DE19736509A1 - Titanium-alloyed, isotropic, earing-free, cold rolled strip steel is produced - Google Patents
Titanium-alloyed, isotropic, earing-free, cold rolled strip steel is producedInfo
- Publication number
- DE19736509A1 DE19736509A1 DE1997136509 DE19736509A DE19736509A1 DE 19736509 A1 DE19736509 A1 DE 19736509A1 DE 1997136509 DE1997136509 DE 1997136509 DE 19736509 A DE19736509 A DE 19736509A DE 19736509 A1 DE19736509 A1 DE 19736509A1
- Authority
- DE
- Germany
- Prior art keywords
- steel
- max
- cold
- rolling
- strip
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 25
- 239000010959 steel Substances 0.000 title claims abstract description 25
- 238000005097 cold rolling Methods 0.000 claims abstract description 7
- 238000005096 rolling process Methods 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 4
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 4
- 229910052799 carbon Inorganic materials 0.000 claims abstract 5
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract 5
- 238000000137 annealing Methods 0.000 claims abstract 3
- 229910052742 iron Inorganic materials 0.000 claims abstract 2
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 238000005098 hot rolling Methods 0.000 claims 2
- 238000001953 recrystallisation Methods 0.000 abstract description 3
- 238000005266 casting Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 7
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 229910001257 Nb alloy Inorganic materials 0.000 description 1
- 229910001275 Niobium-titanium Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- RJSRQTFBFAJJIL-UHFFFAOYSA-N niobium titanium Chemical compound [Ti].[Nb] RJSRQTFBFAJJIL-UHFFFAOYSA-N 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/04—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
- C21D8/0421—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the working steps
- C21D8/0426—Hot rolling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/22—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
- B21B1/24—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/04—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
- C21D8/0421—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the working steps
- C21D8/0436—Cold rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/04—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
- C21D8/0447—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the heat treatment
- C21D8/0473—Final recrystallisation annealing
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Sheet Steel (AREA)
Abstract
Description
Die Erfindung betrifft ein Verfahren zur Herstellung eines kaltgewalzten Ti-If- Bandstahles, wobei derartige Stähle und deren Zusammensetzung zum Stand der Technik gehören.The invention relates to a method for producing a cold-rolled Ti-If Steel strip, such steels and their composition to the state of the Technology belongs.
Kaltgewalztes Stahlband wird vielfach zur Herstellung von kaltumgeformten Erzeug nissen verwendet. Je nach Art des Umformverfahrens sind unterschiedliche Eigen schaften (Kennwerte) erforderlich.Cold rolled steel strip is widely used for the production of cold formed products nits used. Depending on the type of forming process, they are different properties (characteristic values) required.
Die steigenden Anforderungen bezüglich der Anwendungs- und Gebrauchseigen schaften bei niedrigen Herstellungskosten erfordern zunehmend noch bessere me chanische, insbesondere Umformeigenschaften. Eine gute Umformbarkeit ist ge kennzeichnet durch möglichst hohe, die Tiefziehbarkeit kennzeichnende r-Werte bei niedrigem Δr-Wert, hohe, die Streckziehbarkeit kennzeichnende n-Werte und hohe, die plane strain-Eigenschaften kennzeichnende Dehnungswerte.The increasing demands regarding the application and usage s at low production costs increasingly require better me Chanic, especially forming properties. Good formability is ge characterized by the highest possible r-values, which characterize the deep-drawability low Δr-value, high n-values characterizing the stretchability and high, elongation values characterizing the plane strain properties.
Es hat sich als vorteilhaft erwiesen, wenn die Umformeigenschaften in den verschie denen Richtungen, insbesondere in der Längs-, der Quer- und der Diagonalrichtung, möglichst gleich sind, d. h. weitgehend isotrop sind. Wenn diese Bedingung für den r-Wert zutrifft, bedeutet dies außerdem, daß der sog. Δr-Wert sehr klein ist, und nach dem Abpressen von rotationssymmetrischen Teilen weitgehende Freiheit von Zipfeln erreicht wird. Die Vorteile isotroper Eigenschaften drücken sich im wesentlichen in einer Gleichmäßigkeit des Stoffflusses und einer Reduzierung des Blechverschnitts aus. It has proven to be advantageous if the forming properties in the different which directions, in particular in the longitudinal, transverse and diagonal directions, are as equal as possible, d. H. are largely isotropic. If this condition for the If the r value applies, this also means that the so-called Δr value is very small, and after the pressing of rotationally symmetrical parts largely freedom from corners is achieved. The advantages of isotropic properties are essentially expressed a uniformity of the material flow and a reduction of the sheet waste out.
Auch gibt es seit längerer Zeit erfolgreiche Bemühungen zur Erzielung isotroper Ei genschaften. Beispiele hierfür sind zipfelfrei verformte Stähle, abgestreckte Geträn kedose (KHS) oder "B-faktor" von Fa. Brockhaus "Der Spiegel", Nr. 19/1966, S. 125. Dieser Herstellungsweg erfordert aber einen sehr hohen Kaltwalzgrad oder sogar eine normalisierende Glühung zur Einstellung der Zipfelfreiheit.There have also been successful efforts to achieve isotropic egg for a long time properties. Examples of this are steels deformed without tails, drawn drinks kedose (KHS) or "B-factor" from Brockhaus "Der Spiegel", No. 19/1966, p. 125. However, this production route requires a very high degree of cold rolling or even a normalizing glow to set the tip clearance.
In jüngster Zeit sind Beispiele von höherfesten Feinblechstählen zur Erzielung von Zipfelfreiheit aus DE-PS 38 03 064 und DE 195 47 181 C1 bekannt geworden. Auch wurde bereits in früheren Veröffentlichungen die positive Wirkung des Legierungse lementes Niob (Satoh, S. u. a.: Kawasaki, Techn. Rep. 8 (1983) S. 1, Stahl und Ei sen 110 (1990), Heft 9, S. 65-68) sowie einer Niob-Titan-Legierung (EP 0 108 268) bei If-Stählen bezüglich einer Verringerung des Δr-Wertes gezeigt.In recent times, examples of high strength sheet steel have been used to achieve Tip freedom from DE-PS 38 03 064 and DE 195 47 181 C1 become known. Also The positive effect of the alloy was already mentioned in previous publications elemental niobium (Satoh, S. et al .: Kawasaki, Techn. Rep. 8 (1983) S. 1, steel and egg sen 110 (1990), No. 9, pp. 65-68) and a niobium-titanium alloy (EP 0 108 268) in the case of If steels with regard to a reduction in the Δr value.
Es fehlte jedoch an einem Konzept zur Kaltbanderzeugung eines nur mit Titan legier
ten isotropen If-Stahles, welcher gegenüber einem mit Nb-legierten Stahl folgende
Vorteile aufweist.
However, there was a lack of a concept for cold strip production of an isotropic If steel only alloyed with titanium, which has the following advantages over an alloy with Nb alloy steel.
- - Niedrige Legierungskosten- Low alloy costs
- - Niedrige Rekristallisationstemperatur- Low recrystallization temperature
Hier setzt die vorliegende Erfindung mit den im Anspruch 1 angegebenen Merkma len ein. Nach der vorliegenden Erfindung wird eine niedrige Walztemperatur unter halb Ar3 mit einem bestimmten Haspeltemperaturbereich kombiniert. Überraschend ergaben sich hierdurch Eigenschaften und Merkmale, wie sie bislang für Ti-If-Stahl unbekannt waren.Here, the present invention uses the features specified in claim 1 len. According to the present invention, a low rolling temperature below half A r3 is combined with a certain reel temperature range. Surprisingly, this resulted in properties and features that were previously unknown for Ti-If steel.
Das erfindungsgemäße Verfahren läßt die Herstellung isotroper Bandstähle nicht nur nach dem Hauben-, sondern auch nach dem Durchlaufverfahren zu sowie die Vered lung im Schmelztauchverfahren. The process according to the invention not only allows the production of isotropic steel strips after the hood, but also according to the continuous process as well as the Vered development in the hot-dip process.
Einige Beispiele sollen das Ergebnis des erfindungsgemäßen Verfahrens verdeutli chen.Some examples are intended to illustrate the result of the method according to the invention chen.
In der Tabelle 1 ist die chemische Zusammensetzung des Stahles aufgeführt.Table 1 shows the chemical composition of the steel.
Tabelle 2 zeigt die Fertigungsbedingungen der Stahlbänder. Sie weisen die erfin dungsgemäße Eigenschaftskombination niedriger Walztemperatur in Kombination mit einem bestimmten Haspeltemperaturbereich aus.Table 2 shows the manufacturing conditions of the steel strips. You show the inventions combination of properties according to the invention low rolling temperature in combination with a certain reel temperature range.
In der Tabelle 3 sind die mechanischen Gütewerte und die Korngröße der Stähle von 70% kaltgewalztem Band aufgeführt.Table 3 shows the mechanical quality values and the grain size of the steels of 70% cold rolled strip.
In der Fig. 1 ist die Zipfelhöhe über dem Kaltwalzgrad für die durchlaufgeglühten Stähle und in Fig. 2 die für die haubengeglühten Stähle grafisch aufgetragen. Die Aufzeichnungen zeigen, daß sowohl bei den durchlaufgeglühten als auch bei den haubengeglühten Stählen bei Kaltwalzgraden zwischen rd. 40 und 80% zipfelarme Kaltbänder erzeugt wurden. Dabei war bei dem für die Kaltbandfertigung üblichen Kaltwalzgrad von rd. 70% die Zipfelhöhe aller Beispiele zipfelfrei.In Fig. 1 the tip height is plotted against the degree of cold rolling for the continuously annealed steels and in Fig. 2 that for the annealed steels. The records show that in the case of the continuous annealed as well as the annealed annealed steels at cold rolling grades between approx. 40 and 80% low-strip cold strips were produced. The usual degree of cold rolling of approx. 70% the tip height of all examples
Zudem ist den Fig. 1 und 2 zu entnehmen, daß eine abweichend von der Erfindung zu hohe (Nr. 1) oder zu niedrige (Nr. 5 u. 6) Haspeltemperatur eine hohe Zipfligkeit bewirkt. Dies unterstreicht das Erfordernis der erfindungsgemäßen Kombination von Walz- und Haspeltemperatur.It can also be seen from FIGS. 1 and 2 that a reel temperature which is too high (No. 1) or too low (No. 5 and 6), in deviation from the invention, results in a high degree of trickle. This underlines the requirement of the combination of rolling and coiling temperature according to the invention.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1997136509 DE19736509A1 (en) | 1997-08-22 | 1997-08-22 | Titanium-alloyed, isotropic, earing-free, cold rolled strip steel is produced |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1997136509 DE19736509A1 (en) | 1997-08-22 | 1997-08-22 | Titanium-alloyed, isotropic, earing-free, cold rolled strip steel is produced |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE19736509A1 true DE19736509A1 (en) | 1999-04-22 |
Family
ID=7839800
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1997136509 Ceased DE19736509A1 (en) | 1997-08-22 | 1997-08-22 | Titanium-alloyed, isotropic, earing-free, cold rolled strip steel is produced |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE19736509A1 (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0108268A1 (en) * | 1982-10-08 | 1984-05-16 | Nippon Steel Corporation | Method for the production of cold rolled steel sheet having super deep drawability |
| DE3803064C2 (en) * | 1988-01-29 | 1995-04-20 | Preussag Stahl Ag | Cold rolled sheet or strip and process for its manufacture |
| DE19547181C1 (en) * | 1995-12-16 | 1996-10-10 | Krupp Ag Hoesch Krupp | Mfg. cold-rolled, high strength steel strip with good shapability |
-
1997
- 1997-08-22 DE DE1997136509 patent/DE19736509A1/en not_active Ceased
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0108268A1 (en) * | 1982-10-08 | 1984-05-16 | Nippon Steel Corporation | Method for the production of cold rolled steel sheet having super deep drawability |
| DE3803064C2 (en) * | 1988-01-29 | 1995-04-20 | Preussag Stahl Ag | Cold rolled sheet or strip and process for its manufacture |
| DE19547181C1 (en) * | 1995-12-16 | 1996-10-10 | Krupp Ag Hoesch Krupp | Mfg. cold-rolled, high strength steel strip with good shapability |
Non-Patent Citations (3)
| Title |
|---|
| Brockhaus, Jaques G.: Zipfeln Sie noch ? Wir nichtmehr. Denn wir haben den B-Faktor. In: Der Spiegel1966, H.19, S.125 * |
| Hulka, Klaus, Heisterkamp, Friedrich: Stand der Entwicklung und Anwendung von IF-Stählen. In: Stahl u. Eisen, 1990, H.9, S.65-68 / S.65 u.66 * |
| Satoh, Susumu u.a.: Development of Non-Aging Cold Rolled Steel Sheets with Deep Drawability by a Continuous Annealing Process. In: Kawasaki Steel Technical Report, September 1983, No.8, S.1-10 / S.1,2 * |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OP8 | Request for examination as to paragraph 44 patent law | ||
| 8127 | New person/name/address of the applicant |
Owner name: THYSSEN KRUPP STAHL AG, 40211 DUESSELDORF, DE |
|
| 8131 | Rejection |