DE202005009617U1 - Delivery system for spraying a cosmetic composition comprises a pressure-resistant pack, a capillary spray head and a composition including a propellant and a hair conditioner - Google Patents

Abstract

Delivery system for spraying a cosmetic composition comprises a pressure-resistant pack, a spray head comprising a capillary, and a cosmetic composition including a propellant and a hair conditioner selected from cationic surfactants, amino surfactants, silicones, fatty alcohols, oils, plant extracts, protein hydrolyzates, amino acids, panthenol, panthenyl ethyl ether, sorbitol, betaine and creatine.

Description

object the present invention is a product delivery system for spraying cosmetic compositions, which a pressure-resistant packaging, containing a capillary spray nozzle and a propellant-containing cosmetic composition and wherein the composition comprises at least one hair conditioning agent Contains active substance, the selected is made of cationic surfactants, aminotensides, silicone compounds, Fatty alcohols, oils, Plant extracts, protein hydrolysates, amino acids, panthenol, panthenyl ethyl ether, Sorbitol, betaine, creatine. The invention is also a corresponding method for hair treatment.

Lots Hair cosmetic products contain hair conditioning agents. Hair conditioning agents are substances which at least one hair care Have effect such. the combability in the wet or dry condition, improve the grip of the hair in the wet or dry condition, improve the shine of the hair improve or reduce the fly-away effect. For the products the most intensive hair care effects are often highly viscous products such as conditioners, cures, gels, waxes, hairdressing creams or treatments with non-fluid, creamy, pasty, semi-solid or gelatinous consistency. Currently on the market Products are usually put out of the package on the hand, between the hands easily distributed and incorporated into the hair. The product will not equally distributed, In addition, product mass remains behind on the hands. It has not been possible to use higher-viscosity formulations (e.g., conditioners and cures having a viscosity> 1500 mPas or> 5000 mPas) are extremely fine to distribute the hair. Lower viscosity, fluid products are indeed easier and more consistent, but often have also a less intensive hair conditioning and hair care Effect.

Out WO 03/051523 A1 discloses a method for spraying liquids, in which the Spray formation takes place by means of a capillary. It will only be the application for spraying liquid, i.e. described fluid compositions. From WO 03/051522 A2 describes a device for spraying liquid products, wherein the spray also takes place by means of a capillary. Only the application to spray liquid, i. fluid compositions which may also be highly viscous, with the maximum sprayable viscosity being 5000 mPa s are called.

It There is therefore a need for products which are finely divided the hair can be applied but still have the intensive care and conditioning effects such as high-viscosity, non-fluid, creamy or pasty hair conditioner or over whose effects go even further. One task was in particular in it, dispersibility on hair, combability, hair shine and / or the grip characteristics of conventional, previously as unversprühbar of existing hair treatment compositions or those treated with them Hair continues to improve.

• (a) eine druckfeste Verpackung,
• (b) einen eine Kapillare enthaltenden Sprühkopf und
• (c) eine treibmittelhaltige kosmetische Zusammensetzung

wobei das Versprühen mittels der Kapillare erfolgt und die Zusammensetzung mindestens einen haarkonditionierenden Wirkstoff enthält, der ausgewählt ist aus kationischen Tensiden, Aminotensiden, Silikonverbindungen, Fettalkoholen, Ölen, Pflanzenextrakten, Proteinhydrolysaten, Aminosäuren, Panthenol, Panthenylethylether, Sorbitol, Betain, Creatin.The invention relates to a product delivery system for spraying cosmetic compositions. The product dispensing system has the following features:

• (a) a pressure-resistant packaging,
• (b) a spray head containing a capillary and
• (c) a propellant-containing cosmetic composition

wherein the spraying is carried out by means of the capillary and the composition contains at least one hair conditioning agent selected from cationic surfactants, amino surfactants, silicone compounds, fatty alcohols, oils, plant extracts, protein hydrolysates, amino acids, panthenol, panthenyl ethyl ether, sorbitol, betaine, creatine.

Under "spraying" is a levy of the product in the form of divided particles. The parted Particles can have different shape, consistency and size. The properties the sprayed Particles range from fine aerosol spray over liquid droplets, snow-like droplets, solid sprayed flakes up to a spray foam.

The the following amounts of ingredients (e.g. % By weight) in each case relate to the propellant-free basic composition, unless expressly stated otherwise stated. Refer to the quantities of the propellant on the overall composition including propellant.

The composition is preferably non-liquid at 25 ° C and / or has a viscosity of more than 5000 mPa s (measured with a HAAKE VT-550 Rheometer, measuring body SV-DIN at a temperature of 25 ° C and a shear rate of 12, 9 s ^-1 ). The referring to the consistency Properties of the compositions to be used according to the invention relate (unless expressly stated otherwise) to the base composition without propellant. Non-liquid compositions within the meaning of the invention are, in particular, non-flowable compositions, which can be determined, for example, by the fact that they do not run down from a 45 ° inclined glass surface at 25 ° C. Gel-shaped compositions are characterized in that at 25 ° C in oscillographic measurements in the usual range (0.01 to 40 Hz), the storage modulus G 'is greater than the loss modulus G ".

The viscosity of the composition to be used is preferably from more than 5000 to 100,000, particularly preferably from 10,000 to 50,000 mPa s, very particularly preferably from 25,000 to 35,000 mPa s, measured with a HAAKE VT-550 Rheometer, measuring body SV-DIN at one temperature of 25 ° C and a shear rate of 12.9 s ^-1 .

When pressure-resistant packaging can conventional Aerosol cans made of metal or plastic can be used. preferred Metals are tinplate and aluminum, more preferably plastic Polyethylene terephthalate.

Suitable spray systems with capillary-containing spray heads, in which the spray formation takes place by means of a capillary, are described in WO 03/051523 A1 and in WO 03/051522 A2. The capillaries preferably have a diameter of 0.1 to 1 mm, in particular of 0.2 to 0.6 mm and a length of preferably 5 to 100 mm, in particular 5 to 50 mm. The spray principle is also described in Aerosol Europe, Vol. 13, no. 1-2005, pages 6-11. The spray system is based on the principle of capillary sputtering. The conventional vortex nozzle and possibly also the riser are replaced by capillaries. The energy-consuming and propellant-intensive turbulence of the can contents and the necessary dilution of the product with solvents is not necessary in comparison to conventional spray systems. Already using a small amount of propellant, the product rises when using a riser capillary on the wall and drives it after the valve in the (further) capillary of the spray head in the direction of the outlet opening. In this way small droplets are torn from the surface of the liquid by the flowing propellant gas and continue to flow as an aerosol. Because there is no swirl chamber inhibiting product flow and no atomizer nozzle, the energy in the system can be used much more efficiently to produce the desired spray. The spray rate can be adjusted by selecting the capillary geometry in combination with the internal pressure generated by the propellant gas or a propellant gas mixture. Preferred spray rates are 0.01 to 0.5 g / s, in particular 0.1 to 0.3 g / s. The size of the spray droplets generated during spraying can be adjusted by selecting the capillary geometry in combination with the internal pressure or the viscosity of the composition. Suitable capillary atomization systems are available under the name TRUSPRAY ^® Boehringer Ingelheim microParts.

preferred Droplet size distributions are those in which the dv (50) value is at most 200 μm, e.g. from SO up to 200 μm more preferably not more than 100 μm, e.g. from 70 to 90 μm is and / or wherein the dv (90) value is at most 160 μm, e.g. from 90 to 160 μm, especially preferably not more than 150 μm, e.g. from 115 to 150 μm is. The dv (50) and dv (90) values, respectively indicate the maximum diameter that 50% and 90% of all droplets have. The droplet size distribution can be determined, for example, with the help of a particle measuring device Base of laser beam diffraction, e.g. a Malvern Particle Sizer Meter. Preference is also given to compositions which leave on exiting the capillary spray system Snow, flakes or foam (spray foam) form.

The propellant to be used may be selected from lower alkanes, in particular C3 to C5 hydrocarbons such as n-butane, i-butane and propane, or mixtures thereof, and dimethyl ether or fluorohydrocarbons such as F 152a (1,1-difluoroethane) or F 134 (Tetrafluoroethane) and also at the pressures in question gaseous blowing agent, such as N ₂ , N ₂ O and CO ₂ and mixtures of the above blowing agents. The propellant is preferably selected from propane, n-butane, isobutane, dimethyl ether, fluorinated hydrocarbons and mixtures thereof. The propellant content is additionally preferably 15 to 85 wt.%, Particularly preferably 25 to 75 wt.%.

The composition contains cosmetically acceptable solvents, preferably an aqueous, alcoholic or aqueous-alcoholic medium. As alcohols, in particular, the lower alcohols having 1 to 4 carbon atoms commonly used for cosmetic purposes such as ethanol and isopropanol may be included. The composition may be in a pH range of 2.0 to 9.5. The pH range between 4 and 8 is particularly preferred, unless special application forms require other pH values. As additional co-solvents, organic solvents or a mixture of solvents having a boiling point below 400 ° C. may be present in an amount of from 0.1 to 15% by weight, preferably from 1 to 10% by weight be. Particularly suitable as additional co-solvents are unbranched or branched hydrocarbons such as n-pentane, hexane, isopentane and cyclic hydrocarbons such as cyclopentane and cyclohexane. These volatile hydrocarbons can also be used as propellants. Further, particularly preferred water-soluble solvents are glycerol, ethylene glycol and propylene glycol in an amount of up to 30% by weight.

The Inventive product delivery system can be used for hair treatment. In the compositions can it be funds for the care of the hair such as Hair conditioners or hair conditioners that e.g. as leave on or as rinse off products can; for funds for the temporary one Deformation and / or stabilization of the hairstyle (styling agent), e.g. Hair sprays, hair lacquers, hair gels, hair waxes, hairstyle creams, etc .; permanent, semipermanent or temporary hair dyes, e.g. oxidative hair dye or non-oxdidative hair tinting agents or hair bleach; permanent hair-shaping agents, e.g. in the form of a reducing agent containing mildly alkaline or Acid perming or hair decongestants or in the form of act an oxidizing agent Dauerwellfixiermitteln act.

The Hair conditioning agents are used in the invention Composition in an amount of preferably 0.01 to 20 wt.%, in particular from 0.05 to 10 or from 0.1 to 5% by weight. Hair conditioning agents are understood to mean such substances when used in 0.01 to 5% aqueous, alcoholic or aqueous-alcoholic solution or dispersion are able to wet or dry Hair to have a conditioning or conditioning effect, e.g. the Grip or combability improve or enhance the shine. Hair conditioning agents are especially those for which in the International Cosmetic Ingredient Dictionary and Handbook, 10th Edition, 2004, the function "Hair Conditioning Agents " is.

Suitable cationic surfactants or amino surfactants include amino groups or quaternized hydrophilic ammonium groups which carry a positive charge in solution and the general formula N ⁽⁺⁾ R ¹ R ² R ³ R ⁴ X ^(-) where R1 to R4 independently of one another are aliphatic groups, aromatic groups, alkoxy groups, polyoxyalkylene groups, alkylamido groups, hydroxyalkyl groups, aryl groups or alkaryl groups having 1 to 22 C atoms, where at least one radical has at least 6, preferably at least 8, C atoms and X ^{- represents} an anion, for example a halogen, acetate, phosphate, nitrate or alkyl sulfate, preferably a chloride.

The aliphatic groups can additionally to the carbon atoms and the hydrogen atoms also cross-links or other groups such as other amino groups. examples for suitable cationic surfactants are the chlorides or bromides of Alkyldimethylbenzylammonium salts, alkyltrimethylammonium salts, e.g. Cetyltrimethylammonium chloride or bromide, tetradecyltrimethylammonium chloride or bromide, alkyldimethylhydroxyethylammonium chlorides or bromides, the dialkyldimethylammonium chlorides or bromides, alkylpyridinium salts, for example, lauryl or Cetylpyridinium chloride, alkylamidoethyltrimethylammonium ether sulfates and cationic compounds such as amine oxides, e.g. Alkylmethylamine oxides or alkylaminoethyldimethylamine oxides. Especially preferred are C8-22-alkyldimethylbenzylammonium compounds, C8-22-alkyltrimethylammonium compounds, in particular cetyltrimethylammonium chloride, C8-22-alkyldimethylhydroxyethylammonium compounds, di (C8-22-alkyl) -dimethylammonium compounds, C8-22-alkylpyridinium salts, C8-22-alkylamidoethyltrimethylammonium ether sulfates, C8-22 alkylmethylamine oxides, C8-22 alkylaminoethyldimethylamine oxides.

In addition to the above-mentioned cationic surfactants, further suitable cationic or amine-substituted surfactants are those of the formula R 1 -NH- (CH ₂ ) n -NR ₂ R 3
or of the formula R 1 -NH- (CH ₂ ) n N ⁺ R ₂ R 3 R 4 X ^-
wherein R 1 is an acyl or an alkyl radical having 8 to 24 C atoms, which may be branched or unbranched, saturated or unsaturated, wherein the acyl and / or the alkyl radical may contain one or more OH groups, R 2, R 3 and R4 are independently hydrogen, alkyl or alkoxy alkyl radicals having 1 to 6 carbon atoms, which may be the same or different, saturated or unsaturated and substituted with one or more hydroxy groups, X ^{- is} an anion, in particular a halide ion or a compound of general formula RSO ₃ ^- , in which R has the meaning of saturated or unsaturated alkyl radicals having 1 to 4 carbon atoms, and n is an integer between 1 and 10, preferably from 2 to 5.

Preferably, the hair-care agent is an amidoamine and / or a quaternized amidoamine of the abovementioned formulas, in which R 1 is a branched or unbranched, saturated or unsaturated acyl radical having 8 to 24 C atoms, which may contain at least one OH group. Also preferred are those amines and / or quaternized amines in which at least one of R2, R3 and R4 is a radical according to the general formula CH ₂ CH ₂ OR5, wherein R5 is the meaning of alkyl radicals having 1 to 4 carbon atoms, hydroxyethyl or H can have. Suitable amines or amidoamines, which may optionally be quaternized, are in particular those having the INCI names Ricinoleamidopropyl Betaine, Ricinoleamidopropyl Dimethylamine, Ricinoleamidopropyl Dimethyl Lactate, Ricinoleamidopropyl Ethyldimonium Ethosulfate, Ricinoleamidopropyltrimonium Chloride, Ricinoleamidopropyltrimonium Methosulfate, Cocamidopropyl Betaine, Cocamidopropyl Dimethylamine, Cocamidopropyl Ethyldimonium Ethosulfate, Cocamidopropyltrimonium Chlorides, behenamidopropyl dimethylamines, isostearylamidopropyl dimethylamines, stearylamidopropyl dimethylamines, quaternium-33, undecyleneamidopropyltrimonium methosulfates.

In an embodiment contains the agent of the invention as hair-conditioning agent at least one silicone compound in an amount of preferably 0.01 to 15 wt.%, particularly preferably of 0.1 to 5% by weight. The silicone compounds include volatile and nonvolatile Silicones and soluble in the middle and insoluble Silicones. In one embodiment these are high molecular weight silicones with a viscosity of 1,000 up to 2,000,000 cSt at 25 ° C, preferably 10,000 to 1,800,000 or 100,000 to 1,500,000. The Silicone compounds include polyalkyl and polyaryl siloxanes, in particular with methyl, ethyl, propyl, phenyl, methylphenyl and phenylmethyl groups. Preference is given to polydimethylsiloxanes, polydiethylsiloxanes, polymethylphenylsiloxanes. Shiny, arylated silicones with a refractive index are also preferred of at least 1.46, or at least 1.52. The silicone compounds include in particular the substances with the INCI names Cyclomethicone, Dimethicone, dimethiconol, dimethicone copolyol, phenyl trimethicone, Amodimethicones, trimethylsilylamodimethicones, stearyl siloxysilicates, Polymethylsilsesquioxane, Dimethicone Crosspolymer. Are suitable also silicone resins and silicone elastomers, which are highly crosslinked Siloxane acts. Crosslinked silicones can also be used as Consistency of preferably creamy, solid or high viscosity Serve composition. Crosslinked silicones are e.g. those with the INCI names Acrylates / Bis-Hydroxypropyl Dimethicone Crosspolymer, Butyl Dimethicone Methacrylate / Methyl Methacrylate Crosspolymer, C30-45 Alkyl Cetearyl Dimethicone Crosspolymer, C30-45 Alkyl Dimethicone / Polycyclohexenes Oxide Crosspolymer, Cetearyl Dimethicone / Vinyl Dimethicone Crosspolymer, Dimethicone Crosspolymer, Dimethicone Crosspolymer-2, Dimethicone Crosspolymer-3, dimethicone / divinyldimethicone / silsesquioxane crosspolymer, Dimethicone / PEG-10/15 Crosspolymer, Dimethicone / PEG-15 Crosspolymer, Dimethicone / PEG-10 Crosspolymer, Dimethicone / Phenyl Vinyl Dimethicone Crosspolymer, Dimethicone / Polyglycerol-3 Crosspolymer, Dimethicone / Titanate Crosspolymer, Dimethicone / Vinyl Dimethicone Crosspolymer, Dimethicone / Vinyltrimethylsiloxysilicate Crosspolymer, dimethiconol / methylsilanol / silicate crosspolymer, Diphenyl Dimethicone Crosspolymer, Diphenyl Dimethicone / Vinyl Diphenyl Dimethicone / Silsesquioxane Crosspolymer, Divinyl Dimethicone / Dimethicone Crosspolymer, Lauryl Dimethicone PEG-15 Crosspolymer, Lauryl Dimethicone / Polyglycerol-3 Crosspolymer, Methylsilanol / Silicate Crosspolymer, PEG-10 Dimethicone Crosspolymer, PEG-12 Dimethicone Crosspolymer, PEG-10 Dimethicone / Vinyl Dimethicone Crosspolymer, PEG-10 / Lauryl Dimethicone Crosspolymer, PEG-15 / Lauryl Dimethicone Crosspolymer, Silicone Quaternium-16 / Glycidoxy Dimethicone Crosspolymer, Styrene / Acrylates / Dimethicone Acrylate Crosspolymer, Trifluoropropyl Dimethicone / PEG-10 Dimethicone Crosspolymer, Trifluoropropyl Dimethicone / trifluoropropyl divinyldimethicone crosspolymer, trifluoropropyl Dimethicone / Vinyl Trifluoropropyl Dimethicone / Silsesquioxane Crosspolymer, Trimethylsiloxysilicate / Dimethicone Crosspolymer, Trimethylsiloxysilicate / Dimethiconol Crosspolymer, Vinyl Dimethicone / Lauryl Dimethicone Crosspolymer, Vinyl Dimethicone / Methicone Silsesquioxane Crosspolymer, Vinyldimethyl / Trimethylsiloxysilicate Stearyl Dimethicone Crosspolymer.

preferred Silicones are: cyclic dimethylsiloxanes, linear polydimethylsiloxanes, Block polymers of polydi methylsiloxane and polyethylene oxide and / or Polypropylene oxide, polydimethylsiloxanes with terminal or pendant polyethylene oxide or polypropylene oxide radicals, hydroxyl-terminated polydimethylsiloxanes, phenyl-substituted polydimethylsiloxanes, silicone emulsions, silicone elastomers, Silicone waxes, silicone gums, amino-substituted silicones, with quaternary ammonium groups substituted silicones and crosslinked silicones.

Also particularly preferred are cationic silicone compounds. These are substituted with cationic or cationizable groups. Suitable cationic silicone compounds have either at least one amino group or at least one ammonium group. Silicone polymers with amino groups are known under the INCI names amodimethicone and trimethylsilylamodimethicone. These are polydimethylsiloxanes with aminoalkyl groups. The aminoalkyl groups may be side or terminal. Suitable aminosilicones are those of the general formula R ⁸ R ⁹ R ¹⁰ Si (OSiR ¹¹ R ¹² ) x- (OSiR ¹³ Q) y-OSiR ¹⁴ R ¹⁵ R ¹⁶ R ⁸ , R ⁹ , R ¹¹ and R ¹⁵ are each independently the same or different and are C 1 to C 10 alkyl, phenyl, hydroxy, hydrogen, C 1 to C 10 alkoxy or acetoxy, preferably C 1 to C 4 alkyl, more preferably Methyl or trimethylsilyl;
R ¹⁰ and R ¹⁶ are each independently the same or different and are - (CH ₂ ) _a -NH ₂ where a is 1 to 6, C 1 to C 10 alkyl, phenyl, hydroxy, hydrogen, C 1 to C 10 alkoxy or acetoxy , preferably C 1 -C 4 -alkyl, more preferably methyl;
R ¹¹ R ¹² and R ¹³ are each independently the same or different and are hydrogen, C 1 to C 20 hydrocarbon, which may contain O and N atoms, preferably C 1 to C 10 alkyl or phenyl, more preferably C 1 to C 4 Alkyl, in particular methyl;
Q is -A-NR ¹⁷ R ¹⁸ , or -AN ⁺ R ¹⁷ R ¹⁸ R ¹⁹ where A is a divalent C 1 to C 20 -alkylene linking group, which may also contain O and N atoms and OH groups, and R ¹⁷ , R ¹⁸ and R ^{19 are} independently the same or different and are hydrogen, C 1 to C 22 hydrocarbon, preferably C 1 to C 4 alkyl or phenyl.

Preferred radicals for Q are - (CH ₂ ) ₃ -NH ₂ , - (CH ₂ ) ₃ NHCH ₂ CH ₂ NH ₂ , - (CH ₂ ) ₃ OCH ₂ CHOHCH ₂ NH ₂ and - (CH ₂ ) ₃ N (CH ₂ CH ₂ OH) ₂ , - (CH ₂ ) ₃ -NH ₃ ⁺ and - (CH ₂ ) ₃ OCH ₂ CHOHCH ₂ N ⁺ (CH ₃ ) ₂ R ²⁰ , where R ^{20 is} a C 1 to C 22 alkyl radical, which may also have OH groups; x represents a number between 1 and 10,000, preferably between 1 and 1,000; y is a number between 1 and 500, preferably between 1 and 50. The molecular weight of the aminosilicones is preferably between 500 and 100,000. The proportion of amine (meq / g) is preferably in the range from 0.05 to 2.3, particularly preferably from 0.1 to 0.5.

Suitable silicone polymers having two terminal quaternary ammonium groups are known by the INCI name Quaternium-80. These are dimethylpolysiloxanes with 2 terminal alkylammonium groups. Suitable quaternary aminosilicones are those of the general formula R ²¹ R ²² R ²³ N ⁺ -A-SiR ⁸ R ⁹ - (OSiR ¹¹ R ¹² ) _n -OSiR ⁸ R ⁹ -AN ⁺ R ²¹ R ²² R ²³ 2X ^- A is a divalent C 1 to C 20 -alkylene linking group, which may also contain O and N atoms and OH groups, and is preferably - (CH ₂ ) ₃ OCH ₂ CHOHCH ₂ ;
R ⁸ , R ⁹ , independently of one another, are identical or different and denote C 1 - to C 10 -alkyl, phenyl, hydroxyl, hydrogen, C 1 - to C 10 -alkoxy or acetoxy, preferably C 1 -C 4 -alkyl, particularly preferably methyl;
R ¹¹ , R ¹² are each independently the same or different and are hydrogen, C 1 to C 20 hydrocarbon, which may contain O and N atoms, preferably C 1 to C 10 alkyl or phenyl, more preferably C 1 to C 4 alkyl , especially methyl;
R ²¹ R ²² , and R ²³ independently of one another are C 1 -C ²² -alkyl radicals which may contain hydroxyl groups and wherein preferably at least one of the radicals has at least 10 C atoms and the remaining radicals have 1 to 4 C atoms; n is a number from 0 to 200, preferably 10 to 100. Such diquaternary polydimethylsiloxanes of the company Goldschmidt / Germany under the trade names Abil Quat ^® 3270, 3272 and 3274 sold.

suitable hair conditioning oils are especially liquid, hydrophobic oils with a melting point of less than 25 ° C and a boiling point of preferably above 250 ° C, in particular above 300 ° C. But also volatile oils are used. In principle, any oil known to the person skilled in the art can be used become. For example, vegetable oils, animal oils, mineral oils (paraffin liquidum) or mixtures thereof. Suitable are hydrocarbon oils, e.g. Paraffin or isoparaffin oils, Squalane, fatty acid esters like e.g. Isopropyl myristate, oils from fatty acids and polyols, especially triglycerides.

suitable vegetable oils are e.g. Sunflower oil, Coconut oil, Castor oil, lanolin, jojoba oil, Corn oil, soybean oil, kukui nut oil, (sweet) almond oil, walnut oil, peach kernel oil, avocado oil, tea tree oil (Tea tree oil), sesame oil, tsubaki, Evening primrose oil, rice bran oil, Palm kernel oil, Mango oil, Meadowfoam seed oil, Safflower oil, Macadamia nut oil, grape seed oil, apricot kernel oil, babassu oil, olive oil, wheat germ oil, pumpkin seed oil, mallow oil, hazelnut oil, safflower oil, canola oil, sasanqua oil and shea butter.

As fatty alcohols it is possible to use saturated, mono- or polyunsaturated, branched or unbranched fatty alcohols with C ₆ -C ₃₀ -, preferably C ₁₀ -C ₂₂ - and particularly preferably C ₁₂ -C ₂₂ -carbon atoms. For the purposes of the invention, for example, decanol, octanol, octenol, dodecanol, dodecenol, decenol, octadienol, dodecadienol, decadienol, oleyl alcohol, eruca alcohol, ricinoleic alcohol, stearyl alcohol, isostearyl alcohol, cetyl alcohol, lauryl alcohol, myristylalkahol, arachidyl alcohol, caprylic alcohol, capri nalkohol, linoleyl alcohol, linolenyl alcohol and behenyl alcohol, and their Guerbet alcohols, this list should have exemplary and non-limiting character. However, the fatty alcohols are derived from preferably natural fatty acids, which can usually be based on recovery from the esters of fatty acids by reduction. Also usable according to the invention are those fatty alcohol cuts which are produced by reducing naturally occurring triglycerides such as beef tallow, palm oil, peanut oil, rapeseed oil, cottonseed oil, soybean oil, sunflower oil and linseed oil or fatty acid esters formed from their transesterification products with corresponding alcohols, and thus represent a mixture of different fatty alcohols. Wool wax alcohols can also be used according to the invention.

suitable Plant extracts are usually produced by extraction of the entire plant. But it can in individual cases also be preferred, the extracts exclusively from flowers and / or Scroll the Plant to produce. According to the invention, especially the extracts from green Tea, oak bark, nettle, witch hazel, hops, henna, chamomile, Burdock root, horsetail, hawthorn, lime blossom, almond, aloe Vera, spruce needle, horse chestnut, Sandalwood, juniper, coconut, Mango, Apricot, Lime, Wheat, Kiwi, Melon, Orange, Grapefruit, Sage, Rosemary, Birch, Mallow, Meadowfoam, Quendel, Yarrow, Thyme, Melissa, hominy, coltsfoot, marshmallow, meristem, ginseng and ginger root prefers. As extracting agent for the preparation of said plant extracts can Water, alcohols and mixtures thereof are used. Under the alcohols are lower alcohols such as ethanol and isopropanol, but especially polyhydric alcohols such as ethylene glycol and propylene glycol, both as sole extractant and in mixture with Water, preferably, e.g. Plant extracts based on water / propylene glycol in relation to 1:10 to 10: 1. The plant extracts can be found both in pure as well in dilute Form are used. If used in dilute form, they usually contain about 2 to 80 wt.% Active substance and as a solvent in their recovery used extraction agent or extractant mixture.

It can also mixtures of several, especially two, different Plant extracts are used.

Further suitable hair conditioning agents are protein hydrolysates and amino acids. Protein hydrolysates in the context of the invention are protein hydrolysates and / or amino acids and their derivatives understood. Derivatives are e.g. condensates with fatty acids or cationically modified protein hydrolysates. protein are product mixtures that are acidic, basic or enzymatic catalyzed degradation of proteins (proteins) can be obtained. Under The term protein hydrolyzates are also total hydrolyzates as well individual amino acids and their derivatives as well as mixtures of different amino acids understood. amino acids are e.g. Alanine, arginine, asparagine, aspartic acid, cystine, glutamine, glutamic acid, glycine, Histidine, isoleucine, leucine, lysine, methionine, phenylalanine, proline, Serine, threonine, tryptophan, tyrosine, valine. Furthermore, according to the invention from amino acids and amino acid derivatives understood polymers understood by the term protein hydrolysates. To the latter are e.g. Polyalanine, polyasparagine, polyserine etc. to count. other examples are L-alanyl-L-proline, polyglycine, glycylglutamine or D / L-methionine-S-methylsulfonium chloride. It can also beta-amino acids and their derivatives such as .beta.-alanine, anthranilic acid or hippuric be used. The molecular weight of the protein hydrolysates is in between 75, the molecular weight for Glycine, and 200,000, preferably, the molecular weight is 75 to 50,000 and most preferably 75 to 20,000 daltons.

According to the invention, protein hydrolysates both herbal and animal or marine or synthetic Origin are used. Animal protein hydrolysates are for example Elastin, collagen, keratin, silk and milk protein protein hydrolysates, too may be in the form of salts. According to the invention preferred is the use of protein hydrolysates of plant origin, z. Soybean, almond, pea, potato, rice and wheat protein hydrolysates as well as their condensation products with fatty acids. Although the use the protein hydrolysates are preferred as such may their place optionally also otherwise obtained amino acid mixtures be used.

Suitable cationically derivatized protein hydrolysates are mixtures of substances which can be obtained, for example, by reacting alkaline, acidic or enzymatically hydrolysed proteins with glycidyltrialkylammonium salts or 3-halo-2-hydroxypropyltrialkylammonium salts. Proteins which serve as starting materials for the protein hydrolysates can be of plant as well as animal origin. Common starting materials are, for example, keratin, collagen, elastin, soy protein, rice protein, milk protein, wheat protein, silk protein or almond protein. The hydrolysis produces mixtures of substances with molecular weights in the range from about 100 to about 50,000. Typical average molecular weights range from about 500 to about 1000. Advantageously, the cationically derivatized protein hydrolysates contain one or two long C8 to C22 alkyl ketones and correspondingly two or one short C1 to C4 alkyl chains. Compounds containing a long alkyl chain are preferred. Cationic protein derivatives are known, for example, under the INCI names Lauryldimonium Hydroxypropyl Hydrolyzed Wheat Protein, Lauryldimonium Hydroxypropyl Hydrolyzed Casein, Lauryldimonium Hydroxypropyl Hydrolyzed Collagen, Lauryldimonium Hydroxypropyl Hydrolyzed Keratin, Lauryldimonium Hydroxypropyl Hydrolyzed Silk, Lauryldimonium Hydroxypropyl Hydrolyzed Soy Protein or Hydroxypropyltrimonium Hydrolyzed Wheat, Hydroxypropyltrimonium Hydrolyzed Casein, Hydroxypropyltrimonium Hydrolyzed Collagen, Hydroxypropyltrimonium Hydrolyzed Keratin, Hydroxypropyltrimonium Hydrolyzed Rice Bran Protein, Hydroxypropyltrimonium Hydrolyzed Silk, Hydroxypropyltrimonium Hydrolyzed Soy Protein, Hydroxypropyltrimonium Hydrolyzed Vegetable Protein.

In an embodiment is the invention to be used Composition gel and contains at least one thickener or gelling agent in an amount of preferably 0.01 to 20 wt.% Or 0.05 to 10 wt.% Or more preferably from 0.1 to 5% by weight. In principle, substances are suitable for use in the International Cosmetic Ingredient Dictionary and Handbook, 10th Edition, 2004, the function "Viscosity Increasing Agent " is. The thickener or gelling agent is preferably a thickening Polymer and is particularly preferably selected from copolymers of at least a first type of monomer selected from acrylic acid and methacrylic acid and at least one second type of monomer selected from esters of acrylic acid and ethoxylated fatty alcohol; crosslinked polyacrylic acid; networked Copolymers of at least one first type of monomer selected from acrylic acid and methacrylic acid and at least one second type of monomer selected from esters of acrylic acid with C10 to C30 alcohols; Copolymers of at least a first Monomer type selected is made of acrylic acid and methacrylic acid and at least one second type of monomer selected from esters of itaconic acid and ethoxylated fatty alcohol; Copolymers of at least one first monomer species selected is made of acrylic acid and methacrylic acid, at least one second type of monomer selected from esters of itaconic acid and ethoxylated C10 to C30 alcohol and a third type of monomer, selected from C 1 to C 4 aminoalkyl acrylates; Copolymers of two or more Monomers selected from acrylic acid, methacrylic acid, Acrylsäureestern and methacrylic acid esters; Copolymers of vinylpyrrolidone and ammonium acryloyldimethyltaurate; Copolymers of Ammoniumacryloyldimethyltaurat and monomers selected from Esters of methacrylic acid and ethoxylated fatty alcohols; hydroxyethyl cellulose; hydroxypropyl cellulose; hydroxypropyl; Glycerylpolyacrylat; glyceryl; Copolymers of at least one C 2 -C 3 or C 4 alkylene and styrene; polyurethanes; hydroxypropyl starch; polyacrylamide; decadiene crosslinked copolymer of maleic anhydride and methyl vinyl ether; Locust bean gum; Guar gum; xanthan; Dehydroxanthan; carrageenan; Karaya gum; hydrolyzed cornstarch; copolymers of polyethylene oxide, fatty alcohols and saturated methylene diphenyl diisocyanate (e.g., PEG-150 / stearyl alcohol / SMDI copolymer).

In a further embodiment the composition is waxy and contains at least one at 25 ° C solid wax in an amount of preferably 10 to 80% by weight, in particular from 20 to 60% by weight or from 25 to 50% by weight, and optionally further, liquid at room temperature, water-insoluble substances. The waxy consistency is preferably characterized that the needle penetration number (unit 0.1 mm, test weight 100 g, test duration 5 s, test temperature 25 ° C; to DIN 51 579) preferably in the range of 2 to 70, in particular of 3 to 40 and / or that the composition is meltable and has a freezing point greater than 25 ° C, preferably in the range of 30 to 70 ° C, particularly preferably in the range from 40 to 55 ° C.

When Wax or waxy substance can in principle be any in the state of Technique known wax can be used. These include animal, vegetable, mineral and synthetic waxes, microcrystalline waxes, macrocrystalline waxes, solid paraffins, petrolatum, vaseline, Ozokerite, montan wax, Fischer-Tropsch waxes, polyolefin waxes e.g. Polybutene, beeswax, wool wax and its derivatives, e.g. Wool wax alcohols, candelilla wax, olive wax, carnauba wax, Japan wax, apple wax, hardened Fats, fatty acid esters and fatty acid glycerides with a solidification point of above 40 ° C, silicone waxes or hydrophilic waxes such as e.g. high molecular weight polyethylene glycol waxes with a molecular weight of e.g. 800 to 20,000, preferably from 2,000 to 10,000 g / mol. The waxes or waxy substances have a solidification point above 25 ° C, preferably above 40 ° C or 55 ° C. The needle penetration number (0.1 mm, 100 g, 5 s, 25 ° C; according to DIN 51 579) is preferably in the range of 2 to 70, in particular from 3 to 40.

In a further embodiment, the composition is emulsion-shaped, wherein the consistency is preferably creamy. It may be a water-in-oil, an oil-in-water, a microemulsion or a higher emulsion. In addition to water, it is preferable to contain at least one hydrophobic oil which is liquid at room temperature (25 ° C.) and at least one emulsifier. The content of oil is preferably from 1 to 20% by weight, in particular from 2 to 10% by weight. The emulsifier content is preferably from 0.01 to 30% by weight, in particular from 0.1 to 20% by weight, or from 0.5 to 10% by weight. Further hair-conditioning substances may be present in an amount of, for example, from 0 to 20% by weight, preferably from 0.01 to 10% by weight.

• – Ethoxylierte Fettalkohole, Fettsäuren, Fettsäureglyceride oder Alkylphenole, insbesondere Anlagerungsprodukte von 2 bis 30 mol Ethylenoxid und/oder 1 bis 5 mol Propylenoxid an C8- bis C22-Fettalkohole, an C12- bis C22-Fettsäuren oder an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe
• – C12- bis C22-Fettsäuremono- und -diester von Anlagerungsprodukten von 1 bis 30 mol Ethylenoxid an Glycerin
• – Anlagerungsprodukte von 5 bis 60 mol Ethylenoxid an Rizinusöl oder an gehärtetes (hydriertes) Rizinusöl.
• – Fettsäurezuckerester, insbesondere Ester aus Saccharose und ein oder zwei C8- bis C22-Fettsäuren, INCI: Sucrose Cocoate, Sucrose Dilaurate, Sucrose Distearate, Sucrose Laurate, Sucrose Myristate, Sucrose Oleate, Sucrose Palmitate, Sucrose Ricinoleate, Sucrose Stearate
• – Ester aus Sorbitan und ein, zwei oder drei C8- bis C22-Fettsäuren und einem Ethoxylierungsgrad von 4 bis 20
• – Polyglycerylfettsäureester, insbesondere aus ein, zwei oder mehreren C8- bis C22-Fettsäuren und Polyglycerin mit vorzugsweise 2 bis 20 Glyceryleinheiten
• – Alkylglukoside, Alkyloligoglukoside und Alkylpolyglucoside mit C8- bis C22-Alkylgruppen, z.B. Decyl Glucoside oder Lauryl Glucoside.

The emulsifiers may be nonionic, anionic, cationic or zwitterionic surfactants. Suitable nonionic surfactants are, for example

• Ethoxylated fatty alcohols, fatty acids, fatty acid glycerides or alkylphenols, in particular addition products of 2 to 30 mol of ethylene oxide and / or 1 to 5 mol of propylene oxide onto C 8 to C 22 fatty alcohols, to C 12 to C 22 fatty acids or to alkylphenols having 8 to 15 C Atoms in the alkyl group
• C12 to C22 fatty acid mono- and diesters of addition products of 1 to 30 mol of ethylene oxide with glycerol
• - Addition products of 5 to 60 moles of ethylene oxide to castor oil or to hydrogenated (hydrogenated) castor oil.
• - fatty acid sugar esters, especially esters of sucrose and one or two C8 to C22 fatty acids, INCI: sucrose cocoate, sucrose dilaurate, sucrose distearate, sucrose laurate, sucrose myristate, sucrose oleate, sucrose palmitate, sucrose ricinoleate, sucrose stearate
• - esters of sorbitan and one, two or three C8 to C22 fatty acids and a degree of ethoxylation of 4 to 20
• - Polyglycerylfettsäureester, in particular from one, two or more C8 to C22 fatty acids and polyglycerol having preferably 2 to 20 Glyceryleinheiten
• - Alkylglucoside, Alkyloligoglukoside and Alkylpolyglucoside with C8 to C22-alkyl groups, eg Decyl Glucoside or Lauryl Glucoside.

suitable anionic surfactants are e.g. Salts and esters of carboxylic acids, alkyl ether sulfates and alkyl sulfates, fatty alcohol ether sulfates, sulfonic acid and their salts (e.g., sulfosuccinates or fatty acid isethienates), phosphoric acid esters and their salts, acylamino acids and their salts. A detailed Description of these anionic surfactants is the publication "FIEDLER - Lexikon of excipients ", Volume 1, fifth Edition (2002), pages 97 to 102, to which hereby expressly Reference is made. Preferred surfactants are mono-, di- and / or Triester of phosphoric acid with addition products of 2 to 30 moles of ethylene oxide with C 8 to C 22 fatty alcohols.

wobei R1 eine geradkettige oder verzweigtkettige Alkyl-, Alkenyl- oder Hydroxyalkylgruppe mit 8 bis 18 C-Atomen und 0 bis etwa 10 Ethylenoxideinheiten und 0 bis 1 Glycerineinheit darstellt; Y eine N-, P- oder S-haltige Gruppe ist; R2 eine Alkyl- oder Monohydroxyalkylgruppe mit 1 bis 3 C-Atomen ist; die Summe von x+y gleich 2 ist, falls Y ein Schwefelatom ist und die Summe von x+y gleich 3 ist, wenn Y ein Stickstoffatom oder ein Phosphoratom ist; R3 eine Alkylen- oder Hydroxyalkylengruppe mit 1 bis 4 C-Atomen ist und Z^(-) eine Carboxylat-, Sulfat-, Phosphonat- oder Phosphatgruppe darstellt. Andere amphotere Tenside wie Betaine sind ebenso geeignet. Beispiele für Betaine umfassen C8- bis C18-Alkylbetaine wie Cocodimethylcarboxymethylbetain, Lauryldimethylcarboxymethylbetain, Lauryldimethylalphacarboxyethylbetain, Cetyldimethylcarboxymethylbetain, Oleyldimethylgammacarboxypropylbetain und Lauryl-bis(2-hydroxypropyl)alphacarboxyethylbetain; C8- bis C18-Sulfobetaine wie Cocodimethylsulfopropylbetain, Stearyldimethylsulfopropylbetain, Lauryldimethylsulfoethylbetain, Laurylbis-(2-hydroxyethyl)sulfopropylbetain; die Carboxylderivate des Imidazols, die C8- bis C18-Alkyldimethylammoniumacetate, die C8- bis C18-Alkyldimethylcarbonylmethylammoniumsalze sowie die C8- bis C18-Fettsäurealkylamidobetaine wie beispielsweise Kokosfettsäureamidopropylbetain und N-Kokosfettsäureamidoethyl-N-[2-(carboxymethoxy)ethyl]-glycerin (CTFA-Name: Cocoamphocarboxyglycinate).Suitable amphoteric surfactants are, for example, derivatives of aliphatic quaternary ammonium, phosphonium and sulfonium compounds of the formula

wherein R 1 represents a straight-chain or branched-chain alkyl, alkenyl or hydroxyalkyl group having 8 to 18 C atoms and 0 to about 10 ethylene oxide units and 0 to 1 glycerol unit; Y is an N-, P- or S-containing group; R 2 is an alkyl or monohydroxyalkyl group having 1 to 3 C atoms; the sum of x + y is 2 if Y is a sulfur atom and the sum of x + y is 3 if Y is a nitrogen atom or a phosphorus atom; R3 is an alkylene or hydroxyalkylene group having 1 to 4 carbon atoms and Z ^{(-) is} a carboxylate, sulfate, phosphonate or phosphate group. Other amphoteric surfactants such as betaines are also suitable. Examples of betaines include C8 to C18 alkyl betaines such as cocodimethylcarboxymethylbetaine, lauryldimethylcarboxymethylbetaine, lauryldimethylalphacarboxyethylbetaine, cetyldimethylcarboxymethylbetaine, oleyldimethylgammacarboxypropylbetaine and lauryl-bis (2-hydroxypropyl) alphacarboxyethylbetaine; C8 to C18 sulfobetaines such as cocodimethylsulfopropyl betaine, stearyl dimethyl sulfopropyl betaine, lauryl dimethyl sulfoethyl betaine, lauryl bis- (2-hydroxyethyl) sulfopropyl betaine; the carboxyl derivatives of imidazole, the C8 to C18 alkyldimethylammonium acetates, the C8 to C18 alkyldimethylcarbonylmethylammonium salts and the C8 to C18 fatty acid alkylamidobetaines such as coconut fatty acid amidopropylbetaine and N-coconut fatty acid amidoethyl-N- [2- (carboxymethoxy) ethyl] glycerol (CTFA Name: cocoamphocarboxyglycinate).

The cosmetic composition to be used according to the invention may additionally comprise at least one further hair or skin cosmetic active ingredient or additive. This active ingredient or additive may be selected, for example, from hair-care substances, hair-setting substances, light stabilizers, preservatives, pigments, substantive hair dyes, particulate substances, oxidizing agents, reducing agents and oxidation hair dye precursors. The active ingredients and additives are depending on the type and one preferably in an amount of 0.01 to 20 wt.%, In particular from 0.05 to 10 or from 0.1 to 5 wt.% Contain.

In an embodiment contains the agent of the invention at least one hair-conditioning or hair-setting additive Polymer with anionic or anionizable groups in an amount from preferably 0.01 to 20% by weight or from 0.05 to 10% by weight, especially preferably from 0.1 to 5% by weight. Under anionizable groups are acid groups such as. carboxylic acid, sulfonic acid or phosphoric acid groups understood, which by means of conventional Bases such as e.g. organic amines or alkali or alkaline earth metal hydroxides can be deprotonated. The anionic polymers can partially or completely be neutralized with a basic neutralizing agent. Prefers are those agents in which the acidic groups in the polymer too 50 to 100%, more preferably 70-100 are neutralized. When Neutralizing agents can organic or inorganic bases are used. Examples of bases In particular, aminoalkanols, e.g. Aminomethylpropanol (AMP), Triethanolamine or monoethanolamine, but also ammonia, NaOH, KOH inter alia ..

The anionic polymer may be a homo- or copolymer with acid groups containing monomer units to natural or synthetic Base, which optionally with comonomers, which are not acid groups contained, copolymerized. The acid groups are sulfonic acid, phosphoric acid and carboxylic acid groups into consideration, of which the carboxylic acid groups are preferred. Suitable acid groups containing Monomers are, for example, acrylic acid, methacrylic acid, crotonic acid, maleic acid or maleic anhydride, maleic, in particular the mono-C1-C7-alkyl esters maleic acid and aldehyde carboxylic acids or ketocarboxylic acids. Not with acid groups substituted comonomers are, for example, acrylamide, methacrylamide, Alkyl and dialkylacrylamide, alkyl and dialkylmethacrylamide, alkyl acrylate, Alkyl methacrylate, vinyl caprolactone, vinyl pyrrolidone, vinyl ester, Vinyl alcohol, propylene glycol or ethylene glycol, amine-substituted Vinyl monomers such as e.g. Dialkylaminoalkyl acrylate, dialkylaminoalkyl methacrylate, monoalkylaminoalkyl acrylate and monoalkylaminoalkyl methacrylate, wherein the alkyl groups of these Monomers preferably Cl- to C7-alkyl groups, more preferably C1 to C3 alkyl groups are.

suitable Polymers with acid groups are in particular uncrosslinked or with polyfunctional agents crosslinked homopolymers of acrylic acid or methacrylic acid, copolymers the acrylic acid or methacrylic acid selected with monomers from acrylic acid or methacrylic acid esters, Acrylamides, methacrylamides and vinylpyrrolidone, homopolymers of crotonic and copolymers of crotonic acid selected with monomers from vinyl esters, acrylic acid or methacrylic acid esters, Acrylamides and methacrylamides. A suitable natural Polymer is shellac, for example.

Preferred polymers with acid groups are:
Terpolymers of acrylic acid, alkyl acrylate and N-alkylacrylamide (INCI name: acrylates / acrylamide copolymer), in particular terpolymers of acrylic acid, ethyl acrylate and N-tert-butylacrylamide; crosslinked or uncrosslinked vinyl acetate / crotonic acid copolymers (INCI name: VA / crotonates copolymer); Copolymers of one or more C 1 -C 5 -alkyl acrylates, in particular C 2 -C 4 -alkyl acrylates and at least one monomer selected from acrylic acid or methacrylic acid (INCI name: acrylates copolymer), for example terpolymers of tert-butyl acrylate, ethyl acrylate and methacrylic acid; sodium polystyrene sulfonate; Vinyl acetate / crotonic acid / vinyl alkanoate copolymers, for example copolymers of vinyl acetate, crotonic acid and vinyl propionate; Copolymers of vinyl acetate, crotonic acid and vinyl neodecanoate (INCI names: VA / Crotonates / Vinyl Propionate Copolymer, VA / Crotonates / Vinyl Neodecanoate Copolymer); Aminomethylpropanol acrylate copolymers; Copolymers of vinylpyrrolidone and at least one other monomer selected from acrylic acid and methacrylic acid and optionally acrylic acid esters and methacrylic acid esters; Copolymers of methyl vinyl ether and maleic acid monoalkyl esters (INCI names: ethyl ester of PVM / MA copolymer, butyl ester of PVM / MA copolymer); Aminomethylpropanolsalze of copolymers of allyl methacrylate and at least one other monomer selected from acrylic acid, and methacrylic acid and optionally acrylic acid esters and methacrylic acid esters; crosslinked copolymers of ethyl acrylate and methacrylic acid; Copolymers of vinyl acetate, mono-n-butyl maleate and isobornyl acrylate; Copolymers of two or more monomers selected from acrylic acid and methacrylic acid and optionally acrylic acid esters and methacrylic acid esters; Copolymers of octylacrylamide and at least one monomer selected from acrylic acid and methacrylic acid and optionally acrylic acid esters and methacrylic acid esters; Polyesters of diglycol, cyclohexanedimethanol, isophthalic acid and sulfoisophthalic acid, wherein the alkyl groups of the abovementioned polymers generally have preferably 1, 2, 3 or 4 carbon atoms.

In one embodiment, the composition according to the invention contains as a hair-care or hair-setting additive at least one zwitterionic and / or amphoteric polymer in an amount of preference from 0.01 to 20% by weight or from 0.05 to 10% by weight, particularly preferably from 0.1 to 5% by weight. Zwitterionic polymers have at the same time at least one anionic and at least one cationic charge. Amphoteric polymers have at least one acidic group (eg carboxylic acid or sulphonic acid group) and at least one basic group (eg amino group). Acid groups may be deprotonated by conventional bases such as organic amines or alkali or alkaline earth hydroxides.

preferred zwitterionic or amphoteric polymers are: copolymers formed of alkylacrylamide, alkylaminoalkylmethacrylate and two or more Monomers of acrylic acid and methacrylic acid and optionally their esters, in particular copolymers of octylacrylamide, Acrylic acid, Butylaminoethyl methacrylate, methyl methacrylate and hydroxypropyl methacrylate (INCI name: octylacrylamide / acrylates / butylaminoethyl methacrylates Copolymer); Copolymers which are formed from at least one first type of monomer which has quaternary amine groups and at least one second type of monomer having acid groups; copolymers from fatty alcohol acrylates, alkylamine oxide methacrylate and at least a monomer selected from acrylic acid and methacrylic acid and optionally acrylic acid esters and methacrylic acid esters, in particular copolymers of lauryl acrylate, stearyl acrylate, ethylamine oxide methacrylate and at least one monomer selected from acrylic acid and methacrylic acid and, if appropriate, their esters; Copolymers of methacryloyl ethyl betaine and at least one monomer selected from methacrylic acid and methacrylic acid esters; Copolymers of acrylic acid, Methyl acrylate and methacrylamidopropyltrimethylammonium chloride (INCI name: Polyquaternium-47); Copolymers of acrylamidopropyltrimethylammonium chloride and acrylates or copolymers of acrylamide, acrylamidopropyltrimethylammonium chloride, 2-amidopropylacrylamide sulfonate and dimethylaminopropylamine (INCI name: Polyquaternium-43); Oligomers or polymers preparable from quaternary Crotonbetainen or quaternary Crotonbetainestern.

In an embodiment contains the agent of the invention as a further hair care or hair setting additive at least a cationic polymer, i. a polymer with cationic or cationizable groups, in particular primary, secondary, tertiary or quaternary amine groups in an amount of preferably 0.01 to 20% by weight or 0.05 to 10% by weight, more preferably from 0.1 to 5% by weight. The cationic Charge density is preferably 1 to 7 meq / g.

at the suitable cationic polymer is preferably hair-setting or hair-conditioning polymers. suitable cationic polymers preferably contain quaternary amine groups. The cationic polymers can Homo- or copolymers, wherein the quaternary nitrogen groups either in the polymer chain or preferably as a substituent on one or more of the monomers are contained. The ammonium group-containing Monomers can be copolymerized with non-cationic monomers. suitable cationic monomers are unsaturated, radically polymerizable compounds which contain at least one carry cationic group, in particular ammonium-substituted vinyl monomers such as. Trialkylmethacryloxyalkylammonium, trialkylacryloxyalkylammonium, Dialkyldiallylammonium and quaternary Vinylammoniummonomere with cyclic, cationic nitrogen-containing groups such as pyridinium, Imidazolium or quaternary Pyrrolidones, e.g. Alkylvinylimidazolium, Alkylvinylpyridinium, or Alkylvinylpyrrolidone salts. The alkyl groups of these monomers are preferably lower alkyl groups such as e.g. C1 to C7 alkyl groups, especially preferably Cl- to C3-alkyl groups.

The Ammonium group-containing monomers may be non-cationic Be copolymerized monomers. Suitable comonomers are, for example Acrylamide, methacrylamide, alkyl and dialkylacrylamide, alkyl and Dialkylmethacrylamide, alkylacrylate, alkylmethacrylate, vinylcaprolactone, Vinylcaprolactam, vinylpyrrolidone, vinylester, e.g. vinyl acetate, Vinyl alcohol, propylene glycol or ethylene glycol, wherein the alkyl groups these monomers preferably C1 to C7 alkyl groups, especially preferably C1 to C3 alkyl groups.

suitable Polymers with quaternary Amine groups are e.g. in the CTFA Cosmetic Ingredient Dictionary polymers described under the names Polyquaternium Methylvinylimidazolium chloride / vinylpyrrolidone copolymer (Polyquaternium-16) or quaternized vinylpyrrolidone / dimethylaminoethylmethacrylate Copolymer (Polyquaternium-11) and quaternary silicone polymers or oligomers such as silicone polymers with quaternary end groups (Quaternium-80).

Preferred cationic polymers on a synthetic basis:
Poly (dimethyldiallylammonium chloride); Copolymers of acrylamide and dimethyldiallylammonium chloride; quaternary ammonium polymers formed by the reaction of diethyl sulfate and a copolymer of vinylpyrrolidone and dimethylaminoethyl methacrylate, especially vinylpyrrolidone / dimethylaminoethyl methacrylate copolymer (such as Gafquat ^® 755 N, Gafquat ^® 734); quaternary ammonium polymers of methyl vinyl limidazoliumchlorid and vinylpyrrolidone (eg LUVIQUAT ^® HM 550); Polyquaternium-35; Polyquaternium-57; Polymer of trimethyl ammonium ethyl methacrylate chloride; Terpolymers of dimethyldiallylammonium chloride, sodium acrylate and acrylamide (eg Merquat ^® Plus 3300); Copolymers of vinylpyrrolidone, dimethylaminopropylmethacrylamide and methacryloylaminopropyllauryldimethylammonium chloride; Terpolymers of vinylpyrrolidone, dimethylaminoethyl methacrylate and vinylcaprolactam (such as Gaffix ^® VC 713); Vinylpyrrolidone / methacrylamidopropyltrimethylammonium chloride copolymers (eg Gafquat ^® HS 100); Copolymers of vinylpyrrolidone and dimethylaminoethyl methacrylate; Copolymers of vinylpyrrolidone, vinylcaprolactam and dimethylaminopropylacrylamide; Poly or oligoester, composed of at least one first type of monomer, which is selected from substituted with at least one quaternary ammonium group hydroxy acid; terminally substituted with quaternary ammonium groups dimethylpolysiloxanes.

Suitable cationic polymers derived from natural polymers are, in particular, cationic derivatives of polysaccharides, for example cationic derivatives of cellulose, starch or guar. Also suitable are chitosan and chitosan derivatives. Cationic polysaccharides have, for example, the general formula GOBN ⁺ R ^a R ^b R ^c X ^- G is an anhydroglucose residue, for example starch or cellulose anhydroglucose;
B is a divalent linking group, for example, alkylene, oxyalkylene, polyoxyalkylene or hydroxyalkylene;
R ^a , R ^b and R ^c are independently alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl or alkoxyaryl each having up to 18 carbon atoms, wherein the total number of carbon atoms in R ^a , R ^b and R ^{c is} preferably not more than 20 is;
X is a common counter anion, for example a halogen, acetate, phosphate, nitrate or alkyl sulfate, preferably a chloride. Cationic celluloses are, for example, those with the INCI names Polyquaternium-4, Polyquaternium-10 or Polyquaternium-24. A suitable cationic guar derivative has, for example, the INCI name Guar Hydroxypropyltrimonium Chloride.

Particularly preferred cationic substances are chitosan, chitosan salts and chitosan derivatives. The chitosans to be used according to the invention are completely or partially deacetylated chitins. The molecular weight can be distributed over a broad spectrum, for example from 20,000 to about 5 million g / mol, for example from 30,000 to 70,000 g / mol. Preferably, however, the molecular weight is above 100,000 g / mol, more preferably from 200,000 to 700,000 g / mol. The degree of deacetylation is preferably 10 to 99%, more preferably 60 to 99%. A preferred chitosan salt is Chitosoniumpyrrolidoncarboxylat, eg Kytamer ^® PC with a molecular weight of about 200,000 to 300,000 g / mol and deacetylation of 70 to 85%. Suitable chitosan derivatives are quaternized, alkylated or hydroxyalkylated derivatives, for example hydroxyethyl, hydroxypropyl or hydroxybutylchitosan. The chitosans or chitosan derivatives are preferably in neutralized or partially neutralized form. The degree of neutralization is preferably at least 50%, particularly preferably between 70 and 100, based on the number of free base groups. As neutralizing agents, it is possible in principle to use all cosmetically acceptable inorganic or organic acids, such as, for example, formic acid, tartaric acid, malic acid, lactic acid, citric acid, pyrrolidonecarboxylic acid, hydrochloric acid, among others, of which the pyrrolidonecarboxylic acid is particularly preferred.

preferred cationic polymers on natural Basis: cationic cellulose derivatives of hydroxyethyl cellulose and diallyl dimethyl ammonium chloride; cationic cellulose derivatives Hydroxyethyl cellulose and trimethyl ammonium substituted epoxide; Chitosan and its salts; Hydroxyalkyl chitosans and their salts; Alkyl hydroxyalkyl chitosans and their salts; N-Hydroxyalkylchitosanalkylether.

In an embodiment contains the agent of the invention 0.01 to 15 wt.%, Preferably 0.5 to 10 wt.% Of at least one synthetic or natural nonionic film-forming polymer. Suitable synthetic nonionic Polymers are homopolymers or copolymers which consist of at least one of composed of the following monomers: vinyllactams, e.g. vinylpyrrolidone or vinyl caprolactam; Vinyl esters, e.g. vinyl acetate; Vinyl alcohol, Vinylformamide, acrylamides, methacrylamides, alkylacrylamides, dialkylacrylamides, Alkylmethacrylamides, dialkylmethacrylamides, alkylacrylates, alkylmethacrylates, Alkylmaleimides such as e.g. Ethylmaleimide or hydroxyethylmaleimide and alkylene glycols, e.g. Propylene glycol or ethylene glycol, wherein the alkyl or Alkylene groups of these monomers preferably C1 to C7 alkyl groups, especially preferably C1 to C3 alkyl groups.

For example, homopolymers of vinylcaprolactam, of vinylpyrrolidone or of N-vinyl are suitable formamide. Further suitable synthetic nonionic polymers are, for example, polyacrylamides, polyethylene glycol / polypropylene glycol copolymers, copolymers of vinylpyrrolidone and vinyl acetate, terpolymers of vinylpyrrolidone, vinyl acetate and vinyl propionate, polyacrylamides; Polyvinyl alcohols and polyethylene glycol / polypropylene glycol copolymers. Suitable natural film-forming polymers are in particular those based on saccharides, preferably glucans, for example, cellulose and its derivatives. Suitable derivatives are, in particular, those having alkyl and / or hydroxyalkyl substituents, where the alkyl groups may contain, for example, 1 to 20, preferably 1 to 4, carbon atoms, for example hydroxyalkylcellulose. Preferred nonionic polymers are: polyvinylpyrrolidone, polyvinylcaprolactam, vinylpyrrolidone / vinyl acetate copolymers, polyvinyl alcohol, isobutylene / ethylmaleimide / hydroxyethylmaleimide copolymer; Copolymers of vinylpyrrolidone, vinyl acetate and vinyl propionate.

In one embodiment, the composition according to the invention contains a light stabilizer in an amount of preferably 0.01 to 10 wt. Or from 0.1 to 5 wt.%, Particularly preferably from 0.2 to 2 wt.%. The light stabilizers include in particular all in the EP 1 084 696 mentioned light stabilizers. Preference is given to 4-methoxycinnamic acid 2-ethylhexyl ester, methyl methoxycinnamate, 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and polyethoxylated p-aminobenzoates.

In an embodiment contains the agent of the invention 0.01 to 20, more preferably from 0.05 to 10, most especially preferably from 0.1 to 5% by weight of at least one hair conditioning agent Additive, selected from A-B block copolymers from alkyl acrylates and alkyl methacrylates; A-B block copolymers of alkyl methacrylates and acrylonitrile; A-B-A block copolymers from lactide and ethylene oxide; A-B-A block copolymers of caprolactone and ethylene oxide; A-B-C block copolymers from alkylene or alkadiene compounds, styrene and alkyl methacrylates; A-B-C block copolymers of acrylic acid, styrene and alkyl methacrylates; stellate Block copolymers; hyperbranched polymers; dendrimers; intrinsically electric conductive 3,4-polyethylenedioxythiophenes and intrinsically electrically conductive polyanilines.

In an embodiment contains the agent of the invention From 0.01 to 5, more preferably from 0.05 to 1, weight of at least a preservative. Suitable preservatives are the International Cosmetic Ingredient Dictionary and Handbook, 10th edition with the function "Preservatives" listed substances, e.g. Phenoxyethanol, benzylparaben, butylparaben, ethylparaben, Isobutylparaben, isopropylparaben, methylparaben, propylparaben, Iodopropynyl butyl carbamate, methyl dibromoglutaronitrile, DMDM hydantoin.

In a preferred embodiment contains the agent of the invention at least one pigment. These can be colored pigments act, which give the product mass or hair color effects or it may be glossy effect pigments which are the product mass or give the hair gloss effects. The color or gloss effects on the hair are preferably temporary, i.e. they hold until the next shampooing and can by washing the hair with usual Shampoos are removed again. The pigments are in the product mass in unresolved Form and can in an amount of 0.01 to 25 wt.%, particularly preferably 5 be contained to 15 wt.%. The preferred particle size is 1 to 200 microns, in particular 3 to 150 μm, more preferably 10 to 100 microns. The pigments are practically insoluble colorants in the application medium and can be inorganic or organic. Also inorganic-organic mixed pigments are possible. Preference is given to inorganic pigments. The advantage of inorganic pigments is their excellent light, weather and temperature resistance. The inorganic pigments can natural Origin, for example made of chalk, ocher, umber, Green earth, burnt Terra di Siena or graphite. For the pigments it can about white pigments such as. Titanium dioxide or zinc oxide to form black pigments, e.g. Iron oxide black, colored pigments such as e.g. Ultramarine or iron oxide red, to luster pigments, metallic effect pigments, pearlescent pigments and to act fluorescence or Phosphoreszenzpigmente, preferably at least one pigment is a colored, non-white pigment. Are suitable Metal oxides, hydroxides and oxide hydrates, mixed phase pigments, sulfur-containing Silicates, metal sulfides, complex metal cyanides, metal sulfates, -chromates and -molybdate and the metals themselves (bronze pigments). Titanium dioxide (CI 77891), black iron oxide are particularly suitable (CI 77499), yellow iron oxide (CI 77492), red and brown iron oxide (CI 77491), manganese violet (CI 77742), ultramarines (sodium aluminum sulfosilicates, CI 77007, Pigment Blue 29), chromium oxide hydrate (CI77289), iron blue (Ferric Ferrocyanide, CI77510), Carmine (Cochineal).

Particular preference is given to pearlescent and color pigments based on mica or mica which are coated with a metal oxide or a metal oxychloride such as titanium dioxide or bismuth oxychloride and optionally further coloring substances such as iron oxides, iron blue, ultramarines, carmines, etc., and the color is determined by varying the layer thickness can be. Such pigments are, for example, under the trade names Rona ^®, Colorona® ^{®, ®} and Dichrona® Timiron ^® from Merck, Germany distributed.

organic Pigments are, for example, the natural pigments sepia, cambogia, Bone charcoal, Kasseler brown, indigo, chlorophyll and other plant pigments. Synthetic organic pigments are, for example, azo pigments, Anthraquinoids, indigoids, dioxazine, quinacridone, phthalocyanine, Isoindolinone, Perylene and Perinone, Metal Complex, Alkali Blue and diketopyrrolopyrrole pigments.

In an embodiment contains the agent of the invention 0.01 to 10, more preferably from 0.05 to 5 wt.% Of at least a particulate Material. Suitable substances are e.g. Substances at room temperature (25 ° C) are and in the form of particles. Suitable are, for example, silica, Silicates, aluminates, clays, mica, salts, especially inorganic Metal salts, metal oxides, e.g. Titanium dioxide, minerals and polymer particles. The particles are in the agent in undissolved, preferably stably dispersed Form and can after application to the hair and evaporation of the solvent on the hair in solid form. A stable dispersion can be achieved by adding the composition with a yield point is provided that big enough is to prevent a decrease of the solid particles. A sufficient yield can by using suitable gelling agents in an appropriate amount be set. Preferred particulate substances are silica (silica gel, Silica) and metal salts, especially inorganic metal salts, with silica being particularly preferred. Metal salts are e.g. Alkali- or alkaline earth halides such as sodium chloride or potassium chloride; Alkali or alkaline earth sulfates such as sodium sulfate or magnesium sulfate.

A another embodiment relates to a means for permanent deformation of the hair. It contains at least a reducing agent, in particular a keratin-reducing mercapto compound in an amount of preferably 0.5 to 15% by weight. The permanent wave agent is preferably as an aqueous, alkaline (pH = 5 to 10) adjusted preparation, which as keratin reducing Mercapto compound, for example cysteine, cysteamine, N-acetyl-L-cysteine, mercaptocarboxylic such as. thioglycolic or thiolactic acid, or Salts of mercaptocarboxylic acids, such as. Ammonium and guanidine salts of thioglycolic acid or thiolactic contains. The required alkalinity This is due to the addition of ammonia, organic amines, Ammonium and alkali carbonates or bicarbonates set. But it also comes a neutral or sour (pH = 4.5 to 7) adjusted hair shaping agent, that in the aqueous Medium an effective content of sulfites or mercaptocarboxylic acid esters having. In the former case, preferably sodium or ammonium sulfite or the salt of sulphurous acid with an organic amine, e.g. Monoethanolamine and guanidine, in a concentration of about 2 to 12% by weight (calculated as SO 2) used. In the latter case, in particular, thioglycolic acid monoglycol esters are used or glycerol ester in a concentration of about 5 to 50% by weight (corresponding to a content of free thioglycolic acid from 2 to 16% by weight) Application. The agent according to the invention for permanent hair deformation can also be a mixture of the above contain mentioned keratin reducing compounds. For the oxidative Post-treatment may be an inventive, at least one oxidizing agent containing fixing agent can be used. Examples in one oxidants usable in such fixatives are sodium and potassium bromate, sodium perborate, urea peroxide and hydrogen peroxide. The concentration of the oxidizing agent can be about 0.5 to 10% by weight. Both the inventive composition for permanent hair deformation as well as the fixing agent according to the invention may be in the form of an emulsion or in thickened form on aqueous Base, in particular as a cream, gel or paste.

The used according to the invention Composition can about it addition, for Hair treatment agent usual Contain additional ingredients, e.g. Perfume oils; Opacifiers such as e.g. ethylene glycol, Styrene / PVP copolymers or polystyrenes; Humectants; Luster-imparting agents; Produktanfärbestoffe; antioxidants; in amounts of in each case preferably 0.01 to 10% by weight, the total amount preferably does not exceed 10% by weight.

A particular application of the invention relates to a hair care product. Hair care products are e.g. Conditioners, treatments, hair treatments, or rinses like. An inventive hair care product Can after application to dry, damp or wet hair either remain in the hair or it may after a suitable exposure time rinsed out again become. The exposure times depend on the type of hair. As a general guideline may be of exposure times between 0.5 and 30 minutes, especially 0.5 and 10 minutes, preferably between 1 and 5 minutes.

• – ein erfindungsgemäßes Produktabgabesystem bereit gestellt wird,
• – mittels des Produktabgabesystems die darin befindliche Zusammensetzung auf das Haar aufgesprüht wird und
• – die aufgesprühte Zusammensetzung entweder nach einer Einwirkzeit aus dem Haar ausgespült oder im Haar belassen wird.

The invention also provides a method for hair treatment, wherein

• A product delivery system according to the invention is provided,
• - Sprayed by means of the product delivery system, the composition contained therein on the hair will and
• - The sprayed composition is either rinsed out of the hair after an exposure time or left in the hair.

Instead of of direct spraying on the hair, the product, especially if it is in the form of snow, Flakes or foam escapes, too, first on the hand or a Application aids such as e.g. applied to a comb or a brush and subsequently be distributed in the hair.

The products according to the invention are characterized by their particular application with the invention to be used special aerosol spray system, by a high care performance on the hair. The advantages in the Application show a comfortable application, a better one Distributability and a more economical dosage in comparison to conventional Products equal good to better care results, as well as in one Improvement of wet and dry combability, in an improvement the wet and dry grip, without straining the hair. Due to the extremely fine spray behavior of the Capillary system gives you a very high uniform distribution of the product on the hair. This leads to a better care result and at a lower consumption because the product is not distributed in the hand must become. Another advantage of the products of the invention is that by simple variation of the blowing agent, the blowing agent composition or the propellant pressure set different spray characteristics targeted leave as they have been for the underlying drug compositions were not available. The spray properties range from a fine aerosol spray over snow-like droplet and sprayed flakes up to a spray foam.

The The following examples are intended to explain the subject matter of the invention in more detail.

Examples

In the following examples, the respective active compound compositions were filled together with the specified propellant in a pressure-resistant aerosol can and provided with a capillary, as it is available, for example, under the name TRUSPRAY ^® from Boehringer Ingelheim microParts GmbH.

Example 1: hair conditioning agent with cationic surfactants

basic care for normal Hair, nourishes without straining the hair.

Example 2: hair conditioning agent with amino surfactants

positive Properties: Very good care for damaged hair

Example 3: Hair fluid with silicone compounds

positive Properties: Structure compensation for severely damaged hair.

Example 4: Sensitive hair treatment with fatty alcohols

positive Properties: Well tolerated Hair cure for sensitive scalp

Example 5: Sensitive Hair Treatment with Oils

positive Properties: Mild conditioner, for sensitive scalp, for heavily damaged hair.

Example 6: Sealing Serum with Plant Extracts

positive Properties: The serum compensates for structurally damaged hair.

Example 7 Leave-on Conditioner with Protein Hydrolyzates

positive Features: Daily Hair care for normal to damaged hair, nourishes without strain.

Example 8: Hydrating Conditioner with Amino Acids

positive Properties: Maintains dry and damaged hair.

Example 9: Hair conditioner with panthenol

positive Properties: Gel-shaped Hair conditioner that smoothes and nourishes the hair very well, without the hair to charge.

Example 10 Hair Conditioner with Panthenyl Ethyl Ether

positive Features: Base hair care for every day.

Example 11: Hair conditioning agent with sorbitol

positive Features: Conditioner for colored and damaged hair

Example 12: Conditioner with betaine

positive Properties: Nourishing conditioner for colored and heavily damaged hair

Example 13: Anionic hair cure with creatine

positive Properties: Mild, scalp-compatible conditioner for strong strained hair.

Filling ratios in% by weight:

With these bottling conditions, can the products are discharged with a fine spray.

Filling ratios in% by weight:

With these bottling conditions, can the products as spray snow, or in small flakes.

Claims (25)

Product delivery system for spraying a hair cosmetic composition comprising (a) one flameproof packaging, (b) one containing a capillary spray nozzle and (c) a propellant-containing cosmetic composition, in which the spraying by means of the capillary and the composition at least contains a hair conditioning agent that is selected from cationic surfactants, aminotensides, silicone compounds, fatty alcohols, oils, plant extracts, Protein hydrolysates, amino acids, Panthenol, panthenyl ethyl ether, sorbitol, betaine, creatine. Product delivery system according to claim 1, characterized in that that the capillary has a diameter of 0.1 to 1 mm and a length of 5 to 100 mm. Product delivery system according to one of the preceding Claims, characterized in that the spray rate is 0.01 to 5 g / s. Product delivery system according to one of the preceding Claims, characterized in that the blowing agents are selected from propane, butane, dimethyl ether, fluorinated hydrocarbons and their mixtures. Product delivery system according to one of the preceding Claims, characterized in that the hair conditioning cationic Surfactants and amino surfactants selected out are C8-22 alkyl dimethyl benzyl ammonium compounds, C8-22 alkyl trimethyl ammonium compounds, C8-22 Alkyldimethylhydroxyethylammoniumverbindungen, Di (C8-22-alkyl) -dimethylammonium compounds, C8-22-alkylpyridinium salts, C8-22- Alkylamidoethyltrimethylammonium ether sulfates, C8-22-alkylmethylamine oxides, C8-22 alkyl amino, Amidoamines and quaternized amidoamines. Product delivery system according to one of the preceding Claims, characterized in that the hair conditioning silicone compounds selected are cyclic dimethylsiloxanes, linear polydimethylsiloxanes, Block polymers of polydimethylsiloxane and polyethylene oxide and / or Polypropylene oxide, polydimethylsiloxanes having terminal or pendant polyethylene oxide or polypropylene oxide residues, Polydimethylsiloxanes with terminal Hydroxyl groups, phenyl-substituted polydimethylsiloxanes, silicone emulsions, Silicone elastomers, silicone waxes, silicone gums, amino substituted ones Silicones substituted with one or more quaternary ammonium groups Silicones and crosslinked silicones. Product delivery system according to one of the preceding Claims, characterized in that the hair conditioning fatty alcohols and oils selected are from branched or unbranched alcohols having 8 to 22 C atoms, fatty acid esters, mineral oils, isoparaffin, Paraffin oils, Squalane, sunflower oil, coconut oil, castor oil, lanolin oil, jojoba oil, corn oil, soybean oil. Product delivery system according to one of the preceding Claims, characterized in that the composition is gel, waxy or emulsion form is. Product delivery system according to claim 8, characterized in that that the gel-like Composition at least one thickener or gelling agent in one Amount of 0.01 to 20 wt.% Contains. Product delivery system according to claim 9, characterized in that the thickener or gelling agent is a thickening polymer, selected of copolymers of at least one first type of monomer selected from acrylic acid and methacrylic acid and at least one second type of monomer selected from Esters of acrylic acid and ethoxylated fatty alcohol; crosslinked polyacrylic acid; networked Copolymers of at least one first type of monomer selected from acrylic acid and methacrylic acid and at least one second type of monomer selected from esters of acrylic acid with C10 to C30 alcohols; Copolymers of at least a first Monomer type selected is made of acrylic acid and methacrylic acid and at least one second type of monomer selected from esters of itaconic acid and ethoxylated fatty alcohol; Copolymers of at least one first monomer species selected is made of acrylic acid and methacrylic acid, at least one second type of monomer selected from esters of itaconic acid and ethoxylated C10 to C30 alcohol and a third type of monomer, selected from C1 to C4 aminoalkyl acrylates; copolymers of two or more monomers selected from acrylic acid, methacrylic acid, acrylic acid esters and methacrylic acid esters; Copolymers of vinylpyrrolidone and ammonium acryloyldimethyltaurate; Copolymers of Ammoniumacryloyldimethyltaurat and monomers selected from Esters of methacrylic acid and ethoxylated fatty alcohols; hydroxyethyl cellulose; hydroxypropyl cellulose; hydroxypropyl; Glycerylpolyacrylat; glyceryl; Copolymers of at least one C2, C3 or C4 alkylene and styrene; polyurethanes; hydroxypropyl starch; polyacrylamide; decadiene crosslinked copolymer of maleic anhydride and methyl vinyl ether; Locust bean gum; Guar gum; xanthan; Dehydroxanthan; carrageenan; Karaya gum; hydrolyzed cornstarch; copolymers of polyethylene oxide, fatty alcohols and saturated methylene diphenyl diisocyanate. Product delivery system according to claim 8, characterized in that that the waxy Composition at least one fixed at 25 ° C wax in an amount from 10 to 80% by weight. Product delivery system according to claim 11, characterized in that that the wax is selected is made of paraffin waxes, polyolefin waxes, wool wax, wool wax alcohols, Candelilla wax, olive wax, carnauba wax, japan wax, apple wax, hardened Fats, fatty acid esters, fatty acid glycerides, fatty acid triglycerides, Polyethylene glycol waxes. Product delivery system according to claim 8, characterized in that that the emulsion-shaped Composition a water-in-oil, an oil-in-water or a microemulsion is at least one emulsifier in one Amount of 0.1 to 30 wt.%, And at least one oil in an amount of 1 to Contains 20 wt.% And water. Product delivery system according to claim 13, characterized that the emulsifier is selected from: adducts of 2 to 30 moles of ethylene oxide and / or 1 to 5 moles of propylene oxide on C8 to C22 fatty alcohols; Adducts from 2 to 30 mol of ethylene oxide and / or 1 to 5 mol of propylene oxide at C 12 to C22 fatty acids; Addition products of 2 to 30 moles of ethylene oxide and / or 1 to 5 mol of propylene oxide to alkylphenols having 8 to 15 carbon atoms in the alkyl group; C12 to C22 fatty acid mono- and diesters of addition products of 1 to 30 moles of ethylene oxide of glycerol; Addition products of 5 to 60 mol of ethylene oxide castor oil or hydrogenated castor oil; Mono-, di- or triesters of phosphoric acid with addition products from 2 to 30 moles of ethylene oxide to C8 to C22 fatty alcohols; ester of sucrose and one or two C8 to C22 fatty acids; ester from sorbitan and one, two or three C8 to C22 fatty acids and a degree of ethoxylation from 4 to 20; polyglyceryl fatty acid esters from one, two or more C8 to C22 fatty acids and polyglycerol with 2 to 20 glyceryl units; Alkyl glycosides. Product delivery system according to one of the preceding Claims, characterized in that the composition comprises at least one contains further active substance or additive selected from hair-care substances, hair-setting substances, light stabilizers, preservatives, Pigments, substantive hair dyes, particulate matter, Oxidizing agents, reducing agents and oxidation hair dye precursors. Product delivery system according to claim 15, characterized in that that the active ingredients and additives in an amount of 0.01 to 20 wt.% are included. Product delivery system according to claim 15 or 16, characterized characterized in that as a hair care or hair-setting substance a non-ionic polymer is selected, selected from polyvinylpyrrolidone, Polyvinylcaprolactam, vinylpyrrolidone / vinyl acetate copolymers, polyvinyl alcohol, Isobutylene / ethylmaleimide / hydroxyethylmaleimide copolymer; copolymers from vinyl pyrrolidone, vinyl acetate and vinyl propionate. Product delivery system according to claim 15 or 16, characterized characterized in that as a hair care or hair-setting substance an anionic polymer is selected, selected from terpolymers of acrylic acid, ethyl acrylate and N-tert-butylacrylamide; crosslinked or uncrosslinked vinyl acetate / crotonic acid copolymers; Terpolymers of tert-butyl acrylate, ethyl acrylate and methacrylic acid; sodium polystyrene sulfonate; Copolymers of vinyl acetate, crotonic acid and vinyl propionate; copolymers from vinyl acetate, crotonic acid and vinyl neodecanoate; Aminomethylpropanol acrylate copolymers; copolymers selected from vinylpyrrolidone and at least one other monomer Acrylic acid, methacrylic acid, Acrylsäureestern and methacrylic acid esters; Copolymers of methyl vinyl ether and maleic acid monoalkyl esters; Aminomethylpropanol salts of Copolymers of allyl methacrylate and at least one other monomer selected from acrylic acid, methacrylic acid, acrylic esters and methacrylic acid esters; crosslinked copolymers of ethyl acrylate and methacrylic acid; copolymers from vinyl acetate, mono-n-butyl maleate and isobornyl acrylate; copolymers of two or more monomers selected from acrylic acid, methacrylic acid, acrylic acid esters and methacrylic acid esters, Copolymers of octylacrylamide and at least one monomer selected from Acrylic acid, methacrylic acid, acrylic esters and methacrylic acid esters; Polyesters of diglycol, cyclohexanedimethanol, isophthalic acid and Sulfoisophthalic. Product delivery system according to claim 15 or 16, characterized characterized in that as a hair care or hair-setting substance a zwitterionic or amphoteric polymer is selected from Copolymers of octylacrylamide, acrylic acid, butylaminoethyl methacrylate, Methyl methacrylate and hydroxypropyl methacrylate; From copolymers Lauryl acrylate, stearyl acrylate, ethyl amine oxide methacrylate and at least a monomer selected from acrylic acid, methacrylic acid, Acrylsäureestern and methacrylic acid esters; Copolymers of methacryloyl ethyl betaine and at least one monomer selected from methacrylic acid and methacrylic acid esters; Copolymers of acrylic acid, Methyl acrylate and methacrylamidopropyltrimethylammonium chloride; Oligomers or polymers preparable from quaternary Crotonbetainen or quaternary Crotonbetainestern. Product delivery system according to claim 15 or 16, characterized characterized in that as a hair care or hair-setting substance contain a polymer with cationic or cationizable groups is, selected from cationic cellulose derivatives of hydroxyethylcellulose and diallyl dimethyl ammonium chloride; cationic cellulose derivatives of hydroxyethyl cellulose and trimethyl ammonium substituted epoxy; Poly (dimethyldiallylammonium chloride); Copolymers of acrylamide and dimethyldiallylammonium chloride; quaternary ammonium polymers by the reaction of diethyl sulfate and a copolymer of vinylpyrrolidone and dimethylaminoethyl methacrylate; quaternary ammonium polymers of methylvinylimidazolium chloride and vinyl pyrrolidone; Polyquaternium-35; Polymer of trimethyl ammonium ethyl methacrylate chloride; Polyquaternium-57; terminally with quaternary Ammonium group-substituted dimethylpolysiloxanes; Copolymer off Vinylpyrrolidone, dimethylaminopropylmethacrylamide and methacryloylaminopropyllauryldimethylammonium chloride; Chitosan and its salts; Hydroxyalkyl chitosans and their salts; Alkyl hydroxyalkyl chitosans and their salts; N-Hydroxyalkylchitosanalkylether; Copolymer of vinylcaprolactam, vinylpyrrolidone and dimethylaminoethyl methacrylate; Copolymers of vinyl pyrrolidone and dimethylaminoethyl methacrylate, Copolymers of vinylpyrrolidone, vinylcaprolactam and dimethylaminopropylacrylamide; Poly or Oligoestern, composed of at least a first monomer, the selected is substituted with at least one quaternary ammonium group Hydroxy acid. Product delivery system according to one of claims 15 to 20, characterized in that at least one light stabilizer is included, selected from 4-methoxycinnamic acid 2-ethylhexyl ester, Methylmethoxycinnamate, 2-hydroxy-4-methoxy-benzophenone-5-sulfonic acid and polyethoxylated p-aminobenzoates. Product delivery system according to one of claims 15 to 21, characterized in that contain an active substance and additive is the one selected is from A-B block copolymers of alkyl acrylates and alkyl methacrylates; A-B block copolymers of alkyl methacrylates and acrylonitrile; A-B-A block copolymers from lactide and ethylene oxide; A-B-A block copolymers of caprolactone and ethylene oxide; A-B-C block copolymers of alkylene or alkadiene compounds, Styrene and alkyl methacrylates; A-B-C block copolymers from acrylic acid, Styrene and alkyl methacrylates; star-shaped block copolymers; hyperbranched Polymers, dendrimers, intrinsically electrically conductive 3,4-polyethylenedioxythiophenes and intrinsically electrically conductive Polyanilines. Product delivery system according to one of Claims 15 to 22, characterized in that it contains at least one pigment selected from titanium dioxide (CI 77891), black iron oxide (CI 77499), yellow iron oxide (CI 77492), red and brown iron oxide (CI 77491), Manganese violet (CI 77742), ultramarines (CI 77007), chromium oxide hydrate (CI77289), iron blue (CI77510), bismuth oxychloride (CI77163), carmine (Cochineal), Pearlescent and color pigments based on micas which are coated with a metal oxide or a metal oxychloride such as titanium dioxide or bismuth oxychloride and optionally further colorants such as iron oxides, iron blue, ultramarines or carmines and wherein the color is determined by varying the layer thickness. Product delivery system according to one of claims 15 to 23, characterized in that at least one particulate matter is included, selected of silica, silicates, aluminates, clays, mica, insoluble Metal salts, metal oxides, minerals and insoluble polymer particles. Product delivery system according to claim 1, characterized in that that the composition in the form of an O / W emulsion, a W / O emulsion or a Microemulsion is present and has a content of (a) from 1 to 20% by weight of at least one oil or fatty alcohol, (b) from 0.1 to 30% by weight of at least one Emulsifier, selected from cationic, anionic, zwitterionic and nonionic Surfactants and (c) from 0 to 20% by weight of at least one other hair conditioning agent selected from silicone compounds, Plant extracts, protein hydrolysates, amino acids, panthenol, panthenyl ethyl ether, Sorbitol, betaine, creatine.