Lanette ^® N 1.5 Phospholipid ^® EFA 2.1 Dehydol ^® LS 3 deo N 0.8 EDTA-Na4 powder 87% 0.4 sodium 0.5 ascorbic acid 0.5 Puricare ^® LS 9658 1.0 Hostaphat ^® KW 340 D 1.0 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.67 m-aminophenol 0.12 resorcinol 0.39 2-methyl 0.05 2-amino-3-hydroxypyridine 0.06 HC Blue 12 0.08 raw material Concentration [%] Ammoniumcarbomer soln. 1.0% 8.9 Ammoniumrohagit soln. 6% 1.9 Eumulgin ^® KE 2602 2.2 Potassium salt soap (12.5% in water) 22.5 Titanium dioxide ^Kronos® 1171 0.8 Cetiol ^® V 2.3 Lorol C 16 ^® 13.3 Emulgade® ^® F 1.1 Eumulgin ^® B3 0.8 Lowenol ^® C 279 0.5 Cutina ^® GMS-V 2.2 Lanette ^® N 1.5 Phospholipid ^® EFA 2.1 Dehydol ^® LS 3 deo N 0.8 EDTA-Na4 powder 87% 0.4 sodium 0.5 ascorbic acid 0.5 Puricare ^® LS 9658 1.0 Hostaphat ^® KW 340 D 1.0 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.12 2-methyl 0.28 4-chlororesorcinol 0.13 3-amino-2-methylamino-6-methoxypyridine 0.01 Acid Violet 43 0.2 raw material Concentration [%] Ammoniumcarbomer soln. 1.0% 8.9 Ammoniumrohagit soln. 6% 1.9 Eumulgin ^® KE 2602 2.2 Potassium salt soap (12.5% in water) 22.5 Titanium dioxide ^Kronos® 1171 0.8 Cetiol ^® V 2.3 Lorol C 16 ^® 13.3 Emulgade® ^® F 1.1 Eumulgin ^® B3 0.8 Lowenol ^® C 279 0.5 Cutina ^® GMS-V 2.2 Lanette ^® N 1.5 Phospholipid ^® EFA 2.1 Dehydol ^® LS 3 deo N 0.8 EDTA-Na4 powder 87% 0.4 sodium 0.5 ascorbic acid 0.5 Puricare ^® LS 9658 1.0 Hostaphat ^® KW 340 D 1.0 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.4437 2,4,5,6-tetra-sulfate .7741 m-aminophenol .4200 2-amino-3-hydroxypyridine .1650 4-chlororesorcinol .2400

7.2 colorations

The colorants mentioned under point 7.1 were in each case immediately before the coloration in the ratio 1 part by weight cream: 1 part by weight Developer mixed with the following composition: raw material Concentration [% by weight] disodiumpyrophosphate 0.3 Disodium EDTA 0.2 Na benzoate 0.04 Emulgade® ^® F 2.1 Phosphoric acid 85% 0.04 Hydrogen peroxide 50% 12.2 Perfume 0.1 water ad 100

The resulting application mixtures were each dyed to 6 cm long strands (Kerling, 80% mottled). The duration of use was 30 minutes at 32 ° C. Then each tress was rinsed for one minute with lukewarm water and dried with a hair dryer. 8 Colorant base H 8.1 Formulations raw material Concentration [%] Dehydol ^® LS 2 deo 4.9 Mergital ^® CS 50 A 5.0 Lorol® ^® techn. 8.0 Edenor ^® PK 1805 6.8 isopropanol 15.0 1,2-propanediol 6.8 Texapon.RTM ^® NSO UP 4.5 Merquat ^® 280 2.0 Amphoterge K-2 ^® 1.0 Monoethanolamine 8.2 L-arginine 1.0 Benecel ^® MP 333C 0.5 Xanthan gum 0.5 sodium 0.4 Ascorbic acid E 300 DAB 0.2 Monoammonium phosphate 0.4 Turpinal® ^® SL 0.2 Merquat Plus ^® 3330 1.5 Dow ^Corning® 345 Fluid 1.5 water ad 100 PH value 10 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.88 p-aminophenol hydrochloride 0.52 resorcinol 0.43 m-aminophenol 0.8 5-amino-2-methylphenol 0.18 Disperse Violet 1 0.2 raw material Concentration [%] Dehydol ^® LS 2 deo 4.9 Mergital ^® CS 50 A 5.0 Lorol® ^® techn. 8.0 Edenor ^® PK 1805 6.8 isopropanol 15.0 1,2-propanediol 6.8 Texapon.RTM ^® NSO UP 4.5 Merquat ^® 280 2.0 Amphoterge K-2 ^® 1.0 Monoethanolamine 8.2 L-arginine 1.0 Benecel ^® MP 333C 0.5 Xanthan gum 0.5 sodium 0.4 Ascorbic acid E 300 DAB 0.2 Monoammonium phosphate 0.4 Turpinal® ^® SL 0.2 Merquat Plus ^® 3330 1.5 Dow ^Corning® 345 Fluid 1.5 water ad 100 PH value 10 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.38 resorcinol 0.13 m-aminophenol 0.07 5-amino-2-methylphenol 0.22 3-Amino-2-chloro-6-methylphenol 0.07 2,7-dihydroxynaphthalene 0.08 1,5-dihydroxynaphthalene 0.05 1-phenyl-3-methyl-5-pyrazolone 0.1 HC Red 7 0.2 raw material Concentration [%] Dehydol ^® LS 2 deo 4.9 Mergital ^® CS 50 A 5.0 Lorol® ^® techn. 8.0 Edenor ^® PK 1805 6.8 isopropanol 15.0 1,2-propanediol 6.8 Texapon.RTM ^® NSO UP 4.5 Merquat ^® 280 2.0 Amphoterge K-2 ^® 1.0 Monoethanolamine 8.2 L-arginine 1.0 Benecel ^® MP 333C 0.5 Xanthan gum 0.5 sodium 0.4 Ascorbic acid E 300 DAB 0.2 Monoammonium phosphate 0.4 Turpinal® ^® SL 0.2 Merquat Plus ^® 3330 1.5 Dow ^Corning® 345 Fluid 1.5 water ad 100 PH value 10 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.21 resorcinol 0.55 m-aminophenol 0.15 3-amino-2-methylamino-6-methoxypyridine 0.04 Basic Brown 16 0.20 raw material Concentration [%] Dehydol ^® LS 2 deo 4.9 Mergital ^® CS 50 A 5.0 Lorol® ^® techn. 8.0 Edenor ^® PK 1805 6.8 isopropanol 15.0 1,2-propanediol 6.8 Texapon.RTM ^® NSO UP 4.5 Merquat ^® 280 2.0 Amphoterge K-2 ^® 1.0 Monoethanolamine 8.2 L-arginine 1.0 Benecel ^® MP 333C 0.5 Xanthan gum 0.5 sodium 0.4 Ascorbic acid E 300 DAB 0.2 Monoammonium phosphate 0.4 Turpinal® ^® SL 0.2 Merquat Plus ^® 3330 1.5 Dow ^Corning® 345 Fluid 1.5 water ad 100 PH value 10 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.39 resorcinol 0.30 2,4-Diaminophenoxyethanol 1.74 HC Blue 2 0.20 raw material Concentration [%] Dehydol ^® LS 2 deo 4.9 Mergital ^® CS 50 A 5.0 Lorol® ^® techn. 8.0 Edenor ^® PK 1805 6.8 isopropanol 15.0 1,2-propanediol 6.8 Texapon.RTM ^® NSO UP 4.5 Merquat ^® 280 2.0 Amphoterge K-2 ^® 1.0 Monoethanolamine 8.2 L-arginine 1.0 Benecel ^® MP 333C 0.5 Xanthan gum 0.5 sodium 0.4 Ascorbic acid E 300 DAB 0.2 Monoammonium phosphate 0.4 Turpinal® ^® SL 0.2 Merquat Plus ^® 3330 1.5 Dow ^Corning® 345 Fluid 1.5 water ad 100 PH value 10 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.73 2,4-diaminophenoxyethanol 2 HC 1.91 resorcinol 0.33 4-nitro-o-phenylenediamine 0.30 raw material Concentration [%] Dehydol ^® LS 2 deo 4.9 Mergital ^® CS 50 A 5.0 Lorol® ^® techn. 8.0 Edenor ^® PK 1805 6.8 isopropanol 15.0 1,2-propanediol 6.8 Texapon.RTM ^® NSO UP 4.5 Merquat ^® 280 2.0 Amphoterge K-2 ^® 1.0 Monoethanolamine 8.2 L-arginine 1.0 Benecel ^® MP 333C 0.5 Xanthan gum 0.5 sodium 0.4 Ascorbic acid E 300 DAB 0.2 Monoammonium phosphate 0.4 Turpinal® ^® SL 0.2 Merquat Plus ^® 3330 1.5 Dow ^Corning® 345 Fluid 1.5 water ad 100 PH value 10 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.82 resorcinol 0.17 2,7-dihydroxynaphthalene 0.29 1,3-bis (2,4-diaminophenoxy) propan-tetrahydrochloird 0.44 Basic Violet 2 0.30 raw material Concentration [%] Dehydol ^® LS 2 deo 4.9 Mergital ^® CS 50 A 5.0 Lorol® ^® techn. 8.0 Edenor ^® PK 1805 6.8 isopropanol 15.0 1,2-propanediol 6.8 Texapon.RTM ^® NSO UP 4.5 Merquat ^® 280 2.0 Amphoterge K-2 ^® 1.0 Monoethanolamine 8.2 L-arginine 1.0 Benecel ^® MP 333C 0.5 Xanthan gum 0.5 sodium 0.4 Ascorbic acid E 300 DAB 0.2 Monoammonium phosphate 0.4 Turpinal® ^® SL 0.2 Merquat Plus ^® 3330 1.5 Dow ^Corning® 345 Fluid 1.5 water ad 100 PH value 10 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.36 resorcinol 0.24 m-aminophenol 0.12 o-aminophenol 0.16 2,6-diaminopyridine 0.55 HC Red 3 0.20 raw material Concentration [%] Dehydol ^® LS 2 deo 4.9 Mergital ^® CS 50 A 5.0 Lorol® ^® techn. 8.0 Edenor ^® PK 1805 6.8 isopropanol 15.0 1,2-propanediol 6.8 Texapon.RTM ^® NSO UP 4.5 Merquat ^® 280 2.0 Amphoterge K-2 ^® 1.0 Monoethanolamine 8.2 L-arginine 1.0 Benecel ^® MP 333C 0.5 Xanthan gum 0.5 sodium 0.4 Ascorbic acid E 300 DAB 0.2 Monoammonium phosphate 0.4 Turpinal® ^® SL 0.2 Merquat Plus ^® 3330 1.5 Dow ^Corning® 345 Fluid 1.5 water ad 100 PH value 10 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.31 4,4'-diaminodiphenylamine sulfate 0.04 resorcinol 0.08 m-aminophenol 0.06 N, N'-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine 0.20 raw material Concentration [%] Dehydol ^® LS 2 deo 4.9 Mergital ^® CS 50 A 5.0 Lorol® ^® techn. 8.0 Edenor ^® PK 1805 6.8 isopropanol 15.0 1,2-propanediol 6.8 Texapon.RTM ^® NSO UP 4.5 Merquat ^® 280 2.0 Amphoterge K-2 ^® 1.0 Monoethanolamine 8.2 L-arginine 1.0 Benecel ^® MP 333C 0.5 Xanthan gum 0.5 sodium 0.4 Ascorbic acid E 300 DAB 0.2 Monoammonium phosphate 0.4 Turpinal® ^® SL 0.2 Merquat Plus ^® 3330 1.5 Dow ^Corning® 345 Fluid 1.5 water ad 100 PH value 10 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.16 resorcinol 0.51 m-aminophenol 0.12 2-amino-4-Hydroxyethylaminoanisolsulfat 0.18 HC Red 13 0.30 raw material Concentration [%] Dehydol ^® LS 2 deo 4.9 Mergital ^® CS 50 A 5.0 Lorol® ^® techn. 8.0 Edenor ^® PK 1805 6.8 isopropanol 15.0 1,2-propanediol 6.8 Texapon.RTM ^® NSO UP 4.5 Merquat ^® 280 2.0 Amphoterge K-2 ^® 1.0 Monoethanolamine 8.2 L-arginine 1.0 Benecel ^® MP 333C 0.5 Xanthan gum 0.5 sodium 0.4 Ascorbic acid E 300 DAB 0.2 Monoammonium phosphate 0.4 Turpinal® ^® SL 0.2 Merquat Plus ^® 3330 1.5 Dow ^Corning® 345 Fluid 1.5 water ad 100 PH value 10 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.55 m-aminophenol 0.22 2-amino-4-Hydroxyethylaminoanisolsulfat 0.04 4-chlororesorcinol 0.78 HC Yellow 2 0.15 HC Orange 1 0.25 raw material Concentration [%] Dehydol ^® LS 2 deo 4.9 Mergital ^® CS 50 A 5.0 Lorol® ^® techn. 8.0 Edenor ^® PK 1805 6.8 isopropanol 15.0 1,2-propanediol 6.8 Texapon.RTM ^® NSO UP 4.5 Merquat ^® 280 2.0 Amphoterge K-2 ^® 1.0 Monoethanolamine 8.2 L-arginine 1.0 Benecel ^® MP 333C 0.5 Xanthan gum 0.5 sodium 0.4 Ascorbic acid E 300 DAB 0.2 Monoammonium phosphate 0.4 Turpinal® ^® SL 0.2 Merquat Plus ^® 3330 1.5 Dow ^Corning® 345 Fluid 1.5 water ad 100 PH value 10 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.93 4,5-diamino-1- (2-hydroxyethyl) -1H-pyrazol-sulfate 0.93 2,4-diaminophenoxyethanol dihydrochloride 0.58 resorcinol 0.56 m-aminophenol 0.09 5-amino-2-methylphenol 0.39 Hydroxyethyl-2-nitro-p-toluidine 0.3 raw material Concentration [%] Dehydol ^® LS 2 deo 4.9 Mergital ^® CS 50 A 5.0 Lorol® ^® techn. 8.0 Edenor ^® PK 1805 6.8 isopropanol 15.0 1,2-propanediol 6.8 Texapon.RTM ^® NSO UP 4.5 Merquat ^® 280 2.0 Amphoterge K-2 ^® 1.0 Monoethanolamine 8.2 L-arginine 1.0 Benecel ^® MP 333C 0.5 Xanthan gum 0.5 sodium 0.4 Ascorbic acid E 300 DAB 0.2 Monoammonium phosphate 0.4 Turpinal® ^® SL 0.2 Merquat Plus ^® 3330 1.5 Dow ^Corning® 345 Fluid 1.5 water ad 100 PH value 10 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.39 2,4-diaminophenoxyethanol dihydrochloride 1.74 resorcinol 0.3 Basic Blue 99 0.3 raw material Concentration [%] Dehydol ^® LS 2 deo 4.9 Mergital ^® CS 50 A 5.0 Lorol® ^® techn. 8.0 Edenor ^® PK 1805 6.8 isopropanol 15.0 1,2-propanediol 6.8 Texapon.RTM ^® NSO UP 4.5 Merquat ^® 280 2.0 Amphoterge K-2 ^® 1.0 Monoethanolamine 8.2 L-arginine 1.0 Benecel ^® MP 333C 0.5 Xanthan gum 0.5 sodium 0.4 Ascorbic acid E 300 DAB 0.2 Monoammonium phosphate 0.4 Turpinal® ^® SL 0.2 Merquat Plus ^® 3330 1.5 Dow ^Corning® 345 Fluid 1.5 water ad 100 PH value 10 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.73 resorcinol 0.3 m-aminophenol 0.19 3-amino-2-methylamino-6-methoxypyridine 0.01 2,6-dihydroxy-3,4-dimethylpyridine 0.12 HC Yellow 13 0.2 Basic Brown 17 0 raw material Concentration [%] Dehydol ^® LS 2 deo 4.9 Mergital ^® CS 50 A 5.0 Lorol® ^® techn. 8.0 Edenor ^® PK 1805 6.8 isopropanol 15.0 1,2-propanediol 6.8 Texapon.RTM ^® NSO UP 4.5 Merquat ^® 280 2.0 Amphoterge K-2 ^® 1.0 Monoethanolamine 8.2 L-arginine 1.0 Benecel ^® MP 333C 0.5 Xanthan gum 0.5 sodium 0.4 Ascorbic acid E 300 DAB 0.2 Monoammonium phosphate 0.4 Turpinal® ^® SL 0.2 Merquat Plus ^® 3330 1.5 Dow ^Corning® 345 Fluid 1.5 water ad 100 PH value 10 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.67 resorcinol 0.27 3-amino-2-methylamino-6-methoxypyridine 0.06 4-chlororesorcinol 0.37 1,3-bis (2,4-diaminophenoxy) propane 4HCl 0.2 Basic Red 76 0.2 Basic Brown 17 0.05 raw material Concentration [%] Dehydol ^® LS 2 deo 4.9 Mergital ^® CS 50 A 5.0 Lorol® ^® techn. 8.0 Edenor ^® PK 1805 6.8 isopropanol 15.0 1,2-propanediol 6.8 Texapon.RTM ^® NSO UP 4.5 Merquat ^® 280 2.0 Amphoterge K-2 ^® 1.0 Monoethanolamine 8.2 L-arginine 1.0 Benecel ^® MP 333C 0.5 Xanthan gum 0.5 sodium 0.4 Ascorbic acid E 300 DAB 0.2 Monoammonium phosphate 0.4 Turpinal® ^® SL 0.2 Merquat Plus ^® 3330 1.5 Dow ^Corning® 345 Fluid 1.5 water ad 100 PH value 10 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.31 4-chlororesorcinol 0.04 resorcinol 0.05 3-Amino-2-chloro-6-methylphenol 0.01 3-amino-2-methylamino-6-methoxypyridine 0.03 Basic Yellow 57 0.08

For the streak dyed with this staining cream, the following colorimetric values were determined: L value: 46.8 a-value: 2.7 b-value: 12.7 raw material Concentration [%] Dehydol ^® LS 2 deo 4.9 Mergital ^® CS 50 A 5.0 Lorol® ^® techn. 8.0 Edenor ^® PK 1805 6.8 isopropanol 15.0 1,2-propanediol 6.8 Texapon.RTM ^® NSO UP 4.5 Merquat ^® 280 2.0 Amphoterge K-2 ^® 1.0 Monoethanolamine 8.2 L-arginine 1.0 Benecel ^® MP 333C 0.5 Xanthan gum 0.5 sodium 0.4 Ascorbic acid E 300 DAB 0.2 Monoammonium phosphate 0.4 Turpinal® ^® SL 0.2 Merquat Plus ^® 3330 1.5 Dow ^Corning® 345 Fluid 1.5 water ad 100 PH value 10 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.71 2,4,5,6-tetra-sulfate 0.23 resorcinol 0.11 2-methyl 0.11 2,7-dihydroxynaphthalene 0.2 HC Red 1 0.2

For the streak dyed with this staining cream, the following colorimetric values were determined: L value: 41.3 a-value: 10.4 b-value: 19.2 raw material Concentration [%] Dehydol ^® LS 2 deo 4.9 Mergital ^® CS 50 A 5.0 Lorol® ^® techn. 8.0 Edenor ^® PK 1805 6.8 isopropanol 15.0 1,2-propanediol 6.8 Texapon.RTM ^® NSO UP 4.5 Merquat ^® 280 2.0 Amphoterge K-2 ^® 1.0 Monoethanolamine 8.2 L-arginine 1.0 Benecel ^® MP 333C 0.5 Xanthan gum 0.5 sodium 0.4 Ascorbic acid E 300 DAB 0.2 Monoammonium phosphate 0.4 Turpinal® ^® SL 0.2 Merquat Plus ^® 3330 1.5 Dow ^Corning® 345 Fluid 1.5 water ad 100 PH value 10 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.67 m-aminophenol 0.12 resorcinol 0.39 2-methyl 0.05 2-amino-3-hydroxypyridine 0.06 HC Blue 12 0.08 raw material Concentration [%] Dehydol ^® LS 2 deo 4.9 Mergital ^® CS 50 A 5.0 Lorol® ^® techn. 8.0 Edenor ^® PK 1805 6.8 isopropanol 15.0 1,2-propanediol 6.8 Texapon.RTM ^® NSO UP 4.5 Merquat ^® 280 2.0 Amphoterge K-2 ^® 1.0 Monoethanolamine 8.2 L-arginine 1.0 Benecel ^® MP 333C 0.5 Xanthan gum 0.5 sodium 0.4 Ascorbic acid E 300 DAB 0.2 Monoammonium phosphate 0.4 Turpinal® ^® SL 0.2 Merquat Plus ^® 3330 1.5 Dow ^Corning® 345 Fluid 1.5 water ad 100 PH value 10 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.12 2-methyl 0.28 4-chlororesorcinol 0.13 3-amino-2-methylamino-6-methoxypyridine 0.01 Acid Violet 43 0.2 raw material Concentration [%] Dehydol ^® LS 2 deo 4.9 Mergital ^® CS 50 A 5.0 Lorol® ^® techn. 8.0 Edenor ^® PK 1805 6.8 isopropanol 15.0 1,2-propanediol 6.8 Texapon.RTM ^® NSO UP 4.5 Merquat ^® 280 2.0 Amphoterge K-2 ^® 1.0 Monoethanolamine 8.2 L-arginine 1.0 Benecel ^® MP 333C 0.5 Xanthan gum 0.5 sodium 0.4 Ascorbic acid E 300 DAB 0.2 Monoammonium phosphate 0.4 Turpinal® ^® SL 0.2 Merquat Plus ^® 3330 1.5 Dow ^Corning® 345 Fluid 1.5 water ad 100 PH value 10 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.4437 2,4,5,6-tetra-sulfate .7741 m-aminophenol .4200 2-amino-3-hydroxypyridine .1650 4-chlororesorcinol .2400

8.2 colorations

The dyestuffs mentioned under point 8.1 were each mixed immediately before the dyeing in the ratio 5 parts by weight of cream: 4 parts by weight of developer with the following composition: raw material Concentration [% by weight] Caustic soda 45% techn. 0.8 dipicolinic 0.1 disodiumpyrophosphate 0.03 Turpinal® ^® SL 1.5 FAEOS-Na C12-14 2EO 27% 2.0 Aculyn ^® 33 4.5 Hydrogen peroxide 50% 10.0 water ad 100

The resulting application mixtures were each dyed to 6 cm long strands (Kerling, 80% mottled). The duration of use was 30 minutes at 32 ° C. Then each tress was rinsed for one minute with lukewarm water and dried with a hair dryer. 9 Colorant base 1 9.1 Formulations raw material Concentration [%] Preferences. Ammoniumcarbomer soln. 1.0% 12.0 Lanette ^® E 0.6 Sodium lauryl ether sulfate (27% in water) 3.5 Potassium Ricinusöl Soap (12,5% in water) 1.2 Potassium salt soap (12.5% in water) 1.2 Cutina ^® GMS SE 1.6 Cutina ^® AGS 1.6 Eutanol ^® G 1.6 Stenol ^® 16/18 9.6 Eumulgin ^® B2 2.4 L-serine 0.5 EDTA-Na4 powder 87% 0.2 Phospholipid ^® EFA 0.1 ammonium sulfate 0.4 sodium 0.2 Ascorbic acid E 300 DAB 0.1 Tween® ^20V 0.2 alpha-lipoic acid 0.2 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.88 p-aminophenol hydrochloride 0.52 resorcinol 0.43 m-aminophenol 0.8 5-amino-2-methylphenol 0.18 Disperse Violet 1 0.2 raw material Concentration [%] Preferences. Ammoniumcarbomer soln. 1.0% 12.0 Lanette ^® E 0.6 Sodium lauryl ether sulfate (27% in water) 3.5 Potassium Ricinusöl Soap (12,5% in water) 1.2 Potassium salt soap (12.5% in water) 1.2 Cutina ^® GMS SE 1.6 Cutina ^® AGS 1.6 Eutanol ^® G 1.6 Stenol ^® 16/18 9.6 Eumulgin ^® B2 2.4 L-serine 0.5 EDTA-Na4 powder 87% 0.2 Phospholipid ^® EFA 0.1 ammonium sulfate 0.4 sodium 0.2 Ascorbic acid E 300 DAB 0.1 Tween® ^20V 0.2 alpha-lipoic acid 0.2 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.38 resorcinol 0.13 m-aminophenol 0.07 5-amino-2-methylphenol 0.22 3-Amino-2-chloro-6-methylphenol 0.07 2,7-dihydroxynaphthalene 0.08 1,5-dihydroxynaphthalene 0.05 1-phenyl-3-methyl-5-pyrazolone 0.1 HC Red 7 0.2 raw material Concentration [%] Preferences. Ammoniumcarbomer soln. 1.0% 12.0 Lanette ^® E 0.6 Sodium lauryl ether sulfate (27% in water) 3.5 Potassium Ricinusöl Soap (12,5% in water) 1.2 Potassium salt soap (12.5% in water) 1.2 Cutina ^® GMS SE 1.6 Cutina ^® AGS 1.6 Eutanol ^® G 1.6 Stenol ^® 16/18 9.6 Eumulgin ^® B2 2.4 L-serine 0.5 EDTA-Na4 powder 87% 0.2 Phospholipid ^® EFA 0.1 ammonium sulfate 0.4 sodium 0.2 Ascorbic acid E 300 DAB 0.1 Tween® ^20V 0.2 alpha-lipoic acid 0.2 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.21 resorcinol 0.55 m-aminophenol 0.15 3-amino-2-methylamino-6-methoxypyridine 0.04 Basic Brown 16 0.20 raw material Concentration [%] Preferences. Ammoniumcarbomer soln. 1.0% 12.0 Lanette ^® E 0.6 Sodium lauryl ether sulfate (27% in water) 3.5 Potassium Ricinusöl Soap (12,5% in water) 1.2 Potassium salt soap (12.5% in water) 1.2 Cutina ^® GMS SE 1.6 Cutina ^® AGS 1.6 Eutanol ^® G 1.6 Steno) ^® 16/18 9.6 Eumulgin ^® B2 2.4 L-serine 0.5 EDTA-Na4 powder 87% 0.2 Phospholipid ^® EFA 0.1 ammonium sulfate 0.4 sodium 0.2 Ascorbic acid E 300 DAB 0.1 Tween® ^20V 0.2 alpha-lipoic acid 0.2 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.39 resorcinol 0.30 2,4-Diaminophenoxyethanol 1.74 HC Blue 2 0.20 raw material Concentration [%] Preferences. Ammoniumcarbomer soln. 1.0% 12.0 Lanette ^® E 0.6 Sodium lauryl ether sulfate (27% in water) 3.5 Potassium Ricinusöl Soap (12,5% in water) 1.2 Potassium salt soap (12.5% in water) 1.2 Cutina ^® GMS SE 1.6 Cutina ^® AGS 1.6 Eutanol ^® G 1.6 Stenol ^® 16/18 9.6 Eumulgin ^® B2 2.4 L-serine 0.5 EDTA-Na4 powder 87% 0.2 Phospholipid ^® EFA 0.1 ammonium sulfate 0.4 sodium 0.2 Ascorbic acid E 300 DAB 0.1 Tween® ^20V 0.2 alpha-lipoic acid 0.2 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.73 2,4-diaminophenoxyethanol 2 HC 1.91 resorcinol 0.33 4-nitro-o-phenylenediamine 0.30 raw material Concentration [%] Preferences. Ammoniumcarbomer soln. 1.0% 12.0 Lanette ^® E 0.6 Sodium lauryl ether sulfate (27% in water) 3.5 Potassium Ricinusöl Soap (12,5% in water) 1.2 Potassium salt soap (12.5% in water) 1.2 Cutina ^® GMS SE 1.6 Cutina ^® AGS 1.6 Eutanol ^® G 1.6 Stenol ^® 16/18 9.6 Eumulgin ^® B2 2.4 L-serine 0.5 EDTA-Na4 powder 87% 0.2 Phospholipid ^® EFA 0.1 ammonium sulfate 0.4 sodium 0.2 Ascorbic acid E 300 DAB 0.1 Tween® ^20V 0.2 alpha-lipoic acid 0.2 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.82 resorcinol 0.17 2,7-dihydroxynaphthalene 0.29 1,3-bis (2,4-diaminophenoxy) propan-tetrahydrochloird 0.44 Basic Violet 2 0.30 raw material Concentration [%] Preferences. Ammoniumcarbomer soln. 1.0% 12.0 Lanette ^® E 0.6 Sodium lauryl ether sulfate (27% in water) 3.5 Potassium Ricinusöl Soap (12,5% in water) 1.2 Potassium salt soap (12.5% in water) 1.2 Cutina ^® GMS SE 1.6 Cutina ^® AGS 1.6 Eutanol ^® G 1.6 Stenol ^® 16/18 9.6 Eumulgin ^® B2 2.4 L-serine 0.5 EDTA-Na4 powder 87% 0.2 Phospholipid ^® EFA 0.1 ammonium sulfate 0.4 sodium 0.2 Ascorbic acid E 300 DAB 0.1 Tween® ^20V 0.2 alpha-lipoic acid 0.2 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.36 resorcinol 0.24 m-aminophenol 0.12 o-aminophenol 0.16 2,6-diaminopyridine 0.55 HC Red 3 0.20 raw material Concentration [%] Preferences. Ammoniumcarbomer soln. 1.0% 12.0 Lanette ^® E 0.6 Sodium lauryl ether sulfate (27% in water) 3.5 Potassium Ricinusöl Soap (12,5% in water) 1.2 Potassium salt soap (12.5% in water) 1.2 Cutina ^® GMS SE 1.6 Cutina ^® AGS 1.6 Eutanol ^® G 1.6 Stenol ^® 16/18 9.6 Eumulgin ^® B2 2.4 L-serine 0.5 EDTA-Na4 powder 87% 0.2 Phospholipid ^® EFA 0.1 ammonium sulfate 0.4 sodium 0.2 Ascorbic acid E 300 DAB 0.1 Tween® ^20V 0.2 alpha-lipoic acid 0.2 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.31 4,4'-diaminodiphenylamine sulfate 0.04 resorcinol 0.08 m-aminophenol 0.06 N, N'-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine 0.20 raw material Concentration [%] Preferences. Ammoniumcarbomer soln. 1.0% 12.0 Lanette ^® E 0.6 Sodium lauryl ether sulfate (27% in water) 3.5 Potassium Ricinusöl Soap (12,5% in water) 1.2 Potassium salt soap (12.5% in water) 1.2 Cutina ^® GMS SE 1.6 Cutina ^® AGS 1.6 Eutanol ^® G 1.6 Stenol ^® 16/18 9.6 Eumulgin ^® B2 2.4 L-serine 0.5 EDTA-Na4 powder 87% 0.2 Phospholipid ^® EFA 0.1 ammonium sulfate 0.4 sodium 0.2 Ascorbic acid E 300 DAB 0.1 Tween® ^20V 0.2 alpha-lipoic acid 0.2 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.16 resorcinol 0.51 m-aminophenol 0.12 2-amino-4-Hydroxyethylaminoanisolsulfat 0.18 HC Red 13 0.30 raw material Concentration [%] Preferences. Ammoniumcarbomer soln. 1.0% 12.0 Lanette ^® E 0.6 Sodium lauryl ether sulfate (27% in water) 3.5 Potassium Ricinusöl Soap (12,5% in water) 1.2 Potassium salt soap (12.5% in water) 1.2 Cutina ^® GMS SE 1.6 Cutina ^® AGS 1.6 Eutanol ^® G 1.6 Stenol ^® 16/18 9.6 Eumulgin ^® B2 2.4 L-serine 0.5 EDTA-Na4 powder 87% 0.2 Phospholipid ^® EFA 0.1 ammonium sulfate 0.4 sodium 0.2 Ascorbic acid E 300 DAB 0.1 Tween® ^20V 0.2 alpha-lipoic acid 0.2 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.55 m-aminophenol 0.22 2-amino-4-Hydroxyethylaminoanisolsulfat 0.04 4-chlororesorcinol 0.78 HC Yellow 2 0.15 HC Orange 1 0.25 raw material Concentration [%] Preferences. Ammoniumcarbomer soln. 1.0% 12.0 Lanette ^® E 0.6 Sodium lauryl ether sulfate (27% in water) 3.5 Potassium Ricinusöl Soap (12,5% in water) 1.2 Potassium salt soap (12.5% in water) 1.2 Cutina ^® GMS SE 1.6 Cutina ^® AGS 1.6 Eutanol ^® G 1.6 Stenol ^® 16/18 9.6 Eumulgin ^® B2 2.4 L-serine 0.5 EDTA-Na4 powder 87% 0.2 Phospholipid ^® EFA 0.1 ammonium sulfate 0.4 sodium 0.2 Ascorbic acid E 300 DAB 0.1 Tween® ^20V 0.2 alpha-lipoic acid 0.2 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.93 4,5-diamino-1- (2-hydroxyethyl) -1H-pyrazol-sulfate 0.93 2,4-diaminophenoxyethanol dihydrochloride 0.58 resorcinol 0.56 m-aminophenol 0.09 5-amino-2-methylphenol 0.39 Hydroxyethyl-2-nitro-p-toluidine 0.3 raw material Concentration [%] Preferences. Ammoniumcarbomer soln. 1.0% 12.0 Lanette ^® E 0.6 Sodium lauryl ether sulfate (27% in water) 3.5 Potassium Ricinusöl Soap (12,5% in water) 1.2 Potassium salt soap (12.5% in water) 1.2 Cutina ^® GMS SE 1.6 Cutina ^® AGS 1.6 Eutanol ^® G 1.6 Stenol ^® 16/18 9.6 Eumulgin ^® B2 2.4 L-serine 0.5 EDTA-Na4 powder 87% 0.2 Phospholipid ^® EFA 0.1 ammonium sulfate 0.4 sodium 0.2 Ascorbic acid E 300 DAB 0.1 Tween® ^20V 0.2 alpha-lipoic acid 0.2 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.39 2,4-diaminophenoxyethanol dihydrochloride 1.74 resorcinol 0.3 Basic Blue 99 0.3 raw material Concentration [%] Preferences. Ammoniumcarbomer soln. 1.0% 12.0 Lanette ^® E 0.6 Sodium lauryl ether sulfate (27% in water) 3.5 Potassium Ricinusöl Soap (12,5% in water) 1.2 Potassium salt soap (12.5% in water) 1.2 Cutina ^® GMS SE 1.6 Cutina ^® AGS 1.6 Eutanol ^® G 1.6 Stenol ^® 16/18 9.6 Eumulgin ^® B2 2.4 L-serine 0.5 EDTA-Na4 powder 87% 0.2 Phospholipid ^® EFA 0.1 ammonium sulfate 0.4 sodium 0.2 Ascorbic acid E 300 DAB 0.1 Tween® ^20V 0.2 alpha-lipoic acid 0.2 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.73 resorcinol 0.3 m-aminophenol 0.19 3-amino-2-methylamino-6-methoxypyridine 0.01 2,6-dihydroxy-3,4-dimethylpyridine 0.12 HC Yellow 13 0.2 Basic Brown 17 0 raw material Concentration [%] Preferences. Ammoniumcarbomer soln. 1.0% 12.0 Lanette ^® E 0.6 Sodium lauryl ether sulfate (27% in water) 3.5 Potassium Ricinusöl Soap (12,5% in water) 1.2 Potassium salt soap (12.5% in water) 1.2 Cutina ^® GMS SE 1.6 Cutina ^® AGS 1.6 Eutanol ^® G 1.6 Stenol ^® 16/18 9.6 Eumulgin ^® B2 2.4 L-serine 0.5 EDTA-Na4 powder 87% 0.2 Phospholipid ^® EFA 0.1 ammonium sulfate 0.4 sodium 0.2 Ascorbic acid E 300 DAB 0.1 Tween® ^20V 0.2 alpha-lipoic acid 0.2 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.67 resorcinol 0.27 3-amino-2-methylamino-6-methoxypyridine 0.06 4-chlororesorcinol 0.37 1,3-bis (2,4-diaminophenoxy) propane 4HCl 0.2 Basic Red 76 0.2 Basic Brown 17 0.05 raw material Concentration [%] Preferences. Ammoniumcarbomer soln. 1.0% 12.0 Lanette ^® E 0.6 Sodium lauryl ether sulfate (27% in water) 3.5 Potassium Ricinusöl Soap (12,5% in water) 1.2 Potassium salt soap (12.5% in water) 1.2 Cutina ^® GMS SE 1.6 Cutina ^® AGS 1.6 Eutanol ^® G 1.6 Stenol ^® 16/18 9.6 Eumulgin ^® B2 2.4 L-serine 0.5 EDTA-Na4 powder 87% 0.2 Phospholipid ^® EFA 0.1 ammonium sulfate 0.4 sodium 0.2 Ascorbic acid E 300 DAB 0.1 Tween® ^20V 0.2 alpha-lipoic acid 0.2 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.31 4-chlororesorcinol 0.04 resorcinol 0.05 3-Amino-2-chloro-6-methylphenol 0.01 3-amino-2-methylamino-6-methoxypyridine 0.03 Basic Yellow 57 0.08 raw material Concentration [%] Preferences. Ammoniumcarbomer soln. 1.0% 12.0 Lanette ^® E 0.6 Sodium lauryl ether sulfate (27% in water) 3.5 Potassium Ricinusöl Soap (12,5% in water) 1.2 Potassium salt soap (12.5% in water) 1.2 Cutina ^® GMS SE 1.6 Cutina ^® AGS 1.6 Eutanol ^® G 1.6 Stenol ^® 16/18 9.6 Eumulgin ^® B2 2.4 L-serine 0.5 EDTA-Na4 powder 87% 0.2 Phospholipid ^® EFA 0.1 ammonium sulfate 0.4 sodium 0.2 Ascorbic acid E 300 DAB 0.1 Tween® ^20V 0.2 alpha-lipoic acid 0.2 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.71 2,4,5,6-tetra-sulfate 0.23 resorcinol 0.11 2-methyl 0.11 2,7-dihydroxynaphthalene 0.2 HC Red 1 0.2 raw material Concentration [%] Preferences. Ammoniumcarbomer soln. 1.0% 12.0 Lanette ^® E 0.6 Sodium lauryl ether sulfate (27% in water) 3.5 Potassium Ricinusöl Soap (12,5% in water) 1.2 Potassium salt soap (12.5% in water) 1.2 Cutina ^® GMS SE 1.6 Cutina ^® AGS 1.6 Eutanol ^® G 1.6 Stenol ^® 16/18 9.6 Eumulgin ^® B2 2.4 L-serine 0.5 EDTA-Na4 powder 87% 0.2 Phospholipid ^® EFA 0.1 ammonium sulfate 0.4 sodium 0.2 Ascorbic acid E 300 DAB 0.1 Tween® ^20V 0.2 alpha-lipoic acid 0.2 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.67 m-aminophenol 0.12 resorcinol 0.39 2-methyl 0.05 2-amino-3-hydroxypyridine 0.06 HC Blue 12 0.08

For the streak dyed with this staining cream, the following colorimetric values were determined: L value: 25.8 a-value: 2.2 b-value: 4.8

The application preparation prepared analogously to point 9.2 was additionally for determining the gray coverage on 2 different strands dyed (buffalo belly hair and alkinco, light brown).

The Application time was 30 minutes at 32 ° C. Subsequently Each strand was rinsed for one minute with lukewarm water and dried with a hair dryer.

to Determination of the gray coverage index was followed by each strand measured colorimetrically by drying. As a reference, the buffalo belly hair strand also measured colorimetrically before the coloration process.

The following gray coverage index was determined: streak L value a-value b-value Δ value Gray coverage index Buffalo belly hair, uncolored 73.3 -0.4 6.3 51.2 85.4 Alkinco light brown, colored 22.3 3.7 5.7 7.5 Buffalo belly hair, colored 28.9 0.5 4.3 raw material Concentration [%] Preferences. Ammoniumcarbomer soln. 1.0% 12.0 Lanette ^® E 0.6 Sodium lauryl ether sulfate (27% in water) 3.5 Potassium Ricinusöl Soap (12,5% in water) 1.2 Potassium salt soap (12.5% in water) 1.2 Cutina ^® GMS SE 1.6 Cutina ^® AGS 1.6 Eutanol ^® G 1.6 Stenol ^® 16/18 9.6 Eumulgin ^® B2 2.4 L-serine 0.5 EDTA-Na4 powder 87% 0.2 Phospholipid ^® EFA 0.1 ammonium sulfate 0.4 sodium 0.2 Ascorbic acid E 300 DAB 0.1 Tween® ^20V 0.2 alpha-lipoic acid 0.2 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.12 2-methyl 0.28 4-chlororesorcinol 0.13 3-amino-2-methylamino-6-methoxypyridine 0.01 Acid Violet 43 0.2

For the streak dyed with this staining cream, the following colorimetric values were determined: L value: 35.9 a-value: 3.8 b-value: 12.0 raw material Concentration [%] Preferences. Ammoniumcarbomer soln. 1.0% 12.0 Lanette ^® E 0.6 Sodium lauryl ether sulfate (27% in water) 3.5 Potassium Ricinusöl Soap (12,5% in water) 1.2 Potassium salt soap (12.5% in water) 1.2 Cutina ^® GMS SE 1.6 Cutina ^® AGS 1.6 Eutanol ^® G 1.6 Stenol ^® 16/18 9.6 Eumulgin ^® B2 2.4 L-serine 0.5 EDTA-Na4 powder 87% 0.2 Phospholipid ^® EFA 0.1 ammonium sulfate 0.4 sodium 0.2 Ascorbic acid E 300 DAB 0.1 Tween® ^20V 0.2 alpha-lipoic acid 0.2 Ammonia, 25% ad pH 10.5 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.4437 2,4,5,6-tetra-sulfate .7741 m-aminophenol .4200 2-amino-3-hydroxypyridine .1650 4-chlororesorcinol .2400

9.2 colorations

The colorants mentioned under point 9.1 were each immediately before the coloration in the ratio 1 part by weight of cream: 1 part by weight Developer mixed with the following composition: raw material Concentration [% by weight] Na benzoate 0.04 dipicolinic 0.1 disodiumpyrophosphate 0.1 Potassium hydroxide 50% 0.3 1,2-propanediol 1.5 Turpinal® ^® SL 0.4 Paraffin Liquidum 0.3 Genamin ^® STAC 0.4 Eumulgin ^® B2 1.0 Cetearyl Alcohol 3.4 Hydrogen peroxide 50% 8.2 Perfume 0.1 water ad 100

The resulting application mixtures were each dyed to 6 cm long strands (Kerling, 80% mottled). The duration of use was 30 minutes at 32 ° C. Then each tress was rinsed for one minute with lukewarm water and dried with a hair dryer. 10 coloring cream J 10.1 recipes raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. Purely .4700 Sodium sulphite anhydrous A 96% MIN 0.40 Ascorbic acid E 300 DAB 0.10 Turpnial ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Ammonia 25% 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.88 p-aminophenol hydrochloride 0.52 resorcinol 0.43 m-aminophenol 0.8 5-amino-2-methylphenol 0.18 Disperse Violet 1 0.2 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. Purely .4700 Sodium sulphite anhydrous A 96% MIN 0.40 Ascorbic acid E 300 DAB 0.10 Turpnial ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Ammonia 25% 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.38 resorcinol 0.13 m-aminophenol 0.07 5-amino-2-methylphenol 0.22 3-Amino-2-chloro-6-methylphenol 0.07 2,7-dihydroxynaphthalene 0.08 1,5-dihydroxynaphthalene 0.05 1-phenyl-3-methyl-5-pyrazolone 0.1 HC Red 7 0.2 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. Purely .4700 Sodium sulphite anhydrous A 96% MIN 0.40 Ascorbic acid E 300 DAB 0.10 Turpnial ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Ammonia 25% 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.21 resorcinol 0.55 m-aminophenol 0.15 3-amino-2-methylamino-6-methoxypyridine 0.04 Basic Brown 16 0.20 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. Purely .4700 Sodium sulphite anhydrous A 96% MIN 0.40 Ascorbic acid E 300 DAB 0.10 Turpnial ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Ammonia 25% 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.39 resorcinol 0.30 2,4-Diaminophenoxyethanol 1.74 HC Blue 2 0.20 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. Purely .4700 Sodium sulphite anhydrous A 96% MIN 0.40 Ascorbic acid E 300 DAB 0.10 Turpnial ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Ammonia 25% 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.73 2,4-diaminophenoxyethanol 2 HC 1.91 resorcinol 0.33 4-nitro-o-phenylenediamine 0.30 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. Purely .4700 Sodium sulphite anhydrous A 96% MIN 0.40 Ascorbic acid E 300 DAB 0.10 Turpnial ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Ammonia 25% 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.82 resorcinol 0.17 2,7-dihydroxynaphthalene 0.29 1,3-bis (2,4-diaminophenoxy) propan-tetrahydrochloird 0.44 Basic Violet 2 0.30 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. Purely .4700 Sodium sulphite anhydrous A 96% MIN 0.40 Ascorbic acid E 300 DAB 0.10 Turpnial ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Ammonia 25% 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.36 resorcinol 0.24 m-aminophenol 0.12 o-aminophenol 0.16 2,6-diaminopyridine 0.55 HC Red 3 0.20 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. Purely .4700 Sodium sulphite anhydrous A 96% MIN 0.40 Ascorbic acid E 300 DAB 0.10 Turpnial ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Ammonia 25% 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.31 4,4'-diaminodiphenylamine sulfate 0.04 resorcinol 0.08 m-aminophenol 0.06 N, N'-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine 0.20 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. Purely .4700 Sodium sulphite anhydrous A 96% MIN 0.40 Ascorbic acid E 300 DAB 0.10 Turpnial ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Ammonia 25% 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.16 resorcinol 0.51 m-aminophenol 0.12 2-amino-4-Hydroxyethylaminoanisolsulfat 0.18 HC Red 13 0.30 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. Purely .4700 Sodium sulphite anhydrous A 96% MIN 0.40 Ascorbic acid E 300 DAB 0.10 Turpnial ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Ammonia 25% 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl) amine trihydrochloride 2.55 m-aminophenol 0.22 2-amino-4-Hydroxyethylaminoanisolsulfat 0.04 4-chlororesorcinol 0.78 HC Yellow 2 0.15 HC Orange 1 0.25 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. Purely .4700 Sodium sulphite anhydrous A 96% MIN 0.40 Ascorbic acid E 300 DAB 0.10 Turpnial ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Ammonia 25% 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.93 4,5-diamino-1- (2-hydroxyethyl) -1H-pyrazol-sulfate 0.93 2,4-diaminophenoxyethanol dihydrochloride 0.58 resorcinol 0.56 m-aminophenol 0.09 5-amino-2-methylphenol 0.39 Hydroxyethyl-2-nitro-p-toluidine 0.3 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. Purely .4700 Sodium sulphite anhydrous A 96% MIN 0.40 Ascorbic acid E 300 DAB 0.10 Turpnial ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Ammonia 25% 82.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.39 2,4-diaminophenoxyethanol dihydrochloride 1.74 resorcinol 0.3 Basic Blue 99 0.3 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. Purely .4700 Sodium sulphite anhydrous A 96% MIN 0.40 Ascorbic acid E 300 DAB 0.10 Turpnial ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Ammonia 25% 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.73 resorcinol 0.3 m-aminophenol 0.19 3-amino-2-methylamino-6-methoxypyridine 0.01 2,6-dihydroxy-3,4-dimethylpyridine 0.12 HC Yellow 13 0.2 Basic Brown 17 0 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. Purely .4700 Sodium sulphite anhydrous A 96% MIN 0.40 Ascorbic acid E 300 DAB 0.10 Turpnial ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Ammonia 25% 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.67 resorcinol 0.27 3-amino-2-methylamino-6-methoxypyridine 0.06 4-chlororesorcinol 0.37 1,3-bis (2,4-diaminophenoxy) propane 4HCl 0.2 Basic Red 76 0.2 Basic Brown 17 0.05 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. Purely .4700 Sodium sulphite anhydrous A 96% MIN 0.40 Ascorbic acid E 300 DAB 0.10 Turpnial ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Ammonia 25% 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.31 4-chlororesorcinol 0.04 resorcinol 0.05 3-Amino-2-chloro-6-methylphenol 0.01 3-amino-2-methylamino-6-methoxypyridine 0.03 Basic Yellow 57 0.08 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. Purely .4700 Sodium sulphite anhydrous A 96% MIN 0.40 Ascorbic acid E 300 DAB 0.10 Turpnial ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Ammonia 25% 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.71 2,4,5,6-tetra-sulfate 0.23 resorcinol 0.11 2-methyl 0.11 2,7-dihydroxynaphthalene 0.2 HC Red 1 0.2 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. Purely .4700 Sodium sulphite anhydrous A 96% MIN 0.40 Ascorbic acid E 300 DAB 0.10 Turpnial ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Ammonia 25% 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.67 m-aminophenol 0.12 resorcinol 0.39 2-methyl 0.05 2-amino-3-hydroxypyridine 0.06 HC Blue 12 0.08 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. Purely .4700 Sodium sulphite anhydrous A 96% MIN 0.40 Ascorbic acid E 300 DAB 0.10 Turpnial ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Ammonia 25% 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.12 2-methyl 0.28 4-chlororesorcinol 0.13 3-amino-2-methylamino-6-methoxypyridine 0.01 Acid Violet 43 0.2 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. Purely .4700 Sodium sulphite anhydrous A 96% MIN 0.40 Ascorbic acid E 300 DAB 0.10 Turpnial ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Ammonia 25% 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.4437 2,4,5,6-tetra-sulfate .7741 m-aminophenol .4200 2-amino-3-hydroxypyridine .1650 4-chlororesorcinol .2400

The application preparation prepared analogously to point 10.2 was additionally for determining the gray coverage on 2 different strands dyed (buffalo belly hair and alkinco, light brown).

The Application time was 30 minutes at 32 ° C. Subsequently Each strand was rinsed for one minute with lukewarm water and dried with a hair dryer.

to Determination of the gray coverage index was followed by each strand measured colorimetrically by drying. As a reference, the buffalo belly hair strand also measured colorimetrically before the coloration process.

The following gray coverage index was determined: streak L value a-value b-value Δ value Gray coverage index Buffalo belly hair, uncolored 74.6 -0.2 9.1 58.0 81.2 Alkinco light brown, colored 17.2 3.4 1.4 10.9 Buffalo belly hair, colored 26.8 7.5 4.6

10.2 Coloring

The colorants mentioned under point 10.1 were in each case immediately before the dyeing in the ratio 5 parts by weight cream: 4 parts by weight Developer mixed with the following composition: raw material Concentration [% by weight] Caustic soda 45% techn. 0.8 dipicolinic 0.1 disodiumpyrophosphate 0.03 Turpinal® ^® SL 1.5 FAEOS-Na C12-14 2EO 27% 2.0 Aculyn ^® 33 4.5 Hydrogen peroxide 50% 10.0 water ad 100

The resulting application mixtures were each dyed to 6 cm long strands (Kerling, 80% mottled). The duration of use was 30 minutes at 32 ° C. Then each tress was rinsed for one minute with lukewarm water and dried with a hair dryer. 11 Colorant base K 11.1 Formulations raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50 A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. Purely .4700 sodium; anhydrous 0.40 Ascorbic acid E 300 DAB 0.10 Turpinal® ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Monoethanolamine 4.0 Ammonia, 25% in water 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.88 p-aminophenol hydrochloride 0.52 resorcinol 0.43 m-aminophenol 0.8 5-amino-2-methylphenol 0.18 Disperse Violet 1 0.2 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50 A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. purely .4700 sodium; anhydrous 0.40 Ascorbic acid E 300 DAB 0.10 Turpinal® ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Monoethanolamine 4.0 Ammonia, 25% in water 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.38 resorcinol 0.13 m-aminophenol 0.07 5-amino-2-methylphenol 0.22 3-Amino-2-chloro-6-methylphenol 0.07 2,7-dihydroxynaphthalene 0.08 1,5-dihydroxynaphthalene 0.05 1-phenyl-3-methyl-5-pyrazolone 0.1 HC Red 7 0.2 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50 A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. purely .4700 sodium; anhydrous 0.40 Ascorbic acid E 300 DAB 0.10 Turpinal® ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Monoethanolamine 4.0 Ammonia, 25% in water 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.21 resorcinol 0.55 m-aminophenol 0.15 3-amino-2-methylamino-6-methoxypyridine 0.04 Basic Brown 16 0.20 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50 A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. purely .4700 sodium; anhydrous 0.40 Ascorbic acid E 300 DAB 0.10 Turpinal® ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Monoethanolamine 4.0 Ammonia, 25% in water 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.39 resorcinol 0.30 2,4-Diaminophenoxyethanol 1.74 HC Blue 2 0.20 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50 A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. purely .4700 sodium; anhydrous 0.40 Ascorbic acid E 300 DAB 0.10 Turpinal® ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Monoethanolamine 4.0 Ammonia, 25% in water 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.73 2,4-diaminophenoxyethanol 2 HC 1.91 resorcinol 0.33 4-nitro-o-phenylenediamine 0.30 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50 A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. purely .4700 sodium; anhydrous 0.40 Ascorbic acid E 300 DAB 0.10 Turpinal® ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Monoethanolamine 4.0 Ammonia, 25% in water 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.82 resorcinol 0.17 2,7-dihydroxynaphthalene 0.29 1,3-bis (2,4-diaminophenoxy) propan-tetrahydrochloird 0.44 Basic Violet 2 0.30 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50 A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. purely .4700 sodium; anhydrous 0.40 Ascorbic acid E 300 DAB 0.10 Turpinal® ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Monoethanolamine 4.0 Ammonia, 25% in water 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.36 resorcinol 0.24 m-aminophenol 0.12 o-aminophenol 0.16 2,6-diaminopyridine 0.55 HC Red 3 0.20 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50 A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. purely .4700 sodium; anhydrous 0.40 Ascorbic acid E 300 DAB 0.10 Turpinal® ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Monoethanolamine 4.0 Ammonia, 25% in water 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.31 4,4'-diaminodiphenylamine sulfate 0.04 resorcinol 0.08 m-aminophenol 0.06 N, N'-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine 0.20 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50 A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. purely .4700 sodium; anhydrous 0.40 Ascorbic acid E 300 DAB 0.10 Turpinal® ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Monoethanolamine 4.0 Ammonia, 25% in water 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.16 resorcinol 0.51 m-aminophenol 0.12 2-amino-4-Hydroxyethylaminoanisolsulfat 0.18 HC Red 13 0.30 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50 A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. purely .4700 sodium; anhydrous 0.40 Ascorbic acid E 300 DAB 0.10 Turpinal® ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Monoethanolamine 4.0 Ammonia, 25% in water 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.55 m-aminophenol 0.22 2-amino-4-Hydroxyethylaminoanisolsulfat 0.04 4-chlororesorcinol 0.78 HC Yellow 2 0.15 HC Orange 1 0.25 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50 A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. purely .4700 sodium; anhydrous 0.40 Ascorbic acid E 300 DAB 0.10 Turpinal® ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Monoethanolamine 4.0 Ammonia, 25% in water 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 2.93 4,5-diamino-1- (2-hydroxyethyl) -1H-pyrazol-sulfate 0.93 2,4-diaminophenoxyethanol dihydrochloride 0.58 resorcinol 0.56 m-aminophenol 0.09 5-amino-2-methylphenol 0.39 Hydroxyethyl-2-nitro-p-toluidine 0.3 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50 A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. purely .4700 sodium; anhydrous 0.40 Ascorbic acid E 300 DAB 0.10 Turpinal® ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Monoethanolamine 4.0 Ammonia, 25% in water 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 3.39 2,4-diaminophenoxyethanol dihydrochloride 1.74 resorcinol 0.3 Basic Blue 99 0.3 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50 A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. purely .4700 sodium; anhydrous 0.40 Ascorbic acid E 300 DAB 0.10 Turpinal® ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Monoethanolamine 4.0 Ammonia, 25% in water 8.0 Monoethanolamine 1.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.73 resorcinol 0.3 m-aminophenol 0.19 3-amino-2-methylamino-6-methoxypyridine 0.01 2,6-dihydroxy-3,4-dimethylpyridine 0.12 HC Yellow 13 0.2 Basic Brown 17 0 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50 A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. purely .4700 sodium; anhydrous 0.40 Ascorbic acid E 300 DAB 0.10 Turpinal® ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Monoethanolamine 4.0 Ammonia, 25% in water 8.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.67 resorcinol 0.27 3-amino-2-methylamino-6-methoxypyridine 0.06 4-chlororesorcinol 0.37 1,3-bis (2,4-diaminophenoxy) propane 4HCl 0.2 Basic Red 76 0.2 Basic Brown 17 0.05 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50 A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. purely .4700 sodium; anhydrous 0.40 Ascorbic acid E 300 DAB 0.10 Turpinal® ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Monoethanolamine 4.0 Ammonia, 25% in water 8.0 Monoethanolamine 1.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.31 4-chlororesorcinol 0.04 resorcinol 0.05 3-Amino-2-chloro-6-methylphenol 0.01 3-amino-2-methylamino-6-methoxypyridine 0.03 Basic Yellow 57 0.08 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50 A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. purely .4700 sodium; anhydrous 0.40 Ascorbic acid E 300 DAB 0.10 Turpinal® ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Monoethanolamine 4.0 Ammonia, 25% in water 8.0 Monoethanolamine 1.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 0.71 2,4,5,6-tetra-sulfate 0.23 resorcinol 0.11 2-methyl 0.11 2,7-dihydroxynaphthalene 0.2 HC Red 1 0.2 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50 A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. purely .4700 sodium; anhydrous 0.40 Ascorbic acid E 300 DAB 0.10 Turpinal® ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Monoethanolamine 4.0 Ammonia, 25% in water 8.0 Monoethanolamine 1.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.67 m-aminophenol 0.12 resorcinol 0.39 2-methyl 0.05 2-amino-3-hydroxypyridine 0.06 HC Blue 12 0.08 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50 A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. purely .4700 sodium; anhydrous 0.40 Ascorbic acid E 300 DAB 0.10 Turpinal® ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Monoethanolamine 4.0 Ammonia, 25% in water 8.0 Monoethanolamine 1.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.12 2-methyl 0.28 4-chlororesorcinol 0.13 3-amino-2-methylamino-6-methoxypyridine 0.01 Acid Violet 43 0.2 raw material Concentration [% by weight] Hydrenol ^® D 20.0 Lorol® ^® techn. 12.0 Eumulgin ^® B3 1.0 Eumulgin ^® B2 1.0 Mergital ^® CS 50 A 4.0 1,2-propanediol 2.0 Xanthan FN 0.4 Merquat ^® 281 3.0 Amphoterge K-2 ^® 2.0 Ammonium sulfate techn. purely .4700 sodium; anhydrous 0.40 Ascorbic acid E 300 DAB 0.10 Turpinal® ^® SL 0.20 Sodium silicate 40/42 0.50 Perfume 0.30 Monoethanolamine 4.0 Ammonia, 25% in water 8.0 Monoethanolamine 1.0 water ad 100 N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol-1-yl) propyl] amine trihydrochloride 1.4 2,4,5,6-tetra-sulfate 0.8 m-aminophenol 0.4 2-amino-3-hydroxypyridine 0.2 4-chlororesorcinol 0.2

11.2 Coloring

The colorants mentioned under point 11.1 were in each case mixed immediately before the dyeing in the ratio 5 parts by weight of cream: 4 parts by weight of developer with the following composition: raw material Concentration [% by weight] Caustic soda 45% techn. 0.8 dipicolinic 0.1 disodiumpyrophosphate 0.03 Turpinal® ^® SL 1.5 FAEOS-Na C12-14 2EO 27% 2.0 Aculyn ^® 33 4.5 Hydrogen peroxide 50% 10.0 water ad 100

The resulting application mixtures were each on 6 cm long Strands (Kerling, 80% mottled) dyed. The Application time was 30 minutes at 32 ° C. Subsequently Each strand was rinsed for one minute with lukewarm water and dried with a hair dryer.

12 List of used commercial products

The commercial products used in the examples are defined as follows: Aculyn ^® 33 Acrylic polymer (about 28% solids in water, INCI name: Acrylates copolymer) Akypo Soft 45 NV ^® Lauryl Alcohol 4.5 EO Acetic Acid Sodium Salt (at least 21%) Active substance content; INCI name: sodium laureth-6 carboxylates) (Chem-Y) Ammoniumcarbopollsg. Solution of an ammonium salt of a methacrylic acid-methyl acrylate Copolymers (INCI name: Ammonium Polyacrylate) (Röhm GmbH) Ammoniumrohagitlösung Solution of an ammonium salt of an acrylic acid polymer (INCI Name: Ammonium Acrylates Copolymer) (Goodrich) AMP 95 2-amino-2-methyl-propanol (about 93-97% active in water, INCI Name: aminomethyl propanol) (Dow Chemical) AMP Ultra PC 2000 2-amino-2-methyl-propanol (about 94.5-95.4% active substance in water; Name: aminomethyl propanol) (Dow Chemical) Amphoterge K 2 ^® Disodium-N- [2- (carboxylatomethoxy) ethyl] -N- [2 - [(1- oxododecyl) amino] ethyl] glycinate; 40% by weight of active substance content (INCI Name: Disodium Cocoamphodipropionate (Manufacturer: Lonza) Antil ^® 141 Polyoxyethylene propylene glycol dioleate (about 40% active ingredient content; Name: Propylene Glycol, PEG-55 Propylene Glycol Oleate) (Goldschmidt) Benecel ^® MP 333C Highly purified methylhydroxypropylcellulose (max 10% water; Name: hydroxypropyl methylcellulose) (Hercules) Carbopol ^® Ultrez 10 Polyacrylate (INCI name: carbomer) (Lubrizol) Cetiol ^® HE Coconut monoglyceride with approx. 7.3 EO units (INCI name: PEG-7 Glyceryl cocoate) (Cognis) Cetiol ^® V Oleic acid decyl ester (INCI name: Decyl Oleate) (Cognis) Comperlan® ^® 100 Coco fatty acid monoethanolamide (95% amide content, 5% ester of Coconut fatty acid with monoethanolamine, solid, INCI name: Cocamide MEA) (Cognis) Cosmedia® ^® CTH (E) about 50% active ingredient content, INCI name: Polyquaternium-37, Propylene Glycol Dicaprylate / Dicaprate, PPG-1 Trideceth-6 (Cognis) Cutina ^® AGS Ethylene glycol distearate (INCI name: Glycol Distearate) (Cognis) Cutina ^® GMS Glyceryl monostearate (max 2% water, INCI name: glyceryl Stearates) (Cognis) Cutina ^® GMS-SE INCI name: Glyceryl Stearate SE (Cognis) Dehydol ^® LS 2 C _12-14 fatty alcohol with approx. 2 EO units (INCI name: Laureth- 2) (Cognis Pulcra) Dehyquart® ^® A-CA Trimethylhexadecylammonium chloride (about 24-26% active ingredient; Name: Aqua (Water), Cetrimonium Chloride) (Cognis) Disponil ^® FES 77 Fatty alcohol ether sulfate (about 31-33% active ingredient content in water; Name: Sodium Coceth-30 Sulfate) (Cognis) Dow ^Corning® DB 110 nonionic silicone emulsion (about 10% active ingredient content; Name: dimethicone) (Dow Corning) Dow ^Corning® 193 Fluid Silicone-glycol copolymer (INCI name: PEG-12 Dimethicone) (Dow Corning) Dow ^Corning® 345 Fluid Decamethylcyclopentasiloxane (INCI name: Cyclomethicone) (Dow Corning) Dow ^Corning® 580 Wax Mixture of stearoxytrimethylsilane and stearyl alcohol (about 40%) stearyl alcohol; INCI name: Stearoxytrimethylsilane, Stearyl Alcohol) (Dow Corning) Edenor ^® C14 Myristic acid (INCI name: Myristic Acid) (Cognis) Edenor ^® PK 1805 Oleic acid (INCI name: Oleic Acid) (Cognis) Elfacos ^® ST 37 INCI name: PEG-22 / dodecyl glycol copolymer (Akzo) Emulgade® ^® 1000 NI INCI name: Cetearyl alcohol, Ceteareth-20) (Cognis) Emulgade® ^® F Mixture of cetylstearyl alcohol, castor oil with approx. 40 EO units and the sodium salt of cetyl stearyl sulfate (INCI name: Cetearyl Alcohol, PEG-40 Castor Oil, Sodium Cetearyl Sulfate) (Cognis) Eumulgin ^® B1 Cetylstearyl alcohol with approx. 12 EO units (INCI name: Ceteareth- 12) (Cognis) Eumulgin ^® B2 Cetylstearyl alcohol with approx. 20 EO units (INCI name: Ceteareth- 20) (Cognis) Eumulgin ^® B3 Cetylstearyl alcohol with approx. 30 EO units (INCI name: Ceteareth- 30) (Cognis) Eumulgin ^® KE 2602 ethoxylated oleyl alcohol (INCI name: Oleth-7) (Cognis) Eumulgin ^® O5 Oleyl cetyl alcohol with about 5 EO units on a vegetable basis (INCI Name: Oleth-5) (Cognis) Eumulgin ^® RO 40 ethoxylated castor oil with about 40 EO units (INCI name: PEG-40 Castor Oil) (Cognis) Eutanol ^® G 2-Octyldodecyl alcohol (INCI name: octyldodecanol) (Cognis) Genamin ^® STAC Trimethylstearylammonium chloride (about 80% active in isopropanol; INCI name: Steartrimonium Chloride) (Clariant) Gluadin® ^® W40 Wheat protein hydrolyzate (at least 40-44% solids in water; Name: Aqua (Water), Hydrolyzed Wheat Protein, Sodium Benzoate, Phenoxyethanol, methylparaben, propylparaben) (Cognis) Hostaphat ^® KW 340 D Mono- and di- and tri- (C _12-14 -alkyl tetraglycol ether) ortho Phosphoric acid ester (INCI name: Trilaureth-4 Phosphate) (Clariant) Hydrenol ^® D C _{18-18 fatty} alcohol (INCI name: Cetearyl alcohol) (Cognis) Lame Soft ^® PO65 Alkylpolyglucoside oleic acid monoglyceride Mixture (about 65-70% solids; INCI name: Coco-Glucoside, Glyceryl Oleate, Aqua (Water)) (Cognis) Lanette ^® 14 Myristyl alcohol (INCI name: Myristyl Alcohol) (Cognis) Lanette ^® E Fatty alcohol sulfate sodium salt (about 90-96% active ingredient content; Name: Sodium Cetearyl Sulfate) (Cognis) Lanette ^® N Mixture of 90 parts by weight of cetylstearyl alcohol and 10 parts by weight Natriumcetylstearylsulfatl (INCI name: Cetearyl Alcohol, Sodium Cetearyl sulphates) (Cognis) Lorol® ^® C16 INCI name: Cetyl Alcohol (Cognis) Lorol® ^® tech. C _12-18 fatty alcohol (INCI name: Coconut alcohol) (Cognis) Lowenol ^® C-279 Fatty alcohol with approx. 2 EO units (at least 99% active substance content; INCI name: Ceteareth-2) (Lowenstein) Luviquat ^® Care Vinylimidazolium methosulfate-vinylpyrrolidone copolymer (20:80) (6-7% Solid in water; INCI name: Polyquaternium-44) (BASF) Luviquat.RTM ^® Excellence 3-Methyl-1-vinylimidazolium chloride-vinylpyrrolidone copolymer (95: 5) (38- 42% solids in water; INCI name: Polyquaternium-16) (BASF) Luviquat Mono CP ^® Hexadecyl (2-hydroxyethyl) dimethyl ammonium dihydrogen phosphate (27-33% Solid in water; INCI name: hydroxyethyl cetyldimonium Phosphates) (BASF) Mergital ^® CS 50A Fatty alcohol with approx. 50 EO units (INCI name: Ceteareth-50) (Cognis) Merquat ^® 280 Dimethyldiallylammonium chloride acrylic acid copolymer (approx Active substance in water; INCI name: Polyquaternium-22) (ondeo Nalco) Merquat ^® 281 Dimethyldiallylammonium chloride acrylic acid copolymer (about 39-43% Solid in water; INCI name: Polyquaternium-22) (ondeo Nalco) Merquat ^® Plus 3330 Dimethyldiallylammonium chloride acrylic acid acrylamide terpolymer (about 9.5% Solid in water; INCI name: Polyquaternium-39) (ondeo Nalco) Natrosol ^® 250 HR Hydroxyethylcellulose (INCI name: Hydroxyethylcellulose) (Hercules) Phospholipid ^® EFA (about 30% solids in water / propylene glycol; Name: Linoleamidopropyl PG-Dimonium Chloride Phosphate) (Uniqema) Plantacare® ^® 2000 C _8-16 alkylglucoside (about 51-55% active ingredient content in water; Name: Decyl Glucoside, Aqua (Water)) (Cognis) Plantapon ^® LGC about 28-34% active ingredient content in water; INCI name: Lauryl Glucose Carboxylates, Lauryl Glucosides (Cognis) Polawax ^® GP 200 INCI name: Cetearyl Alcohol, PEG-20 Stearate (Croda) Polychol ^® 5 ethoxylated lanolin alcohol with approx. 5 EO units (INCI name: Laneth-5) (Croda) Polyglycol 400 Polyethylene glycol (INCI name: PEG-8) (Cognis) Polymer ^® W 37194 about 20% by weight of active substance content in water; INCI name: Acrylamidopropyltrimonium Chloride / Acrylates Copolymer (Stockhausen) Procetyl ^® AWS ethoxylated and propoxylated hexadecanol (20 EO + 5 PO) (INCI Name: PPG-5-Ceteth-20) (Croda) Protelan ^® MST 35 Mixture of sodium N-myristoyl sarcosinate and sodium N-methyl-N- cocoyltaurate (40% by weight of active substance, Zschimmer & Schwartz) Puricare ^® LS 9658 Moringa pterygosperm extract, in water / glycerin (INCI name: Water, Glycerine, Moringa Pterygosperma Seed Extract) (Cognis) Stenol ^® 1618 C _16-18 fatty alcohol (INCI name: Cetearyl Alcohol) (Cognis) Synthalen ^® K Polyacrylic acid (about 89% active ingredient content, INCI name: carbomer) (3V Sigma) Texapon ^® K 14 S 70 Lauryl myristyl ether sulfate sodium salt (about 68% to 73% Active ingredient content "; INCI name: Sodium Myreth Sulfate) (Cognis) Texapon ^® NSO UP Lauryl ether sulfate, sodium salt (about 27.5% active ingredient; INCI name: Sodium Laureth Sulfate) (Cognis) Turpinal® ^® SL 1-hydroxyethane-1,1-diphosphonic acid (about 58-61% active ingredient content; INCI name: Etidronic Acid, Aqua (Water)) (Solutia) Tween ^® 20 ethoxylated sorbitan monolaurate (about 2.5-3 wt% water content; Name: Polysorbate-20) (Croda) ^Xanthan® FN INCI name: Xanthan Gum (Jungbunzlauer)

QUOTES INCLUDE IN THE DESCRIPTION

This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.

Cited patent literature

• DE 3725030 A [0043]
• - DE 3723354 A [0043]
• - DE 3926344 A [0043]

Claims (7)

Agent for coloring keratinic fibers, in particular human hair, characterized in that it contains in a cosmetically acceptable carrier as the developing component N- (4-amino-3-methylphenyl) -N- [3- (1H-imidzol-1-yl) propyl] amine

or one of its physiologically acceptable salts in combination with at least one further developer component and / or at least one coupler component and / or at least one substantive dye. Means according to claim 1, characterized in that it as developer components N- (4-amino-3-methylphenyl) -N- [3- (1H-imidzol-1-yl) propyl] amine trihydrochloride contains. Agent according to one of claims 1 or 2, characterized in that the at least one further developer component is selected from 4-amino-3-methylphenol, 2,4,5,6-tetraaminopyrimidine, 2- (2-hydroxyethyl) -p-phenylenediamine, bis (5-amino-2-hydroxyphenyl) -methane and 1- (2-hydroxyethyl) -4,5-diaminopyrazole and their physiological compatible salts. Agent according to one of claims 1 to 3, characterized in that it contains 2-methoxymethyl-p-phenylenediamine as developer component or one of its physiologically acceptable salts. Agent according to one of claims 1 to 4, characterized in that the at least one further coupler component is selected from resorcinol, 4-chlororesorcinol, m-aminophenol, 1-Methoxy-2-amino-4- (2-hydroxyethylamino) -benzene, 3-amino-2-chloro-6-methylphenol, 2,6-dihydroxy-3,4-dimethylpyridine, 2-methyl-4-chloro-5-aminophenol, 6-Methoxy-2-methylamino-3-aminopyridine, 2-amino-3-hydroxypyridine and 2,6-di (2-hydroxyethylamino) toluene and their physiological compatible salts. Agent according to one of claims 1 to 5, characterized in that the at least one further substantive Dye is selected from Basic Brown 17, N, N'-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine, 1-methyl-3-nitro-4- (2-hydroxyethylamino) benzene, 4- (3-hydroxypropylamino) -3-nitrophenol, Acid Red 33 and Acid Red 52 and their physiologically acceptable Salt. Agent according to one of claims 1 to 6, characterized in that except those mentioned no further Contains dye precursors and / or direct dyes.