DE19922292A1 - Cosmetic composition for hair comprise water soluble and/or water dispersible comb polymers having polyester side chains containing sulfone groups and physiologically compatible nonionic polymers - Google Patents

Abstract

Mixtures (I), preferably cosmetic compositions for hair, comprise (A) water soluble and/or water dispersible comb polymers, consisting of a main chain having polyester side chains containing sulfone groups and (B) physiologically compatible nonionic polymers.

Description

The present invention relates to combinations and preparations containing such combinations. In particular, the present invention relates to hair cosmetics and preparations for strengthening, shaping, Strengthening and structural improvement of the hair.

An appealing-looking hairstyle is now generally considered an indispensable part a well-groomed exterior. It is due to current fashion flow Again and again, hairstyles are chic, which can only be used with many hair types build up certain solidifying active substances or for a longer period of time keep up.

For these reasons, some hair care cosmetics are used for some time, which are intended to be rinsed out again after exposure from the hair the, partly those, which should remain on the hair. The latter can formu that they not only serve the care of individual hair, but also improve the appearance of the hairstyle overall, for example, by the fact that they Give the hair more fullness, fix the hairstyle over a longer period of time or improve his manageability.

The attribute of fullness is attributed to a hairstyle, for example, if that Hair does not lie flat on the scalp after treatment and is easy to style.

The property of volume is attributed to a hairstyle, for example, when the hair after treatment has fullness and bounce.

The property of the body is attributed to a hairstyle, for example, if that Hair volume remains large even under external, disturbing influences.  

Firming agents, which are usually polymeric compounds can be incorporated into conventional hair cleansing or conditioning who the. In many cases, however, it is advantageous to use them in the form of special remedies such as hair follicles ger or hair sprays.

There have recently been a number of developments on the Haarkosmetikge There is a need for novel fortifying agents or formulas have awakened. Many of these developments are not based on it technical disadvantages or inadequacies of the known means, son for example B. on environmental protection issues, legal requirements or other "non-technical" causes.

In particular, a shift from funds based on volatile organi shear compounds (so-called "volatile organic compounds" or in short: VOC's), z. For example, alcohols, sought to aqueous-based agents.

However, the state of the art leaves it open to active ingredients (polymers) and preparations lack, which correspond to the aforementioned requirements. The haircut fi xierende preparations of the prior art include, for example in the Usually ingredients (synthetic or natural polymers) that are at risk partial or complete replacement of volatile organic compounds Water to experience a significant impairment of product properties, what often has to be compensated by clever formulation. In addition, the stand out fixing preparations of the prior art frequently difficult or complicated to formulate formulation ingredients with insufficient long-term stability this applies particularly to silicone derivatives, which improve the Flexibility and tactility of the polymer film surface can be used.

It was therefore the task to develop appropriate means, with regard to application properties, such as the spray behavior and the Drying time of hair sprays meeting consumer expectations and at the same time a reduced amount of volatile organic compounds without the elementary properties of the polymer film on the hair, such as Clarity, transparency, surface tactility, gloss, elasticity, and washout negligibility and the processability of Formierungsbe components is simple and unproblematic.  

It has now been found, and therein lies the solution to the problems that combinations of

• a) water-soluble and / or water-dispersible comb polymers consisting from a polymer backbone and with this polymer backbone via esters group-linked sulfone polyester-containing polyester side arms

and

• a) one or more substances selected from the group of physiological compatible nonionic polymers

or hair cosmetic preparations containing an effective amount of Kom combinations of

• a) water-soluble and / or water-dispersible comb polymers consisting from a polymer backbone and with this polymer backbone via esters group-linked sulfone polyester-containing polyester side arms

and

• a) one or more substances selected from the group of physiological compatible nonionic polymers

eliminate or at least mitigate the disadvantages of the prior art.

The combinations of the invention are characterized by both good water and Alcohol compatibility as well as favorable film properties and high network able to. Moreover, they are easy to formulate.

The basic structure of the comb polymers used according to the invention essentially follows the following scheme:

Here are the interconnected groups with the name XXX the main body of a polymer backbone, on which ester functions Molecular groupings are associated, which bear the name YYY. The mole Combinations of YYY represent both the complete sulfonated poly ester side arms of the comb polymers used in the invention, but can represent other molecular groups.  

The polymeric main chain of the comb polymers used according to the invention preferably consists of:

• a) polymeric aliphatic, cycloaliphatic or aromatic Polycarbonsäu ren or derivatives thereof such as polyacrylic acid, polymethacrylic acid and their esters (esters of the two acids with aliphatic, cycloaliphatic or aromatic alcohols with C ₁ to C ₂₂ ), maleic acid, maleic anhydride, fumaric acid and polynorboric acid. The average molecular weights of the polycarboxylic acid used can be between 200 and 2,000,000 g / mol, the range of 2,000-100,000 g / mol preferably being used.

The average molecular weights of the polycarboxylic acid used can be between 200 and 2,000,000 g / mol, with the range of 2,000-100,000 g / mol before zugt use finds.

The attachment of the polyester side chains via an ester group, by the Reaction of a functional group of the main chain (-COOH in the case of polycarbon acids or -OH in the case of the polyalcohols) with a corresponding group of the Polyester (OH in the case of the polycarboxylic acids and COOH in the case of the polyalcohols). Of course, reactive derivatives of the above-mentioned components be brought to the rection (for example, anhydrides, esters, halogen compounds and more).

The comb polymers used according to the invention may advantageously be distinguished by the following generic structural formulas:

etc.

Here, p and o can be chosen so that the previously designated mean moles Kulargewichte the used main chain components come about.

The polyester side chains according to formula I-III advantageously consist of:
G: an aromatic, aliphatic or cycloaliphatic Organyleinheiten containing at least two terminal oxygen atoms having a carbon number of C ₂ to C ₂₂ or derivatives of a polyglycol of the form HO- [R ³ -O] _k - [R ⁴ -O] _m -H, according to an organyl unit

The radicals R ³ and R ⁴ represent alkylene radicals having a carbon number of C ₂ -C ₂₂ , where both radicals need not necessarily be different.

For the coefficients k and m the following applies: k + m ≧ 1, where k and m can furthermore be chosen such that the previously described average molecular weights of the main chain constituents used are obtained.
D: an at least two terminal acyl-containing aromatic, aliphatic or cycloaliphatic organyleinheit having a carbon number of C ₂ to C ₂₂ , wherein combinations of several different acid components may be included in the claimed target molecule, beispielswei se an organyl moiety of the scheme

where R ^{s can represent} aromatic and linear or cyclic, saturated or unsaturated aliphatic bifunctional radicals having carbon numbers of C ₂ to C ₂₂ .
T: a compound from the group of at least two terminal acyl-containing sulfonated aromatic, aliphatic or cycloaliphatic organyl compounds.
R ¹ : may mean lithium, sodium, potassium, magnesium, calcium, ammonium, monoalkylammonium, dialkylammonium, trialkylammonium or tetraalkylammonium, wherein the alkyl positions of the amines are independently occupied by C ₁ to C ₂₂ alkyl radicals and 0 to 3 hydroxyl groups.
R ² : a molecule residue selected from the groups of

• aromatic, aliphatic or cycloaliphatic amino functions: (-NH-R ⁵ , -NR ⁵ ₂ , where R ^{5 may be} an alkyl or aryl radical with C ₁ to C ₂₂ )
• aromatic, aliphatic or cycloaliphatic monocarboxylic acid groups: (-COOR ⁶ , where R ^{6 represents} an alkyl or aryl radical with C ₁ to C ₂₀₀ )
• - via ether functions bridged aromatic, aliphatic or cycloaliphatic rule organyl radicals: (-OR ⁵ )
• - Via ether functions bridging polyalkoxy compounds of the formula
  -O- [R ⁷ -O] _q - [R ⁸ -O] _r -Y
  The radicals R ⁷ and R ⁸ are advantageously alkylene radicals having a carbon number of C ₂ -C ₂₂ , where both radicals do not necessarily have to be different. The radical Y can be both hydrogen and aliphatic with C ₁ -C ₂₂ . For the coefficients q and r: q + r ≧ 1,
• - Ether-bridging mono- or poly-ethoxylated sulfonated organyl radicals or preferably their alkali metal or alkaline earth metal salts, such as advantageously characterized by the generic structural formula
  - (O-CH ₂ -CH ₂ ) _s -SO ₃ R ¹
  with s ≧ 1 and wherein s can further be chosen so that the vorab denote th average molecular weights of the main chain components used zuwe ge come.
  Of course, the functionality of the components used according to the invention is not limited to the use of OH groups, but also includes COOH end groupings or mixtures of both, wherein it also applies here that at least two COOH groups must be present in the molecule freely. Reactive derivatives such as anhydrides, esters, epoxides or halides are of course also usable.

The average molecular weights of the comb polymers used according to the invention can advantageously be between 200 and 2,000,000 g / mol, particularly advantageously between 200 and 100,000 g / mol, the range of 1,000-30,000 g / mol be is preferably used, very particularly advantageous from 5,000 to 15,000 g / mol.

The comb polymers used according to the invention are advantageously prepared by esterification or transesterification of the underlying functional Alcohol components and diols with the carboxylic acids or their suitable Derivatives (for example, alkyl esters, halides and the like) in the presence an esterification catalyst such as alkali metal hydroxides, their carbonates and Acetates, alkaline-earth metal oxides, hydroxides, carbonates and acetates, and alkali metal and alkaline earth metal salts of fatty acids having 6 to 22 carbon atoms. Farther come titanium compounds, such as titanates, metallic tin and organic Tin compounds, such as mono- and dialkyltin derivatives as esterification catalysts in Consideration. Preferably, the esterification / transesterification is carried out using Pewter or Titantetraisopropylat performed as a catalyst.

The esterification / transesterification is preferred at temperatures of 120 ° C to 280 ° C. carried out, wherein the resulting lower boiling condensate (alcohols or Water) is removed by distillation from the condensation product, preferably under ver reduced pressure up to <0.1 mbar.  

As starting materials for the polyester skeleton comb polymers according to the invention poly mers aliphatic, cycloaliphatic or aromatic polycarboxylic acids or their derivatives such as polyacrylic acid, polymethacrylic acid and their esters (esters of the two acids with aliphatic, cycloaliphatic or aromatic alcohols with C ₁ to C ₂₂ ), maleic acid, Maleic anhydride, fumaric acid and polynorbornensäure be used. The average molecular weights of the individual polycarboxylic acids can be between 200 and 2,000,000 g / mol, the range of 2,000-100,000 g / mol preferably being used.

Also random or block copolymers of the above compound class with other vinylic monomers such as styrene, acrylamide, α- Methylstyrene, styrene, N-vinylpyrrolidone, N-vinylcaprolactone, acrylamidopropylsulfone acid and its alkali, alkaline earth and ammonium salts, MAPTAC (Methacrylamido propyltrimethylammonium chloride), DADMAC, vinylsulfonic acid, vinylphosphonic acid, Crotonic acid, vinylacetamide, vinylmethylacetamide, vinylforamide, acrylic acid or meth acrylic acid derivatives (for example, free acid or ester), or acrylamide derivatives or vinyl acetate may serve to form the polymeric backbone.

As a basis for at least two terminal oxygen atoms containing aromatic, aliphatic or cycloaliphatic Organyleinheiten having a carbon number of C ₂ to C ₂₂ or derivatives of a polyglycol of the form HO- [R ³ -O) _k - [R ⁴ -O) _m -H bifunctional alcohol components are used.

For this are in particular at least difunctional aromatic, aliphatic or cycloaliphatic alcohols having a carbon number of C ₂ to C ₂₂ or a poly glycol of the form HO- [R ³ -O] _k - [R ⁴ -O] _m -H. The radicals R ³ and R ⁴ represent alkyl radicals having a carbon number of C ₂ to C ₂₂ , where both radicals may be identical or different. For the coefficients k and m the following applies: k + m ≧ 1, where k and m can furthermore be chosen such that the previously described mean molecular weights of the main chain constituents used are obtained.

It may be of particular advantage, instead of difunctional alcohol components tri-, te tra- or generally polyfunctional alcohol components use, for example favorably selected from the following group:

glycerin

diglycerol

triglycerol

pentaerythritol

sorbitol

xylitol

ascorbic acid

As a basis for at least two terminal acyl-containing aromatic, ali phatic or cycloaliphatic Organyleinheiten having a carbon number of C ₂ to C ₂₂ , for example, organyl moieties of the scheme

For example, aromatic and linear or cyclic, saturated or unge saturated aliphatic carboxylic acids having a carbon number of C ₂ to C ₂₂ or the sen anhydrides are used, for example phthalic acid, isophthalic acid, Naph thalindicarbonsäure, cyclohexanedicarboxylic acid, adipic acid, succinic acid, glutaric acid, pimelic acid, suberic acid , Azelaic acid, sebacic acid, brassylic acid. Combinations of several different acid components are possible as a monomer unit in the claimed target molecule.

Suitable sulfone-containing monomers are sulfonated aromatic, aliphatic or cycloaliphatic dialcohols, diacids or their esters, such as sulfosuccinic acid, 5-sulfoisophthalic acid or its alkali metal or alkaline earth metal salts or mono-, di-, tri- or tetraalkylammonium salts with C ₁ - to C ₂₂ alkyl radicals. Among the alkali salts, lithium and sodium salts are particularly preferred.

Furthermore, aromatic, aliphatic or cycloaliphatic amines having C ₁ - to C ₂₂ -alkyl or aryl radicals and / or aromatic, aliphatic or cycloaliphatic monocarboxylic acids having C ₁ - to C ₂₀₀ -alkyl or aryl radicals and / or Polyalkoxyverbin applications of the form - O- [R ⁷ -O] _q - [R ⁸ -O] _r -X, wherein the radicals R ⁷ and R ^{8 represent} alkyl radicals which may be identical or different, a carbon number of C ₂ to C ₂₂ and the radical X be both hydrogen and aliphatic nature with C ₁ -C ₂₂ and the coefficients q and r: q + r ≧ 1 are used.

Also suitable are sulfonated mono- or polyethylene glycols or preferably their alkali metal or alkaline earth metal salts: (H- (O-CH ₂ -CH ₂ ) _s -SO ₃ R ¹ with s ≧ 1, wherein s can also be chosen so that the above designated average molecular weights of a regulated main chain components come about.

For the preparation of comb polymers used in the invention, the Forming the side chain used alcohols and acids or esters advantageous in the molar ratios of 1: 1 to about 10: 1 (1 or 10 parts of di- or polyol) used and the forming alcohol and water and the excess component removed by distillation after condensation. In the target molecule are alcohol and Acid components preferably in the approximate stoichiometric ratio of 1: 1 before.  

The proportion of sulfonic acid ester-containing acid components is 1 to 99 mol .-%, preferably from 10 to 40, particularly preferably from 15 to 25, mol%, based on the total amount of carboxylic acids.

Very favorable performance properties have the sulfone group-containing Comb polymers of the general formula I, when 1,2-propanediol as diol components and / or diethylene glycol and / or cyclohexanedimethanol, as carboxylic acids iso phthalic also with 1,3-cyclohexanedicarboxylic acid or with 2,6-Naphthalindicar Bonic acid or with adipic acid and as sulfo-containing radicals 5-sulfoiso phthalic acid sodium salt, the sodium salt of isethionic acid are used.

The following is a section of a Kammpoly used in the invention Molecule listed, wherein a polyacrylic acid chain, the backbone of Kammpoly Mermoleküls forms. The acid functions are esterified with polyols, which in turn esterified with an acid function of isophthalic acid molecules. Other polyols, of which are derived structural elements of this polymer molecule are pentaerythri Tol, 1,2-propanediol. As sulfonate group-containing agent of which structural elements derived from the polymer molecule, for example, serves the 5-Sulfoisophthalsäuredialkyl ester sodium salt.

For reasons of reaction, which are known in the art, prevails in the target polymer no absolute monotony of the substitution, but is to start from a certain statistical distribution width of the substitution. Furthermore, certain reactive molecular moieties will also be observed to crosslink two or more polymer chains to a more or less complex network, as the following molecular scheme also attempts to do.

The sulfone-containing comb polymers to be used according to the invention are colorless to yellowish, odorless solids. They are well soluble in water and alcohols Lich. They can be beneficial in cosmetic preparations for strengthening the hair be incorporated.  

The preparation of inventive comb polymers is advantageously carried out by one or a plurality of polyfunctional alcohols having a sulfonic acid group-containing, at least two substances containing carboxyl groups, for example 5-sulfoisophthalic acid dimethyl ester Na salt, optionally a further at least two Carboxylgrup pen containing substance and a polymer with one or more polycarbon acids, for example polyacrylic acid or polymethacrylic acid, heated and subjected to the usual treatment steps.

In the cosmetic preparations according to the invention, together with the Comb polymers also one or more physiologically acceptable nonionic poly mers are used as film formers to obtain special product profiles or product characteristics such as B. the max. Consolidation level, curl retention, reduction the formation of residues or the characteristic of strengthening under utilization the individual positive characteristics of the different polymer types and the To influence comb polymers as desired.

In hair sprays, the use of synergistic effects can specifically target the Disadvantages of high water contents are reduced or reduced to a minimum.

The film-forming nonionic polymers used according to the invention can be used before Partly from the group of the usual in the field of cosmetics, in particular the Hair cosmetics used raw materials are chosen, but also polymers for tech nische applications, such as coating and binder.

Suitable nonionic polymers are, for example

• Homopolymers of N-vinylpyrrolidone, which are available as LUVISKOL® K grades from the company BASF or PVP-K® grades from the company ISP with various average molar masses as powder or in aqueous or aqueous / alcoholic solutions.
  Preference is given here to the type Luviskol K30.
• - Homopolymers of N-vinylcaprolactam, z. B. from the company BASF among the Trade name LUVISKOL® Plus.
• Homopolymers of N-vinylformamide.
• Copolymers of N-vinylpyrrolidone and vinyl acetate and / or vinyl propionate, which are available as LUVISKOL®VA grades from the company BASF or PVP / VA® grades from the company ISP in various concentration ratios as powders or in aqueous or aqueous / alcoholic solutions Tobe offered.
  Preference is given here to the types LUVISKOL® VA 37E and VA 64W.
• Terpolymers of N-vinylpyrrolidone, vinyl acetate and vinyl propionate, e.g. B. of the Company BASF under the trade name LUVISKOL® VAP 343.

Particular preference is given here to the nonionic polymers LUVISKOL® Plus and LUVISKOL® VA 64W.

The cosmetic preparations according to the invention for strengthening the hair enthal The silicone-modified comb polymers preferably in concentrations between 0.5 and 20 weight percent and the nonionic polymers are preferably in concentrate between 0.5 and 20% by weight, based in each case on the overall formulation tion.

Preference is given here to a total polymer content of max. 20% by weight, bezo gene to the overall formulation, which consists of the proportions of the inventive Comb polymers and nonionic polymers composed.

The cosmetic and dermatological preparations according to the invention can contain cosmetic excipients, such as those commonly used in such preparations be used, for. As preservatives, bactericides, perfumes, substances for Preventing foaming, dyes, pigments that have a coloring effect, Thickeners, surface-active substances, emulsifiers, softening, on moisturizing and / or moisturizing substances, fats, oils, waxes or other substances Liche components of a cosmetic or dermatological formulation such as Alko hole, polyols, polymers, foam stabilizers, electrolytes, organic solvents or silicone derivatives.

In cosmetic preparations for strengthening the hair, such as. Hair sprays, hair paints, mousse, liquid, styling gels, etc., the present invention to be used comb polymers preferably in concentrations of 0.5 to 30 Ge percent by weight.

The compositions according to the invention for strengthening the hair can be described as Hair sprays or Schaumaerosole present and the usual and the state of the Technique corresponding additions contain, provided appropriate compatibility  is present. These are, for example, further solvents such as lower polyalcohols and their toxicologically tolerated ethers and esters, plasticizers, light and low volatility silicones, branched or unbranched hydrocarbons of low volatility and low volatility Hydrocarbons, emulsifiers, antioxidants, waxes, stabilizers, pH-value Regulators, dyes, bodying agents, antistatic agents, UV absorbers, perfumes, etc.

If the composition of the invention as hair spray or foam aerosol are used, so a blowing agent is usually added. Usual propellants are lower alkanes, for example propane, butane or isobutane, dimethyl ether, Nitrogen, nitrogen dioxide or carbon dioxide or mixtures of these substances.

When used in mechanical spray or foam devices, for example Spray pumps or manual foam pumps or squeeze systems, can Propellants usually omitted.

The aqueous preparations according to the invention optionally contain advantageous Alcohols, diols or polyols of low C number, and their ethers, preferably etha nol, isopropanol, propylene glycol, glycerol, ethylene glycol, ethylene glycol monoethyl or monobutyl ether, propylene glycol monomethyl, monoethyl or monobutyl ether, Diethylene glycol monomethyl or monoethyl ether and analogous products, further Al low C-number alcohols, e.g. As ethanol, isopropanol, 1,2-propanediol, glycerol and in particular one or more thickening agents, which or which are advantageous can be selected from the group silicon dioxide, aluminum silicates, polysac charide or its derivatives, eg. Hyaluronic acid, xanthan gum, hydroxypropylme cellulose, particularly advantageous from the group of polyacrylates, preferably a Polyacrylate from the group of so-called Carbopols, such as Carbopols of Types 980, 981, 1382, 2984, 5984, each individually or in combination.

In the technical sense are understood by gels: Relatively dimensionally stable, light deformable disperse systems of at least two components, which are usually from a - usually solid - colloid-divided substance from long-chain molecule grouping gene (eg, gelatin, silicic acid, polysaccharides) as a scaffolding agent and a liquid Dispersing agent (eg water) exist. The colloidally divided substance is often called Thickening or gelling referred to. He forms a spatial network in the Di Sparsiermittel, wherein individual colloidal particles via electrostatic Interaction can be more or less firmly linked together. The Di Sporulation agent surrounding the network is characterized by electrostatic Af  fineness of the gelling agent, d. h., a predominantly polar (in particular: hydrophilic) Gelling agent preferably gels a polar dispersant (especially: What whereas a predominantly nonpolar gelling agent is preferably non-polar di gels sputtered.

Strong electrostatic interactions, for example, in Wasserstoffbrüc kenbindungen between gelling agent and dispersing agent, but also between Di Sporer molecules are realized with each other, can strong Vernet tion of the dispersant. Hydrogels can make up almost 100% of what consist of (for example, about 0.2-1.0% of a gelling agent) and thereby have solid consistency. The water content is in ice-like Structural elements before, so that gels therefore their name origin [from Latin "gelatum" = "Frozen" about the alchemical expression "gelatina" (16th century) for nhdt. "Gelati ne "] are quite fair.

Gels according to the invention usually contain lower C number alcohols, e.g. B. Ethanol, isopropanol, 1,2-propanediol, glycerol and water in the presence of a Ver thickening agent, the oily-alcoholic gels preferably silica or a Aluminum silicate, in aqueous-alcoholic or alcoholic gels, preferably one Polyacrylate is.

In cosmetic and dermatological preparations according to the invention For example, it may be, for example, shampoo, preparations for hair-drying or hair-dyeing, preparations for dyeing, or treatment lotion.

If appropriate, preparations according to the invention can advantageously be obtained by a Characterize content of surfactants. Surfactants are amphiphilic substances that are organic, un can dissolve polar substances in water. They provide, due to their specifi molecular structure with at least one hydrophilic and one hydrophobic Mo lekülteil, for a reduction in the surface tension of the water, the Benet tearing the skin, facilitating the removal and dissolution of the soil, a slight decrease Rinse and - as desired - for foam control.

The hydrophilic moieties of a surfactant molecule are mostly polar functional groups, for example -COO ^-, -OSO ₃ ^2-, -SO ₃ ^- , while the hydrophobic parts are usually nonpolar hydrocarbon radicals. Surfactants are generally classified according to the nature and charge of the hydrophilic part of the molecule. Here four groups can be distinguished:

• - anionic surfactants,
• - cationic surfactants,
• Amphoteric surfactants and
• - nonionic surfactants.

Anionic surfactants generally have carboxylate, sulfate or sulfonate groups as functional groups. In aqueous solution, they form negatively charged organic ions in the acidic or neutral state. Cationic surfactants are almost exclusively characterized by the presence of a quaternary ammonium group. In aqueous solution they form positive gela dene organic ions in an acidic or neutral medium. Amphoteric surfactants contain both anionic and kat ionic groups and behave accordingly in aqueous solution depending on the pH as anionic or cationic surfactants. They have a positive charge in a strongly acidic environment and a negative charge in an alkaline environment. In the neutral pH range, they are zwitterionic, as the following example illustrates:
RNH ₂ ⁺ CH ₂ CH ₂ COOH X ^- (at pH = 2) X ^- = any anion, e.g. B. Cl ^-
RNH ₂ ⁺ CH ₂ CH ₂ COO ^- (at pH = 7)
RNHCH ₂ CH ₂ CQO ^- B ⁺ (at pH = 12) B ⁺ = any cation, eg. Na ⁺

Typical of non-ionic surfactants are polyether chains. Nonionic surfactants bil no ions in aqueous medium.

A. Anionic surfactants

Advantageously used anionic surfactants are acylamino acids (and their salts), such as

• 1. Acylglutamates, for example sodium acylglutamate, di-TEA-palmitoyl aspartate and sodium caprylic / capric glutamate,
• 2. Acyl peptides, for example palmitoyl-hydrolyzed milk protein, sodium coco yl-hydrolyzed soy protein and sodium / potassium cocoyl-hydrolyzed collagen gene,
• 3. sarcosinates, for example myristoyl sarcosine, TEA lauroyl sarcosinate, sodium lauroyl sarcosinate and sodium cocoyl sarcosinate,
• 4. taurates, for example sodium lauroyl taurate and sodium methyl cocoyl taurate,  
• 5. Acyl lactylates, lauroyl lactylate, caproyl lactylate
• 6. alaninates.

Carboxylic acids and derivatives, such as

• 1. Carboxylic acids, for example lauric acid, aluminum stearate, magnesium alka nolate and zinc undecylenate,
• 2. Ester carboxylic acids, for example, calcium stearoyl lactylate, laureth-6 citrate and Sodium PEG-4 lauramide carboxylate,
• 3. Ether carboxylic acids, for example sodium laureth-13 carboxylate and sodium PEG-6 cocamide carboxylate.

Phosphoric acid esters and salts such as DEA-oleth-10-phosphate and Dilaureth-4 phosphate,
Sulfonic acids and salts, such as

• 1. Acyl-isethionates, z. B. sodium / ammonium cocoyl isethionate,
• 2. alkylarylsulfonates,
• 3. alkyl sulfonates, for example sodium coconut monoglyceride sulfate, sodium C _12-14 olefin sulfonate, sodium lauryl sulfoacetate and magnesium PEG-3 cocamide sulfate,
• 4. Sulfosuccinates, for example dioctyl sodium sulfosuccinate, disodium laurethsul fosuccinate, disodium lauryl sulfosuccinate and disodium undecylenamido MEA-Sul fosuccinat

such as
Sulfuric acid esters, such as

• 1. alkyl ether sulfate, for example sodium, ammonium, magnesium, MIPA, TIPA laureth sulfate, sodium myreth sulfate and sodium C _12-13 pareth sulfate,
• 2. Alkyl sulfates, for example sodium, ammonium and TEA lauryl sulfate.

B. Cationic surfactants

Optionally, cationic surfactants to be used are advantageous

• 1. alkylamines,
• 2. Alkylimidazoles,
• 3. Ethoxylated amines and
• 4. Quaternary surfactants
• 5. esterquats.

Quaternary surfactants contain at least one N-atom, which with 4 alkyl or Arylgrup pen is covalently connected. This leads to a positive, regardless of the pH value  Charge. Alkylbetaine, alkylamidopropylbetaine and alkyl-amidopropylhy are advantageous droxysulfain. The cationic surfactants used according to the invention can furthermore are preferably selected from the group of quaternary ammonium compounds, in particular Benzyltrialkyiammoniumchloride or bromides, such as Ben cyldimethylstearylammonium chloride, further alkyltrialkylammonium salts, for example, cetyltrimethylammonium chloride or bromide, alkyldimethylhydro xyethylammonium chlorides or bromides, dialkyldimethylammonium chlorides or bros mide, Alkylamidethyltrimethylammoniumethersulfate, alkylpyridinium salts, for example example, lauryl or cetylpyrimidinium chloride, imidazoline derivatives and compounds with cationic character such as amine oxides, for example Alkyldimethylaminoxide or Alkylaminoethyldimethylamine. Particularly advantageous are cetyltrimethyl to use ammonium salts.

C. Amphoteric surfactants

Advantageously used amphoteric surfactants

• 1. acyl / dialkylethylenediamine, for example, sodium acylamphoacetate, disodium acylamphodipropionate, disodium alkyl amphodiacetate, sodium acylamphohydroxy propylsulfonate, disodium acylamphodiacetate and sodium acylamphopropionate,
• 2. N-alkyl amino acids, for example Aminopropylalkylglutamid, Alkylaminopropi onsäure, Natriumalkylimidodipropionat and Lauroamphocarboxyglycinat.

D. Nonionic surfactants

Advantageously used nonionic surfactants are

• 1. Alcohols,
• 2. alkanolamides, such as cocamide MEA / DEA / MIPA,
• 3. amine oxides, such as cocoamidopropylamine oxide,
• 4. Esters obtained by esterification of carboxylic acids with ethylene oxide, glycerol, sorbi tan or other alcohols,
• 5. Ethers, for example ethoxylated / propoxylated alcohols, ethoxylated / propoxy esters, ethoxylated / propoxylated glycerol esters, ethoxylated / propoxylated Cholesterols, ethoxylated / propoxylated triglyceride esters, ethoxylated propoxy lanolin, ethoxylated / propoxylated polysiloxanes, propoxylated POE ethers and alkyl polyglycosides such as lauryl glucoside, decyl glycoside and cocoglycoside,
• 6. sucrose esters, ethers,
• 7. polyglycerol esters, diglycerol esters, monoglycerol esters,
• 8. Methyl glucose esters, esters of hydroxy acids.

It is also advantageous to use a combination of anionic and / or amphoteric surfactants with one or more non-ionic surfactants.

As a rule, in the context of the present invention, the use of anionic, amphoteric and / or nonionic surfactants over the use of cationic surfactants are preferred.

The cosmetic and dermatological contain active ingredients and excipients, as they are Usually for this type of preparations for hair care and hair treatment be used. As auxiliaries are preservatives, surface-active Substances, foaming inhibitors, thickeners, emulsifiers gators, fats, oils, waxes, organic solvents, bactericides, perfumes, color substances or pigments whose function is the hair or the cosmetic or dermatological preparation to dye itself, Elektroyte, substances against the Greasing the hair.

Electrolytes in the sense of the present invention are water-soluble alkali, Ammonium, alkaline earth (including magnesium) and zinc salts anorga nischer anions and any mixtures of such salts, where must be ensured that these salts by pharmaceutical or cosmeti safety.

The anions used according to the invention are preferably selected from Group of chlorides, sulfates and hydrogen sulfates, phosphates, Hydrogen phosphates and the linear and cyclic oligophosphates and the Carbonates and bicarbonates.

Cosmetic preparations which are a shampooing agent are included preferably at least one anionic, nonionic or amphoteric surfaceak tive substance, or mixtures of such substances in an aqueous medium and Aids, as they are usually used for it. The surface-active sub punch or the mixtures of these substances can be in a concentration between 1 wt .-% and 50 wt .-% in the shampoo.

A cosmetic preparation in the form of a lotion that is not rinsed, esp especially a lotion for inserting the hair, a lotion when blow-drying the hair is used, a hairdressing and treatment lotion, generally provides an aqueous  rige, alcoholic or aqueous-alcoholic solution and contains the comb polymers used according to the invention.

The compositions according to the invention optionally contain those in the Cosmetic customary additives, for example perfume, thickener, dyes, Des odorants, antimicrobials, lipid-replenishing agents, complexing and seque agents, pearlescent agents, plant extracts, vitamins, active substances and like.

The following examples are intended to illustrate the present invention without it limit. All quantities, percentages and percentages are, if not otherwise indicated, on the weight and the total amount or on the total Weight of the preparations based.  

(A) Production Examples Production Example 1

reactant Mass (g) isophthalic 265.81 5-sulfoisophthalic acid, Na salt 118.49 Isethionic acid, Na salt 10.96 polyacrylic acid * 3.00 sodium 0.60 tetraisopropoxide 0.60 1,2-propanediol 195.40 diethylene glycol 166.95 * 2 mol-OH groups, M = 25,000 g / mol equim. COOH

of preparation

In a 2 l four-necked flask equipped with KPG stirrer, internal thermometer, gas inlet tube and distillation still 1,2-propanediol, diethylene glycol, the sodium salt of Ise thionsäure and titanium tetraisopropylate are presented, stirred briefly and then Natri umcarbonat and 5-Sulfophthalsäuredimethylester-Na salt, isophthalic acid and Poly acrylic acid registered. Thereafter, it is evacuated twice and rendered inert with N ₂ . While stirring is then heated to 170 ° C within 30 min. At about 173 ° C, the transesterification or distillation begins. In the course of 2 hours, the internal temperature is increased to 210 ° C, then to 240-250 ° C and condensed for a further 30 min. Subsequently, the pressure is reduced to <1 mbar and condensed for 1 hour at 250 ° C in 30 minutes. Then it is aerated with N ₂ and the melt discharged.

Production Example 2

reactant Mole (mmol) 1,3-cyclohexane 132.80 isophthalic 132.91 5-sulfoisophthalic acid, Na salt 118.49 Isethionic acid, Na salt 10.94 polyacrylic acid * 3.00 sodium 0.60 tetraisopropoxide 0.60 1,2-propanediol 195.40 diethylene glycol 166.95 * 2 mol-OH groups, M = 25,000 g / mol equim. COOH

of preparation

In a 2 l four-necked flask equipped with KPG stirrer, internal thermometer, gas inlet tube and distillation still 1,2-propanediol, diethylene glycol, the sodium salt of Ise thionsäure and titanium tetraisopropylate are presented, stirred briefly and then Natri umcarbonat and 5-Sulfophthalsäuredimethylester-Na salt, isophthalic acid, Cyclohe xandicarboxylic acid and polyacrylic acid registered. Thereafter, it is evacuated twice and rendered inert with N ₂ . While stirring is then heated to 170 ° C within 30 min. At about 173 ° C, the transesterification or distillation begins. In the course of 2 hours, the internal temperature is increased to 210 ° C, then to 240-250 ° C and condensed for a further 30 min. Subsequently, the pressure is reduced to <1 mbar and condensed for 1 hour at 250 ° C in 30 minutes. Then it is aerated with N ₂ and the melt discharged.

Production Example 3

reactant Mole (mmol) 2,6-naphthalene 172.95 isophthalic 132.91 5-sulfoisophthalic acid, Na salt 118.49 Isethionic acid, Na salt 10.94 polyacrylic acid * 3.00 sodium 0.60 tetraisopropoxide 0.60 1,2-propanediol 195.40 diethylene glycol 166.95 * 2 mol-OH groups, M = 25,000 g / mol equim. COOH

of preparation

In a 2 l four-necked flask equipped with KPG stirrer, internal thermometer, gas inlet tube and distillation still 1,2-propanediol, diethylene glycol, the sodium salt of Ise thionsäure and titanium tetraisopropylate are presented, stirred briefly and then Natri umcarbonat and 5-Sulfophthalsäuredimethylester-Na salt, isophthalic acid, 2,6-Na phthalindicarbonsäure and polyacrylic acid registered. Thereafter, it is evacuated twice and rendered inert with N ₂ . While stirring is then heated to 170 ° C within 30 min. At about 173 ° C, the transesterification or distillation begins. In the course of 2 hours, the internal temperature is increased to 210 ° C, then to 240-250 ° C and condensed for a further 30 min. Subsequently, the pressure is reduced to <1 mbar and condensed for 1 hour at 250 ° C in 30 minutes. Then it is aerated with N ₂ and the melt discharged.

Production Example 4

reactant Mole (mmol) adipic acid 161.80 isophthalic 132.91 5-sulfoisophthalic acid, Na salt 118.49 Isethionic acid, Na salt 10.94 polyacrylic acid * 3.00 sodium 0.60 tetraisopropoxide 0.60 1,2-propanediol 195.40 diethylene glycol 166.95 * 2 mol-OH groups, M = 25,000 g / mol equim. COOH

of preparation

In a 2 l four-necked flask equipped with KPG stirrer, internal thermometer, gas inlet tube and distillation bridge 1,2-propanediol, diethylene glycol, the sodium salt of isethionic acid and titanium tetraisopropylate are initially stirred and then Na triumcarbonat and 5-Sulfophthalsäuredimethylester-Na salt, isophthalic acid, adipic acid acid and polyacrylic acid registered. Thereafter, it is evacuated twice and rendered inert with N ₂ . While stirring is then heated to 170 ° C within 30 min. At about 173 ° C, the transesterification or distillation begins. In the course of 2 hours, the internal temperature is increased to 210 ° C, then to 240-250 ° C and condensed for a further 30 min. Subsequently, the pressure is reduced to <1 mbar and condensed for 1 hour at 250 ° C in 30 minutes. Then it is aerated with N ₂ and the melt discharged.

Production Example 5

reactant Mole (mmol) 1,3-cyclohexane 99.20 isophthalic 66.46 5-sulfoisophthalic acid, Na salt 118.49 Isethionic acid, Na salt 10.94 polyacrylic acid * 3.00 sodium 0.60 tetraisopropoxide 0.60 1,2-propanediol 195.40 diethylene glycol 166.95 * 2 mol-OH groups, M = 25,000 g / mol equim. COOH

of preparation

In a 2 l four-necked flask equipped with KPG stirrer, internal thermometer, gas inlet tube and distillation still 1,2-propanediol, diethylene glycol, the sodium salt of Ise thionsäure and titanium tetraisopropylate are presented, stirred briefly and then Natri umcarbonat and 5-Sulfophthalsäuredimethylester-Na salt, isophthalic acid, 1,3-Cyclo hexanedicarboxylic acid and polyacrylic acid registered. Thereafter, it is evacuated twice and rendered inert with N ₂ . While stirring is then heated to 170 ° C within 30 min. At about 173 ° C, the transesterification or distillation begins. In the course of 2 hours, the internal temperature is increased to 210 ° C, then to 240-250 ° C and condensed for a further 30 min. Subsequently, the pressure is reduced to <1 mbar and condensed for 1 hour at 250 ° C in 30 minutes. Then it is aerated with N ₂ and the melt discharged.

Production Example 6

reactant Mole (mmol) isophthalic 265.80 5-sulfoisophthalic acid, Na salt 118.49 Isethionic acid, Na salt 10.94 polyacrylic acid * 3.00 sodium 0.60 tetraisopropoxide 0.60 1,4-cyclohexanedimethanol 144.21 1,2-propanediol 119.31 diethylene glycol 166.95 * 2 mol-OH groups, M = 25,000 g / mol equim. COOH

of preparation

In a 2 l four-necked flask equipped with KPG stirrer, internal thermometer, gas inlet tube and distillation still 1,4-cyclohexanedimethanol, 1,2-propanediol, diethylene glycol, the sodium salt of isethionic acid and titanium tetraisopropylate are presented, stirred briefly and then sodium carbonate and 5-Sulfophthalsäuredimethylester- Na salt, isophthalic acid, and polyacrylic acid registered. Thereafter, it is evacuated twice and rendered inert with N ₂ . While stirring is then heated to 170 ° C within 30 min. At about 173 ° C, the transesterification or distillation begins. In the course of 2 hours, the internal temperature is increased to 210 ° C, then to 240-250 ° C and condensed for a further 30 min. Subsequently, the pressure is reduced to <1 mbar and condensed for 1 hour at 250 ° C in 30 minutes. Then it is aerated with N ₂ and the melt discharged.

(B) recipe examples

hairsprays

Examples 1-15

mousse

Examples 16-17

styling gels

Examples 18-21

Claims (6)

1. Combinations

• a) water-soluble and / or water-dispersible comb polymers, consisting of a polymer main chain and with this polymer main chain via ester groups linked sulfongruppenhaltigen polyester side arms and
• b) one or more substances selected from the group of physiologically acceptable nonionic polymers.

2. Hair cosmetic preparations containing an effective amount of com binations from

• a) water-soluble and / or water-dispersible comb polymers, consisting of a polymer main chain and with this polymer main chain via ester groups linked sulfongruppenhaltigen polyester side arms and
• b) one or more substances selected from the group of physiologically acceptable nonionic polymers.

3. Combinations according to claim 1 or preparations according to claim 2, characterized in that the polymeric backbone of the comb polymers is selected from the group of polymeric aliphatic, cycloaliphatic or aromatic polycarboxylic acids or their derivatives such as polyacrylic acid, polymethacrylic acid and their esters (esters the two acids with aliphatic, cycloaliphatic or aromatic alcohols with C ₁ to C ₂₂ ), maleic acid, maleic anhydride, fumaric acid and polynorborneneic acid. 4. Combinations according to claim 1 or preparations according to claim 2, characterized in that the comb polymers are selected from the group of polyesters of the following generic structural formulas
at p and o be chosen so that the average molecular weights of the main chain constituents used are between 200 and 2,000,000 g / mol, the range of 2,000-100,000 g / mol preferably being used,
the polyester side chains according to formula I-III advantageously consist of:
G: is selected from the group of at least two terminal Sauerstoffato me containing aromatic, aliphatic or cycloaliphatic organyl units having a carbon number of C ₂ to C ₂₂ or derivatives of a polyglycol of the form HO- [R ³ -O) _h - [R ⁴ - O) _m -H, corresponding to an organyl unit
where the radicals R ³ and R ^{4 are} alkylene radicals having a carbon number of C ₂ -C ₂₂ , where both radicals do not necessarily have to be different,
where for the coefficients k and m: k + m ≧ 1, wherein k and m can also be selected so ge that the previously designated average molecular weights of the main chain components used come about.
D: an at least two terminal acyl-containing aromatic, aliphatic or cycloaliphatic organyleinheit having a carbon number of C ₂ to C ₂₂ , wherein combinations of several different acid components in the claimed target molecule may be included, example, an organyl moiety of the scheme
where R ^{s can represent} aromatic and linear or cyclic, saturated or unsaturated aliphatic bifunctional radicals having carbon numbers of C ₂ to C ₂₂ .
T: a compound from the group of at least two terminal acyl-containing sulfonated aromatic, aliphatic or cyclo aliphatic organyl compounds.
R ^{1 can be} lithium, sodium, potassium, magnesium, calcium, ammonium, monoalkylammonium, dialkylammonium, trialkylammonium or tetraalkylammonium, in which the alkyl positions of the amines are independently of each other occupied by C ₁ to C ₂₂ -alkyl radicals and 0 to 3 hydroxyl groups,
R ² : a molecule residue selected from the groups of

• aromatic, aliphatic or cycloaliphatic amino functions: (-NH-R ⁵ , -NR ⁵ ₂ , where R ^{5 may be} an alkyl or aryl radical with C ₁ to C ₂₂ ),
• aromatic, aliphatic or cycloaliphatic monocarboxylic acid groups: (-COOR ⁶ , where R ^{6 represents} an alkyl or aryl radical with C ₁ to C ₂₀₀ ),
• aromatic, aliphatic or cycloaliphatic organyl radicals bridged by ether functions: (-OR ⁵ ),
• - Via ether functions bridging polyalkoxy compounds of the form
  -O- [R ⁷ -O] _q - [R ⁸ -O] _r -Y
  The radicals R ⁷ and R ⁸ are advantageously alkyl radicals having a carbon number of C ₂ -C ₂₂ , where both radicals do not necessarily have to be different. The radical Y can be both hydrogen and aliphatic with C ₁ -C ₂₂ . For the coefficients q and r: q + r ≧ 1,
• - Ether-bridging mono- or poly-ethoxylated sulfonated organyl radicals or preferably their alkali metal or alkaline earth metal salts, such as advantageously characterized by the generic structural formula
  - (O-CH ₂ -CH ₂ ) _s -SO ₃ R ¹
  with s ≧ 1, and wherein s can also be chosen so that the pre-designated Neten average molecular weights of the main chain components used to get away.

5. Combinations according to claim 1 or preparations according to claim 2, characterized ge indicates that the average molecular weights of the comb polymers are advantageous between 200 and 2,000,000 g / mol, especially between 200 and 200 100,000 g / mol are preferably the range of 1,000-30,000 g / mol Verwen tion, very particularly advantageous from 5,000-15,000 g / mol. 6. Combinations according to claim 1 or preparations according to claim 2, characterized in that the one or more nonionic polymers are selected from the group of

• Homopolymers of N-vinylpyrrolidone,
• Homopolymers of N-vinylcaprolactam,
• Homopolymers of N-vinylformamide,
• Copolymers of N-vinylpyrrolidone and vinyl acetate and / or vinyl propionate,
• - Terpolymers of N-vinylpyrrolidone, vinyl acetate and vinyl propionate.