DE1153178B - Use of a deformable silver-metal oxide material for electrical contacts - Google Patents
Use of a deformable silver-metal oxide material for electrical contactsInfo
- Publication number
- DE1153178B DE1153178B DED36488A DED0036488A DE1153178B DE 1153178 B DE1153178 B DE 1153178B DE D36488 A DED36488 A DE D36488A DE D0036488 A DED0036488 A DE D0036488A DE 1153178 B DE1153178 B DE 1153178B
- Authority
- DE
- Germany
- Prior art keywords
- metal oxide
- silver
- deformable
- electrical contacts
- oxide material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K20/00—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
- B23K20/22—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating taking account of the properties of the materials to be welded
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K20/00—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
- B23K20/22—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating taking account of the properties of the materials to be welded
- B23K20/233—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating taking account of the properties of the materials to be welded without ferrous layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K28/00—Welding or cutting not covered by any of the preceding groups, e.g. electrolytic welding
- B23K28/02—Combined welding or cutting procedures or apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/001—Interlayers, transition pieces for metallurgical bonding of workpieces
- B23K35/007—Interlayers, transition pieces for metallurgical bonding of workpieces at least one of the workpieces being of copper or another noble metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
- B23K35/3006—Ag as the principal constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C5/00—Alloys based on noble metals
- C22C5/06—Alloys based on silver
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H1/00—Contacts
- H01H1/02—Contacts characterised by the material thereof
- H01H1/021—Composite material
- H01H1/023—Composite material having a noble metal as the basic material
- H01H1/0237—Composite material having a noble metal as the basic material and containing oxides
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Composite Materials (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Conductive Materials (AREA)
Description
DEUTSCHESGERMAN
PATENTAMTPATENT OFFICE
kl. 40 b-4 -kl. 40 b-4 -
INTESNAT. KL. C 22 CINTESNAT. KL. C 22 C
D 36488 VIa/40bD 36488 VIa / 40b
ANMELDETAG: 1. AUGUST 1959REGISTRATION DATE: AUGUST 1, 1959
BEKANNTMACHUNG DERANMELDUNG UND AUSGABE DER AUSLEGESCHRIFT: 22. AUGUST 196JNOTICE LOGIN AND ISSUE OF THE EDITORIAL: AUGUST 22, 196J
Die Erfindung betrifft die Verwendung eines verformbaren Silber-Metalloxyd-Werkstoffes für elektrische Kontakte.The invention relates to the use of a deformable silver-metal oxide material for electrical Contacts.
Silber-Metalloxyd-Werkstoffe, insbesondere Ag-CdO, eignen sich wegen ihrer geringen Schweißneigung besonders gut als Kontaktwerkstoffe. Die eingeschlossenen Metalloxydpartikel erschweren jedoch eine Verformung, wie sie zur Herstellung von Halbzeug und auch fertiger Kontakte erforderlich ist. Man hat deshalb die Kontakte bisher einzeln aus der noch nicht oxydierten Silber-Metall-Legierung geformt und anschließend die innere Oxydation zur Umwandlung in Silber-Metalloxyd vorgenommen. Dies beansprucht wegen der langen Oxydationszeit viel Zeit. Aus demselben Grunde konnte man auch Halbzeug aus fertigoxydiertem Metalloxyd nicht auf Vorrat legen, um später daraus die jeweils gewünschten Kontaktteile anzufertigen.Silver-metal oxide materials, especially Ag-CdO, are suitable because of their low tendency to weld particularly good as contact materials. However, the enclosed metal oxide particles make it difficult a deformation, as it is necessary for the production of semi-finished products and also finished contacts. For this reason, the contacts have hitherto been formed individually from the not yet oxidized silver-metal alloy and then carried out the internal oxidation for conversion into silver metal oxide. This claims a lot of time because of the long oxidation time. For the same reason you could also use semi-finished products Do not put in stock from ready-oxidized metal oxide, in order to later use the desired contact parts to make.
Eine Verformbarkeit des Kontaktwerkstoffes ist außerdem unbedingt erforderlich, wenn die Verbin- ao dung des Kontaktwerkstoffs mit einem Trägerwerkstoff durch Kaltpreßschweißen erfolgen soll, so daß diese Art der Verbindung von Silber-Metalloxyd-Kontaktwerkstoffen mit ihren Trägern bisher nicht möglich war.Deformability of the contact material is also essential if the connection ao tion of the contact material with a carrier material is to be carried out by cold pressure welding, so that this type of connection of silver-metal oxide contact materials with their carriers has not yet been carried out was possible.
Auch die neuerdings mögliche, nicht zum Stand der Technik gehörende Warmverschweißung solcher Kontaktwerkstoffe (Patentanmeldung D 31214 Ib/49h und entsprechende Auslegeschrift 1122812) erfordert bei der Weiterverarbeitung des geschweißten Rohlings eine ausreichende Duktilität des Silber-Metalloxyd-Werkstoffes. Es hat sich nun überraschend herausgestellt, daß Silber-Metalloxyd-Werkstoffe, in die, wie zur Erniedrigung des elektrischen Widerstands und/ oder zu Verringerung der Materialwanderungserscheinungen bekannt, Spuren anderer Metalle einlegiert sind, den Silber-Metalloxyd-Werkstoff verformbar machen. Als für diesen Zweck vorteilhaft haben sich erfindungsgemäß Zusätze von 0,001 bis 1% Nickel, Eisen, Molybdän, Kobalt, Chrom, Titan und/ oder Vanadium zu dem aus Silber und Metalloxyd bestehenden Rest erwiesen. Diese sehr geringen Zusätze wirken offenbar kornverfeinernd und als Kristallisationskeime für die Ausscheidung des Metalloxyds bei der Oxydation.Also the recently possible hot welding of such contact materials, which does not belong to the state of the art (Patent application D 31214 Ib / 49h and corresponding Auslegeschrift 1122812) required Sufficient ductility of the silver-metal oxide material in the further processing of the welded blank. It has now been found, surprisingly, that silver-metal oxide materials in which how to lower the electrical resistance and / or to reduce the phenomena of material migration known, traces of other metals are alloyed, the silver-metal oxide material is deformable do. According to the invention, additives of 0.001 to 1% have proven advantageous for this purpose Nickel, iron, molybdenum, cobalt, chromium, titanium and / or vanadium to that of silver and metal oxide existing remainder proved. These very small additions apparently have a grain-refining effect and as Crystallization nuclei for the precipitation of the metal oxide during oxidation.
Die üblichen Metalloxyde, z. B. CdO, scheiden sich dadurch nicht mehr nadelig oder in den Korn-Verwendung eines verformbarenThe usual metal oxides, e.g. B. CdO, thereby no longer divide needle-like or in the grain use a deformable one
Silber - Metalloxyd -WerkstoffesSilver - metal oxide material
für elektrische Kontaktefor electrical contacts
Anmelder:Applicant:
Dr. Eugen Dürrwächter DODUCO5
Pforzheim, Westliche 61Dr. Eugen Dürrwächter DODUCO 5
Pforzheim, West 61
Dr. Eugen Dürrwächter, Pforzheim,
ist als Erfinder genannt wordenDr. Eugen Dürrwächter, Pforzheim,
has been named as the inventor
grenzen aus, sondern extrem feinkörnig und etwa kugelig, so daß das Gefüge ohne Bruchgefahr verformbar wird. Die erfindungsgemäßen Zusätze erlauben es auch, bei erheblich höheren Temperaturen als sonst zu oxydieren, ohne daß dadurch grobkörnige Ausscheidungen erhalten werden. Durch die möglichen hohen Oxydationstemperaturen und die feinkörnige Ausscheidung gelingt es so auch, dickere Platten, Stäbe oder Drähte in wirtschaftlich tragbaren Zeiten und mit qualitativ gutem Ergebnis (feinkörnige Ausscheidung auch bei großer Oxydationstiefe, dadurch gut verformbar) durchzuoxydieren. limit, but extremely fine-grained and roughly spherical, so that the structure can be deformed without the risk of breakage will. The additives according to the invention also allow at considerably higher temperatures than otherwise to oxidize without coarse-grained precipitates being obtained as a result. Through the possible high oxidation temperatures and the fine-grained excretion also succeed in thicker ones Plates, rods or wires in economically viable times and with good quality results (fine-grained Precipitation even with great depth of oxidation, thus easily deformable) to oxidize through.
Claims (1)
Deutsche Auslegeschrift Nr. 1 050 551;
USA.-Patentschriften Nr. 2 673 167, 2 830 898.Considered publications:
German Auslegeschrift No. 1 050 551;
U.S. Patent Nos. 2,673,167, 2,830,898.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DED36488A DE1153178B (en) | 1959-08-01 | 1959-08-01 | Use of a deformable silver-metal oxide material for electrical contacts |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DED36488A DE1153178B (en) | 1959-08-01 | 1959-08-01 | Use of a deformable silver-metal oxide material for electrical contacts |
| DED31214A DE1122812B (en) | 1959-08-01 | 1959-08-01 | Use of the pressure welding process, in which no liquid phase occurs, for joining silver-metal-oxide materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1153178B true DE1153178B (en) | 1963-08-22 |
Family
ID=25970977
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DED36488A Pending DE1153178B (en) | 1959-08-01 | 1959-08-01 | Use of a deformable silver-metal oxide material for electrical contacts |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE1153178B (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1279937B (en) * | 1965-08-06 | 1968-10-10 | Rau Fa G | Contact materials based on silver for electrical switch contacts |
| DE2358840A1 (en) * | 1972-11-28 | 1974-05-30 | Chugai Electric Ind Co Ltd | METHOD FOR MAKING ELECTRICAL CONTACTS |
| DE2411322A1 (en) * | 1973-03-22 | 1974-09-26 | Chugai Electric Ind Co Ltd | CONTACT MATERIAL MADE OF SILVER METAL OXIDE |
| DE2432335A1 (en) * | 1973-07-05 | 1975-01-30 | Sumitomo Electric Industries | ELECTRICAL CONTACT MATERIAL |
| DE2428147A1 (en) * | 1973-07-20 | 1975-02-06 | Chugai Electric Ind Co Ltd | ELECTRICAL CONTACT MATERIAL |
| US3933486A (en) * | 1974-02-12 | 1976-01-20 | Chugai Denki Kogyo Kabushiki-Kaisha | Silver-metal oxide composite and method of manufacturing the same |
| US4072515A (en) * | 1973-07-05 | 1978-02-07 | Sumitomo Electric Industries, Ltd. | Electrical contact material |
| DE3232627A1 (en) * | 1981-09-24 | 1983-04-07 | Doduco KG Dr. Eugen Dürrwächter, 7530 Pforzheim | Material for electrical contacts |
| US4462841A (en) * | 1982-04-23 | 1984-07-31 | Mitsubishi Kinzoku Kabushiki Kaisha | Silver-metal oxide alloy electrical contact materials |
| DE3728328A1 (en) * | 1986-08-26 | 1988-03-10 | Matsushita Electric Works Ltd | CONTACT MATERIAL AND METHOD FOR THE PRODUCTION THEREOF |
| DE3816895A1 (en) * | 1987-06-06 | 1988-12-22 | Degussa | USE OF A SILVER-IRON MATERIAL FOR ELECTRICAL CONTACTS |
| DE19607183C1 (en) * | 1996-02-27 | 1997-04-10 | Degussa | Sintered silver@-iron@ alloy for making electrical contacts |
| WO1998006119A1 (en) * | 1996-08-01 | 1998-02-12 | Metalor Contacts Deutschland Gmbh | Method of producing a product from a silver-based contact material, contact material and product produced therefrom |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2673167A (en) * | 1945-12-28 | 1954-03-23 | C S Brainin Company | Electric contact |
| US2830898A (en) * | 1956-10-04 | 1958-04-15 | Metals & Controls Corp | Electrical contact elements |
| DE1050551B (en) * | 1959-02-12 | Siemens Schuckertw erke Aktien gesellschaft Berlin und Erlangen | PuK ermetallic process for the manufacture of a contact material based on silver cadmium ox> d |
-
1959
- 1959-08-01 DE DED36488A patent/DE1153178B/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1050551B (en) * | 1959-02-12 | Siemens Schuckertw erke Aktien gesellschaft Berlin und Erlangen | PuK ermetallic process for the manufacture of a contact material based on silver cadmium ox> d | |
| US2673167A (en) * | 1945-12-28 | 1954-03-23 | C S Brainin Company | Electric contact |
| US2830898A (en) * | 1956-10-04 | 1958-04-15 | Metals & Controls Corp | Electrical contact elements |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1279937B (en) * | 1965-08-06 | 1968-10-10 | Rau Fa G | Contact materials based on silver for electrical switch contacts |
| DE2358840A1 (en) * | 1972-11-28 | 1974-05-30 | Chugai Electric Ind Co Ltd | METHOD FOR MAKING ELECTRICAL CONTACTS |
| DE2411322A1 (en) * | 1973-03-22 | 1974-09-26 | Chugai Electric Ind Co Ltd | CONTACT MATERIAL MADE OF SILVER METAL OXIDE |
| DE2432335A1 (en) * | 1973-07-05 | 1975-01-30 | Sumitomo Electric Industries | ELECTRICAL CONTACT MATERIAL |
| US4072515A (en) * | 1973-07-05 | 1978-02-07 | Sumitomo Electric Industries, Ltd. | Electrical contact material |
| US3933485A (en) * | 1973-07-20 | 1976-01-20 | Chugai Denki Kogyo Kabushiki-Kaisha | Electrical contact material |
| DE2428147A1 (en) * | 1973-07-20 | 1975-02-06 | Chugai Electric Ind Co Ltd | ELECTRICAL CONTACT MATERIAL |
| US3933486A (en) * | 1974-02-12 | 1976-01-20 | Chugai Denki Kogyo Kabushiki-Kaisha | Silver-metal oxide composite and method of manufacturing the same |
| DE3232627A1 (en) * | 1981-09-24 | 1983-04-07 | Doduco KG Dr. Eugen Dürrwächter, 7530 Pforzheim | Material for electrical contacts |
| US4462841A (en) * | 1982-04-23 | 1984-07-31 | Mitsubishi Kinzoku Kabushiki Kaisha | Silver-metal oxide alloy electrical contact materials |
| DE3728328A1 (en) * | 1986-08-26 | 1988-03-10 | Matsushita Electric Works Ltd | CONTACT MATERIAL AND METHOD FOR THE PRODUCTION THEREOF |
| DE3816895A1 (en) * | 1987-06-06 | 1988-12-22 | Degussa | USE OF A SILVER-IRON MATERIAL FOR ELECTRICAL CONTACTS |
| DE19607183C1 (en) * | 1996-02-27 | 1997-04-10 | Degussa | Sintered silver@-iron@ alloy for making electrical contacts |
| WO1998006119A1 (en) * | 1996-08-01 | 1998-02-12 | Metalor Contacts Deutschland Gmbh | Method of producing a product from a silver-based contact material, contact material and product produced therefrom |
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