DE19721785C1 - Simultaneous dyeing and brightening of hair - Google Patents
Simultaneous dyeing and brightening of hairInfo
- Publication number
- DE19721785C1 DE19721785C1 DE1997121785 DE19721785A DE19721785C1 DE 19721785 C1 DE19721785 C1 DE 19721785C1 DE 1997121785 DE1997121785 DE 1997121785 DE 19721785 A DE19721785 A DE 19721785A DE 19721785 C1 DE19721785 C1 DE 19721785C1
- Authority
- DE
- Germany
- Prior art keywords
- water
- hair
- ammonium
- soluble
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000004043 dyeing Methods 0.000 title claims abstract description 6
- 238000005282 brightening Methods 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 claims abstract description 31
- 239000000975 dye Substances 0.000 claims abstract description 15
- 230000003647 oxidation Effects 0.000 claims abstract description 11
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 11
- 239000007844 bleaching agent Substances 0.000 claims abstract description 8
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 claims abstract description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002243 precursor Substances 0.000 claims abstract description 6
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000000118 hair dye Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- 230000002087 whitening effect Effects 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 2
- 239000000843 powder Substances 0.000 abstract description 22
- 239000000982 direct dye Substances 0.000 abstract description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 239000011734 sodium Substances 0.000 description 9
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000007800 oxidant agent Substances 0.000 description 7
- 244000303965 Cyamopsis psoralioides Species 0.000 description 6
- -1 betaines Chemical compound 0.000 description 6
- 230000037308 hair color Effects 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 5
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 4
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 4
- 235000019270 ammonium chloride Nutrition 0.000 description 4
- 238000004061 bleaching Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229920002907 Guar gum Polymers 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 3
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 3
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 229920006317 cationic polymer Polymers 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- 239000000665 guar gum Substances 0.000 description 3
- 235000010417 guar gum Nutrition 0.000 description 3
- 229960002154 guar gum Drugs 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 239000003531 protein hydrolysate Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 2
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 2
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 2
- 229940018563 3-aminophenol Drugs 0.000 description 2
- DBFYESDCPWWCHN-UHFFFAOYSA-N 5-amino-2-methylphenol Chemical compound CC1=CC=C(N)C=C1O DBFYESDCPWWCHN-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 2
- 239000004254 Ammonium phosphate Substances 0.000 description 2
- 229920000858 Cyclodextrin Polymers 0.000 description 2
- 229920000926 Galactomannan Polymers 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 2
- 229920000161 Locust bean gum Polymers 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- LUSZGTFNYDARNI-UHFFFAOYSA-N Sesamol Chemical compound OC1=CC=C2OCOC2=C1 LUSZGTFNYDARNI-UHFFFAOYSA-N 0.000 description 2
- UXEAWNJALIUYRH-UHFFFAOYSA-N [8-[(4-aminophenyl)hydrazinylidene]-7-oxonaphthalen-2-yl]-trimethylazanium;chloride Chemical compound [Cl-].C12=CC([N+](C)(C)C)=CC=C2C=CC(=O)\C1=N/NC1=CC=C(N)C=C1 UXEAWNJALIUYRH-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000001099 ammonium carbonate Substances 0.000 description 2
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical class [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 2
- 235000019289 ammonium phosphates Nutrition 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- JSYBAZQQYCNZJE-UHFFFAOYSA-N benzene-1,2,4-triamine Chemical compound NC1=CC=C(N)C(N)=C1 JSYBAZQQYCNZJE-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- ZXJXZNDDNMQXFV-UHFFFAOYSA-M crystal violet Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1[C+](C=1C=CC(=CC=1)N(C)C)C1=CC=C(N(C)C)C=C1 ZXJXZNDDNMQXFV-UHFFFAOYSA-M 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229910021485 fumed silica Inorganic materials 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 235000010420 locust bean gum Nutrition 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 239000001024 permanent hair color Substances 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 238000005956 quaternization reaction Methods 0.000 description 2
- SOUHUMACVWVDME-UHFFFAOYSA-N safranin O Chemical compound [Cl-].C12=CC(N)=CC=C2N=C2C=CC(N)=CC2=[N+]1C1=CC=CC=C1 SOUHUMACVWVDME-UHFFFAOYSA-N 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- JSLISSGEILAIOU-UHFFFAOYSA-N (4-chloro-2-iodophenyl)hydrazine Chemical compound NNC1=CC=C(Cl)C=C1I JSLISSGEILAIOU-UHFFFAOYSA-N 0.000 description 1
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-dioxonaphthalene Natural products C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- BOKGTLAJQHTOKE-UHFFFAOYSA-N 1,5-dihydroxynaphthalene Chemical compound C1=CC=C2C(O)=CC=CC2=C1O BOKGTLAJQHTOKE-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- PZKPUGIOJKNRQZ-UHFFFAOYSA-N 1-methylcyclohexa-3,5-diene-1,3-diamine Chemical compound CC1(N)CC(N)=CC=C1 PZKPUGIOJKNRQZ-UHFFFAOYSA-N 0.000 description 1
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 1
- DBIJZEYNEPBLGA-UHFFFAOYSA-N 2,4-diamino-3-chlorophenol Chemical compound NC1=CC=C(O)C(N)=C1Cl DBIJZEYNEPBLGA-UHFFFAOYSA-N 0.000 description 1
- 229940075142 2,5-diaminotoluene Drugs 0.000 description 1
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- KWSVXCAQFTWTEF-UHFFFAOYSA-N 2-(2,5-diaminophenyl)ethanol Chemical compound NC1=CC=C(N)C(CCO)=C1 KWSVXCAQFTWTEF-UHFFFAOYSA-N 0.000 description 1
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- DFQICHCWIIJABH-UHFFFAOYSA-N naphthalene-2,7-diol Chemical compound C1=CC(O)=CC2=CC(O)=CC=C21 DFQICHCWIIJABH-UHFFFAOYSA-N 0.000 description 1
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- 230000007935 neutral effect Effects 0.000 description 1
- RBXVOQPAMPBADW-UHFFFAOYSA-N nitrous acid;phenol Chemical class ON=O.OC1=CC=CC=C1 RBXVOQPAMPBADW-UHFFFAOYSA-N 0.000 description 1
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- 150000001451 organic peroxides Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- ATGUVEKSASEFFO-UHFFFAOYSA-N p-aminodiphenylamine Chemical compound C1=CC(N)=CC=C1NC1=CC=CC=C1 ATGUVEKSASEFFO-UHFFFAOYSA-N 0.000 description 1
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- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
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- 229920006316 polyvinylpyrrolidine Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
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- 229920001592 potato starch Polymers 0.000 description 1
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- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- VHNQIURBCCNWDN-UHFFFAOYSA-N pyridine-2,6-diamine Chemical compound NC1=CC=CC(N)=N1 VHNQIURBCCNWDN-UHFFFAOYSA-N 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
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- FZUOVNMHEAPVBW-UHFFFAOYSA-L quinoline yellow ws Chemical compound [Na+].[Na+].O=C1C2=CC=CC=C2C(=O)C1C1=NC2=C(S([O-])(=O)=O)C=C(S(=O)(=O)[O-])C=C2C=C1 FZUOVNMHEAPVBW-UHFFFAOYSA-L 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
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- 239000000741 silica gel Substances 0.000 description 1
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- 235000010413 sodium alginate Nutrition 0.000 description 1
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- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- GTKIEPUIFBBXJQ-UHFFFAOYSA-M sodium;2-[(4-hydroxy-9,10-dioxoanthracen-1-yl)amino]-5-methylbenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC1=CC=C(O)C2=C1C(=O)C1=CC=CC=C1C2=O GTKIEPUIFBBXJQ-UHFFFAOYSA-M 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 235000012756 tartrazine Nutrition 0.000 description 1
- UJMBCXLDXJUMFB-GLCFPVLVSA-K tartrazine Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-GLCFPVLVSA-K 0.000 description 1
- 239000004149 tartrazine Substances 0.000 description 1
- REZOIPSCCRVWNN-UHFFFAOYSA-N tetratriacontan-17-ol Chemical compound CCCCCCCCCCCCCCCCCC(O)CCCCCCCCCCCCCCCC REZOIPSCCRVWNN-UHFFFAOYSA-N 0.000 description 1
- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 description 1
- DWKARHJHPSUOBW-UHFFFAOYSA-N trimethyl-[3-[(2e)-2-(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)hydrazinyl]phenyl]azanium;chloride Chemical compound [Cl-].CC1=NN(C=2C=CC=CC=2)C(O)=C1N=NC1=CC=CC([N+](C)(C)C)=C1 DWKARHJHPSUOBW-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- SWGJCIMEBVHMTA-UHFFFAOYSA-K trisodium;6-oxido-4-sulfo-5-[(4-sulfonatonaphthalen-1-yl)diazenyl]naphthalene-2-sulfonate Chemical compound [Na+].[Na+].[Na+].C1=CC=C2C(N=NC3=C4C(=CC(=CC4=CC=C3O)S([O-])(=O)=O)S([O-])(=O)=O)=CC=C(S([O-])(=O)=O)C2=C1 SWGJCIMEBVHMTA-UHFFFAOYSA-K 0.000 description 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- LLWJPGAKXJBKKA-UHFFFAOYSA-N victoria blue B Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC(=CC=1)N(C)C)=C(C=C1)C2=CC=CC=C2C1=[NH+]C1=CC=CC=C1 LLWJPGAKXJBKKA-UHFFFAOYSA-N 0.000 description 1
- ROVRRJSRRSGUOL-UHFFFAOYSA-N victoria blue bo Chemical compound [Cl-].C12=CC=CC=C2C(NCC)=CC=C1C(C=1C=CC(=CC=1)N(CC)CC)=C1C=CC(=[N+](CC)CC)C=C1 ROVRRJSRRSGUOL-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
- A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/23—Sulfur; Selenium; Tellurium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/31—Anhydrous
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/432—Direct dyes
- A61K2800/4322—Direct dyes in preparations for temporarily coloring the hair further containing an oxidizing agent
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
Description
Die vorliegende Erfindung betrifft ein neues, verbessertes Verfahren zum gleichzeitigen Färben und Aufhellen von menschlichen Haaren.The present invention relates to a new, improved process for simultaneous dyeing and lightening of human hair.
Blondierung bzw. Aufhellung und Färbung von menschlichen Haaren finden üblicherweise in zwei getrennten Arbeitsgängen statt.Bleaching or coloring of human hair are commonly found in two separate operations.
Aus der EP 0 642 783 B1 ist es bereits bekannt, eine Blondierung bzw. Aufhellung mit einer Haarfärbung zu kombinieren. Das dort beschriebene Verfahren geht jedoch von der Verwendung konventioneller wäßriger Oxidationsfärbemittel aus und vermag daher die Vorteile nach der vorliegenden Erfindung nicht zu bieten.From EP 0 642 783 B1 it is already known to bleach or brighten with a Hair coloring to combine. The method described there, however, goes from the Use of conventional aqueous oxidation colorants and is therefore able to Not to offer advantages according to the present invention.
Diese Erfindung gestattet nämlich auf einfache Weise, neben einer Aufhellung die Intensität der Färbung und auch die Zahl der Farbnuancen in einem Arbeitsgang nahezu beliebig zu variieren, unabhängig von der Wasserlöslichkeit und -stabilität der eingesetzten Haarfarbstoffe.In fact, in a simple way, this invention permits, in addition to a lightening, the intensity of the Coloring and the number of shades in a single operation to vary almost arbitrarily, regardless of the water solubility and stability of the hair dyes used.
Das erfindungsgemäße Verfahren zum gleichzeitigen Färben bzw. Tönen und Aufhellen von menschlichen Haaren besteht darin, vor der Anwendung auf dem Haar eine homogene Mischung aus einem Mittel auf wäßriger Basis, das mindestens ein Oxidationsmittel enthält, und einer pulverförmigen, in Wasser löslichen oder dispergierbaren Zusammensetzung, die mindestens einen direktziehenden Haarfarbstoff und/oder mindestens ein Oxidationsfarbstoffvorprodukt enthält, sowie einem an sich bekannten, mindestens ein Persulfat enthaltenden, wasserlöslichen bzw. wasserdispergierbaren Blondierpulver herzustellen, und diese Mischung auf das Haar aufzubringen.The inventive method for simultaneous coloring or whitening and whitening Human hair is a homogeneous before application on the hair A mixture of an aqueous-based agent containing at least one oxidizing agent, and a powdery, water-soluble or dispersible composition which at least one substantive hair dye and / or at least one Oxidation dye precursor contains, as well as a known, at least one Persulfate-containing, water-soluble or water-dispersible bleaching powder and apply this mixture to the hair.
Dem Benutzer ist es so möglich, durch Dosierung des Mischungsverhältnisses die Intensität und durch die Auswahl der den Farbstoff enthaltenden Zusammensetzung den gewünschten Farbton auszuwählen und einzustellen. The user is thus able, by metering the mixing ratio, the intensity and by selecting the dye-containing composition, the desired one To select and adjust the color tone.
Wird bei der Behandlung nur eine Farbauffrischung bzw. eine Wiederherstellung einer, beispielsweise durch Dauerwellung, abgeschwächten Haarfärbung gewünscht, ist im allgemeinen der Einsatz eines Tönungspulvers, d. h. eines semi-permanenten Färbemittels auf Basis direktziehender Farbstoffe, ausreichend.If the treatment is only a color refresh or a restoration of a For example, by Dauerwellung, weakened hair coloring desired, is in in general, the use of a tinting powder, d. H. a semi-permanent colorant on Basis of direct dyes, sufficient.
Falls jedoch eine stärkere Haarfärbung, z. B. im Sinne einer echten Farbveränderung des Haares, erwünscht ist, ist die Anwendung eines permanenten Haarfärbemittels auf Basis von Oxidationsfarbstoffvorprodukten, d. h. Entwickler- und Kupplersubstanzen, erforderlich.However, if a stronger hair coloring, z. B. in terms of a true color change of Haares, is the application of a permanent hair dye based on Oxidation dye precursors, d. H. Developer and coupler substances required.
Durch die Verwendung eines pulverförmigen Trägermaterials für die den direktziehenden Haarfarbstoff bzw. das Oxidationsfarbstoffvorprodukt enthaltende Zusammensetzung können keinerlei Stabilitäts-, Löslichkeits- und Verträglichkeitsprobleme auftreten.Through the use of a powdery carrier material for the substantive Hair dye or the oxidation dye precursor containing composition can no stability, solubility and compatibility problems occur.
Gemäß einer bevorzugten Ausführungsform der Erfindung kann beim Vermischen zusätzlich eine bestimmte Menge Wasser zugesetzt werden.According to a preferred embodiment of the invention, in addition to mixing a certain amount of water is added.
Geeignete pulverförmige direktziehende Haarfarbstoffe enthaltende Haarfärbemittel sind an sich bekannt, beispielsweise aus der DE 195 30 998 A1.Suitable powdered substantive hair dyes containing hair dyes are on known, for example from DE 195 30 998 A1.
Diese Farbpulver enthalten üblicherweise eine in Wasser lösliche oder zumindest dispergier- bzw. quellbare Pudergrundlage, beispielsweise Stärke, Maltodextrin, Cyclodextrin, Silicagel, Polyethylenglykole, etc., vorzugsweise in einer Menge von etwa 10 bis etwa 70, insbesondere etwa 20 bis etwa 50 Gew.-% der Gesamtzusammensetzung.These color powders usually contain a water-soluble or at least dispersing agent. or swellable powder base, for example starch, maltodextrin, cyclodextrin, silica gel, Polyethylene glycols, etc., preferably in an amount of about 10 to about 70, in particular from about 20% to about 50% by weight of the total composition.
Diese Bestandteile sind ebenso bekannt wie die Mitverwendung von Tensiden, vorzugsweise in einer Menge von etwa 5 bis etwa 30 Gew.-% des Pulvers.These ingredients are known as well as the use of surfactants, preferably in an amount of about 5 to about 30% by weight of the powder.
Geeignete Tenside sind anionische Tenside wie langkettige N-Acylaminocarbonsäuren und deren Salze wie N-Lauroylsarkosinat und -glutamat, amphotere Tenside wie Betaine, z. B. Cocoamidopropylbetain, sowie nichtionische und kationische Tenside, z. B. C12-C18- Alkylpolyglykolether und Ethylenoxid/Propylenoxid-Copolykondensate sowie langkettige quaternäre Ammoniumverbindungen, z. B. Distearyl- oder Dilauryldimethylammoniumchlorid. Suitable surfactants are anionic surfactants such as long-chain N-acylaminocarboxylic acids and their salts such as N-lauroyl sarcosinate and glutamate, amphoteric surfactants such as betaines, z. Cocoamidopropyl betaine, as well as nonionic and cationic surfactants, e.g. B. C 12 -C 18 - Alkylpolyglykolether and ethylene oxide / propylene oxide copolycondensates and long-chain quaternary ammonium compounds, eg. B. distearyl or dilauryldimethylammonium chloride.
Weitere bevorzugte Bestandteile sind Dispergier- und Verdickungsmittel, beispielsweise verschiedene wasserlösliche Cellulosederivate wie Hydroxyethyl- und Hydroxypropylcellulose oder entsprechende synthetische Polymere wie Polyacrylsäure und deren Salze, Polyvinylpyrrolidon, etc.Further preferred ingredients are dispersing and thickening agents, for example various water-soluble cellulose derivatives such as hydroxyethyl and hydroxypropyl cellulose or corresponding synthetic polymers such as polyacrylic acid and its salts, Polyvinylpyrrolidone, etc.
Auch andere Polysaccharide wie z. B. Galactomannane sind geeignete Bestandteile von Farbstoffpulvern, z. B. Guar Gum-Derivate, insbesondere Hydroxy-C2-C4-alkyl-Guar Gum wie Hydroxypropyl-Guar, d. h., der Propylenglykolether des Guar Gums, sowie auch Quaternisierungsprodukte desselben, insbesondere das Hydroxypropyl-Guar hydroxypropyltrimoniumchlorid. Weitere geeignete Hydroxyalkyl-Guar-Derivate sind beispielsweise Hydroxyethyl-Guar, Hydroxybutyl-Guar und deren Quaternisierungsprodukte. Entsprechende Handelsprodukte sind unter den Markennamen "Jaguar HP®", "Jaguar C-17®" und "Jaguar C-162®" sowie "Galactosol®" auf dem Markt.Other polysaccharides such. B. galactomannans are suitable components of dye powders, for. As guar gum derivatives, in particular hydroxy-C 2 -C 4 alkyl guar gum such as hydroxypropyl guar, ie, the propylene glycol ether of the guar gum, as well as quaternization thereof, in particular the hydroxypropyl guar hydroxypropyltrimoniumchlorid. Further suitable hydroxyalkyl guar derivatives are, for example, hydroxyethyl guar, hydroxybutyl guar and their quaternization products. Corresponding commercial products are on the market under the brand names "Jaguar HP®", "Jaguar C-17®" and "Jaguar C-162®" as well as "Galactosol®".
Eine weitere Gruppe von Galactomannanen sind die aus den Früchten des Johannisbrotbaums gewonnenen Polysaccharide, die unter den Trivialnamen "Locust Bean Gum" bzw. "Carob Bean Gum" bekannt und beispielsweise unter der Marke "Seagel L®" im Handel sind.Another group of galactomannans are those from the fruits of the carob tree obtained polysaccharides, under the common names "Locust Bean Gum" and "Carob Bean gum known and, for example, under the brand "Seagel L®" in the trade.
Als direktziehende Haarfarbstoffe, mit denen eine semi-permanente Haarfärbung, auch Tönung genannt, erzielt wird, können im Prinzip alle für diesen Zweck zugelassenen Farbstoffe verwendet werden; es wird hierzu insbesondere auf die deutsche "Verordnung über kosmetische Mittel (Kosmetik-Verordnung)" in der jeweils geltenden Fassung, Anlage 3, verwiesen.As substantive hair dyes that give a semi-permanent hair coloring, even tinting can be obtained, in principle, all approved for this purpose dyes be used; For this purpose, reference is made in particular to the German Ordinance on Cosmetic Products (Cosmetics Regulation) ", as amended, Appendix 3, directed.
Bevorzugt sind jedoch die kationischen (basischen) Farbstoffe, da deren Stabilität und Farbaufziehvermögen in dem erfindungsgemäßen Verfahren besonders erhöht wird.However, preference is given to the cationic (basic) dyes, since their stability and Color absorption in the method according to the invention is particularly increased.
Besonders geeignete basische (kationische) Farbstoffe sind:
Basic Blue 6, C.I.-No. 51,175;
Basic Blue 7, C.I.-No. 42,595;
Basic Blue 9, C.I.-No. 52,015;
Basic Blue 26, C.I.-No. 44,045;
Basic Blue 41, C.I.-No. 11,154;
Basic Blue 99, C.I.-No. 56,059;
Basic Brown 4, C.I.-No. 21,010;
Basic Brown 16, C.I.-No. 12,250;
Basic Brown 17, C.I.-No. 12,251;
Basic Green 1, C.I.-No. 42,040;
Basic Red 2, C.I.-No. 50,240;
Basic Red 22, C.I.-No. 11,055;
Basic Red 76, C.I.-No. 12,245;
Basic Violet 1, C.I.-No. 42,535;
Basic Violet 3, C.I.-No. 42,555;
Basic Violet 10, C.I.-No. 45,170;
Basic Violet 14, C.I.-No. 42,510;
Basic Yellow 57, C.I.-No. 12,719.Particularly suitable basic (cationic) dyes are:
Basic Blue 6, CI-No. 51,175;
Basic Blue 7, CI-No. 42.595;
Basic Blue 9, CI-No. 52.015;
Basic Blue 26, CI-No. 44.045;
Basic Blue 41, CI-No. 11.154;
Basic Blue 99, CI-No. 56.059;
Basic Brown 4, CI-No. 21.010;
Basic Brown 16, CI-No. 12.250;
Basic Brown 17, CI-No. 12.251;
Basic Green 1, CI-No. 42.040;
Basic Red 2, CI-No. 50.240;
Basic Red 22, CI-No. 11.055;
Basic Red 76, CI-No. 12.245;
Basic Violet 1, CI-No. 42.535;
Basic Violet 3, CI-No. 42.555;
Basic Violet 10, CI-No. 45.170;
Basic Violet 14, CI-No. 42.510;
Basic Yellow 57, CI-No. 12,719.
Als mögliche saure (anionische), jedoch weniger bevorzugte Farbstoffe können Verwendung
finden:
Acid Black 1, C.I.-No. 20,470;
Acid Blue 9, C.I.-No. 42,090;
Acid Blue 74, C.I.-No. 73,015
Acid Red 18, C.I.-No. 16,255;
Acid Red 27, C.I.-No. 16,185;
Acid Red 87, C.I.-No. 45,380;
Acid Red 92, C.I.-No. 45,410;
Acid Violet 43, C.I.-No. 60,730;
Acid Yellow 1, C.I.-No. 10,316;
Acid Yellow 23, C.I.-No. 19,140;
Acid Yellow 3, C.I.-No. 47,005;
D Brown No. 1, C.I.-No. 20,170;
D Green No. 5, C.I.-No. 61,570;
D Orange No. 4, C.I.-No. 15,510;
D Orange No. 10, C.I.-No. 45,425 : 1;
D Orange No. 11 C.I.-No. 45,425;
D Red No. 21, C.I.-No. 45,380 : 2;
D Red No. 27; C.I.-No. 45,410 : 1;
D Red No. 33, C.I.-No. 17,200;
D Yellow No. 7, C.I.-No. 45,350 : 1;
D Yellow No. 8, C.I.-No. 45,350;
FD Red No. 4, C.I.-No. 14,700;
FD Yellow No. 6, C.I.-No. 15,985.As possible acidic (anionic), but less preferred dyes can be used:
Acid Black 1, CI-No. 20.470;
Acid Blue 9, CI-No. 42.090;
Acid Blue 74, CI-No. 73,015
Acid Red 18, CI-No. 16.255;
Acid Red 27, CI-No. 16.185;
Acid Red 87, CI-No. 45,380;
Acid Red 92, CI-No. 45,410;
Acid Violet 43, CI-No. 60.730;
Acid Yellow 1, CI-No. 10.316;
Acid Yellow 23, CI-No. 19,140;
Acid Yellow 3, CI-No. 47.005;
D Brown no. 1, CI-No. 20.170;
D Green No. 5, CI-No. 61.570;
D Orange No. 4, CI-No. 15.510;
D Orange No. 10, CI-No. 45.425: 1;
D Orange No. 11 CI-No. 45,425;
D Red No. 21, CI-No. 45.380: 2;
D Red No. 27; CI-No. 45.410: 1;
D Red No. 33, CI-No. 17,200;
D Yellow No. 7, CI-No. 45.350: 1;
D Yellow No. 8, CI-No. 45.350;
FD Red No. 4, CI-No. 14,700;
FD Yellow No. 6, CI-No. 15,985.
Auch pflanzliche Farbstoffe können allein oder in Kombination mit synthetischen Direktziehern eingesetzt werden, beispielsweise Henna (rot oder schwarz), Alkannawurzel, Laccainsäure (Stocklack), Blauholzpulver, Krappwurzel- und Rhabarberwurzelpulver, etc. Direktziehende Farbstoffe sind auch die verschiedenen Nitrophenol- bzw. Nitrophenylendiamin-Derivate, beispielsweise (hydroxy-)alkyl-substituierte Nitrophenole.Also, vegetable dyes may be used alone or in combination with synthetic directing agents For example, henna (red or black), alkana root, laccinic acid (Stocklack), bluewood powder, madder root and rhubarb root powder, etc. Direct dyes are also the various nitrophenol or Nitrophenylenediamine derivatives, for example (hydroxy) alkyl-substituted nitrophenols.
Der Anteil der direktziehenden Farbstoffe in den erfindungsgemäß eingesetzten pulverförmigen Zusammensetzungen ist je nach gewünschtem Farbton variabel und liegt im allgemeinen zwischen etwa 0,01 bis etwa 25, vorzugsweise 0,5 bis 10, insbesondere 1 bis 5 Gew.-%, des Mittels.The proportion of substantive dyes in the powdered used in the invention Compositions vary depending on the desired shade and are generally between about 0.01 to about 25, preferably 0.5 to 10, especially 1 to 5 wt .-%, of Agent.
Dieses Haarfärbe- und -tönungsmittel kann auch mindestens ein synthetisches oder natürliches haarkonditionierendes Polymeres, vorzugsweise in einer Menge von 0,1 bis 10, insbesondere 0,5 bis 5 Gew.-% der Gesamtzusammensetzung, enthalten. Obwohl grundsätzlich alle Arten von Polymeren verwendet werden können, also nichtionische, anionische, amphotere und kationische Polymere, werden kationische Polymere bevorzugt. This hair dyeing and tinting agent may also be at least one synthetic or natural Hair conditioning polymer, preferably in an amount of 0.1 to 10, in particular From 0.5% to 5% by weight of the total composition. Although basically all kinds can be used by polymers, ie nonionic, anionic, amphoteric and cationic polymers, cationic polymers are preferred.
Eine Rahmenrezeptur für ein erfindungsgemäß verwendendes Farbstoffpulver läßt sich etwa
folgendermaßen darstellen:
A frame formulation for a dye powder to be used according to the invention can be represented as follows:
Falls mit dem erfindungsgemäß einzusetzenden Farbpulver neben der Dauerwellung eine permanente Haarfärbung erzielt werden soll, enthält dieses mindestens ein Oxidationsfarbstoffvorprodukt, zweckmäßigerweise jedoch ein Gemisch aus mindestens einer Entwickler- und mindestens einer Kupplersubstanz.If, with the color powder to be used according to the invention, in addition to the permanent wave, a permanent hair coloring is to be achieved, this contains at least one Oxidation dye precursor, but expediently a mixture of at least one Developer and at least one coupler substance.
Diese sind an sich bekannt und beispielsweise in der bereits erwähnten Monographie von K. Schrader, Grundlagen und Rezepturen der Kosmetika, 2. Aufl. (1989), S. 784-799, beschrieben.These are known per se and, for example, in the abovementioned monograph by K. Schrader, Grundlagen und Rezepturen der Kosmetika, 2nd ed. (1989), pp. 784-799, described.
Beispielhafte Entwicklersubstanzen sind insbesondere 1,4-Diaminobenzol, 2,5-Diaminotoluol, Tetraaminopyrimidine, Triaminohydroxypyrimidine, 1,2,4-Triaminobenzol, 2-(2, 5- Diaminophenyl)ethanol, 2-(2'-Hydroxyethylamino)-5-aminotoluol und 1-Amino-4-bis-(2'- hydroxyethyl)-aminobenzol bzw. deren wasserlösliche Salze, beispielhafte Kupplersubstanzen sind Resorcin, 2-Methylresorcin, 4-Chlorresorcin, 2-Amino-4-chlorphenol,4-(N- methyl)aminophenol, 2-Aminophenol, 3-Aminophenol, 1-Methyl-2-hydroxy-4-aminobenzol, 3- N,N-Dimethylaminophenol, 4-Amino-3-methylphenol, 5-Amino-2-methylphenol, 6-Amino-3- methylphenol, 3-Amino-2-methylamino-6-methoxypyridin, 2-Amino-3-hydroxypyridin, 4- Aminodiphenylamin, 4,4'-Diaminodophenylamin, 2-Dimethylamino-5-aminopyridin, 2,6- Diaminopyridin, 1,3-Diaminobenzol, 1-Amino-3-(2'-hydroxyethylamino)benzol, 1-Amino-3- [bis(2'-hydroxyethyl)amino]benzol, 1,3-Diaminotoluol, α-Naphthol, 1,4-Diamino-2-chlor benzol, 4,6-Dichlorresorcin, 4-Hydroxy-1,2-methylendioxybenzol, 1,5-Dihydroxy naphthalin, 1,7-Dihydroxynaphthalin, 2,7-Dihydroxynaphthalin, 1-Hydroxynaphthalin, 4- Hydroxy-1,2-methylendioxybenzol, 2,4-Diamino-3-chlorphenol, und/oder 1-Methoxy-2- amino-4-(2'-hydroxyethylamino)-benzol, ohne daß diese beispielhafte Aufzählung Anspruch auf Vollständigkeit erheben könnte.Exemplary developing agents are in particular 1,4-diaminobenzene, 2,5-diaminotoluene, Tetraaminopyrimidines, triaminohydroxypyrimidines, 1,2,4-triaminobenzene, 2- (2, 5 Diaminophenyl) ethanol, 2- (2'-hydroxyethylamino) -5-aminotoluene and 1-amino-4-bis- (2'- hydroxyethyl) aminobenzene or their water-soluble salts, exemplary coupler substances are resorcinol, 2-methylresorcinol, 4-chlororesorcinol, 2-amino-4-chlorophenol, 4- (N- methyl) aminophenol, 2-aminophenol, 3-aminophenol, 1-methyl-2-hydroxy-4-aminobenzene, 3- N, N-dimethylaminophenol, 4-amino-3-methylphenol, 5-amino-2-methylphenol, 6-amino-3- methylphenol, 3-amino-2-methylamino-6-methoxypyridine, 2-amino-3-hydroxypyridine, 4- Aminodiphenylamine, 4,4'-diaminodophenylamine, 2-dimethylamino-5-aminopyridine, 2,6- Diaminopyridine, 1,3-diaminobenzene, 1-amino-3- (2'-hydroxyethylamino) benzene, 1-amino-3- [bis (2'-hydroxyethyl) amino] benzene, 1,3-diaminotoluene, α-naphthol, 1,4-diamino-2-chloro benzene, 4,6-dichlororesorcinol, 4-hydroxy-1,2-methylenedioxybenzene, 1,5-dihydroxy naphthalene, 1,7-dihydroxynaphthalene, 2,7-dihydroxynaphthalene, 1-hydroxynaphthalene, 4- Hydroxy-1,2-methylenedioxybenzene, 2,4-diamino-3-chlorophenol, and / or 1-methoxy-2- amino-4- (2'-hydroxyethylamino) benzene without this exemplary enumeration claim could be exhaustive.
Entwickler- und Kupplersubstanzen sind vorzugsweise im Molverhältnis 1 : 3 bis 5 : 1, insbesondere etwa 1 : 1 und etwa 3 : 1, enthalten; ihr Anteil in dem erfindungsgemäß eingesetzten Farbpulver kann jeweils etwa 0,25 bis etwa 5 Gew.-%, je nach gewünschter Färbung, betragen.Developer and coupler substances are preferably in the molar ratio of 1: 3 to 5: 1, especially about 1: 1 and about 3: 1; their proportion in the invention used Color powder may be from about 0.25% to about 5% by weight, depending on the color desired.
Geeignete Blondierpulver sind aus dem Stand der Technik bekannt und beispielsweise in der Monographie von K. Schrader, Grundlagen und Rezepturen der Kosmetika, 2. Aufl. (1989), S. 815-823, beschrieben.Suitable bleaching powders are known from the prior art and for example in the Monograph by K. Schrader, Basics and Formulations of Cosmetics, 2nd ed. (1989), p. 815-823.
Sie enthalten, neben den als Wirkstoffe anzusehenden Persulfaten wie Ammonium-, Natrium- und/oder Kaliumpersulfat, inerte pulverförmige Trägerstoffe, beispielsweise pyrogenes Siliciumdioxid, Stärkepulver, etc., Alkalisierungsmittel wie Natriummetasilikat, oberflächenaktive Substanzen, Bindemittel, etc.They contain, in addition to the persulphates to be regarded as active substances, such as ammonium, sodium and / or potassium persulfate, inert powdery carriers, for example pyrogenic Silica, starch powder, etc., alkalizing agents such as sodium metasilicate, surface-active substances, binders, etc.
Bevorzugt eingesetzte Blondierpulver im Rahmen der Erfindung sind solche, die anstelle von Ammoniumpersulfat ein Gemisch aus Natrium- und Kaliumpersulfat, vorzugsweise im Gewichtsverhältnis von 1 : 1 bis 1 : 15, insbesondere 1 : 2 bis 1 : 12, enthalten, wie sie in der DE 197 16 494 A-1 beschrieben sind.Preferred bleaching powders used in the invention are those which, instead of Ammonium persulfate a mixture of sodium and potassium persulfate, preferably in Weight ratio of 1: 1 to 1: 15, in particular 1: 2 to 1: 12, as described in the DE 197 16 494 A-1 are described.
Neben dem Natriumpersulfat/Kaliumpersulfat-Gemisch enthalten auch diese Blondiermittel mit verringerter Haarschädigung und verbesserter Blondierwirkung die in solchen Mitteln üblichen Bestandteile.In addition to the sodium persulfate / potassium persulfate mixture also contain these Blondiermittel with reduced hair damage and improved bleaching action common in such agents Ingredients.
Die Mitverwendung weiterer Peroxide in untergeordneten Mengen, z. B. Magnesiumperoxid, Melaminperoxid oder Harnstoffperoxid, in diesen Zusammensetzungen ist im Prinzip möglich; der Anteil an Ammoniumpersulfat sollte dabei 0 bis maximal 1 Gew.-% betragen. The concomitant use of other peroxides in minor amounts, eg. For example, magnesium peroxide, Melamine peroxide or urea peroxide, in these compositions is possible in principle; the proportion of ammonium persulfate should be 0 to a maximum of 1 wt .-%.
Gemäß einer bevorzugten Ausführungsform der Erfindung können diese Blondierpulver noch 0,1 bis 10 Gew.-%, berechnet auf die Gesamtzusammensetzung, eines oder mehrerer Ammoniumsalze enthalten.According to a preferred embodiment of the invention, these Blondierpulver can still 0.1 to 10% by weight, calculated on the total composition, of one or more Contain ammonium salts.
Geeignete Ammoniumsalze sind dabei Ammoniumcarbonat, Ammoniumhydrogencarbonat, Ammoniumcarbamat, Ammoniumchlorid, Ammoniumsulfat, Ammoniumphosphate, Ammoniumnitrat, Ammoniumbromid, Ammoniumjodid, Ammoniumthiosulfat, Ammo niummolybdat, Ammoniumvanadat, Ammoniumsulfamat, Ammoniumcitrat, Ammoniumsa licylat, Ammoniumvalerat, Ammoniumtartrat, Ammoniumbenzoat, Ammoniumacetat, Ammoniumformiat und Ammoniumlactat.Suitable ammonium salts are ammonium carbonate, ammonium bicarbonate, Ammonium carbamate, ammonium chloride, ammonium sulfate, ammonium phosphates, Ammonium nitrate, ammonium bromide, ammonium iodide, ammonium thiosulfate, ammo ammonium molybdate, ammonium vanadate, ammonium sulfamate, ammonium citrate, ammonium a licylate, ammonium valerate, ammonium tartrate, ammonium benzoate, ammonium acetate, Ammonium formate and ammonium lactate.
Bevorzugt sind hierbei die Ammoniumphosphate wie NH4H2PO4, (NH4)2HPO4, (NH4)2NaPO4, NaNH4HPO4 oder NH4Na2PO4, Ammoniumchlorid, Ammoniumsulfat und Diammoniumhydrogencitrat sowie Ammoniumchlorid, vorzugsweise in einer Menge von 0,1 bis 5 Gew.-% Animoniumchlorid.Preferred here are the ammonium phosphates such as NH 4 H 2 PO 4 , (NH 4 ) 2 HPO 4 , (NH 4 ) 2 NaPO 4 , NaNH 4 HPO 4 or NH 4 Na 2 PO 4 , ammonium chloride, ammonium sulfate and diammonium hydrogen citrate and ammonium chloride, preferably in an amount of 0.1 to 5% by weight of ammonium chloride.
Diese Pulver können auch, wie aus der EP-A 560 088 bekannt, mit Ölen bzw. mit einem flüssigen Wachs beschichtet sein oder, wie es in der EP-A 630 643 beschrieben ist, als mit Binde- und Verdickungsmitteln verfestigtes Agglomerat vorliegen und dadurch staubfrei gemacht werden.These powders can also, as known from EP-A 560 088, with oils or with a be coated liquid wax or, as described in EP-A 630,643, as with Binders and thickeners solidified agglomerate and thus dust-free be made.
Der pH-Wert der gebrauchsfertigen Mischungen kann im sauren, neutralen oder alkalischen Bereich liegen, beispielsweise bei einem pH-Wert von etwa 6 bis etwa 11. The pH of the ready-mixes can be acidic, neutral or alkaline Range, for example, at a pH of about 6 to about 11th
Farbpulver und Blondierpulver werden mit den wäßrigen Oxidationsmittelzusammensetzungen vorzugsweise im Gewichtsverhältnis von etwa 1 : 1 bis 1 : 15, insbesondere etwa 1 : 2 bis 1 : 12, vor allem etwa 1 : 5 bis 1 : 10, vermischt, wobei das optimale Mischungsverhältnis von dem erwünschten Färbungs- und Aufhellungsgrad abhängig ist und vom behandelnden Friseur auch vor der Behandlung durch kurzes Ausprobieren an Strähnchen ermittelt werden kann.Color powder and bleaching powder are mixed with the aqueous oxidizing agent compositions preferably in a weight ratio of about 1: 1 to 1:15, in particular about 1: 2 to 1: 12, Above all, about 1: 5 to 1: 10, mixed, with the optimum mixing ratio of the desired degree of dyeing and whitening and by the hairdresser treating too can be determined before the treatment by briefly trying on highlights.
Das Verhältnis von Farbpulver zu Blondierpulver ist ebenfalls variabel und kann zwischen etwa 5 : 1 bis etwa 1 : 5, insbesondere 1 : 2 zu 2 : 1, liegen.The ratio of color powder to Blondierpulver is also variable and can be between about 5: 1 to about 1: 5, in particular 1: 2 to 2: 1, lie.
Es kann auch noch Wasser zugesetzt werden, beispielsweise im Verhältnis von Farb- und Blondierpulver zu Wasser von etwa 1 : 5 bis etwa 1 : 30, vorzugsweise 1 : 10 bis 1 : 20. Die Mischung wird auf dem Haar gleichmäßig verteilt, und dort nach etwa 10- bis 30-minütiger, insbesondere 15- bis 25-minütiger Einwirkung durch Waschen bzw. Spülen entfernt.It can also be added to water, for example in the ratio of color and Blondierpulver to water of about 1: 5 to about 1: 30, preferably 1:10 to 1: 20. The Mixture is spread evenly on the hair, and there after about 10 to 30 minutes, especially 15 to 25 minutes exposure by washing or rinsing removed.
Das Mischungsverhältnis ist selbstverständlich auch von der Konzentration des Oxidationsmittels und der Tatsache, ob es sich um bei dem Farbpulver um ein semi permanentes oder permanentes Haarfärbemittel handelt, sowie auch der Konsistenz der das Oxidationsmittel enthaltenden Zusammensetzung abhängig.The mixing ratio is of course also the concentration of the Oxidizer and the fact of whether the paint powder is a semi permanent or permanent hair dye, as well as the consistency of the Oxidizing agent-containing composition dependent.
Gleiches gilt für die Notwendigkeit eines eventuellen Wasserzusatzes.The same applies to the need for a possible addition of water.
Bevorzugtes Oxidationsmittel ist Wasserstoffperoxid, vorzugsweise in etwa 2- bis etwa 30% iger, besonders bevorzugt 3- bis 20%-iger, insbesondere 6- bis 12%-iger wäßriger Zusammensetzung wie Lösung, Dispersion, Gel oder Emulsion. Es sind jedoch auch andere Oxidationsmittel wie organische Peroxide geeignet.Preferred oxidizing agent is hydrogen peroxide, preferably from about 2 to about 30%. iger, particularly preferably 3 to 20%, in particular 6 to 12% aqueous Composition such as solution, dispersion, gel or emulsion. However, other oxidizing agents such as organic peroxides are also suitable.
Die für die Oxidationsfärbung, beispielsweise bei Schrader, l.c. S. 808, 822-823, und 832-840 beschriebenen Produkte eignen sich im Regelfall für die Anwendung im Rahmen der Erfindung.For oxidation staining, for example, Schrader, l.c. Pp. 808, 822-823, and 832-840 As a rule, the products described are suitable for use in the context of the invention.
Die folgenden Beispiele illustrieren die Erfindung:The following examples illustrate the invention:
-
a) Auf Strähnen aus hellbraunem Menschenhaar wurde eine homogene Mischung, erhalten
durch intensives Vermischen von 6 g Tönungspulver der Zusammensetzung A1 und 6,25 g
staubfreies Blondierpulver der Zusammensetzung B1 mit 8,75 g einer Oxidationslotion der
Zusammensetzung C unter Zusatz von 20 ml Wasser (pH-Wert der Mischung: 9,8),
aufgebracht und 20 Minuten bei 50°C ausgefärbt.
Nach dem Ausspülen mit Wasser und Trockenen wurde ein glänzender, heller Kupferton erzielt.a) On strands of light brown human hair, a homogeneous mixture was obtained by thoroughly mixing 6 g of tinting powder of composition A1 and 6.25 g of dust-free bleaching powder of composition B1 with 8.75 g of an oxidation lotion of composition C with the addition of 20 ml of water ( pH of the mixture: 9.8), applied and dyed at 50 ° C for 20 minutes.
After rinsing with water and dry, a bright, bright copper tone was achieved. -
b) 10 g eines Oxidationsfarbstoff-Pulvers nach Beispiel A2 wurden mit 80 ml einer
Oxidationsmittel-Zusammensetzung C und 10 g eines Blondierpulvers der
Zusammensetzung B2 vermischt und auf Strähnen aus hellbraunem Menschenhaar
aufgebracht.
Nach 15-minütiger Einwirkung bei Raumtemperatur wurde gespült und getrocknet. Es wird eine kräftige, langlebige, glänzende helle Braunfärbung erhalten.b) 10 g of an oxidation dye powder according to Example A2 were mixed with 80 ml of an oxidizing agent composition C and 10 g of a bleaching powder of composition B2 and applied to strands of light brown human hair.
After 15 minutes exposure to room temperature, it was rinsed and dried. It will get a strong, long lasting, shiny light brown color.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1997121785 DE19721785C1 (en) | 1997-05-24 | 1997-05-24 | Simultaneous dyeing and brightening of hair |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1997121785 DE19721785C1 (en) | 1997-05-24 | 1997-05-24 | Simultaneous dyeing and brightening of hair |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE19721785C1 true DE19721785C1 (en) | 1998-09-03 |
Family
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|---|---|---|---|
| DE1997121785 Expired - Fee Related DE19721785C1 (en) | 1997-05-24 | 1997-05-24 | Simultaneous dyeing and brightening of hair |
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000076469A1 (en) * | 1999-06-15 | 2000-12-21 | Revlon Consumer Products Corporation | One step method and compositions for simultaneously coloring and highlighting hair |
| EP1129688A1 (en) * | 2000-02-10 | 2001-09-05 | Bristol-Myers Squibb Company | Hair coloring composition using an inorganic peroxymonosulfate salt as an oxidation agent. |
| WO2002045666A3 (en) * | 2000-12-09 | 2002-08-22 | Henkel Kgaa | Novel use of protein hydrolysates |
| WO2002032383A3 (en) * | 2000-10-19 | 2002-10-10 | Henkel Kgaa | Novel use of short-chained carboxylic acids |
| WO2002032386A3 (en) * | 2000-10-19 | 2002-11-07 | Henkel Kgaa | Novel use of short-chained carboxylic acids |
| WO2004078150A1 (en) * | 2003-03-06 | 2004-09-16 | Wella Aktiengesellschaft | Agent for simultaneously dying and brightening keratin fibers |
| EP1372581A4 (en) * | 2001-03-19 | 2005-04-20 | Avant Garde Inc L | Composition for simultaneously lightening and coloring hair utilizing bleach-stable acid and basic dyes |
| WO2005051336A1 (en) * | 2003-11-21 | 2005-06-09 | Henkel Kommanditgesellschaft Auf Aktien | Method for dyeing fibres containing keratine |
| EP1040821B2 (en) † | 1999-03-31 | 2005-10-12 | L'oreal | Cosmetic composition comprising at least one powdery phase, a hydrating agent and a galactomannane derivative and its uses |
| EP1251823A4 (en) * | 2000-01-19 | 2006-04-12 | Artec Systems Group Inc | One-step bleach and coloring composition for hair and method of using same |
| WO2006039990A1 (en) * | 2004-10-12 | 2006-04-20 | The Procter & Gamble Company | Colouring agents containing cationic indazoline-thiazolazo dyes- |
| WO2010023560A3 (en) * | 2008-08-29 | 2010-05-20 | L'oreal | Methods and kits for permanently coloring hair using persulfates, perborates or percarbonates |
| WO2009010883A3 (en) * | 2007-07-03 | 2010-08-19 | L'oreal | Methods and kits for permanently coloring hair using persulfates, perborates or percarbonates |
| FR2996123A1 (en) * | 2012-09-28 | 2014-04-04 | Oreal | A CAPILLARY COLORING PROCESS USING AT LEAST ONE ANTHR (AQUIN) ONE DERIVATIVE, A MANGANESE OR ZINC SALT, HYDROGEN PEROXIDE AND (BI) CARBONATE |
| IT201700045844A1 (en) * | 2017-04-27 | 2018-10-27 | Beauty & Business S P A | COMPOSITION TO DECOLORATE AND COLOR THE KERATIN FIBER |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0642783B1 (en) * | 1993-09-14 | 1996-03-06 | GOLDWELL GmbH | Composition for simultaneously coloring and lightening human hair |
-
1997
- 1997-05-24 DE DE1997121785 patent/DE19721785C1/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0642783B1 (en) * | 1993-09-14 | 1996-03-06 | GOLDWELL GmbH | Composition for simultaneously coloring and lightening human hair |
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| EP1040821B2 (en) † | 1999-03-31 | 2005-10-12 | L'oreal | Cosmetic composition comprising at least one powdery phase, a hydrating agent and a galactomannane derivative and its uses |
| WO2000076469A1 (en) * | 1999-06-15 | 2000-12-21 | Revlon Consumer Products Corporation | One step method and compositions for simultaneously coloring and highlighting hair |
| KR100853581B1 (en) * | 2000-01-19 | 2008-08-21 | 아텍 시스템즈 그룹, 인코포레이티드 | One-step bleaching and dyeing composition of hair and its use |
| EP1251823A4 (en) * | 2000-01-19 | 2006-04-12 | Artec Systems Group Inc | One-step bleach and coloring composition for hair and method of using same |
| EP1129688A1 (en) * | 2000-02-10 | 2001-09-05 | Bristol-Myers Squibb Company | Hair coloring composition using an inorganic peroxymonosulfate salt as an oxidation agent. |
| WO2002032383A3 (en) * | 2000-10-19 | 2002-10-10 | Henkel Kgaa | Novel use of short-chained carboxylic acids |
| WO2002032386A3 (en) * | 2000-10-19 | 2002-11-07 | Henkel Kgaa | Novel use of short-chained carboxylic acids |
| WO2002045666A3 (en) * | 2000-12-09 | 2002-08-22 | Henkel Kgaa | Novel use of protein hydrolysates |
| EP1372581A4 (en) * | 2001-03-19 | 2005-04-20 | Avant Garde Inc L | Composition for simultaneously lightening and coloring hair utilizing bleach-stable acid and basic dyes |
| EP1372581B1 (en) | 2001-03-19 | 2015-12-23 | L'Avant Garde Inc. | Composition for simultaneously lightening and coloring hair utilizing bleach-stable acid and basic dyes |
| US7189265B2 (en) | 2001-03-19 | 2007-03-13 | L'avant Garde, Inc. | Composition for simultaneously lightening and coloring hair utilizing bleach-stable acid and basic dyes |
| JP2007186520A (en) * | 2001-03-19 | 2007-07-26 | L'avant Garde Inc | A composition for lightening and coloring the hair using a stable acidic and basic pigment as a depigmenting agent |
| WO2004078150A1 (en) * | 2003-03-06 | 2004-09-16 | Wella Aktiengesellschaft | Agent for simultaneously dying and brightening keratin fibers |
| WO2005051336A1 (en) * | 2003-11-21 | 2005-06-09 | Henkel Kommanditgesellschaft Auf Aktien | Method for dyeing fibres containing keratine |
| US7413579B2 (en) | 2003-11-21 | 2008-08-19 | Henkel Kommanditgesellschaft Auf Aktien | Method for dyeing fibers containing keratin |
| WO2006039990A1 (en) * | 2004-10-12 | 2006-04-20 | The Procter & Gamble Company | Colouring agents containing cationic indazoline-thiazolazo dyes- |
| WO2009010883A3 (en) * | 2007-07-03 | 2010-08-19 | L'oreal | Methods and kits for permanently coloring hair using persulfates, perborates or percarbonates |
| US7905926B2 (en) | 2007-07-03 | 2011-03-15 | L'oréal | Methods and kits for permanently coloring hair |
| CN101980750B (en) * | 2007-07-03 | 2015-10-14 | 欧莱雅 | Use persulfate, perborate or percarbonate by method forever painted for hair and test kit |
| US8163037B2 (en) | 2008-08-29 | 2012-04-24 | L'oreal | Methods and kits for providing lift and then a permanent color to hair |
| WO2010023560A3 (en) * | 2008-08-29 | 2010-05-20 | L'oreal | Methods and kits for permanently coloring hair using persulfates, perborates or percarbonates |
| FR2996123A1 (en) * | 2012-09-28 | 2014-04-04 | Oreal | A CAPILLARY COLORING PROCESS USING AT LEAST ONE ANTHR (AQUIN) ONE DERIVATIVE, A MANGANESE OR ZINC SALT, HYDROGEN PEROXIDE AND (BI) CARBONATE |
| IT201700045844A1 (en) * | 2017-04-27 | 2018-10-27 | Beauty & Business S P A | COMPOSITION TO DECOLORATE AND COLOR THE KERATIN FIBER |
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