DE202005014974U1 - Water-in-oil-emulsion preparation, useful in skin and mucous membrane application, comprises silicone, polyethylene glycol/polypropylene glycol-dimethicone, a lipid phase, water and a particle forming material - Google Patents

Abstract

Water-in-oil-emulsion preparation comprises at least a silicone; at least a polyethylene glycol (PEG)/polypropylene glycol (PPG)-dimethicone with 15-20 units of PEG and PPG as an emulgator; a lipid phase; water (0.1-5%); and at least a particle forming material.

Description

The The present invention relates to a preparation, in particular a cosmetic preparation and a process for its preparation.

The inventive preparation lies in the form of a water-in-oil or water-in-silicone emulsion. The use of W / O or W / Si emulsions in the field of cosmetics is known. silicones be due to their non-transfer properties like for cosmetic compositions used since the finished products smoothly applicable, adherent and stationary. However, have the known compositions often due to the high water content, which is inherent in these compositions has the disadvantage that they have a unpleasant burning cooling effect cause. The products of the prior art also have the Disadvantage that they are damaged by moisture, e.g. Sweat or tears, run and spread out. To avoid this, the formulations became film-forming agents added. However, this can lead to sticky products that a feeling of tension on the skin cause.

Around To lend structure to the composition are often waxes and waxy compounds added, which have the disadvantage that the resulting film is dull. Besides, they are Waxes usually refractory, resulting in higher temperatures for processing must be applied. This complicates the processing of silicone-containing compositions, because usually volatile Silicones used as solvents Need to become, which have a low flash point, below 80 ° C. For processing of such compositions therefore increased Safety precautions are taken.

One Another problem of cosmetic compositions that have a high Proportion of volatile and non-volatile Containing silicones is that they can be applied well and are adherent, but that after evaporation of the volatile solvent a feeling of tension On the skin arises, which is perceived as unpleasant.

Out JP 2001 058921 is, for example, a water-in-oil emulsion known, which has excellent stability and which is a specific Silicone, Oil, Water, ethyl alcohol and dextrin fatty acid ester contains. Of the Proportion of water and ethyl alcohol is very high in these emulsions high. Such high levels of ethanol can cause irritation to the skin and especially the mucous membranes to lead. In addition, you can aqueous Systems of this type are microbially contaminated. To a contamination to avoid Preservatives are used, in particular in conjunction with ethanol to new problems in terms of poorer skin tolerance to lead can.

Farther is a cosmetic preparation known from JP 2000 0239119, the may contain a pearl pigment, wherein the emulsion of a silicone compound built in combination with a low alcohol and water is. Also with this product is the proportion of water and alcohol high.

A gelatinous product will be in JP 09194323 described, which also has a very high water content. This product can be made into make-up products such as eye shadow and lipstick as well as sunscreen. All these compositions have in common that a polyether-modified silicone is used as the emulsifier. In all of these compositions, the levels of water and alcohol are high.

Farther it was known from US 2004/0028633 A1, a water-in-oil emulsion with a high content of internal aqueous phase for which special Emulsifiers and salts used for stabilization. The emulsifier is a combination of two different polyether-modified Suggested silicones of different molecular weight, which stabilize the outer oil phase, while the salt the inner watery Phase is to stabilize. The water content can be up to 80% be.

Out EP 0 568 102 there is known a silicone gel composition consisting of silicone oil, water and an emulsifier, wherein the emulsifier is a polyether-modified silicone having 25-30 ethoxy and propoxy units, respectively.

One Disadvantage of the known compositions is their high water content, which in addition to the microbiological problems to a significantly cooling Effect leads. Unlike so-called "cold creams ", the large area over face and body distributed and where a cooling effect is desired, is at small area Order, especially near the eyes, the cooling effect as disturbing or even as irritation.

task the invention was to improve the known compositions, and in particular to provide preparations which are based on skin and mucous membranes, especially eyelids and lips can be applied without there a disturbing and tension to produce their original flexibility and do not lose elasticity that is adherent and stationary, can be easily removed from make-up and remain stable for a long time. Furthermore, products are to be provided as desired semi-matt, semi-glossy, shiny or high gloss Deliver films.

These Problems are solved with a preparation as defined in claim 1 is.

• a) mindestens ein Silikon;
• b) mindestens ein PEG/PPG-Dimethicone mit jeweils 15 bis 20 Einheiten PEG und PPG als Emulgator;
• c) eine Lipidphase, die Öl, Fett und/oder Wachs aufweisen kann;
• d) Wasser in einem Anteil von 0,1 bis 5 % bezogen auf das Gesamtgewicht der Zusammensetzung; und
• e) mindestens einen teilchenförmigen Inhaltsstoff.

The preparation according to the invention, which is in the form of a water-in-oil emulsion, contains the following components:

• a) at least one silicone;
• b) at least one PEG / PPG dimethicone having in each case 15 to 20 units of PEG and PPG as emulsifier;
• c) a lipid phase which may contain oil, fat and / or wax;
• d) water in a proportion of 0.1 to 5% based on the total weight of the composition; and
• e) at least one particulate ingredient.

Further Ingredients can added as needed to modify the properties of the product.

Surprisingly it was found that a preparation of the claimed form, which is present as W / O emulsion or W / Si emulsion for silicones has advantageous properties, without generating tension feelings. About that In addition, the preparation according to the invention remains stable for a long time. It has been found that the preparation according to the invention, when applied to the skin, by moisture, the is present at the applied location or its immediate vicinity or arises, such as sweat, tears, etc., not only is not carried away, but even stabilized. This effect can only occur if the preparation already a small amount of water or other polar substances, such as mono- or polyhydric alcohols. Without to be bound by theory, it is believed that in a Preparation of the claimed type of low proportion of a polar Substance leads to a gelation and in that the formed gel structure additionally incorporated in the preparation Water stabilized. As a result, in the products of the invention achieved the benefits achieved with the silicones and at the same time avoided the otherwise associated problems. These advantageous Properties are only achieved if the preparation already contains a polar substance, especially water, but only in a small amount Proportion of. A preparation that is free of polar solvents leads to application to the skin after evaporation of the solvent to a feeling of tension, while preparations with higher Water content of the above Disadvantages.

Furthermore it was found that the preparation of the invention has a pronounced thixotropic behavior shows. Thixotropic or pseudoplastic properties are for these Kind of compositions very advantageous, since the preparation in pasty Bottled form and does not leak out of the container when Apply but very supple and therefore in a thin layer pleasant to apply. The advantageous properties of the preparation according to the invention arise in addition to the low water content through the use a special combination of emulsifier and silicone.

Of the Silicone portion of the preparation according to the invention can be fleeting or non-volatile Silicones are formed. Preference is given in the preparations according to the invention at least one fleeting Silicone included. fugitive Silicones are known to those skilled in the art, e.g. volatile cyclomethicones and volatile linear dimethicones. examples for volatile Cyclomethicones are cyclic siloxanes having 3 to 7 dimethylsiloxane units, such as cyclotrisiloxane (hexamethylcylotrisiloxane) cyclotetrasiloxane (Octamethylcyclotetrasiloxane), cyclopentasiloxane (decamethylcyclopentasiloxane), Cyclohexasiloxane (dodecamethylcyclohexasiloxane). Examples of linear Silicones are linear siloxanes with 3 to 10 dimethylsiloxane units, such as hexamethyldisiloxane, octamethyltrisiloxane, decamethyltretrasiloxane, Dodecamethylpentasiloxane or mixtures of the individual substances, wherein both mixtures of different linear silicone oils, various Cyclomethicones as well as mixtures of cyclic and linear silicones are suitable. Usually become as fleeting Silicones are considered such compounds that have a boiling point below 200 ° C.

In addition to the volatile silicone, the preparation according to the invention may also contain a silicone which is essentially non-volatile at body temperature and at room temperature. Silicone oils and silicone resins are contemplated, and examples of which are well known to those skilled in the cosmetics arts. For cosmetic preparations suitable silicone oils and silicone resins are available in great variety bar and commercially available. As examples, silicone oils in the form of long-chain dimethylsiloxanes and branched siloxanes, which are also referred to as silicone resins, may be mentioned. As nonvolatile silicone oils, products such as dimethicone, phenyltrimethicone, diphenyldimethicone, alkyldimethicone can be used. Also mixtures of different silicone compounds are suitable. A preferred class of silicones are compounds having 3 siloxane units, of which the middle siloxane unit bears a longer-chain alkyl radical, while the remaining valences are saturated by methyl groups. This type of compound is commercially available under the INCI name trisiloxane or trimethicone. Preference may here be given to caprylyltrimethicones, lauryltrimethicones and stearyltrimethicones and mixtures thereof.

Basically, the use of W / Si emulsions and of suitable silicone emulsifiers is known. Particularly useful emulsifiers polyether-modified silicones have been found, as for example in EP 0 568 102 to be discribed. This type of emulsifier has a long chain of dimethylsiloxane units bearing polyethoxy-polypropoxy units in the chain and at the chain ends. The number of units and the length of the units affect the properties. It has now been found that, in particular, PEG / PPG dimethicones come into consideration for the present invention, each having 15 to 20 ethoxy and 15 to 20 propoxy units. This type of emulsifier is known and commercially available. Examples include the products marketed by DOW CORNING with the INCI names cyclopentasiloxanes PEG / PPG-18/18 dimethicones and cyclopentasiloxanes PEG / PPG-19/19 dimethicones. These emulsifiers are usually used dissolved in a volatile siloxane as described above.

The preparation according to the invention contains as further essential constituent a lipid phase, as is customary in the field of cosmetics. The lipid phase can be formed from oils, fats, linear or branched chain, saturated or monounsaturated or polyunsaturated fatty alcohols, wax alcohols and fatty acids, their esters, as well as waxes and wax esters in liquid or solid form. The individual components may be of plant, animal, mineral or synthetic origin. The term 'liquid' refers to substances which are in a flowable form in a temperature range between 0 and 45 ° C. Examples of lipid components will now be enumerated without intending to limit the invention. The substances are referred to below with the "INCI name" customary in this field and familiar to the person skilled in the art:
Vegetable oils and hydrogenated vegetable oils such as Buxus Chinensis Oil (Jojoba Oil), Hydrogenated Jojoba Oil, Cottonseed Oil, Hydrogenated Cottonseed Oil, Vegetable Oil, Hydrogenated Vegetable Oil, Rapeseed Oil, Hydrogenated Rapeseed Oil, Castor Oil, Hydrogenated Castor Oil, Hydrogenated Coco-Glycerides and similar, as well as Magnifera Indica (Mango Seed Oil), Limnanthes Alba (Meadaowfoam Seed Oil), Butyrosperum Parkii (Shea Butter), Coconut Fat, Cocoa Butter, Macadamia Ternifolia Nut Oil (Macadamia Nut Oil), Isopropyl Myristate, Isopropyl Palmitate, Isopropyl Isostearate, Butyl Stearate , Isopropyl isostearate, isodecyl neopentanoate, oleyl erucate, oleyl oleate, diethyl sebacate, hexyl laurate, PPG-5-laureth-5, ethylhexyl-dodecanol, caprylic / capric triglyceride, paraffin oils or mixtures thereof. It makes sense here to keep the amounts used low in order to maintain the good adhesion after evaporation of the volatile constituents. Shares below 20% are preferred. Particular preference is given to use concentrations of less than 5%.

suitable Fatty alcohols, fatty acids or wax alcohols are cetyl alcohol, stearyl alcohol, behenyl alcohol or mixtures thereof, palmitic acid, stearic acid, behenic acid, melissic acid or Mixtures thereof. The waxes are selected from waxing animal, of vegetable, mineral or synthetic origin or theirs Mixtures and hybrids. The waxes used have a hardness of 2 to 40, wherein the hardness value determined by the method of needle penetration. The determination Complies with the American standard ASTM D5: At a temperature from 25 ° C becomes a needle with a defined cone and a weight of 2.5 g, weighted 47.5 g, in a plane Surface of a specimen let in. The penetration depth is determined in tenths of a Millimeters after 5 seconds.

Prefers beeswax, modified beeswax or so-called "Cera Bellina", lanolin wax, Japan wax, Candelilla wax, ouricuri wax, carnauba wax, rice wax, blossom waxes or fruit waxes such as Orange blossom wax, orange wax, jasmine wax or apple wax, montan wax, microcrystalline wax, paraffin waxes, Ozokerite, polyethylene waxes produced by the Fischer-Tropsch process Waxes, silicone waxes, long-chain esters, e.g. myristyl myristate, Cetyl palmitate, stearyl stearate, behenyl stearate, behenyl behenate, hydrogenated jojoba oil or mixtures thereof and their hybrids. The amounts of this Waxes or the mixtures thereof and / or their hybrids lie generally in the range below 20 wt .-%, preferably below 5 wt .-%.

Around To impart the special properties of the invention is as essential component is water or a polar solvent or a mixture from water and polar solvents contained in a small proportion of only 0.1 to 5 wt .-%. It was found that, surprisingly the addition of a small amount of a polar solvent causes a film that is not blurred by water or runs, but is stabilized. It is believed that a gelatinous Consistency arises, which, without the other properties such as adhesion, Stationary strength, flexibility and to change suppleness, Can absorb water from the environment and thereby surprisingly the Structure stabilized.

The inventive preparation contains therefore, water or other polar solvent such as ethanol, 1,2-propylene glycol, Dipropylene glycol, tripropylene glycol, glycerol, diglycerol, triglycerol, Butylene glycols (e.g., 1,2-, 1,3-, 1,4-butanediol), hexylene glycols (e.g., 1,2-, 1,3-, 1,4- or 1,6-hexanediol), trimethylpentanediol, polyethylene glycols with molecular weights in the range of 200 to 2000 daltons or their Mixtures with water. Essential for the invention is that of Proportion of polar liquid 5% based on the finished composition does not exceed. The polar liquid is preferred used in a proportion of 0.5 to 3%, in particular 0.8 to 2%. If the water content is too low, i. less than 0.5% the desired Stabilization no longer achieved. A quantity over 5% carries no further favorable ones Properties at, leads but to the ones listed above Disadvantages.

The inventive emulsion made of special silicones and emulsifiers in combination with a small amount Proportion of polar solvent is well suited to take solid particulate ingredients and to stabilize in the formed structure. The preparation according to the invention contains therefore particulate ingredients as another component. The amount the particulate Ingredients will vary depending on the desired Consistency and effect of the mass adjusted. As particulate ingredients In particular, colorants, Effect agents and fillers or thickening agent used. This is the proportion the colorant and effect agent according to the desired Color and effect while Thickeners and fillers to adjust the consistency.

When dye in particular according to the invention finely divided pigments used, which may also be coated could be. examples for inorganic and organic pigments include: titanium dioxide, zinc oxide, Iron oxides, chromium oxide, chromium oxide hydrate, ultramarine, Berlin blue (Ferric Blue), mica, pearlescing agents, e.g. with titanium dioxide coated mica, colored, with titanium dioxide and metal oxides coated mica, bismuth oxychloride, coated bismuth oxychloride, platelet-shaped metal powder of aluminum, brass, bronze, copper, silver, gold, if necessary also can be coated with colored metal oxides, so-called "glitter" in the form of in thin and finely divided plastic platelets Polyester or the like. Immobilized colorants and varnishes organic colorant with aluminum, zirconium, barium, calcium or strontium.

These enumeration is only an example and not exhaustive. Judge these additions in general, to what extent they differ from the respective national ones or regional cosmetics legislation.

The dye are preferably selected from opaque to strongly opaque colorants with average particle sizes between 200 nm and 5 μm at the spherical, powdery Colorants and / or from platelet-shaped coloring agents with a mean particle size between 5 and 145 μm, in particular between 10 and 30 microns. To achieve special effects, e.g. Glitter effects, too used significantly larger particle sizes become. The proportions of pigments are usually in a range of 0.1 to 30% by weight, preferably in a range from 3 to 15% by weight and most preferably in one range from 5 to 10% by weight. If the preparation according to the invention is used as a light stabilizer, especially used as a nourishing lip product, so you can in addition to selected from the aforementioned pigments as basic coloring cerium oxide, Titanium dioxide and / or zinc oxide in the form of so-called "nanopigments" with particle sizes in the range between 5 and 25 nm in an amount of 1 to 10% by weight, and preferably 3 to 8 wt .-%, optionally in combination with conventional and by the relevant cosmetics legislation approved UV-A and UV-B filter substances added become.

When Effect agents are in particular iridescent, fluorescent, phosphorescent, glittering and shimmering ingredients used as they Those skilled in the art are known. These effectants will be often in the form of globules used on their surface the wished Effect-delivering compounds are immobilized. Also connections, which shine in the long-wave UV light, the so-called black light, come into consideration here.

The particulate dye have an influence on the consistency of the mass. If necessary, the Consistency over it addition by addition of known thickeners and fillers in the desired Range can be adjusted. Suitable for this purpose, for example fillers such as talc, kaolin, alumina, silica, each in finely divided and amorphous form, strength and modified starch, Polytetrafluoroethylene powder (Teflon), nylon powder and boron nitride. Thickeners are also suitable, such as hectorite, bentonite, Montmorillonite and its chemically modified forms. The thickeners are preferably modified in the form of insoluble metal soaps, e.g. as stearates to make them more compatible.

Around the processability of the particulate ingredients, in particular the fillers and to improve thickening agents, these are preferred incorporation into the formulation with a volatile solvent, e.g. a solvent, as well as for the incorporation of the emulsifier can be used pretreated. In a preferred embodiment become the particulate ones Ingredients before further processing with a part of the volatile solvent mixed so that wetting takes place.

The inventive preparation can additionally to the above essential components further usual in the field of cosmetics Contain ingredients. Often used ingredients are perfumes, individually and in combination, Flavors, antioxidants, preservatives, nourishing ingredients etc. These ingredients can the composition in a conventional manner and in the usual Added quantities become.

The Emulsion-like invention Preparation should be a pasty Have consistency, their viscosity Shifts so much under the action of a shearing force that it is very light spread on the skin or mucous membrane. The viscosity of the preparation is preferred in a range of 800 to 5000 Pa · s, preferably 1100 to 3500 Pa.s set. The viscosity is doing with a commercial Rheometer with a sandblasted plate / plate measuring device determined with a plate diameter of 25 mm. Due to pronounced normal voltage formation under shear can the preparations can be reproduced only under highly dynamic measuring conditions checked become. The measured values become smaller at a shear rate of γ = 1 / s eight seconds at 25 ° C determined.

The preparations according to the invention are in the form of a soft, supple paste which can be applied and distributed easily and uniformly. It can be removed again from the skin in the user's known manner - by suitable make-up removing means or cloths or by washing with fine soap or suitable mild surfactant preparations. It can be filled in a known manner in suitable containers, such as bottles, possibly with spatula, crucible or tubes and removed from the user again. However, it can also, because of the improved hygienic conditions associated therewith, be introduced into suitable application devices, so-called donor mechanisms, and applied therefrom. For the order of small quantities, such as those required for the application in the lip or eye area, applicators are suitable, as for example US 6,238,117 or off US 6,309,128 are known, as they allow a fine dosage.

The inventive preparation contains in a preferred embodiment et al a share of a fleeting Silicon with low flash point. As stated above, the Use of the special emulsifier that lowers the preparation Temperatures can be processed, which is in terms of safety is of particular advantage. Another subject of the present Invention is therefore also a process for the preparation of a preparation, as stated in the claims is defined, in which the emulsifier is dissolved in a volatile solvent, the particulate Ingredients added be, then the lipid phase and the other ingredients are added and homogenizing, all process steps at ambient temperature carried out be, then the batch is vented by applying vacuum and then water and silicone may be added if necessary.

One particular advantage of the method according to the invention is that it can be carried out at room temperature, while still a homogeneous product with a pleasant texture is obtained.

According to the invention a preparation is provided, which has non-transfer properties due to their components and due to the content of volatile ingredients also very smoothly applicable, is very adherent and stationary and does not migrate into the Feinfältelung the skin. In addition, the preparation according to the invention can absorb further moisture from the environment after application, without adversely affecting the properties as a result. On the contrary, the water absorption even increases the stability and strength. This can be due to increasing viscosity values Absorption of moisture can be shown. It was surprising that this silicone-containing and thus the type strongly hydrophobic - water-repellent - preparation is able to absorb moisture from the outside in addition and thereby stabilize without losing suppleness. Applied to the eyelids or lips, the preparations according to the invention thus do not produce a disturbing or foreign sensation on the skin, but improve in their positive properties without losing the original flexibility and elasticity.

The invention will now be explained with reference to some examples, but without limiting it. The above quantities may well be slightly below or exceeded in individual cases while still obtaining inventive preparations. The raw materials mentioned in the examples are designated by the "INCI name" (International Nomenclature of Cosmetic Ingredients) known to the person skilled in the art. The quantities are given in percent by weight, based on the total weight of the preparation Example 1 (Pearl lip color ) PEG / PPG-19/19 Dimethicone 16,000 Cyclopentasiloxane 14,800 trisiloxane 38.050 Polyethylene (micronized) 1,800 Carnauba (micronized) 2,200 Mica and Titanium Dioxide (Cl No 77.891) 11,000 Iron Oxides (Cl No. 77,491, Cl No. 77,492 and Cl No. 77,499) 1,300 silica 4,800 Gel A: cyclopentasiloxane and disteardimonium hectorite 5,000 Gel B: Isodecyl Neopentanoate and Cyclopentasiloxane and Stearalkonium Bentonite and Propylene Glycol and Dimethicone / Vinyl Dimethicone Crosspolymer 3,000 phenoxyethanol 0,500 methylparaben 0,150 Ethylparaben 0,025 Propylparaben 0,075 Fragrance 0,200 tocopherol 0,100 Aqua / Water 1,000

For preparation, the PEG / PPG-19/19 dimethicone is dissolved in about half of the cyclopentasiloxane in a vacuum process plant with vigorous stirring, then the iron oxides, silica, micronized waxes and premixed gels A and B are added and the mixture well homogenized at normal ambient temperature. Now the rest of the cyclopentasiloxane and the mica are added and the mixture stirred well without the use of the homogenizer. If necessary, the parabens and the tocopherol are dissolved in the phenoxyethanol with heating, the fragrance mixture is added and the mixture is added to the batch. The batch is then vented by applying a vacuum with gentle stirring. Now, the trisiloxane is added, the mixture is stirred homogeneously and gelled by adding the water. A highly lustrous, copper-colored, highly viscous, yet easily spreadable on the skin paste with a viscosity of 3,000 Pa · s. Example 2 (Pearl Lip Balm with Sunscreen) PEG / PPG-19/19 Dimethicone 18,000 Cyclopentasiloxane 15,500 trisiloxane 29,500 Buxus Chinensis Oil 3,500 Butyrospermum Parkii (Shea Butter) 1,200 Theobroma cacao (cocoa) seed butter 1,500 Euphorbia cerifera (candelilla) wax 1,800 Isopropyl isostearates 2,000 Mica and Titanium Dioxide (Cl No 77.891) 10,000 Titanium Dioxide Nanopigment (Cl No. 77.891) 5,000 Iron Oxides (Cl No. 77,491) 0.900 Red 7 (Cl No. 15.850) 0,450 silica 4,800 Cyclopentasiloxanes and disteardimonium hectorites 3,800 phenoxyethanol 0,500 methylparaben 0,150 Ethylparaben 0,025 Propylparaben 0,075 Fragrance 0,200 Tocopheryl acetate 0,350 bisabolol 0,100 Retinyl palmitate 0,150 Aqua / Water 0,500

The preparation is carried out in analogy to Example 1. This gives a reddish, slightly opaque, very pearlescent paste with very good light protection, which can be easily applied to the lips and does not stretch after drying and does not transfer to other objects. It has a viscosity of 1,200 Pas. Example 3 (Pearl Eyeshadow) PEG / PPG-19/19 Dimethicone 15,000 Cyclopentasiloxane 19,500 trisiloxane 32,000 Limnanthes Alba (Meadowfoam Seed Oil) 2,500 Butyrospermum Parkii (Shea Butter) 1,350 Isostearyl isostearates 1,500 Mica and Titanium Dioxide (Cl No 77.891) 12,500 Ultramarines (Cl No. 77,007) 2,000 Chromium Hydroxide Green (Cl No. 77.289) 3,500 silica 4,800 Cyclopentasiloxanes and disteardimonium hectorites 3,800 phenoxyethanol 0,500 methylparaben 0,100 Ethylparaben 0,025 Propylparaben 0,075 Fragrance 0,100 tocopherol 0,100 Aqua / Water 0,650

The preparation takes place in analogy to Example 1. A turquoise-colored, well-covering, very pearlescent paste is obtained, which can easily be distributed on the eyelid and holds at the place of application for a very long time and does not stretch after drying. It has a viscosity of 2,400 Pa · s. Example 4 (Blusher Cream) PEG / PPG-19/19 Dimethicone 12,500 Cyclopentasiloxane 19,500 trisiloxane 38.650 Limnanthes Alba (Meadowfoam Seed Oil) 3,500 Butyrospermum Parkii (Shea Butter) 1,350 Boron Nitride 2,800 Isostearyl isostearates 1,500 Titanium Dioxide (Cl No 77.891) 4,500 Iron Oxides (Cl No. 77,491, Cl No. 77,492, Cl No. 77,499) , 3,550 Red 7 Lake (Cl No 15.850) 0,350 kaolin 1,500 silica 4,800 Isodecyl Neopentanoate and Cyclopentasiloxane and Stearalkonium Bentonite and Propylene Glycol and Dimethicone / Vinyl Dimethicone Crosspolymer 3,700 phenoxyethanol 0,500 methylparaben 0,150 Ethylparaben 0,025 Propylparaben 0,075 Fragrance 0,200 tocopherol 0,100 Aqua / Water 0,750

The preparation is analogous to Example 1. This gives a matte, well-covering, light, brownish-red paste that spreads very well on the skin and allows the modeling of flowing transitions, which does not tension on the skin after drying and good adhesion. It has a viscosity of 2,800 Pa · s. Example 5 (hair gel shining in UV light) PEG / PPG-19/19 Dimethicone 20,100 Cyclopentasiloxane 10,500 trisiloxane 41,900 Mica and Titanium Dioxide (Cl No 77.891) 14,500 Polyethylene (micronized) 4,000 silica 3,850 Isodecyl Neopentanoate and Cyclopentasiloxane and Stearalkonium Bentonite and Propylene Glycol and Dimethicone / Vinyl Dimethicone Crosspolymer 2,500 phenoxyethanol 0,500 methylparaben 0,150 Ethylparaben 0,025 Propylparaben 0,075 Disodium Distyrylbiphenyl Disulfonate and Sodium Chloride 1,000 Aqua / Water 0.900

The Preparation is carried out in analogy to Example 1. One receives a slightly clouded Paste that can be applied well to individual strands of hair and when irradiated with ultraviolet light, so-called "black light" (e.g., in a dance hall) bluish shimmers. It has a viscosity of 2,700 Pa · s.

Claims (22)

Preparation in the form of a water-in-oil emulsion containing a) at least one silicone; b) at least one PEG / PPG dimethicone having in each case 15 to 20 units of PEG and PPG as emulsifier; c) a lipid phae; d) water in a proportion of 0.1 to 5% based on the total weight of the composition; and e) at least one particulate matter. Preparation according to claim 1, characterized in that that as a silicone at room temperature and body temperature substantially volatile Silicone is used. Preparation according to claim 1, characterized in that that as a silicone at room temperature and body temperature substantially non-volatile Silicone or a combination of a room temperature and body temperature essentially volatile and one at room temperature and body temperature substantially volatile Silicone is used. Preparation according to one of the preceding claims, characterized characterized as being non-volatile Silicone a silicone oil or silicone resin is used. Preparation according to one of the preceding claims, characterized in that the silicone is a C ₈ -C ₂₀ -alkyl trimethicone is included. Preparation according to one of the preceding claims, characterized in that the emulsifier PEG / PPG-19/19 contains dimethicones is. Preparation according to one of the preceding claims, characterized characterized in that as volatile silicone a linear silicone with 2 to 20 dimethyl siloxane units or a cyclomethicone having from 3 to 7 dimethylsiloxane units is. Preparation according to one of the preceding claims, characterized characterized in that as volatile silicone Hexamethylcycloltrisiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, Dodecamethylcyclohexasiloxane, hexamethyldisiloxane, octamethyltrisiloxane, Decamethyltetrasiloxane, dodecamethylpentasiloxane or mixtures of which are included. Preparation according to one of the preceding claims, characterized characterized in that the lipid phase oils, fats, linear or branched chain saturated or monounsaturated or polyunsaturated Fatty alcohols, wax alcohols, fatty acids and their esters, waxes and wax esters or mixtures thereof. Preparation according to one of the preceding claims, characterized characterized as being oil vegetable or hydrogenated vegetable oil. Preparation according to one of the preceding claims, characterized characterized in that the particulate ingredients are particulate colorants, Effect agents and / or fillers are included. Preparation according to one of the preceding claims, characterized characterized in that as a colorant Pigments are contained in finely divided and / or amorphous form, which may optionally be coated. Preparation according to one of the preceding claims, characterized characterized in that glittering, shimmering, fluorescent, phosphorescent, ultraviolet light-emitting or iridescent agents are included. Preparation according to one of the preceding claims, characterized characterized in that additional fillers and thickening agents, optionally in chemically modified Form are included. Preparation according to one of the preceding claims, characterized characterized in that the particulate ingredients are in the form of insoluble Metal soaps are included. Preparation according to one of the preceding claims, characterized marked that in addition for cosmetic Preparations usual Ingredients are included. Preparation according to one of the preceding claims, characterized characterized in that in addition fragrances and fragrance mixtures, flavors, antioxidants, preservatives and / or care ingredients are included. Preparation according to one of the preceding claims, characterized characterized in that the finished preparation measured a viscosity on a commercial Rheometer with a sandblasted plate / plate measuring device with a plate diameter of 25 mm, at 25 ° C 800 to 5000 mPa · s. Preparation according to one of the preceding claims, characterized characterized in that it is present as a pasty emulsion. Preparation according to one of the preceding claims, characterized characterized in that it is present as a thixotropic paste. Preparation according to one of the preceding claims, characterized characterized in that the preparations in addition to conventional additives 12 to 21 emulsifier, 10 to 25% volatile Silicone, 25 to 45% non-volatile Silicone, 2 to 10% lipid phase, 2 to 10% thickener, 5 up to 20% colorant and 0.1 to 5% water. Preparation according to Claim 21, characterized that as usual Additives suspending agents, preservatives, fragrances, Antioxidants and / or flavors are included.