DE1148804B - Means for protecting against termite damage - Google Patents
Means for protecting against termite damageInfo
- Publication number
- DE1148804B DE1148804B DEF33412A DEF0033412A DE1148804B DE 1148804 B DE1148804 B DE 1148804B DE F33412 A DEF33412 A DE F33412A DE F0033412 A DEF0033412 A DE F0033412A DE 1148804 B DE1148804 B DE 1148804B
- Authority
- DE
- Germany
- Prior art keywords
- hydroxy
- termite damage
- termite
- radical
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 241000256602 Isoptera Species 0.000 title claims description 17
- 230000006378 damage Effects 0.000 title claims description 10
- -1 benzoic acid radical Chemical class 0.000 claims description 8
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- LODHFNUFVRVKTH-ZHACJKMWSA-N 2-hydroxy-n'-[(e)-3-phenylprop-2-enoyl]benzohydrazide Chemical compound OC1=CC=CC=C1C(=O)NNC(=O)\C=C\C1=CC=CC=C1 LODHFNUFVRVKTH-ZHACJKMWSA-N 0.000 claims description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N Salicylic acid Natural products OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 4
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 4
- 229960004889 salicylic acid Drugs 0.000 claims description 4
- 239000005711 Benzoic acid Substances 0.000 claims description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Natural products OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 2
- WZKSXHQDXQKIQJ-UHFFFAOYSA-N F[C](F)F Chemical compound F[C](F)F WZKSXHQDXQKIQJ-UHFFFAOYSA-N 0.000 claims description 2
- 235000010233 benzoic acid Nutrition 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 2
- 239000000463 material Substances 0.000 description 9
- 241000607479 Yersinia pestis Species 0.000 description 6
- 239000000123 paper Substances 0.000 description 6
- 239000002023 wood Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- LVTWXQZCFTXATF-UHFFFAOYSA-N 5-chloro-2-hydroxy-3-methylbenzoic acid Chemical compound CC1=CC(Cl)=CC(C(O)=O)=C1O LVTWXQZCFTXATF-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- HMUNWXXNJPVALC-UHFFFAOYSA-N 1-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical group C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C(CN1CC2=C(CC1)NN=N2)=O HMUNWXXNJPVALC-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000237858 Gastropoda Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 125000003106 haloaryl group Chemical group 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/38—Aromatic compounds
- B27K3/40—Aromatic compounds halogenated
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/06—Nitrogen directly attached to an aromatic ring system
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Forests & Forestry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
Mittel zum Schutz gegen Termitenfraß In tropischen und subtropischen Ländern spielen Termiten als Materialschädlinge eine große Rolle. Zwar verdauen die genannten Schädlinge nur Zellulose, sie zerstören jedoch neben zellulosehaltigen Substanzen auch fast alle anderen Materialien unabhängig von deren Zusammensetzung. So greifen Termiten als Materialschädlinge im weitesten Sinn neben Holz auch Textilien, Dokumentenpapier, Bücher, Elektrogeräte, Isolierungen, Schaltanlagen, Auto- und Maschinenbestandteile, Transportbänder, Straßen- und Wohnungsbau- und Isolierstoffe usw. an. Die angerichteten Schäden sind in den meisten Fällen sehr schwer, weil Termiten als soziale Insekten stets in größeren Verbänden auftreten.Means for protection against termite damage in tropical and subtropical Termites play a major role as material pests in countries. Digest it though the pests mentioned only destroy cellulose, but they also destroy cellulose-containing ones Substances also almost all other materials regardless of their composition. Termites attack textiles as material pests in the broadest sense in addition to wood, Document paper, books, electrical appliances, insulation, switchgear, auto and Machine components, conveyor belts, road and housing construction and insulation materials etc. The damage done is in most cases very serious because Termites as social insects always appear in larger associations.
Da eine unmittelbare Bekämpfung der Schädlinge wegen ihrer versteckten Lebensweise vielfach unmöglich ist, müssen die termitenanfälligen Werkstoffe, also Holz, Textilien, Papier, Kunststoffe, Lacke, Kautschuk, Leder, Bitumen usw., durch entsprechende Ausrüstung mit geeigneten Mitteln vor dem Angriff und der Zerstörung durch Termiten geschützt werden.As an immediate control of the pests because of their hidden Lifestyle is often impossible, the termite-prone materials, so Wood, textiles, paper, plastics, paints, rubber, leather, bitumen, etc., through appropriate equipment with suitable means prior to attack and destruction be protected by termites.
Bei der Anwendung von Termitenschutzmitteln ist es im Gegensatz zu den Insektiziden nicht nötig, daß die Schädlinge vernichtet, d. h. abgetötet werden. Ein Termitenschutzmittel muß lediglich eine langdauernde fraßabweisende Wirkung besitzen, ohne dabei natürlich Qualität und Eigenschaften der betreffenden ausgerüsteten Materialien in ungünstiger Weise zu beeinflussen. Außerdem darf die Anwendung der Termitenabwehr- bzw. -abschreckmittel keine physiologischen Schäden für Menschen und Nutztiere mit sich bringen.When using termite repellants, it is the opposite of the insecticides do not need to destroy the pests, d. H. be killed. A termite repellent only has to have a long-lasting antifouling effect own, without sacrificing of course quality and properties of the equipment in question To influence materials in an unfavorable way. In addition, the application of the Termite repellants or repellants do not cause physiological harm to humans and bring farm animals with them.
Es wurde nun gefunden, daß 2-Hydroxybenzoesäurearylamide, die im Benzoesäurerest mindestens ein Chloratom neben gegebenenfalls einer Methylgruppe oder zwei Nitrogruppen und im Anilidrest mindestens ein Chloratom neben gegebenenfalls einem Trifluormethylrest enthalten, zum Schutz von Materialien der verschiedensten Art gegen Termitenfraß hervorragend geeignet sind. Besonders bewährt haben sich für den genannten Zweck Halogenaryl- bzw. Trifluormethylarylamide der Chlor-, Trifluormethyl-, tert.-Butyl-, Cyclohexyl-, Phenylsalicyl- und Chlorkresotinsäuren und ähnliche. Die erfindungsgemäß zu verwendenden Verbindungen können unter anderem zum Schützen von Holz, Bauplatten, Papier, Textilien, Kunststoffen, Natur- und Synthesekautschuk, Leder, Bitumen, Zementmassen und anderen termitenanfälligen Materialien dienen.It has now been found that 2-hydroxybenzoic acid arylamides in the benzoic acid radical at least one chlorine atom in addition to optionally a methyl group or two nitro groups and in the anilide radical at least one chlorine atom in addition to optionally a trifluoromethyl radical included, to protect materials of various kinds against termite damage are excellently suited. Have proven particularly useful for the stated purpose Haloaryl or trifluoromethylarylamides of chlorine, trifluoromethyl, tert-butyl, Cyclohexyl, phenylsalicyl, and chlorocresotinic acids and the like. According to the invention Connections to be used can be used to protect wood, building boards, Paper, textiles, plastics, natural and synthetic rubber, leather, bitumen, cement compounds and other termite-prone materials.
Aus der deutschen Patentschrift 1024 745 ist bereits die Verwendbarkeit von 2-Oxybenzaniliden bzw. deren O-Acylderivaten als Gastropod'en-Bekämpfungsmittel beschrieben. Weiterhin hat die deutsche Patentschrift 1028 381 die Verwendung der vorgenannten 2-Oxybenzanilide bzw. deren O-Acylderivaten zur Bekämpfung von Wasserschädlingen zum Gegenstand.The usability is already from the German patent specification 1024 745 of 2-oxybenzanilides or their O-acyl derivatives as gastropods control agents described. Furthermore, the German patent specification 1028 381 has the use of the aforementioned 2-oxybenzanilides or their O-acyl derivatives for combating water pests to the subject.
Die hervorragende Eignung von 2-Hydroxybenzoesäurearylamiden als Schutzmittel gegen den Angriff und die Zerstörung der verschiedenartigsten Materialien durch Termiten war dem vorgenannten Schrifttum in keiner Weise zu entnehmen.The excellent suitability of 2-hydroxybenzoic acid arylamides as protective agents against the attack and destruction of the most diverse materials Termites could not be inferred in any way from the aforementioned literature.
Beispiel 1 2 cms einer 0,05'o/oigen Lösung von 2-Hydroxy-3 - methyl- 5 - chlorbenzoesäure- 3',4'- dichloranilid in Aceton werden auf eine 0,5 mm starke Filterscheibe von 9 cm Durchmesser so aufgetragen, daß das Papier gleichmäßig durchtränkt ist. Nach 4tägiger Ausdunstung setzt man 20 Termitenarbeiter in einem Metallring auf die behandelte Papierfläche. Das Papier bleibt während einer Versuchszeit von 72 Stunden unbeschädigt, und auch nach 4monatiger Lagerung im Tropenklima unter ständigem Luftwechsel besitzt die in der oben beschriebenen Weise ausgerüstete Filterscheibe noch gleich gute fraßabweisende Eigenschaften.Example 1 2 cms of a 0.05% solution of 2-hydroxy-3-methyl- 5 - chlorobenzoic acid 3 ', 4'-dichloroanilide in acetone are applied to a 0.5 mm thick A filter disk with a diameter of 9 cm is applied in such a way that the paper is evenly saturated is. After 4 days of evaporation, 20 termite workers are placed in a metal ring onto the treated paper surface. The paper remains during a trial period of 72 hours undamaged, and even after 4 months of storage in a tropical climate below The filter disc equipped in the manner described above has a constant air change equally good anti-fretting properties.
Statt des 2-Hydroxy-3-methyl-5-chlorbenzoesäure-3',4'-dichloranilids können mit gleich gutem Erfolg die folgenden 2-Hydroxybenzoesäurearylamide als Termitenschutzmittel Verwendung finden: 2-Hydroxy-3-methyl-5-chlorbenzoesäure-2',4',5',-trichloranilid, 2-Hydroxy-3-methyl-5-chlorbenzoesäure-4'-chloranilid, 2-Hydroxy-5-chlorbenzoesäure-2'-trifluormethyl-4'-chloranüid, 2-Hydroxy-3,5-dichlorbenzoesäure-2',4',5'-trichloranilid, 2-Hydroxy-4,5-dichlorbenzoesäure-2' fiuor-5'-trifluormethylanilid, 2-Hydroxy-3,5-dinitrobenzoesäure-2',4',5'-trichloranilid, 2-Hydroxy-3,5,6-trichlorbenzoesäure-2',4',5'-trichloranilid, 2-Hydroxy-3,5,6-trichlorbenzoesäure-2'-trifluormethyl-4'-chloranilid. Beispiel 2 Mit Wasser von 50° C angeschlämmtem Defibratorstoff (feinzerfasertes Holz) setzt man alkalisch eingestelltes Phenolformaldehydharz und Paraffin, mit Emulgator dispergiert, zu. Anschließend wird 1% 2-Hydroxy- 3 -methyl-5-chlorbenzoesäure-2',4',5'-trichloranilid, gelöst in etwas Natronlauge, in die Mischung eingerührt, der Brei mit Aluminiumsulfat auf einen pH-Wert von 4 gefällt und zuletzt entwässert. So ausgerüstete Hartfaserplatten erweisen sich als termitenresistent und besitzen selbst nach Lagerung im Tropenklima noch einen guten Schutz gegen Termitenfraß. Beispiel 3 1 Gewichtstei12-Hydroxy-3,5,6-trichlorbenzoesäure-2'-trifluormethyl-4'-chloranilid wird bei 130° C 6 bis 8 Minuten lang in 100 Gewichtsteile Polyäthylen so eingewalzt, daß der Wirkstoff im Polymeren homogen gelöst ist. Derart ausgerüstete Folien oder Kabel aus Polyäthylen sind gegen Termitenfraß resistent.Instead of 2-hydroxy-3-methyl-5-chlorobenzoic acid 3 ', 4'-dichloroanilide can use the following 2-hydroxybenzoic acid arylamides as termite repellants with equal success Find use: 2-Hydroxy-3-methyl-5-chlorobenzoic acid-2 ', 4', 5 ', - trichloroanilide, 2-Hydroxy-3-methyl-5-chlorobenzoic acid-4'-chloroanilide, 2-hydroxy-5-chlorobenzoic acid-2'-trifluoromethyl-4'-chloroanilide, 2-hydroxy-3,5-dichlorobenzoic acid-2 ', 4', 5'-trichloroanilide, 2-hydroxy-4,5-dichlorobenzoic acid-2 ' fluoro-5'-trifluoromethylanilide, 2-hydroxy-3,5-dinitrobenzoic acid-2 ', 4', 5'-trichloroanilide, 2-hydroxy-3,5,6-trichlorobenzoic acid-2 ', 4', 5'-trichloroanilide, 2-hydroxy-3,5,6-trichlorobenzoic acid-2'-trifluoromethyl-4'-chloroanilide. Example 2 Defibrator material (finely fiberized Wood), alkaline phenol-formaldehyde resin and paraffin are added Emulsifier dispersed, too. Then 1% 2-hydroxy-3-methyl-5-chlorobenzoic acid-2 ', 4', 5'-trichloroanilide, dissolved in a little sodium hydroxide solution, stirred into the mixture, the pulp with aluminum sulfate precipitated to a pH value of 4 and drained last. Hardboard panels equipped in this way prove to be termite-resistant and have even after storage in a tropical climate still a good protection against termite damage. Example 3 1 part by weight of 12-hydroxy-3,5,6-trichlorobenzoic acid-2'-trifluoromethyl-4'-chloroanilide is rolled into 100 parts by weight of polyethylene at 130 ° C for 6 to 8 minutes in such a way that that the active ingredient is homogeneously dissolved in the polymer. Such equipped foils or Polyethylene cables are resistant to termite damage.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF33412A DE1148804B (en) | 1961-03-14 | 1961-03-14 | Means for protecting against termite damage |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF33412A DE1148804B (en) | 1961-03-14 | 1961-03-14 | Means for protecting against termite damage |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1148804B true DE1148804B (en) | 1963-05-16 |
Family
ID=7095084
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEF33412A Pending DE1148804B (en) | 1961-03-14 | 1961-03-14 | Means for protecting against termite damage |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE1148804B (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1024745B (en) * | 1955-09-26 | 1958-02-20 | Bayer Ag | Gastropod antipoders |
| DE1028381B (en) * | 1956-12-13 | 1958-04-17 | Bayer Ag | Control of aquatic pests |
-
1961
- 1961-03-14 DE DEF33412A patent/DE1148804B/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1024745B (en) * | 1955-09-26 | 1958-02-20 | Bayer Ag | Gastropod antipoders |
| DE1028381B (en) * | 1956-12-13 | 1958-04-17 | Bayer Ag | Control of aquatic pests |
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