DE19702156C1 - Hair styling product giving good elasticity, bounce and shininess - Google Patents

Abstract

Hair treatment agent comprises: (a) natural oils, i.e.cedar-wood oil, crambe oil (from Grambe abyssinica), cameline oil and/or hemp seed oil; and (b) 1 or more film-forming polymers for fixing hair

Description

The invention relates to agents for the treatment of Hair used to make a hairstyle and to care for the Hair can be used advantageously.

There are already numerous products known that treat hair through polymer addition, hold, volume, elasticity, bounce and give shine. These are referred to as styling products Preparations as a gel facilitate shaping, improve as Hairspray the stand and as a setting foam the volume of the Hair. In addition, styling products are said to be next to the hair natural bounce and elasticity a natural Give shine. The shine of the hair is a mirror for Beauty, health and vitality.

The task therefore arises with existing styling products with suitable additives, the elasticity Bounce and above all the shine of human hair further increase. This object can be done according to the invention particularly impressive due to the addition of cedarwood oil to it solve the recipes of well-known styling products.

It has now been found that a hair treatment agent exceeds the beneficial properties of the previously known styling products when it does

• - 0.01 to 10 percent by weight of cedar oil,  
• - 0.01 to 50 weight percent of a film-forming hair setting polymers

and possibly other additives common for hair cosmetics in an organic solvent or a water-based one contains organic solvent mixture.

By adding cedarwood oil, the elasticity is reduced Bounce and hair shine significantly improved. One leads undergo a hair treatment with styling products using or were made without adding cedarwood oil, show with Preparations containing cedarwood oil treated hair a sensory assessment a much more elastic one Feel. Application tests at half-side ver immediately confirm the increase found in the experiment Elasticity and bounce. It also becomes clear that the addition of cedarwood oil to the styling product adds to the shine of the treated hair significantly increased.

The beauty of hair is mainly due to two parameters influenced, namely by the depth of color and the gloss. The Color depth is determined by the proportion of white in the light. Is the white content is high, the color depth is small.

The gloss is determined by the proportion of the straightened reflected light in relation to the diffusely reflected Light. Directed light is emitted on a smooth surface reflected and the surface (the hair) then appears glittering. What additives to styling products the shine of the hair treated with it can increase particularly strongly cannot be predicted. It was therefore surprising that especially by adding cedarwood oil to styling products achieved such a remarkable increase in hair shine can be.  

Cedarwood oil is a collective name for essential oils, which by steam distillation from the wood various Cedar species can be preserved. Above all, they contain sesqui terpenes and vary in their composition at the Little from different types of cedar. Cedarwood oil is commercially available and can, for example from the company IFF, Hamburg or in a purified form from the Merck, Darmstadt.

According to the cedarwood oil in an amount of 0.01 to 10 percent by weight, preferably in an amount of 0.05 up to 1.0 percent by weight together with a synthetic or natural, nonionic, cationic, anionic or amphoteric, film-forming polymers used. Such a thing Polymer in amounts of 0.01 to 50, preferably in Amounts from 0.05 to 20 percent by weight in the hair treatment medium is included, can also be a mixture of several Polymer exist and with the addition of other polymers thickening effect in its hair-setting properties still be modified.

Among film-forming, hair-fixing polymers understood according to the invention such polymers that when used in 0.01 to 5% aqueous, alcoholic or aqueous alcoholic solution are able to get on the hair Deposit polymer film and in this way the hair consolidate.

Suitable synthetic, nonionic, film-forming, hair-fixing polymers in the hair treatment composition according to the invention are homopolymers of vinylpyrrolidone, which, for example, under the trade names LUVISKOL® K from BASF, Ludwigshafen / Germany or PVP-K from ISP, Wayne / New Jersey, USA are sold, as well as homopolymers of N-vinylformamide, which are sold, for example, under the trade name PVF by National Starch / USA. Other synthetic, nonionic, film-forming, hair-setting polymers are for example

• Copolymers of vinyl pyrrolidone and vinyl acetate, which, for example, under the trade names LUVISKOL® VA are sold by BASF;
• - Terpolymers of vinyl pyrrolidone, vinyl acetate and Vinyl propionate, for example, under the Commercial name LUVISKOL® VAP from the company BASF are distributed;
• - Polyacrylamides, for example, among the Trade names AKYPOMINE® P 191 from the CHEM-Y, Emmerich / Germany or SEPIGEL® 305 are sold by SEPPIC / USA;
• - Polyvinyl alcohols, for example, among the Trade names ELVANOL® from Du Pont or VINOL® 523/540 from Air Products / USA to be expelled; or
• - Polyethylene glycols with a molecular weight of 800 to 20,000 g / mol, for example under the Trade names LIPOXOL® 1000 from the company HÜLS Marl / Germany, PLURACOL® E 4000 from the BASF or UPIWAX 20,000 from UPI to be expelled.

Suitable synthetic, film-forming anionic polymers should be mentioned

• - Crotonic acid-vinyl acetate copolymers, for example wise in the form of a 60% solution in Isopro panol / water under the trade name ARISTO FLEX® are marketed by HOECHST;
• - Terpolymers from acrylic acid, ethyl acrylate and N-t Butylacrylamide, such as those under the trade names ULTRAHOLD® 8 and ULTRAHOLD® STRONG from the company BASF.

Natural film-forming polymers or polymers made therefrom by chemical conversion can also be used in the hair treatment composition according to the invention. Have proven themselves

• - Low molecular weight chitosan with a molecular weight weight of 30,000 to 70,000 g / mol;
• - mixtures of oligo-, mono- and disaccharides, which under the trade name C-PUR® from the company Cerestar, Brussels / Belgium;
• - Chinese balm resin;
• - Cellulose derivatives such as hydroxypropyl cellulose a molecular weight of 30,000 to 50,000 g / mol, which, for example, under the trade name NISSO SL® from Lehmann & Voss, Hamburg is distributed;
• - Shellac, in neutralized or unneutralized ter form, as for example under the trade Description Shellac MHP 210 from Pennig, Hamburg is distributed.

Amphoteric polymers can also be used in the invention Hair treatment agents are used. Are suitable for Example copolymers of octylacrylamide, t-butylaminoethyl methacrylate and two or more monomers from the group Acrylic acid, methacrylic acid and their simple esters like them under the trade names Resyn 28-49 10 and Amphomer LV-71 der National Starch / USA are available.

The cationic polymers which can be used according to the invention include copolymers of vinylpyrrolidone with quaternized derivatives of dialkylaminoacrylate and methacrylate, such as vinylpyrrolidone-dimethylaminomethacrylate copolymers quaternized with diethyl sulfate. Such compounds are marketed by the company Gaf Co., New York / USA. Other cationic polymers are, for example

• - that from BASF under the trade name LUVIQUAT® HM550 sold copolymer of vinyl pyrrole dons with vinylimidazolium methochloride;
• - that of the company Calgon, Pittsburgh / USA under the Trade names Merquat® Plus 3300 distributed Terpolymers of dimethyldialylammonium chloride, Sodium acrylate and acrylamide;
• - that of the company ISP / USA under the trade name - Gaffix VC 713 sold terpolymers made of vinyl pyr rolidone, dimethylaminoethyl methacrylate and vinyl carprolactam;
• - that from Amerchol, Edison / USA under the Trade names Polymer IR sold quaternized Ammonium salt made from hydroxyethyl cellulose and a trimethylammonium substituted epoxide;  
• - that of the company Gaf Co., New York / USA under the Trade names Gafquat® HS 100 distributed vinyl pyr rolidone / methacrylamidopropyl trimethylammonium chloride copolymer; and
• - that of the company Goldschmidt, Essen, under the Trade names Abil® Quat 3272 distributed diquater nary polydimethylsiloxane.

The consistency of the hair treatment composition according to the invention can be increased by adding thickeners. Therefor are homopolymers of acrylic acid with a molecular weight from 2,000,000 to 6,000,000 suitable by the company BF Goodrich, Cleveland / USA under the trade name Carbopol or from Protex / France under the trade name Modarez® V 600 PX are sold. That from the company too HOECHST marketed under the trade name Hostacerin® PN 73 Copolymers of acrylic acid and acrylamide (sodium salt) with a molecular weight of 2,000,000 to 6,000,000 and that of the company Alban Muller, Montreuil / France under the Sclerotium gum sold under the trade name Amigel are suitable. Copolymers of acrylic acid and metha are also suitable crylic acid, as under the trade name Carbopol 1342 or Pemulen® TR 1 from GOODRICH / USA.

The hair treatment composition according to the invention contains generally an aliphatic organic solvent Alcohol with 1 to 4 carbon atoms or a mixture of Water with one of the alcohols mentioned. However, it can also other organic solvents in an amount of 0.5 to 90 Weight percent, preferably in an amount of 5 to 50 Weight percent are used, in particular unbranched or branched hydrocarbons such as pentane, Hexane, isopentane and cyclic hydrocarbons such as Cyclopentane and cyclohexane are mentioned.  

Usually, the hair treatment according to the invention medium further known cosmetic additives added are, for example, non-setting, non-ionic polymers such as polyethylene glycol with a molecular weight of about 600 g / mol, non-setting, anionic and natural polymers and mixtures thereof in an amount of preferably 0.01 up to 50 percent by weight. Also perfume oils in an amount of 0.01 up to 5 percent by weight, opacifiers such as ethylene glycol distea rat in an amount of 0.01 to 5 percent by weight, wetting agent or emulsifiers from the classes of anionic, katio African, amphoteric or non-ionic surfactants such as fatty alcohol holsulfates, ethoxylated fatty alcohols, fatty acid alkanolamides like the esters of hydrogenated castor oil fatty acids in one Quantity from 0.1 to 30 percent by weight, also moisturizing agents, dyes, light stabilizers, antioxidants and Preservatives in an amount of 0.01 to 10 weight percent.

The hair treatment composition according to the invention can be further improved by adding the following silicone polymers:
Polydimethylsiloxane (INCI: dimethicone), α-hydro-ω hydroxypolyoxydimethylsilylene (INCI: dimethiconol), cyclic dimethylpolysiloxane (INCI: cyclomethicone), trimethyl (octade cyloxy) silane (INCI: stearoxytrimethylsilane), dimethylsiloxoloyl glycol: dimethylsiloxolyIcol: glycol, INC. Dimethylsiloxane aminoalkylsiloxane copolymer with hydroxyl end groups (INCI: amodimethicone), monomethylpolysiloxane with lauryl side chains and polyoxyethylene and / or polyoxypropylene end chains, (INCI: laurylmethicon copolyol), dimethylsiloxane glycol glycol copolymer acetate (INCI: dimethiconanoxyliloxiloxiloxiloxiloxiloxiloxiloxiloxiloxiloxiloxiloxyliloxyliloxiloxyliloxiloxyliloxyliloxiloxyliloxyliloxyliloxiloxyliloxyliloxyliloxyliloxiloxyliloxyliloxyliloxyliloxiloxyliloxyliloxyliloxyliloxiloxyliloxane) INCI: trimethylsilylamodimethicone). Preferred silicone polymers are: Dimethicone, which are sold, for example, by Wacker, Munich / Germany under the trade name SILOXANE F-221 or by Dow Corning Europe, Brussels / Belgium under the trade name Dow Corning Fluid 200 / 0.65 cs; Cyclomethicones, which are sold, for example, under the trade names DOW CORNING 244 Fluid by Dow Corning Europe, Brussels / Belgium or ABIL® K4 by Goldschmidt / Germany; Dimethiconols, which are sold, for example, under the trade names SILICONE FLUID F-212 by Wacker / Germany or UNISIL® SF-R by UPI.

The names given in parentheses above speak the INCI nomenclature (International Cosmetic Ingredients) as they are used to label cosmetic active ingredients Auxiliaries are determined.

Mixtures of silicone polymers are also suitable, such as Example a mixture of dimethicone and dimethiconol, the for example under the trade name DOW CORNING 1403 Fluid sold by Dow Corning Europe / Belgium becomes.

Other suitable silicone polymers are dimethicone copolyols, which are sold under the trade names SURFACTANT 193 by Dow Corning Europe / Belgium or SILWET® L from Union Carbide / USA are sold; Amodimethicone, for example wise under the trade names SANDOPERMO FE from the company Sandoz / Switzerland or SM 2059 from General Electric / USA to be expelled; Laurylmethicon Copolyol, which under the Trade name DOW CORNING Q2-5200 from Dow Corning Europe / Belgium is distributed; Trimethylsily lamodimethicone, which is sold under the trade names Dow Corning Q2-8220 from Dow Corning Europe / Belgium or SILICONE FLUID F-801 from Wacker / Germany to be expelled; Dimethicon Copolyol Acetate, which is among the Trade names SILICONE FLUID VP or BELSIL® DMC 6033  are distributed by the company Wacker / Germany and Trimethyl (octadecyloxy) silanes (INCI: Stearoxytrimethylsila ne), for example, under the trade name DOW CORNING 580 WAX from Dow Corning Europe / Belgium to be expelled.

The agent according to the invention can be used in various applications tion forms find application, such as in aerosol preparations as foam or as spray, furthermore as non- Aerosol, which by means of a pump or as "Pump and Spray" is used. Use in usual O / W and W / O Emulsions are possible as well as in application forms as a gel, Wax or microemulsion.

The agent according to the invention can also be used as a coloring or nourishing hair treatment agent such as Color fixer and hair conditioner should be formulated.

If the agent according to the invention in the form of an aerosol Hair sprays or aerosol hair lacquer is present, it contains additionally 15 to 85 percent by weight, preferably 25 to 75 Weight percent, of a blowing agent and is in one Bottled pressure vessel.

As blowing agents are, for example, lower alkanes, such as n-butane, i-butane and propane, or also their mixtures with dimethyl ether and, furthermore, gaseous blowing agents, such as N ₂ , N ₂ O and CO _2, as well as at the pressures under consideration Mixtures of the above blowing agents are suitable.

The hair-setting agent according to the invention can also in the form of a mechanical operation with the help of a suitable NEN spray device sprayable non-aerosol hair sprays or of a non-aerosol hair lacquer.  

Such are among mechanical spray devices to understand directions, which is the spraying of a liquid Enable speed without using a blowing agent. As suitable mechanical spraying device can, for example a spray pump or one equipped with a spray valve elastic container in which the cosmetic according to the invention Medium is filled under pressure, the elastic Container expands and from which the agent as a result of the Kon traction of the elastic container when opening the spray valve continuously released, can be used.

Hair treatment is said to treat human Scalp hair especially for the purpose of making a hairstyle or to understand hair care.

Furthermore, with the polymer combination according to the invention the production of concentrations possible, which one reduced water content and / or solvent content exhibit. The concentrates are Storage by adding the required amount of water and / or Solvent into an applicable hair treatment product transferred.

The following examples are intended to illustrate the subject of Explain the invention in more detail:

example 1 Foam strengthener with strong strengthening

0.25 g Cedarwood oil 0.20 g 2-pyrrolidone-5-carboxylic acid 2.00 g Polyvinyl pyrrolidone 0.50 g Chitosan, M = 30,000 to 70,000 g / mol 0.15 g Formic acid, 85% 0.10 g Cetyltrimethylammonium chloride 0.10 g Isopropanol 96.70 g water           100.00 g         

Example 2 Liquid strengthener with strong strengthening

1.00 g Cedarwood oil 1.00 g Vinyl acetate-crotonic acid copolymer, 60% solution in isopropanol / water (ARISTOFLEX® from Hoechst / Germany) 2.58 g Glycerin 50.00 g Ethanol 0.50 g Perfume oil 44.92 g water           100.00 g         

Example 3 Gel-shaped fastener with strong strengthening

1.00 g Cedarwood oil 0.10 g 2-pyrrolidone-5-carboxylic acid 3.00 g Vinyl pyrrolidone-vinyl acetate copolymer 1.00 g Hydroxyethyl cellulose 5.00 g Glycerin 90.75 g water           100.00 g         

Example 4 Foam setting agent for damaged hair

0.15 g Cedarwood oil 2.00 g Polyvinyl pyrrolidone 0.30 g 13% α-hydro-ω-hydroxy-polyoxydimethylsilylene in cyclodimethylpolysiloxane (Dow Corning Q2 1401 from Dow Corning Europe / Belgium) 5.00 g 1,2-propylene glycol 0.10 g Cetyltrimethylammonium chloride 0.10 g Isopropanol 92.25 g water           100.00 g         

Example 5 Foam strengthener for extra strong hold

0.15 g Cedarwood oil 0.10 g 2-pyrrolidone-5-carboxylic acid 2.00 g Polyvinyl pyrrolidone 2.00 g Glucose syrup, 64% oligosaccharides (C-PUR® 01924 from Cerestar / Belgium) 0.30 g Polyoxyethylene (4) lauryl ether 0.10 g Cetyltrimethylammonium chloride 0.10 g Isopropanol 40.00 g Ethanol 55.25 g water           100.00 g         

Example 6 Gel-shaped setting agent with natural polymers

0.15 g Cedarwood oil 5.00 g Glucose syrup, 64% oligosaccharides (C-PUR® 01924 from Cerestar / Belgium) 5.00 g Sorbitol syrup 2.00 g Ergot resin (Sclerotium Gum) 87.85 g water           100.00 g         

Example 7 Spray strengthener for blow drying

0.10 g Cedarwood oil 0.75 g Vinyl pyrrolidone-vinyl acetate copolymer 30.00 g Ethanol 3.00 g Propylene glycol 0.75 g Isopropanol 65.35 g water           100.00 g         

Example 8 Hair wax

0.30 g Cedarwood oil 30.00 g Polyethylene glycol, M = 3,000 g / mol 44.70 g Polyethylene glycol, M = 600 g / mol 15.00 g Glycerin 10.00 g hydrogenated castor oil, ethoxylated with 45 mol ethylene oxide           100.00 g         

Example 9 Non-aerosol hair spray

0.15 g Cedarwood oil 0.10 g 2-pyrrolidone-5-carboxylic acid 3.00 g Vinyl pyrrolidone-vinyl acetate copolymer 50.00 g Ethanol 46.75 g water           100.00 g         

Example 10 Nourishing shampoo

0.12 g Cedarwood oil 1.00 g Vinyl pyrrolidone-vinyl acetate copolymer 30.00 g Sodium lauryl ether sulfate 7.00 g Sodium chloride 3.00 g Coconut fatty acid amide propyl betaine 0.40 g hydrogenated castor oil, ethoxylated with 45 mol ethylene oxide 0.20 g Perfume 58.28 g water           100.00 g         

Example 11 Color fastener

0.2500 g Cedarwood oil 3.0000 g Vinyl pyrrolidone-vinyl acetate copolymer 50.0000 g Ethanol 0.2000 g Perfume 0.0700 g 1-amino-4- (2 ', 3'-dihydroxypropyl) amino-5-chloro-2-nitrobenzene 0.0500 g Basic Brown 17 (C.1. 12 251) 0.0023 g Basic Violet 14 (C.1.42 510) 0.0100 g Basic Blue 7 (C.1.42 595) 46.4177 g water           100.00 g         

Example 12 Foam setting concentrate

5.0 g Cedarwood oil 20.0 g Povinylpyrrolidone 10.0 g Dimethylsiloxane-glycol copolymer (Belsil DMC 6031 from Wacker / Germany 65.0 g water           100.00 g         

Claims (5)

1. Agent for the treatment of hair, characterized in that it

• - 0.01 to 10 weight percent cedarwood oil and
• - 0.01 to 50 percent by weight of a film-forming, hair-fixing polymer

in an organic solvent or a water-containing organic solvent mixture. 2. Composition according to claim 1, characterized in that it the film-forming, hair-fixing polymer in an amount of Contains 0.5 to 20 percent by weight. 3. Composition according to claim 1 to 2, characterized in that it is the cedarwood oil in an amount of 0.05 to 1.0 weight percent contains. 4. Means according to claim 1, characterized in that it as an organic solvent with an aliphatic alcohol 1 to 4 carbon atoms or a mixture of water with contains one of the alcohols mentioned. 5. Agent according to claims 1 to 4, characterized records that there are other additives common for hair cosmetics contains substances.