DE19858933A1 - Water- and dirt-repellent coating for glass, e.g. window, metal, plastics or other heat-resistant material is produced by flame coating with silicon tetrafluoride and/or titanium tetrachloride in e.g. natural gas oxygen flame - Google Patents
Water- and dirt-repellent coating for glass, e.g. window, metal, plastics or other heat-resistant material is produced by flame coating with silicon tetrafluoride and/or titanium tetrachloride in e.g. natural gas oxygen flameInfo
- Publication number
- DE19858933A1 DE19858933A1 DE1998158933 DE19858933A DE19858933A1 DE 19858933 A1 DE19858933 A1 DE 19858933A1 DE 1998158933 DE1998158933 DE 1998158933 DE 19858933 A DE19858933 A DE 19858933A DE 19858933 A1 DE19858933 A1 DE 19858933A1
- Authority
- DE
- Germany
- Prior art keywords
- coating
- flame
- water
- dirt
- oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000011248 coating agent Substances 0.000 title claims abstract description 22
- 238000000576 coating method Methods 0.000 title claims abstract description 22
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 239000001301 oxygen Substances 0.000 title claims abstract description 9
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 9
- ABTOQLMXBSRXSM-UHFFFAOYSA-N silicon tetrafluoride Chemical compound F[Si](F)(F)F ABTOQLMXBSRXSM-UHFFFAOYSA-N 0.000 title claims abstract description 8
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 title claims abstract description 7
- 239000003345 natural gas Substances 0.000 title claims abstract description 6
- 239000011521 glass Substances 0.000 title claims abstract description 5
- 229910052751 metal Inorganic materials 0.000 title claims abstract 4
- 239000002184 metal Substances 0.000 title claims abstract 4
- 239000004033 plastic Substances 0.000 title claims abstract 4
- 229920003023 plastic Polymers 0.000 title claims abstract 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims description 5
- 239000005871 repellent Substances 0.000 title abstract description 4
- 239000003779 heat-resistant material Substances 0.000 title abstract 3
- -1 window Substances 0.000 title 1
- 239000007800 oxidant agent Substances 0.000 claims abstract description 6
- 239000007788 liquid Substances 0.000 claims abstract description 3
- 239000002245 particle Substances 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims abstract 5
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract 3
- 229930195733 hydrocarbon Natural products 0.000 claims abstract 3
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract 3
- 150000002739 metals Chemical class 0.000 claims abstract 3
- 230000001590 oxidative effect Effects 0.000 claims abstract 3
- 239000005368 silicate glass Substances 0.000 claims abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 3
- 239000004071 soot Substances 0.000 claims description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims 1
- 235000011941 Tilia x europaea Nutrition 0.000 claims 1
- 239000004744 fabric Substances 0.000 claims 1
- 239000004571 lime Substances 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 3
- 230000001699 photocatalysis Effects 0.000 abstract description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 4
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 229910004014 SiF4 Inorganic materials 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910003074 TiCl4 Inorganic materials 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 235000012907 honey Nutrition 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1618—Non-macromolecular compounds inorganic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
- C03C17/245—Oxides by deposition from the vapour phase
- C03C17/2456—Coating containing TiO2
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
- C03C17/3417—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials all coatings being oxide coatings
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
- B05D1/08—Flame spraying
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/212—TiO2
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/23—Mixtures
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/71—Photocatalytic coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
- C03C2218/152—Deposition methods from the vapour phase by cvd
Landscapes
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Wood Science & Technology (AREA)
- Surface Treatment Of Glass (AREA)
- Catalysts (AREA)
Abstract
Water- and dirt-repellent coating for glass, metals, plastics and other materials is produced by flame coating using silicon tetrafluoride and/or titanium tetrachloride in a natural gas/oxygen, methane/oxygen or other hydrocarbon/oxidant flame and has an extremely rough microscopic surface structure. It is suitable for almost all heat-resistant materials and makes window cleaning unnecessary. Water- and dirt-repellent coating for glass, metals, plastics and other materials is produced by flame coating using silicon tetrafluoride (SiF4) and/or titanium tetrachloride (TiCl4) in a natural gas/oxygen, methane/oxygen or other hydrocarbon/oxidant flame and has an extremely rough microscopic surface structure. It is suitable for almost all heat-resistant materials; cannot be wetted by liquid; causes photocatalytic decomposition if particles of dirt stick to the surface; forms a firm bond with various silicate glasses, so that it very durable; and makes window cleaning unnecessary.
Description
Es ist allgemein bekannt, daß es umweltschädigend, teuer und oft umständlich ist Fensterscheiben, Fassaden, Autos und sonstige Dinge ständig reinigen zu müssen.It is well known that it is harmful to the environment, expensive and often cumbersome Always having to clean window panes, facades, cars and other things.
Der im Patentanspruch 1 aufgeführten Erfindung liegt das Problem zugrunde, die fortwährende Verschmutzung von Fensterscheiben, Fassaden, Autos und anderen Dingen zu unterbinden und das ständige Reinigen solcher Dinge zu unterbinden.The invention listed in claim 1 is based on the problem, the ongoing To prevent and prevent pollution of window panes, facades, cars and other things to prevent the constant cleaning of such things.
Dieses Problem wird durch die im Patentanspruch 1 aufgeführten Merkmale gelöst.This problem is solved by the features listed in claim 1.
Die mit der Erfindung erzielten Vorteile bestehen insbesondere darin, das mit der Beschichtung versehene Dinge nicht mehr so oft gereinigt zu werden brauchen, das viele Flüssigkeiten wie Wasser, Zuckerlösung, Honig, Papierkleber auf Wasserbasis usw. die beschichtete Oberfläche nicht mehr benetzen können sondern einfach an ihr abrutschen. Ein weiterer Vorteil der Erfindung ist es, dass sofern es sich um eine solche Beschichtung handelt, welche mit einer TiCl4-SiF4-Methan-Gemisch/Sauerstoff-Flamme hergestellt wurde, eventuell anhaftende Ruß und Schadstoffpartikel unter Einfluß der Sonne und Luftfeuchtigkeit durch das so in der Beschichtung enthaltene TiO2 photokatalytisch zersetzt werden.The advantages achieved with the invention are in particular that things with the coating no longer need to be cleaned as often, that many liquids such as water, sugar solution, honey, water-based paper glue etc. the can no longer wet coated surface but simply slide off it. On Another advantage of the invention is that if such a coating is involved, which was produced with a TiCl4-SiF4-methane mixture / oxygen flame, possibly adhering soot and pollutant particles under the influence of the sun and humidity through the TiO2 contained in the coating can be decomposed photocatalytically.
Eine vorteilhafte Ausgestaltung der Erfindung ist in Patentanspruch 2 angegeben. Eine Weiterbildung nach Patentanspruch 2 ermöglicht es, die Beschichtung auf das Trägermaterial abzustimmen und so eine verbesserte Haftung zu erreichen.An advantageous embodiment of the invention is specified in claim 2. A Further development according to claim 2 enables the coating on the carrier material to coordinate and thus achieve improved liability.
Ein Ausführungsbeispiel ist im folgenden dargestellt:
Einem Gebläsebrenner wird Erdgas(Methan) mit einem Anteil von ca. 10% SiF4
(Siliciumtetraluorid) und als Oxidationsmittel Sauerstoff zugeführt, so dass er mit kräftiger
Flamme brennt. Nun wird die Flamme auf eine Ceran- oder Glasplatte gerichtet und so auf ihr hin
und her geschwenkt dass eine gleichmäßige dünne Beschichtung entsteht. Die so erhaltene
beschichtete Platte wird langsam abgekühlt und zeigt fortan auf der beschichteten Fläche das für
die Beschichtung typische wasserabweisende Verhalten.An exemplary embodiment is shown below:
Natural gas (methane) with a share of approx. 10% SiF4 (silicon tetraluoride) and oxygen as an oxidizing agent are fed into a forced draft burner so that it burns with a strong flame. Now the flame is directed onto a ceramic or glass plate and swung back and forth on it so that an even, thin coating is created. The coated plate thus obtained is slowly cooled and from then on shows the water-repellent behavior typical of the coating on the coated surface.
Werden dem Erdgas neben SiF4 auch noch 2-5% TiCl4-Dampf zugesetzt, zeigt die Beschichtung auch schon beschriebene photokatalytische Verhalten.If 2-5% TiCl4 vapor is also added to the natural gas in addition to SiF4, the coating also shows the photocatalytic behavior already described.
Claims (2)
dass sich nahezu alle hitzebeständigen Stoffe beschichten lassen, dadurch gekennzeichnet,
dass sich die beschichteten Materialien nicht mehr mit Flüssigkeit benetzen lassen, dadurch gekennzeichnet,
dass wenn es Schmutzpartikeln gelingen sollte anzuhaften, sie an der Oberfläche photokatalytisch zersetzt werden, dadurch gekennzeichnet,
dass die Beschichtung eine feste Bindung mit verschiedenen silikatischen Gläsern eingeht, welche die Beschichtung besonders haltbar macht, dadurch gekennzeichnet,
dass mit der Beschichtung versehene Fensterscheiben nicht mehr gereinigt zu werden brauchen, da Wasser und darin gelöster "Kalk" und Schmutz wie Ruß nicht mehr anhaften können, bzw. photokatalytisch zersetzt werden, dadurch gekennzeichnet,
dass die Beschichtung aus Siliciumtetrafluorid (SiF-4) und/oder Titaniumtetrachlorid (TiCl4) in einer Erdgas/Sauerstoff oder Methan/Sauerstoff oder einer anderen Kohlenwasserstoff/Oxidationsmittelflamme hergestellt wird und so auch mit Hilfe jener Flamme auf das zu beschichtende Material aufgetragen wird, des weiteren dadurch gekennzeichnet,
dass die Oberfläche der Beschichtung in der mikroskopischen Struktur eine extrem rauhe Oberfläche aufweist,1. Coating for a wide variety of glasses, metals, plastics and other materials which, after coating, can no longer be wetted with water but repel the water and can no longer contaminate, characterized in that
that almost all heat-resistant fabrics can be coated, characterized in that
that the coated materials can no longer be wetted with liquid, characterized in that
that if dirt particles succeed in adhering, they are photocatalytically decomposed on the surface, characterized in that
that the coating forms a firm bond with various silicate glasses, which makes the coating particularly durable, characterized in that
that window panes provided with the coating no longer need to be cleaned, since water and "lime" and dirt such as soot dissolved in them can no longer adhere or are photocatalytically decomposed, characterized in that
that the coating of silicon tetrafluoride (SiF-4) and / or titanium tetrachloride (TiCl4) is produced in a natural gas / oxygen or methane / oxygen or another hydrocarbon / oxidizing agent flame and is thus also applied to the material to be coated with the aid of that flame further characterized by
that the surface of the coating has an extremely rough surface in the microscopic structure,
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1998158933 DE19858933A1 (en) | 1998-12-08 | 1998-12-08 | Water- and dirt-repellent coating for glass, e.g. window, metal, plastics or other heat-resistant material is produced by flame coating with silicon tetrafluoride and/or titanium tetrachloride in e.g. natural gas oxygen flame |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1998158933 DE19858933A1 (en) | 1998-12-08 | 1998-12-08 | Water- and dirt-repellent coating for glass, e.g. window, metal, plastics or other heat-resistant material is produced by flame coating with silicon tetrafluoride and/or titanium tetrachloride in e.g. natural gas oxygen flame |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE19858933A1 true DE19858933A1 (en) | 2000-06-15 |
Family
ID=7891889
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1998158933 Ceased DE19858933A1 (en) | 1998-12-08 | 1998-12-08 | Water- and dirt-repellent coating for glass, e.g. window, metal, plastics or other heat-resistant material is produced by flame coating with silicon tetrafluoride and/or titanium tetrachloride in e.g. natural gas oxygen flame |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE19858933A1 (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1205243A1 (en) * | 2000-11-09 | 2002-05-15 | Neomat S.A. | Preparation of firmly-anchored photocatalitically-active titanium dioxide coating films with non-gelled organic-doped precursors |
| WO2006048276A1 (en) | 2004-11-03 | 2006-05-11 | Schott Ag | Object comprising a barrier coating, and method for the production of such an object |
| WO2006030250A3 (en) * | 2004-09-14 | 2007-08-16 | Millennium Chemicals Inc | Composition useful for providing nox removing coating on material surface |
| EP1870387A1 (en) * | 2006-06-23 | 2007-12-26 | Verein zur Förderung von Innovationen durch Forschung, Entwicklung und Technologietransfer e.V. (Verein INNOVENT e.V.) | Method for modifying the surface properties of glass |
| WO2013014423A1 (en) * | 2011-07-22 | 2013-01-31 | Pilkington Group Limited | Deposition process |
| US9126145B2 (en) | 2007-08-31 | 2015-09-08 | Cristal USA, Inc. | Photocatalytic coating |
| US9228095B2 (en) | 2006-10-18 | 2016-01-05 | Cristal Usa Inc. | Photocatalytically active polysiloxane coating compositions |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3801111A1 (en) * | 1988-01-16 | 1989-07-27 | Asendorf Abwasser Anlagen Gmbh | Process for curing and conditioning glass surfaces |
| EP0497189A2 (en) * | 1991-01-23 | 1992-08-05 | Matsushita Electric Industrial Co., Ltd. | Water- and oil-repelling absorbed film and method of manufacturing the same |
| DE19708260A1 (en) * | 1996-03-01 | 1997-11-06 | Mitsubishi Paper Mills Ltd | Water-resistant photo-reactive agent for removing pollutants over long period |
-
1998
- 1998-12-08 DE DE1998158933 patent/DE19858933A1/en not_active Ceased
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3801111A1 (en) * | 1988-01-16 | 1989-07-27 | Asendorf Abwasser Anlagen Gmbh | Process for curing and conditioning glass surfaces |
| EP0497189A2 (en) * | 1991-01-23 | 1992-08-05 | Matsushita Electric Industrial Co., Ltd. | Water- and oil-repelling absorbed film and method of manufacturing the same |
| DE19708260A1 (en) * | 1996-03-01 | 1997-11-06 | Mitsubishi Paper Mills Ltd | Water-resistant photo-reactive agent for removing pollutants over long period |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1205243A1 (en) * | 2000-11-09 | 2002-05-15 | Neomat S.A. | Preparation of firmly-anchored photocatalitically-active titanium dioxide coating films with non-gelled organic-doped precursors |
| WO2002038272A1 (en) * | 2000-11-09 | 2002-05-16 | Neomat S.A. | Preparation of firmly-anchored photocatalitically-active titanium dioxide coating films with non-gelled organic-doped precursors |
| WO2006030250A3 (en) * | 2004-09-14 | 2007-08-16 | Millennium Chemicals Inc | Composition useful for providing nox removing coating on material surface |
| WO2006048276A1 (en) | 2004-11-03 | 2006-05-11 | Schott Ag | Object comprising a barrier coating, and method for the production of such an object |
| JP2008518800A (en) * | 2004-11-03 | 2008-06-05 | ショット アクチエンゲゼルシャフト | Articles with barrier coatings and methods for making such articles |
| CN101151223B (en) * | 2004-11-03 | 2012-11-21 | 肖特股份公司 | Object comprising barrier coating and method of making same |
| EP1870387A1 (en) * | 2006-06-23 | 2007-12-26 | Verein zur Förderung von Innovationen durch Forschung, Entwicklung und Technologietransfer e.V. (Verein INNOVENT e.V.) | Method for modifying the surface properties of glass |
| US9228095B2 (en) | 2006-10-18 | 2016-01-05 | Cristal Usa Inc. | Photocatalytically active polysiloxane coating compositions |
| US9126145B2 (en) | 2007-08-31 | 2015-09-08 | Cristal USA, Inc. | Photocatalytic coating |
| US9358502B2 (en) | 2007-08-31 | 2016-06-07 | Cristal Usa Inc. | Photocatalytic coating |
| WO2013014423A1 (en) * | 2011-07-22 | 2013-01-31 | Pilkington Group Limited | Deposition process |
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