DE19745964A1 - Self-foaming instant shampoo, especially packaged in effervescent tablet etc. form - Google Patents
Self-foaming instant shampoo, especially packaged in effervescent tablet etc. formInfo
- Publication number
- DE19745964A1 DE19745964A1 DE19745964A DE19745964A DE19745964A1 DE 19745964 A1 DE19745964 A1 DE 19745964A1 DE 19745964 A DE19745964 A DE 19745964A DE 19745964 A DE19745964 A DE 19745964A DE 19745964 A1 DE19745964 A1 DE 19745964A1
- Authority
- DE
- Germany
- Prior art keywords
- shampoo
- preparation according
- shampoo preparation
- water
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000002453 shampoo Substances 0.000 title claims abstract description 44
- 238000005187 foaming Methods 0.000 title claims abstract description 8
- 239000007938 effervescent tablet Substances 0.000 title claims abstract description 7
- 239000003599 detergent Substances 0.000 claims abstract description 14
- 239000000945 filler Substances 0.000 claims abstract description 9
- 239000004094 surface-active agent Substances 0.000 claims abstract description 7
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
- 239000007787 solid Substances 0.000 claims abstract description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims abstract description 5
- 239000000843 powder Substances 0.000 claims abstract description 5
- 125000002091 cationic group Chemical group 0.000 claims abstract description 4
- 125000000129 anionic group Chemical group 0.000 claims abstract description 3
- 239000011230 binding agent Substances 0.000 claims abstract description 3
- 150000001875 compounds Chemical class 0.000 claims abstract description 3
- 239000006260 foam Substances 0.000 claims abstract description 3
- 239000000490 cosmetic additive Substances 0.000 claims abstract 2
- 238000002360 preparation method Methods 0.000 claims description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 4
- 150000007513 acids Chemical class 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 208000001840 Dandruff Diseases 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 239000003205 fragrance Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 239000007884 disintegrant Substances 0.000 claims 1
- 239000007911 effervescent powder Substances 0.000 claims 1
- 239000005022 packaging material Substances 0.000 claims 1
- 239000002304 perfume Substances 0.000 abstract description 7
- 239000004615 ingredient Substances 0.000 abstract description 4
- 239000000654 additive Substances 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 10
- -1 alkyl succinates Chemical class 0.000 description 9
- 239000003826 tablet Substances 0.000 description 9
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 8
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 8
- 229960003237 betaine Drugs 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- AUXDELGSSOCKOS-UHFFFAOYSA-N C(CCC(=O)[O-])(=O)OCCCCCCCCCCCC.[NH4+] Chemical compound C(CCC(=O)[O-])(=O)OCCCCCCCCCCCC.[NH4+] AUXDELGSSOCKOS-UHFFFAOYSA-N 0.000 description 6
- 235000013162 Cocos nucifera Nutrition 0.000 description 6
- 244000060011 Cocos nucifera Species 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 5
- QTDIEDOANJISNP-UHFFFAOYSA-N 2-dodecoxyethyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOCCOS(O)(=O)=O QTDIEDOANJISNP-UHFFFAOYSA-N 0.000 description 4
- MRUAUOIMASANKQ-UHFFFAOYSA-O carboxymethyl-[3-(dodecanoylamino)propyl]-dimethylazanium Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC(O)=O MRUAUOIMASANKQ-UHFFFAOYSA-O 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 229940075468 lauramidopropyl betaine Drugs 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 4
- 235000017557 sodium bicarbonate Nutrition 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 229960004106 citric acid Drugs 0.000 description 3
- 229940079886 disodium lauryl sulfosuccinate Drugs 0.000 description 3
- KHIQYZGEUSTKSB-UHFFFAOYSA-L disodium;4-dodecoxy-4-oxo-3-sulfobutanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O.CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O KHIQYZGEUSTKSB-UHFFFAOYSA-L 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 239000011975 tartaric acid Substances 0.000 description 3
- 235000002906 tartaric acid Nutrition 0.000 description 3
- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 2
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 2
- 239000001099 ammonium carbonate Substances 0.000 description 2
- STIAPHVBRDNOAJ-UHFFFAOYSA-N carbamimidoylazanium;carbonate Chemical compound NC(N)=N.NC(N)=N.OC(O)=O STIAPHVBRDNOAJ-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- GHOKWGTUZJEAQD-UHFFFAOYSA-N Chick antidermatitis factor Natural products OCC(C)(C)C(O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical class OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 239000004141 Sodium laurylsulphate Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- KZSNJWFQEVHDMF-UHFFFAOYSA-N Valine Chemical compound CC(C)C(N)C(O)=O KZSNJWFQEVHDMF-UHFFFAOYSA-N 0.000 description 1
- JXXCENBLGFBQJM-FYZOBXCZSA-N [(2r)-3-carboxy-2-hydroxypropyl]-trimethylazanium;chloride Chemical compound [Cl-].C[N+](C)(C)C[C@H](O)CC(O)=O JXXCENBLGFBQJM-FYZOBXCZSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 1
- 229960004543 anhydrous citric acid Drugs 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- LGBHQFWRSMFRJF-UHFFFAOYSA-N butanedioic acid;oxalic acid Chemical compound OC(=O)C(O)=O.OC(=O)CCC(O)=O LGBHQFWRSMFRJF-UHFFFAOYSA-N 0.000 description 1
- 210000001217 buttock Anatomy 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 229940107161 cholesterol Drugs 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000002354 daily effect Effects 0.000 description 1
- HXCKLNOIRVJXHN-UHFFFAOYSA-N diazanium dodecanoic acid sulfate Chemical compound C(CCCCCCCCCCC)(=O)O.S(=O)(=O)([O-])[O-].[NH4+].[NH4+] HXCKLNOIRVJXHN-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229960001484 edetic acid Drugs 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000004872 foam stabilizing agent Substances 0.000 description 1
- 229940083122 ganglion-blocking antiandrenergic bisquaternary ammonium compound Drugs 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- XTEYYMUHIGUNIC-UHFFFAOYSA-N n-methylhexadecan-1-amine;hydrochloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[NH2+]C XTEYYMUHIGUNIC-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 229940055726 pantothenic acid Drugs 0.000 description 1
- 235000019161 pantothenic acid Nutrition 0.000 description 1
- 239000011713 pantothenic acid Substances 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 229950001046 piroctone Drugs 0.000 description 1
- BTSZTGGZJQFALU-UHFFFAOYSA-N piroctone olamine Chemical compound NCCO.CC(C)(C)CC(C)CC1=CC(C)=CC(=O)N1O BTSZTGGZJQFALU-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229940068918 polyethylene glycol 400 Drugs 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 229940079776 sodium cocoyl isethionate Drugs 0.000 description 1
- BCISDMIQYBCHAT-UHFFFAOYSA-M sodium;2-(dodecanoylamino)ethanesulfonate Chemical compound [Na+].CCCCCCCCCCCC(=O)NCCS([O-])(=O)=O BCISDMIQYBCHAT-UHFFFAOYSA-M 0.000 description 1
- BCMWYYCCTCFRMH-UHFFFAOYSA-M sodium;4-dodecoxy-4-oxobutanoate Chemical compound [Na+].CCCCCCCCCCCCOC(=O)CCC([O-])=O BCMWYYCCTCFRMH-UHFFFAOYSA-M 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- FXZUKHDLJABRQU-UHFFFAOYSA-N sulfuric acid;1-tetradecoxytetradecane Chemical compound OS(O)(=O)=O.CCCCCCCCCCCCCCOCCCCCCCCCCCCCC FXZUKHDLJABRQU-UHFFFAOYSA-N 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- WWOFRRCIVMFEDS-UHFFFAOYSA-N zinc;pyridine Chemical compound [Zn+2].C1=CC=NC=C1.C1=CC=NC=C1.C1=CC=NC=C1.C1=CC=NC=C1 WWOFRRCIVMFEDS-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0052—Gas evolving or heat producing compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/22—Gas releasing
- A61K2800/222—Effervescent
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Abstract
Description
Gegenstand der Erfindung ist eine selbstschäumende Instant shampoo-Zubereitung, die aus trockenen, wasserlöslichen Bestandteilen zusammengesetzt ist.The invention relates to a self-foaming instant shampoo preparation made from dry, water-soluble Components is composed.
Es ist bekannt, daß zur schonenden, pflegenden Reinigung menschlicher und tierischer Haare die ursprünglich genutzten Alkaliseifen nahezu vollständig durch vorgefertigte Tensidlö sungen (Shampoos) unterschiedlicher Zusammensetzung verdrängt worden sind. Dabei konnte die Waschleistung erhöht, die Pflege gesteigert und die Verträglichkeit für Haut und Haar drastisch verbessert werden. Andererseits stieg damit der Transport- und Verpackungsaufwand: Während konventionelle Seifen einen Anteil an Trockenmasse von etwa 90% aufweisen, bestehen Shampoos zum überwiegenden Teil aus Wasser. So können Seifen unverpackt oder in einfachen Papierhüllen verkauft werden, wogegen für Shampoos flüssigkeitsresistente Behälter notwendig sind. Normalerweise ist der durch den hohen Wasseranteil verursachte Transport- und Verpackungsaufwand ohne Belang oder recht fertigt sich durch beträchtliche anwendungstechnische Vorteile.It is known that for gentle, caring cleaning human and animal hair the originally used Alkali soaps almost completely thanks to ready-made surfactant solutions sungen (shampoos) of different compositions are displaced have been. The washing performance could be increased, the care increased and the tolerance for skin and hair drastically be improved. On the other hand, the transport and Packaging effort: While conventional soaps have a share about 90% dry matter, there are shampoos for predominantly from water. So soaps can be unwrapped or in simple paper sleeves, whereas for Shampoos in liquid-resistant containers are necessary. Usually this is caused by the high water content Transport and packaging effort irrelevant or right manufactures itself through considerable application engineering Advantages.
In speziellen Fällen kann jedoch vor allem der Transport aufwand von Bedeutung sein: Auf Reisen stehen in der Regel keine unbegrenzten Volumina und Gewichtskapazitäten zur Verfügung; deshalb kann es vorteilhaft sein, die Gegenstände des täglichen Bedarfs in möglichst handlicher Form mit sich zu führen. So muß bei mehrtägiger Rucksackwanderung, Rad- oder Tramptouren jede Möglichkeit zur Einsparung von Gewicht oder Volumen beim Gepäck genutzt werden. Auch bei Flugreisen ist das Gewicht des Gepäcks begrenzt. Selbst für den täglichen Einkauf zu Fuß kann das Gewicht der erworbenen Produkte von Interesse sein. Deshalb sind Reinigungsmittel für Haut und Haare sehr begehrt, die die gewohnte volle Leistung erfüllen, aber ohne großen Wasserballast auskommen. Eine weitere Volumen- und Gewichtsersparnis kommt dann auch noch durch die Reduzie rung des Verpackungsaufwandes in qualitativer und quantitati ver Hinsicht zum Tragen.In special cases, however, it is mainly the transport Effort can be important: When traveling, there are usually no unlimited volumes and weight capacities Disposal; therefore it can be beneficial to use the items of daily needs in as handy a form as possible respectively. So you have to go backpacking, cycling or hiking for several days Hitchhiking tours every opportunity to save weight or Volume can be used for luggage. Even when traveling by air limits the weight of luggage. Even for everyday Shopping on foot can increase the weight of the products purchased by Be interested. That is why cleansers are for skin and Hair is in great demand, which fulfills the usual full performance, but manage without large water ballast. Another volume and weight savings also come from the reduction tion of the packaging effort in qualitative and quantitative terms ver ways to bear.
Ein zusätzlicher Nachteil des hohen Wassergehalts konventio nell zusammengesetzter Shampoos ist die Notwendigkeit der Konservierung. Bei ständig steigender Allergieanfälligkeit und zunehmend kritischer Verbraucherhaltung gegenüber den Inhaltsstoffen von Kosmetika stoßen die an sich dringend erforderlichen Konservierungsmittel immer stärker auf Ablehnung.An additional disadvantage of the high water content is conventional Well-formulated shampoos is the need of the Preservation. With constantly increasing susceptibility to allergies and increasingly critical consumer attitudes towards the The ingredients of cosmetics come across them urgently the necessary preservatives Rejection.
Schließlich ist auch zu beachten, daß in konventionelle Shampoos nur hydrolysebeständige Inhaltsstoffe eingearbeitet werden können, die in dem stark wäßrigen Medium und bei dem schwach sauren pH-Wert üblicher Shampoos stabil sind. So ist trotz mancher guter Gebrauchseigenschaften bisher die Anwendbarkeit von Estern in Shampoos beschränkt.Finally, it should also be noted that in conventional Shampoos only incorporate hydrolysis-resistant ingredients can be used in the highly aqueous medium and in the weakly acidic pH value of common shampoos are stable. So is despite some good usage properties so far the The applicability of esters in shampoos is limited.
Der vorliegenden Erfindung liegt deshalb die Aufgabe zugrunde, Shampoozubereitungen in trockener Form zur Verfügung zu stellen, die bei Wasserzugabe aufschäumen und dann unmittelbar zur Haarwäsche eingesetzt werden können.The present invention is therefore based on the object Shampoo preparations are available in dry form too that foam up when water is added and then immediately can be used for shampooing.
Diese Aufgabe wird durch eine selbstschäumende Instantshampoo-
Zubereitung gelöst, die
ein pulverförmig vorliegendes Tensid,
eine feste, sauer reagierende Verbindung und
ein Carbonat oder Bicarbonat
in trockener, wasserlöslicher Form enthält. Vorteilhaft ist
dabei die Zubereitung in Einzelportionen zu verpacken , die
eine für eine einmalige Haarwäsche ausreichende Shampoomenge
ergeben.This object is achieved by a self-foaming instant shampoo preparation which
a powdered surfactant,
a solid, acidic compound and
a carbonate or bicarbonate
contains in dry, water-soluble form. It is advantageous to pack the preparation in individual portions, which result in an amount of shampoo that is sufficient for a single hair wash.
Für ein derartiges Instantshampoo eignen sich anionische, kationische, nichtionische oder amphotere Detergenzien oder Mischungen der genannten Detergenzien, sofern sie wasserlös lich sind.Anionic, cationic, nonionic or amphoteric detergents or Mixtures of the detergents mentioned, provided they are water-soluble are lich.
Die für die erfindungsgemäße Zubereitung besonders geeigneten anionischen Detergenzien umfassen sulfonierte und sulfatierte Alkyl-, Aralkyl- und Alkyaryldetergenzien, Alkylsuccinate, Alkylsulfosuccinate und N-Alkoylsarcosinate. Besonders bevorzugt, sind Natrium-, Magnesium-, Ammonium- und die Mono-, Di- und Triethanolaminsalze von Alkyl- und Aralkylsulfaten sowie entsprechende Salze von Alkarylsulfonaten. Die Alkyl gruppen der Detergenzien haben im allgemeinen 12 bis 21 Kohlenstoffatome und können ungesattigt, vorzugsweise aber gesättigt sein. Auch Alkyläthersulfate, die 1 bis 10 Ethylen oxid oder Propylenoxideinheiten pro Molekül enthalten, können für die erfindungsgemäße Shampoozubereitung eingesetzt werden.Those particularly suitable for the preparation according to the invention anionic detergents include sulfonated and sulfated Alkyl, aralkyl and alkylaryl detergents, alkyl succinates, Alkyl sulfosuccinates and N-alcoholic sarcosinates. Particularly preferred are sodium, magnesium, ammonium and the mono-, Di- and triethanolamine salts of alkyl and aralkyl sulfates and corresponding salts of alkaryl sulfonates. The alkyl groups of detergents generally have 12 to 21 Carbon atoms and can be unsaturated, but preferably be saturated. Also alkyl ether sulfates containing 1 to 10 ethylene oxide or propylene oxide units per molecule are used for the shampoo preparation according to the invention.
Typische geeignete anionische Detergenzien, die erfindungs gemäß eingesetzt werden können, sind Natriumlaurylsulfat, Natriumlauryläthersulfat, Ammoniumlaurylsulfat, Triethanola minlaurylsulfat, Natrium-(C14-16)- Olefinsulfonate, Natriummyristylethersulfat, Ammoniumlaurylethersulfat, Dinatriumlaurylsulfosuccinat, Ammoniumlaurylsulfosuccinat, Natriumdodecylbenzylsulfonat und Natrium-N-lauroylsarcosinat. Typical suitable anionic detergents which can be used according to the invention are sodium lauryl sulphate, sodium lauryl ether sulphate, ammonium lauryl sulphate, triethanola minlauryl sulphate, sodium (C 14-16 ) olefin sulphonates, sodium myristyl ether sulphate, ammonium lauryl succinate, ammonium lauryl succinate, ammonium lauryl succinate, ammonium lauric acid sulphate, ammonium lauryl succinate, ammonium lauryl succinate, sodium lauro succinate, ammonium lauryl succinate, sodium lauryl succinate, sodium llaurylsulphateylsulfate lauryl ether sulphate, ammonium lauryl ether sulphate, ammonium lauryl ether sulphate, sodium lauryl succinateyl,
Als kationische Detergenzien kommen monoquaternäre oder bisquaternäre Ammoniumverbindungen in Frage, die mindestens einen langkettigen aliphatischen Rest mit 10 bis 26 Kohlen stoffatomen tragen. Dieser langkettige aliphatische Rest kann eine Esterbindung (z. B. Do. . .betainesterchlorid) oder einer Amidbindung enthalten. Ganz besonders bevorzugt ist das Hexadecylmethylammoniumchlorid.The cationic detergents used are monoquaternary or bisquaternary ammonium compounds in question, at least a long-chain aliphatic radical with 10 to 26 carbons carry material atoms. This long-chain aliphatic residue can an ester bond (e.g. Do.... betaine ester chloride) or a Amide bond included. This is particularly preferred Hexadecylmethylammonium chloride.
Als nicht-ionische Detergenzien können Kondensationsprodukte aus Ethylenoxid oder Propylenoxid mit einem langkettigen Alkohol, einem langkettigen Amin oder einer langkettigen Carbonsäure eingesetzt werden, sofern sie nicht flüssig sind. Dabei umfaßt die aliphatische Kohlenstoffkette in der Regel 8 bis 20 Kohlenstoffatome und kann mit mit 5 bis 20 Ethylen oxid- oder Propylenoxideinheiten kondensiert sein. Als nicht ionische Detergentien können auch Alkylpolyglykoside mit 8 bis 14 Kohlenstoffen in der Alkylkette eingesetzt werden, u.b. Laurylpolyclucose.Condensation products can be used as non-ionic detergents from ethylene oxide or propylene oxide with a long chain Alcohol, a long chain amine, or a long chain one Carboxylic acid can be used, provided they are not liquid. The aliphatic carbon chain usually includes 8 to 20 carbon atoms and can match with 5 to 20 ethylene oxide or propylene oxide units be condensed. Than not Ionic detergents can also be alkyl polyglycosides with 8 to 14 carbons are used in the alkyl chain, u.b. Lauryl polycucose.
Als amphotere Detergenzien werden vor allem Betaine einge setzt, die lange Alkylgruppen tragen. Hierzu gehören das Cocosdimethyl-carboxymethylbetain, das Lauryldimethyl carboxymethylbetain, das Lauryldimethyl-α-carboxyethylbetain, das Cetyldimethyl-carboxymethylbetain, aber auch Sulfobetaine, wie das Cocosdimethyl-sufodimethylbetain, und Amido- und Amidosulfobetaine. Die Carboxybetaine und die Amidobetaine werden erfindungsgemäß besonders bevorzugt. Spezielle Beispiele hierfür sind das Cocosamidopropylbetain, das Lauramidopropylbetain, das Myristyl-amidopropylbetain und Mischungen der genannten Verbindungen.Betaines are mainly used as amphoteric detergents sets that carry long alkyl groups. This includes that Coconut dimethyl carboxymethyl betaine, lauryl dimethyl carboxymethyl betaine, lauryldimethyl-α-carboxyethyl betaine, the cetyldimethyl-carboxymethylbetaine, but also sulfobetaines, like the coconut dimethyl sufodimethyl betaine, and amido and Amidosulfobetaines. The carboxy betaines and the amido betaines are particularly preferred according to the invention. Specific Examples of this are cocamidopropyl betaine, the Lauramidopropyl betaine, myristyl amidopropyl betaine and Mixtures of the compounds mentioned.
Als feste, sauer reagierende Verbindung können in der erfindungsgemäßen Instantshampoo-Zubereitung Carbonsäuren wie Zitronensäure, Weinsäure, Äpfelsäure, Bernsteinsäure oder Oxalsäure, aber auch sauer reagierende anorganische Verbindun gen wie Hydrogensulfate, Dihydrogenphosphate, Borsäure, oder Amidoschwefelsäure eingesetzt werden.As a solid, acidic compound, the instant shampoo preparation according to the invention carboxylic acids such as Citric acid, tartaric acid, malic acid, or succinic acid Oxalic acid, but also acidic inorganic compounds gene such as hydrogen sulfates, dihydrogen phosphates, boric acid, or Amidosulfuric acid can be used.
Als Carbonat oder Bicarbonat haben sich vor allem Alkalicarbo nate, Alkalihydrogencarbonate, Erdalkalicarbonate, Erdalkali hydrogencarbonate, Ammoniumhydrogencarbonat aber auch orga nische Carbonate wie Guanidincarbonat bewährt.Alkali carbonate has proven to be the most common carbonate or bicarbonate nates, alkali hydrogen carbonates, alkaline earth carbonates, alkaline earth metals hydrogen carbonate, ammonium hydrogen carbonate but also orga niche carbonates such as guanidine carbonate have proven successful.
Zusätzlich zu den vorstehend genannten Bestandteilen kann die erfindungsgemäße, wasserfreie Instantshampoo-Zubereitung weitere übliche Zusatzstoffe enthalten.In addition to the ingredients mentioned above, the anhydrous instant shampoo preparation according to the invention contain other common additives.
Hierzu gehöre Pflegestoffe wie Betain, D,L-Valin, Cholesterin oder Pantothensäure sowie Antischuppenmittel, wie das unter dem Handelsnamen Octopirox bekannte Produkt oder Zinkpyridint hion, Duftstoffe wie Vanillin und Schaumstabilisatoren wie Aminoxyde oder Eiweiß-Festtsäurekondensate.These include care substances such as betaine, D, L-valine and cholesterol or pantothenic acid and anti-dandruff agents, such as the one below the product known under the trade name Octopirox or zinc pyridine hion, fragrances like vanillin and foam stabilizers like Amine oxides or solid protein acid condensates.
Außerdem können insbesondere bei der Herstellung der erfin dungsgemäßen Instantshampoo-Zubereitung als Brausetablette auch Hilfsstoffe zugesetzt werden, die auch bei der Her stellung von arzneiliche Wirkstoffe enthaltenden Brause tabletten eingesetzt werden. Hierbei handelt es sich um Bindemittel und Füllstoffe wie Talkum oder Stärke, Spreng mittel wie Natriumcarboxymethylcelullose, Gelatine oder Apfelpektin, aber auch um Zusatzstoffe, die bei Brause tabletten für perorale Anwendungen aus sensorischen Gründen nicht akzeptiert werden können, wie die Salze der Ethylen diamintetraessigsäure oder Betaine.In addition, especially in the production of the inven proper instant shampoo preparation as an effervescent tablet auxiliaries are also added, which are also used in the Her Positioning of effervescent containing medicinal substances tablets are used. This is Binders and fillers such as talc or starch, explosives agents such as sodium carboxymethylcelullose, gelatin or Apple pectin, but also additives that are used in effervescent tablets for oral use for sensory reasons cannot be accepted as the salts of ethylene diamine tetraacetic acid or betaine.
Die erfindungsgemäße wasserfreie Instantshampoo-Zubereitung kann als Pulver oder Granulat, vorzugsweise jedoch als gepreßte Brausetablette eingesetzt werden. Dabei empfiehlt sich eine portionsweise Verpackung in wasserabweisendem Papier oder in einer wasserunlöslichen Kunststoff- oder Alumini umfolie. Jede Verpackungseinheit enthält dabei einen aus reichende Menge der erfindungsgemäßen Instantshampoo-Zu bereitung, die für eine einmalige Haarwäsche ausreicht. Zur Anwendung wird eine Einzelportion mit etwa der gleichen Menge Wasser vermischt, wobei sich unter lebhaftem Aufschäumen in kürzester Zeit ein gebrauchsfertiger Shampoo bildet. Die Herstellung des gebrauchsfertigen Shampoos kann entweder in einer kleinen Schale, aber auch in der hohlen Hand erfolgen.The anhydrous instant shampoo preparation according to the invention can be as powder or granules, but preferably as Compressed effervescent tablet can be used. Here recommends packaged in portions in water-repellent paper or in a water-insoluble plastic or aluminum wrap around. Each packaging unit contains one from sufficient amount of the instant shampoo according to the invention preparation that is sufficient for a single hair wash. To the Application will be a single serving with approximately the same amount Water mixed, with vigorous foaming in A ready-to-use shampoo forms in a very short time. the Production of the ready-to-use shampoo can be done in either a small bowl, but also in the cupped hand.
Bei der erfindungsgemäßen Instantshampoo-Zubereitung handelt es sich nicht um einen Trockenshampoo, da auf den Zusatz von Wasser für den eigentlichen Waschvorgang nicht verzichtet werden kann. Es handelt sich somit hier um ein echtes Instantprodukt, das heißt um eine Zubereitung, die unmittelbar vor der Anwendung durch Wasserzugabe in den gebrauchsfertigen Zustand versetzt wird. Eine derartige Zubereitung ist nicht nur als vollwertiges Shampoo für den Reisenden gedacht, der an einem möglichst geringen Volumen und leichten Gewicht seines Gepäcks interessiert ist. Vielmehr ist das Prinzip der erfindungsgemäßen trockenen Instantshampoo-Zubereitung auch übertragbar auf andere Reinigungsmittel wie Duschbäder, Handgeschirrspülmittel, Haushaltsreiniger, Autoshampoos und WC-Reiniger.The instant shampoo preparation according to the invention is it is not a dry shampoo because of the addition of Water for the actual washing process is not dispensed with can be. So this is a real one Instant product, i.e. a preparation that is immediate before use by adding water to the ready-to-use State is shifted. Such a preparation is not only intended as a full-fledged shampoo for the traveler who the smallest possible volume and light weight interested in his luggage. Rather, the principle is the dry instant shampoo preparation according to the invention as well transferable to other cleaning agents such as shower baths, Hand dishwashing detergents, household cleaners, car shampoos and WC cleaner.
Um die für die praktische Anwendung wichtige schnelle Auflösung der Zubereitung in Wasser sicherzustellen, können die Shampoo-Tabletten auch äußerlich so gestaltet werden, daß eine besonderes hohe Auflösegeschwindigkeit erreicht wird. Diese kann durch eine Vergrößerung der Oberfläche der Tablette verbessert werden. Das kann beispielsweise dadurch erreicht werden, daß die Oberfläche der Tablette aufgerauht oder reliefartig geprägt ist oder - abweichend von der traditionel len Kreisscheibenform von Tabletten - ringförmig, eckig oder gitterförmig gestaltet ist. In order to achieve the fast Can ensure dissolution of the preparation in water the shampoo tablets are also designed externally so that a particularly high dissolving speed is achieved. This can be done by increasing the surface area of the tablet be improved. This can be achieved, for example be that the surface of the tablet is roughened or is embossed in relief or - deviating from tradition len circular disc shape of tablets - ring-shaped, angular or Is designed in a grid shape.
Die erfindungsgemäßen selbstschäumenden Shampoo-Zubereitungen in Pulver-, Granulat- oder Tablettenform werden durch die nachfolgenden Beispiele noch genauer beschrieben:The self-foaming shampoo preparations according to the invention in powder, granulate or tablet form are used by the The following examples are described in more detail:
Claims (9)
- - ein pulverförmig vorliegendes Tensid,
- - eine feste, sauer reagierende Verbindung und
- - ein Carbonat oder Bicarbonat
- - a surfactant in powder form,
- - a solid, acid reacting compound and
- - a carbonate or bicarbonate
- - 20-60 Gew.-% des pulverförmigen Tensids,
- - 5-30 Gew.-% der festen, sauer reagierenden Verbin dung und
- - 10-40 Gew.-% des Carbonats oder Bicarbonats enthält.
- - 20-60% by weight of the powdered surfactant,
- - 5-30% by weight of the solid, acidic compound and
- - Contains 10-40% by weight of the carbonate or bicarbonate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19745964A DE19745964A1 (en) | 1996-12-24 | 1997-10-17 | Self-foaming instant shampoo, especially packaged in effervescent tablet etc. form |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19654312 | 1996-12-24 | ||
| DE19745964A DE19745964A1 (en) | 1996-12-24 | 1997-10-17 | Self-foaming instant shampoo, especially packaged in effervescent tablet etc. form |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE19745964A1 true DE19745964A1 (en) | 1998-06-25 |
Family
ID=7816172
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19745964A Withdrawn DE19745964A1 (en) | 1996-12-24 | 1997-10-17 | Self-foaming instant shampoo, especially packaged in effervescent tablet etc. form |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE19745964A1 (en) |
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