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DE1213779B - Process for the homogeneous connection of old and fresh hydraulically setting building materials with the help of an organic binding agent - Google Patents

Process for the homogeneous connection of old and fresh hydraulically setting building materials with the help of an organic binding agent

Info

Publication number
DE1213779B
DE1213779B DEC25779A DEC0025779A DE1213779B DE 1213779 B DE1213779 B DE 1213779B DE C25779 A DEC25779 A DE C25779A DE C0025779 A DEC0025779 A DE C0025779A DE 1213779 B DE1213779 B DE 1213779B
Authority
DE
Germany
Prior art keywords
old
fresh
help
building materials
aqueous dispersion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DEC25779A
Other languages
German (de)
Inventor
Dipl-Chem Dr Gerhart Benz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gruenau Illertissen GmbH
Original Assignee
Chemische Fabrik Gruenau AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemische Fabrik Gruenau AG filed Critical Chemische Fabrik Gruenau AG
Priority to DEC25779A priority Critical patent/DE1213779B/en
Publication of DE1213779B publication Critical patent/DE1213779B/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48Macromolecular compounds
    • C04B41/4857Other macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/61Coating or impregnation
    • C04B41/62Coating or impregnation with organic materials
    • C04B41/63Macromolecular compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Description

Verfahren zum homogenen Verbinden von alten und frischen hydraulisch abbindenden Baustoffen mit Hilfe eines organischen Bindemittels Es ist bekannt, alten Beton mit frischem dadurch homogen zu verbinden, daß man dazwischen eine selbständige Zwischenschicht bildet. Diese Zwischenschicht kann aus Füllstoffen und Polyvinylacetat oder aus Mischpolymerisaten, wie Polyvinylacetat und Polyvinylchlorid oder Polyvinylacetat und Polyvinylarylsäureester bestehen. Die organischen Verbindungen werden hierbei in Form einer wäßrigen Dispersion verwendet. Man kann auch den alten Beton mit einer Mischung aus Polyvinylacetatemulsion und einer wäßrigen Lösung von Kondensationsharzen, vorzugsweise Harnstoffharz, grundieren. Alle diese Haftbrücken haben den Nachteil, daß sie nicht wasserfest sind. Bei Einwirkung von Feuchtigkeit wird Polyvinylacetat verseift oder verliert durch andere Gründe seine Haftung an den Beton. Der Reparaturmörtel läßt sich mit der Zeit durch mechanische Beanspruchung entfernen oder löst sich von selbst ab.Process for the homogeneous connection of old and fresh hydraulically setting building materials with the help of an organic binder It is known to combine old concrete with fresh one homogeneously by having an independent one in between Forms intermediate layer. This intermediate layer can be made from fillers and polyvinyl acetate or from copolymers such as polyvinyl acetate and polyvinyl chloride or polyvinyl acetate and polyvinyl arylic acid esters. The organic compounds are here used in the form of an aqueous dispersion. You can also remove the old concrete with a Mixture of polyvinyl acetate emulsion and an aqueous solution of condensation resins, preferably urea resin. All of these adhesive bridges have the disadvantage that they are not waterproof. When exposed to moisture, it becomes polyvinyl acetate saponifies or loses its adhesion to the concrete for other reasons. The repair mortar can be removed or loosened over time through mechanical stress by itself.

Es wurde nun überraschenderweise gefunden, daß wäßrige Dispersionen von Polyvinylpropionat beim Verbinden von altem mit neuem Mörtel oder Beton die guten Eigenschaften von Polyvinylacetat besitzen, darüber hinaus aber auch noch wasserfest sind. Mit Hilfe derartiger Dispersionen verbundene Schichten von Mörtel oder Beton sind wasserfest und können daher auch für Bauten im Freien oder in einer feuchten Umgebung verwendet werden. Die Haftfestigkeit von Polyvinylpropionat ist besser als die von Polyvinylacetat. In einem alkalischen Medium ist das Polyvinylpropionat schwerer verseifbar.It has now surprisingly been found that aqueous dispersions of polyvinyl propionate when joining old with new mortar or concrete have good properties of polyvinyl acetate, but also still are waterproof. Layers of mortar bonded together with the aid of such dispersions or concrete are waterproof and can therefore also be used for buildings outdoors or in a humid environment. The adhesive strength of polyvinyl propionate is better than that of polyvinyl acetate. In an alkaline medium, this is polyvinyl propionate more difficult to saponify.

Die erfindungsgemäß verwendeten Dispersionen können, wenn es gewünscht wird, auch noch andere Bindemittel enthalten, z. B. Copolymerisate von Polyvinylpropionat mit anderen polymerisierbaren Stoffen.The dispersions used according to the invention can, if desired will also contain other binders, e.g. B. copolymers of polyvinyl propionate with other polymerizable substances.

Die wäßrigen Dispersionen von Polyvinylpropionat können in an sich bekannter Weise hergestellt werden, wobei gegebenenfalls geringe Mengen von Dispergiermitteln verwendet werden können. Man kann den Dispersionen auch noch Weichmacher zusetzen, z. B. Terpentinöl oder Deka-Hydronaphthalin. In den meisten Fällen genügt es, auf 100 Teile des in der Dispersion vorhandenen Feststoffes 10 Teile Weichmacher zu verwenden. In der Regel empfiehlt es sich, Dispersionen zu verwenden, die etwa 5 bis 50°/o Polyvinylpropionat enthalten.The aqueous dispersions of polyvinyl propionate can in itself be prepared in a known manner, where appropriate small amounts of dispersants can be used. You can also add plasticizers to the dispersions, z. B. turpentine oil or Deka hydronaphthalene. In most cases, it is enough 100 parts of the solid present in the dispersion to 10 parts of plasticizer use. As a rule, it is advisable to use dispersions that are about 5 Contains up to 50% polyvinyl propionate.

Häufig ist es zweckmäßig, mit Dispersionen zu arbeiten, die außer dem Polyvinylpropionat noch Füllstoffe enthalten, z. B. Sand und/oder Zement. Hierbei ist es richtig, verdünntere Dispersionen des Polyvinylpropionats zu verwenden. Meistens nimmt man auf 1 Teil Polyvinylpropionat 0,5 bis 5 Teile Füllstoffe. Bei der Verwendung dieser Dispersionen empfiehlt es sich, feucht auf feucht zu arbeiten. Man geht am besten so vor, daß man den Untergrund reinigt, anfeuchtet und die Dispersion aufträgt. Vor dem Trocknen bringt man dann den feuchten Baustoff auf. Beispiel 1 Ein Untergrund aus altem Beton wird mit Wasser und einem scharfen Besen von allen Verunreinigungen und lockeren Anteilen befreit. Dann trägt man eine 25°/oige wäßrige Dispersion von Polyvinylpropionat mit einem Pinsel auf. Man wartet so lange, bis der Untergrund den Anstrich weitgehend aufgesogen hat, wobei er noch nicht trocken sein darf. Dann bringt man feucht auf feucht den üblichen Frischmörtel oder -beton auf.It is often useful to work with dispersions that except the polyvinyl propionate still contain fillers, e.g. B. sand and / or cement. Here it is correct to use more dilute dispersions of polyvinyl propionate. Usually one takes 0.5 to 5 parts of fillers for 1 part of polyvinyl propionate. When using For these dispersions, it is advisable to work wet on wet. One goes on the best way to do this is to clean the surface, moisten it and apply the dispersion. The moist building material is then applied before drying. Example 1 A subsurface from old concrete is removed from all impurities with water and a sharp broom and loose parts. Then you wear a 25% aqueous dispersion of Polyvinyl propionate with a brush. You wait until the subsurface has largely soaked up the paint, although it must not be dry yet. then the usual fresh mortar or concrete is applied wet on wet.

Beispiel 2 Man reinigt den Untergrund wie im Beispiel 1. Dann trägt man eine wäßrige Dispersion von Polyvinylpropionat auf, die in 100 Teilen 10 Teile Polyvinylpropionat, 2 Teile Terpentinöl, 20 Teile Zement und 20 Teile Sand enthält. Im übrigen arbeitet man so, wie es im Beispiel 1 beschrieben ist.Example 2 The surface is cleaned as in example 1. Then it bears an aqueous dispersion of polyvinyl propionate, 10 parts in 100 parts Contains polyvinyl propionate, 2 parts turpentine oil, 20 parts cement and 20 parts sand. Otherwise the procedure is as described in Example 1.

Claims (6)

Patentansprüche: 1. Verfahren zum homogenen Verbinden von alten und frischen hydraulisch abbindenden Baustoffen mit Hilfe eines organischen Bindemittels, das eine selbständige Zwischenschicht bildet, dadurch gekennzeichnet, daß man als Bindemittel eine wäßrige Dispersion von Polyvinylpropionat verwendet. Claims: 1. Method for the homogeneous connection of old and fresh hydraulically setting building materials with the help of an organic binder, which forms an independent intermediate layer, characterized in that as The binder used is an aqueous dispersion of polyvinyl propionate. 2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß man eine wäßrige Dispersion verwendet, die 5 bis 50 °/o Polyvinylpropionat enthält. 2. Procedure according to claim 1, characterized in that an aqueous dispersion is used, which contains 5 to 50% polyvinyl propionate. 3. Verfahren nach Anspruch 1 oder 2, dadurch gekennzeichnet, daß man eine wäßrige Dispersion verwendet, die Weichmacher und/oder Netzmittel enthält. 3. The method according to claim 1 or 2, characterized in that an aqueous dispersion is used which Contains plasticizers and / or wetting agents. 4. Verfahren nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß man eine wäßrige Dispersion verwendet, die ein Füllmittel enthält. 4. The method according to any one of claims 1 to 3, characterized in that an aqueous dispersion is used which has a Contains filler. 5. Verfahren nach Anspruch 4, dadurch gekennzeichnet, daß man als Füllmittel Sand und/oder Zement verwendet. 5. The method according to claim 4, characterized in that one used as filler sand and / or cement. 6. Verfahren nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, daß man die Dispersion auf einen feuchten Untergrund aufträgt und vor dem Trocknen die neue Schicht aufbringt. In Betracht gezogene Druckschriften: Deutsche Patentschrift Nr. 966 648; deutsche Auslegeschriften Nr. 1061689, 1054 900.6. The method according to any one of the claims 1 to 5, characterized in that the dispersion is applied to a moist substrate applies and applies the new layer before drying. Considered publications: German Patent No. 966,648; German explanatory documents No. 1061689, 1054 900
DEC25779A 1961-12-19 1961-12-19 Process for the homogeneous connection of old and fresh hydraulically setting building materials with the help of an organic binding agent Pending DE1213779B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEC25779A DE1213779B (en) 1961-12-19 1961-12-19 Process for the homogeneous connection of old and fresh hydraulically setting building materials with the help of an organic binding agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEC25779A DE1213779B (en) 1961-12-19 1961-12-19 Process for the homogeneous connection of old and fresh hydraulically setting building materials with the help of an organic binding agent

Publications (1)

Publication Number Publication Date
DE1213779B true DE1213779B (en) 1966-03-31

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DEC25779A Pending DE1213779B (en) 1961-12-19 1961-12-19 Process for the homogeneous connection of old and fresh hydraulically setting building materials with the help of an organic binding agent

Country Status (1)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1265023B (en) * 1966-05-28 1968-03-28 Gruenau Gmbh Chem Fab The use of an aqueous dispersion for the homogeneous bonding of building materials
FR2629832A1 (en) * 1988-04-06 1989-10-13 Warmoctro Bv ADHESIVE PRODUCT FOR LAYERS REPORTED ON CONSTRUCTION MATERIALS AND METHOD FOR BONDING BUILDING MATERIALS WITH AN ADHESIVE PRODUCT

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE966648C (en) * 1951-11-16 1957-08-29 Polychemie Chemie Ingenieur Ge Process for joining two layers and suitable dispersions for this
DE1054900B (en) * 1954-12-09 1959-04-09 Albert Emulsionswerk Ges Mit B Process for firmly bonding fresh and old concrete
DE1061689B (en) * 1956-10-05 1959-07-16 Cela Farbenfabrik C Lagoni & S Binder for the production of concrete-like building materials

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE966648C (en) * 1951-11-16 1957-08-29 Polychemie Chemie Ingenieur Ge Process for joining two layers and suitable dispersions for this
DE1054900B (en) * 1954-12-09 1959-04-09 Albert Emulsionswerk Ges Mit B Process for firmly bonding fresh and old concrete
DE1061689B (en) * 1956-10-05 1959-07-16 Cela Farbenfabrik C Lagoni & S Binder for the production of concrete-like building materials

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1265023B (en) * 1966-05-28 1968-03-28 Gruenau Gmbh Chem Fab The use of an aqueous dispersion for the homogeneous bonding of building materials
FR2629832A1 (en) * 1988-04-06 1989-10-13 Warmoctro Bv ADHESIVE PRODUCT FOR LAYERS REPORTED ON CONSTRUCTION MATERIALS AND METHOD FOR BONDING BUILDING MATERIALS WITH AN ADHESIVE PRODUCT

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