DE19907376A1 - Body cleaning composition, useful particularly as tinting or dyeing shampoo, contains quaternary ammonium di-amide and has excellent conditioning effects - Google Patents
Body cleaning composition, useful particularly as tinting or dyeing shampoo, contains quaternary ammonium di-amide and has excellent conditioning effectsInfo
- Publication number
- DE19907376A1 DE19907376A1 DE1999107376 DE19907376A DE19907376A1 DE 19907376 A1 DE19907376 A1 DE 19907376A1 DE 1999107376 DE1999107376 DE 1999107376 DE 19907376 A DE19907376 A DE 19907376A DE 19907376 A1 DE19907376 A1 DE 19907376A1
- Authority
- DE
- Germany
- Prior art keywords
- alkyl
- group
- composition according
- surfactant
- calculated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 45
- 239000002453 shampoo Substances 0.000 title claims description 30
- 238000004140 cleaning Methods 0.000 title abstract 3
- 230000003750 conditioning effect Effects 0.000 title description 8
- 238000004043 dyeing Methods 0.000 title description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 title 1
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 15
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 13
- 239000004094 surface-active agent Substances 0.000 claims abstract description 12
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 9
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 3
- 150000001450 anions Chemical group 0.000 claims abstract description 3
- -1 saccharide radical Chemical class 0.000 claims description 24
- 150000001875 compounds Chemical class 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 4
- 239000002280 amphoteric surfactant Substances 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical compound [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 claims 2
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 claims 1
- 239000000118 hair dye Substances 0.000 claims 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 abstract description 3
- 125000003368 amide group Chemical group 0.000 abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 description 20
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 11
- 235000014113 dietary fatty acids Nutrition 0.000 description 10
- 239000000194 fatty acid Substances 0.000 description 10
- 229930195729 fatty acid Natural products 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 229910052708 sodium Inorganic materials 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 230000003766 combability Effects 0.000 description 7
- 229920006317 cationic polymer Polymers 0.000 description 6
- 150000004665 fatty acids Chemical class 0.000 description 6
- 239000002304 perfume Substances 0.000 description 6
- 239000003755 preservative agent Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 230000002335 preservative effect Effects 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 229920006318 anionic polymer Polymers 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 125000004985 dialkyl amino alkyl group Chemical group 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- 229930182478 glucoside Natural products 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- OOCCDEMITAIZTP-QPJJXVBHSA-N (E)-cinnamyl alcohol Chemical compound OC\C=C\C1=CC=CC=C1 OOCCDEMITAIZTP-QPJJXVBHSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- BEWCNXNIQCLWHP-UHFFFAOYSA-N 2-(tert-butylamino)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCNC(C)(C)C BEWCNXNIQCLWHP-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- DDGPBVIAYDDWDH-UHFFFAOYSA-N 3-[dodecyl(dimethyl)azaniumyl]-2-hydroxypropane-1-sulfonate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC(O)CS([O-])(=O)=O DDGPBVIAYDDWDH-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 244000144730 Amygdalus persica Species 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 208000001840 Dandruff Diseases 0.000 description 2
- JDRSMPFHFNXQRB-CMTNHCDUSA-N Decyl beta-D-threo-hexopyranoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)C(O)[C@H](O)C1O JDRSMPFHFNXQRB-CMTNHCDUSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 235000006040 Prunus persica var persica Nutrition 0.000 description 2
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000003868 ammonium compounds Chemical class 0.000 description 2
- 239000010775 animal oil Substances 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 229940073499 decyl glucoside Drugs 0.000 description 2
- 239000000982 direct dye Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 2
- FYUWIEKAVLOHSE-UHFFFAOYSA-N ethenyl acetate;1-ethenylpyrrolidin-2-one Chemical compound CC(=O)OC=C.C=CN1CCCC1=O FYUWIEKAVLOHSE-UHFFFAOYSA-N 0.000 description 2
- UPBDXRPQPOWRKR-UHFFFAOYSA-N furan-2,5-dione;methoxyethene Chemical compound COC=C.O=C1OC(=O)C=C1 UPBDXRPQPOWRKR-UHFFFAOYSA-N 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 150000004668 long chain fatty acids Chemical class 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- AWGZKFQMWZYCHF-UHFFFAOYSA-N n-octylprop-2-enamide Chemical compound CCCCCCCCNC(=O)C=C AWGZKFQMWZYCHF-UHFFFAOYSA-N 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000003531 protein hydrolysate Substances 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- YZZPMSRIIZWDAJ-AWEZNQCLSA-N (2s)-2-(2-oxotridecylamino)propanoic acid Chemical compound CCCCCCCCCCCC(=O)CN[C@@H](C)C(O)=O YZZPMSRIIZWDAJ-AWEZNQCLSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- 229920003067 (meth)acrylic acid ester copolymer Polymers 0.000 description 1
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
- ZPFAVCIQZKRBGF-UHFFFAOYSA-N 1,3,2-dioxathiolane 2,2-dioxide Chemical compound O=S1(=O)OCCO1 ZPFAVCIQZKRBGF-UHFFFAOYSA-N 0.000 description 1
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- HXVJQEGYAYABRY-UHFFFAOYSA-N 1-ethenyl-4,5-dihydroimidazole Chemical compound C=CN1CCN=C1 HXVJQEGYAYABRY-UHFFFAOYSA-N 0.000 description 1
- JLBXCKSMESLGTJ-UHFFFAOYSA-N 1-ethoxypropan-1-ol Chemical compound CCOC(O)CC JLBXCKSMESLGTJ-UHFFFAOYSA-N 0.000 description 1
- LHENQXAPVKABON-UHFFFAOYSA-N 1-methoxypropan-1-ol Chemical compound CCC(O)OC LHENQXAPVKABON-UHFFFAOYSA-N 0.000 description 1
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 1
- RECMXJOGNNTEBG-UHFFFAOYSA-N 1-phenylmethoxyethanol Chemical compound CC(O)OCC1=CC=CC=C1 RECMXJOGNNTEBG-UHFFFAOYSA-N 0.000 description 1
- LGEZTMRIZWCDLW-UHFFFAOYSA-N 14-methylpentadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCC(C)C LGEZTMRIZWCDLW-UHFFFAOYSA-N 0.000 description 1
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- FLPJVCMIKUWSDR-UHFFFAOYSA-N 2-(4-formylphenoxy)acetamide Chemical compound NC(=O)COC1=CC=C(C=O)C=C1 FLPJVCMIKUWSDR-UHFFFAOYSA-N 0.000 description 1
- WWIAGBQICFHIPP-UHFFFAOYSA-N 2-[3-(dodecanoylamino)propylamino]acetic acid Chemical compound CCCCCCCCCCCC(=O)NCCCNCC(O)=O WWIAGBQICFHIPP-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
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- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 description 1
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- PDQICKRFOKDJCH-UHFFFAOYSA-N 6-amino-2-(dodecanoylamino)hexanoic acid Chemical compound CCCCCCCCCCCC(=O)NC(C(O)=O)CCCCN PDQICKRFOKDJCH-UHFFFAOYSA-N 0.000 description 1
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- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
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- 210000001217 buttock Anatomy 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 229960001777 castor oil Drugs 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
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- 229920002678 cellulose Polymers 0.000 description 1
- 229960002788 cetrimonium chloride Drugs 0.000 description 1
- 229940074979 cetyl palmitate Drugs 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 229940096362 cocoamphoacetate Drugs 0.000 description 1
- 229940071160 cocoate Drugs 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
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- 229920001436 collagen Polymers 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 229920013750 conditioning polymer Polymers 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 229940086555 cyclomethicone Drugs 0.000 description 1
- 229940100539 dibutyl adipate Drugs 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- TVFJAZCVMOXQRK-UHFFFAOYSA-N ethenyl 7,7-dimethyloctanoate Chemical compound CC(C)(C)CCCCCC(=O)OC=C TVFJAZCVMOXQRK-UHFFFAOYSA-N 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 235000008524 evening primrose extract Nutrition 0.000 description 1
- 229940089020 evening primrose oil Drugs 0.000 description 1
- 239000010475 evening primrose oil Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
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- 229920000578 graft copolymer Polymers 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 1
- PXDJXZJSCPSGGI-UHFFFAOYSA-N hexadecanoic acid hexadecyl ester Natural products CCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC PXDJXZJSCPSGGI-UHFFFAOYSA-N 0.000 description 1
- 229940100463 hexyl laurate Drugs 0.000 description 1
- 235000012907 honey Nutrition 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229920000831 ionic polymer Polymers 0.000 description 1
- 229940078545 isocetyl stearate Drugs 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 229940071085 lauroyl glutamate Drugs 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 229940070782 myristoyl sarcosinate Drugs 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- GLDOVTGHNKAZLK-UHFFFAOYSA-N n-octadecyl alcohol Natural products CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 239000010466 nut oil Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- BARWIPMJPCRCTP-UHFFFAOYSA-N oleic acid oleyl ester Natural products CCCCCCCCC=CCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC BARWIPMJPCRCTP-UHFFFAOYSA-N 0.000 description 1
- 229940120511 oleyl erucate Drugs 0.000 description 1
- BARWIPMJPCRCTP-CLFAGFIQSA-N oleyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC BARWIPMJPCRCTP-CLFAGFIQSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 1
- 229960001173 oxybenzone Drugs 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940101267 panthenol Drugs 0.000 description 1
- 235000020957 pantothenol Nutrition 0.000 description 1
- 239000011619 pantothenol Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 229940086539 peg-7 glyceryl cocoate Drugs 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- BTSZTGGZJQFALU-UHFFFAOYSA-N piroctone olamine Chemical compound NCCO.CC(C)(C)CC(C)CC1=CC(C)=CC(=O)N1O BTSZTGGZJQFALU-UHFFFAOYSA-N 0.000 description 1
- 229940081510 piroctone olamine Drugs 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001184 polypeptide Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Chemical group CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 238000005956 quaternization reaction Methods 0.000 description 1
- NXLOLUFNDSBYTP-UHFFFAOYSA-N retene Chemical compound C1=CC=C2C3=CC=C(C(C)C)C=C3C=CC2=C1C NXLOLUFNDSBYTP-UHFFFAOYSA-N 0.000 description 1
- 229940071089 sarcosinate Drugs 0.000 description 1
- 108700004121 sarkosyl Proteins 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 229940006186 sodium polystyrene sulfonate Drugs 0.000 description 1
- LROWVYNUWKVTCU-STWYSWDKSA-M sodium sorbate Chemical compound [Na+].C\C=C\C=C\C([O-])=O LROWVYNUWKVTCU-STWYSWDKSA-M 0.000 description 1
- 235000019250 sodium sorbate Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000019635 sulfation Effects 0.000 description 1
- 238000005670 sulfation reaction Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 125000001174 sulfone group Chemical group 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/006—Antidandruff preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/92—Sulfobetaines ; Sulfitobetaines
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
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- General Health & Medical Sciences (AREA)
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- Epidemiology (AREA)
- Birds (AREA)
- Engineering & Computer Science (AREA)
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- Organic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
Description
Die Erfindung betrifft ein flüssiges Körperreinigungsmittel, insbesondere ein Haarwaschmit tel, mit guten konditionierenden Eigenschaften.The invention relates to a liquid body cleanser, in particular a Haarwaschmit tel, with good conditioning properties.
Haarwaschmittel, vorwiegend solche auf Basis anionischer Tenside, werden seit Menschenge denken benutzt.Shampoo, predominantly those based on anionic surfactants, have been used by humans think used.
Seit etwa zwanzig Jahren enthalten solche Haarwaschmittel auch Wirkstoffe, die das Haar konditionieren, d. h., die Naß- und Trockenkämmbarkeit, das Volumen, die Fülle, den Griff und den Glanz des gewaschenen Haares verbessern sollen.For about twenty years, such shampoos also contain active ingredients that the hair condition, d. h., the wet and dry combability, the volume, the fullness, the handle and to improve the shine of the washed hair.
Bevorzugt eingesetzte konditionierende Wirkstoffe sind dabei natürliche oder synthetische Polymere sowie quaternäre langkettige Ammoniumverbindungen, wobei bei letzteren aller dings Kompatibilitätsprobleme mit anionischen Tensiden auftreten können.Preferably used conditioning agents are natural or synthetic Polymers and quaternary long-chain ammonium compounds, wherein in the latter all However, compatibility problems with anionic surfactants may occur.
Die vorliegende Erfindung geht von der Aufgabenstellung aus, ein flüssiges Körperreini gungsmittel auf wäßriger Basis, insbesondere ein Haarwaschmittel, enthaltend anionische und nichtionische Tenside, zu schaffen, das eine gute Hautverträglichkeit und ausgezeichnete kon ditionierende Eigenschaften besitzt, ohne irgendwelche Stabilitätsprobleme aufzuweisen.The present invention is based on the task, a liquid Körperreini Aqueous-based, in particular a shampoo, containing anionic and nonionic surfactants, to create good skin tolerance and excellent con has updating properties without exhibiting any stability problems.
Diese Aufgabe wird erfindungsgemäß durch ein flüssiges Körperreinigungsmittel gelöst, das 5
bis 50 Gew.-%, berechnet auf seine Gesamtzusammensetzung, eines Tensidgemisches, umfas
send eine Kombination aus
This object is achieved according to the invention by a liquid body cleanser comprising 5 to 50% by weight, calculated on its total composition, of a surfactant mixture comprising a combination of
- a) mindestens einem anionischen Tensid, vorzugsweise in einer Menge von 2,5 bis 25 Gew.-% der Gesamtzusammensetzung, unda) at least one anionic surfactant, preferably in an amount of from 2.5 to 25% by weight the overall composition, and
- b) mindestens einem nichtionischen Tensid, vorzugsweise in einer Menge von 2,5 bis 25 Gew.-% der Gesamtzusammensetzung, sowie b) at least one nonionic surfactant, preferably in an amount of from 2.5 to 25% by weight of the total composition, as well
-
c) 0,25 bis 15 Gew.-% mindestens einer Verbindung der allgemeinen Formel (I)
c) 0.25 to 15% by weight of at least one compound of the general formula (I)
worin R1 wherein R 1
und R2 and R 2
jeweils eine gegebenenfalls hydroxysubstituierte C8 in each case an optionally hydroxy-substituted C 8
-C22 -C 22
-Alkyl- oder Al kenylgruppe, R3 Alkyl or alkenyl group, R 3
und R4 and R 4
eine C1 a C 1
-C3 -C 3
-Alkylgruppe oder eine Gruppe -CH2 Alkyl group or a group -CH 2
-CH2 -CH 2
-O(EO)x -O (EO) x
-H, x 0 bis 5, und Y- -H, x 0 to 5, and Y -
ein Anion bedeuten, enthält.an anion.
Diese Zusammensetzungen sind stabil, sehr gut haut- und schleimhautverträglich, schäumen gut und verleihen dem Haar eine ausgezeichnete Naß- und Trockenkämmbarkeit, Glanz, Fül le, Volumen und einen vollen, weichen Griff.These compositions are stable, very well tolerated by skin and mucous membranes, foam good and give the hair excellent wet and dry combability, shine, filling le, volume and a full, soft feel.
Geeignete anionaktive Tenside im Rahmen der Erfindung sind in einer Menge von vorzugs weise mindestens 5 bis etwa 25 Gew.-% der Zusammensetzung enthalten.Suitable anionic surfactants in the invention are in an amount of preference Were at least 5 to about 25 wt .-% of the composition.
Dabei handelt es sich um solche vom Sulfat-, Sulfonat-, Carboxylat- und Alkylphosphat-Typ, vor allem natürlich diejenigen, die in Shampoos üblicherweise zum Einsatz gelangen, bei spielsweise die bekannten C10-C18-Alkylsulfate und insbesondere die entsprechenden Ether sulfate, beispielsweise C12-C14-Alkylethersulfat, Laurylethersulfat, insbesondere mit 1 bis 4 Ethylenoxidgruppen im Molekül, weiterhin Monoglycerid(ether)sulfate, Fettsäureamidsulfate, die durch Ethoxylierung und anschließende Sulfatierung von Fettsäurealkanolamiden erhalten werden, und deren Alkalisalze sowie Salze langkettige Mono- und Dialkylphosphate, die mil de, hautverträgliche Detergentien darstellen.These are those of the sulfate, sulfonate, carboxylate and alkyl phosphate type, especially of course those that are commonly used in shampoos, for example, the known C 10 -C 18 alkyl sulfates and in particular the corresponding ether sulfates For example, C 12 -C 14 alkyl ether sulfate, lauryl ether, in particular having 1 to 4 ethylene oxide groups in the molecule, further monoglyceride (ether) sulfates, Fettsäureamidsulfate obtained by ethoxylation and subsequent sulfation of fatty acid alkanolamides, and their alkali salts and salts long-chain mono- and Dialkyl phosphates, which are mil, skin-friendly detergents.
Im Rahmen der Erfindung weiterhin geeignete anionische Tenside sind α-Olefinsulfonate bzw. deren Salze und insbesondere Alkalisalze von Sulfobernsteinsäurehalbestern, beispiels weise das Dinatriumsalz des Monooctylsulfosuccinats und Alkalisalze langkettiger Monoal kylethoxysulfosuccinate. In the context of the invention further suitable anionic surfactants are α-olefinsulfonates or their salts and in particular alkali metal salts of sulfosuccinic monoesters, for example example, the disodium salt of Monooctylsulfosuccinats and alkali metal salts langkettiger Monoal kylethoxysulfosuccinate.
Geeignete Tenside vom Carboxylat-Typ sind Alkylpolyethercarbonsäuren und deren Salze der
Formel
Suitable carboxylate-type surfactants are alkylpolyethercarboxylic acids and their salts of the formula
R-(C2H4O)n-O-CH2COOX,
R- (C 2 H 4 O) n -O-CH 2 COOX,
worin R eine C8-C20-Alkylgruppe, vorzugsweise C12-C14-Alkylgruppe, n eine Zahl von 1 bis
20, vorzugsweise 2 bis 17, und X H oder vorzugsweise ein Kation der Gruppe Natrium, Kali
um, Magnesium und Ammonium, das gegebenenfalls hydroxyalkylsubstituiert sein kann, be
deuten, sowie Alkylamidopolyethercarbonsäuren der allgemeinen Formel
in which R is a C 8 -C 20 -alkyl group, preferably C 12 -C 14 -alkyl group, n is a number from 1 to 20, preferably 2 to 17, and X is H or preferably a cation of the group sodium, potassium, magnesium and ammonium, which may optionally be hydroxyalkyl-substituted, be interpreted, and Alkylamidopolyethercarbonsäuren the general formula
worin R und X die vorstehend angegebene Bedeutung haben, und n insbesondere für eine Zahl von 1 bis 10, vorzugsweise 2,5 bis 5, steht.wherein R and X are as defined above, and n is in particular a number from 1 to 10, preferably 2.5 to 5, stands.
Derartige Produkte sind seit längerem bekannt und im Handel, beispielsweise unter den Han delsnamen "AKYPO®" und AKYPO-SOFT®".Such products have long been known and commercially, for example, under the Han the trade name "AKYPO®" and AKYPO-SOFT® ".
Auch C8-C20-Acylisethionate können, allein oder im Gemisch mit anderen anionaktiven Ten siden, eingesetzt werden, ebenso Sulfofettsäuren und deren Ester.Also, C 8 -C 20 acyl isethionates can be used alone or in admixture with other anionic surfactants, as well as sulfo fatty acids and their esters.
Es können auch Mischungen aus mehreren anionischen Tensiden eingesetzt werden, bei spielsweise ein Gemisch aus einen α-Olefinsulfonat und einem Sulfosuccinat, vorzugsweise im Verhältnis 1 : 3 bis 3 : 1, oder einem Ethersulfat und einer Polyethercarbonsäure oder Alkyl amidoethercarbonsäure.It is also possible to use mixtures of a plurality of anionic surfactants For example, a mixture of an α-olefinsulfonate and a sulfosuccinate, preferably in the ratio 1: 3 to 3: 1, or an ether sulfate and a polyether carboxylic acid or alkyl amidoether carboxylic acid.
Eine Übersicht über die in flüssigen Körperreinigungsmitteln zum Einsatz gelangenden anionaktiven Tenside findet sich im übrigen in der Monographie von K. Schrader, "Grundlagen und Rezepturen der Kosmetika", 2. Aufl. (1989, Hüthig Buchverlag), S. 595-600 und S. 683 bis 691. An overview of those used in liquid body cleansing agents Anionic surfactants are also found in the monograph by K. Schrader, "Basics and Formulations of Cosmetics", 2nd ed. (1989, Hüthig Buchverlag), p. 595-600 and pp. 683-691.
Weitere geeignete anionische Tenside sind auch C8-C22-Acylaminocarbonsäuren bzw. deren wasserlöslichen Salze, vorzugsweise in einer Menge von 0,5 bis 10, insbesondere 1 bis 7,5 Gew.-%, berechnet auf die Gesamtzusammensetzung. Besonders bevorzugt sind N-Lauroyl glutamat, insbesondere als Natriumsalz, sowie beispielsweise N-Lauroylsarcosinat, N-C12-C1 g-Acylasparaginsäure, N-Myristoylsarcosinat, N-Oleoylsarcosinat, N-Lauroylmethylalanin, N-Lauroyllysin und N-Lauroylaminopropylglycin, vorzugsweise in Form ihrer wasserlösli chen Alkali- oder Ammonium-, insbesondere Natriumsalze, vorzugsweise im Gemisch mit den obengenannten anionaktiven Tensiden.Other suitable anionic surfactants are also C 8 -C 22 -acylaminocarboxylic acids or their water-soluble salts, preferably in an amount of 0.5 to 10, in particular 1 to 7.5 wt .-%, calculated on the total composition. Particular preference is given to N-lauroyl glutamate, in particular as the sodium salt, and also, for example, N-lauroyl sarcosinate, NC 12 -C 1 g acylaspartic acid, N-myristoyl sarcosinate, N-oleoyl sarcosinate, N-lauroylmethylalanine, N-lauroyl lysine and N-lauroylaminopropylglycine, preferably in the form of theirs wasserlösli chen alkali metal or ammonium, in particular sodium salts, preferably in admixture with the above-mentioned anionic surfactants.
Weitere essentielle Tenside in den erfindungsgemäßen Haarwaschmitteln sind nichtionische- Tenside im Gemisch mit anionaktiven und gegebenenfalls zwitterionischen bzw. amphoteren Tensiden.Further essential surfactants in the shampoos according to the invention are nonionic Surfactants mixed with anionic and optionally zwitterionic or amphoteric Surfactants.
Diese sind bei Schrader, l.c., auf den Seiten 600-601 und S. 694-695 beschrieben.
Geeignet sind insbesondere Alkylpolyglucoside mit der allgemeinen Formel
These are described in Schrader, lc, pages 600-601 and pp. 694-695. Particularly suitable are alkyl polyglucosides having the general formula
R-O-(R1O)n-Zx,
RO- (R 1 O) n -Z x ,
worin R eine Alkylgruppe mit 8 bis 18 Kohlenstoffatomen, R1 eine Ethylen- oder Propylen gruppe, Z einen Saccaridrest mit 5 bis 6 Kohlenstoffatomen, n eine Zahl von 0 bis 10 und x eine Zahl zwischen 1 und 5 bedeuten.wherein R is an alkyl group having 8 to 18 carbon atoms, R1 is an ethylene or propylene Z, a Saccaridrest having 5 to 6 carbon atoms, n is a number from 0 to 10 and x mean a number between 1 and 5.
Diese Alkylpolyglucoside sind in letzter Zeit insbesondere als ausgezeichnete hautver trägliche schaumverbessernde Mittel in flüssigen Wasch- und Körperreinigungsmitteln be kannt geworden und sind in einer Menge von etwa 2,5 bis 25, insbesondere 5 bis 10 Gew.-%, der Gesamtzusammensetzung enthalten.These alkylpolyglucosides have recently become particularly excellent as skin ver Useful foam-improving agents in liquid washing and body cleansing be become known and are in an amount of about 2.5 to 25, especially 5 to 10 wt .-%, of the total composition.
Gemische aus anionaktiven Tensiden und Alkylpolyglucosiden sowie deren Verwendung in flüssigen Körperreinigungsmitteln sind an sich bereits bekannt, beispielsweise aus der EP-A 70 074. Die dort beschriebenen Alkylpolyglucoside sind prinzipiell auch im Rahmen der vor liegenden Erfindung geeignet; ebenso die aus der EP-A 358 216 bekannten Gemische aus Sul fosuccinaten und Alkylpolyglucosiden.Mixtures of anionic surfactants and alkylpolyglucosides and their use in liquid body cleansers are already known per se, for example from the EP-A 70 074. The alkyl polyglucosides described therein are in principle also within the scope of lying invention suitable; as well as the known from EP-A 358 216 mixtures of Sul fosuccinates and alkyl polyglucosides.
Weitere nichtionische Tensidbestandteile sind beispielsweise langkettige Fettsäuremono- und -dialkanolamide, wie Cocosfettsäuremonoethanolamid und Myristinfettesäuremonoethanol. Further nonionic surfactant components are, for example, long-chain fatty acid mono- and dialkanolamides such as coconut fatty acid monoethanolamide and myristic fatty acid monoethanol.
Weitere nichtionische Tensidbestandteile sind beispielsweise langkettige Fettsäuremono- und -dialkanolamide, wie Cocosfettsäuremonoethanolamid und Myristinfettsäuremonoethanol amid, die auch als Schaumverstärker, vorzugsweise in einer Menge von etwa 2 bis etwa 5 Gew.-% eingesetzt werden können.Further nonionic surfactant components are, for example, long-chain fatty acid mono- and dialkanolamides such as coconut fatty acid monoethanolamide and myristic fatty acid monoethanol amide, which is also used as a foam enhancer, preferably in an amount of about 2 to about 5 wt .-% can be used.
Andere zusätzlich mitverwendbare nichtionische Tenside sind z. B. die verschiedenen Sorbi tanester, wie Polyethylenglykolsorbitanstearinsäureester, Fettsäurepolyglykolester oder auch Mischkondensate aus Ethylenoxid und Propylenoxid, wie sie beispielsweise unter der Han delsbezeichnung "Pluronics" im Verkehr sind, sowie Fettalkoholethoxylate.Other additionally co-usable nonionic surfactants are, for. B. the different sorbi tanester, such as Polyethylenglykolsorbitanstearinsäureester, Fettsäuregolyglykolester or else Mixed condensates of ethylene oxide and propylene oxide, as described for example under the Han label "Pluronics" in circulation, as well as fatty alcohol ethoxylates.
Weitere zusätzlich einsetzbare Tenside sind Aminoxide in einer Menge von etwa 0,25 bis etwa 5, vorzugsweise etwa 0,5 bis etwa 3,5 Gew.-%, berechnet auf die Gesamtzusammenset zung des Mittels.Further surfactants which may additionally be used are amine oxides in an amount of about 0.25 to about 5, preferably about 0.5 to about 3.5 wt .-%, calculated on the Gesamtzusammenset tion of the agent.
Solche Aminoxide gehören seit langem zum Stand der Technik, beispielsweise C12-C18-Al kyldimethylaminoxide wie Lauryldimethylaminoxid, C12-C18-Alkylamidopropyl- oder -ethylaminoxide, C12-C18-Alkyldi(hydroxyethyl)- oder -(hydroxypropyl)aminoxide, oder auch Aminoxide mit Ethylenoxid- und/oder Propylenoxidgruppen in der Alkylkette.Such amine oxides have long been state of the art, for example C 12 -C 18 -alkyldimethylamine oxides such as lauryldimethylamine oxide, C 12 -C 18 -alkylamidopropyl or -ethylamine oxides, C 12 -C 18 -alkyldi (hydroxyethyl) - or - (hydroxypropyl) amine oxides, or amine oxides with ethylene oxide and / or propylene oxide groups in the alkyl chain.
Solche Aminoxide sind beispielsweise unter den Bezeichnungen "Ammonyx®", "Aromox®" oder "Genaminox®" im Handel.Such amine oxides are known, for example, under the names "Ammonyx®", "Aromox®" or "Genaminox®" commercially.
Die erfindungsgemäßen Zusammensetzungen können als weiteren Tensid-Bestandteil am photere bzw. zwitterionische Tenside, beispielsweise in einer Menge von etwa 0,5 bis etwa 10, vorzugsweise von etwa 1 bis etwa 7,5 Gew.-%, bezogen auf die Gesamtzusammen setzung, enthalten.The compositions according to the invention can be used as further surfactant constituent on photere or zwitterionic surfactants, for example in an amount of about 0.5 to about 10, preferably from about 1 to about 7.5% by weight, based on the total included.
Als solche sind insbesondere die verschiedenen bekannten Betaine wie Fettsäureamidoalkyl betaine und Sulfobetaine, beispielsweise Laurylhydroxysulfobetain, zu nennen; auch langket tige Alkylaminosäuren wie Cocoaminoacetat, Cocoaminopropionat und Natriumcocoampho propionat und -acetat haben sich als geeignet erwiesen. As such, in particular the various known betaines such as fatty acid amidoalkyl betaines and sulfobetaines, for example lauryl hydroxysulfobetaine; also long-lasting tiger alkyl amino acids such as cocoaminoacetate, cocoaminopropionate and sodium cocoampho Propionate and acetate have been found to be suitable.
Im einzelnen können Betaine der Struktur
In particular, Betaine's structure
wobei R eine C8-C18-Alkylgruppe und n 1 bis 3 bedeuten,
Sulfobetaine der Struktur
where R is a C 8 -C 18 -alkyl group and n is 1 to 3,
Sulfobetaines of the structure
wobei R eine C8-C18-Alkylgruppe und n 1 bis 3 bedeuten,
und Amidoalkylbetaine der Struktur
where R is a C 8 -C 18 -alkyl group and n is 1 to 3,
and amidoalkylbetaines of the structure
wobei R eine C8-C18-Alkylgruppe und n 1 bis 3 bedeuten, verwendet werden.wherein R is a C 8 -C 18 alkyl group and n is 1 to 3, are used.
Bevorzugte Verbindungen der allgemeinen Formel (I) sind solche, bei denen R1 und R2 einen
C12-C18-Alkylrest oder eine Oleylgruppe bedeuten. R3 und R4 sind vorzugsweise eine Methyl
gruppe, wobei in einer besonders vorteilhaften Konstellation R3 für Methyl und R4 für eine
Gruppe -CH2-CH2-O[EO]x-H steht, worin x eine Zahl von 0 bis 3 bedeutet.
Y- steht vorzugsweise für ein Ethosulfat-, Methosulfat-, Chlorid oder Phosphat-Anion.Preferred compounds of the general formula (I) are those in which R 1 and R 2 denote a C 12 -C 18 -alkyl radical or an oleyl group. R 3 and R 4 are preferably a methyl group, wherein in a particularly advantageous constellation R 3 is methyl and R 4 is a group -CH 2 -CH 2 -O [EO] x -H, wherein x is a number from 0 to 3 means.
Y - is preferably an ethosulfate, methosulfate, chloride or phosphate anion.
Diese Verbindungen sind bekannt und beispielsweise unter der Bezeichnung "INCROQUAT® HO-80" bzw. "OSC" im Handel.These compounds are known and, for example, under the name "INCROQUAT® HO-80" or "OSC" in the trade.
Ihr Anteil in den erfindungsgemäßen Zusammensetzungen liegt vorzugsweise bei etwa 0,5 bis 10, insbesondere etwa 1 bis 7,5 Gew.-%. Their proportion in the compositions according to the invention is preferably from about 0.5 to 10, in particular about 1 to 7.5 wt .-%.
Die erfindungsgemäßen Shampoos können auch weitere Wirkstoffe wie Eiweißhydrolysate und Polypeptide, z. B. Keratinhydrolysate, Kollagenhydrolysate vom Typ "Nutrilan®" oder Elastinhydrolysate sowie insbesondere auch pflanzliche, gegebenenfalls kationisierte Eiweiß hydrolysate, z. B. "Gluadin®", enthalten.The shampoos according to the invention may also contain other active ingredients such as protein hydrolysates and polypeptides, e.g. B. Keratinhydrolysate, collagen hydrolysates of the type "Nutrilan®" or Elastinhydrolysate and in particular also vegetable, optionally cationized protein hydrolyzates, e.g. B. "Gluadin®" included.
Weitere konditionierende Zusätze sind geeignete Polymere. Diese können nichtionische Po lymere, vorzugsweise alkohol- und/oder wasserlösliche Vinylpyrrolidon-Polymere wie ein Vinylpyrrolidon-Homopolymerisat oder -Copolymerisat, insbesondere mit Vinylacetat, sein. Geeignete Vinylpyrrolidon-Polymere sind z. B. die unter dem Handelsnamen "Luviskol®" be kannten Produkte, beispielsweise die Homopolymerisate "Luviskol® K 30, K 60 und K 90" sowie die wasser- bzw. alkohollöslichen Copolymerisate aus Vinylpyrrolidon und Vinylacetat, die unter dem Handelsnamen "Luviskol® VA 55 bzw. VA 64" von der BASF AG vertrieben werden.Other conditioning additives are suitable polymers. These can be nonionic buttocks polymers, preferably alcohol and / or water-soluble vinylpyrrolidone polymers such as Vinylpyrrolidone homopolymer or copolymer, in particular with vinyl acetate. Suitable vinylpyrrolidone polymers are, for. B. under the trade name "Luviskol®" be knew products, for example the homopolymers "Luviskol® K 30, K 60 and K 90" and the water- or alcohol-soluble copolymers of vinylpyrrolidone and vinyl acetate, sold under the trade name "Luviskol® VA 55 or VA 64" by BASF AG become.
Weitere geeignete nichtionische Polymere sind Vinylpyrrolidon/Vinylacetat/Vinylpropionat- Copolymere wie "Luviskol® VAP 343", Vinylpyrrolidon/(Meth)Acrylsäureester-Copolymere sowie Chitosan-Derivate. Ihr Anteil in den erfindungsgemäßen Haarwaschmitteln liegt, wenn vorhanden, zwischen etwa 0,05 und etwa 5, vorzugsweise 0,1 und 2,5, insbesondere etwa 0,15 bis 1,5 Gew.-%, bezogen auf die Gesamtzusammensetzung des Mittels.Further suitable nonionic polymers are vinylpyrrolidone / vinyl acetate / vinyl propionate Copolymers such as "Luviskol® VAP 343", vinylpyrrolidone / (meth) acrylic acid ester copolymers as well as chitosan derivatives. Their share in the shampoos of the invention is when present, between about 0.05 and about 5, preferably 0.1 and 2.5, especially about 0.15 to 1.5% by weight, based on the total composition of the composition.
Anstelle oder zusätzlich zu den nichtionischen Polymeren können als haarkonditionierende Polymere auch kationische und/oder anionische und/oder amphotere Polymere in den ge nannten Mengen eingesetzt werden.Instead of or in addition to the nonionic polymers may be hair conditioning Polymers also cationic and / or anionic and / or amphoteric polymers in the ge quantities are used.
Bevorzugte haarkonditionierende kationische Polymere sind die altbekannten quaternären Cellulosederivate des Typs "Polymer JR" sowie quaternisierte Homo- und Copolymere des Dimethyldiallylammoniumchlorids, wie sie unter dem Handelsnamen "Merquat®" im Handel sind, quaternäre Vinylpyrrolidon-Copolymere, insbesondere mit Dialkylaminoalkyl(meth)- acrylaten, wie sie unter dem Namen "Gafquat®" bekannt sind, Copolymerisate aus Vinyl pyrrolidon und Vinylimidazoliniummethochlorid, die unter dem Handelsnamen "Luviquat®" angeboten werden, Polyamino-Polyamid-Derivate, beispielsweise Copolymere von Adipin säure-Dimethylaminohydroxypropyldiethylentriamin, wie sie unter dem Namen "Cartaretine® F" vertrieben werden, sowie auch bisquaternäre langkettige Ammoniumverbindungen der in der US-PS 4 157 388 beschriebenen Harnstoff-Struktur, die unter dem Handelsnamen "Mirapol® A 15" im Handel sind.Preferred hair conditioning cationic polymers are the well-known quaternaries Cellulose derivatives of the type "Polymer JR" and quaternized homo- and copolymers of Dimethyldiallylammonium chloride, as sold under the trade name "Merquat®" are quaternary vinylpyrrolidone copolymers, in particular with dialkylaminoalkyl (meth) - acrylates, as they are known under the name "Gafquat®", copolymers of vinyl pyrrolidone and vinylimidazolinium methochloride sold under the trade name "Luviquat®" are offered, polyamino-polyamide derivatives, for example copolymers of adipic acid dimethylaminohydroxypropyldiethylenetriamine, as sold under the name "Cartaretine® F "are distributed, as well as bisquaternary long-chain ammonium compounds of in U.S. Patent 4,157,388, which is under the trade name "Mirapol® A 15" are on the market.
Verwiesen wird in diesem Zusammenhang auch auf die in den DE-OSen 25 21 960, 28 11 010, 30 44 738 und 32 17 059 genannten kationaktiven Polymeren sowie die in der EP-A 337 354 auf den Seiten 3 bis 7 beschriebenen Produkte. Es könne auch Mischungen ver schiedener kationischer Polymerer eingesetzt werden.Reference is made in this context to the in DE-OSs 25 21 960, 28 11 010, 30 44 738 and 32 17 059 mentioned cationic polymers and in the EP-A 337 354 on pages 3 to 7 described products. It could also ver various cationic polymers are used.
Zu den kationischen Polymeren zählen auch die in der EP-A 524 612 und der EP-A 640 643 beschriebenen Quaternisierungsprodukte aus Pfropfpolymerisaten von Organopolysiloxanen und Polyethyloxazolinen.The cationic polymers also include those in EP-A 524 612 and EP-A 640 643 described quaternization of graft polymers of organopolysiloxanes and polyethyloxazolines.
Als amphotere Polymere, die allein oder im Gemisch mit mindestens einem weiteren kationi schen, nichtionischen oder anionischen Polymeren zum Einsatz gelangen, seien insbesondere Copolymerisate aus N-Octylacrylamid, (Meth)-Acrylsäure und tert.-Butylamino ethylmethacrylat vom Typ "Amphomer®"; Copolymerisate aus Methacryloylethylbetain und Alkylmethacrylaten vom Typ "Yukaformer®", z. B. das Butylmethacrylat-Copolymere "Yukaformer® Am 75"; Copolymerisate aus Carboxylgruppen und Sulfongruppen enthalten den Monomeren, z. B. (Meth)Acrylsäure und Itaconsäure, mit basischen Gruppen, insbesonde re Aminogruppen, enthaltenden Monomeren wie Mono- bzw. Dialkylaminoalkyl(meth)- acrylaten bzw. Mono- bzw. Dialkylaminoalkyl(meth)acrylamiden; Copolymere aus N-Octyl acrylamid, Methylmethacrylat, Hydroxypropylmethacrylat, N-tert.-Butylaminoethyl methacrylat und Acrylsäure sowie die aus der US-A 3,927,199 bekannten Copolymeren ge nannt.As amphoteric polymers, alone or in admixture with at least one other kationi particular, non-ionic or anionic polymers are used Copolymers of N-octylacrylamide, (meth) acrylic acid and tert-butylamino ethyl methacrylate type "Amphomer®"; Copolymers of methacryloylethylbetaine and Alkyl methacrylates of the type "Yukaformer®", z. B. the butyl methacrylate copolymers "Yukaformer® At 75"; Contain copolymers of carboxyl groups and sulfone groups the monomers, for. As (meth) acrylic acid and itaconic acid, with basic groups, in particular amino groups containing monomers such as mono- or dialkylaminoalkyl (meth) - acrylates or mono- or dialkylaminoalkyl (meth) acrylamides; Copolymers of N-octyl acrylamide, methyl methacrylate, hydroxypropyl methacrylate, N-tert-butylaminoethyl methacrylate and acrylic acid and the copolymers known from US-A 3,927,199 ge Nannt.
Geeignete anionische Polymere sind Vinylalkylether-, insbesondere Methylvinyle ther/Maleinsäure-Copolymere, die durch Hydrolyse von Vinylether/Maleinsäureanhydrid- Copolymeren entstehen und unter der Handelbezeichnung "Gantrez® AN oder Es" vertrieben werden. Diese Polymere können auch teilverestert sein, beispielsweise "Gantrez® ES 255", der Ethylester eines Ethylvinylethers/Maleinsäure-Copolymers, oder der Butyl- oder Isobutyl ester desselben. Suitable anionic polymers are vinylalkyl ether, especially methylvinyl ether / maleic acid copolymers obtained by hydrolysis of vinyl ether / maleic anhydride Copolymers are produced and sold under the trade name "Gantrez® AN or Es" become. These polymers can also be partially esterified, for example "Gantrez® ES 255", the ethyl ester of an ethyl vinyl ether / maleic acid copolymer, or the butyl or isobutyl ester of the same.
Weitere geeignete anionische Polymere sind insbesondere Vinylacetat/Crotonsäure- oder Vinylacetat/Vinylneodecanoat/Crotonsäure-Copolymere des Typs "Resyn®"; Natriumacry lat/Vinylalkohol-Copolymere des Typs "Hydagen® F", Natriumpolystyrolsulfonat, z. B. "Flexan® 130", Ethylacrylat/Acrylsäure/N-tert.-Butylacrylamid-Copolymere des Typs"Ultrahold®"; Vinylpyrrolidon/Vinylacetat/ltaconsäure-Copolymere, Acrylsäu re/Acrylamid-Copolymere bzw. Natriumsalze derselben vom Typ "Reten®; etc.Other suitable anionic polymers are in particular vinyl acetate / crotonic acid or Vinyl acetate / vinyl neodecanoate / crotonic acid copolymers of the "Resyn®" type; Natriumacry lat / vinyl alcohol copolymers of the type "Hydagen® F", sodium polystyrenesulfonate, z. B. "Flexan® 130", ethyl acrylate / acrylic acid / N-tert-butylacrylamide copolymers of Type "Ultrahold®"; Vinylpyrrolidone / vinyl acetate / ltaconic acid copolymers, acrylic acid acrylamide copolymers or sodium salts thereof of the "Reten®" type, etc.
Die erfindungsgemäßen Körperreinigungsmittel können selbstverständlich alle üblichen, in solchen Mitteln zum Einsatz gelangenden Stoffe enthalten.The body cleansing compositions according to the invention may of course be all customary, in containing such agents used.
Als solche seien beispielhaft Komplexbildner, Farbstoffe, Konservierungsmittel, pH-Regler, Viskositätsregler wie anorganische Salze, soweit sie nicht ohnehin in den Tensid- Ausgangsmischungen enthalten sind, Duftstoffe, Perlglanzmittel, Verdickungsmittel, Feucht haltemittel, pflanzliche und tierische Öle, etc. genannt.As such are, for example, complexing agents, dyes, preservatives, pH regulators, Viscosity regulators such as inorganic salts, unless they are already present in the surfactant Starting mixtures are included, fragrances, pearlescing agents, thickeners, moist preservatives, vegetable and animal oils, etc.
Geeignete pflanzliche und tierische Öle sowie synthetische Fettsäureester, zu denen auch Wachse zählen, sind insbesondere natürliche Öle wie Avocadoöl, Cocosöl, Palmöl, Sesamöl, Erdnußöl, Spermöl, Sonnenblumenöl, Mandelöl, Pfirsichkernöl, Weizenkeimöl, Macadamia nußöl, Nachtkerzenöl, Jojobaöl, Ricinusöl, oder auch Oliven- bzw. Sojaöl, Lanolin und dessen Derivate, ebenso Mineralöle wie Paraffinöl und Vaseline.Suitable vegetable and animal oils as well as synthetic fatty acid esters, which include Waxes are, in particular, natural oils such as avocado oil, coconut oil, palm oil, sesame oil, Peanut oil, sperm oil, sunflower oil, almond oil, peach kernel oil, wheat germ oil, macadamia nut oil, evening primrose oil, jojoba oil, castor oil, or olive oil or soybean oil, lanolin and its Derivatives, as well as mineral oils such as paraffin oil and Vaseline.
Synthetische Öle und Wachse sind beispielsweie Silikonöle, Polyethylenglykole, etc. Weitere geeignete hydrophobe Komponenten sind insbesondere Fettalkohole, vorzugsweise soclhe mit etwa 8 bis 22 Kohlenstoffatomen im Molekül wie Myristyl-, Cetyl-, Stearylalko hol,Wachsalkohole und Fettsäureester wie Isopropylmyristat, -palmitat, -stearat und -iso stearat, Oleyloleat, Isocetylstearat, Hexyllaurat, Dibutyladipat, Dioctyladipat, Myristylmyri stat, Oleylerucat, Polyethylenglykol- und polyglycerylfettsäureester wie PEG-7-glyceryl cocoat, Cetylpalmitat, etc.Synthetic oils and waxes are, for example, silicone oils, polyethylene glycols, etc. Other suitable hydrophobic components are especially fatty alcohols, preferably molecules having about 8 to 22 carbon atoms in the molecule, such as myristyl, cetyl, stearyl alcohol alcohols, wax alcohols and fatty acid esters such as isopropyl myristate, palmitate, stearate and iso stearate, oleyl oleate, isocetyl stearate, hexyl laurate, dibutyl adipate, dioctyl adipate, myristyl myri stat, oleyl erucate, polyethylene glycol and polyglyceryl fatty acid esters such as PEG-7-glyceryl cocoate, cetyl palmitate, etc.
Diese hydrophoben Komponenten sind in den erfindungsgemäßen Zusammensetzungen vor zugsweise in einer Gesamtmenge von etwa 0,5 bis etwa 10, insbesondere etwa 1 bis 7,5, vor allem etwa 1,5 bis 5 Gew.-%, berechnet auf die Gesamtzusammensetzung, enthalten. These hydrophobic components are present in the compositions of the invention preferably in a total amount of about 0.5 to about 10, especially about 1 to 7.5 before all about 1.5 to 5 wt .-%, calculated on the total composition included.
Eine Auflistung solcher Zusatzstoffe findet sich ebenfalls bei Schrader, l.c., auf S. 695 bis 722.A list of such additives can also be found in Schrader, l.c., p. 695 bis 722nd
Weitere bevorzugte Bestandteile sind Benzylalkohol, Benzyloxyethanol, Phenoxyethanol, Phenethylalkohol, Zimtalkohol, 1-Methoxypropanol(-2), 1-Ethoxypropanol(-2), Diethylengly kolmonomethyl- oder -ethylether, Dipropylenglykolmonomethyl- oder -ethylether und/oder Harnstoff, vorzugsweise in einer Menge von 0,1 bis 15 Gew.-%, insbesondere etwa 0,5 bis 7,5 Gew.-% des erfindungsgemäßen Körperreinigungsmittels.Further preferred ingredients are benzyl alcohol, benzyloxyethanol, phenoxyethanol, Phenethyl alcohol, cinnamyl alcohol, 1-methoxypropanol (-2), 1-ethoxypropanol (-2), diethylene glycol colomonomethyl or ethyl ether, dipropylene glycol monomethyl or ethyl ether and / or Urea, preferably in an amount of 0.1 to 15 wt .-%, in particular about 0.5 to 7.5% by weight of the body cleanser according to the invention.
Schließlich können auch noch bekannte Polysiloxane als konditionierende Mittel in den erfin dungsgemäßen flüssigen Haarwaschmitteln mitverwendet werden. Deren bevorzugter Anteil liegt dabei etwa zwischen 0,5 und etwa 5, insbesondere 1 bis 3 Gew.-% der Gesamtzusam mensetzung. Geeignet sind sowohl leichtflüchtige als auch schwerflüchtige cyclische oder lineare Polysiloxane, beispielsweise die unter dem Trivialnamen "Dimethicone" bzw. "Phenyldimethicone" sowie "Cyclomethicone" bekannten Silikonöle.Finally, it is also possible to use known polysiloxanes as conditioning agents in the invention To be used according to the invention liquid shampoos. Their preferred proportion is about between 0.5 and about 5, in particular 1 to 3 wt .-% of Gesamtzusam mensetzung. Suitable are both volatile and semi-volatile cyclic or linear polysiloxanes, for example those under the trivial name "Dimethicone" or "Phenyldimethicone" and "Cyclomethicone" known silicone oils.
Geeignet sind beispielsweise auch die in der EP-A 398 177 beschriebenen Silikonderivate, die dort in Kombination mit Alkylpolyglucosiden in flüssigen Detergens-Zusammensetzungen eingesetzt werden.Also suitable, for example, are the silicone derivatives described in EP-A 398 177, which there in combination with alkyl polyglucosides in liquid detergent compositions be used.
Gemäß einer bevorzugten Ausführungsform der Erfindung können erfindungsgemäße Sham poos auch Farbstoffe zur direkten oder oxidativen Färbung von Haaren enthalten, also soge nannte Tönungs- oder Färbeshampoos.According to a preferred embodiment of the invention sham Poos also contain dyes for direct or oxidative coloring of hair, so soge called tinting or dyeing shampoos.
Besonders geeignet sind direktziehende Farbstoffe enthaltende Tönungsshampoos.Tinting shampoos containing substantive dyes are particularly suitable.
Es wurde nämlich festgestellt, daß solche Shampoos, die die erfindungsgemäße Tensidzu sammensetzung und insbesondere kationische direktziehende Farbstoffe enthalten, eine be sonders brillante, glänzende und stabile Haarfärbung gegenüber bekannten Tönungsshampoos auf Basis konventioneller Tenside bzw. Tensidmischungen ergeben.It has been found that such shampoos containing the surfactant according to the invention composition and in particular cationic substantive dyes, a be especially brilliant, shiny and stable hair coloring compared to known tinting shampoos based on conventional surfactants or surfactant mixtures.
Der pH-Wert der erfindungsgemäßen Shampoos liegt im üblichen Bereich zwischen etwa 5 und 8,5, für Spezialprodukte kann er auch unterhalb 5 eingestellt werden. The pH of the shampoos according to the invention is in the usual range between about 5 and 8.5, for specialty products it can also be set below 5.
Die Viskosität liegt im üblichen Bereich zwischen etwa 1000 und etwa 10 000 mPa.s bei 20°C, vorzugsweise etwa 2000 bis etwa 6000, insbesondere 2500 bis 5000 mPa.s bei 20°C, gemessen nach Brookfield oder Höppler bei einer Scherspannung von 10 sec-1.The viscosity is in the usual range between about 1000 and about 10,000 mPa.s at 20 ° C, preferably about 2000 to about 6000, especially 2500 to 5000 mPa.s at 20 ° C, measured according to Brookfield or Hoppler at a shear stress of 10 sec -1 .
Sie können, abgefüllt mit entsprechenden Treibmitteln, auch als Aerosolshampoos konfektio niert werden.You can, filled with appropriate propellants, as an aerosol shampoo confection be defined.
Die folgenden Beispiele dienen der Illustration der Erfindung.The following examples serve to illustrate the invention.
R1=R2=Oleyl; R3=CH3; R4=(CH2-CH2-O)3H; Y-=CH3SO4 -.R 1 = R 2 = oleyl; R 3 = CH 3; R 4 = (CH 2 -CH 2 -O) 3 H; Y - = CH 3 SO 4 - .
Es wurde eine stabile Zusammensetzung erhalten, die bei der Haarwäsche gut schäumte und eine ausgezeichnete Naß- und Trockenkämmbarkeit, ein Haar mit vollem, weichem Griff und dezentem Glanz ergab.A stable composition was obtained which foamed well during hair washing and excellent wet and dry combability, a hair with a full, soft feel and discreet shine resulted.
Der Ersatz der Verbindung der Formel I durch die gleiche Menge an Cetrimoniumchlorid, einem üblichen quaternären konditionierenden Wirkstoff, führte zu einem instabilen, schlecht schäumenden Produkt mit nahezu keiner konditionierenden Wirkung. The replacement of the compound of the formula I by the same amount of cetrimonium chloride, a usual quaternary conditioning agent, resulted in an unstable, bad foaming product with almost no conditioning effect.
R1=R2=Stearyl; R3=CH3; R4=-CH2CH2-OH; Y-=CH3SO4 -.R 1 = R 2 = stearyl; R 3 = CH 3; R 4 = -CH 2 CH 2 -OH; Y - = CH 3 SO 4 - .
Mit dem erhaltenen Shampoo ließen sich eine ausgezeichnete Naß- und Trockenkämmbarkeit des Haares, gutes Volumen und voller Griff sowie Fülle und Glanz erzielen. The obtained shampoo was excellent in wet and dry combability Hair, good volume and full feel and achieve fullness and shine.
*R1=R2=Oleyl; R3=CH3; R4=CH2-CH2-O(EO)2-H; Y-=MeSO4 - .* R 1 = R 2 = oleyl; R 3 = CH 3; R 4 = CH 2 -CH 2 -O (EO) 2 -H; Y - = MeSO 4 - .
Bei Anwendung dieses Shampoos wurde eine glänzende Rotfärbung erhalten, wobei das Haar zusätzlich eine gute Naß- und Trockenkämmbarkeit aufwies sowie Volumen, Elastizität und einen vollen Griff zeigte. When using this shampoo a bright red color was obtained, with the hair additionally good wet and dry combability and volume, elasticity and showed a full grip.
*R1=R2=Oleyl; R3=CH3; R4=(CH2-CH2-O)3-H; Y-=CH3SO4 -.* R 1 = R 2 = oleyl; R 3 = CH 3; R 4 = (CH 2 -CH 2 -O) 3 -H; Y - = CH 3 SO 4 - .
Dieses Shampoo wurde im bekannten Halbseiten-Doppelblindversuch an 10 Probanden mit einem Shampoo verglichen, das keine Verbindung der Formel I und statt dessen 1,5 Gew.-% einer konventionellen quaternären Ammoniumverbindung enthielt.This shampoo was in the known half-page double blind trial with 10 subjects with compared to a shampoo containing no compound of formula I and instead 1.5% by weight a conventional quaternary ammonium compound.
Die unabhängige Auswertung durch zwei Friseure ergab eine Präferenz von 9 : 1 zugunsten des erfindungsgemäßen Shampoos im Hinblick auf die Schaumeigenschaften sowie die Naß- und Trockenkämmbarkeit, die Geschmeidigkeit und Lockerheit des nassen, gewaschenen Haares und von 8 : 2 zugunsten des erfindungsgemäßen Shampoos im Hinblick auf Volumen, Weich heit und Sprungkraft des trockenen Haares. The independent evaluation by two hairdressers showed a preference of 9: 1 in favor of the shampoos according to the invention with regard to the foam properties and the wet and Dry combability, suppleness and looseness of wet, washed hair and 8: 2 in favor of the shampoo of the invention in terms of volume, softness and the bounce of dry hair.
*R1=R2=C18H37; R3=CH3; R4=CH2CH2OH; Y-=CH3SO4 -.* R 1 = R 2 = C 18 H 37 ; R 3 = CH 3; R 4 = CH 2 CH 2 OH; Y - = CH 3 SO 4 - .
Dieses Shampoo entsprach in seinen Eigenschaften dem Shampoo nach Beispiel 4. This shampoo corresponded in its properties to the shampoo according to Example 4.
*R1=R3=Oleyl; R3=CH3; R4=(CH2-CH2-O)3-H; Y- =CH3SO4 -.* R 1 = R 3 = oleyl; R 3 = CH 3; R 4 = (CH 2 -CH 2 -O) 3 -H; Y - = CH 3 SO 4 - .
Dieses Antischuppenshampoo verleiht dem Haar zusätzlich Glanz, Volumen und ausgezeich nete Naß- und Trockenkämmbarkeit und zeigt eine exzellente Schaumqualität.This anti-dandruff shampoo gives hair extra shine, volume and excellent wet and dry combability and shows excellent foam quality.
Claims (9)
- a) mindestens einem anionischen Tensid,
- b) mindestens einem nichtionischen Tensid; und
- c) 0,25 bis 15 Gew.-% mindestens einer Verbindung der allgemeinen Formel (1)
- a) at least one anionic surfactant,
- b) at least one nonionic surfactant; and
- c) 0.25 to 15% by weight of at least one compound of the general formula (1)
R-O-(R1O)n-Zx,
worin R eine Alkylgruppe mit 8 bis 18 Kohlenstoffatomen, R1 eine Ethylen- oder Propylengruppe, Z einen Saccharidrest mit 5 bis 6 Kohlenstoffatomen, n eine Zahl von 0 bis 10, und x eine Zahl zwischen 1 und 2,5 bedeuten.4. Composition according to one or more of claims 1 to 3, comprising as component b) a C 8 -C 18 -Alkylpolyglucosid the general formula
RO- (R 1 O) n -Z x ,
wherein R is an alkyl group having 8 to 18 carbon atoms, R 1 is an ethylene or propylene group, Z is a saccharide radical having 5 to 6 carbon atoms, n is a number from 0 to 10, and x is a number between 1 and 2.5.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19964155A DE19964155A1 (en) | 1999-02-20 | 1999-02-20 | Water-based cleanser, especially shampoo, contains anionic and nonionic surfactants and N,N-di(acylaminoethyl)-N,N-dialkyl-, -hydroxyethyl- or -hydroxy(poly)ethoxyethyl-ammonium salt |
| DE19964178A DE19964178A1 (en) | 1999-02-20 | 1999-02-20 | Liquid body cleanser |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19964155A DE19964155A1 (en) | 1999-02-20 | 1999-02-20 | Water-based cleanser, especially shampoo, contains anionic and nonionic surfactants and N,N-di(acylaminoethyl)-N,N-dialkyl-, -hydroxyethyl- or -hydroxy(poly)ethoxyethyl-ammonium salt |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE19907376A1 true DE19907376A1 (en) | 2000-08-24 |
Family
ID=7935239
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1999107376 Withdrawn DE19907376A1 (en) | 1999-02-20 | 1999-02-20 | Body cleaning composition, useful particularly as tinting or dyeing shampoo, contains quaternary ammonium di-amide and has excellent conditioning effects |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE19907376A1 (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10342418A1 (en) * | 2003-09-13 | 2005-04-07 | Beiersdorf Ag | Washing-active cosmetic or dermatological formulations, used for e.g. for bath and shower formulation or shampoo, contain alkyl and/or alkyl ether sulfate, anionic surfactant and ethoxylated fatty acid glycerides |
| WO2006007925A1 (en) * | 2004-07-20 | 2006-01-26 | Unilever Plc | Mild, moisturizing sulfosuccinate cleansing compositions |
| WO2006007945A1 (en) * | 2004-07-20 | 2006-01-26 | Unilever Plc | Mild, moisturizing cleansing compositions |
| WO2006058755A1 (en) * | 2004-12-04 | 2006-06-08 | Unilever Plc | Shampoo compositions containing cationic polymer and an anionic surfactant mixture |
| EP2617805A1 (en) * | 2012-01-23 | 2013-07-24 | Kao Corporation, S.A. | Alkaline cleaning compositions for non-horizontal surfaces |
| EP1951039B1 (en) * | 2005-11-14 | 2015-02-25 | Solvay USA Inc. | Agricultural adjuvant compositions, pesticide compositions, and methods for using such compositions |
| GB2571414A (en) * | 2017-12-20 | 2019-08-28 | Henkel Kgaa | Toning shampoo with improved colour performance |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5710113A (en) * | 1990-12-05 | 1998-01-20 | The Procter & Gamble Company | Hair conditioning compositions with silicone conditioning agent containing silicone resin |
| US5714446A (en) * | 1990-12-05 | 1998-02-03 | The Procter & Gamble Company | Shampoo compositions with silicone and cationic surfactant conditioning agents |
| WO1999038476A1 (en) * | 1998-02-03 | 1999-08-05 | The Procter & Gamble Company | Styling shampoo compositions which deliver improved hair curl retention and hair feel |
-
1999
- 1999-02-20 DE DE1999107376 patent/DE19907376A1/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5710113A (en) * | 1990-12-05 | 1998-01-20 | The Procter & Gamble Company | Hair conditioning compositions with silicone conditioning agent containing silicone resin |
| US5714446A (en) * | 1990-12-05 | 1998-02-03 | The Procter & Gamble Company | Shampoo compositions with silicone and cationic surfactant conditioning agents |
| WO1999038476A1 (en) * | 1998-02-03 | 1999-08-05 | The Procter & Gamble Company | Styling shampoo compositions which deliver improved hair curl retention and hair feel |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10342418A1 (en) * | 2003-09-13 | 2005-04-07 | Beiersdorf Ag | Washing-active cosmetic or dermatological formulations, used for e.g. for bath and shower formulation or shampoo, contain alkyl and/or alkyl ether sulfate, anionic surfactant and ethoxylated fatty acid glycerides |
| WO2006007925A1 (en) * | 2004-07-20 | 2006-01-26 | Unilever Plc | Mild, moisturizing sulfosuccinate cleansing compositions |
| WO2006007945A1 (en) * | 2004-07-20 | 2006-01-26 | Unilever Plc | Mild, moisturizing cleansing compositions |
| RU2380086C2 (en) * | 2004-07-20 | 2010-01-27 | Унилевер Н.В. | Soft, moistening sulfosuccinate cleaning compositions |
| CN1988877B (en) * | 2004-07-20 | 2010-06-16 | 荷兰联合利华有限公司 | mild moisturizing cleansing composition |
| WO2006058755A1 (en) * | 2004-12-04 | 2006-06-08 | Unilever Plc | Shampoo compositions containing cationic polymer and an anionic surfactant mixture |
| EP1951039B1 (en) * | 2005-11-14 | 2015-02-25 | Solvay USA Inc. | Agricultural adjuvant compositions, pesticide compositions, and methods for using such compositions |
| EP2617805A1 (en) * | 2012-01-23 | 2013-07-24 | Kao Corporation, S.A. | Alkaline cleaning compositions for non-horizontal surfaces |
| WO2013110551A1 (en) | 2012-01-23 | 2013-08-01 | Kao Corporation S.A. | Alkaline cleaning compositions for non-horizontal surfaces |
| US9611448B2 (en) | 2012-01-23 | 2017-04-04 | Kao Corporation, S.A. | Alkaline cleaning compositions for non-horizontal surfaces |
| GB2571414A (en) * | 2017-12-20 | 2019-08-28 | Henkel Kgaa | Toning shampoo with improved colour performance |
| US10639262B2 (en) | 2017-12-20 | 2020-05-05 | Henkel Ag & Co. Kgaa | Toning shampoo with improved colour performance |
| GB2571414B (en) * | 2017-12-20 | 2022-10-12 | Henkel Ag & Co Kgaa | Toning shampoo with improved colour performance |
| DE102017223419B4 (en) * | 2017-12-20 | 2025-05-22 | Henkel Ag & Co. Kgaa | Tinting shampoo with improved coloring performance |
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